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Conference Record of the Twenty Fifth IEEE Photovoltaic Specialists Conference - 1996最新文献

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SUNALYZER-a powerful and cost-effective solar cell I-V tester for the photovoltaic community sunalyzer -一个强大的和具有成本效益的光伏社区太阳能电池I-V测试仪
A. Aberle, T. Lauinger, S. Bowden, S. Wegener, G. Betz
SUNALYZER, a powerful yet cost-effective solar cell I-V tester is introduced. The costs of the optical components are kept at tolerable levels by means of a halogen lamp array. In combination with a computerized height adjuster, this lamp system allows the measurement of a set of illuminated I-V curves covering the intensity range from 0.1 to 4 Suns. Furthermore, the dark I-V curve is measured over a current range of up to 8 orders of magnitude. From these measurements, an analysis subroutine accurately determines the solar cell's series resistance R/sub s.light/ and R/sub s.dark/ as well as the diode ideality factor n and the saturation current density J/sub 0/ as a function of the external current density. Furthermore, design modifications are described which allow for speedy, fully automated illuminated I-V measurements, as required for testing and sorting purposes in solar cell production lines.
SUNALYZER是一款功能强大且具有成本效益的太阳能电池I-V测试仪。通过卤素灯阵列,光学元件的成本保持在可接受的水平。结合计算机高度调节器,该灯系统允许测量一组照明的I-V曲线,覆盖0.1到4太阳的强度范围。此外,暗的I-V曲线在高达8个数量级的电流范围内测量。从这些测量中,分析子程序准确地确定了太阳能电池的串联电阻R/sub .light/和R/sub .dark/以及二极管理想因数n和饱和电流密度J/sub . 0/作为外部电流密度的函数。此外,设计修改描述,允许快速,全自动照明I-V测量,需要在太阳能电池生产线的测试和分类目的。
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引用次数: 9
Progress in triple-junction amorphous silicon alloy solar cells with improved current mismatch in component cells 改善组件电池电流失配的三结非晶硅合金太阳能电池研究进展
J. Yang, X. Xu, A. Banerjee, S. Guha
We have achieved a new world record stable efficiency of 11.8% for amorphous silicon alloy solar cells using a spectrum-splitting, triple-junction structure. In addition to our previously reported key factors leading to high performance multijunction solar cells, we have improved the current matching among the component cells. We have designed the triple structure such that the top cell, which usually exhibits the highest fill factor, remains to be the current-limiting cell in the degraded state. One critical requirement for achieving the desired current matching without sacrificing the triple cell current is to obtain a high quality narrow bandgap bottom cell capable of producing sufficient red current. Details on this narrow bandgap amorphous silicon germanium alloy cell as well as stability data on the triple-junction cell are presented.
我们已经实现了一个新的世界纪录的稳定效率11.8%的非晶硅合金太阳能电池使用光谱分裂,三结结构。除了我们之前报道的导致高性能多结太阳能电池的关键因素外,我们还改进了组件电池之间的电流匹配。我们设计了三重结构,使得通常具有最高填充因子的顶部电池在退化状态下仍然是限流电池。在不牺牲三单元电流的情况下实现所需电流匹配的一个关键要求是获得能够产生足够红电流的高质量窄带隙底单元。详细介绍了这种窄带隙非晶硅锗合金电池以及三结电池的稳定性数据。
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引用次数: 8
Processing evaluations of an automated high-throughput system for interconnecting crystalline silicon solar cells 晶体硅太阳能电池互连自动化高通量系统的工艺评估
M. Nowlan, S. Hogan, J. Patterson, S. Sutherland, J. Murach, W. Breen, G. Darkazalli
The objective of this work is to reduce the cost and improve the quality of terrestrial photovoltaic (PV) modules by developing automated high-throughput (5 MW/yr) processes for interconnecting crystalline silicon solar cells. A new automated processing system was developed for high-throughput, high-yield solar cell interconnection. The results of extensive processing evaluations with a range of different commercially produced cells are reported. Process yields typically exceeded 98%. No degradation in cell performance was observed. Modules made from cell strings fabricated with the new assembly system were subjected to accelerated environmental testing per IEC 1215 and IEEE 1262 standards. Testing consisted of thermal cycling, thermal and humidity-freeze cycling, and damp heat soaking. All modules passed these qualification tests, with an average power loss of only 2.3%.
这项工作的目的是通过开发用于互连晶体硅太阳能电池的自动化高通量(5兆瓦/年)工艺来降低成本并提高地面光伏(PV)模块的质量。研制了一种新型的高通量、高产能太阳能电池互连自动化处理系统。报告了对一系列不同商业生产的细胞进行广泛处理评估的结果。工艺收率通常超过98%。未观察到细胞性能下降。采用新装配系统制造的电池串制成的模块按照IEC 1215和IEEE 1262标准进行加速环境测试。试验包括热循环、热湿冻结循环和湿热浸泡。所有模块都通过了这些资格测试,平均功率损耗仅为2.3%。
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引用次数: 3
Molecular beam epitaxy grown GaInP top cells and GaAs tunnel diodes for tandem applications 分子束外延生长的GaInP顶层电池和GaAs隧道二极管的串联应用
J. Lammasniemi, K. Tappura, R. Jaakkola, A. Kazantsev, K. Rakennus, P. Uusimaa, M. Pessa
Ga/sub 0.51/In/sub 0.49/P solar cells and GaAs tunnel diodes were grown by gas-source molecular beam epitaxy. The effect of various window layer materials, such as Al/sub 0.51/In/sub 0.49/P, Al/sub 0.8/Ga/sub 0.2/As and ZnSe were studied for n-on-p Ga/sub 0.51/In/sub 0.49/P cells. The best carrier collection was obtained with Al/sub 0.51/In/sub 0.49/P window and with graded doping in emitter and base layers. A total-area AM0 efficiency of 14.0% for 2/spl times/2 cm/sup 2/ area has been measured for this cell. The GaAs tunnel diodes were grown with Be-doping for p-type and Si-doping for n-type material. Specific resistance of 0.09 m/spl Omega/cm/sup 2/ and peak tunneling current of 200 A/cm/sup 2/ were obtained for the best GaAs tunnel diodes. In addition, tunneling effect in a n++Ga/sub 0.51/In/sub 0.49/P/p++GaAs diode was observed.
采用气源分子束外延技术制备了Ga/sub 0.51/In/sub 0.49/P太阳能电池和GaAs隧道二极管。研究了Al/sub 0.51/In/sub 0.49/P、Al/sub 0.8/Ga/sub 0.2/ as和ZnSe等不同窗层材料对n-on-p Ga/sub 0.51/In/sub 0.49/P电池的影响。在Al/sub 0.51/In/sub 0.49/P窗口和发射极和基材层中梯度掺杂时,载流子收集效果最好。在2/ sp1次/ 2cm /sup 2/面积下,该电池的AM0效率为14.0%。在p型材料中掺杂be,在n型材料中掺杂si,制备了GaAs隧道二极管。最佳的GaAs隧道二极管比电阻为0.09 m/spl ω /cm/sup 2/,峰值隧穿电流为200 A/cm/sup 2/。此外,在n++Ga/sub 0.51/In/sub 0.49/P/ P ++GaAs二极管中观察到隧穿效应。
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引用次数: 5
Crystal-orientation dependence of surface recombination velocity for silicon nitride passivated silicon wafers 氮化硅钝化硅片表面复合速度的晶体取向依赖性
F. Schuurmans, A. Schonecker, J. Eikelboom, W. Sinke
The crystal-orientation dependence of the surface recombination velocity for silicon nitride coated silicon wafers is investigated and compared with thermal oxides. A qualitative very similar orientation dependence of S/sub eff,d/(/spl Delta/n) for thermal oxide and PECVD nitride coated p-Si wafers etched in diluted HF is found with S/sub eff,d/(/spl Delta/n) (100)<[110]<(111). The type of HF-etch (diluted or buffered HF) prior to deposition has a large influence on S/sub eff,d/ for the nitride coated p-Si wafers. For the nitride coated n-Si wafers etched in diluted HF no orientation dependence of S/sub eff,d/ is observed.
研究了氮化硅包覆硅片表面复合速度与晶体取向的关系,并与热氧化物进行了比较。在稀释HF中蚀刻的热氧化物和PECVD氮化物涂层p-Si晶圆中,S/sub - eff,d/(/spl Delta/n)的取向依赖性定性非常相似,S/sub - eff,d/(/spl Delta/n) <(100)<[110]<(111)。沉积前的HF蚀刻类型(稀释或缓冲HF)对氮化p-Si晶圆的S/sub /,d/有很大影响。对于在稀释HF中蚀刻的氮化氮包覆的n-Si晶片,没有观察到S/sub /,d/的取向依赖性。
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引用次数: 16
Study of buffer layer design in single junction solar cells 单结太阳能电池缓冲层设计研究
Hong Zhu, S. Fonash
Two different approaches to reduce the influence of the solar cell interface have been explored using the authors' AMPS (Analysis of Microelectronics and Photonic Structures) computer program. The two particular approaches they considered both focus on shaping the field at the p layer/absorber interface between a-SiC:H and a-Si:H to enhance p-i-n solar cell performance and in both cases they assume this can be done without introducing any new defects at the interface. The two approaches examined are: (1) the bandgap grading buffer layer; and (2) the doped buffer layer.
利用作者的微电子与光子结构分析(AMPS)计算机程序,探索了两种不同的方法来减少太阳能电池界面的影响。他们考虑的两种特殊方法都侧重于在a-SiC:H和a-Si:H之间的p层/吸收器界面处形成场,以增强p-i-n太阳能电池的性能,在这两种情况下,他们都认为这可以在不引入任何新缺陷的情况下完成。研究的两种方法是:(1)带隙分级缓冲层;(2)掺杂缓冲层。
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引用次数: 3
Record high 18.6% efficient solar cell on HEM multicrystalline material 在HEM多晶材料上创造了18.6%的太阳能电池效率
A. Rohatgi, S. Narasimha, S. Kamra, P. Doshi, C. Khattak, K. Emery, H. Field
Solar cells with efficiencies as high as 18.6% (1 cm/sup 2/ area) have been achieved by a process which involves impurity gettering and effective back surface passivation on 0.65 /spl Omega/-cm multicrystalline silicon (mc-Si) grown by the heat exchanger method (HEM). This represents the highest reported solar cell efficiency on mc-Si to date. PCD analysis revealed that the bulk lifetime (/spl tau//sub b/) in HEM samples after phosphorus gettering can be as high as 135 /spl mu/s. This increases the impact of the back surface recombination velocity (S/sub b/) on the solar cell performance. By incorporating a deeper aluminum BSF, the S/sub b/ for solar cells in this study was lowered from 10000 cm/s to 2000 cm/s on HEM mc-Si. This combination of high /spl tau//sub b/ and moderately low S/sub b/ resulted in the record high efficiency mc-Si solar cell. Model calculations indicate that lowering S/sub b/ further can raise the efficiency of untextured HEM mc-Si solar cells above 19.0%, thus closing the efficiency gap between good quality, untextured single crystal and mc-Si solar cells.
在热交换器法(HEM)生长的0.65 /spl Omega/-cm多晶硅(mc-Si)上,通过杂质捕集和有效的背表面钝化工艺,获得了效率高达18.6% (1 cm/sup 2/面积)的太阳能电池。这代表了迄今为止mc-Si上报道的最高太阳能电池效率。PCD分析表明,吸磷后HEM样品的体积寿命(/spl tau//sub b/)可高达135 /spl mu/s。这增加了后表面复合速度(S/sub b/)对太阳能电池性能的影响。通过加入更深的铝BSF,本研究中太阳能电池的S/sub / b/在HEM mc-Si上从10000 cm/ S降低到2000 cm/ S。这种高/spl τ //sub b/和中等低S/sub b/的组合导致了创纪录的高效率mc-Si太阳能电池。模型计算表明,进一步降低S/sub b/可以使无纹理HEM mc-Si太阳电池的效率提高到19.0%以上,从而缩小了质量好的无纹理单晶与mc-Si太阳电池的效率差距。
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引用次数: 40
Elimination of parasitic effects in floating junction rear surface passivation for solar cells 太阳能电池浮结后表面钝化中寄生效应的消除
C. Honsberg, S. Ghozati, A. Ebong, Y. Tang, S. Wenham
Floating junction (FJ) passivation is a relatively recent passivation scheme which has both experimentally and theoretically demonstrated superior passivation than either oxide or back surface field passivation. In addition, it is suited not only to high efficiency laboratory cells, but also to commercial solar cells. The improvement in surface passivation for commercial cells is an especially critical issue in achieving lower cost solar cells through reducing substrate thickness while simultaneously increasing efficiency. Despite the many advantages of FJ passivation, its applicability has been limited by the apparent inability to translate the excellent modelling results into actual solar cells. The objective of this paper is to present a complete analysis of FJ passivation and to demonstrate a method by which the problems with FJ passivation can be eliminated. Experimental evidence as well as theoretical modelling demonstrates that a solar cell with an optimized rear FJ is insensitive to parasitic effects.
浮结(FJ)钝化是一种相对较新的钝化方案,从实验和理论上都证明了它比氧化物钝化或后表面场钝化有更好的钝化效果。此外,它不仅适用于高效率的实验室电池,也适用于商业太阳能电池。改善商业电池的表面钝化是通过减少衬底厚度同时提高效率来实现低成本太阳能电池的一个特别关键的问题。尽管FJ钝化有许多优点,但由于明显无法将出色的建模结果转化为实际的太阳能电池,其适用性受到限制。本文的目的是对FJ钝化进行完整的分析,并展示一种消除FJ钝化问题的方法。实验证据和理论模型表明,优化后FJ的太阳能电池对寄生效应不敏感。
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引用次数: 16
200 /spl mu/m thick encapsulated amorphous silicon solar cells 200 /spl亩/米厚封装非晶硅太阳能电池
B. Crone, A. Payne, S. Wagner
A 200 /spl mu/m thick fully glass-encapsulated a-Si:H solar cell is demonstrated. The cell structure is 75 /spl mu/m glass foil superstrate/a-Si,N:H diffusion barrier/specular ZnO:Al/a-Si:H pin solar cell/Al. The solar cell is encapsulated with 50 /spl mu/m ethylene vinyl acetate (EVA) and another 75 /spl mu/m glass foil. The current-voltage characteristics of a 0.24 cm/sup 2/ cell measured under AM1.5 (100 mW/cm/sup 2/) light give V/sub OC/=0.83 V, J/sub SC/=11.1 mA/cm/sup 2/, and FF=0.61, for an initial efficiency of 5.6%.
展示了一种200 /spl亩/米厚的全玻璃封装的A - si:H太阳能电池。电池结构为75 /spl mu/m玻璃箔上覆层/a-Si,N:H扩散阻挡层/镜面ZnO:Al/a-Si:H引脚太阳能电池/Al。太阳能电池用50 /磅/米的醋酸乙烯酯(EVA)和另外75 /磅/米的玻璃箔封装。在AM1.5 (100 mW/cm/sup 2/)光下测量的0.24 cm/sup 2/电池的电流-电压特性为V/sub OC/=0.83 V, J/sub SC/=11.1 mA/cm/sup 2/, FF=0.61,初始效率为5.6%。
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引用次数: 1
Test results on DC injection phenomenon of grid connected PV system at Rokko test center 六甲试验中心并网光伏系统直流注入现象的试验结果
A. Kitamura, F. Yamamoto, H. Matsuda, K. Akhmad, Y. Hamakawa
Since power output of a PV system is DC and the commercial grid carriers AC, in any linked system, attention is paid to prevent direct mixture of these two currents. Usually alternating and direct currents mix through the inverter, and because of the great variety in types and specifications, phenomena may be extremely complex. To observe the basic phenomena, demonstration tests were conducted in which direct coupling of PV arrays and the grid have been performed. PV arrays' short circuit current is relatively weak, so the effect on transformers are not so substantial as in the case of a storage battery system linkage. After a certain time exciting current appears, and grows, on the AC side of the transformer. Consequently, with increase of the exciting current when DC and AC powers are mixed, higher harmonic currents appear on the AC side. Breakdown phenomenon on the array side is different depending on whether AC injection happens during an active power generating period, or a passive one and also the existence, or lack, of by-pass diodes or blocking diodes is significant. Blocking diodes prevent larger AC currents from flowing through the solar cells, whereas by-pass diodes let those currents get around the blocking diodes.
由于光伏系统的输出功率是直流电,而商业电网的输出功率是交流电,因此在任何连接系统中,都要注意防止这两种电流的直接混合。通常交流电和直流电通过逆变器混合,由于种类和规格繁多,现象可能极其复杂。为了观察这些基本现象,进行了光伏阵列与电网直接耦合的示范试验。光伏阵列的短路电流相对较弱,因此对变压器的影响不像蓄电池系统联动时那么大。一段时间后,在变压器的交流侧出现并增大励磁电流。因此,当直流和交流混合时,随着励磁电流的增大,交流侧出现了更高的谐波电流。阵列侧的击穿现象取决于交流注入是发生在有功发电时段还是无功发电时段,而且旁路二极管或阻塞二极管的存在与否也很重要。阻塞二极管阻止较大的交流电流过太阳能电池,而旁路二极管则让这些电流绕过阻塞二极管。
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引用次数: 10
期刊
Conference Record of the Twenty Fifth IEEE Photovoltaic Specialists Conference - 1996
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