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Conference Record of the Twenty Fifth IEEE Photovoltaic Specialists Conference - 1996最新文献

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High-power density (1040 W/kg) GaAs cells for ultralight aircraft 用于超轻型飞机的高功率密度(1040 W/kg)砷化镓电池
S. Wojtczuk, K. Reinhardt
Ultralight 5 /spl mu/m thick PIN GaAs solar cells were bonded to 3 mm coverglass with 1 mm of adhesive to create very high power density cells for use in ultralight aircraft. Cells were first made on a thick GaAs wafer and then bonded to a coverglass. The GaAs wafer was removed by selectively etching through the wafer to a buried etch stop in the cell epilayers. The cell was completed with a final nonalloyed back metal contact to prevent heat damage to the adhesive, as opposed to a high temperature alloyed contact used in a normal thick p-n GaAs cell. Prototype 1/spl times/1 cm cells were measured by microbalance at an average weight of 0.0228 g/cm/sup 2/ with a one-Sun AMO efficiency up to 17.3% at 28 /spl deg/C (V/sub oc/ 1.024 V, J/sub sc/ 29.9 mA/cm/sup 2/, fill factor 77.4%) for a solar cell power density of 1040 W/kg (weight including coverglass, adhesive and cell).
超轻的5 /spl mu/m厚的PIN - GaAs太阳能电池用1毫米的粘合剂粘接在3毫米的覆盖玻璃上,以制造用于超轻飞机的非常高的功率密度电池。电池首先在厚的砷化镓晶片上制造,然后粘在覆盖玻璃上。通过选择性蚀刻将砷化镓硅片去除到电池涂层中的埋藏蚀刻停止处。与普通厚p-n GaAs电池中使用的高温合金接触相反,该电池完成了最后的非合金背面金属接触,以防止粘合剂的热损伤。在28 /spl度/C (V/sub oc/ 1.024 V, J/sub sc/ 29.9 mA/cm/sup 2/,填充系数77.4%)下,太阳能电池功率密度为1040 W/kg(重量包括覆盖玻璃、粘合剂和电池),1/spl次/1 cm的原型电池平均重量为0.0228 g/cm/sup 2/,单太阳AMO效率高达17.3%。
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引用次数: 8
High efficiency line-focus photovoltaic receivers using optical secondaries for radiation resistance 利用光学二次光抗辐射的高效线聚焦光伏接收器
J. Avery, K. Kimes, P. Custard, L. Fraas, M. Piszczor, M. O'neill
Multijunction GaAs/GaSb solar cells have now been demonstrated in space in a point-focus concentrator module on the PASP Plus flight experiment. The test results on this concentrator module were so impressive that there is now considerable interest in commercializing space concentrator power systems. However, because arched line-focus Fresnel lenses are easier to make than point-focus domed Fresnel lenses and because it is easier to track the Sun using line-focus concentrator modules, JX Crystals has been developing high efficiency line-focus photovoltaic receivers incorporating optical secondaries for radiation resistance. This work is being performed under a NASA SBIR contract with ENTECH as a subcontractor.
多结GaAs/GaSb太阳能电池现在已经在PASP Plus飞行实验的点聚焦集中器模块中进行了空间演示。这种聚光模块的测试结果令人印象深刻,现在人们对将空间聚光电源系统商业化产生了相当大的兴趣。然而,由于弓形线焦菲涅耳透镜比点焦圆顶菲涅耳透镜更容易制造,而且使用线焦聚光器模块更容易跟踪太阳,JX Crystals一直在开发高效率的线焦光伏接收器,其中包含光学二次系统以抵抗辐射。这项工作是根据NASA SBIR合同与ENTECH作为分包商进行的。
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引用次数: 1
Thin film GaAs solar cells on glass substrates by epitaxial liftoff 玻璃基板外延提升的薄膜砷化镓太阳能电池
X. Lee, A. Verma, C.Q. Wu, M. Goertemiller, E. Yablonovitch, J. Eldredge, D. Lillington
In this work, the authors describe the fabrication and operating characteristics of GaAs/AlGaAs thin-film solar cells using the epitaxial liftoff (ELO) technique. This technique allows the transfer of these solar cells onto nonabsorbing glass substrates, and makes possible light-trapping operation. The enhanced performance of the lifted-off solar cell is demonstrated by means of electrical measurements under both dark and illuminated conditions.
在这项工作中,作者描述了利用外延提升(ELO)技术制备GaAs/AlGaAs薄膜太阳能电池和工作特性。这项技术允许将这些太阳能电池转移到不吸收的玻璃基板上,并使光捕获操作成为可能。通过在黑暗和照明条件下的电气测量,证明了提升太阳能电池的增强性能。
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引用次数: 15
A novel, nondestructive, technique using EBIC to determine diffusion lengths in GaAs solar cells 利用EBIC测定砷化镓太阳能电池中扩散长度的一种新颖的、非破坏性的技术
C. Hardingham
A nondestructive technique for measuring minority carrier diffusion lengths in GaAs and other single crystal solar cells is described. The technique relies on the measurement of EBIC (electron beam induced current) from a cell. As the primary beam voltage is varied, the penetration depth of the beam changes. Using a Monte-Carlo simulation of the carrier generation produced by the beam, and solving the minority carrier continuity equation, one can model the current collection. Adjusting the diffusion lengths used in the model, to fit the experimental data, one can determine, with good accuracy, diffusion lengths in the actual device. The technique has been applied to as-made and irradiated cells and used to determine material degradation coefficients.
介绍了一种测量砷化镓和其他单晶太阳能电池中少数载流子扩散长度的无损技术。该技术依赖于从细胞中测量EBIC(电子束感应电流)。随着主光束电压的变化,光束的穿透深度也会发生变化。利用蒙特卡罗模拟光束产生的载流子,并求解少数载流子连续性方程,可以对电流集合进行建模。调整模型中使用的扩散长度,以拟合实验数据,可以很准确地确定实际装置中的扩散长度。该技术已应用于制造和辐照细胞,并用于确定材料降解系数。
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引用次数: 0
Defect chalcopyrite Cu(In/sub 1-x/Ga/sub x/)/sub 3/Se/sub 5/ materials and high Ga-content Cu(In,Ga)Se/sub 2/-based solar cells 缺陷黄铜矿Cu(In/sub 1-x/Ga/sub x/)/sub 3/Se/sub 5/材料和高Ga含量Cu(In,Ga)Se/sub 2/基太阳能电池
M. Contreras, H. Wiesner, D. Niles, K. Ramanathan, R. Matson, J. Tuttle, J. Keane, R. Noufi
Crystallographic, optical, and electrical properties of defect chalcopyrite Cu(In/sub 1-x/Ga)/sub 3/Se/sub 5/ (00.3) is due to a relatively inferior character-both structural and electrical-at the very chalcopyrite/defect chalcopyrite interface. We demonstrate that this situation can be circumvented (for absorbers with x>0.3) by properly engineering such an interface by reducing Ga content in the region near the surface of the absorber.
缺陷黄铜矿Cu(In/sub - 1-x/Ga)/sub - 3/Se/sub - 5/(00.3)的晶体学、光学和电学性质是由于在黄铜矿/缺陷黄铜矿界面处具有相对较差的结构和电学性质。我们证明了这种情况可以避免(对于x>0.3的吸收体),通过减少吸收体表面附近区域的Ga含量来适当地设计这样的界面。
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引用次数: 7
The road to commercialization in the PV industry: a case study of EFG technology 光伏产业的商业化之路:EFG技术的案例研究
E. Henderson, J. Kalejs
The successful commercialization of the PV industry will be a direct function of the effective management of the total cost of its delivered products. A central indicator of this success is a firm's capability to attain and preserve a productivity advantage over its competitors in the market of choice. The interdependency of technical know-how and success in the business climate is measurable along multiple dimensions. Arguably among these indicators are issues related to technical intensity, the willingness and ability to deploy significant technological changes, and certainly sustainable market participation. Several dozen new silicon wafer production technologies have been introduced and taken to various levels of maturity over the past two decades. Here, the authors trace the development of edge-defined film-fed growth (EFG) technology from a fledgling R&D phase to commercialization in this paper within the context of a conventional experience curve for EFG technology.
光伏产业的成功商业化将直接取决于对其交付产品的总成本的有效管理。这种成功的一个中心指标是企业在其选择的市场上获得并保持相对于竞争对手的生产率优势的能力。在商业环境中,技术诀窍和成功之间的相互依赖关系可以从多个维度来衡量。可以说,这些指标包括与技术强度、部署重大技术变革的意愿和能力、当然还有可持续的市场参与有关的问题。在过去的二十年里,几十种新的硅片生产技术已经被引入并达到了不同的成熟程度。在本文中,作者在EFG技术的传统经验曲线的背景下,追溯了边缘定义膜馈式生长(EFG)技术从刚刚起步的研发阶段到商业化的发展。
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引用次数: 5
Development of back junction point contact photovoltaic cells and arrays for space 用于空间的后接点接触光伏电池和阵列的发展
V. Garboushian, G. Turner, S. Yoon, G. Vendura
This paper presents the results of a project to develop back-junction, point-contact silicon solar cells and modules for space. Such cells are already fabricated commercially for terrestrial applications using standardized equipment and processes originally developed for high manufacturing throughput, low-cost semiconductor chip technologies. Individual 2 cm/spl times/2 cm cell outputs of 18%, AM0 are routinely obtained. Since all contacting takes place at the back surface, very high packing densities are possible resulting in comparatively higher output for arrays. The present study is divided into three phases: (1) development of individual cells into a space product, (2) development of rigid and flexible modules (3) and module fabrication for flight experimentation upon the Small Satellite Technology Initiative (SSTI). The first phase focused upon silicon surface and bulk features to increase photon absorption and reduce recombination. The compatibility of the finished cells with space worthy components such as interconnects and coverglasses was confirmed. In the next phase, cells were assembled into small modules. Substrate material included both rigid, 8 mil, silicon wafers as well as flexible, 1 mil Kapton. An interconnection system was developed which consisted of redundant thin-film metal patterns deposited directly on the substrate surfaces. This was followed by a solder reflow bonding process compatible with high volume robotic fabrication equipment. This effort resulted in the fabrication and testing of two SSTI flight modules consisting of a series arrangement of nine 2 cm/spl times/2 cm cells each.
本文介绍了一个开发用于空间的后结点接触硅太阳能电池和组件的项目的结果。这种电池已经商业化,用于地面应用,使用标准化的设备和工艺,最初是为高制造吞吐量、低成本的半导体芯片技术而开发的。单个2cm /spl倍/ 2cm细胞输出18%,常规得到AM0。由于所有接触都发生在背面,因此非常高的填充密度可能导致阵列相对较高的输出。目前的研究分为三个阶段:(1)将单个单元开发为空间产品,(2)开发刚性和柔性模块,(3)以及根据小卫星技术倡议(SSTI)进行飞行实验的模块制造。第一阶段的重点是硅表面和体特征,以增加光子吸收和减少复合。成品电池与有空间价值的组件(如互连和覆盖玻璃)的兼容性得到了证实。在下一阶段,细胞被组装成小模块。衬底材料包括刚性的8mil硅片和柔性的1mil卡普顿硅片。开发了一种由直接沉积在衬底表面的冗余薄膜金属图案组成的互连系统。随后是与大批量机器人制造设备兼容的焊料回流焊工艺。这一努力导致了两个SSTI飞行模块的制造和测试,该模块由9个2厘米/ 1倍/2厘米单元组成。
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引用次数: 4
Effect of porous silicon layer re-emission on silicon solar cell photocurrent 多孔硅层再发射对硅太阳电池光电流的影响
V. Skryshevsky, A. Laugier, V.I. Strikha, V. Vikulov, A. Kaminski
The feasibility of the improvement of crystalline Si solar cells is considered by employing a thick porous Si (PS) layer. The influence of re-emission, absorption and reflectivity of PS on the photocurrent of the solar cell are studied using numerical simulations and experimental verification. The measurement of additional photocurrent caused by re-emission of PS is shown to allow to evaluate the external quantum efficiency of PS photoluminescence which can achieve approximately 4-5% on n-Si. In this case the effect of PS re-emission on short circuit current of commercial solar cells reaches up to a few percent for terrestrial applications. The calculated total benefit of a PS antireflection coating on short-circuit current can be up to 35-41%.
采用厚多孔硅(PS)层对晶体硅太阳能电池性能进行了改进。通过数值模拟和实验验证,研究了聚苯乙烯的再发射、吸收和反射率对太阳能电池光电流的影响。对PS再发射引起的额外光电流的测量表明,可以评估PS光致发光的外部量子效率,在n-Si上可以达到约4-5%。在这种情况下,PS再发射对商用太阳能电池短路电流的影响在地面应用中可达几个百分点。经计算,PS增透涂层对短路电流的总增益可达35-41%。
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引用次数: 5
Influence of humidity on polycrystalline Cu(In,Ga)Se/sub 2/ thin films for solar cells: a study of Na and H/sub 2/O coadsorption 湿度对太阳能电池用多晶Cu(In,Ga)Se/sub 2/薄膜的影响:Na和H/sub 2/O共吸附的研究
C. Heske, G. Richter, Zhonghui Chen, R. Fink, E. Umbach, W. Riedl, F. Karg
Photoelectron spectroscopy (XPS, UPS) has been employed to study the influence of humidity on external and internal surfaces of RTP-processed polycrystalline Cu(In,Ga)Se/sub 2/ thin films for solar cells. Various interactions of deliberately deposited or segregated Na with adsorbed H/sub 2/O have been found. The Na content at the CIGS surface is changed by an H/sub 2/O-induced segregation of Na at low temperatures (100 K) and by reaction and desorption at higher temperatures. Further reactions, such as the passivation of as-deposited "metallic" Na and the formation of a Na-O-CIGS complex influence the electronic structure (i.e. the workfunction and band bending) and are thus of great importance for the electrical performance of corresponding solar cells.
利用光电子能谱(XPS, UPS)研究了湿度对rtp法制备的太阳能电池用多晶Cu(In,Ga)Se/sub 2/薄膜内外表面的影响。发现了有意沉积或分离的Na与吸附的H/sub /O的各种相互作用。低温(100 K)下H/sub / o诱导的Na偏析和高温下的反应和脱附改变了CIGS表面的Na含量。进一步的反应,如沉积“金属”Na的钝化和Na- o - cigs复合物的形成,影响电子结构(即工作函数和能带弯曲),因此对相应的太阳能电池的电性能非常重要。
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引用次数: 5
Use of high back surface reflectance in PV cell design 在光伏电池设计中使用高背表面反射率
P. Iles, C. Chu
The paper describes the factors which control back surface reflectance (BSR) in solar cells. High BSR has been used to reduce operating temperatures for space power solar cells and solar cells operated at high current, under concentrators or in TPV applications. High BSR also increases current in high efficiency Si solar cells.
本文介绍了控制太阳能电池后表面反射率(BSR)的因素。高BSR已用于降低空间动力太阳能电池和在大电流、聚光器或TPV应用下运行的太阳能电池的工作温度。高BSR也增加了高效率硅太阳能电池的电流。
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引用次数: 3
期刊
Conference Record of the Twenty Fifth IEEE Photovoltaic Specialists Conference - 1996
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