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Operando Photoelectron Photoion Coincidence Spectroscopy to Detect Short-lived Intermediates in Catalysis. Operando光电子-光子符合光谱法检测催化过程中的短寿命中间体。
IF 1.2 2区 社会学 Q1 Social Sciences Pub Date : 2023-03-29 DOI: 10.2533/chimia.2023.132
Zihao Zhang, Javier Pérez-Ramírez, Jeroen A Van Bokhoven, Andras Bodi, Patrick Hemberger

Understanding the reaction mechanism is critical yet challenging in heterogeneous catalysis. Reactive intermediates, e.g., radicals and ketenes, are short-lived and often evade detection. In this review, we summarize recent developments with operando photoelectron photoion coincidence (PEPICO) spectroscopy as a versatile tool capable of detecting elusive intermediates. PEPICO combines the advantages of mass spectrometry and the isomer-selectivity of threshold photoelectron spectroscopy. Recent applications of PEPICO in understanding catalyst synthesis and catalytic reaction mechanisms involving gaseous and surface-confined radical and ketene chemistry will be summarized.

在非均相催化中,了解反应机理是一个关键而又具有挑战性的问题。活性中间体,如自由基和烯酮,寿命很短,经常逃避检测。在这篇综述中,我们总结了operando光电子-光子离子重合(PEPICO)光谱作为一种能够检测难以捉摸的中间体的多功能工具的最新进展。PEPICO结合了质谱的优点和阈值光电子能谱的异构体选择性。综述了近年来PEPICO在理解催化剂合成和催化反应机理方面的应用,包括气体和表面限制自由基和烯酮化学。
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引用次数: 1
Who Uses the Social Safety Net? Trends in Public Benefit Use among American Households with Children, 1980-2020. 谁在使用社会安全网?1980-2020 年有子女美国家庭使用公共福利的趋势》。
IF 2.8 2区 社会学 Q1 Social Sciences Pub Date : 2023-03-01 Epub Date: 2023-12-20 DOI: 10.1177/00027162231200305
Margot Jackson, Ester Fanelli

Increasingly, research suggests that overlapping, simultaneous forms of public investment are especially beneficial for child development. However, participation in social safety net programs is rarely universal among the eligible population, and the phenomenon of multiple benefit use is even more complex: which households with children receive multiple benefits, which combinations of benefits are most common, and which households are most likely to access the social safety net as it has expanded in some areas while contracting in others? Using almost 40 years of data from the Survey of Income and Program Participation (SIPP), we examine trends in both the number of public benefits accessed by American households with children, as well as the types and combinations of benefits accessed. We find that the percentage of households with children who use at least two benefits has increased during this period. However, the beneficiaries of increasing benefit use have been disproportionately higher-educated, White and married households with incomes above the poverty line.

越来越多的研究表明,重叠的、同时进行的公共投资形式尤其有利于儿童的发展。然而,在符合条件的人群中,参与社会安全网计划的人很少具有普遍性,而且多重福利的使用现象更为复杂:哪些有孩子的家庭领取了多重福利,哪些福利组合最为常见,以及随着社会安全网在某些领域的扩大而在另一些领域的收缩,哪些家庭最有可能获得社会安全网的帮助?我们利用收入与计划参与调查 (Survey of Income and Program Participation, SIPP) 近 40 年的数据,研究了有子女的美国家庭享受公共福利的数量趋势,以及享受福利的类型和组合。我们发现,在此期间,至少使用两种福利的有子女家庭的比例有所上升。然而,越来越多地使用福利的受益者是受教育程度较高的白人和收入高于贫困线的已婚家庭。
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引用次数: 0
Assessing the Civic-Building Capacities of Schools: Early Findings from a Survey of Parents and Students 评估学校的公民建设能力:来自家长和学生调查的早期发现
2区 社会学 Q1 Social Sciences Pub Date : 2023-01-01 DOI: 10.1177/00027162231179825
Ashley berner, Crystal Spring, Andrea Ochoa
Schools in the U.S. have long been charged with the work of preparing young people for engaged citizenship. Do they, in fact, accomplish this work? Using survey data from 164 schools, we find mixed performance of schools in terms of their civic-building capacity, with striking disconnects between rhetoric and reality. We show that although students rate citizenship as a strong school priority, they are infrequently exposed to activities that support community engagement. Similarly, parents expect classrooms to have open climates in which students are free to discuss and disagree about controversial topics, but students report that such environments are a rarity. Additional findings indicate that lower-socioeconomic-status, female, nonbinary, and public/charter school students are significantly less likely to perceive their classrooms as open, and Black students perceive more open climates than their White counterparts.
长期以来,美国的学校一直肩负着培养年轻人成为积极公民的责任。他们真的完成了这项工作吗?利用164所学校的调查数据,我们发现学校在公民建设能力方面的表现参差不齐,言论与现实之间存在明显脱节。我们表明,尽管学生将公民身份列为学校的优先事项,但他们很少参加支持社区参与的活动。同样,家长希望教室里有开放的氛围,让学生可以自由地讨论和反对有争议的话题,但学生们报告说,这样的环境很少见。其他研究结果表明,社会经济地位较低、女性、非二元性别和公立/特许学校的学生明显不太可能认为他们的教室是开放的,黑人学生比白人学生更容易感受到开放的氛围。
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引用次数: 1
What the Sciences of Human Learning and Development Tell Us about Civic Reasoning and Discourse 人类学习和发展的科学告诉我们关于公民推理和话语
2区 社会学 Q1 Social Sciences Pub Date : 2023-01-01 DOI: 10.1177/00027162231188575
Carol D. Lee, Na’ilah Suad Nasir, Mary Helen Immordino-Yang
There is perhaps no more important skill to cultivate in today’s students than civic reasoning: the ability to think about social issues in complex ways. Civic reasoning involves the integration of knowledge, epistemological orientations, and ethics, and this integration is influenced by individuals’ perceptions of themselves and others, and by the problems they seek to address in the civic domain. We synthesize research from psychology, learning science, human development, and brain development to identify conditions that maximize opportunities for children, adolescents, and adults to learn to engage in civic reasoning. We argue that a commitment to democratic principles, and the development of the reasoning skills and ethical dispositions that undergird them, results in a more engaged populace that is willing and able to understand multiple perspectives and to make sound decisions for the collective good.
在今天的学生中,也许没有比培养公民推理更重要的技能了:以复杂的方式思考社会问题的能力。公民推理涉及知识、认识论取向和伦理的整合,而这种整合受到个人对自己和他人的看法以及他们在公民领域寻求解决的问题的影响。我们综合了心理学、学习科学、人类发展和大脑发育方面的研究,以确定为儿童、青少年和成年人提供最大机会学习公民推理的条件。我们认为,对民主原则的承诺,以及支撑民主原则的推理技能和道德倾向的发展,会导致一个更积极参与的民众,他们愿意也能够理解多种观点,并为集体利益做出合理的决定。
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引用次数: 0
Educating Students for Democracy: What Colleges Are Doing, How It’s Working, and What Needs to Happen Next 教育学生民主:大学在做什么,它是如何工作的,以及下一步需要发生什么
2区 社会学 Q1 Social Sciences Pub Date : 2023-01-01 DOI: 10.1177/00027162231188567
Elizabeth A. Bennion, Melissa R. Michelson
In the U.S., we have historically looked to our educators to prepare citizens for full participation in our democracy as engaged and informed voters. We examine the student voting movement that has taken root in colleges and universities across the country—a movement that offers a promising way forward in forming a new generation of engaged citizens. We detail what we know about how to increase student turnout, suggest ways to strengthen voter mobilization efforts through a broader civic education agenda, chart a path forward for future research, and offer recommendations for college administrators who seek to make voting a lifelong habit for their students. We also look beyond the student voting movement to argue for new forms of pedagogy that foster civic identity so that students think of themselves as voters who always vote, because voting is a necessary way to express themselves as engaged citizens.
在美国,我们历来期待我们的教育工作者为公民做好充分参与民主的准备,让他们成为积极参与和知情的选民。我们研究了已经在全国高校扎根的学生投票运动——这一运动为形成新一代参与公民提供了一条有希望的道路。我们详细介绍了我们所知道的如何提高学生投票率,提出了通过更广泛的公民教育议程加强选民动员工作的方法,为未来的研究指明了前进的道路,并为那些寻求使投票成为学生终身习惯的大学管理者提供了建议。我们也将目光投向学生投票运动之外,为培养公民身份的新教育形式而争论,这样学生们就会认为自己是经常投票的选民,因为投票是表达自己作为参与公民的必要方式。
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引用次数: 0
Examining Food Security, Choices and Barriers among Community Supported Agriculture participants during COVID- 19 in Kentucky. 在肯塔基州 COVID- 19 期间,对社区支持农业参与者的食品安全、选择和障碍进行研究。
IF 1.6 2区 社会学 Q1 Social Sciences Pub Date : 2023-01-01 Epub Date: 2021-11-20 DOI: 10.1080/19320248.2021.1994084
Martha J Biddle, JungHee Kang, Julie Derringer, Anna Rose, Dawn P Brewer, Misook Chung, Terry A Lennie, Gia Mudd-Martin, Timothy A Woods

The coronavirus disease (COVID-19) pandemic is challenging food security. Our study's purpose was to examine relationships among food security status, eating patterns and perceived barriers to food choices among shareholders (N= 209) in a Community Supported Agriculture (CSA) program during stay-at-home restrictions due to the pandemic. The food insecure group (n= 33) reported lower consumption of fruits/vegetables, whole grains and greater consumption of fast foods and more barriers to food choices compared to the food secure group (p<.05). A low food insecure proportion (16%) among the CSA participants suggests a potential role of a CSA program to prevent food insecurity.

冠状病毒病(COVID-19)大流行给食品安全带来了挑战。我们的研究旨在考察社区支持农业(CSA)计划的股东(人数= 209)在因大流行而限制在家期间的食品安全状况、饮食模式和食品选择障碍之间的关系。与食品安全组(n= 33)相比,食品不安全组(n= 33)的水果/蔬菜和全谷物消费量较低,快餐消费量较高,食品选择障碍较多(p=0.05)。
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引用次数: 0
The Future of Civic Education: Implications for Research, Policy, and Practice 公民教育的未来:对研究、政策和实践的启示
2区 社会学 Q1 Social Sciences Pub Date : 2023-01-01 DOI: 10.1177/00027162231193538
Gregory White, Dian Dong, David E. Campbell, Carol D. Lee
We present a summary of the volume’s main insights and recommendations for a robust form of civic education that will prepare young people to become civic actors who can take responsibility for upholding and advancing democracy. This volume establishes the need to expand civic education across curricula, beyond a one-shot course. We argue that the challenges of democracy and civic problems we face are multifaceted, requiring reasoned judgment and democratic decision-making, and involving discourse around rights and responsibilities. To meet these challenges, the stature of civic education must be elevated, its content expanded, and its delivery improved upon to ensure that civic learning is meaningful and relevant to students’ diverse lives. Students also need to develop a civic and problem-solving toolkit: this work should start at an early age, involve opportunities to explore their own questions about democracy and civic involvement, and model democratic engagement in their own schools and communities.
我们总结了本书的主要见解和建议,以建立一种强有力的公民教育形式,使年轻人成为能够承担维护和推进民主的责任的公民行动者。这本书建立了需要扩大公民教育的课程,超越一个单一的过程。我们认为,我们面临的民主挑战和公民问题是多方面的,需要理性的判断和民主的决策,并涉及围绕权利和责任的讨论。为了应对这些挑战,必须提高公民教育的水平,扩大其内容,改进其提供方式,以确保公民学习是有意义的,与学生多样化的生活相关。学生还需要开发一个公民和解决问题的工具包:这项工作应该从小开始,包括有机会探索他们自己关于民主和公民参与的问题,并在他们自己的学校和社区中示范民主参与。
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引用次数: 0
Civic Education in a Time of Democratic Crisis 民主危机时期的公民教育
2区 社会学 Q1 Social Sciences Pub Date : 2023-01-01 DOI: 10.1177/00027162231190539
Gregory White, Dian Dong, David E. Campbell, Carol D. Lee
This volume features frontiers of scholarship in the political, social, and behavioral sciences that are advancing civic education. The volume begins with an analysis of recent efforts to create a shared agenda for civic learning against a backdrop of politicization in education. Additional articles provide theoretical and empirical support for the knowledge, skills, and dispositions necessary for students to become engaged civic actors and problem solvers; other contributions offer illustrations of civic learning in action. A cross-cutting theme is the role that cultural contexts and environments play in helping to ensure meaningful student learning in the United States’ multiethnic democracy. The volume concludes with recommendations for research, policy, and practice that can further advance a type of civic education that invigorates and preserves our democratic traditions and prepares students to address the political, socioeconomic, and ecological challenges that loom ever larger on the horizon.
这本书的特点是学术前沿的政治,社会和行为科学,正在推进公民教育。本书首先分析了最近在教育政治化的背景下为公民学习创造共同议程的努力。额外的文章提供了理论和实证支持的知识,技能和必要的处置学生成为参与公民行为者和问题解决者;其他文章则提供了公民学习的实例。一个跨领域的主题是文化背景和环境在帮助确保学生在美国多民族民主中有意义的学习中所起的作用。本书最后对研究、政策和实践提出了建议,这些建议可以进一步推进一种公民教育,使我们的民主传统焕发活力,并使学生准备好应对日益严峻的政治、社会经济和生态挑战。
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引用次数: 0
Lessons in Empowerment: The Civic Potential of Historically Grounded Conversations among Racially Marginalized Youth 赋权的教训:种族边缘化青年之间基于历史的对话的公民潜力
2区 社会学 Q1 Social Sciences Pub Date : 2023-01-01 DOI: 10.1177/00027162231188576
Matthew D. Nelsen
Civic education is associated with the development of democratic capacity. However, this concept is measured using a limited battery of metrics (e.g., trust in government) that do not adequately capture the political sentiments of racially marginalized youth. Drawing from conversations with Chicago high school students and their teachers, I argue that democratic capacity should comprise a broader set of attitudes and behaviors, including political empowerment and acts of public voice. In the process, I identify one pedagogical technique associated with the development of empowerment: historically grounded conversations about politics that validate students’ distrust of government. Nationally representative survey data suggests that civic learning experiences of this kind are associated with feelings of political empowerment and that empowerment is associated with multiple forms of political participation, particularly among Black and Latinx youth. Overall, this study provides a path forward for those interested in reimagining civic education in the U.S.
公民教育与民主能力的发展有关。然而,这一概念是用有限的指标(例如,对政府的信任)来衡量的,这些指标不能充分捕捉种族边缘化青年的政治情绪。通过与芝加哥高中学生和他们的老师的对话,我认为民主能力应该包括一系列更广泛的态度和行为,包括政治赋权和公众发声的行为。在这个过程中,我发现了一种与赋权发展相关的教学技巧:基于历史的政治对话,证实了学生对政府的不信任。具有全国代表性的调查数据表明,这种公民学习经历与政治赋权的感觉有关,这种赋权与多种形式的政治参与有关,尤其是在黑人和拉丁裔青年中。总的来说,这项研究为那些对重塑美国公民教育感兴趣的人提供了一条前进的道路
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引用次数: 0
Refocusing Civic Education: Developing the Skills Young People Need to Engage in Democracy 重新聚焦公民教育:培养年轻人参与民主所需的技能
2区 社会学 Q1 Social Sciences Pub Date : 2023-01-01 DOI: 10.1177/00027162231177798
D. Sunshine Hillygus, John B. Holbein
Schools have traditionally taken a “just-the-facts-ma’am” approach to civic education, focusing on governmental structures and political systems. We argue that preparing young people to engage with democracy requires far more than rote memorization of facts and figures. Schools should be laboratories of democracy, where young people’s civic intentions are converted into civic behaviors. We argue that to realize that transformation, educators must impart real-world knowledge, practical skills, and nurturing abilities that are not captured by standardized tests of academic achievement: namely, the interpersonal and intrapersonal abilities conducive to civic mindedness. We discuss what these oft-labeled “noncognitive” skills are and how they are measured, review the evidence that shows how they foster democratic participation, articulate a vision for how civics can help develop students’ noncognitive skills, and lay out a research agenda for scholars seeking to teach young people the skills requisite to actively participate in democracy.
学校传统上采取“实事求是”的方式进行公民教育,重点关注政府结构和政治制度。我们认为,让年轻人准备好参与民主,需要的远不止死记硬背事实和数字。学校应该成为民主的实验室,将年轻人的公民意愿转化为公民行为。我们认为,要实现这种转变,教育工作者必须传授现实世界的知识、实用技能,并培养那些在标准化的学术成就测试中没有体现出来的能力:即有利于公民意识的人际交往和内向型能力。我们讨论了这些经常被贴上“非认知”标签的技能是什么以及如何衡量它们,回顾了显示它们如何促进民主参与的证据,阐明了公民如何帮助培养学生的非认知技能的愿景,并为寻求教授年轻人积极参与民主所必需的技能的学者制定了研究议程。
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引用次数: 0
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Annals of the American Academy of Political and Social Science
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