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Pollution source identification methods and remediation technologies of groundwater: A review 地下水污染源识别方法和修复技术:综述
IF 4.5 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-01-01 DOI: 10.31035/cg2022080
Ya-ci Liu , Yu-hong Fei , Ya-song Li , Xi-lin Bao , Peng-wei Zhang

Groundwater is an important source of drinking water. Groundwater pollution severely endangers drinking water safety and sustainable social development. In the case of groundwater pollution, the top priority is to identify pollution sources, and accurate information on pollution sources is the premise of efficient remediation. Then, an appropriate pollution remediation scheme should be developed according to information on pollution sources, site conditions, and economic costs. The methods for identifying pollution sources mainly include geophysical exploration, geochemistry, isotopic tracing, and numerical modeling. Among these identification methods, only the numerical modeling can recognize various information on pollution sources, while other methods can only identify a certain aspect of pollution sources. The remediation technologies of groundwater can be divided into in-situ and ex-situ remediation technologies according to the remediation location. The in-situ remediation technologies enjoy low costs and a wide remediation range, but their remediation performance is prone to be affected by environmental conditions and cause secondary pollution. The ex-situ remediation technologies boast high remediation efficiency, high processing capacity, and high treatment concentration but suffer high costs. Different methods for pollution source identification and remediation technologies are applicable to different conditions. To achieve the expected identification and remediation results, it is feasible to combine several methods and technologies according to the actual hydrogeological conditions of contaminated sites and the nature of pollutants. Additionally, detailed knowledge about the hydrogeological conditions and stratigraphic structure of the contaminated site is the basis of all work regardless of the adopted identification methods or remediation technologies.

©2024 China Geology Editorial Office.

地下水是重要的饮用水源。地下水污染严重危及饮用水安全和社会可持续发展。对于地下水污染,当务之急是查明污染源,准确的污染源信息是有效治理的前提。然后,根据污染源信息、现场条件和经济成本,制定合适的污染修复方案。确定污染源的方法主要包括地球物理勘探、地球化学、同位素追踪和数值模拟。在这些识别方法中,只有数值模型可以识别污染源的各种信息,而其他方法只能识别污染源的某一方面。地下水修复技术按修复地点可分为原位修复技术和非原位修复技术。原位修复技术成本低、修复范围广,但修复效果易受环境条件影响,造成二次污染。异地修复技术修复效率高、处理能力强、处理浓度高,但成本高。不同的污染源识别方法和修复技术适用于不同的条件。为了达到预期的识别和修复效果,可以根据污染场地的实际水文地质条件和污染物的性质,将多种方法和技术结合起来。此外,无论采用何种识别方法或修复技术,详细了解污染场地的水文地质条件和地层结构是一切工作的基础。
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引用次数: 0
The morphology and histology of a juvenile Sinokannemeyeria from the Middle Triassic Ermaying Formation of Shanxi, North China 华北山西二马营地层中三叠世Sinokannemeyeria幼体的形态和组织学研究
IF 4.5 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-10-01 DOI: 10.31035/cg2023030
Li-juan Xie , Jian Yi , Jian-ru Shi , Zhi-shuai Kang , Shi-chao Xu , Run-fu Wang

Kannemeyeriiformes were dominated tetrapods in the Middle Triassic terrestrial faunae of China. Although abundant materials of Sinokannemeyeria have been collected, their postcranial morphology information is not well studied, especially the juveniles. This paper presents a description of an articulated Sinokannemeyeria skeleton from the Middle Triassic Ermaying Formation and reports the histological microstructure of its femur. This specimen represents a late-stage juvenile based on the histological information. For the first time, this specimen offers insights into the postcrania information of juvenile Sinokannemeyeria.

©2023 China Geology Editorial Office.

在中国中三叠世的陆生动物群中,四足类中以坎尼梅里亚目(Kannemeyeriiformes)为主。虽然已收集到丰富的卡尼美耶亚类的材料,但对其颅骨后的形态信息,尤其是幼体的研究并不深入。本文描述了中三叠世二马营地层中的一具有关节的Sinokannemeyeria骨架,并报告了其股骨的组织学显微结构。根据组织学信息,该标本为晚期幼体。该标本首次揭示了Sinokannemeyeria幼体的颅后信息。
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引用次数: 0
Second Editorial Committee of China Geology 中国地质》第二届编辑委员会
IF 4.5 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-10-01 DOI: 10.31035/S2096-5192(23)01508-2
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引用次数: 0
Melt extraction and mineralization: A case study from the Shuangjianzishan supergiant Ag-Pb-Zn deposit (208 Mt), Inner Mongolia, NE China 熔融萃取与成矿作用:中国东北内蒙古双尖子山超大型银铅锌矿床(208 Mt)案例研究
IF 4.5 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-10-01 DOI: 10.31035/cg2022044
Meng Dai , Guang-sheng Yan , Yong-sheng Li , Wen-bin Jia , Fan-yu Qi , Xing Ju

The supergiant Shuangjianzishan (SJZ) Ag-Pb-Zn deposit is in the southern segment of the Great Hinggan Range (SGHR), northeast China. Previous studies suggest the ore-forming material and fluid originated from the magmatic system, and the mineralization age was consistent with the diagenetic age. However, the relationship between granitic magmatism and mineralization is still unclear in the SJZ. In this study, C-H-O-He-Ar and in-situ S-Pb isotope analyses were conducted to determine the sources of ore-forming fluids and metals, which were combined with geochemistry data of SJZ granitoids from previous studies to constrain the relationship between the magmatism and the mineralization. The C-H-O-He-Ar-S-Pb isotopic compositions suggested the SJZ ore-forming material and fluids were derived from a magmatic source, which has mixed a small amount of mantle-derived materials. In addition, the disseminated sulfide from the syenogranite has comparable S-Pb isotopic composition with the sulfide minerals from ore veins, suggesting that the generation of the SJZ ore-forming fluids has a close relationship with the syenogranite magmatism. Combining with the geochemical characters of the syenogranite, the authors proposed that the mantle-derived fingerprint of the SJZ ore-forming fluid might be caused by the parent magma of the syenogranite, which was derived from partial melting of the juvenile lower crust, and underwent the residual melts segregated from a crystal mush in the shallow magma reservoir. The extraction of the syenogranite parent magma further concentrated the fertilized fluids, which was crucial to mineralization of the SJZ Ag-Pb-Zn deposit.

©2023 China Geology Editorial Office.

超大型双尖子山银铅锌矿床位于中国东北大兴安岭南段。以往的研究表明,成矿物质和流体来源于岩浆系统,成矿时代与成岩时代一致。然而,上海金东区花岗岩岩浆与成矿之间的关系尚不清楚。本研究开展了C-H-O-He-Ar和原位S-Pb同位素分析,以确定成矿流体和金属的来源,并结合以往研究中SJZ花岗岩的地球化学数据,对岩浆与成矿之间的关系进行了约束。C-H-O-He-Ar-S-Pb同位素组成表明,SJZ的成矿物质和流体来自岩浆源,其中混合了少量地幔源物质。此外,正长岩中的浸染状硫化物与矿脉中的硫化物矿物具有相似的S-Pb同位素组成,表明SJZ成矿流体的生成与正长岩岩浆作用有着密切的关系。结合正长花岗岩的地球化学特征,作者提出,SJZ成矿流体的地幔源性指纹可能是由正长花岗岩的母岩浆引起的,它来源于幼年下地壳的部分熔融,并经历了浅部岩浆储层中晶泥分离出的残余熔体。正长岩母岩的提取进一步浓缩了肥沃流体,这对SJZ银铅锌矿床的成矿至关重要。
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引用次数: 0
Classification and mineralization of global lithium deposits and lithium extraction technologies for exogenetic lithium deposits 全球锂矿床的分类和矿化以及外生锂矿床的提锂技术
IF 4.5 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-10-01 DOI: 10.31035/cg2023061
Mian-ping Zheng , En-yuan Xing , Xue-fei Zhang , Ming-ming Li , Dong Che , Ling-zhong Bu , Jia-huan Han , Chuan-yong Ye

A reasonable classification of deposits holds great significance for identifying prospecting targets and deploying exploration. The world’s keen demand for lithium resources has expedited the discovery of numerous novel lithium resources. Given the presence of varied classification criteria for lithium resources presently, this study further ascertained and classified the lithium resources according to their occurrence modes, obtaining 10 types and 5 subtypes of lithium deposits (resources) based on endogenetic and exogenetic factors. As indicated by surveys of Cenozoic exogenetic lithium deposits in China and abroad, the formation and distribution of the deposits are primarily determined by plate collision zones, their primary material sources are linked to the anatectic magmas in the deep oceanic crust, and they were formed primarily during the Miocene and Late Paleogene. The researchers ascertained that these deposits, especially those of the salt lake, geothermal, and volcanic deposit types, are formed by unique slightly acidic magmas, tend to migrate and accumulate toward low-lying areas, and display supernormal enrichment. However, the material sources of lithium deposits (resources) of the Neopaleozoic clay subtype and the deep brine type are yet to be further identified. Given the various types and complex origins of lithium deposits (resources), which were formed due to the interactions of multiple spheres, it is recommended that the mineralization of exogenetic lithium deposits (resources) be investigated by integrating tectono-geochemistry, paleoatmospheric circulation, and salinology. So far, industrialized lithium extraction is primarily achieved in lithium deposits of the salt lake, clay, and hard rock types. The lithium extraction employs different processes, with lithium extraction from salt lake-type lithium deposits proving the most energy-saving and cost-effective.

©2023 China Geology Editorial Office.

对矿床进行合理分类对确定勘探目标和部署勘探工作具有重要意义。全球对锂资源的殷切需求加速了众多新型锂资源的发现。鉴于目前对锂资源的分类标准不一,本研究根据锂资源的成矿模式,对锂资源进行了进一步的确认和分类,得到了基于内生和外生因素的10种类型和5个亚型的锂矿床(资源)。国内外新生代外生锂矿床调查表明,这些矿床的形成和分布主要由板块碰撞带决定,其主要物质来源与深海地壳中的无生界岩浆有关,主要形成于中新世和晚古新世。研究人员确定,这些矿床,尤其是盐湖、地热和火山矿床类型的矿床,是由独特的微酸性岩浆形成的,倾向于向低洼地区迁移和堆积,并显示出超常富集。然而,新古生代粘土亚型和深层卤水型锂矿床(资源)的物质来源还有待进一步确定。鉴于锂矿床(资源)的类型多样、成因复杂,是由多个球体相互作用形成的,建议综合构造地球化学、古大气环流和盐碱学等研究外生锂矿床(资源)的成矿作用。迄今为止,工业化提锂主要是在盐湖、粘土和硬岩类型的锂矿床中实现的。锂的提取采用了不同的工艺,其中从盐湖型锂矿床中提取锂最为节能和经济。
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引用次数: 0
Heavy metal pollution assessment in marine sediments in the Northwest coast of Sabah, Malaysia 马来西亚沙巴州西北海岸海洋沉积物中的重金属污染评估
IF 4.5 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-10-01 DOI: 10.31035/cg2022079
Sin-Yi Ling , Asis Junaidi , Abdullah Mohd-Harun , Musta Baba

Heavy metal contents along the Northwest coast of Sabah were determined to interpret the pollution level in the marine sediment. The metal abundance is regulated by the physico-chemical properties such as the average sediment pH (7.82, 9.00 and 8.99), organic matter (0.62%, 1.60%, and 2.27%), moisture content (25.00%, 29.70%, and 15.00%) and sandy texture in Kota Belud, Kudat and Mantanani Island, respectively. The major elements show Ca>Fe>Mg>Al>Mn for all study sites, while the heavy metals show Ni>Cr>Zn>Cu>Co>Pb, Cr>Ni>Zn>Cu>Pb>Co and Zn>Pb>Cr>Ni, for Kota Belud, Kudat and Mantanani Island, respectively. The pollution degree of heavy metals was evaluated by using the Sediment Quality Assessment (SQA). The SQA parameters indicated none to moderate pollution in Kota Belud that shows Class 0, Class 1 and Class 2 pollution. The parameters also indicated none to low pollution in Kudat and Mantanani Island that show only Class 0 pollution. The enrichment factor (EF) suggested minor to moderately severe metal enrichment by anthropogenic sources in Kota Belud, whereas only minor enrichment in Kudat and Mantanani Island. The modified pollution degree (MCD<1.5) and pollution load index (0 ⩽ PLI<1) indicating only low pollution level in the marine sediments for all study sites. The objectives of this study are: (1) to determine the physico-chemical parameters of sediments, (2) interpret the heavy metal contents and (3) evaluate the sediment quality.

©2023 China Geology Editorial Office.

对沙巴州西北海岸的重金属含量进行了测定,以解释海洋沉积物的污染程度。在哥打伯鲁、古达和曼塔纳尼岛,金属含量分别受平均沉积物 pH 值(7.82、9.00 和 8.99)、有机物(0.62%、1.60% 和 2.27%)、含水量(25.00%、29.70% 和 15.00%)和砂质地等物理化学特性的影响。所有研究地点的主要元素均为 Ca>Fe>Mg>Al>Mn,而哥打白鲁德、古达和曼塔纳尼岛的重金属分别为 Ni>Cr>Zn>Cu>Co>Pb、Cr>Ni>Zn>Cu>Pb>Co 和 Zn>Pb>Cr>Ni。重金属污染程度通过沉积物质量评估(SQA)进行评估。SQA 参数显示哥打白鲁德没有污染到中度污染,污染等级为 0 级、1 级和 2 级。这些参数还显示,古达和曼塔纳尼岛没有污染,污染程度较低,仅为 0 级污染。富集因子 (EF) 表明,哥打白鲁德的人为来源造成了轻度到中度严重的金属富集,而库达和曼塔纳尼岛则只有轻度富集。修正污染度(MCD<1.5)和污染负荷指数(0 ⩽ PLI<1)表明,所有研究地点的海洋沉积物均处于低污染水平。本研究的目标是(1)测定沉积物的物理化学参数;(2)解释重金属含量;(3)评价沉积物质量。
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引用次数: 1
Sources, distribution, behavior, and detection techniques of microplastics in soil: A review 土壤中微塑料的来源、分布、行为和检测技术:综述
IF 4.5 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-10-01 DOI: 10.31035/cg2023042
Yu-chen Yan , Zhong-fang Yang

In recent years, the problem of environmental pollution caused by microplastics has attracted widespread attention. This paper reviews the latest research progress in terms of the source, content and distribution characteristics, harm, and detection technology of soil microplastics by referring to the relevant literature on soil microplastics worldwide. It concludes that: (1) Existing studies worldwide have detected the presence of microplastics in soil, water, and atmosphere, and the use of agricultural films, sewage sludge, and other man-made activities are the main sources of microplastics in soil; (2) microplastics can adsorb heavy metals, persistent organic pollutants and antibiotics in soil, change the physical and chemical properties of soil. This will result in composite pollution and harm to the ecosystem; (3) microplastics in soil not only can destroy the activity of key soil microorganisms, but also enter the body of crops and soil animals, affecting normal growth of crops and soil animals, and further threaten human health; (4) at present, there is no unified operating standard for the sampling, processing, and detection process of microplastics. Analysis methods such as visual inspection, spectroscopy, and thermal analysis have both advantages and disadvantages, and emerging detection technologies require urgent development. Microplastics have become a new pollutant in soil and their distribution characteristics are closely related to human activities. They pollute the environment and threaten human health through the food chain. Although related research on soil microplastics has just begun, it will become the focus of research in the future.

©2023 China Geology Editorial Office.

近年来,微塑料造成的环境污染问题引起了人们的广泛关注。本文参考了世界范围内有关土壤微塑料的相关文献,从土壤微塑料的来源、含量和分布特征、危害、检测技术等方面综述了最新的研究进展。结论如下(1)现有的世界范围内的研究已经检测到土壤、水和大气中存在微塑料,农膜的使用、污水污泥和其他人为活动是土壤中微塑料的主要来源;(2)微塑料可以吸附土壤中的重金属、持久性有机污染物和抗生素,改变土壤的物理和化学性质。这将造成复合污染,危害生态系统;(3)土壤中的微塑料不仅会破坏土壤关键微生物的活性,还会进入农作物和土壤动物体内,影响农作物和土壤动物的正常生长,进一步威胁人类健康;(4)目前,微塑料的采样、处理和检测过程还没有统一的操作标准。目测、光谱、热分析等分析方法各有利弊,新兴检测技术亟待开发。微塑料已成为土壤中新的污染物,其分布特征与人类活动密切相关。它们通过食物链污染环境,威胁人类健康。虽然土壤微塑料的相关研究刚刚起步,但它将成为未来研究的重点。
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引用次数: 0
Discovery of bauxite-type helium source rock in Jinzhong basin, central North China and its resource potential evaluation 华北中部晋中盆地铝土矿型氦源岩的发现及其资源潜力评价
IF 4.5 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-10-01 DOI: 10.31035/cg2023037
Qiao Zhang , Jun-lin Zhou , Yu-hong Li , Ya-zhuo Niu , Wang Guo , Shang-wei Ma , Yun-peng Zhang , Shao-hua Hu , Yu Ding
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引用次数: 0
Carbon emission reduction: Contribution of karst carbon sinks and practice in China 碳减排:中国岩溶碳汇的贡献与实践
IF 4.5 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-10-01 DOI: 10.31035/cg2023050
Liang Wang , Dong-hui Wang , Qiong Xiao
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引用次数: 0
Health risk assessment of heavy metals in soils and crops in a mining area (Au-Ag-Cu-trona-oil et al.) of the Nanyang Basin, Henan Province, China 中国河南省南阳盆地一矿区(金银铜油等)土壤和农作物中重金属的健康风险评估
IF 4.5 3区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2023-10-01 DOI: 10.31035/cg2022078
Qiu-yao Dong , Hao-tian Wen , Pan Wang , Chao Song , Shu-ya Lai , Zhen-jing Yang , Yuan-yi Zhao , Ming-jiang Yan

Heavy metal distribution in mining areas has always been a hot research topic due to the special environment of these areas. This study aims to explore the impact of heavy metal pollution on soils and crops in the study area, ensure the safety of local crops and the health of local residents, and provide a basis for the subsequent environmental restoration and the prevention and control of environmental pollution. Based on the analysis of the heavy metal concentrations in local soils and crops, the study investigated the spatial distribution, pollution degrees, and potential ecological risks of heavy metals in the farmland of a mining area in the southeastern Nanyang Basin, Henan province, China explored the sources of heavy metals and assessed the health risks caused by crop intake. The results of this study are as follows. The root soils of crops in the study area suffered heavy metal pollution to varying degrees. The degree of heavy metal pollution in maize fields is higher than that in wheat fields, and both types of fields suffer the most severe Cd pollution. Moreover, the root soils of different crops suffer compound pollution. The root soils in the maize fields suffer severe compound pollution at some sampling positions, whose distribution is similar to that of the mining area. Cd poses the highest potential ecological risks among all heavy metals, and the study area mainly suffers low and moderate comprehensive potential ecological risks. The principal component analysis (PCA) shows that the distribution of Zn, Cd, Pb, and As in soils of the study area is mainly affected by anthropogenic factors such as local mining activities; the distribution of Cr and Ni is primarily controlled by the local geological background; the distribution of Hg is mainly affected by local vehicle exhaust emissions, and the distribution of Cu is influenced by both human activities and the geological background. Different cereal crops in the study area are polluted with heavy metals dominated by Cd and Ni to varying degrees, especially wheat. As indicated by the health risk assessment results, the intake of maize in the study area does not pose significant human health risks; however, Cu has high risks to human health, and the compound heavy metal pollution caused by the intake of wheat in the study area poses risks to the health of both adults and children. Overall, the soils and crops in the study area suffer a high degree of heavy metal pollution, for which mining activities may be the main reason.

©2023 China Geology Editorial Office.

由于矿区环境的特殊性,矿区重金属分布一直是研究的热点。本研究旨在探讨重金属污染对研究区土壤和农作物的影响,保障当地农作物的安全和当地居民的健康,为后续环境修复和环境污染防治提供依据。本研究在分析当地土壤和农作物中重金属浓度的基础上,调查了河南省南阳盆地东南部某矿区农田中重金属的空间分布、污染程度和潜在生态风险,探索了重金属的来源,评估了农作物摄入重金属对健康造成的风险。研究结果如下。研究区农作物根系土壤受到不同程度的重金属污染。玉米田的重金属污染程度高于小麦田,而这两类田地的镉污染最为严重。此外,不同作物的根系土壤也受到复合污染。玉米田的根系土壤在部分采样位置受到严重的复合污染,其分布情况与矿区相似。在所有重金属中,镉的潜在生态风险最高,研究区主要遭受低度和中度的综合潜在生态风险。主成分分析表明,研究区土壤中 Zn、Cd、Pb 和 As 的分布主要受当地采矿活动等人为因素的影响,Cr 和 Ni 的分布主要受当地地质背景的控制,Hg 的分布主要受当地汽车尾气排放的影响,Cu 的分布受人类活动和地质背景的双重影响。研究区内不同的谷类作物都受到不同程度的重金属污染,其中以镉和镍为主,尤其是小麦。健康风险评估结果表明,研究区玉米的摄入量不会对人体健康造成重大风险;但铜对人体健康的风险较高,研究区小麦的摄入量造成的复合重金属污染对成人和儿童的健康都有风险。总体而言,研究区的土壤和农作物受到了严重的重金属污染,采矿活动可能是主要原因。
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引用次数: 0
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