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Conference Record of the Twenty Fifth IEEE Photovoltaic Specialists Conference - 1996最新文献

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Surface recombination at the Si/SiO/sub 2/ overgrowth interface Si/SiO/sub /过生长界面处的表面复合
D.D. Smith, D. Aiken, A. M. Barnett
Thin silicon solar cells must meet several requirements for high efficiency. These are minority carrier diffusion lengths exceeding the active layer thickness, enhanced absorption from light trapping, and passivation of all surfaces bounding the active region. A thin silicon solar cell will in general be supported by a foreign substrate. This approach will produce a buried interface which will not allow for characterization of surface recombination by short wavelength spectral response. New methods must be developed to measure and control surface recombination at a buried interface. A gated diode device structure is proposed for this purpose. The gate will be formed at the buried interface. Varying the gate bias is expected to control carrier populations due to field effect, and hence the recombination rate at the back surface. In this work, a thin layer of single crystal silicon is formed on the gate structure by epitaxial lateral overgrowth (ELO) using liquid phase epitaxy. The dielectric insulator is currently thermally grown SiO/sub 2/. This device structure could enable control of buried surface recombination for a wide variety of substrate materials.
薄硅太阳能电池必须满足几个要求才能获得高效率。这些是超过活性层厚度的少数载流子扩散长度,光捕获的吸收增强,以及活性区域周围所有表面的钝化。薄硅太阳能电池通常由外来衬底支撑。这种方法将产生一个埋藏界面,这将不允许表征表面复合的短波长光谱响应。必须开发新的方法来测量和控制埋藏界面的表面复合。为此提出了一种门控二极管器件结构。闸门将在埋藏界面处形成。改变栅极偏置可以控制由场效应引起的载流子数量,从而控制后表面的复合率。在本研究中,利用液相外延技术在栅极结构上通过外延横向过生长(ELO)形成单晶硅薄层。介质绝缘体目前是热生长SiO/ sub2 /。该器件结构可以控制多种衬底材料的埋藏表面重组。
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引用次数: 1
Reaction analysis of the formation of CIS at temperatures from 250 to 400/spl deg/C 在250 ~ 400℃温度下形成CIS的反应分析
N. Orbey, H. Hichri, R. Birkmire, T. Russell
A chemical reaction analysis of the selenization of copper indium layers to form copper indium diselenide is presented. Time progressive selenizations were carried out in a tubular laminar flow reactor in a dilute H/sub 2/Se atmosphere at 250, 325 and 400/spl deg/C. The reacted films were analyzed by X-ray diffraction and atomic absorption spectroscopy. The chemical species present in the reacted films were identified and a reaction network for film formation is proposed. The data from time progressive selenizations were analyzed to obtain species concentration profiles. Rate expressions were postulated and a mathematical model for the selenization was developed. The behavior of the model is compared with the experimentally determined species concentrations to obtain specific reaction rate constants at each temperature and the activation energies. This information is needed for the design and process control of commercial scale selenization reactors.
介绍了铜铟层硒化生成二硒化铜铟的化学反应分析。在250、325和400℃的稀H/sub 2/Se气氛下,在管状层流反应器中进行了时间渐进硒化。用x射线衍射和原子吸收光谱对反应膜进行了分析。确定了反应膜中存在的化学物质,并提出了成膜的反应网络。对时间渐进硒化的数据进行分析,得到物种浓度分布。假设了反应速率表达式,建立了硒化反应的数学模型。将模型的行为与实验确定的物质浓度进行比较,得到了各温度下的反应速率常数和活化能。这些信息对于商业规模的硒化反应器的设计和过程控制是必要的。
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引用次数: 4
Environmental issues related to commercialization of CuInSe/sub 2/-based photovoltaics 与基于CuInSe/sub - 2/的光伏商业化有关的环境问题
C. Eberspacher, V. Fthenakis, P. Moskowitz
One of the most promising materials for low-cost thin film photovoltaic cells is copper indium selenide (CuInSe/sub 2/ or CIS). As with any new material, successful commercialization of CIS photovoltaic (PV) technology will require attention to environmental issues related to the sources of raw materials, their usage, and the disposal and/or recycling of products at the end of their useful life. This paper focuses on three specific environmental issues related to CIS technology: (i) economics of the use and re-use of materials; (ii) regulations on environmental disposal and waste handling; and (iii) logistics and economics of recycling and disposal of products by industries faced with comparable environmental issues.
硒化铜铟(CuInSe/sub 2/或CIS)是最有前途的低成本薄膜光伏电池材料之一。同任何新材料一样,独联体光电技术的成功商业化将需要注意与原材料来源、其使用以及产品使用寿命结束时的处置和/或回收有关的环境问题。本文着重于与CIS技术相关的三个具体环境问题:(i)材料使用和再利用的经济学;(ii)有关环境处置和废物处理的规例;(三)面临类似环境问题的行业回收和处置产品的物流和经济学。
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引用次数: 3
Radiation-hard, lightweight 12% AM0 BOL InP/Si solar cells 抗辐射,重量轻,12% AM0 BOL InP/Si太阳能电池
S. Wojtczuk, P. Colter, N. Karam, H. Serreze, G. Summers, R. Walters
Indium phosphide (InP) space solar cells were made by Spire on lightweight Si wafers to greatly increase the cell end-of-life (EOL) power density. A NASA-measured best cell efficiency of 12.5% was obtained at one-sun AM0 beginning-of-life (BOL) for a 2/spl times/4 cm cell. Average efficiency for fifteen 2/spl times/2 cm InP heteroepitaxial cells on 16 mil Si wafers tested by NASA was 12.3%. Data are presented comparing 1 MeV electron and 3.9 MeV alpha particle irradiation showing relatively little cell power output degradation out to a very high fluence (less than 20% after a fluence of about 4/spl times/10/sup 16/ 1 MeV electrons/cm/sup 2/, about 40/spl times/ the "standard" fluence). Calculations are presented which show that in very high radiation environments (e.g. van Allen proton belts), these cells can provide over twice as much EOL power density than GaAs/Ge or Si cells.
Spire公司在轻质硅片上制备了磷化铟(InP)空间太阳能电池,大大提高了电池的寿命终止功率密度。nasa测量的最佳细胞效率为12.5%,在一个太阳AM0开始生命(BOL), 2/spl倍/4厘米的细胞。NASA在16mil硅片上测试的15个2/spl次/ 2cm InP异质外延电池的平均效率为12.3%。比较1 MeV电子和3.9 MeV α粒子辐照的数据显示,在非常高的影响下,电池输出功率衰减相对较小(在约4/spl倍/10/sup / 16/ 1 MeV电子/cm/sup 2/,约40/spl倍/“标准”影响下,电池输出功率衰减小于20%)。计算表明,在非常高的辐射环境中(例如范艾伦质子带),这些电池可以提供比GaAs/Ge或Si电池多两倍的EOL功率密度。
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引用次数: 4
Determination of the internal series resistance of CIS and CIGS photovoltaic cell structures CIS和CIGS光伏电池结构内部串联电阻的测定
A. Delahoy, A. Payne
A new method is described to determine the internal series resistance of thin film solar cells. The method involves illumination of a small area of the solar cell with light sufficiently intense to make the internal resistance easily observable. For the CIS and CIGS cells examined, specific internal resistances ranging between 7/spl times/10/sup -2/ and 3/spl times/10/sup -4/ /spl Omega/ cm/sup 2/ were obtained. Such remarkably low values confirm the ability of CIGS to function as a concentrator solar cell.
介绍了一种测定薄膜太阳能电池内部串联电阻的新方法。该方法包括用足够强的光照射太阳能电池的一个小区域,使内阻容易观察到。对于所检测的CIS和CIGS细胞,获得了7/spl倍/10/sup -2/和3/spl倍/10/sup -4/ /spl ω / cm/sup 2/之间的特定内阻。如此低的数值证实了CIGS作为聚光太阳能电池的能力。
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引用次数: 10
Interpretation of capacitance-voltage characteristics in thin-film solar cells using a detailed numerical model 用详细的数值模型解释薄膜太阳能电池的电容电压特性
J. Gray
The objective of this paper is to present a numerical simulation tool that can be used as an aid in the interpretation of the C-V characteristics of thin-film solar cells. The example simulations presented here are for a ZnO/CdS/CuInSe/sub 2/ solar cell, but the simulation tool can be used for a variety of solar cells, including CdTe. Model equations for the simulation of the small-signal behavior of semiconductor devices are presented. Sample simulations incorporating these small-signal equations into a detailed numerical model are interpreted.
本文的目的是提出一种数值模拟工具,可以用作解释薄膜太阳能电池的C-V特性的辅助工具。这里给出的示例模拟是针对ZnO/CdS/CuInSe/sub 2/太阳能电池的,但模拟工具可以用于各种太阳能电池,包括CdTe。给出了模拟半导体器件小信号行为的模型方程。将这些小信号方程纳入详细的数值模型的样本模拟进行了解释。
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引用次数: 4
High-efficiency cell structures and processes applied to photovoltaic-grade Czochralski silicon 应用于光伏级奇克拉尔斯基硅的高效电池结构和工艺
J. Gee, R. King, K. Mitchell
We performed a detailed study to examine the limiting performance available using "photovoltaic-grade" Cz silicon. Photovoltaic-grade silicon refers to silicon produced by the photovoltaic industry, which may differ from the silicon used in the semiconductor device industry in impurity and defect concentrations. The study included optimization of fabrication processes, development of advanced device structures, and detailed model calculations to project future performance improvements. Process and device optimization resulted in demonstration of 75-/spl mu/s bulk lifetimes and 17.6% efficient large-area cells using photovoltaic-grade Cz silicon. Detailed calculations based on the material and device evaluation of the present work project efficiencies of 20% for photovoltaic-grade Cz silicon with properly optimized processing and device structures.
我们进行了一项详细的研究,以检查使用“光伏级”Cz硅的极限性能。光伏级硅是指光伏行业生产的硅,其杂质和缺陷浓度可能与半导体器件行业使用的硅不同。该研究包括制造工艺的优化、先进器件结构的开发以及详细的模型计算,以预测未来性能的改进。工艺和设备优化导致了75-/spl mu/s的体积寿命和17.6%的高效大面积电池使用光伏级Cz硅。在材料和器件评价的基础上,详细计算了目前工作项目效率为20%的光伏级Cz硅,并适当优化了工艺和器件结构。
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引用次数: 6
Cost performance of multi-junction, gallium arsenide, and silicon solar cells on spacecraft 航天器上多结、砷化镓和硅太阳能电池的性价比
E. Gaddy
Spacecraft solar array engineers now have cell choices running from inexpensive and less efficient silicon (Si) cells, to gallium arsenide on germanium (GaAs/Ge) cells, to more expensive and efficient multi-junction (MJ) cells. This paper finds that the more array weight can be reduced by using more efficient cells, even when they are a very expensive option in terms of the array alone, and put into the spacecraft payload i.e. the scientific instruments or in the case of commercial spacecraft, the communications equipment, the more cost effective the spacecraft array system. This is true for a wide variety of spacecraft. This is because of the very high price of launching a spacecraft payload and supporting it with a spacecraft.
航天器太阳能电池阵列工程师现在有多种电池选择,从便宜但效率较低的硅(Si)电池,到锗(GaAs/Ge)上的砷化镓电池,再到更昂贵但效率更高的多结(MJ)电池。本文发现,通过使用更高效的电池可以减少更多的阵列重量,即使它们单独就阵列而言是一个非常昂贵的选择,并放入航天器有效载荷中,即科学仪器或在商业航天器的情况下,通信设备,航天器阵列系统的成本效益越高。对于各种各样的航天器来说都是如此。这是因为发射航天器有效载荷和用航天器支持它的价格非常高。
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引用次数: 11
Technical evaluation of two 6-kW mono-Si photovoltaic systems at the National Renewable Energy Laboratory 国家可再生能源实验室两个6千瓦单硅光伏系统的技术评估
E. Van Dyk, T. Strand, R. Hansen
This paper presents an analysis of performance data on the two 6-kW/sub AC/ grid-connected photovoltaic systems at the National Renewable Energy Laboratory (NREL). The performance parameters analyzed include DC and AC power, aperture efficiency, energy, capacity factor and performance index which are compared to plane-of-array irradiance, ambient temperature, and back-of-module temperature as a function of time, either daily or monthly. Power ratings of the systems were also obtained for data corresponding to different test conditions. This study has shown, in addition to expected seasonal trends, that system monitoring is a valuable tool in assessing performance and detecting faulty equipment. In addition, methods applied for this study may be used to evaluate and compare systems employing different cell technologies.
本文介绍了国家可再生能源实验室(NREL)的两个6千瓦/分交流/并网光伏系统的性能数据分析。分析的性能参数包括直流和交流功率、孔径效率、能量、容量因子和性能指标,这些指标与阵列平面辐照度、环境温度和模块后端温度作为时间的函数(每日或每月)进行比较。根据不同试验条件下的数据,得到了系统的额定功率。这项研究表明,除了预期的季节性趋势外,系统监测是评估性能和检测故障设备的有价值的工具。此外,本研究应用的方法可用于评估和比较采用不同细胞技术的系统。
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引用次数: 1
Line-focus optics for multijunction cells in space power arrays 空间功率阵列中多结电池的线聚焦光学
M. O'neill
Since 1986, ENTECH has been developing lightweight, high-performance Fresnel lens optics for space photovoltaic concentrator systems. This development work has been technically and financially supported by NASA-Lewis, SDIO, BMDO, Boeing, JX Crystals and AEC-ABLE. A fully functional experimental mini-dome Fresnel lens concentrator solar cell array was onboard the PASP Plus mission launched in August 1994. This array, assembled by Boeing using mechanically stacked multijunction (MSMJ) solar cells, confirmed the high-performance and low-radiation-degradation characteristics predicted for the refractive concentrator approach. Since PASP Plus, ENTECH has developed a line-focus Fresnel lens offering much improved manufacturability, cost, and sun-pointing error tolerance. This paper presents the latest line-focus optical designs customized for use with MSMJ cells and with monolithic multijunction (MMJ) cells.
自1986年以来,恩泰克一直致力于开发用于空间光伏聚光系统的轻质、高性能菲涅耳透镜光学系统。这项开发工作得到了NASA-Lewis、SDIO、BMDO、波音、JX Crystals和AEC-ABLE的技术和资金支持。1994年8月发射的PASP Plus任务上装有一个功能齐全的实验性迷你菲涅耳透镜聚光器太阳能电池阵列。该阵列由波音公司使用机械堆叠多结(MSMJ)太阳能电池组装,证实了折光聚光器方法的高性能和低辐射退化特性。自PASP Plus以来,ENTECH开发了一种线聚焦菲涅耳透镜,可大大提高可制造性,成本和太阳指向误差容错性。本文介绍了用于MSMJ电池和单片多结(MMJ)电池的最新线聚焦光学设计。
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引用次数: 8
期刊
Conference Record of the Twenty Fifth IEEE Photovoltaic Specialists Conference - 1996
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