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An impact of different injection timing operating on chlorellea emersonii methyl ester (CEME) with best fuel (BF) 不同喷射时间对最佳燃料(BF)下绿球藻甲酯(CEME)的影响
IF 1.1 Pub Date : 2022-12-20 DOI: 10.15251/jobm.2022.144.191
K. Rangasamy, N. Panchacharam
Biodiesel is a clean-burning, oxygenated monoalkyl-ester fuel manufactured from natural, renewable sources like new/used vegetable oils and animal fats. The injection time has a significant impact on engine performance, particularly pollutant emissions. The purpose of this research is to see if Chlorellea Emersonii methyl ester (CEME) can be used as a fuel alternative in a compression ignition (CI) engine. The CEME was synthesised using a transesterification technique, and the engine parameters (performance, emission, and combustion) were investigated using 20 (v/v%) biodiesel blends at retard, standard, and advanced injection timings (IT). In this study an alteration in injection timing were done with TRC and BF combination. Other than conventional injection timing of 23o bTDC three more injection timing included ie 24o bTDC (advance IT), 21o bTDC (retarded IT) and 22o bTDC (retarded IT). Outcome results showed 22o bTDC(retarded IT) with 2.12% improvement in BTE followed by 24.5%,35.15% and 90.2% reduction in HC,CO and smoke.
生物柴油是一种清洁燃烧的含氧单烷基酯燃料,由天然可再生资源(如新/旧植物油和动物脂肪)制造而成。喷油时间对发动机的性能,尤其是污染物排放有着重要的影响。本研究的目的是了解小球藻甲酯(cme)是否可以作为压缩点火(CI)发动机的替代燃料。使用酯交换技术合成了cme,并使用20 (v/v%)生物柴油混合物在延迟,标准和提前喷射时间(IT)下研究了发动机参数(性能,排放和燃烧)。在本研究中,通过TRC和BF组合来改变注射时间。除了常规的230点上止点喷射时间外,还有另外三种喷射时间,即240点上止点(提前IT)、210点上止点(延迟IT)和220点上止点(延迟IT)。结果显示,有220名迟滞IT患者,BTE改善2.12%,HC、CO和烟雾分别降低24.5%、35.15%和90.2%。
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引用次数: 0
Structural and optical properties of Zn doped Bi2O3 thin films prepared by chemical route with effect of bath temperatures 化学法制备的含锌Bi2O3薄膜的结构和光学性能
IF 1.1 Pub Date : 2022-12-20 DOI: 10.15251/jobm.2022.144.211
T. Samidurai, U. Karunanithi, S. Prabahar, S. Srikanth, R. Karunakaran, K. Karthikadevi
The present work attempts to synthesize Zn doped Bismuth Oxide thin films deposited effectively on to micro glass substrates at different bath temperatures by Chemical Bath Route. The films were characterized by XRD, SEM, EDAX and optical analysis. XRD analysis reveals that all the films belong to monoclinic in polycrystalline structure with preferred orientation along (012). The optical energy gap values of Zn doped Bi2O3 thin films were in the range 2.21- 2.81 eV which depend on deposition temperatures. Zn - Bi2O3 thin films can be used in photo voltaic cells, gas sensors, optical coatings, flat-panel displays, micro electronics, light emitting diodes, batteries, super capacitors and fuel cell industries.
本工作试图通过化学浴法在不同浴温下在微玻璃衬底上合成有效沉积的Zn掺杂氧化铋薄膜。通过XRD、SEM、EDAX和光学分析对薄膜进行了表征。XRD分析表明,所有薄膜都属于单斜多晶结构,沿(012)方向取向较好。掺杂Zn的Bi2O3薄膜的光学能隙值在2.21-2.81eV范围内,这取决于沉积温度。Zn-Bi2O3薄膜可用于光伏电池、气体传感器、光学涂层、平板显示器、微电子、发光二极管、电池、超级电容器和燃料电池行业。
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引用次数: 0
Design of micro-jet plasma system: a novel nanoparticles manufacturing method in atmospheric pressure 微喷流等离子体系统设计:一种新的常压纳米颗粒制造方法
IF 1.1 Pub Date : 2022-12-20 DOI: 10.15251/jobm.2022.144.203
N. Abdalameer, S. N. Mazhir, H. M. Salim, J. K. Hammood, Z. H. Abdul Raheem
Micro jet atmospheric (MPJ) plasma was first utilized to create nano-sized crystals. Nanosized particles may have advantageous characteristics such as better internal quality and dissolving rates of the product compared to traditional crystalline goods. A nebulizer system sprays an aerosol solution into plasma by use of a carrier gas in a cold plasma crystal (argon). The plasma warms and loads the droplets causing solvent and columbic fission evaporation, and then the nucleation and crystal formation start within the limited volume given by the tiny drops. This produces nano-sized crystals. MPJ was used to establish the operating parameters for producing nano-sized ZnSe material crystals using electron microscope transmitting and X-ray powder diffraction tests as well as sensitivity testing have been carried out. Sensitivity tests showed lower friction sensitivity for the nano-scale product, suggesting a better internal quality of the crystal product.
微射流大气等离子体(MPJ)首次被用于制造纳米级晶体。与传统的晶体产品相比,纳米颗粒可能具有诸如更好的内部质量和产品的溶解率等有利特性。喷雾器系统通过使用冷等离子体晶体(氩)中的载气将气溶胶溶液喷射到等离子体中。等离子体加热并装载液滴,导致溶剂和柱状裂变蒸发,然后在微小液滴提供的有限体积内开始成核和晶体形成。这就产生了纳米级的晶体。利用MPJ建立了制备纳米ZnSe材料晶体的操作参数,并进行了电镜透射和x射线粉末衍射测试以及灵敏度测试。灵敏度测试表明,纳米级产品的摩擦灵敏度较低,表明晶体产品的内部质量较好。
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引用次数: 0
Physical-chemical properties of InSb+Mg3Sb2 eutectic systems: synthesis, characterization, and applications InSb+Mg3Sb2共晶体系的理化性质:合成、表征及应用
IF 1.1 Pub Date : 2022-10-01 DOI: 10.15251/jobm.2022.144.187
M. Kazimov, G. Ibragimov, G. I. Isakov, B. G. Ibragimov
InSb+Mg3Sb2 systems are synthesized by the vertical Bridgman–Stockbarger method. InSb and Mg3Sb2, a form of lamellar eutectic. XRD analysis and microstructural study of InSb+Mg3Sb2 composites show that Mg3Sb2 lamellar are uniformly distributed in the InSb matrices. The initial and final melting temperatures for InSb+Mg3Sb2 eutectic alloys are 770K and 772K, respectively.
采用垂直Bridgman-Stockbarger方法合成了InSb+Mg3Sb2体系。InSb和Mg3Sb2。InSb+Mg3Sb2复合材料的XRD分析和微观结构研究表明,Mg3Sb2在InSb基体中均匀分布。InSb+Mg3Sb2共晶合金的初始和最终熔融温度分别为770K和772K。
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引用次数: 0
Biomimetic tissue regeneration using electrospun nanofibrous scaffolds 电纺纳米纤维支架的仿生组织再生
IF 1.1 Pub Date : 2022-10-01 DOI: 10.15251/jobm.2022.144.169
H. Owida, M. Al-Ayyad, M. Rashid
An emerging field of tissue engineering combines medical, biological, and engineering principles to produce tissue-engineered constructs that regenerate, preserve, or slightly enhance the functions of natural tissue. By creating structures that replicate the extracellular matrix, oxygen and nutrients will be transmitted more effectively while releasing toxins during tissue repair, all while creating mature tissues. Three-dimensional nanostructures for tissue engineering have been the focus of numerous studies over the last few years. Electrospinning is a highly effective technique in this category. The last few decades, numerous nanofibrous scaffolds have been developed for tissue repair and restoration. Nanofibrous meshes as tissue engineered scaffolds for various tissues, such as neural, cardiovascular, skin, cartilage, and tendon are discussed in this article. In addition, the current article discusses recent advancements in tissue regeneration as well as challenges associated with electrospinning.
组织工程的一个新兴领域结合了医学、生物学和工程原理,生产出再生、保存或略微增强自然组织功能的组织工程构建体。通过创造复制细胞外基质的结构,氧气和营养物质将更有效地传递,同时在组织修复过程中释放毒素,同时创造成熟组织。用于组织工程的三维纳米结构在过去几年中一直是许多研究的焦点。静电纺丝是这一类中非常有效的技术。在过去的几十年里,已经开发了许多用于组织修复和修复的纳米纤维支架。本文讨论了纳米纤维网作为组织工程支架用于神经、心血管、皮肤、软骨和肌腱等各种组织。此外,本文还讨论了组织再生的最新进展以及与静电纺丝相关的挑战。
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引用次数: 0
Solar expedited photodegradation of orange-g using H2O2 太阳能加速H2O2对橙g的光降解
IF 1.1 Pub Date : 2022-10-01 DOI: 10.15251/jobm.2022.144.145
R. Raja, A. R. Venis, C. Kalaivanan, R. Padmavathi
Decolourisation and degradation of azo dye Orange G was carried out by using the solarassisted photodegradation process using H2O2 and the effect of various parameters on decolourisation and degradation were analysed. Dye solutions of concentration 100 mg/L treated with 30% H2O2 were taken in 250 ml conical flasks and they were exposed to sunlight in the lux intensity range of 60,000 to 90,000 lux to study its decolourisation and degradation. Effect of various parameters on decolourisation and degradation of dye like the effect of initial pH, the effect of initial H2O2concentration, the effect of initial dye concentration, the effect of additives like chloride and dihydrogen phosphate of concentration 1 M, the effect of solar light intensity, the effect of temperature were studied as kinetic studies. Optimum pH was found to be 11 and optimum H2O2 concentration was found to be 250 mM to achieve 100 % decolourisation of the dye within the shortest time duration of 1.5 hours. Kinetic studies done on the effect of pH and the effect of H2O2 concentration also provided evidence for that. Effect of chloride ion has lead to enhancement in the rate of decolourisation whereas addition of dihydrogen phosphate ion inhibits the rate of decolourisation. An increase in solar light intensity has lead to increase in the rate of decolourisation. An increase in temperature has lead to increase in the rate of decolourisation. UV spectrum was taken for the dye and degraded dye to study the extent of degradation of the dye. COD and TOC removal were also studied to know about the mineralisation of the dye.
采用H2O2辅助光降解法对偶氮染料橙G进行脱色降解,并分析了各参数对脱色降解的影响。取浓度为100 mg/L的染料溶液,经30% H2O2处理,置于250 ml锥形烧瓶中,在6万~ 9万勒克斯的光照强度范围内,研究其脱色和降解。考察了初始pH、初始h2o2浓度、初始染料浓度、氯离子和浓度为1 M的磷酸二氢等添加剂、太阳光照强度、温度等对染料脱色降解的影响,并进行了动力学研究。最佳pH值为11,最佳H2O2浓度为250 mM,可在最短时间(1.5小时)内实现染料100%脱色。对pH和H2O2浓度影响的动力学研究也提供了证据。氯离子的作用使脱色率提高,而磷酸二氢离子的加入抑制了脱色率。太阳光照强度的增加导致脱色率的增加。温度升高导致脱色速度加快。对染料和降解染料进行紫外光谱分析,研究染料的降解程度。还研究了COD和TOC的去除情况,以了解染料的矿化情况。
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引用次数: 0
Indigo carmine pigment adsorption utilizing MgO nanostructures fabricated from pimpinella anisum extract 利用茴香皮条虫提取物制备的MgO纳米结构吸附靛蓝胭脂红色素
IF 1.1 Pub Date : 2022-07-01 DOI: 10.15251/jobm.2022.143.115
N. Elamin
The effectiveness of MgO nanostructures for removing indigo carmine (IC) dye from an aqueous solution is demonstrated in this article. The nanomaterials were synthesized using MgCl2.2H2O and NaOH in a medium containing Pimpinella anisum extract. The microstructure of the samples was investigated using XRD, SEM, EDX, BET, and FTIR. Additionally, the IC dye uptake and adsorption processes were investigated using a MgO sorbent. To synthesize the MgO1 and MgO2 materials, the adsorption kinetics of IC dye, the starting pH of IC dye solution, and contact time were optimized. The maximal theoretical adsorption efficiency of the MgO1 and MgO2 adsorbents for IC dye was 559.2 and 492.6 mg/g, respectively, according to the Langmuir isotherm adsorption model. Further, recycling the MgO1 adsorbent proved conceivable due to its ease of collection and re-use following five adsorption-regeneration cycles.
本文证明了MgO纳米结构从水溶液中去除靛蓝胭脂红(IC)染料的有效性。使用MgCl2.2H2O和NaOH在含有茴香Pimpinella提取物的介质中合成纳米材料。利用XRD、SEM、EDX、BET和FTIR对样品的微观结构进行了研究。此外,使用MgO吸附剂研究了IC染料的吸收和吸附过程。为了合成MgO1和MgO2材料,对IC染料的吸附动力学、IC染料溶液的起始pH和接触时间进行了优化。根据Langmuir等温线吸附模型,MgO1和MgO2吸附剂对IC染料的最大理论吸附效率分别为559.2和492.6mg/g。此外,由于MgO1吸附剂在五个吸附-再生循环后易于收集和重复使用,因此证明回收MgO1吸收剂是可行的。
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引用次数: 0
Synthesis and analysis of flakes graphene oxide 氧化石墨烯薄片的合成与分析
IF 1.1 Pub Date : 2022-07-01 DOI: 10.15251/jobm.2022.143.107
Rashad Gabil Abaszade
The presented article is devoted to the synthesis and analysis of flakes graphene oxide obtained by the Hammers method. The synthesized flakes graphene oxide was studied using SEM, EDX, X-ray diffraction, Raman spectroscopy, element analysis, temperature dependent of resistance and IR spectroscopy. As a result of calculating the results of X-ray analysis according to the Debye-Scherer’s formula, the thickness of graphite flakes was about 12,9nm and the number of layers was 38. The result of the Raman analysis show that high quality flakes grapheme oxide was obtained. Based on the result of elementary analysis of grapheme oxide mass, the C/O ratio was determined to be 1,42. The grapheme layers inside the sample were 3,31nm thick and 14,8nm long by scanning electron microscope. The temperature variation of the resistance was determined. IR spectroscopy shows the results of the absorption of electromagnetic radiation in the infrared range by atomic groups of reduced grapheme oxide and the excitation of the molecule by light quanta. When a molecule is irradiated with infrared radiation, it is shown that only quantum absorption quantities are formed according to the frequencies of the molecules.
本文介绍了用hammer法制备氧化石墨烯薄片的合成和分析。采用SEM、EDX、x射线衍射、拉曼光谱、元素分析、电阻温度依赖性和红外光谱对合成的氧化石墨烯薄片进行了研究。根据Debye-Scherer公式计算x射线分析结果,石墨薄片厚度约为12.9 nm,层数为38层。拉曼分析结果表明,得到了高质量的氧化石墨烯薄片。根据氧化石墨烯质量的元素分析结果,确定其碳氧比为1,42。扫描电镜下,样品内石墨烯层厚度为3.31 nm,长14.8 nm。测定了电阻的温度变化。红外光谱显示了还原氧化石墨烯原子群对红外范围内电磁辐射的吸收和分子被光量子激发的结果。当分子受到红外辐射照射时,根据分子的频率只会形成量子吸收量。
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引用次数: 7
Synthesis and characterizations of phosphorus doped ZnO nanoparticles 磷掺杂ZnO纳米粒子的合成与表征
IF 1.1 Pub Date : 2022-07-01 DOI: 10.15251/jobm.2022.143.137
J. El Ghoul, N. Abdel All
We reported the synthesis of phosphorus doped ZnO nanoparticles for a concentration of P ranging from 2 to 8%by a sol–gel processing technique. The structural and optical properties of these nanoparticles were characterised by different techniques. The structural study confirms the presence of hexagonal wurtzite phase with average crystallite size around 30nm. However, the optical study was shown a high absorption in the UV range and an important reflectance in the visible range. The optical band gap of P-ZnO samples were varied between 3.32 and 3.28 eV. The aim of this work is to study the effect of phosphorus doping on the structural, morphological and optical properties of ZnO nanoparticles.
我们报道了通过溶胶-凝胶处理技术合成磷掺杂的ZnO纳米颗粒,磷浓度范围为2%至8%。通过不同的技术表征了这些纳米颗粒的结构和光学性质。结构研究证实了六方纤锌矿相的存在,平均晶粒尺寸约为30nm。然而,光学研究表明,在紫外线范围内具有高吸收率,在可见光范围内具有重要反射率。P-ZnO样品的光学带隙在3.32~3.28eV之间变化。本工作的目的是研究磷掺杂对ZnO纳米颗粒结构、形态和光学性能的影响。
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引用次数: 0
Photodegradation, thermodynamic and kinetic study of cationic and anionic dyes from effluents using polyazomethine/ZnO and polyazomethine/TiO2 nanocomposites 聚亚胺/ZnO和聚亚胺/TiO2纳米复合材料对废水中阳离子和阴离子染料的光降解、热力学和动力学研究
IF 1.1 Pub Date : 2022-07-01 DOI: 10.15251/jobm.2022.143.89
S. Pradeeba, K. Sampath
Water is a life-giving and energising substance. People all around the world are struggling due to the deficiency of fresh and hygienic potable water. Clean water is a significant resource for human civilization on Earth and one of the most crucial requirements for all living species to survive. Contamination of water due to synthetic dye is one of the most serious threats to human health. The photocatalystspoly(azomethine), ZnO, TiO2, poly(azomethine)/TiO2 and poly(azomethine)/ZnO were synthesized and used to remove cationic and anionic dyes from contaminated water.The band gap of photocatalysts, reaction kinetics, isotherm studies and thermodynamic studies were assessed and the photocatalytic studies revealed that polyazomethine/ZnO and polyazomethine/TiO2 nanocomposites had significantly higher photocatalytic activity and are more efficient at removing dyes from effluents than PAZ, ZnO, and TiO2 in natural sunlight.
水是一种赋予生命和活力的物质。由于缺乏新鲜和卫生的饮用水,世界各地的人们都在苦苦挣扎。清洁的水是地球上人类文明的重要资源,也是所有生物生存的最重要条件之一。合成染料对水的污染是对人类健康最严重的威胁之一。合成了光催化剂聚(亚甲胺)、ZnO、TiO2、聚(亚甲胺)/TiO2和聚(亚甲胺)/ZnO,并用于去除污染水中的阳离子和阴离子染料。对光催化剂的带隙、反应动力学、等温线研究和热力学研究进行了评估。光催化研究表明,聚亚胺/ZnO和聚亚胺/TiO2纳米复合材料的光催化活性显著高于PAZ、ZnO和TiO2,在自然光照下对废水中染料的去除效率更高。
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引用次数: 2
期刊
Journal of Optoelectronic and Biomedical Materials
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