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Geology and mineralization of the Hongqiling large magmatic nickel-copper-cobalt deposit (22×104 t) in Jilin Province, China: A review 中国吉林省红旗岭大型岩浆型镍铜钴矿床(22×104 吨)的地质与矿化:综述
IF 4.6 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-25 DOI: 10.31035/cg2023106
Cong Chen , Yu-chao Gu , Di Zhang , Tao-tao Wu , Ai Li , Yun-sheng Ren , Qing-qing Shang , Jian Zhang , Xiong-fei Bian , Fei Su , Jia-lin Yang , Qiu-shi Sun , Xiao-hai Li , Wan-zhen Liu , Zhen-ming Sun , Sen Zhang , Yu-hui Feng
The Hongqiling large nickel-copper-cobalt deposit (hereafter referred to as the Hongqiling deposit), a typical mafic-ultramafic copper-nickel deposit in China, boasts proven Ni (Ni) resources of approximately 22×104 t, associated copper resources of 2×104 t, and associated cobalt (Co) resources of 0.5×104 t, with Ni reserves ranking 10th among China’s magmatic nickel deposits. Geotectonically, the Hongqiling deposit is situated in the superimposed zone between the Xing’an-Mongolian orogenic belt and the circum-Western Pacific’s active continental margin belt. Its ore-bearing plutons occur within the metamorphic rocks of the Ordovician Hulan Group, with the emplacement of plutons and the locations of orebodies governed by the deep-seated Huifahe fault and its secondary NW-trending Fujia-Hejiagou-Beixinglong-Changsheng fault zone. In the deposit, the rock assemblages of ore-bearing plutons predominantly encompass gabbro - pyroxenite - olivine pyroxenite - pyroxene peridotite (pluton No. 1) and noriteorthopyroxenite-harzburgite (pluton No. 7), with ore-bearing lithofacies consisting primarily of olivine pyroxenite and pyroxenite facies. The Hongqiling deposit hosts stratoid, overhanging lentoid, veined, and pure-sulfide veined orebodies. Its ores principally contain metallic minerals including pyrrhotite, pentlandite, chalcopyrite, violarite, and pyrite. Despite unidentified magma sources of ore-bearing mafic-ultramafic rocks, it is roughly accepted that the magmatic evolution in the Hongqiling deposit primarily involved fractional crystallization and crustal contamination. The ore-forming materials were primarily derived from the upper mantle, mixed with minor crustal materials. The ore-bearing mafic-ultramafic rocks in the deposit, primarily emplaced during the Indosinian (208–239 Ma), were formed in an intense extension setting followed by the collisional orogeny between the North China Plate and the Songnen-Zhangguangcai Range Block during the Middle-Late Triassic. From the perspective of the metallogenic geological setting, surrounding rocks, ore-controlling structures, and rock assemblages, this study identified one favorable condition and seven significant indicators for prospecting for Hongqiling-type nickel deposits and developed a prospecting model of the Hongqiling deposit. These serve as valuable references for exploring similar nickel deposits in the region, as well as the deep parts and margins of the Hongqiling deposit.
红旗岭大型镍铜钴矿床(以下简称红旗岭矿床)是中国典型的岩浆-超基性铜镍矿床,已探明镍资源量约22×104吨,伴生铜资源量2×104吨,伴生钴资源量0.5×104吨,镍储量居中国岩浆镍矿床第10位。从大地构造上看,红旗岭矿床位于兴安-蒙古造山带与环西太平洋活动大陆边缘带的叠加地带。其含矿岩体位于奥陶系呼兰组变质岩中,岩体的成因和矿体的位置受深层辉发河断裂及其次生的西北走向傅家-何家沟-北兴隆-长胜断裂带的制约。在矿床中,含矿岩体的岩石组合主要包括辉长岩-辉石-橄榄辉石-辉石橄榄岩(1 号岩体)和诺雷石-正辉石-哈氏辉石(7 号岩体),含矿岩相主要由橄榄辉石面和辉石面组成。红旗岭矿床拥有层状、悬垂透镜状、脉状和纯硫化物脉状矿体。其矿石主要含有金属矿物,包括黄铁矿、戊兰铁矿、黄铜矿、辉钼矿和黄铁矿。尽管含矿黑云母-超黑云母岩的岩浆来源不明,但人们大致认为红旗岭矿床的岩浆演化主要涉及碎屑结晶和地壳污染。成矿物质主要来自上地幔,并混有少量地壳物质。矿床中的含矿岩浆岩-超基性岩主要赋存于印支期(208-239Ma),形成于中晚三叠世华北板块与松嫩-张广才岭地块碰撞造山运动之后的强烈延伸环境中。本研究从成矿地质环境、围岩、控矿构造、岩石组合等方面,确定了红旗岭型镍矿床找矿的1个有利条件和7个重要指标,建立了红旗岭矿床找矿模型。这些对勘探该地区的类似镍矿床以及红旗岭矿床的深部和边缘具有重要的参考价值。
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引用次数: 0
Hydrochemical characteristics of surface water in Hengduan mountain region of Eastern Tibet and its response to human activities: A case study of Duoqu Basin, Jinsha River 藏东横断山区地表水水化学特征及其对人类活动的响应:金沙江多曲盆地案例研究
IF 4.6 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-25 DOI: 10.31035/cg2023053
Jing-jie Li , Sheng Lian , Ming-guo Wang , Huai-sheng Zhang , Tao Yang
The analysis of hydrochemical characteristics and influencing factors of surface river on plateau is helpful to study water hydrological cycle and environmental evolution, which can scientifically guide rational development and utilization of water resources and planning of ecological environment protection. With the expansion and diversification of human activities, the quality of surface rivers will be more directly affected. Therefore, it is of great significance to pay attention to the hydrochemical characteristics of plateau surface rivers and the influence of human activities on their circulation and evolution. In this study, surface water in the Duoqu basin of Jinsha River located in Hengduan mountain region of Eastern Tibet was selected as the representative case. Twenty-three groups of surface water samples were collected to analyze the hydrochemical characteristics and ion sources based on correlation analysis, piper trigram, gibbs model, hydrogen and oxygen isotopic techniques. The results suggest the following: (1) The pH showed slight alkalinity with the value ranged from 7.25 to 8.62. Ca2+, Mg2+ and HCO3 were the main cations and anions. HCO3-Ca and HCO3-Ca·Mg were the primary hydrochemical types for the surface water of Duoqu River. The correlation analysis showed that TDS had the most significant correlation with Ca2+, Mg2+ and HCO3. Analysis on hydrogen and oxygen isotopes indicated that the surface rivers were mainly recharged by atmospheric precipitation and glacial melt water in this study area. (2) The surface water had a certain reverse cation alternating adsorption, and surface water ions were mainly derived from rock weathering, mainly controlled by weathering and dissolution of carbonates, and secondly by silicates and sodium rocks. (3) The influence of human activities was weak, while the development of cinnabar minerals had a certain impact on the hydrochemistry characteristics, which was the main factor for causing the increase of SO42–. The densely populated county towns and temples with frequent incense burning activities may cause some anomalies of surface water quality. At present, the Duoqu River watershed had gone through a certain influence of mineral exploitation, so the hydrological cycle and river ecoenvironment at watershed scale will still bound to be change. The results could provide basic support for better understanding water balance evolution as well as the ecological protection of Duoqu River watershed.
分析高原地表河流的水化学特征和影响因素,有助于研究水文循环和环境演变规律,科学指导水资源的合理开发利用和生态环境保护规划。随着人类活动的扩展和多样化,地表河流的水质将受到更直接的影响。因此,关注高原地表河流的水化学特征以及人类活动对其循环和演变的影响具有重要意义。本研究选取了位于西藏东部横断山区的金沙江朵曲流域地表水作为研究对象。采集了 23 组地表水样品,采用相关分析、哌啶三叉法、吉布斯模型、氢氧同位素等技术分析了水化学特征和离子源。结果表明(1) pH 值在 7.25 至 8.62 之间,呈现轻微碱性。Ca2+、Mg2+ 和 HCO3- 是主要的阳离子和阴离子。HCO3-Ca 和 HCO3-Ca-Mg 是多曲河地表水的主要水化学类型。相关性分析表明,TDS 与 Ca2+、Mg2+ 和 HCO3- 的相关性最大。氢、氧同位素分析表明,该研究区地表河流主要由大气降水和冰川融水补给。(2)地表水具有一定的反阳离子交替吸附作用,地表水离子主要来源于岩石风化,主要受碳酸盐岩风化溶解控制,其次受硅酸盐岩和钠盐岩控制。(3)人类活动影响较弱,而朱砂矿物的发育对水化学特征有一定影响,是导致 SO42- 增加的主要因素。人口密集的县城和寺庙烧香活动频繁,可能会导致地表水水质出现异常。目前,多曲河流域已经历了一定的矿产开发影响,流域尺度的水文循环和河流生态环境仍将发生一定的变化。研究结果可为更好地认识多曲河流域水量平衡演变规律和生态保护提供基础支撑。
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引用次数: 0
Sedimentary environment and organic matter accumulation of Wufeng-Longmaxi shales, southwest Yangtze Plate, China: Insights from geochemical and petrological evidence 中国长江西南板块五峰-龙马溪页岩的沉积环境与有机质积累:地球化学和岩石学证据的启示
IF 4.6 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-25 DOI: 10.31035/cg2022074
An-kun Zhao , Dong Wang , Qian Zhang , Zi-hui Lei , Qian Yu , Di Zhang , Ye-xin Zhou
Upper Ordovician–Lower Silurian Wufeng-Longmaxi Formation is the most developed strata of shale gas in southern China. Due to the complex sedimentary environment adjacent to the Kangdian Uplift, the favorable area for organic-rich shale development is still undetermined. The authors, therefore, focus on the mechanism of accumulation of organic matter and the characterization of the sedimentary environment of the Wufeng-Longmaxi Shales to have a more complete understanding and new discovering of organic matter enrichment and favorable area in the marginal region around Sichuan Basin. Multiple methods were applied in this study, including thin section identification, scanning electron microscopy (SEM) observations and X-ray diffraction (XRD), and elemental analysis on outcrop samples. Five lithofacies have been defined according to the mineralogical and petrological analyses, including mudstone, bioclastic limestone, silty shale, dolomitic shale, and carbonaceous siliceous shale. The paleo-environments have been reconstructed and the organic enrichment mechanism has been identified as a reduced environment and high productivity. The Wufeng period is generally a suboxic environment and the early Longmaxi period is a reducing environment based on geochemical characterization. High dolomite content in the study area is accompanied by high TOC, which may potentially indicate the restricted anoxic environment formed by biological flourishing in shallower water. And for the area close to the Kangdian Uplift, the shale gas generation capability is comparatively favorable. The geochemical parameters implied that new favorable areas for shale gas exploration could be targeted, and more shale gas resources in the mountainbasin transitional zone might be identified in the future.
上奥陶统-下志留统五峰-龙马溪地层是中国南方页岩气最发育的地层。由于康店隆起附近沉积环境复杂,富含有机质页岩发育的有利区域尚未确定。因此,作者重点研究了五峰-龙马溪页岩的有机质富集机制和沉积环境特征,以期对四川盆地周边边缘地区的有机质富集和有利区域有更全面的认识和新的发现。本研究采用了多种方法,包括薄片鉴定、扫描电子显微镜(SEM)观察和 X 射线衍射(XRD),以及露头样品的元素分析。根据矿物学和岩石学分析,确定了五种岩性,包括泥岩、生物碎屑灰岩、硅质页岩、白云质页岩和碳质硅质页岩。对古环境进行了重建,并确定了有机质富集机制为还原环境和高生产力。根据地球化学特征,五峰期总体为亚缺氧环境,龙马溪早期为还原环境。研究区白云岩含量高,同时总有机碳含量也高,这可能表明生物在较浅的水体中繁衍形成了限制性缺氧环境。而在靠近康店隆起带的地区,页岩气的生成能力相对较好。这些地球化学参数表明,可以锁定新的页岩气勘探有利区域,未来可能会在山盆过渡带发现更多的页岩气资源。
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引用次数: 0
Pacific oyster (Crassostrea gigas) shell growth duration in a year in Bohai Bay and implication for its carbon sink potential 渤海湾太平洋牡蛎(Crassostrea gigas)一年中贝壳生长持续时间及其对碳汇潜力的影响
IF 4.6 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-25 DOI: 10.31035/cg2023054
Wen-yu Wang , Chang-fu Fan , Zhao-jun Song , Hong Wang , Fu Wang
Oyster is a bivalve mollusk widely distributed in estuarine and shallow sea environments. Its growth and burial process is a carbon sequestration and storage process. Oyster shell may stop growing due to suffer from freeze shock during the winter season within a temperate climate, therefore, in order to study the carbon sequestration capacity of oysters we need to know the water temperature at which the shell suffer from winter freeze shock. This study examines δ18O profiles across consecutive micro-growth layers found in three modern Pacific oyster shells from the northwest coast of Bohai Bay. A total of 165 oxygen isotope values from sequential samples of their left shells showed periodically varying values, and the variation fluctuation of oxygen isotope values was 4.97‰ on average. According to the variation range of the oxygen isotope value of the shell, combined with the sea surface temperature and the sea surface salinity data of the water in which the oysters grew, the water temperature that suffer from winter freeze shock and stops or retards the growth of Pacific oysters in Bohai Bay is about 8.3°C, and the corresponding period is from December to March of the following year. The calcification time of oysters within one year is nearly a month longer than previously thought, therefore, its carbon sink potential is also improved.
牡蛎是一种双壳软体动物,广泛分布于河口和浅海环境。其生长和埋藏过程是一个固碳和储碳过程。在温带气候的冬季,牡蛎壳可能会因遭受冻害而停止生长,因此,为了研究牡蛎的固碳能力,我们需要了解牡蛎壳遭受冬季冻害的水温。本研究考察了渤海湾西北海岸三个现代太平洋牡蛎贝壳中连续微生长层的δ18O剖面。从它们的左壳中连续取样,共有 165 个氧同位素值呈现周期性变化,氧同位素值的变化波动平均为 4.97‰。根据贝壳氧同位素值的变化范围,结合牡蛎生长水域的海表温度和海表盐度数据,渤海湾太平洋牡蛎遭受冬季冰冻冲击而停止或延缓生长的水温约为 8.3℃,相应时期为 12 月至次年 3 月。牡蛎一年内的钙化时间比以前想象的长了近一个月,因此其碳汇潜力也得到了提高。
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引用次数: 0
Geological risk assessment of traffic engineering construction among 7.0–8.5 magnitude earthquake areas: Practice from the Sichuan-Tibet transport corridor in the eastern Tibetan Plateau 7.0-8.5 级地震区交通工程建设地质风险评估:来自青藏高原东部川藏交通走廊的实践
IF 4.6 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-25 DOI: 10.31035/cg2023055
Ning Zhong , Xian-bing Zhang , Chang-bao Guo , Zhen Yang , Hao Yu , Rui-an Wu , Yang Wang , Hai-bing Li
At least 13 active fault zones have developed in the Ya’an-Linzhi section of the Sichuan-Tibet transport corridor, and there have been undergone 17 MS ≥ 7.0 earthquakes, the largest earthquake is 1950 Chayu MS 8.5 earthquake, which has very strong seismic activity. Therefore, carrying out engineering construction in the Sichuan-Tibet transport corridor is a huge challenge for geological technological personnel. To determining the spatial geometric distribution, activity of active faults and geological safety risk in the Sichuan-Tibet transport corridor. Based on remote sensing images, ground surveys, and chronological tests, as well as the deep geophysical and current GPS data, we investigated the geometry, segmentation, and paleoearthquake history of five major active fault zones in the Ya’an-Linzhi section of the Sichuan-Tibet transport corridor, namely the Xianshuihe, Litang, Batang, Jiali-Chayu and Lulang-Yigong. The five major fault zones are all Holocene active faults, which contain strike-slip components as well as thrust or normal fault components, and contain multiple branch faults. The Selaha-Kangding segment of the Xianshuihe fault zone, the Maoyaba and Litang segment of the Litang fault zone, the middle segment (Yigong-Tongmai-Bomi) of Jiali-Chayu fault zone and Lulang-Yigong fault zone have the risk of experiencing strong earthquakes in the future, with a high possibility of the occurrence of MS ≥ 7.0 earthquakes. The Jinsha River and the Palong-Zangbu River, which is a high-risk area for geological hazard chain risk in the Ya’an-Linzhi section of the Sichuan-Tibet transport corridor. Construction and safe operation Ya’an-Linzhi section of the Sichuan-Tibet transport corridor, need strengthen analysis the current crustal deformation, stress distribution and fault activity patterns, clarify active faults relationship with large earthquakes, and determine the potential maximum magnitude, epicenters, and risk range. This study provides basic data for understanding the activity, seismicity, and tectonic deformation patterns of the regional faults in the Sichuan-Tibet transport corridor.
川藏交通走廊雅安至林芝段至少发育了 13 条活动断裂带,发生过 17 次 MS≥7.0 级地震,最大地震为 1950 年察隅 MS 8.5 级地震,地震活动性极强。因此,在川藏交通走廊进行工程建设,对地质技术人员来说是一个巨大的挑战。为确定川藏交通走廊活动断层的空间几何分布、活动性及地质安全风险。基于遥感影像、地面调查和年代学测试,以及深部地球物理和当前 GPS 数据,我们研究了川藏交通走廊雅安至林芝段的五大活动断裂带,即咸水河段、理塘段、巴塘段、嘉黎至察隅段和鲁朗至宜贡段的几何形状、断裂分段和古地震历史。这五大断层带均为全新世活动断层,其中既有走向滑动断层,也有推覆断层或正断层,并包含多个分支断层。仙水河断裂带的色拉哈-康定段、理塘断裂带的毛家坝-理塘段、嘉黎-察右断裂带的中段(宜工-通麦-波密)和鲁朗-宜工断裂带未来有发生强震的危险,发生 MS≥7.0 地震的可能性较大。金沙江和帕隆藏布江,是川藏交通走廊雅安至林芝段地质灾害连锁风险高发区。川藏交通走廊雅安至林芝段的建设和安全运行,需要加强对当前地壳变形、应力分布和断层活动规律的分析,明确活动断层与大地震的关系,确定潜在的最大震级、震中和危险范围。本研究为了解川藏交通走廊区域断层的活动性、地震性和构造变形规律提供了基础数据。
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引用次数: 0
Apatite and zircon (U-Th)/He dating of sandstone in the Weibei Uplift, Ordos Basin and its revealed Eocene rapid uplift denudation event 鄂尔多斯盆地渭北隆起带砂岩的磷灰石和锆石(U-Th)/He年代测定及其揭示的始新世快速隆起剥蚀事件
IF 4.6 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-25 DOI: 10.31035/cg2023064
Peng Gao , Sheng-biao Hu
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引用次数: 0
Hydrochemistry of the lakes in the southern Badain Jaran Desert and its paleosalinity reconstruction 巴丹吉林沙漠南部湖泊的水化学及其古盐度重建
IF 4.6 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-25 DOI: 10.31035/cg2023057
Gao-lei Jiang , Zhe Wang , Zhen-long Nie , Zhong-shuang Cheng , Pu-cheng Zhu , Le Cao , Jian-mei Shen
The reconstruction of paleohydrology, especially paleosalinity, is an important component of paleoenvironmental research. Researches on the modern characteristics of lake water chemistry and the relationship between lake salinity and hydrochemistry are the basis of paleoenvironment reconstruction. The modern hydrochemical characteristics and the relationship between ion composition and salinity of modern lakes are the basis of paleosalinity reconstruction. In this study, hydrochemical analysis of 21 lakes in the Badain Jaran Desert (BJD) was carried out. The relationships between the Sr/Ca and Mg/Ca ratios and total dissolved solids (TDS) were analyzed. The results show that Na+, K+, Cl and SO42− have high positive correlations with TDS, and Mg2+, Sr2+, CO32− and HCO3 have lower correlations with TDS. The Sr/Ca and Mg/Ca ratios do not increase linearly with TDS. Hydrochemical analysis indicates that the studied lakes are in the carbonate precipitation stage and that evaporation is the main factor controlling lake evolution in the BJD. The relationships between the Mg/Ca and Sr/Ca ratios and TDS are mainly influenced by lake evolution stage and the hydrochemical types of the lakes. On the basis of comprehensive previous studies, the factors affecting lake evolution, the Mg and Sr partition coefficients and other hydrochemical parameters that change with lake evolution all affect the relationship between chemical composition and salinity. To reconstruct paleosalinity more accurately, more detailed research on the modern hydrochemical characteristics of lakes and the relationship between the element ratios of carbonates and water salinity should be carried out.
古水文,特别是古盐度的重建是古环境研究的重要组成部分。研究现代湖泊水化学特征以及湖泊盐度与水化学的关系是重建古环境的基础。现代湖泊水化学特征及离子组成与盐度的关系是古盐度重建的基础。本研究对巴丹吉林沙漠(BJD)的 21 个湖泊进行了水化学分析。分析了 Sr/Ca 和 Mg/Ca 比率与总溶解固体(TDS)之间的关系。结果表明,Na+、K+、Cl- 和 SO42- 与 TDS 呈高度正相关,而 Mg2+、Sr2+、CO32- 和 HCO3- 与 TDS 的相关性较低。Sr/Ca 和 Mg/Ca 比值并不随 TDS 线性增长。水化学分析表明,所研究的湖泊处于碳酸盐沉淀阶段,蒸发是控制北京九龙坡区湖泊演变的主要因素。镁/钙、锶/钙比值与 TDS 的关系主要受湖泊演化阶段和湖泊水化学类型的影响。综合前人研究,影响湖泊演化的因素、镁和锶的分配系数以及其他随湖泊演化而变化的水化学参数都会影响化学成分与盐度之间的关系。为了更准确地重建古盐度,应对湖泊的现代水化学特征以及碳酸盐元素比值与水盐度之间的关系进行更详细的研究。
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引用次数: 0
Multi-stage formation of the Feragen ophiolite, Norway: Implication from petrology and geochemistry of peridotites and chromitites and its potential for prospecting 挪威费拉根蛇绿岩的多阶段形成:橄榄岩和铬铁矿岩石学和地球化学的影响及其勘探潜力
IF 4.6 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-25 DOI: 10.31035/cg2023017
Tian Qiu , Fa-hui Xiong , David G. Gee , Yuan Li , Jing-sui Yang
The ultramafic massif of Feragen, which belongs to the eastern ophiolitic belt of Norway, has abundant amounts of chromite ores. Recent studies have revealed a complex melt evolution in a supra-subduction zone (SSZ) environment. This study presents new whole-rock major element, trace element, and platinum-group element chemistry to evaluate their petrogenesis and tectonic evolution. Harzburgites have high CaO, Al2O3, TiO2, MgO, and REE contents corresponding to abyssal peridotites, whereas dunites have low CaO, Al2O3, TiO2, MgO, and REE contents corresponding to SSZ peridotites. The Cr# and TiO2 of chromian spinels in the harzburgites suggest as much as about 15%–20% melting and the dunites are more depleted with > 40% melting. The harzburgites and the dunites and high-Cr chromitites represent, respectively, the products of low-degree partial melting in a back-arc setting, and the products of melt-rock interaction in a SSZ environment. The calculated ƒO2 values for dunites and high-Cr chromitites (−0.17 – +0.23 and +2.78 – +5.65, respectively and generally above the FMQ buffer) are also consistent with the interaction between back-arc ophiolites with oxidized boninitic melts in a SSZ setting.
属于挪威东部蛇绿岩带的费拉根超基性岩块拥有大量铬铁矿。最近的研究揭示了超俯冲带(SSZ)环境中复杂的熔融演化过程。本研究提出了新的全岩主要元素、微量元素和铂族元素化学成分,以评估其岩石成因和构造演化。哈尔茨堡岩的CaO、Al2O3、TiO2、MgO和REE含量较高,与深海橄榄岩相对应,而云英岩的CaO、Al2O3、TiO2、MgO和REE含量较低,与SSZ橄榄岩相对应。海兹堡岩中铬尖晶石的Cr#和TiO2表明熔融程度高达15%-20%,而云英岩的熔融程度为40%,贫化程度更高。海兹堡岩和云英岩以及高铬铬铁矿分别代表了弧后环境中低度部分熔融的产物和SSZ环境中熔岩与岩石相互作用的产物。计算得出的云英岩和高铬铬铁矿的 ƒO2 值(分别为 -0.17 - +0.23 和 +2.78 - +5.65,一般高于 FMQ 缓冲值)也与后弧蛇绿混杂岩与 SSZ 环境中氧化倭黑质熔体之间的相互作用相一致。
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引用次数: 0
In situ U-Pb dating and trace elements of magmatic rutile from Mujicun Cu-Mo deposit, North China Craton: Insights into porphyry mineralization 华北克拉通穆吉村铜钼矿床岩浆金红石的原位 U-Pb 定年和痕量元素:斑岩成矿的启示
IF 4.6 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-25 DOI: 10.31035/cg2023038
Fan Yang , Jing-wen Mao , Wei-dong Ren , Jia-run Tu , Gilby Jepson , Si-yuan Meng , Zhi-min Wang
Porphyry Cu (Mo-Au) deposit is one of the most important types of copper deposit and usually formed under magmatic arc-related settings, whilst the Mujicun porphyry Cu-Mo deposit in North China Craton uncommonly generated within intra-continental settings. Although previous studies have focused on the age, origin and ore genesis of the Mujicun deposit, the ore-forming age, magma source and tectonic evolution remain controversial. Here, this study targeted rutile (TiO2) in the ore-hosting diorite porphyry from the Mujicun Cu-Mo deposit to conduct in situ U-Pb dating and trace element composition studies, with major views to determine the timing and magma evolution and to provide new insights into porphyry Cu-Mo metallogeny. Rutile trace element data show flat-like REE patterns characterized by relatively enrichment LREEs and depleted HREEs, which could be identified as magmatic rutile. Rutile U-Pb dating yields lower intercept ages of 139.3–138.4 Ma, interpreted as post magmatic cooling timing below about 500°C, which are consistent or slightly postdate with the published zircon U-Pb ages of diorite porphyry (144.1–141.7 Ma) and skarn (146.2 Ma; 139.9 Ma) as well as the molybdenite Re-Os ages of molybdenum ores (144.8–140.0 Ma). Given that the overlap between the closure temperature of rutile U-Pb system and ore-forming temperature of the Mujicun deposit, this study suggests that the ore-forming ages of the Mujicun deposit can be constrained at 139.3–138.4 Ma, with temporal links to the late large-scale granitic magmatism at 138–126 Ma in the Taihang Orogen. Based on the Mg and Al contents in rutile, the magma of ore-hosting diorite porphyry was suggested to be derived from crust-mantle mixing components. In conjunction with previous studies in Taihang Orogen, this study proposes that the far-field effect and the rollback of the subducting Paleo-Pacific slab triggered lithospheric extension, asthenosphere upwelling, crust-mantle interaction and thermo-mechanical erosion, which jointly facilitated the formation of dioritic magmas during the Early Cretaceous. Subsequently, the dioritic magmas carrying crust-mantle mixing metallic materials were emplaced and precipitated at shallow positions along NNE-trending ore-controlling faults, eventually resulting in the formation of the Mujicun Cu-Mo deposit within an intracontinental extensional setting.
斑岩型铜(钼-金)矿床是最重要的铜矿床类型之一,通常形成于岩浆弧相关环境中,而华北克拉通地区的穆家村斑岩型铜-钼矿床则罕见地形成于大陆内部环境中。虽然以往的研究主要集中在穆吉村矿床的年龄、成因和矿石成因方面,但对其成矿时代、岩浆来源和构造演化仍存在争议。本研究以木吉村铜钼矿床含矿闪长岩斑岩中的金红石(TiO2)为研究对象,开展原位U-Pb定年和痕量元素组成研究,主要目的是确定成矿时代和岩浆演化,为斑岩铜钼成矿作用提供新的认识。金红石痕量元素数据显示了扁平状的 REE 模式,其特征是相对富集的 LREEs 和贫化的 HREEs,可确定为岩浆金红石。金红石 U-Pb 测定得出的截距年龄较低,为 139.3-138.4 Ma,解释为低于约 500°C 的岩浆后冷却时间,与已公布的闪长岩斑岩(144.1-141.7 Ma)和矽卡岩(146.2 Ma;139.9 Ma)的锆石 U-Pb 年龄以及钼矿石的钼矿 Re-Os 年龄(144.8-140.0 Ma)一致或略微晚于。考虑到金红石U-Pb系统的闭合温度与穆家村矿床成矿温度的重叠,本研究认为穆家村矿床的成矿年龄可推定为139.3-138.4Ma,与太行造山带晚期138-126Ma大规模花岗岩岩浆活动有时间上的联系。根据金红石中的镁和铝含量,认为含矿闪长岩斑岩的岩浆来源于地壳-地幔混合成分。结合以往在太行造山带的研究,本研究提出古太平洋板块俯冲的远场效应和滚回作用引发了岩石圈延伸、天体层上涌、地壳-地幔相互作用和热力-机械侵蚀,共同促进了早白垩世闪长岩岩浆的形成。随后,携带地壳-地幔混合金属物质的闪长岩岩浆在沿北东向控矿断层的浅部位置喷出并沉淀,最终在大陆内部延伸环境中形成了穆吉村铜钼矿床。
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引用次数: 0
Carbon neutrality: China’s energy transition over the past decade 碳中和:中国过去十年的能源转型
IF 4.6 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-10-25 DOI: 10.31035/cg2024086
Li-qiong Jia , Xi-jie Chen , Zi-guo Hao
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引用次数: 0
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China Geology
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