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Modifikacija elektrokemijskih senzora nanočesticama metalnih oksida 金属氧化物纳米粒子修饰电化学传感器
IF 0.7 Pub Date : 2023-05-17 DOI: 10.15255/kui.2022.068
Andrea Paut, Ante Prkić, Ivana Mitar, Lucija Guć
SUMMARY
摘要
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引用次数: 0
Procjena životnog ciklusa sustava gospodarenja krutim komunalnim otpadom: studija slučaja grad Dubrovnik
IF 0.7 Pub Date : 2023-05-17 DOI: 10.15255/kui.2022.064
Ivana Smoljko, Matea Matić
Gospodarenje otpadom u Republici Hrvatskoj jedno je od najvažnijih pitanja zaštite okoliša, kao i jedno od najzahtjevnijih područja radi usklađivanja sa standardima Europske unije. U Republici Hrvatskoj su trenutačno na snazi kvantitativni ciljevi gospodarenja otpadom definirani Zakonom o gospodarenju otpadom1 i podzakonskim aktima i Planom gospodarenja otpadom Republike Hrvatske za razdoblje 2017. – 2022.2 te izmjenama Plana gospodarenja otpadom Republike Hrvatske za razdoblje 2017. – 2022. godine.3
Gospodarenje otpadom u Republici Hrvatskoj jedno je od najvažnijih pitanja zaštite okoliša,kao i jedno od najzahtjevnijh područja radi uskla dj ivanja是欧洲统一标准化组织。在克罗地亚共和国,量化废物管理目标目前由《废物管理法》和克罗地亚2017年废物管理计划确定。2022.2和克罗地亚共和国2017年废物管理计划修正案2022.3
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引用次数: 0
HPLC Analysis of Phytosterols in Prunus spinosa L. Extracts and Their Antiproliferative Activity on Prostate Cancer Cell Lines 刺李提取物中植物甾醇的HPLC分析及其对前列腺癌细胞的抗增殖活性
IF 0.7 Pub Date : 2023-05-17 DOI: 10.15255/kui.2022.077
A. Dedić, Hurija Džudžević Čančar, T. Stanojković, M. Roje, A. Damjanović, A. Alispahić, A. Jerković-Mujkić
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引用次数: 0
Onečišćenje bukom i svjetlošću na području grada Splita – sadašnje stanje i vizija budućnosti 一个是我的丈夫
IF 0.7 Pub Date : 2023-05-17 DOI: 10.15255/kui.2022.070
Mirko Marušić, Iva Tojčić, Luka Marijan Alešković
Light and noise pollution are a growing global problem, with consequences varying from the destruction of biodiversity and disturbances in the ecological system, security problems, to the im-pact on human health. This paper analyses noise pollution and light pollution in the area of the city of Split. In this area, there are no systematic measurements of the noise level in all parts of the city, while there are no measurements of light pollution at all. Results of the analysis of the data from the strategic noise maps, on the exposure of the population of the city of Split to noise pollution, show that 42 % of the population is exposed to excessive levels of road traffic noise during the day, evening, and night. The analysis of publicly available satellite measurements showed that, ac-cording to light pollution classification, the sky above the city of Split falls within the city sky class, with a tendency toward the highest light pollution class. These results point to the urgent need for implementation of measures that enable the reduction of noise pollution and light pollution, with the aim of improving the quality of life in the area of the city of Split.
光和噪音污染是一个日益严重的全球问题,其后果从生物多样性的破坏和生态系统的干扰、安全问题到对人类健康的影响各不相同。本文分析了斯普利特市地区的噪声污染和光污染。在这个地区,没有系统地测量城市所有地区的噪音水平,而根本没有测量光污染。战略噪音地图中关于斯普利特市人口暴露在噪音污染中的数据分析结果显示,42%的人口在白天、晚上和晚上暴露在过高水平的道路交通噪音中。对公开可用的卫星测量结果的分析表明,根据光污染分类,斯普利特市上空属于城市天空等级,有最高光污染等级的趋势。这些结果表明,迫切需要采取措施,减少噪音污染和光污染,以提高斯普利特市地区的生活质量。
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引用次数: 0
An Overview of Coking Wastewater Characteristics and Treatment Technologies 焦化废水特性及处理技术综述
IF 0.7 Pub Date : 2023-05-17 DOI: 10.15255/kui.2022.080
Ana Tutić, M. Miloloža, M. Cvetnić, V. Martinjak, Lidija Furač, M. Markić, Š. Ukić, T. Bolanča, D. Kučić Grgić
Coke is a high-calorie carbon mass obtained by dry distillation of coal, and used in various processes, the most significant of which is production of iron and steel. Coke production is present worldwide, especially in recent years when due to economic growth the global demand for steel is growing, which consequently increases demand for coke. During coke production, enor- mous amounts of toxic wastewater of extremely complex composition are generated. Priority pollutants that coking wastewater contains are phenols, cyanides, and thiocyanates. For successful treatment of such wastewater and achieving safety discharge standards, the application of a single process is insufficient. Accordingly, a combination of different physicochemical and bio - logical treatment procedures, of which biological treatment is the most important, should be applied. In this article, a literature review of coking wastewater characteristics and treatment technologies is presented. In addition, this review addresses the complexity and limitations associated with coking wastewater treatment, with special emphasis on biological treatment meth- ods. The aim of this review was to summarise the current knowledge on coking wastewater treatment technologies, which could eventually help optimisation of existing solutions
焦炭是一种高热量的碳物质,通过煤的干馏得到,并用于各种过程,其中最重要的是生产钢铁。焦炭生产是目前世界范围内,特别是近年来,由于经济增长,全球对钢铁的需求不断增长,从而增加了对焦炭的需求。在焦炭生产过程中,会产生大量成分极其复杂的有毒废水。焦化废水中含有的主要污染物是酚类、氰化物和硫氰酸盐。要成功处理这类废水并达到安全排放标准,单一工艺的应用是不够的。因此,应采用不同的物理化学和生物处理程序的组合,其中生物处理是最重要的。本文对焦化废水的特性及处理技术进行了综述。此外,本文还讨论了焦化废水处理的复杂性和局限性,特别强调了生物处理方法。这篇综述的目的是总结目前关于焦化废水处理技术的知识,这些技术最终可以帮助优化现有的解决方案
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引用次数: 0
Application of Different Metals as Electrode Material in Compost Leachate Treatment 不同金属电极材料在堆肥渗滤液处理中的应用
IF 0.7 Pub Date : 2023-05-17 DOI: 10.15255/kui.2022.066
L. Vrsalović, N. Vukojević Medvidović, S. Svilović, Josip Sarić
In this paper, different metallic materials (alloys of Fe, Al, and Zn) were investigated as sacrificial anodes during electrocoag - ulation (EC) for the treatment of compost leachate. Taguchi’s L9 orthogonal array design was applied to investigate the four controllable factors (different metallic material, initial pH value, stirring speed, and contact time) on decrease of chemical oxygen demand (COD) and electrodes mass loss. COD decrease reached values in the range of 75.72–92.97 %. The Taguchi optimisation results showed that the most effective factor for decrease of COD is the duration of the experiment, while the electrode material was for electrodes mass loss. The zinc electrode showed the lowest potential for use in the EC process for treatment of compost leachate, while the Al and Fe electrodes could be used in an acid or slightly acidic environment. The following decreasing order of energy consumption was recorded: Zn > Al > Fe. The measured values of metal electrode mass loss exceeded the theoretical values calculated using Faraday’s law in EC experiments with Al electrodes, while in experiments with Fe and Zn electrodes, those differences were insignificant.
本文研究了不同金属材料(Fe、Al和Zn合金)在电渗析(EC)处理堆肥渗滤液过程中作为牺牲阳极的情况。采用田口L9正交阵列设计,研究了四个可控因素(不同金属材料、初始pH值、搅拌速度和接触时间)对降低化学需氧量和电极质量损失的影响。COD下降幅度在75.72~92.97%之间。田口优化结果表明,降低COD的最有效因素是实验的持续时间,而电极材料是电极质量损失。锌电极在EC工艺中处理堆肥渗滤液的潜力最低,而Al和Fe电极可在酸性或微酸性环境中使用。能耗的递减顺序为:Zn>Al>Fe。在使用Al电极的EC实验中,金属电极质量损失的测量值超过了使用法拉第定律计算的理论值,而在使用Fe和Zn电极的实验中,这些差异是不显著的。
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引用次数: 1
Recycling of PET Post-consumer Bottles: Effect of the Re-extrusion Process on the Structure, Thermal Properties, and Apparent Activation Energy PET消费后瓶的回收:再挤出工艺对结构、热性能和表观活化能的影响
IF 0.7 Pub Date : 2023-05-17 DOI: 10.15255/kui.2022.072
M. Jakić, Sanja Perinović Jozić, Ivana Bandić, Laura Ključe
In this work, post-consumer poly(ethylene terephthalate) (PET) bottles were gathered, separated from other materials, and re-extruded. In order to evaluate the effect of re-extrusion on the structure of PET, Fourier transform infrared spectroscopy was utilised. No significant effect of the re-extrusion process on the structure of the PET sample was noticed. Obtained samples were also characterised by differential scanning calorimetry (DSC) in order to determine characteristic thermal transitions of PET. DSC results indicated the influence of re-extrusion; extruded PET started to melt at lower temperatures, and the crystal - lisation of re-extruded PET took place at significantly higher temperatures in comparison to PET. Likewise, thermogravimetric analysis (TG) was used to evaluate the effect of re-extrusion process on the thermal stability of samples. TG analysis revealed that the re-extrusion process had no effect on the thermal stability of the investigated PET samples. Finally, the activation energy of thermal degradation of the investigated samples was calculated using iso-conversional Flynn-Wall-Ozawa and Friedman method. Consequently, higher activation energies were noticed for the re-extruded PET sample in comparison to the PET bottle sample, which is a good argument in support of PET bottle recycling.
在这项工作中,收集消费后的聚对苯二甲酸乙二醇酯(PET)瓶,将其与其他材料分离,并重新挤出。为了评估再挤出对PET结构的影响,利用傅立叶变换红外光谱法。再挤出工艺对PET样品的结构没有显著影响。还通过差示扫描量热法(DSC)对所获得的样品进行表征,以确定PET的特征热转变。DSC结果表明了再挤压的影响;挤出的PET在较低的温度下开始熔融,并且与PET相比,再挤出的PET的结晶化在显著较高的温度下发生。同样,使用热重分析(TG)来评估再挤出工艺对样品热稳定性的影响。TG分析表明,再挤出工艺对所研究的PET样品的热稳定性没有影响。最后,使用等转换Flynn Wall Ozawa和Friedman方法计算了所研究样品的热降解活化能。因此,与PET瓶样品相比,重新挤出的PET样品的活化能更高,这是支持PET瓶回收的一个很好的论据。
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引用次数: 0
LPMO as a Key Enzyme in the Sustainable Conversion of Lignocellulosic Biomass LPMO作为木质纤维素生物质可持续转化的关键酶
IF 0.7 Pub Date : 2023-05-17 DOI: 10.15255/kui.2023.010
T. Rezić, Martina Andlar, Ana Vrsalović Presečki
The importance of the lytic polysaccharide monooxygenase (LPMO) enzyme in the preparation of lignocellulosic raw materials for production in biorefineries has been confirmed in numerous investigations. Therefore, LPMO enzymes were investigated to explore the enzyme-substrate interaction with the aim of successful biomass conversion in biorefinery processes. After reduc - tive activation of LPMOs active site, they cleave the substrate and prepare it for biomass degradation by hydrolytic enzymes. In this paper, the role of LPMO in lignocellulosic biomass conversion is described based on the recent studies of: LPMO enzyme structure, LPMO substrate preferences, and the LPMO reaction mechanism. These findings are important for the selection of suitable bioprocess conditions with the aim of LPMO activation/stabilisation in biorefinery production processes.
裂解多糖单加氧酶(LPMO)在制备用于生物炼制的木质纤维素原料中的重要性已在大量研究中得到证实。因此,对LPMO酶进行了研究,以探索酶与底物的相互作用,目的是在生物炼制过程中成功转化生物质。LPMO活性位点还原活化后,他们切割底物,并通过水解酶将其制备为生物量降解。本文基于对LPMO酶结构、LPMO底物偏好和LPMO反应机理的最新研究,描述了LPMO在木质纤维素生物质转化中的作用。这些发现对于在生物炼制生产过程中选择合适的生物工艺条件以实现LPMO活化/稳定具有重要意义。
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引用次数: 0
Mechanical Behaviour of Dual Phase Steels under Different Strain Rates 双相钢在不同应变速率下的力学行为
IF 0.7 Pub Date : 2023-03-18 DOI: 10.15255/kui.2022.044
Labinot Topilla, S. Toros
The objective of this research was to analyse the stress and strain behaviours of the triaxiality specimens (specimens of different shaping) of dual-phase steels, respectively DP600 and DP800, whose microstructures mainly comprise ferrite and martensite phases. These steels find wide application in the automotive industry, which is constantly searching for better quality materials in the aim of increasing vehicle safety, protecting the environment, and reducing fuel consumption. In this case, for all tested specimens the experimental uniaxial tensile tests were performed at three different strain rates, 0.0083 s −1 , 0.042 s −1 , and 0.16 s −1 , to determine mechanical properties such as stress, strain, yield strength, and ultimate tensile strength of mentioned steels. In addition, uniaxial tensile tests with characteristics similar to those experimental were carried out through the finite element modelling method using the Mat_Picewise_Linear_Plasticity_024 model, to determine the mentioned mechanical properties, but also to determine the failure parameters or plastic strain up to failure, of all triaxiality modelled specimens. The obtained results were validated by comparing the experimental results with numerical simulation results. The comparative scale of accuracy between both steels was made at the fracture strain, and the average accuracy of both steels for the standard (s) specimens was < 1 %, for the (20a) specimens 1.50 %, for the (4a) specimens 4 %, and for (a) specimens 3.50 %. Finally, it was concluded that the proposed material model and calibrated failure data fitted very well.
本研究的目的是分析双相钢DP600和DP800的三轴度试样(不同形状的试样)的应力和应变行为,其微观结构主要包括铁素体和马氏体相。这些钢材在汽车行业有着广泛的应用,汽车行业不断寻找质量更好的材料,以提高车辆安全性、保护环境和降低燃料消耗。在这种情况下,对于所有测试样品,在三种不同的应变速率(0.0083 s−1、0.042 s−1和0.16 s−1)下进行实验单轴拉伸试验,以确定上述钢的机械性能,如应力、应变、屈服强度和极限拉伸强度。此外,通过有限元建模方法,使用Mat_Picewise_Lineer_Plasticity_024模型,进行了具有与实验相似特性的单轴拉伸试验,以确定所有三轴建模试样的上述力学性能,但也确定了失效参数或直至失效的塑性应变。通过将实验结果与数值模拟结果进行比较,验证了所获得的结果。在断裂应变下对两种钢的精度进行了比较,标准试样的两种钢平均精度<1%,(20a)试样的平均精度为1.50%,(4a)试样为4%,(a)试样为3.50%。最后得出结论,所提出的材料模型和标定的失效数据拟合良好。
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引用次数: 0
Prediction of Hourly Global Solar Radiation: Comparison of Neural Networks / Bootstrap Aggregating 每小时全球太阳辐射的预测:神经网络/自举聚合的比较
IF 0.7 Pub Date : 2023-03-18 DOI: 10.15255/kui.2022.065
Abdennasser Dahmani, Y. Ammi, S. Hanini, M. Yaiche, H. Zentou
This research work explores the use of single neural networks and bootstrap aggregated neural networks for predicting hourly global solar radiation. A database of 3606 data points were from the Renewable Energies Development Center, radiometric station ‘Shems’ of Bouzareah. The single neural networks and bootstrap aggregated neural networks were built together. The precision and durability of neural network models generated with an incomplete quantity of training datasets were improved using bootstrap aggregated neural networks. To produce numerous sets of training data points, the training data was re-sampled utilising bootstrap resampling by replacement. A neural network model was built for each of the data points. The individual neural network models were then combined to produce the bootstrap aggregated neural networks. The experimental and predicted values of global solar radiation were compared, and lower root mean squared errors (68.3968 and 62.4856 Wh m −2 ) were discovered during the testing phases for single neural networks and bootstrap aggregated neural networks, respectively. The results of these models show that the bootstrap aggregated neural networks model is more accurate and robust than single neural networks.
本研究工作探讨了单神经网络和自举聚合神经网络用于预测每小时全球太阳辐射的使用。3606个数据点的数据库来自Bouzareah的可再生能源发展中心的辐射测量站“Shems”。将单神经网络与自举聚合神经网络相结合。采用自举聚合神经网络,提高了由不完全训练数据集生成的神经网络模型的精度和耐久性。为了产生大量的训练数据点,训练数据被重新采样利用自举重采样替换。为每个数据点建立神经网络模型。然后将单个神经网络模型组合在一起,生成自举聚合神经网络。结果表明,单神经网络和自举聚合神经网络在测试阶段分别获得了较低的均方根误差(68.3968和62.4856 Wh m−2)。这些模型的结果表明,自举聚合神经网络模型比单个神经网络模型具有更高的精度和鲁棒性。
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引用次数: 1
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Kemija u Industriji-Journal of Chemists and Chemical Engineers
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