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Characteristics and ecological risk assessment of antibiotics and hormones in landfill waters 垃圾填埋场水体中抗生素和激素的特征及生态风险评价
IF 4.7 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-25 DOI: 10.1016/S2096-5192(25)00097-7
Yi Huang , Xuan Dong , Zhi-yuan Ma , Xi-zhao Tian , Zhu Rao
Antibiotics, as emerging pollutants, pose significant risks to aquatic ecosystems and human health by disrupting the endocrine systems of aquatic organisms and affecting ecosystem stability through food chain enrichment. In a study conducted in Hebei Province, China, liquid chromatography-triple quadrupole-linear ion trap mass spectrometry (LC-TQ-LIT-MS) was used to analyze 90 different antibiotics in 31 water samples, including surface water, groundwater, and waste leachate from three urban landfills. This analysis included hormones, broad-spectrum antimicrobials, macrolides, tetracyclines, β-lactams, sulfonamides, and quinolones. The study’s results indicated that quinolones, β-lactams, and macrolides were the most frequently detected substances in the landfills. It is noteworthy that the concentrations of these antibiotics varied significantly among different cities, reflecting local production and living characteristics. The results of the tests showed that the concentration of amoxicillin was 1171 ng/L in surface water, 811 ng/L in groundwater, and 1926 ng/L of ciprofloxacin in waste leachate. Furthermore, a consistent pattern was observed between the compounds present in the leachate, groundwater, and surface water at the three sites. Risk assessments revealed that the ecological risk was higher for surface water and lower for groundwater. This study is the first to systematically analyze the pollution status of antibiotics and hormones in the water around the landfill in Hebei Province, which not only fills the blank of groundwater-related research in Hebei Province but also provides key data support and theoretical basis for local groundwater hydrological and environmental detection and pollution prevention.
抗生素作为新兴污染物,通过扰乱水生生物的内分泌系统,通过食物链富集影响生态系统的稳定性,对水生生态系统和人类健康构成重大风险。在中国河北省进行的一项研究中,采用液相色谱-三重四极杆线性离子阱质谱(lc - tq - litt - ms)分析了31个水样中的90种不同抗生素,包括来自三个城市垃圾填埋场的地表水、地下水和垃圾渗滤液。该分析包括激素、广谱抗菌剂、大环内酯类、四环素类、β-内酰胺类、磺胺类和喹诺酮类药物。研究结果表明,喹诺酮类、β-内酰胺类和大环内酯类是垃圾填埋场中最常检测到的物质。值得注意的是,这些抗生素在不同城市的浓度差异较大,反映了当地的生产和生活特点。试验结果表明,地表水中阿莫西林浓度为1171 ng/L,地下水中为811 ng/L,垃圾渗滤液中环丙沙星浓度为1926 ng/L。此外,在三个地点的渗滤液、地下水和地表水中存在的化合物之间观察到一致的模式。风险评价结果表明,地表水生态风险较高,地下水生态风险较低。本研究首次系统分析了河北省垃圾填埋场周边水体中抗生素和激素的污染状况,不仅填补了河北省地下水相关研究的空白,也为当地地下水水文环境检测和污染防治提供了关键数据支持和理论依据。
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引用次数: 0
Evolution from Medical Geology to GeoHealth and future development prospects 从医学地质学到地球健康的演变及未来发展前景
IF 4.7 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-25 DOI: 10.1016/S2096-5192(25)00086-2
Robert B. Finkelman
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引用次数: 0
Insights into wind-driven heavy metal pollution and human health risk assessment in a typical lead-zinc mining area of northern China 中国北方典型铅锌矿区风致重金属污染及人体健康风险评价
IF 4.7 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-25 DOI: 10.1016/S2096-5192(25)00088-6
Zun-zhuang Ke , Xue Han , Ran Zhou , Yi-fei Zhang , Guan-nan Liu , Chang-qing Zhang , Zhao Liu , Xiao-sai Li , Wen-bo Li
Long-term mining activities can result in the release of heavy metals into soil, ultimately posing a threat to human health. In arid and semi-arid regions, wind-driven transport of these toxic metals from mining areas represents a primary mechanism for their spatial distribution. To evaluate pollution levels and associated health risks of eight metals, A total of 95 soil samples, corresponding 25 vegetable samples and 3 tailing samples were collected from various land types surrounding a typical Pb-Zn mine in northern China’s semi-arid region. The mean concentrations of As, Cd, Cr, Cu, Hg, Ni, Pb and Zn in soils were 62.8, 0.27, 29.6, 11.5, 0.02, 14.4, 49.9 and 109.5 mg/kg, respectively. Among these, As, Cd, Pb, and Zn emerged as the predominant pollutants, with some samples exceeding national risk screening values. The results of contamination factor (CF), pollution load index (PLI) and geo-accumulation index (Igeo) indicated that heavy metals in most soils exhibited non-polluted level or slight pollution level, though localized severe contamination by As, Cd, Pb, and Zn was observed. Spatial distribution analysis demonstrated similar dispersion patterns for As, Cd, Pb, and Zn, with wind-mediated transport extending up to 2.0 km from contamination sources. Pearson’s correlation analysis and principal component analysis (PCA) suggested that As, Cd, Pb and Zn mainly originated from mining activities, and Cr, Ni, Cu and Hg derived from soil parent materials. All vegetable samples contained metal concentrations below food safety thresholds. Health risk assessment showed hazard quotient (HQ) values for individual metals below 1 across all exposure groups, indicating negligible non-carcinogenic risk. Similarly, carcinogenic risk (CR) values for As, Cd, Cr, and Pb fell within acceptable ranges. While mining activities have induced significant localized contamination, the overall affected area remains limited in arid and semi-arid regions. However, greater attention should be directed toward potential health implications from vegetable consumption in proximity to mining operations within arid and semi-arid regions.
长期采矿活动可能导致重金属释放到土壤中,最终对人类健康构成威胁。在干旱和半干旱地区,这些有毒金属的空间分布主要是由矿区的风力运输造成的。为评价8种金属的污染水平及相关健康风险,在中国北方半干旱区某典型铅锌矿周边不同土地类型中采集了95份土壤样品、25份蔬菜样品和3份尾矿样品。土壤中As、Cd、Cr、Cu、Hg、Ni、Pb和Zn的平均浓度分别为62.8、0.27、29.6、11.5、0.02、14.4、49.9和109.5 mg/kg。其中,As、Cd、Pb、Zn是主要污染物,部分样本超过国家风险筛查值。污染因子(CF)、污染负荷指数(PLI)和土壤累积指数(Igeo)结果表明,大部分土壤重金属表现为未污染或轻度污染,但局部存在As、Cd、Pb和Zn的严重污染。砷、镉、铅和锌的空间分布分析表明,砷、镉、铅和锌具有相似的分散模式,并且风介导的迁移从污染源扩展到2.0 km。Pearson相关分析和主成分分析表明,As、Cd、Pb、Zn主要来源于采矿活动,Cr、Ni、Cu、Hg主要来源于土壤母质。所有蔬菜样本的金属含量均低于食物安全阈值。健康风险评估显示,在所有接触组中,个别金属的危害商(HQ)值均低于1,表明非致癌风险可以忽略不计。同样,砷、镉、铬和铅的致癌风险(CR)值也在可接受范围内。虽然采矿活动造成了严重的局部污染,但总的受影响地区仍然限于干旱和半干旱地区。但是,应更多地注意在干旱和半干旱地区采矿作业附近食用蔬菜可能对健康造成的影响。
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引用次数: 0
Chemical elements and human health from the perspective of “One Health” “一个健康”视域下的化学元素与人体健康
IF 4.7 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-25 DOI: 10.1016/S2096-5192(25)00098-9
Qing Wen , Li-yue Zhang , Ming-xin Liu , Wen-bing Ji , Chang Li , Tao Yu , Qi-feng Tang , Hui Lu , Qing-ye Hou , Zhong-fang Yang
Human activities are closely related to geological environments or those influenced by geological factors, which can significantly impact human health. Previous studies have predominantly focused on isolated spheres or single environmental indicators, lacking research on the multifactorial influences affecting the overall geographic environment. From the “One Health” perspective, this paper synthesizes natural environmental factors across the lithosphere, hydrosphere, atmosphere, and pedosphere, encompassing the sources, forms, concentrations, and bioavailability of chemical elements, as well as pollutants and their associations with human health. Comprehensive natural environmental factors, based on GeoHealth, are intimately connected to human health. Under the pressures of future population growth and rapid industrial development, the relationship between the global geological environment and human health will become increasingly prominent. Therefore, it is crucial to pay close attention to health-based thresholds and promptly implement pollution prevention and control measures.
人类活动与地质环境或受地质因素影响的活动密切相关,对人类健康有重大影响。以往的研究主要集中在孤立的领域或单一的环境指标上,缺乏对影响整体地理环境的多因素影响的研究。本文从“同一个健康”的角度,综合了岩石圈、水圈、大气、土壤圈的自然环境因子,包括化学元素的来源、形态、浓度、生物利用度、污染物及其与人类健康的关系。以地球健康为基础的综合自然环境因素与人类健康密切相关。在未来人口增长和工业快速发展的压力下,全球地质环境与人类健康的关系将日益突出。因此,密切关注健康阈值,及时实施污染防治措施至关重要。
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引用次数: 0
Zircon U-Pb age of the mafic microgranular enclaves in the ore-forming porphyry of the Tongchanggou Mo (Cu) deposit, northwestern Yunnan, China 滇西北铜厂沟莫(铜)矿床成矿斑岩中基性微颗粒包体锆石U-Pb年龄
IF 4.7 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-25 DOI: 10.1016/S2096-5192(25)00099-0
Shou-kui Li , Xue-long Liu , Shi-tao Zhang , Jie-hu Zhou , Bo-de Lu , Yun He
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引用次数: 0
Mechanisms behind zinc transport in a calcareous soil-wheat system and their impacts on human health 钙质土壤-小麦系统锌转运机制及其对人体健康的影响
IF 4.7 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-07-25 DOI: 10.1016/S2096-5192(25)00095-3
Su-rong Zhang , Jun-quan Yang , Da-ming Wang , Xue-sheng Gao , Ji-hong Liu , Jing Zhang , Xiao-long Duan , Jian-hua Wang , Ling-zhi Yang
Zinc is recognized as a vital biological element for animals and plants. Both zinc deficiency and excess will cause damage to cells, and zinc deficiency in the human body may lead to severe health problems. Zinc deficiency has been identified as a global nutritional issue. Wheat, one of the most significant food crops for humans, is primarily planted in potentially zinc-deficient, calcareous soils in China. It proves to be a major global challenge to increase the zinc concentration in wheat crops to boost crop yields and improve human health. This study investigated the growth process of wheat in calcareous soils with various zinc concentrations using outdoor pot experiments and systematically explored the characteristics and mechanism of zinc transport in the soil-wheat system. The results indicate that the zinc concentrations in various wheat organs decreased in the order of roots, stems, and leaves in the jointing stage and in the order of seeds, roots, and stems in the mature stage. Overall, the zinc enrichment in various wheat organs decreased in the order of seeds, roots, stems, and leaves. In the case of zinc deficiency in soils, wheat roots exhibited elevated zinc availability in the rhizosphere by secreting phytosiderophores. This enhances the zinc uptake capacity of wheat roots. In the case of sufficient zinc supply from soils, chelated zinc formed with citric acid as the chelating ligand occurred stably in soils, contributing to enhanced utilization and uptake rates of zinc, along with elevated transport and enrichment capacities of zinc inside the plants. The results indicate that the zinc concentration in wheat seeds can be somewhat enhanced by regulating the background value of bioavailable zinc concentration in soils. A moderate zinc concentration gradient of 1.0 mg/kg is unfavorable for zinc accumulation in wheat seeds, while a high zinc concentration gradient of 6.0 mg/kg corresponds to the highest degree of zinc enrichment in wheat seeds. This study holds critical scientific significance for enhancing the zinc supply capacity of soils, increasing the zinc concentrations in wheat seeds, and, accordingly, addressing zinc deficiency in the human body. Additionally, this study offers a mechanistic reference and basis for research on the interplay between soils, plants, and human health.
锌被认为是动物和植物的重要生物元素。锌缺乏和过量都会对细胞造成损害,人体缺锌可能会导致严重的健康问题。锌缺乏已被确定为一个全球性的营养问题。小麦是人类最重要的粮食作物之一,在中国主要种植在可能缺乏锌的钙质土壤中。事实证明,提高小麦作物中的锌浓度以提高作物产量和改善人类健康是一项重大的全球挑战。本研究通过室外盆栽试验,研究了小麦在不同锌浓度钙质土壤中的生长过程,系统探讨了锌在土壤-小麦系统中的运移特征和机理。结果表明:拔节期小麦各器官锌含量依次为根、茎、叶,成熟期小麦各器官锌含量依次为种子、根、茎。锌在小麦各器官中的富集程度依次为种子、根、茎、叶。在土壤缺锌的情况下,小麦根系通过分泌植物铁载体来提高根际锌的有效性。这增强了小麦根系对锌的吸收能力。在土壤锌供应充足的情况下,以柠檬酸为螯合配体形成的螯合锌在土壤中稳定发生,有助于提高锌的利用和吸收率,同时提高锌在植物体内的运输和富集能力。结果表明,调节土壤生物有效锌浓度背景值可在一定程度上提高小麦种子中锌的含量。中等锌浓度梯度为1.0 mg/kg不利于小麦种子锌的富集,而高锌浓度梯度为6.0 mg/kg时,小麦种子锌富集程度最高。该研究对增强土壤供锌能力,提高小麦种子中锌的浓度,进而解决人体锌缺乏问题具有重要的科学意义。此外,该研究为土壤、植物与人体健康相互作用的研究提供了机制参考和基础。
{"title":"Mechanisms behind zinc transport in a calcareous soil-wheat system and their impacts on human health","authors":"Su-rong Zhang ,&nbsp;Jun-quan Yang ,&nbsp;Da-ming Wang ,&nbsp;Xue-sheng Gao ,&nbsp;Ji-hong Liu ,&nbsp;Jing Zhang ,&nbsp;Xiao-long Duan ,&nbsp;Jian-hua Wang ,&nbsp;Ling-zhi Yang","doi":"10.1016/S2096-5192(25)00095-3","DOIUrl":"10.1016/S2096-5192(25)00095-3","url":null,"abstract":"<div><div>Zinc is recognized as a vital biological element for animals and plants. Both zinc deficiency and excess will cause damage to cells, and zinc deficiency in the human body may lead to severe health problems. Zinc deficiency has been identified as a global nutritional issue. Wheat, one of the most significant food crops for humans, is primarily planted in potentially zinc-deficient, calcareous soils in China. It proves to be a major global challenge to increase the zinc concentration in wheat crops to boost crop yields and improve human health. This study investigated the growth process of wheat in calcareous soils with various zinc concentrations using outdoor pot experiments and systematically explored the characteristics and mechanism of zinc transport in the soil-wheat system. The results indicate that the zinc concentrations in various wheat organs decreased in the order of roots, stems, and leaves in the jointing stage and in the order of seeds, roots, and stems in the mature stage. Overall, the zinc enrichment in various wheat organs decreased in the order of seeds, roots, stems, and leaves. In the case of zinc deficiency in soils, wheat roots exhibited elevated zinc availability in the rhizosphere by secreting phytosiderophores. This enhances the zinc uptake capacity of wheat roots. In the case of sufficient zinc supply from soils, chelated zinc formed with citric acid as the chelating ligand occurred stably in soils, contributing to enhanced utilization and uptake rates of zinc, along with elevated transport and enrichment capacities of zinc inside the plants. The results indicate that the zinc concentration in wheat seeds can be somewhat enhanced by regulating the background value of bioavailable zinc concentration in soils. A moderate zinc concentration gradient of 1.0 mg/kg is unfavorable for zinc accumulation in wheat seeds, while a high zinc concentration gradient of 6.0 mg/kg corresponds to the highest degree of zinc enrichment in wheat seeds. This study holds critical scientific significance for enhancing the zinc supply capacity of soils, increasing the zinc concentrations in wheat seeds, and, accordingly, addressing zinc deficiency in the human body. Additionally, this study offers a mechanistic reference and basis for research on the interplay between soils, plants, and human health.</div></div>","PeriodicalId":45329,"journal":{"name":"China Geology","volume":"8 3","pages":"Pages 573-585"},"PeriodicalIF":4.7,"publicationDate":"2025-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144757056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Timing, geometry, and kinematics of the Yilan-Yitong fault zone in the Northern Tan-Lu fault system of Northeast Asia 东北亚郯庐北断系宜兰-伊通断裂带的时间、几何和运动学
IF 4.6 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-04-25 DOI: 10.31035/cg20230060
Liang Qiu , Yu Fu , Dan-Ping Yan , Tian-heng Wang , Wei Gan , Cheng-ming Li , Ruo-yan Kong , Rong Chu , Xiao-yu Chen , Rui Zhang , Shou-heng Sun , Xiao-yu Dong
The largest Tan-Lu active fault system in northeastern Asia, spans approximately 3500 km in length and varies in width from 10 km to 200 km. In 1668, an earthquake with a magnitude of 8.5 occurred in Tancheng, causing the loss of over 50000 lives. To constrain the timing and process of the Tan-Lu fault system on eastern Asian margin, this study presents the field mapping, thin section observation, geochronology, and microanalysis of Weiyuanpu-Yehe ductile shear zone (WYSZ) of the northern Tan-Lu fault system. Kinematic indicators and microstructures suggest a sense of sinistral strike-slip. The deformation temperature of the mylonite is mediate to high based on the quartz deformation, c-axis fabrics. The differential stress of the shear zone is 20‒40 MPa using quartz paleopiezometry. The dikes within the shear zone yielded zircon U-Pb ages of 165‒163 Ma. However, due to the ambiguous geological relationship between the dikes and shear zone, additional geochronology is warranted. Since the Mesozoic era, based on the exposure of mylonite and dikes, the upper crust has been extensively eroded, exposing the ductile shear zone. Moreover, the understanding of the geometry and process of pre-existing structures has fundamental implications for predicating the potential earthquakes for the Tan-Lu fault system.
东北亚最大的郯庐活动断裂系统,长约3500公里,宽10公里至200公里不等。1668年,郯城发生8.5级地震,造成5万多人死亡。为了约束东亚边缘郯庐断裂系统的时间和过程,本文对郯庐断裂系统北部的威源堡—叶河韧性剪切带(WYSZ)进行了野外填图、薄片观测、年代学和微观分析。运动学指标和显微结构显示左旋走滑。根据石英变形的c轴结构,糜棱岩的变形温度为中至高。石英古层压测量显示剪切带的差应力为20 ~ 40 MPa。剪切带内岩脉的锆石U-Pb年龄为165 ~ 163 Ma。然而,由于岩脉与剪切带之间的地质关系不明确,需要进行额外的地质年代学研究。中生代以来,基于糜棱岩和岩脉的暴露,上地壳被广泛侵蚀,暴露出韧性剪切带。此外,了解已有构造的几何形状和过程对预测郯庐断裂系统的潜在地震具有重要意义。
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引用次数: 0
Distribution and role of fluorine in the aquatic ecosystem (mineral springs, groundwater, tributaries, Baikal water, and the Angara water source) of Lake Baikal, Russia 氟在俄罗斯贝加尔湖水生生态系统(矿泉、地下水、支流、贝加尔湖水和安加拉水源)中的分布和作用
IF 4.6 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-04-25 DOI: 10.31035/cg20230100
Valentina Grebenshchikova , Mikhail Kuzmin , Anna Novopashina , Elena Kuz'mina
Several conjugate components represent the aquatic ecosystem of Lake Baikal: Baikal water (surface and deep water), groundwater from boreholes, water of numerous Baikal tributaries, cold and hot mineral springs around Lake Baikal, and the Angara River, the only runoff reflecting all this aquatic diversity. River waters in the Baikal region are known to be deficient in some vital elements, including fluorine. This article discusses the features of the fluorine distribution in the water from the conjugate components of the Baikal ecosystem. Fluorine ion concentrations in the water of the Baikal ecosystem was determined using the potentiometric method. The study represents the monitoring that was carried out between 1997 and 2022 years. We determine likely causes of high and low fluorine concentrations in the water from different components, propose and substantiate the fluorine sources, geological and geochemical model of its influx and distribution features in the water of the Baikal ecosystem.
贝加尔湖的水生生态系统由几个组成部分组成:贝加尔湖水(地表水和深水)、钻孔地下水、众多贝加尔湖支流的水、贝加尔湖周围的冷热矿泉和安加拉河,这是唯一反映所有这些水生多样性的径流。众所周知,贝加尔湖地区的河水缺乏一些重要元素,包括氟。本文从贝加尔湖生态系统的共轭组分出发,讨论了水体中氟的分布特征。采用电位法测定了贝加尔湖生态系统水体中的氟离子浓度。该研究代表了1997年至2022年间进行的监测。我们从不同成分确定了水中氟浓度高和低的可能原因,提出并证实了贝加尔湖生态系统中氟的来源、流入的地质和地球化学模型及其分布特征。
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引用次数: 0
Geology, mineralization and model of the giant Maoping carbonate-hosted Pb-Zn deposit (5 Mt), South China 华南茂坪碳酸盐岩铅锌矿床(5 Mt)地质、成矿作用及模式
IF 4.6 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-04-25 DOI: 10.31035/cg2024142
Ye He , Bang-Tao Sun , Hai-Peng Wang , Jia-Xi Zhou , Yan-Jun Li , Foteini Drakou , Kai Luo , Saleh Ibrahim Bute
The giant Upper Yangtze Pb-Zn metallogenic province, also known as the Sichuan-Yunnan-Guizhou (SYG) Pb-Zn province hosting >500 carbonate-hosted epigenetic Pb-Zn deposits that contain >20 Mt Pb + Zn base metal reserves. The giant Maoping Pb-Zn deposit is the second largest deposit in this province and owns >5 Mt Pb + Zn metal reserves with ore grades of 12 wt.%-30 wt.% Pb + Zn. Such large tonnages and high grades make it among the top 100 similar mineral deposits in the world. The ore bodies are predominantly located within the strata of the Upper Devonian (Zaige Formation) and Lower (Baizuo Formation)-Upper (Weining Formation) Carboniferous. The principal ore minerals consist of galena (Gn), sphalerite (Sp), and pyrite (Py), while the primary gangue minerals include dolomite (Dol), calcite (Cal), and quartz (Qtz). Three mineralization stages of carbonate minerals have been identified: (1) pre-sulfide stage 1, (2) syn-sulfide stage 2, and (3) post-sulfide stage 3. Trace elements and C-O-Sr isotopes of three stages’ carbonate minerals, together with S-Pb isotopes of sulfides, revealing that the metamorphic basement rocks played the role of the metal source during the early stage of Pb-Zn mineralization, whereas the metal contribution of the sedimentary wall rocks found to be more prominent during the late stage of Pb-Zn mineralization. In addition, the dissolution of marine carbonate rocks and CO2 degassing may have also played an important role in the formation of the Maoping deposit. Furthermore, syn-sulfide stage 2 calcite has a U-Pb age of 214 ± 20 Ma obtained by LA-ICPMS in-situ analyses, suggesting that the hydrothermal mineralization occurred during the Triassic. Our study proposes a new coupled metallogenic model of fluid-structure-lithology assemblage and provides new insights about the formation and evolution of the Maoping deposit with significant implication for understanding and exploration of similar Pb-Zn deposits worldwide.
巨大的上扬子铅锌矿成矿省,又称川云贵铅锌矿省,拥有500个碳酸盐岩型表生铅锌矿床,含Pb + Zn贱金属储量达20mt。毛坪大型铅锌矿床是我省第二大铅锌矿床,拥有铅锌矿储量500万吨,矿石品位为12.2% ~ 30.0%。吨位之大、品位之高,使其跻身世界同类矿床百强之列。矿体主要分布在上泥盆统(再格组)和下(百左组)-上(威宁组)石炭统地层内。矿石主要矿物为方铅矿(Gn)、闪锌矿(Sp)、黄铁矿(Py),脉石主要矿物为白云石(Dol)、方解石(Cal)、石英(Qtz)。确定了碳酸盐矿物的三个成矿阶段:(1)前硫化物阶段1,(2)同硫化物阶段2,(3)后硫化物阶段3。3期碳酸盐矿物微量元素、C-O-Sr同位素及硫化物S-Pb同位素表明,变质基底岩在铅锌成矿早期起金属源作用,而沉积围岩的金属贡献在铅锌成矿晚期更为突出。此外,海相碳酸盐岩的溶蚀作用和CO2脱气作用也可能对毛坪矿床的形成起了重要作用。同时,LA-ICPMS原位分析显示,同硫化物2期方解石的U-Pb年龄为214±20 Ma,表明其热液成矿作用发生在三叠纪。本研究提出了一种新的流体—构造—岩性组合耦合成矿模式,为毛坪矿床的形成演化提供了新的认识,对全球同类铅锌矿的认识和勘探具有重要意义。
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引用次数: 0
LA-ICP-MS zircon U-Pb dating of dacite in the Sangthong Au mining area, Luang Prabang-Loei metallogenetic belt, SW Laos 老挝琅勃拉邦-洛伊成矿带Sangthong Au矿区英安岩LA-ICP-MS锆石U-Pb定年
IF 4.6 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-04-25 DOI: 10.31035/cg20240051
Lin-nan Guo , Zhen-wen Liao , Chun-mei Huang , Yong-fei Yang , Bin Zhang , Si-wei Xu , Hui-min Liang , Xiang-ting Zeng
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引用次数: 0
期刊
China Geology
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