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Decolorization of malachite green in aqueous solution via MgO nanopowder MgO纳米粉体对孔雀石绿的脱色研究
IF 1.1 Pub Date : 2021-10-01 DOI: 10.15251/jobm.2021.134.183
H. Idriss
Water is one of the essential primary resources for life and development on the planet, where many industrial activities depend on it, but some industries lead to water pollution. Hence, we need economical and effective ways to address the contamination. This article describes the production and utilization of MgO nanopowder using thermal decomposition as an economical and efficient method for malachite green decolorization. The MgO nanopowder was analyzed via various techniques for morphology, cryptography, surface area, etc. Batch adsorption tests have been performed as a function of contact time, pH, and initial dye concentration to study their impact on decolorization of malachite green via MgO nanopowder. The result verified the target nanopowder's production with crystallite size 20.16 nm and a relative surface area of 19.84 m2 /g. MgO nanopowder was employed to decolorize malachite green dye in an aquatic solution utilizing a batch method. The findings revealed that the maximum adsorption capacity value was 232.26 mg/g. The adsorption was found to follow the Freundlich isotherm models and follow the pseudo-second-order kinetics
水是地球上生命和发展的重要主要资源之一,许多工业活动都依赖于水,但一些工业会导致水污染。因此,我们需要经济有效的方法来解决污染问题。本文介绍了利用热分解法生产和利用氧化镁纳米粉体,作为一种经济有效的孔雀石绿脱色方法。通过各种形态、密码术、表面积等技术对MgO纳米粉末进行了分析。进行了作为接触时间、pH和初始染料浓度的函数的分批吸附试验,以研究它们对MgO纳米粒子对孔雀石绿脱色的影响。结果验证了目标纳米粉末的生产,其晶粒尺寸为20.16nm,相对表面积为19.84m2/g。采用MgO纳米粉体对水溶液中的孔雀石绿染料进行分批脱色。结果表明,最大吸附容量值为232.26mg/g。发现吸附遵循Freundlich等温线模型,并遵循伪二阶动力学
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引用次数: 6
An evaluation of noble nanocomposites based on zinc oxide: synthesis, characterization, environmental, optical and biomedical applications 基于氧化锌的贵金属纳米复合材料的合成、表征、环境、光学和生物医学应用评价
IF 1.1 Pub Date : 2021-10-01 DOI: 10.15251/jobm.2021.134.151
G. Prashanth, M. Dileep, P. Prashanth, S. Sreeja Mole, S. Boselin Prabhu, B. Nagabhushana, S. Ravichandran, N. Bhagya
Metal oxide nanocomposites have concerned an obvious agreement of consideration because of their enormous applications in numerous domains like photocatalyst, catalysis, biological and sensors. The conservational purification technology is getting advanced by the development of heterostructured semiconductor photocatalysts. In this paper, we documented a comparative analysis of synthesis process (Solution-based methods, High temperature-based methods and Electrical methods) and characterisation techniques such as Transmission electron microscopy, X-ray diffraction, Fourier-transform infrared spectroscopy and Scanning electron microscopy on various noble Nanocomposites (NCs) of metal (M) - zinc oxide (ZnO/ZO). This review inclines over multiple stat-of-the-art applications like photocatalytic, catalyst, sensor and biological activities. It could be concluded from this study that, the catalytic activity of noble M-ZO nanostructures depends not only on the noble metal species, but on the catalytic material architecture as well. The future research and development challenges together with future prospects are critically presented.
金属氧化物纳米复合材料由于其在光催化剂、催化、生物和传感器等众多领域的巨大应用,引起了人们的广泛关注。随着异质结构半导体光催化剂的发展,环保净化技术得到了进一步的发展。在本文中,我们对金属(M)-氧化锌(ZnO/ZO)的各种贵金属纳米复合材料(NC)的合成过程(基于溶液的方法、基于高温的方法和电学方法)和表征技术(如透射电子显微镜、X射线衍射、傅立叶变换红外光谱和扫描电子显微镜)进行了比较分析。这篇综述涉及光催化、催化剂、传感器和生物活性等多项最新技术应用。从这项研究可以得出结论,贵金属M-ZO纳米结构的催化活性不仅取决于贵金属物种,还取决于催化材料的结构。对未来的研究和开发挑战以及未来前景进行了批判性的介绍。
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引用次数: 0
Synthesis and characterization of ZnS/SiO2 photonic dots ZnS/SiO2光子点的合成与表征
IF 1.1 Pub Date : 2021-10-01 DOI: 10.15251/jobm.2021.133.145
H. M. El-Khair, A. Alakhras, M. A. Ibrahem, H. Idriss
In this report, a facile, low-cost, and effective method has been employed to produce highly monodisperse colloids photonic materials ZnS QDs/SiO2 were fabricated using chemical condensation reactions on poly-methyl methacrylate. The obtained results exhibit whispering gallery emission modes with 1.47nm spacing. In addition, the emission from ZnS QDs was modulated by a spherical microcavity. Furthermore, the spherical cavity dimension was calculated using the relation between modes spacing and cavity dimension and found to be 11.86 m.
在本报告中,采用一种简单、低成本和有效的方法来制备高度单分散的胶体。利用聚甲基丙烯酸甲酯上的化学缩合反应制备了ZnS量子点/SiO2光子材料。所获得的结果显示出1.47nm间距的回音廊发射模式。此外,ZnS量子点的发射受到球形微腔的调制。此外,利用模间距和腔尺寸之间的关系计算出球形腔尺寸,结果为11.86m。
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引用次数: 0
Catalytic pyrolysis of Sweet Sorghum plant by using fixed-bed reactor; Effect of different temperatures on the pyrolytic bio-oil yield and FT-IR characterization 固定床反应器催化热解甜高粱植物不同温度对热解生物油收率及FT-IR表征的影响
IF 1.1 Pub Date : 2021-10-01 DOI: 10.15251/jobm.2021.134.137
A. Amanat, Z. Hussain, M. Imran Din, A. Sharif, A. Mujahid, A. Intisar, E. Ahmed, R. Khaild, M. Arshad
Pyrolysis of sweet sorghum, lignocellulosic graminaceous plant has been conceded using the fixed bed tubular reactor. Temperature plus catalyst are the important factors which effect the pyrolysis process. Here catalytic pyrolysis has been done by the catalyst ZnO-Fe2O3/Al2O3 at different temperatures. We have done our pyrolysis reactions on3changed temperatures i.e. 250̊ C, 350 ̊C, 450 ̊C. By using catalyst, we obtain the pyrolytic products at a very low temperature and it is proved very efficient method for biofuel production. From different temperature experimentation, we concluded that the best optimal temperature along with catalyst for pyrolysis is 350 ̊C for the yield of bio oil. Maximum yield can be obtained at this temperature.
采用固定床管式反应器对甜高粱、木质纤维素类禾本科植物进行了热解。温度和催化剂是影响热解过程的重要因素。本文以ZnO-Fe2O3/Al2O3为催化剂,在不同温度下进行了催化热解。我们已经在3种不同的温度下进行了热解反应,即250、350、450℃。利用催化剂在极低温度下得到热解产物,是生产生物燃料的一种有效方法。通过不同温度的实验,得出在催化剂的作用下,生物油的最佳热解温度为350℃。在此温度下可获得最大产率。
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引用次数: 0
Antibacterial activity with eggshell nano-particles activated by microwave plasma 微波等离子体活化蛋壳纳米粒子的抗菌活性
IF 1.1 Pub Date : 2021-10-01 DOI: 10.15251/jobm.2021.134.177
A. Q. Muryoush, D. Hussain, A. Ali
The eggshell cuticle is the proteinaceous outermost layer of the eggshell which regulates water exchange and protects against entry of micro-organisms. Outer eggshell and cuticle protein was extracted from domestic chicken. The aim of the research is to find out the effect of the treated and untreated nano particles of egg shells with micro wave cold plasma on the effectiveness of E. coli (negative bacteria) that infect the skin and measure the diameter of bacterial inhibition zone, the eggshell has been prepared by a chemical method (sol gel) and measure the level of acidity and the PH is neutral. The result of Atomic Force Microscope (AFM) shows that the particles diameters become smaller with nano-particles solution than for egg shell tests (powder). The nano-particles solution for egg shell exposed to cold plasma. The microwave plasma used in this search has voltage "175v" and the gas flow at " 5liter /min " and frequency (2.45 GHz) at the room temperature for five minutes’ time. The E. coli bacteria were treated with nano-particles solution egg shells. The results indicated that after 24 hours of placing the bacteria in the incubator, the inhibition zone for the nano-particles eggshell that for the is greater than that for nano-particles eggshell exposed to the plasma, and in both cases there were a good response.
蛋壳角质层是蛋壳的最外层蛋白质,它调节水交换并防止微生物进入。以家鸡为试材,提取蛋壳和角质层蛋白。本研究的目的是找出用微波冷等离子体处理和未处理的蛋壳纳米粒子对感染皮肤的大肠杆菌(阴性细菌)的效力的影响,并测量细菌抑制区的直径,通过化学方法(溶胶-凝胶)制备蛋壳,并测量酸度水平和PH为中性。原子力显微镜(AFM)的结果表明,纳米颗粒溶液的颗粒直径比蛋壳测试(粉末)的颗粒直径更小。蛋壳暴露于冷等离子体中的纳米粒子溶液。本研究中使用的微波等离子体电压为“175v”,气流为“5升/分钟”,频率为2.45GHz,室温下持续5分钟。用纳米粒子溶液蛋壳处理大肠杆菌。结果表明,在培养箱中放置细菌24小时后,纳米粒子蛋壳对细菌的抑制区大于暴露于等离子体的纳米粒子蛋壳的抑制区,并且在这两种情况下都有良好的反应。
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引用次数: 3
Synthesis of zinc oxide nanoparticles and its applications in the surface modification of textile materials 纳米氧化锌的合成及其在纺织材料表面改性中的应用
IF 1.1 Pub Date : 2021-10-01 DOI: 10.15251/jobm.2021.134.171
B. S. Babu, R. Srinivasan, B. K. Potnuru, N. Ramanan, P. Gopikrishnan, A. P. Vijayandrahari, M. Sripragash, M. Santhosh, K. P. Yuthith Venkatesh
The application of nanotechnology in the textile finishing is increasingly being explored due to its unique and valuable characteristics. This has brought up many innovative finishes as well as new application techniques. The nano-finished textile materials are found to have better physical properties than the conventionally finished textiles, in areas such as anti-microbial properties, UV blocking, soil-resistance, etc. In the present work, zinc oxide nano-particles were prepared by wet chemical method using zinc nitrate and sodium hydroxide as precursors and solublized starch as stabilizing agent. These nanoparticles were impregnated onto cotton fabrics by pad-dry-cure method using acrylic binder. A fine medium weight cotton fabric samples were used for this. The aims are to impart anti-microbial functions to the textile substrate and the functional properties of coated fabrics. The nano-ZnO impregnated cotton fabrics showed excellent antimicrobial activity against two types of representative bacteria viz. gram-positive organism (S.aureus) and gram-negative organism. (E. coli).
纳米技术在纺织品整理中的应用因其独特而有价值的特点而受到越来越多的探索。这带来了许多创新的饰面以及新的应用技术。研究发现,纳米纺织材料在抗菌、防紫外线、耐土壤等方面比传统纺织材料具有更好的物理性能。以硝酸锌和氢氧化钠为前驱体,可溶性淀粉为稳定剂,采用湿化学法制备了氧化锌纳米颗粒。将这些纳米粒子以丙烯酸为粘结剂,采用垫干固化的方法浸渍在棉织物上。采用了一种优良的中等重量棉织物样品。目的是赋予纺织品基材抗菌功能和涂层织物的功能特性。纳米氧化锌浸渍棉织物对革兰氏阳性菌(金黄色葡萄球菌)和革兰氏阴性菌两种具有代表性的细菌均有良好的抑菌活性。(大肠杆菌)。
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引用次数: 0
Green synthesis and characterization of zinc oxide nanoparticles using extracts of Artemisia annua l. grown in Togo 利用多哥青蒿提取物绿色合成氧化锌纳米颗粒及其表征
IF 1.1 Pub Date : 2021-10-01 DOI: 10.15251/jobm.2021.134.193
K. Sesime, M. M. Dzagli, K. B. Afoudji
Plant-mediated synthesis of ZnO nanoparticles (ZnONPs) is preferable than the conventional methods with many applications in medicine and biology. Artemisia annua is recognized to have antiplasmodial, antimicrobial activities, so the nanoformulation based on its extracts and zinc oxide would be of therapeutic benefit. This study aims to investigate properties of ZnONPs based on Artemisia annua leaves and stems extracts and zinc acetate. Spectroscopy techniques, XRD, SEM and Energy Dispersive X-ray Spectroscopy (EDS) were used to investigate the structural and optical properties of the ZnONPs. The characteristic absorption peak was at 375.5 nm and the excitation at 365 nm showed wide spectra in visible (450-700 nm). XRD, SEM and EDS analysis confirmed a pure ZnONPs in wurtzite hexagonal structure with a size of 21.34 - 24.71 nm. These nanoformulations would be multifunctional and are candidate for treatment of malaria, cosmetics and optoelectronic.
植物介导合成ZnO纳米粒子(ZnONPs)比传统的方法更有优势,在医学和生物学上有许多应用。黄花蒿具有抗疟原虫、抗菌活性,以其提取物和氧化锌为基础的纳米制剂具有良好的治疗效果。本研究以黄花蒿叶茎提取物和乙酸锌为原料,研究其ZnONPs的性质。利用光谱学技术、XRD、SEM和能谱仪(EDS)研究了ZnONPs的结构和光学性质。其特征吸收峰在375.5 nm处,365 nm处激发,可见光谱较宽(450 ~ 700 nm)。XRD、SEM和EDS分析证实了纯ZnONPs为纤锌矿六方结构,尺寸为21.34 ~ 24.71 nm。这些纳米制剂将是多功能的,是治疗疟疾、化妆品和光电子的候选药物。
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引用次数: 0
Quantum chemical designing of 2-(3,4-dihydroxyphenyl)-3,5,7- trihydroxychromenium as a efficient sensitizer for dye sensitized solar cell 染料敏化太阳能电池高效敏化剂2-(3,4-二羟基苯基)-3,5,7-三羟基铬的量子化学设计
IF 1.1 Pub Date : 2021-07-01 DOI: 10.15251/jobm.2021.133.107
X. Maryjosephine, R. Raj Muhamed, S. Krishnaveni, V. Sathyanarayanamoorthi
In this study we have designed six metal free D–π–A system and evaluated their optimum properties for Dye sensitized solar cell (DSSC). The ground state geometries, electronic properties, light harvesting efficiency, and electronic absorption spectra of these dyes were studied using Density functional theory and Time dependant density functional theory. All these calculations were performed in the gas phase and Dimethylformamide, Dichloromethane as solvent. Our theoretical calculation reveals that the designed metal free organic dyes are good candidate for DSSC applications.
在本研究中,我们设计了六个无金属的D–π–A系统,并评估了它们对染料敏化太阳能电池(DSSC)的最佳性能。利用密度泛函理论和时间相关密度泛函理论研究了这些染料的基态几何结构、电子性质、光捕获效率和电子吸收光谱。所有这些计算都是在气相和二氯甲烷作为溶剂的二甲基甲酰胺中进行的。我们的理论计算表明,所设计的无金属有机染料是DSSC应用的良好候选者。
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引用次数: 0
Sol-gel Synthesis of Nanoscaled Spinels using 1, 2-ethanediol as a Gelation Agent 以1,2 -乙醇为胶凝剂的溶胶-凝胶法合成纳米尖晶石
IF 1.1 Pub Date : 2021-07-01 DOI: 10.15251/jobm.2021.133.89
M. Rani, K. Tariq, A. Younus, K. Batool, M. Sattar, R. Shafique, M. Bukhari, N. Akhtar, A. Mehmood
In the present work sodium chromite (NaCr2O4) based pigment was synthesized using sol gel technique. From XRD analysis, it is clear that all samples manufactured by sol gel technique have spinel structure crystallization. Also chromites with a chromium concentration (max) shows black color and Na- substituted shows green color. The samples were annealed at different temperature from 600˚C to 700˚C. The obtained nano particles were characterized by other different techniques as well such as Scanning electron microscopy, Raman spectroscopy, Photoluminence and Energy dispersive spectroscopy. The particle size of parent compound is ranging from 4.4nm to 11nm determined from SEM. The tendency of particles to form the aggregates with the increasing annealing temperature has been observed. The optical characterization of the compound shows that the sol gel attained material is strongly persuasive sodium chromite.
本文采用溶胶-凝胶法制备了铬铁矿钠基颜料。XRD分析表明,溶胶-凝胶法制备的样品均具有尖晶石结构结晶。铬浓度(最大)为黑色,取代钠为绿色。样品在600 ~ 700℃的不同温度下退火。利用扫描电镜、拉曼光谱、光致发光和能量色散光谱等技术对所得纳米粒子进行了表征。扫描电镜测定母化合物的粒径为4.4nm ~ 11nm。随着退火温度的升高,颗粒有形成聚集体的趋势。该化合物的光学表征表明,溶胶-凝胶获得的材料是极具说服力的铬铁矿钠。
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引用次数: 9
Eco friendly synthesis of nickel oxide nanoparticles and its application on pyrolysis of Calotropis procera (AKH) Plant roots 氧化镍纳米颗粒的环保合成及其在植物根热解中的应用
IF 1.1 Pub Date : 2021-07-01 DOI: 10.15251/jobm.2021.133.119
M. I. Din, S. Rehman, Z. Hussain, A. Intisar, E. Ahmed, A. Sharif, T. Hussain, R. Khalid, S. Ameen, M. Arshad
This study covers the slow catalytic pyrolysis of Calotropis procera (Akh plant root) using biogenically synthesized NiO NPs. The synthesized particles were characterized by UV-Visible and FTIR spectrometry. Catalytic activity of the NiO NPs was examined via slow catalytic pyrolysis of Akh plant roots by monitoring temperature and catalyst effect on feedstock for the production of high yield bio-char, bio-oil and bio-gases. At 250°C low bio-oil and higher bio-char yield were obtained. However, at higher temperature inverse results were obtained whereby at optimum temperature of 300°C, the yield of bio-char, bio-oil and biogas 37, 36 and 27% was attained
本研究采用生物合成NiO NPs对卡罗tropis procera (Akh植物根)进行慢速催化热解。用紫外-可见光谱和红外光谱对合成的颗粒进行了表征。通过监测温度和催化剂对原料的影响,研究了NiO NPs对Akh植物根系慢速催化热解生产高产生物炭、生物油和生物气体的催化活性。在250°C下获得了低生物油和高生物炭产量。然而,在较高的温度下,得到了相反的结果,在300℃的最佳温度下,生物炭、生物油和沼气的产率分别达到37%、36%和27%
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引用次数: 0
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Journal of Optoelectronic and Biomedical Materials
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