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Optimization of technological parameters for obtaining mineral additives based on calcined clays and carbonate rocks for cement systems 基于煅烧粘土和碳酸盐岩的水泥体系矿物添加剂的工艺参数优化
IF 1.2 Q2 Engineering Pub Date : 2022-04-30 DOI: 10.15828/2075-8545-2022-14-2-145-155
A. Balykov, T. Nizina, S. Volodin
: Introduction. The management of physical and chemical processes of structure formation of high performance cement composites can be provided at several scale levels through the use of modifiers of various nature and mechanism of action, in particular, micro- and nanoscale mineral additives of natural and technogenic origin. It is known that clays and carbonate rocks are promising raw materials to obtain mineral modifiers for cement systems. The purpose of this study was to establish the influence regularities of the prescription and technological parameters (material and granulometric compositions, temperature calcination) to obtain mineral additives based on calcined clays and carbonate rocks on their activity in cement systems. Methods and materials. Polymineral clays and carbonate rocks (dolomite and chalk) from several deposits of the Republic of Mordovia were used as raw materials for obtaining mineral additives. The specific surface area of modifiers was determined on the PSX-12 dispersion analysis device using the Kozeny-Carman method. The study of the granulometric composition of sedimentary rock powders was carried out by laser diffraction method. The research of physical-chemical processes occurring during the heat treatment of polymineral clays and carbonate rocks was carried out using the synchronous thermal analysis method. Optimization of calcination temperature of clay-carbonate mixtures was carried out based on the research results on the effect of their additives on the cement binder activity with the determination of the modifier activity index in accordance with the methodology of the Russian State Standard GOST R 56178-2014. Results and discussion. The optimum calcination temperature, located for polymineral clays in the area of 500–800 о C, was established according to the study results of dehydration processes of clay minerals using the synchronous thermal analysis. This temperature range corresponds to the initial restructuring processes in the crystal structure of minerals of the kaolinite and illite groups, associated with their dehydroxylation, which contributes to the transition of these phases to the active form. The study results of influence of additives of calcined clay-carbonate mixtures on the cement binder activity proved the thermal analysis data. It was found that calcination of clays and clay-carbonate mixtures at 700°C contributes to obtaining of the most effective mineral modifiers. Conclusions. On the totality of studies, regularities were revealed in the system “modifier composition – calcination temperature of sedimentary rocks – mixed binder activity”, which allow optimizing the prescription and technological parameters for obtaining mineral additives to achieve the required level of strength characteristics of cement composites.
:介绍。通过使用各种性质和作用机制的改性剂,特别是天然和技术来源的微纳米级矿物添加剂,可以在几个尺度上提供高性能水泥复合材料结构形成的物理和化学过程的管理。众所周知,粘土和碳酸盐岩是获得水泥体系矿物改性剂的有前途的原料。本研究的目的是建立基于煅烧粘土和碳酸盐岩的矿物添加剂的配方和工艺参数(材料和粒度组成、煅烧温度)对其在水泥体系中的活性的影响规律。方法和材料。多矿物粘土和碳酸盐岩(白云石和白垩)从摩尔多瓦共和国的几个矿床被用作原料,以获得矿物添加剂。在PSX-12色散分析装置上用Kozeny-Carman法测定了改性剂的比表面积。采用激光衍射法对沉积岩粉末的粒度组成进行了研究。采用同步热分析方法对多矿物粘土和碳酸盐岩热处理过程中的物理化学过程进行了研究。根据粘土-碳酸盐混合料外加剂对水泥粘结剂活性影响的研究结果,根据俄罗斯国家标准GOST R 56178-2014的方法测定改性剂活性指数,对粘土-碳酸盐混合料的煅烧温度进行优化。结果和讨论。根据黏土矿物脱水过程的同步热分析结果,确定了多矿物粘土的最佳煅烧温度在500 ~ 800℃范围内。这个温度范围对应于高岭石和伊利石基团矿物晶体结构的初始重组过程,与它们的去羟基化有关,这有助于这些相向活性形式的转变。煅烧粘土-碳酸盐混合料中添加剂对水泥粘结剂活性影响的研究结果证实了热分析数据的正确性。结果表明,在700℃下煅烧粘土和粘土-碳酸盐混合物有助于获得最有效的矿物改性剂。结论。综合研究,揭示了“改性剂组成-沉积岩煅烧温度-混合粘结剂活性”体系的规律,从而优化了矿物添加剂的配方和工艺参数,使水泥复合材料的强度特性达到所要求的水平。
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引用次数: 0
Additives to reduce the flammability of polymers 降低聚合物易燃性的添加剂
IF 1.2 Q2 Engineering Pub Date : 2022-04-30 DOI: 10.15828/2075-8545-2022-14-2-156-161
I. Zaripov, I. Vikhareva, E. A. Buylova, T. V. Berestova, A. Mazitova
: Introduction. This review article provides data on additives used to reduce the flammability of polymer compositions. It is shown that not individual substances are used for this purpose, but their mixtures, including flame retardants, synergists, and stabilizers. The principle of operation of flame retardants is that when the appropriate degree of concentration of flame retardants in the material is reached, they do not allow it to burn without the presence of an ignition source. Under the influence of fire on the processed material, various chemical and physical processes occur in it, preventing the flame from flaring up. Main part. The advantages and disadvantages of the main flame retardants currently used, which include antimony compounds, halogen-containing compounds, phosphorus-containing substances, as well as aluminum and magnesium hydroxides, are analyzed. Various mechanisms for slowing down combustion processes when flame retardants are used are considered. It has been shown that bromine-containing flame retardants are much more effective than chlorine-containing ones. They decompose in a narrow temperature range. In addi-tion, plastics containing bromine compounds as flame retardants are easily recycled due to the high thermal stability of such flame retardants. Phosphorus-containing compounds have a plasticizing ability and increase the fire resistance of plastic compounds. The action in the condensed phase is that during the decomposition of the flame retardant, phosphoric acid residues are formed, which act as dehydrating agents, contributing to the formation of carbonized structures. In this case, an aerosol can also be formed, which contributes to the deactivation of radicals due to the wall effect. Of particular interest are compounds containing halogen and phosphorus. The advantages of these compounds are as follows: by splitting off halogen radicals during decomposition, they deactivate active radicals; contribute to the formation of carbonized structures. Metal hydroxides decompose under the influence of high temperatures with the release of water. The decomposition reaction is endothermic, resulting in cooling of the substrate to temperatures below the flash point. The formation of water contributes to the dilution of combustible gases released during decomposition, weakens the effect of oxygen and reduces the rate of combustion. The effectiveness of hydroxides is directly proportional to their content in the polymer. The greatest efficiency is observed when aluminum hydroxide is introduced into oxygen-containing polymers (polyethylene terephthalate, polybutylene terephthalate, polyamide). Magnesium hydroxide is more expensive than aluminum hydroxide, but has a higher heat resistance (up to 300 о C). Conclusion. Thus, among the listed flame retardants, aluminum and magnesium hydroxides occupy the first place in terms of the volume of use (more than 40% of the total volume of flame retardants). This is due to their low cost
:介绍。本文综述了用于降低聚合物组合物易燃性的添加剂的数据。结果表明,用于此目的的不是单独的物质,而是它们的混合物,包括阻燃剂、增效剂和稳定剂。阻燃剂的工作原理是,当材料中的阻燃剂达到适当的浓度时,在没有点火源的情况下,它们不允许它燃烧。被加工材料在火的作用下,在其内部发生各种化学和物理过程,防止火焰燃烧起来。主要部分。分析了目前使用的主要阻燃剂的优缺点,包括锑化合物、含卤化合物、含磷物质以及氢氧铝和氢氧镁。当使用阻燃剂时,考虑了减缓燃烧过程的各种机制。研究表明,含溴阻燃剂比含氯阻燃剂的阻燃效果要好得多。它们在很窄的温度范围内分解。此外,含有溴化合物作为阻燃剂的塑料,由于这种阻燃剂的高热稳定性,很容易回收。含磷化合物具有塑化能力,提高塑料化合物的耐火性。缩合相的作用是阻燃剂在分解过程中形成磷酸残渣,磷酸残渣起到脱水剂的作用,促成炭化结构的形成。在这种情况下,还可以形成气溶胶,由于壁效应,它有助于自由基的失活。特别令人感兴趣的是含有卤素和磷的化合物。这些化合物的优点是:通过在分解过程中分裂卤素自由基,使活性自由基失活;有助于碳化结构的形成。金属氢氧化物在高温的影响下随着水的释放而分解。分解反应是吸热的,导致基材冷却到闪点以下的温度。水的形成有助于稀释分解过程中释放的可燃气体,削弱氧气的作用,降低燃烧速度。氢氧化物的有效性与它们在聚合物中的含量成正比。当氢氧化铝被引入含氧聚合物(聚对苯二甲酸乙二醇酯、聚对苯二甲酸丁二酯、聚酰胺)时,效率最高。氢氧化镁比氢氧化铝更昂贵,但具有更高的耐热性(高达300℃)。由此可见,在所列阻燃剂中,氢氧化铝和氢氧化镁的使用体积居首位(占阻燃剂总体积的40%以上)。这是由于它们的低成本、可制造性和环境安全性。一个精心选择的金属氢氧化物系统产生低成本的不燃材料,分解产生的烟雾很少。因此,金属氢氧化物作为阻燃剂的使用量不断增加。
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引用次数: 2
Collagen Based Bio-Additives in Polymer Composites 高分子复合材料中基于胶原蛋白的生物添加剂
IF 1.2 Q2 Engineering Pub Date : 2022-04-30 DOI: 10.15828/2075-8545-2022-14-2-137-144
A. Baldanov, L. Bokhoeva, D. Shalbuev, T. Tumurova
: Introduction. Polymer composite materials (PCM) based on epoxy resins are widely used in the construction industry. They are applied in construction of bridge spans, roadway slabs, footwalk planks, in low-loaded structures, as well as for reinforcement of concrete structures, sheating, strengthening of metal and concrete structures. Various fillers of micro- and nanosizes are used to improve the performance properties of PCM. Interfacial interaction between the filler and the polymer matrix plays an important role in determining the strength of the created composite materials. Methods and materials. The article studies the properties of polymer matrix composites reinforced with collagen based bio-additives obtained from solid organic waste of the leather industry. We have developed a fundamentally new method for obtaining a bioactive collagen product at a relatively low price, described in patent RU No. 2272808. Tensile studies of the PCM samples were carried out by adding dry collagen powder to an epoxy binder. We analyzed the sections of samples made on a JSM-6510LVJEOL scanning electron microscope, and studied the changes in the structure of PCM with fillers. Results and discussion. When 1% collagen is added to the PCM matrix, the amount of chemical elements is increasing: carbon (C) by 2.93%, oxygen (O) by 1.61%, magnesium (Mg) by 0.11%. And the number of micropores on the surface of the matrix, which serve as a stress concentrator, is decreasing by 4.9%, and they are also diminishing in size. The tensile tests have shown that when 1% collagen is added to the PCM matrix, the bearing capacity of the samples is increasing by 15.57%. The results obtained can contribute to the expansion of collagen application, waste reduction in the leather industry due to recycling. Conclusion. A fundamentally new method has been developed for obtaining a bioactive collagen product from solid organic waste of the leather industry at a relatively low price. It has been established that a bioactive collagen product in a powder form has a low cost and can be used as a bio-additive for PCM.
:介绍。以环氧树脂为基础的高分子复合材料(PCM)在建筑工业中得到了广泛的应用。它们适用于桥梁跨径、道路板、人行道板、低荷载结构的施工,以及混凝土结构的加固、护层、金属和混凝土结构的加固。采用各种微、纳米级填料来改善PCM的性能。填料与聚合物基体之间的界面相互作用是决定复合材料强度的重要因素。方法和材料。研究了从皮革工业固体有机废弃物中提取的胶原基生物添加剂增强聚合物基复合材料的性能。我们开发了一种全新的方法,以相对较低的价格获得生物活性胶原蛋白产品,专利RU No. 2272808描述。通过将干燥的胶原蛋白粉末加入到环氧粘合剂中,对PCM样品进行了拉伸研究。用JSM-6510LVJEOL扫描电镜对样品切片进行了分析,研究了填料对PCM结构的影响。结果和讨论。当PCM基质中加入1%的胶原蛋白时,化学元素的数量增加:碳(C)增加2.93%,氧(O)增加1.61%,镁(Mg)增加0.11%。基体表面起应力集中作用的微孔数量减少了4.9%,微孔尺寸也在减小。拉伸试验表明,当PCM基质中加入1%的胶原蛋白时,样品的承载力提高了15.57%。所得结果有助于扩大胶原蛋白的应用,减少皮革工业中因回收而产生的废物。结论。一种从皮革工业的固体有机废物中以相对较低的价格获得生物活性胶原蛋白产品的新方法已经被开发出来。研究表明,粉末形式的生物活性胶原蛋白产品成本低,可作为PCM的生物添加剂。
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引用次数: 0
Phase-structural heterogeneity and activity of the surface of polymineral sand powders 多矿物砂粉表面相结构非均质性及活性
IF 1.2 Q2 Engineering Pub Date : 2022-04-30 DOI: 10.15828/2075-8545-2022-14-2-89-95
M. Morozova, A. Ayzenshtadt, M. Akulova, M. Frolova
: Introduction. The value of the specific surface ( S sp ), the degree of crystallinity (С, %) and surface activity ( k s ) plays an important role in creating various compositions. The increase in the size of S sp is associated with a change in the “С” of rock powders, the value of which characterizes the properties of fillers. The reactivity of the finely dispersed material can be determined by the value of k s , which allows quantifying transition of the potential energy into free surface energy by activating the surface of the raw material. Therefore, determining the functional relationship between the parameters characterizing the reactivity of rock powders is an urgent task. Methods and Materials. Four deposits of polymineral construction sands are selected as raw materials. To obtain fine powders, the samples were ground by dry dispersion. The specific surface area of rock systems was determined by gas sorption. Crystallinity was calculated from the X-ray diffractogram of the samples. Results and Discussion. The certain sizes of specific surfaces for highly dispersed rocks have shown, that deposits “Kenica” and “Nekhtskoye” possess the greatest values S sp . The study of the phase-structural heterogeneity of the samples, showed a significant increase of the content of the amorphous phase. At the same time, the degree of crystallinity for the sands “Kenica” and “Nekhtskoye” deposits decreases 25%. The functional relationship between the surface activity and the shares of the amorphous component ( c ) for highly dispersed sands was characterized by mathematical expression k s = 21 • 10 –6 • c +0,58 • 10 –6 . The identified dependence demonstrates the relationship between the parameters of the phase-structural heterogeneity and k s of fine-dispersed samples. Conclusion. The results obtained showed that mechanical dispersion contributes to the activation of raw materials. This is due to the breakability of the crystal structure of minerals and the texture of the raw materials. These characteristics are reflected in the value of the activity of the surface of fine-dispersed systems of the rocky rocks.
:介绍。比表面(S sp)的值、结晶度(С, %)和表面活性(k S)在创造各种组合物中起着重要作用。粒径的增加与岩石粉末“С”的变化有关,其值表征填料的性质。精细分散的材料的反应性可以通过k s的值来确定,k s可以通过激活原料的表面来量化势能向自由表面能的转变。因此,确定表征岩石粉末反应性的参数之间的函数关系是一项紧迫的任务。方法与材料。选取了四种多矿物建筑砂矿床作为原料。为获得细粉,样品采用干分散法研磨。岩石体系的比表面积由气体吸附量决定。根据样品的x射线衍射图计算结晶度。结果和讨论。高度分散岩石的特定表面尺寸表明,“Kenica”和“Nekhtskoye”矿床具有最大的S sp值。对样品相结构非均质性的研究表明,非晶相的含量显著增加。同时,“Kenica”和“Nekhtskoye”砂的结晶度降低了25%。用数学表达式k s = 21•10 -6•c +0,58•10 -6表征了高分散砂的表面活性与非晶态组分(c)份额之间的函数关系。确定的依赖关系说明了细分散样品的相结构非均质性参数与k s之间的关系。结论。结果表明,机械分散有助于原料的活化。这是由于矿物晶体结构的易碎性和原料的质地。这些特征反映在岩石细分散体系表面活动性的数值上。
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引用次数: 0
Socio-economic assessment of the use of nature-like nanotechnologies for the reengineering of the technosphere 利用类自然纳米技术进行技术圈再造的社会经济评估
IF 1.2 Q2 Engineering Pub Date : 2022-04-30 DOI: 10.15828/2075-8545-2022-14-2-119-136
V. Belozerov, M. Nikulin, V. Belozerov
: Introduction. Recently, the term “nature-like technologies” has appeared in the everyday life of scientists and politicians, which quite deservedly include the so-called alternative energy sources (sun, wind, heat). At the same time, despite the fact that installations using these sources are “seasonal” and low concentrated, their use is rapidly and haphazardly developing, and many economists and politicians mistakenly consider them as basics, misleading business. Based on the analysis of the epistemology of the origin of the term "nature-like technologies", this article shows the groundlessness, and even the harm of the rapid and unsystematic use of wind turbines. Evidence is given of the inconsistency of the "myths" that Nature cannot cope with the compensation of the economic activity of mankind, therefore, according to Academician Sergeyev S.M., President of the Russian Academy of Sciences, "reengineering of the technosphere" is required. At the same time, modern economic science is far from taking into account in his models of the assimilation potentials of the biosphere of regions and the functions of entropy production in them, preferring to model various “cycles and modes”, as well as calculate different “coefficients” in order to predict “crises and equilibria”, without taking into account the interaction nature and society. In this connection, a scientific and technical task about determinating the “place of reengineering of the technosphere” in the structure of the life support systems of society, and, consequently, to evaluate its effectiveness. Methods, models and tools. To solve the tasks set, it is proposed to use the “retro-forecast method” of socio-economic losses from the introduction of “natural nanotechnologies”, using as “tools” the method of “spatio-temporal analysis”, model of the Leontief-Ford and adaptive taxation systems of “harm production”, the use of which in solving the problems of fire and environmental safety in the "technospheres of the regions" of the South of Russia (in road transport infrastructures, in cities and towns, in buildings and structures), proved their adequacy to the processes under study and usefulness. Results and discussion. The results of modeling the costs of efficiency of "reengineering of the technosphere" in Russia, in particular individual residential buildings, and a retro-forecast of changes in socio-economic and environmental losses during the autonomy of their resource supply (electric-ity, water and heat) are presented. It is shown that the production of domestic innovations in this area (“Shukhov’s” wind turbines, atmospheric water condensation devices and electric heating) will allow stopping the “total gasification” of rural settlements, as well as more economically than abroad, to implement decentralized supply of resources in Russia more than 10 million individual houses and about 40 million country houses, thus determining the “true place of alternative energy” in the structure
:介绍。最近,“类自然技术”一词出现在科学家和政治家的日常生活中,其中理所当然地包括所谓的替代能源(太阳能、风能、热能)。与此同时,尽管使用这些能源的装置是“季节性的”、低集中度的,但它们的使用正在迅速而随意地发展,许多经济学家和政治家错误地认为它们是基本的,误导了商业。本文在对“类自然技术”一词起源认识论分析的基础上,揭示了快速、不系统地使用风力发电机的无根据,甚至危害。有证据表明,认为大自然无法补偿人类经济活动的“神话”是不一致的,因此,根据俄罗斯科学院院长谢尔盖耶夫·s.m.院士的说法,“技术圈的再造”是必要的。与此同时,现代经济科学远远没有考虑到他的区域生物圈的同化潜力和其中的熵产函数的模型,而是倾向于模拟各种“循环和模式”,以及计算不同的“系数”,以预测“危机和平衡”,而没有考虑到自然和社会的相互作用。在这方面,一项关于确定“技术圈再造”在社会生命支持系统结构中的位置的科学和技术任务,并因此评估其有效性。方法、模型和工具。解决任务集,提出了使用“retro-forecast法”的社会经济损失的引入“自然纳米技术”,使用“工具”“时空分析”的方法,模型Leontief-Ford和自适应税收系统的“危害生产”,火的使用在解决问题和环境安全的“区域技术领域”俄罗斯南部(在道路运输基础设施,在城市和城镇,在建筑物和结构中),证明了它们在研究过程中的充分性和实用性。结果和讨论。本文介绍了俄罗斯“技术圈再造”效率成本建模的结果,特别是个别住宅建筑,以及在其资源供应(电、水和热)自治期间社会经济和环境损失变化的回顾性预测。该领域的国内创新产品(“舒霍夫”的风力涡轮机,大气冷凝水装置和电加热)将使农村定居点停止“总气化”,并比国外更经济地实现俄罗斯1000多万户个人住宅和约4000万户乡村住宅的资源分散供应。从而确定替代能源在俄罗斯电力、天然气、水和供热系统结构中的“真正地位”。结论。所提出的方法使我们能够确定所谓的可再生能源在城市和农村住区资源供应系统结构中的位置。与此同时,在风能和太阳能电池板领域提出的创新方案中,有可能出现更富有成效的设计解决方案,将“自治”扩展到区域中心和工人居住区的低层和多公寓建筑,而不是主要恢复具有锅炉房和小型热电联产的集中工程系统。
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引用次数: 1
Sustainable municipal solid waste incineration fly ash (MSWIFA) alkali-activated materials in construction: Fabrication and performance 可持续城市生活垃圾焚烧飞灰(MSWIFA)碱活性材料在建筑中的制造和性能
IF 1.2 Q2 Engineering Pub Date : 2022-02-28 DOI: 10.15828/2075-8545-2022-14-1-43-52
Pengwei Dong, Jingyi Liu, Huiru Wang, Hongyan Yuan, Quan Wang
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引用次数: 7
Synthesis of life support nanotechnologies into a replicated autonomous engineering system of an individual dwelling house 将生命维持纳米技术合成到一个独立住宅的复制自主工程系统中
IF 1.2 Q2 Engineering Pub Date : 2022-02-28 DOI: 10.15828/2075-8545-2022-14-1-33-42
V. Belozerov, I. Voroshilov, S. Oleinikov, V. Belozerov
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引用次数: 1
Prescription and technological efficiency of sedimentary rocks of various composition and genesis in cement systems 水泥体系中不同成分和成因沉积岩的配方及工艺效率
IF 1.2 Q2 Engineering Pub Date : 2022-02-28 DOI: 10.15828/2075-8545-2022-14-1-53-61
A. Balykov, T. Nizina, V.M. Kyashkin, S. Volodin
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引用次数: 1
Overview of the instrumental base for the control of greenhouse gases 温室气体控制仪器基础概述
IF 1.2 Q2 Engineering Pub Date : 2022-02-28 DOI: 10.15828/2075-8545-2022-14-1-62-69
E. Muravyova, E. Kulakova
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引用次数: 0
High-strength wall ceramics based on phosphorus slag and bentonite clay 基于磷渣和膨润土的高强度壁陶瓷
IF 1.2 Q2 Engineering Pub Date : 2022-02-28 DOI: 10.15828/2075-8545-2022-14-1-11-17
Zhazira Suleimenov, A. Sagyndykov, Zhangazy N. Moldamuratov, G. M. Bayaliyeva, Z. Alimbayeva
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引用次数: 2
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Nanotechnologies in Construction-A Scientific Internet-Journal
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