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ROLE OF POROUS NANOMATERIAL’S IN WATER PURIFICATION, ELECTRONICS, DRUG DELIVERY AND STORAGE: A COMPREHENSIVE REVIEW 多孔纳米材料在水净化、电子、药物传递和储存中的作用:综述
IF 1.1 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-01-01 DOI: 10.15251/jobm.2021.131.11
N. V. Krishna Prasad, T. Anil Babu, M. Sarma, S. Ramesh, K. Nirisha, T. Mathew, N. Madhavi
Nanoporous materials and their study gained tremendous significance in view of their potential applications such as drug delivery, water purification, biosensing, electronics and storage etc. Based on their synthesis with required shape and size make them application oriented. Nanoporous materials are materials with pore size of hundred nanometres or less. They have inorganic or organic framework supporting regular porous structure. The pores in these materials are occupied with fluid. These materials represent a transition from atom to solid in which pores of uniform shape and diameter need to be obtained for them to be used in some applications. Nanoporous materials possess specific electric, optical and magnetic properties that make them highly potential in applications related to signal transmission, energy, biological applications, catalysis, gas storage and medicine. In spite of existing nanoporous by nature tailored materials can be produced with combination of polymers with different melting points. A nanoporous material with accurate pore sizes allow certain matter to pass through, while blocking others. In view of their tailored properties they find extensive applications at present and in near future. Keeping this in mind, an attempt was made to review the potential applications of these materials with more emphasis on water treatment and drug delivery reported in the last five years in a nut shell.
纳米多孔材料在药物输送、水净化、生物传感、电子和存储等方面具有重要的应用前景。在对其形状和尺寸进行综合的基础上,使其具有应用价值。纳米多孔材料是孔径在百纳米或更小的材料。它们具有无机或有机骨架支撑规则的多孔结构。这些材料中的孔隙被流体所占据。这些材料代表了从原子到固体的过渡,其中需要获得均匀形状和直径的孔,以便在某些应用中使用。纳米多孔材料具有特殊的电学、光学和磁性,这使得它们在信号传输、能源、生物应用、催化、气体储存和医学等方面具有很大的应用潜力。尽管现有的纳米多孔材料是天然的,但可以通过不同熔点的聚合物的组合来生产定制材料。具有精确孔径的纳米多孔材料允许某些物质通过,而阻挡其他物质。鉴于其量身定制的特性,它们在目前和不久的将来都有广泛的应用。鉴于此,本文对近五年来这些材料在水处理和给药方面的潜在应用进行了综述。
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引用次数: 1
CORROSION INHIBITION OF STEEL IN MARINE ENVIRONMENT USING AMINO AMIDE DERIVED FROM PET PLASTIC WASTE 从pet塑料废料中提取的氨基酰胺对海洋环境中钢铁的缓蚀作用
IF 1.1 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2021-01-01 DOI: 10.15251/jobm.2021.131.1
R. A. Abdel Hameed, M. AlElaimi, M. Qureshi, S. Al-Mhyawi, A. M. Al-bonayan, M. A. Abd El-Kader
Inhibition of steel from corrosion process in artificial marine environment of 2.0 M sodium chloride solution using amino amide compound derived from Poly (ethylene terephthalate) plastic waste, PET. In this respect solvent free efficient green recycling of PET waste via aminolysis with 1,3-diaminopropane in the presence of (sodium acetate/acetic acid) catalyst, the product is (N, N'-Bis-(3-amino-propyl)-terephthalamide) compound as nonionic surfactant was separated in good yield, characterized by FT-IR and 1HNMR, and evaluated as green corrosion inhibitor for steel alloys used in manufacturer of petroleum pipe lines using electrochemical techniques and atomic absorption spectroscopy(AAS). Effect of inhibitor concentration and temperature were studied. The corrosion inhibition efficiency found to increases with increasing of the inhibitor concentration and decreased by rising the temperature. Potentiodynamic polarization curves indicate that the used system act as mixed inhibitor. The data of AAS show that the ferric ion Fe+3 concentrations were decreased by increasing inhibitor concentration. The inhibition of amino amide compound derived from waste is due to adsorption and adhesion of its molecules on the steel surface which obeys Langmuir desorption isotherm model.
从聚对苯二甲酸乙酯塑料废料中提取的氨基酰胺化合物PET对人工海洋环境中2.0 M氯化钠溶液中钢的缓蚀作用在(乙酸钠/乙酸)催化剂存在下,利用1,3-二氨基丙烷氨解对PET废弃物进行无溶剂高效绿色回收,得到了(N, N’-双-(3-氨基丙基)-对苯二甲酸)化合物作为非离子表面活性剂,分离得到收率高的产物,并用FT-IR和1HNMR对其进行了表征,并利用电化学技术和原子吸收光谱(AAS)对其作为石油管道制造用钢合金的绿色缓蚀剂进行了评价。研究了缓蚀剂浓度和温度的影响。缓蚀剂的缓蚀效率随缓蚀剂浓度的增加而增加,随温度的升高而降低。动电位极化曲线表明,所使用的体系具有混合抑制剂的作用。原子吸收光谱结果表明,随着抑制剂浓度的增加,铁离子Fe+3浓度降低。来源于废弃物的氨基酰胺类化合物的抑制作用是由于其分子在钢表面的吸附和粘附,符合Langmuir解吸等温线模型。
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引用次数: 4
MECHANICAL, DEGRADATION AND MORPHOLOGICAL INVESTIGATIONS ON TAMARINDUS INDICA REINFROCED POLY LACTIC ACID BIO-COMPOSITE FOR BIOMEDICAL APPLICATIONS 用于生物医学应用的罗望子复合聚乳酸生物复合物的力学、降解和形态研究
IF 1.1 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-10-01 DOI: 10.15251/jobm.2020.124.121
S. Sachin, A. Kuzmin, C. Thiruvasagam
This research investigates the degradation and mechanical potential of Tamarindus Indiaca Fiber (TIF) reinforced into Poly Lactic Acid (PLA) resulting in a Wood Plastic Composite (WPC) that could be a potential alternative for prosthetic limbs. Fiber weight ratios at 10, 15, 20 and 25 wt%, were processed in micro and nano sizes individually through extrusion. Mechanical investigations were studied to analyze tensile, flexural, impact and hardness properties. Water Absorption Test (WAT) and Thermo Gravimetric Analysis (TGA) were performed for degradation studies. Field Emission Scanning Electron Microscope (FESEM) was used to study morphology. Nano TIF filled WPCs had superior properties than the micro TIF filled WPCs.
本研究调查了Tamarindus Indiaca纤维(TIF)增强为聚乳酸(PLA)的降解和力学潜力,从而产生木塑复合材料(WPC),该材料可能是假肢的潜在替代品。10、15、20和25重量%的纤维重量比分别通过挤出加工成微米和纳米尺寸。进行了力学研究,以分析拉伸、弯曲、冲击和硬度特性。进行了吸水性试验(WAT)和热重分析(TGA)进行降解研究。采用场发射扫描电子显微镜(FESEM)对其形貌进行了研究。纳米TIF填充的WPC具有比微TIF填充WPC优越的性能。
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引用次数: 2
RED SAND SYNTHESIZED SILVER NANOPARTICLES: CHARACTERIZATION AND THEIR BIOMEDICAL POTENTIAL 红砂合成纳米银:表征及其生物医学潜力
IF 1.1 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-10-01 DOI: 10.15251/jobm.2020.124.95
M. Alkhulaifi, M. Alwehaibi, J. Alshehri, M. Awad, N. Aldosari, A. Hendi, K. Ortashi
Since the ability of bacteria to acquire resistance is increasing, it is important to find alternative therapeutics. One possible way to deal with this problem is the use of nanoparticles as possible alternatives to antibiotic therapy. Silver nanoparticles (AgNPs) are viewed as a novel type of antibacterial agents. AgNPs can be synthesized using raw materials, such as red sand that found in nature. Characterization of the AgNPs was achieved using variety spectroscopic and microscopic devises. AgNPs showed antibacterial activity and large effect when combined with different antibiotics against Staphylococcus aureus, Acinetobacter baumannii, Escherichia coli, Salmonella typhimurium, Pseudomonas aeruginosa and Proteus vulgaris.
由于细菌获得耐药性的能力正在增加,因此寻找替代疗法非常重要。解决这个问题的一个可能的方法是使用纳米粒子作为抗生素治疗的可能替代品。银纳米颗粒(AgNPs)被认为是一种新型的抗菌药物。AgNPs可以用原料合成,比如在自然界中发现的红砂。AgNPs的表征是通过各种光谱和显微装置实现的。AgNPs与不同抗生素联用对金黄色葡萄球菌、鲍曼不动杆菌、大肠杆菌、鼠伤寒沙门菌、铜绿假单胞菌和寻常变形杆菌均表现出抑菌活性,且效果显著。
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引用次数: 0
CLEAN UP OF MALACHITE GREEN DYE IN AQUEOUS SOLUTION USING ZnO NANOPOWDER ZnO纳米粉净化水溶液中孔雀绿染料
IF 1.1 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-10-01 DOI: 10.15251/jobm.2020.124.109
H. Idriss, A. Alakhras
Malachite green dye has been known to have toxic carcinogenic characteristics and potential health risks for humans even at low concentrations. Hence, it is very vital to remediate the dye before discharge into water bodies or water treatment systems. Thus, this article demonstrated the removal of cleanup of malachite green (MG)dye from the aquatic phase using ZnO nanopowder. In this work batch adsorption experiments were accomplished as a function of contact time, pH, and initial dye concentration to study the efficiency of ZnO nanopowder on dye removal (MG). The obtained nanopowder was characterized using various techniques XRD, FTIR, SEM and EDX. The results shown that the maximum absorbed value was 233.16 mg / g. The findings show that ZnO nanopowder have fast contact time and initial concentration absorbing characteristics in dye removal. The maximum capacity of sorbent was found to be 246.36 mg. Furthermore, the study revealed that ZnO nanopowder is an effective sorbent for cleanup of malachite green dye in aqueous solution when comparing with other adsorbent materials. The Adsorption and kinetics parameters of the maximum capacity of sorbent and correlation coefficient showed that the data were well fitted the to the Langmuir isotherm R2 of 0.923 models and pseudo-second-order kinetic model with R2 of 0.994 respectively.
众所周知,孔雀石绿染料具有毒性致癌特性,即使在低浓度下也会对人类造成潜在的健康风险。因此,在排放到水体或水处理系统之前对染料进行修复是非常重要的。因此,本文演示了使用ZnO纳米粉末去除水相中孔雀石绿(MG)染料的清洁度。为了研究氧化锌纳米粉体对染料的去除效果,通过对接触时间、pH和初始染料浓度的影响进行了批量吸附实验。采用XRD、FTIR、SEM和EDX等多种技术对制备的纳米粉体进行了表征。结果表明,ZnO纳米粉体在脱色过程中具有快速的接触时间和初始浓度吸收特性。吸附剂的最大容量为246.36 mg。与其他吸附材料相比,ZnO纳米粉体对孔雀石绿染料是一种有效的吸附剂。吸附量和动力学参数及相关系数均符合Langmuir等温线模型R2(0.923)和拟二级动力学模型R2(0.994)。
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引用次数: 2
THE EFFECT OF GOLD NANOPARTICLES ON RADIATION DOSE DISTRIBUTION IN BREAST CANCER USING MONTE CARLO SIMULATION 用蒙特卡罗模拟研究金纳米粒子对乳腺癌患者辐射剂量分布的影响
IF 1.1 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-10-01 DOI: 10.15251/jobm.2020.124.101
H. Bush, M. H. Eisa, A. Ramizy, M. Ashari, Kh. M. Haroun, O. Aldaghri, M. D. Abd-Alla
The simulation model for MCNP5 code was used to study the effect of the gold nanoparticle (AuNPs) in cancer breast samples. The dose rate distribution of AuNPs in water and breast phantom was calculated using MCNP5 code. For inhomogeneities, cone cells were designed to calculate dose distribution around Ir-192 source in breast and inhomogeneous medium that includes gold nanoparticles at different concentration. Both barometers, the track length energy deposition tally (F6) and pulse height tally (*F8), were used. The result indicated that the F6 is better than *F8 for radiation dose calculation. Angular doses distribution in water was compared with data published for tally F6 and*F8 with the different percentage range of 0.0136 to 0.3019% for tally F6 at the average angle of 5˚and 175˚respectively. For *F8 tally, different percentage range of - 0.0014 to 0.8253 % was obtained at an average angle of 75˚and 5˚ respectively. For breast phantom, the result of the F6 tally with the *F8 tally was compared. The difference in calculations between the two tallies in the angular anisotropic distribution was found to be in the range from 0.0514 to 0.4596% at the average angle of 15 ˚ and 175 ˚ respectively. The obtained results showed that the AuNP dose increases when the concentration increases up to ten percent (100 mg/ml), and then decreases for concentration higher than ten percent. The concentration of AuNPs greater than ten percent is not recommended. The results indicated that tally F6 is a good tool to calculate the effect of inhomogeneities due to breast cancer on brachytherapy.
利用MCNP5代码的模拟模型研究了金纳米颗粒(AuNPs)在乳腺癌样本中的作用。使用MCNP5代码计算水中和乳腺幻影中AuNPs的剂量率分布。对于不均匀性,设计锥细胞计算Ir-192在乳腺和含有不同浓度金纳米颗粒的非均匀介质中的剂量分布。采用轨迹长度能量沉积计数(F6)和脉冲高度计数(*F8)两种气压计。结果表明,F6比*F8更适合于辐射剂量的计算。在平均角度为5˚和175˚的情况下,与已发表的计数F6和*F8在水中的角剂量分布进行了比较,计数F6的百分比范围为0.0136 ~ 0.3019%。*F8计数在平均角度为75˚和5˚时的百分比范围为- 0.0014 ~ 0.8253 %。对于乳房幻像,比较F6计数和*F8计数的结果。在平均角度为15˚和175˚时,两种计算结果在角度各向异性分布上的差异在0.0514 ~ 0.4596%之间。结果表明,浓度增加到10% (100mg /ml)时,AuNP剂量增加,浓度大于10%时,剂量减小。不推荐超过10%的aunp浓度。结果表明,F6计数是计算乳腺癌不均匀性对近距离放疗影响的良好工具。
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引用次数: 0
EVALUATION OF THE DESTRUCTION POTENTIAL OF Zr-DOPED TiO2NANOPARTICLES FOR THE ABATEMENT of H2S GAS Zr掺杂TiO2纳米颗粒对H2S气体的破坏潜力评价
IF 1.1 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-07-01 DOI: 10.15251/jobm.2020.123.89
N. Shahzad, N. Ali, N. Ahmad
Due to its toxicity, destruction of H2S gas has been an important topic of researchers. Many studies have been carried for investigating various techniques for the removal of this gas. One of those techniques is catalytic and photocatalytic destruction of H2S gas using various catalysts including TiO2 owing to its significant potential for degradation of various pollutants. This study investigates the destruction potential of Zr doped TiO2 for the abatement of H2S gas. The catalysts were characterized using different techniques like XRD, SEM, XRF. The catalytic experiments were performed using fixed bed catalyst system. The samples were analyzed using GC-MC technique and it was revealed that the Zr doping of TiO2 did not favour positively towards enhancing the H2S destruction potential as found in other studies.
由于其毒性,H2S气体的破坏一直是研究人员的重要课题。已经进行了许多研究来研究去除这种气体的各种技术。其中一种技术是使用包括TiO2在内的各种催化剂对H2S气体进行催化和光催化破坏,因为其具有降解各种污染物的显著潜力。本研究调查了Zr掺杂TiO2对H2S气体的破坏潜力。使用XRD、SEM、XRF等不同技术对催化剂进行了表征。采用固定床催化剂体系进行了催化实验。使用GC-MC技术对样品进行了分析,结果表明,TiO2的Zr掺杂并不像其他研究中发现的那样有利于增强H2S的破坏潜力。
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引用次数: 0
PROPERTIES OF CARBON NANOTUBES DOPED WITH GADOLINIUM 钆掺杂碳纳米管的性能
IF 1.1 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-07-01 DOI: 10.15251/jobm.2020.123.61
Rashad Gabil Abaszade, О. Kapush, A. Nabiev
An analysis of some properties of carbon nanotubes using X-ray diffraction analysis, Raman scattering, and IR luminescence is given. After doping with gadolinium the peak intensities in X-ray and Raman spectra drastically increase. It was found that 15% doping with gadolinium strongly affects the physical properties of carbon nanotubes functionalized by a carboxyl group.
利用X射线衍射分析、拉曼散射和红外发光对碳纳米管的一些性质进行了分析。在用钆掺杂之后,X射线和拉曼光谱中的峰值强度急剧增加。研究发现,掺杂15%的钆对羧基官能化的碳纳米管的物理性能有很大影响。
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引用次数: 6
TEMPERATURE DEPENDENT CHARACTERISTICS OF SrAl2O4:Dy 3+PHOSPHOR SrAl2O4: dy3 +荧光粉的温度依赖特性
IF 1.1 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-07-01 DOI: 10.15251/jobm.2020.123.51
S. Tongbram, S. D. Singh, B. Tongbram, B. Sharma
We report the detailed temperature-dependent characteristics of Dy3+ doped SrAl2O4 phosphor. The phosphor synthesised using precipitation method was annealed at three different temperatures, specifically 800ºC, 900ºC, and 1000ºC. The three samples were analyzed using XRD, SEM, TEM, RAMAN, and FTIR. The observed photoluminescence emissions were consisting of peaks arising from the host SrAl2O4 as well as the dopant Dy3+. The crystallite sizes were found to be 27.22nm, 29.74nm, and 31.24nm, respectively, with the increase in annealing temperature. SEM, TEM images showed nearspherical, rod-like shapes of the crystals, and SAED confirmed the crystals were single-crystal. CIE analysis results showed that the colour coordinate was found to be very close to white colour in the three annealing temperatures, which is an advantage in the field of technology development.
我们报道了Dy3+掺杂SrAl2O4荧光粉的详细温度依赖特性。采用沉淀法合成的荧光粉在800ºC、900ºC和1000ºC三种不同温度下退火。采用XRD、SEM、TEM、RAMAN、FTIR对样品进行分析。所观察到的光致发光发射由宿主SrAl2O4和掺杂剂Dy3+产生的峰组成。随着退火温度的升高,晶粒尺寸分别为27.22nm、29.74nm和31.24nm。SEM, TEM图像显示晶体呈近球形,棒状,SAED证实晶体为单晶。CIE分析结果表明,在三种退火温度下发现颜色坐标非常接近白色,这在技术开发领域具有优势。
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引用次数: 0
SYNTHESIS AND STRUCTURAL ANALYSIS OF InSb-CrSb, InSb-Sb, GaSb-CrSb EUTECTIC COMPOSITES InSb-CrSb、InSb-Sb、GaSb-CrSb共晶复合材料的合成及结构分析
IF 1.1 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2020-07-01 DOI: 10.15251/jobm.2020.123.67
M. Kazimov
İnSb-CrSb, İnSb-Sb, GaSb-CrSb eutectic composites are synthesized by the vertical Bridgman method. The existence interphase zones around metallic inclusions in GaSb-CrSb, InSb-CrSb and InSb-Sb eutectic composites have been establishedby study of the structure and elemental composition. It has been found that the peaks detected in the Raman spectra corresponded to the GaSb and InSb compounds and Sb-Sb bond.
采用垂直Bridgman法合成了İnSb-CrSb、İnSb-Sb、GaSb-CrSb共晶复合材料。通过对GaSb-CrSb、InSb-CrSb和InSb-Sb共晶复合材料的结构和元素组成的研究,确定了在金属夹杂物周围存在相区。发现在拉曼光谱中检测到的峰对应于GaSb和InSb化合物以及Sb-Sb键。
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引用次数: 0
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Journal of Optoelectronic and Biomedical Materials
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