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Contaminations assessment of some trace metals in agricultural soil and irrigation water analysis at Hail region Saudi Arabia 沙特阿拉伯海尔地区农业土壤中某些微量金属的污染评估和灌溉水分析
IF 1.1 Pub Date : 2021-07-01 DOI: 10.15251/jobm.2021.133.127
A. Al-Bagawi, D. Mansour, S. Aljabri
The suitability of agricultural soil and irrigation water depends on the presence of trace metals; the aim of the present work is to assessment of the trace metals at Hail region using analytical techniques. The metal contaminations levels were determined using ICP-MS and flame photometer. The result obtained were compared to the standard samples suitable for agricultural and it was in the suitable range. The geo-accumulation (I-geo), single pollution, Nemerow pollution indices showed that the Se pollution intensity was significant for agricultural soils. I-geo values revealed no real sign of contamination with almost all the samples, reflecting a lack of contamination for all elements except Zn. While the enrichment factor (EF) for Fe was less than 2 suggested that the elements come entirely from crustal materials or natural processes. The study showed considerable variation in the levels of the analyzed elements in the soil samples. The total metal concentrations in the soil samples ordered as follows: Na > K > Fe > Mn > Zn > Ba > Cr > Ni > Cu > Pb > Cd > As.
农业土壤和灌溉水的适宜性取决于微量金属的存在;本文的目的是利用分析技术对冰雹地区的痕量金属进行评价。采用ICP-MS和火焰光度计测定金属污染水平。所得结果与农用标准样品进行了比较,均在适宜范围内。土壤累积指数(I-geo)、单一污染指数、Nemerow污染指数表明,土壤硒污染强度显著。几乎所有样品的I-geo值都没有显示出污染的迹象,这反映了除Zn外所有元素都没有受到污染。而铁元素的富集因子(EF)小于2,表明铁元素完全来自地壳物质或自然过程。研究表明,土壤样品中所分析元素的含量存在相当大的差异。土壤样品中金属的总浓度依次为:Na > K > Fe > Mn > Zn > Ba > Cr > Ni > Cu > Pb > Cd > as。
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引用次数: 3
Synthesis and Characterization of Bi2O3 NPS and Photocatalytic Application with Methylene Blue Bi2O3 NPS的合成、表征及亚甲基蓝光催化应用
IF 1.1 Pub Date : 2021-06-09 DOI: 10.21203/rs.3.rs-577935/v1
Fowziya Shaik Ali S.A, F. A. Marzouqi, M. Ragamathunnisa, M. IsmailFathima, A. Jahangir, A. Ayeshamariam, K. Kaviyarasu
Nanoparticles of bismuth oxide were successfully synthesized by hydrothermal process which included Bismuth (III) nitrate (Bi(NO3)3.6H2O), sodium hydroxide(NaOH) and Nitric acid(HNO3) without further purification along with ultra-pure water. To investigate the structural, optical, and photocatalytic activity of two samples (1:5) and (1:6) respectively with two different NaOH precipitating agent molar ratios. The prepared nanoparticles were characterized by X-ray diffraction (XRD), UV-Vis’s spectrometer, scanning electron microscope (SEM), Energy-dispersive X-ray spectroscopy (EDAX), Fourier transform infrared spectroscopy (FTIR) and X-ray Photo electron Spectroscopy (XPS). Based on the obtained results the hydrothermally synthesized Bi2O3 NPs exhibit good efficiency to photocatalytic degradation of Methylene blue under the irradiation of LED white light.
以硝酸铋(III)(Bi(NO3)3.6H2O)、氢氧化钠(NaOH)和硝酸(HNO3)为原料,未经超纯水进一步纯化,采用水热法成功合成了纳米氧化铋。研究两种不同NaOH沉淀剂摩尔比的样品(1:5)和(1:6)的结构、光学和光催化活性。通过X射线衍射(XRD)、紫外-可见光谱(UV-Vis)、扫描电子显微镜(SEM)、能量色散X射线光谱(EDAX)、傅立叶变换红外光谱(FTIR)和X射线光电子能谱(XPS)对制备的纳米颗粒进行了表征。基于所获得的结果,水热合成的Bi2O3纳米粒子在LED白光照射下对亚甲基蓝的光催化降解表现出良好的效率。
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引用次数: 4
Simple preparation of a sunshine -like bismuth oxyiodide nanosheets for photocatalytic degradation of organic pollutant under sunlight 光催化降解阳光下有机污染物的类阳光氧碘化铋纳米片的简单制备
IF 1.1 Pub Date : 2021-04-01 DOI: 10.15251/jobm.2021.132.57
F. K. Algethami, M. R. Elamin, B. Abdulkhair
The spread of organic pollutants in water is encountering colossal problems worldwide, and it gets worst as the industry progresses. Among the suggested solutions, heterogenous photocatalysis was progressively applied to degrade organic pollutants. Herein, a simple ethylene glycol refluxing (EGR) method was optimized to fabricate bismuth oxyiodide (BiOI) nanoparticles with a percentage yield of 94.2%. The EGR method's success in preparing BiOI nanomaterial was confirmed by the results of X-ray diffraction, energy dispersive spectroscopy, and Fourier-transform-infrared spectroscopy. The scanning-electron-microscopy and the transmission electron microscopy analysis revealed that the sunshine-like nanosheets are composed of tiny nanoparticles. The BiOI was employed for photocatalytic degradation of organic pollutants under visible light. The adsorption capability of BiOI was investigated prior to its photocatalytic activity, and both investigations showed appealing results. The outcomes of this study nominated both the EGR method for fast preparation of a nanoscale BiOI and the applicability of BiOI as a photocatalyst to swap the organic pollutants from contaminated water using the free-inexhaustible sunlight.
水中有机污染物的扩散在世界范围内都遇到了巨大的问题,随着工业的发展,情况变得越来越糟。在建议的解决方案中,多相光催化逐渐应用于降解有机污染物。本文优化了简单乙二醇回流法制备氧化铋纳米颗粒的工艺,收率为94.2%。x射线衍射、能量色散光谱和傅里叶变换红外光谱结果证实了EGR方法成功制备了BiOI纳米材料。扫描电镜和透射电镜分析表明,类阳光纳米片是由微小的纳米颗粒组成的。利用BiOI在可见光下光催化降解有机污染物。在其光催化活性之前,研究了BiOI的吸附能力,两项研究都取得了令人满意的结果。这项研究的结果既证明了EGR方法可以快速制备纳米级的BiOI,也证明了BiOI作为光催化剂的适用性,可以利用取之不尽、用之不竭的阳光来交换受污染水中的有机污染物。
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引用次数: 0
POTENTIAL APPLICATIONS OF METAMATERIALS IN ANTENNA DESIGN, CLOAKING DEVICES, SENSORS AND SOLAR CELLS: A COMPREHENSIVE REVIEW 超材料在天线设计、隐身装置、传感器和太阳能电池中的潜在应用综述
IF 1.1 Pub Date : 2021-04-01 DOI: 10.15251/jobm.2021.132.23
N. V. Krishna Prasad, T. A. Babu, S. Phanidhar, R. Singampalli, B. R. Naik, M. Sarma, S. Ramesh
This paper reviewed some of the applications of metamaterials in antenna design, cloaking devices, sensors and solar cells in brief. Metamaterials can be used as environment or as part of the antenna. Based on the required parameters, metamaterials while designing antennas are used in various types. They are highly useful in enhancing the power gain, bandwidth, in creating dense and antennas of multiple frequencies. Usage of metamaterial in antenna require proper designing of unit cell. This require creation of cells with special properties at required frequency. Cloaking is a technique of making specific objects invisible. This was achieved by isolating electromagnetic waves in that region. This paper reviewed some of the cloaking devices that use the technique of coordinate transformation and scattering cancellation. Metamaterial sensors which are more efficient than sensors with traditional materials are reviewed. These sensors exhibit enhanced sensitivity. Sensors used in wave guides and liquid chemical detection were reviewed. Solar cells that use metamaterials were reviewed. Usage of these materials reduce the loss in solar radiation making the solar cell more efficient based on the design. Recent design in solar cells concentrate on obtaining maximum reflection through usage of back reflectors and increased absorption
本文简要介绍了超材料在天线设计、隐身器件、传感器和太阳能电池等方面的一些应用。超材料可以用作环境或天线的一部分。根据所需参数,超材料在设计天线时可用于各种类型。它们在增强功率增益、带宽、创建多个频率的密集天线和天线方面非常有用。超材料在天线中的应用需要对晶胞进行适当的设计。这需要以所需的频率创建具有特殊属性的单元。伪装是一种使特定物体不可见的技术。这是通过隔离该区域的电磁波来实现的。本文介绍了一些使用坐标变换和散射消除技术的隐身装置。综述了超材料传感器比传统材料传感器更有效的性能。这些传感器表现出增强的灵敏度。综述了用于波导和液体化学检测的传感器。综述了使用超材料的太阳能电池。这些材料的使用减少了太阳辐射的损失,使得基于设计的太阳能电池更加高效。太阳能电池的最新设计集中在通过使用背反射器和增加吸收来获得最大反射
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引用次数: 0
Recycling of Some Water Soluble Drugs for Corrosion Inhibition of Steel Materials: Analytical and Electrochemical Measurements 几种水溶性药物在钢铁材料缓蚀中的回收利用:分析和电化学测量
IF 1.1 Pub Date : 2021-04-01 DOI: 10.15251/jobm.2021.132.45
R. A. Abdel Hameed, A. M. Al-bonayan
The accumulation of the expired vitamin B6 drugs is hazards for both our child’s and environment, the present research aimed to reuse the expired water soluble drug in its pharmaceutical form as potential non-toxic corrosion inhibitor for steel alloys used in manufacturer of the petroleum pipe lines in 1.0 M HCl. Atomic absorption spectroscopy(AAS) and electrochemical techniques were used to evaluate the corrosion inhibition efficiency, effect of concentrations and temperature were studied, the data show that the inhibition efficiency was increased with concentrations and decreased with temperature. Potentiodynamic polarization data show that the expired vitamin B6 retard both anodic and cathodic potential meaning it is a mixed inhibitor. The electrochemical impedance spectroscopy EIS, techniques data shows that the expired drug help to increases the polarization resistance by adsorbing on metal/electrolyte interface. This kind of adsorption found to obeying Langmuir adsorption isotherm model. The data obtained from the used techniques exhibit good agreement between them with (± 1) to prove that the used expired vitaminB6 medicinal drugs act as eco-friendly corrosion inhibitor for the steel in acidic environment in its pharmaceutical from
过期的维生素B6药物的积累对我们的孩子和环境都有危害,本研究旨在将过期的水溶性药物以其药物形式重新用作1.0M HCl中石油管道制造商使用的钢合金的潜在无毒缓蚀剂。采用原子吸收光谱(AAS)和电化学技术对其缓蚀效果进行了评价,研究了浓度和温度对缓蚀效果的影响,结果表明,缓蚀效果随浓度的增加而增加,随温度的降低而降低。电位动力学极化数据显示,过期的维生素B6阻滞了阳极和阴极电位,这意味着它是一种混合抑制剂。电化学阻抗谱EIS,技术数据表明,过期药物通过吸附在金属/电解质界面上有助于提高极化电阻。发现这种吸附符合Langmuir吸附等温线模型。从所使用的技术中获得的数据与(±1)之间表现出良好的一致性,证明所使用的过期维生素B6药物在其制药中对酸性环境中的钢具有环保的缓蚀剂作用
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引用次数: 17
Plant-mediated green synthesis, characterization and antibacterial efficacy of Ag-NPS using extracts of Wrightia tinctoria leaves for biological application 植物介导的植物绿色合成、表征及生物应用赖特叶提取物Ag-NPS的抑菌效果
IF 1.1 Pub Date : 2021-04-01 DOI: 10.15251/jobm.2021.132.77
N. Charanya Meenu, S. Lakshmi Manokari, T. S. Senthil
Wrightia tinctoria was one of the medicinal plants that contains enormous amount of phytoconstituents with diverse functions and the plant was said to be the safer drug widely used in treating various ailments. In this present work, silver nanoparticles were synthesized using different solvents (benzene, ethanol and aqueous) of Wrightia tinctoria leaves. The prepared nanoparticles are characterized by UV- Vis spectroscopy, FTIR, XRD, FESEM and HRTEM analysis. Biosynthesized silver nanoparticles of ethanol extract showed strong antibacterial activity compared to the nanoparticles synthesized from other extracts against Staphylococcus aureus and Enterococcus faecalis (gram-positive) and Escherichia coli and Klebsiella pneumoniae(gram-negative) bacterial strains by well diffusion method. In this investigation, the selected plant extract and silver nanoparticle were coated on viscose spunlacednonwoven fabrics and subjected to qualitative and quantitative antibacterial studies.
桔梗是一种药用植物,含有大量具有多种功能的植物成分,据说这种植物是广泛用于治疗各种疾病的更安全的药物。在本工作中,使用不同的溶剂(苯、乙醇和水溶液)合成了银纳米颗粒。通过紫外-可见光谱、红外光谱、X射线衍射、FESEM和HRTEM对制备的纳米颗粒进行了表征。与其他提取物通过良好扩散法合成的纳米颗粒相比,乙醇提取物的生物合成银纳米颗粒对金黄色葡萄球菌和粪肠球菌(革兰氏阳性)以及大肠杆菌和肺炎克雷伯菌(革兰氏阴性)菌株显示出较强的抗菌活性。在本研究中,将选定的植物提取物和银纳米粒子涂覆在粘胶水刺非织造布上,并进行了定性和定量抗菌研究。
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引用次数: 0
Studying the biomechanical effects of zirconia implant geometry and bone quality on the bone-implant interface using finite element analysis 采用有限元方法研究氧化锆种植体几何形状和骨质量对骨-种植体界面的生物力学影响
IF 1.1 Pub Date : 2021-04-01 DOI: 10.15251/jobm.2021.132.67
D. Velmurugan, T. Pridhar, T. Yuvaraj, R. Srinivasan, B. Suresh Babu
The success of dental implants is influenced by several biomechanical factors such as implant design, bone quality, length of the implant, and the load transferred to the implant. The present studyaimsto determine the effects of bone quality, implant length, and bone type on stress/strain distribution in bone and implant for a zirconia implant. The study was performed using the three dimensional finite element analysis and four different lengths, two types of implants, and four different bone qualities. The Elastic modulus of a cancellous bone was varied to represent the four different bone qualities. A load of 100 N was applied at the center of the abutment. The result of this current work shows that a bone is subjected to the maximum equivalent stress and strain when the cancellous bone density decreased. The screw type implant induced lesser strain than the cylinder type load. The study also confirms that longer implants produced lesser stain than shorter implants, and type I, and II bones induced lesser stresses than type III, and IV bones. The importance of bone quality has been confirmed from this study, and zirconia dental implants have induced lesser stresses.
种植体的成功与否受多种生物力学因素的影响,如种植体的设计、骨质量、种植体的长度和转移到种植体上的负荷。本研究旨在确定骨质量、种植体长度和骨类型对氧化锆种植体骨和种植体应力/应变分布的影响。研究采用三维有限元分析和四种不同长度、两种类型的种植体和四种不同的骨质量。松质骨的弹性模量是不同的,以代表四种不同的骨质量。在桥台中心施加100牛的荷载。目前的研究结果表明,当松质骨密度降低时,骨受到最大的等效应力和应变。螺钉型植入物比圆柱型植入物产生更小的应变。该研究还证实,较长的植入物比较短的植入物产生的染色更少,I型和II型骨比III型和IV型骨产生的应力更小。本研究证实了骨质量的重要性,氧化锆牙种植体诱导的应力较小。
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引用次数: 0
Energy performance of R22 blended with nanofluids in refrigeration system R22与纳米流体混合制冷系统的能量性能
IF 1.1 Pub Date : 2021-04-01 DOI: 10.15251/jobm.2021.132.33
S. Vandaarkuzhali, J. F. Xavier, R. Ramadoss, V. Jayaseelan, K. Sudhakar
Nanofluids are possible heat transfer fluids with enhanced thermophysical characteristics and heat transfer performance for improved performance in many devices. The thermal behaviour of air conditioning systems using various nano-fluids is described in this study. The nano-fluid chosen for testing is CuO, ZnO and Al2O3, which are combined with the R22 refrigerants with a volume fraction of 0.1 %, 0.3 % and 0.5 % to analyse the airconditioning Performance. The magnetic stirrer is used to disperse nano-particles and ultrasound for approximately 4 hours, dispersing the specified quantity into compressed oil for 2 hours to the appropriate fraction. The model uses the fluid input information to predict fluid output temperatures, operating pressures, compressor power consumption and overall system output. The experimental results show an increase in performance by using 0.5 percent volume with R22base refrigerant when using CuO
纳米流体是可能的传热流体,具有增强的热物理特性和传热性能,可在许多设备中提高性能。本研究描述了使用各种纳米流体的空调系统的热行为。选择CuO、ZnO和Al2O3作为纳米流体进行测试,将其与体积分数分别为0.1%、0.3%和0.5%的R22制冷剂相结合,以分析空调性能。磁力搅拌器用于分散纳米粒子和超声波约4小时,将指定量分散到压缩油中2小时至合适的馏分。该模型使用流体输入信息来预测流体输出温度、操作压力、压缩机功耗和整个系统输出。实验结果表明,当使用CuO时,使用0.5%体积的R22基制冷剂可提高性能
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引用次数: 0
ROLE OF POROUS NANOMATERIAL’S IN WATER PURIFICATION, ELECTRONICS, DRUG DELIVERY AND STORAGE: A COMPREHENSIVE REVIEW 多孔纳米材料在水净化、电子、药物传递和储存中的作用:综述
IF 1.1 Pub Date : 2021-01-01 DOI: 10.15251/jobm.2021.131.11
N. V. Krishna Prasad, T. Anil Babu, M. Sarma, S. Ramesh, K. Nirisha, T. Mathew, N. Madhavi
Nanoporous materials and their study gained tremendous significance in view of their potential applications such as drug delivery, water purification, biosensing, electronics and storage etc. Based on their synthesis with required shape and size make them application oriented. Nanoporous materials are materials with pore size of hundred nanometres or less. They have inorganic or organic framework supporting regular porous structure. The pores in these materials are occupied with fluid. These materials represent a transition from atom to solid in which pores of uniform shape and diameter need to be obtained for them to be used in some applications. Nanoporous materials possess specific electric, optical and magnetic properties that make them highly potential in applications related to signal transmission, energy, biological applications, catalysis, gas storage and medicine. In spite of existing nanoporous by nature tailored materials can be produced with combination of polymers with different melting points. A nanoporous material with accurate pore sizes allow certain matter to pass through, while blocking others. In view of their tailored properties they find extensive applications at present and in near future. Keeping this in mind, an attempt was made to review the potential applications of these materials with more emphasis on water treatment and drug delivery reported in the last five years in a nut shell.
纳米多孔材料在药物输送、水净化、生物传感、电子和存储等方面具有重要的应用前景。在对其形状和尺寸进行综合的基础上,使其具有应用价值。纳米多孔材料是孔径在百纳米或更小的材料。它们具有无机或有机骨架支撑规则的多孔结构。这些材料中的孔隙被流体所占据。这些材料代表了从原子到固体的过渡,其中需要获得均匀形状和直径的孔,以便在某些应用中使用。纳米多孔材料具有特殊的电学、光学和磁性,这使得它们在信号传输、能源、生物应用、催化、气体储存和医学等方面具有很大的应用潜力。尽管现有的纳米多孔材料是天然的,但可以通过不同熔点的聚合物的组合来生产定制材料。具有精确孔径的纳米多孔材料允许某些物质通过,而阻挡其他物质。鉴于其量身定制的特性,它们在目前和不久的将来都有广泛的应用。鉴于此,本文对近五年来这些材料在水处理和给药方面的潜在应用进行了综述。
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引用次数: 1
CORROSION INHIBITION OF STEEL IN MARINE ENVIRONMENT USING AMINO AMIDE DERIVED FROM PET PLASTIC WASTE 从pet塑料废料中提取的氨基酰胺对海洋环境中钢铁的缓蚀作用
IF 1.1 Pub Date : 2021-01-01 DOI: 10.15251/jobm.2021.131.1
R. A. Abdel Hameed, M. AlElaimi, M. Qureshi, S. Al-Mhyawi, A. M. Al-bonayan, M. A. Abd El-Kader
Inhibition of steel from corrosion process in artificial marine environment of 2.0 M sodium chloride solution using amino amide compound derived from Poly (ethylene terephthalate) plastic waste, PET. In this respect solvent free efficient green recycling of PET waste via aminolysis with 1,3-diaminopropane in the presence of (sodium acetate/acetic acid) catalyst, the product is (N, N'-Bis-(3-amino-propyl)-terephthalamide) compound as nonionic surfactant was separated in good yield, characterized by FT-IR and 1HNMR, and evaluated as green corrosion inhibitor for steel alloys used in manufacturer of petroleum pipe lines using electrochemical techniques and atomic absorption spectroscopy(AAS). Effect of inhibitor concentration and temperature were studied. The corrosion inhibition efficiency found to increases with increasing of the inhibitor concentration and decreased by rising the temperature. Potentiodynamic polarization curves indicate that the used system act as mixed inhibitor. The data of AAS show that the ferric ion Fe+3 concentrations were decreased by increasing inhibitor concentration. The inhibition of amino amide compound derived from waste is due to adsorption and adhesion of its molecules on the steel surface which obeys Langmuir desorption isotherm model.
从聚对苯二甲酸乙酯塑料废料中提取的氨基酰胺化合物PET对人工海洋环境中2.0 M氯化钠溶液中钢的缓蚀作用在(乙酸钠/乙酸)催化剂存在下,利用1,3-二氨基丙烷氨解对PET废弃物进行无溶剂高效绿色回收,得到了(N, N’-双-(3-氨基丙基)-对苯二甲酸)化合物作为非离子表面活性剂,分离得到收率高的产物,并用FT-IR和1HNMR对其进行了表征,并利用电化学技术和原子吸收光谱(AAS)对其作为石油管道制造用钢合金的绿色缓蚀剂进行了评价。研究了缓蚀剂浓度和温度的影响。缓蚀剂的缓蚀效率随缓蚀剂浓度的增加而增加,随温度的升高而降低。动电位极化曲线表明,所使用的体系具有混合抑制剂的作用。原子吸收光谱结果表明,随着抑制剂浓度的增加,铁离子Fe+3浓度降低。来源于废弃物的氨基酰胺类化合物的抑制作用是由于其分子在钢表面的吸附和粘附,符合Langmuir解吸等温线模型。
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引用次数: 4
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Journal of Optoelectronic and Biomedical Materials
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