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A quantitative assessment of the behavior of metallic elements in urban soils exposed to industrial dusts near Dunkirk (Northern France) 对敦刻尔克(法国北部)附近受工业粉尘影响的城市土壤中金属元素的行为进行定量评估
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-10-14 DOI: 10.5194/egusphere-2024-1875
Marine Casetta, Sylvie Philippe, Lucie Courcot, David Dumoulin, Gabriel Billon, François Baudin, Françoise Henry, Michaël Hermoso, Jacinthe Caillaud
Abstract. In urban and industrialized areas, soil contamination and degradation caused by the deposition of industrial dusts may pose significant health and environmental risks. This problem relates to the vertical mobility and bioavailability of Potentially Toxic Elements (PTE). This study investigates the fate of PTE brought by industrial dusts in urban soils located in the Dunkerque agglomeration, one of the most industrialized areas of France. Four soil short cores were collected in the city of Gravelines (Dunkerque agglomeration) following a gradient from the industrial emitters to the deposition site. The soil cores were cut into discrete 1-cm-sections to study their PTE concentrations (using ICP-AES/MS analyses). Single HCl extraction was performed to evaluate the mobility of PTE in soils and to discuss their specific behavior according to the current soil parameters. For this purpose, the main soil parameters were identified (grain-size distribution, mineralogy, pH, CEC, TOC, calcium carbonates and water contents) in addition to the soil chemical composition (XRF, ICP-AES/MS analyses). The studied soils revealed globally low absorbent capacities for pollutants (CEC averaging 5.3 meq/100g), partially counterbalanced by the buffering effect of calcium carbonates (contents ranging from 8 % to 30 %). We highlighted minor (1<EF<3) to moderately severe (5<EF<10) Enrichment Factors in industrial PTE (Cr, Ni, Mo, Mn, Cd, Zn), in the first 3 centimeters of the soils located near the industrial emitters. The contamination profiles of these soils are concordant with atmospheric inputs of metallurgical dust. Using a relatively strong leaching reagent (HCl 1M), we estimated a low vertical mobility for Cr, Ni and Mo (average leached ratios <25 %) in soils, suggesting that these industrial PTE mainly occur in refractory phases (natural or anthropogenic). Mn, Cd and Zn, related to industrial and/or urban sources, present a higher mobility (average leached ratios > 60 % for Mn and Cd, and averaging 44 % for Zn). Our study points out the stability of industrial PTE in soils under current physicochemical conditions (calcareous soils with a slightly basic pH of 7.8). In this context, the monitoring of industrial PTE in these urban soils is highly recommended, considering (1) the presence of allotment gardens in the vicinity of the emitters and (2) the potential evolution of soil conditions as a result of increased flooding events.
摘要在城市和工业化地区,工业粉尘沉积造成的土壤污染和退化可能对健康和环境构成重大风险。这一问题与潜在有毒元素(PTE)的垂直迁移性和生物利用率有关。本研究调查了法国工业化程度最高的地区之一敦刻尔克城市群的城市土壤中工业粉尘带来的 PTE 的归宿。研究人员在格拉夫林市(敦刻尔克城市群)采集了四块土壤短岩芯,这些岩芯从工业排放口到沉积地点呈梯度分布。将土芯切成 1 厘米的不连续切片,以研究其 PTE 浓度(使用 ICP-AES/MS 分析)。为了评估 PTE 在土壤中的流动性,并根据当前的土壤参数讨论其特定行为,进行了单次盐酸萃取。为此,除了土壤化学成分(XRF、ICP-AES/MS 分析)外,还确定了主要的土壤参数(粒度分布、矿物学、pH 值、CEC、总有机碳、碳酸钙和水含量)。所研究的土壤对污染物的吸收能力普遍较低(CEC 平均为 5.3 meq/100g),碳酸钙(含量从 8% 到 30% 不等)的缓冲作用部分抵消了这一影响。我们强调了工业排放口附近前 3 厘米土壤中轻微(1<EF<3)到中度严重(5<EF<10)的工业 PTE(铬、镍、钼、锰、镉、锌)富集因子。这些土壤的污染特征与大气中的冶金粉尘输入相一致。使用相对较强的浸出试剂(1M 盐酸),我们估计铬、镍和钼在土壤中的垂直迁移率较低(平均浸出率为 25%),这表明这些工业 PTE 主要存在于难熔相(天然或人为)中。与工业和/或城市来源有关的锰、镉和锌的流动性较高(锰和镉的平均沥滤率为 60%,锌的平均沥滤率为 44%)。我们的研究表明,在当前的物理化学条件下(pH 值为 7.8 的微碱性石灰质土壤),工业 PTE 在土壤中具有稳定性。在这种情况下,考虑到 (1) 排放口附近有配给园,以及 (2) 土壤条件可能因洪水事件增加而发生变化,我们强烈建议对这些城市土壤中的工业 PTE 进行监测。
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引用次数: 0
Modeling of greenhouse gas emissions from paludiculture in rewetting peatlands is improved by high frequency water table data 利用高频地下水位数据改进泥炭地复湿棕榈栽培温室气体排放模型
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-10-11 DOI: 10.5194/egusphere-2024-3030
Andres F. Rodriguez, Johannes W. M. Pullens, Jesper R. Christiansen, Klaus S. Larsen, Poul E. Lærke
Abstract. Rewetting drained peatlands can reduce CO2 emissions but prevents traditional agriculture. Crop production under rewetted conditions may continue with flood-tolerant crops in paludiculture, but its effects on greenhouse gas (GHG) emissions compared to rewetting without further management are largely unknown This study was conducted between 2021 and 2022 on a fen peatland in central Denmark. At the study site, three harvest/fertilization management treatments were implemented on Reed Canary Grass (RCG) established in 2018. Measurements of CO2 and CH4 emissions were conducted biweekly using a transparent manual chamber connected to a gas analyzer and manipulating light intensities with four shrouding levels. Although this was a rather wet peatland (−8 cm mean annual WTD), the site was a CO2 source with a mean net ecosystem C balance (NECB) of 6.5 t C ha−1 yr−1 across treatments. Model simulation with the use of high temporal resolution water table depth (WTD) data was able to better capture ecosystem respiration (Reco) peaks compared to the use of mean annual WTD, which underestimated Reco. Data on pore water chemistry further improved statistical linear models of CO2 fluxes using soil temperature (Ts), WTD, ratio vegetation indices and PAR as explanatory variables. Significant differences in CO2 emissions and water chemistry parameters were found between studied blocks, with higher Reco corresponding to blocks with higher pore water nutrient concentrations. Methane emissions averaged 113 kg of CH4 ha−1 yr−1, equivalent to 11.3 % of the total carbon emission in CO2 equivalents. Because of large heterogeneity among the experimental blocks no significant treatment effect was found, however, the results indicate that biomass harvest reduces GHG emission from productive rewetted peatland areas in comparison with no management, whereas on less productive areas it is beneficial to leave the biomass unmanaged.
摘要复湿排水泥炭地可减少二氧化碳排放,但会阻碍传统农业的发展。在重新湿润的条件下,可以继续种植耐涝作物,但与没有进一步管理的重新湿润相比,其对温室气体(GHG)排放的影响在很大程度上是未知的。在研究地点,对 2018 年建立的芦苇加那利草(RCG)实施了三种收割/施肥管理处理。每两周测量一次二氧化碳和甲烷的排放量,测量时使用了一个连接到气体分析仪的透明手动室,并通过四种遮蔽水平来控制光照强度。虽然这是一片相当潮湿的泥炭地(年平均 WTD 为-8 厘米),但该地点是一个二氧化碳源,各处理的平均生态系统净 C 平衡(NECB)为 6.5 吨 C ha-1 yr-1。使用高时间分辨率地下水位深度(WTD)数据进行模型模拟,与使用年平均地下水位深度相比,能更好地捕捉到生态系统呼吸作用(Reco)峰值,后者低估了Reco。孔隙水化学数据进一步改进了以土壤温度(Ts)、WTD、植被指数比值和 PAR 为解释变量的二氧化碳通量统计线性模型。二氧化碳排放量和水化学参数在研究区块之间存在显著差异,孔隙水养分浓度越高的区块,Reco 值越高。甲烷排放量平均为每公顷每年 113 千克 CH4,相当于二氧化碳排放总量的 11.3%。由于实验区块之间存在较大差异,因此没有发现显著的处理效果,但结果表明,与不进行管理相比,收获生物质可减少高产复湿泥炭地的温室气体排放量,而在产量较低的地区,不对生物质进行管理则是有益的。
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引用次数: 0
Diachronic assessment of soil organic C and N dynamics under long-term no-till cropping systems in the tropical upland of Cambodia 柬埔寨热带高地长期免耕种植系统下土壤有机碳和氮动态的非同步评估
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-10-10 DOI: 10.5194/soil-10-699-2024
Vira Leng, Rémi Cardinael, Florent Tivet, Vang Seng, Phearum Mark, Pascal Lienhard, Titouan Filloux, Johan Six, Lyda Hok, Stéphane Boulakia, Clever Briedis, João Carlos de Moraes Sá, Laurent Thuriès
Abstract. No-till (NT) cropping systems have been proposed as a strategy to combat soil degradation by storing soil organic carbon (SOC) and total nitrogen (TN). We quantified the impacts of NT cropping systems on the changes in SOC and TN stocks and in particulate and mineral-associated organic matter fractions (POM and MAOM), to 100 cm depth, from three 13-year-old experiments in a tropical red Oxisol in Cambodia using diachronic and equivalent soil mass approaches. Established in 2009 and arranged in a randomized complete-block design with triplicates, the experiments included maize (MaiEx)-, soybean (SoyEx)-, and cassava (CasEx)-based cropping systems. Each experiment comprised three treatments: (1) mono-cropping of main crops (maize, soybean, and cassava) under conventional tillage (CTM); (2) mono-cropping of main crops under NT systems with the use of cover crops (NTM); and (3) bi-annual rotation of main crops under NT systems with the use of cover crops (NTR), with both crops being presented every year and represented by NTR1 and NTR2. Soil samples were collected in 2021, 10 years after the last sampling. All the NT systems significantly (p<0.05) increased SOC stock in the topsoil in SoyEx and MaiEx and down to 40 cm in CasEx. Considering the whole profile (0–100 cm), the SOC accumulation rates ranged from 0.86 to 1.47 and from 0.70 to 1.07 Mg C ha−1 yr−1 in MaiEx and CasEx, respectively. Although SOC stock significantly increased in CTM at 0–20 cm in MaiEx and CasEx, it remained stable at 0–100 cm in all the experiments. At 0–5 cm, NTR systems significantly increased TN stock in all the experiments, while, in NTM systems, it was only significant in MaiEx and SoyEx. At 0–100 cm, TN stock in all the experiments remained stable under NTR systems, whereas a significant decrease was observed under NTM systems in SoyEx and CasEx. Although C-POM stock significantly increased under all NT systems limited to 0–10 cm in MaiEx and SoyEx, all the NT systems significantly increased C-MAOM stock in the 0–10 cm layer in MaiEx and SoyEx and down to 40 cm in CasEx. All the NT systems significantly increased N-POM stock at 0–10 cm in MaiEx and SoyEx, while a significant decreased in N-MAOM stock was observed below 5 cm in CasEx and below 40 cm in MaiEx and SoyEx. Our findings showed that long-term NT systems with crop species diversification accumulated SOC not only on the surface but also in the whole profile by increasing SOC in both the POM and MAOM, even in the cassava-based system. This study highlights the potential of NT systems for storing SOC over time but raises questions about soil N dynamics.
摘要免耕(NT)种植系统是通过储存土壤有机碳(SOC)和全氮(TN)来应对土壤退化的一种策略。我们采用非同步和等效土壤质量的方法,量化了免耕耕作系统对 SOC 和 TN 储量变化的影响,以及对 100 厘米深的颗粒有机质和矿物相关有机质部分(POM 和 MAOM)的影响。这些实验于 2009 年开始,采用随机完整区组设计(三重复),包括以玉米 (MaiEx)、大豆 (SoyEx) 和木薯 (CasEx) 为基础的种植系统。每个实验包括三个处理:(1) 在传统耕作(CTM)条件下单一种植主要作物(玉米、大豆和木薯);(2) 在使用覆盖作物(NTM)的 NT 系统条件下单一种植主要作物;(3) 在使用覆盖作物(NTR)的 NT 系统条件下一年两次轮作主要作物,每年轮作两种作物,分别以 NTR1 和 NTR2 表示。土壤样本于 2021 年采集,即上次采样的 10 年之后。在 SoyEx 和 MaiEx 中,所有新氮肥系统都明显增加了表层土壤中的 SOC 储量(p<0.05),在 CasEx 中,SOC 储量增加到 40 厘米。从整个剖面(0-100 厘米)来看,MaiEx 和 CasEx 的 SOC 积累率分别为 0.86-1.47 和 0.70-1.07 兆克碳/公顷/年。虽然在 MaiEx 和 CasEx 的 CTM 中,SOC 储量在 0-20 厘米处明显增加,但在所有试验中,SOC 储量在 0-100 厘米处保持稳定。在 0-5 厘米处,NTR 系统在所有实验中都显著增加了 TN 储量,而在 NTM 系统中,只有 MaiEx 和 SoyEx 的 TN 储量显著增加。在 0-100 厘米处,所有实验中的 TN 储量在 NTR 系统下都保持稳定,而在 NTM 系统下,SoyEx 和 CasEx 的 TN 储量则明显减少。虽然在 MaiEx 和 SoyEx 中,所有 NT 系统下的 C-POM 储量都明显增加,但在 MaiEx 和 SoyEx 中,所有 NT 系统都明显增加了 0-10 厘米层的 C-MAOM 储量,在 CasEx 中则增加到 40 厘米。在 MaiEx 和 SoyEx,所有氮氧化物脱氮系统都明显增加了 0-10 厘米处的 N-POM 储量,而在 CasEx,5 厘米以下以及 MaiEx 和 SoyEx,40 厘米以下的 N-MAOM 储量明显减少。我们的研究结果表明,作物物种多样化的长期近地栽培系统不仅在地表积累了 SOC,而且还通过增加 POM 和 MAOM 中的 SOC 在整个剖面中积累了 SOC,即使在以木薯为基础的系统中也是如此。这项研究强调了新氮肥系统长期储存 SOC 的潜力,但也提出了有关土壤氮动态的问题。
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引用次数: 0
Methane oxidation potential of soils in a rubber plantation in Thailand affected by fertilization 受施肥影响的泰国橡胶园土壤的甲烷氧化潜力
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-10-10 DOI: 10.5194/egusphere-2024-2937
Jun Murase, Kannika Sajjaphan, Chatprawee Dechjiraratthanasiri, Ornuma Duangngam, Rawiwan Chotiphan, Wutthida Rattanapichai, Wakana Azuma, Makoto Shibata, Poonpipope Kasemsap, Daniel Epron
Abstract. Forest soils, as crucial sinks for atmospheric methane in terrestrial ecosystems, are significantly impacted by changes in ecosystem dynamics due to deforestation and agricultural practices. This study investigated the methane oxidation potential of rubber plantation soils in Thailand, focusing on the effect of fertilization. The methane oxidation activity of the top soils (0–10 cm) in the dry season was found to be extremely low and slightly increased in the wet season, with lower activity for higher fertilization levels. The potential methane oxidation potential of the topsoil was too low to explain the in-situ methane uptake. Soils below 10 cm depth in unfertilized rubber plantations showed higher activity than the surface soils, and methane oxidation was detected at least down to 60 cm depth. In contrast, soils under the high-fertilization treatment exhibited similarly low activity of methane oxidation up to 60 cm depth as surface soils both in dry and wet seasons, indicating that fertilization of para rubber plantation negatively impacts the methane oxidation potential of the soils over the deep profile without recovery in the off-season with no fertilization. Methane uptake per area estimated by integrating the methane oxidation potentials of soil layers was comparable to the field flux data, suggesting that methane oxidation in the soil predominantly occurs in depths below the surface layer. These findings have significant implications for understanding the environmental impacts of tropical forest land uses on methane dynamics and underscore the importance of understanding methane oxidation processes in soils.
摘要森林土壤是陆地生态系统中大气甲烷的重要吸收汇,受到森林砍伐和农业耕作导致的生态系统动态变化的严重影响。本研究调查了泰国橡胶种植园土壤的甲烷氧化潜力,重点关注施肥的影响。研究发现,旱季表层土壤(0-10 厘米)的甲烷氧化活性极低,而在雨季则略有上升,施肥水平越高,甲烷氧化活性越低。表层土壤的潜在甲烷氧化潜力太低,无法解释原地甲烷吸收量。未施肥橡胶园 10 厘米深以下的土壤比表层土壤显示出更高的活性,至少在 60 厘米深的土壤中检测到甲烷氧化。与此相反,高施肥处理下的土壤在旱季和雨季都表现出与表层土壤类似的低甲烷氧化活性,最深可达 60 厘米。通过整合各土层的甲烷氧化潜能估算出的单位面积甲烷吸收量与实地通量数据相当,表明土壤中的甲烷氧化主要发生在表层以下的深度。这些发现对了解热带森林土地利用对甲烷动态的环境影响具有重要意义,并强调了了解土壤中甲烷氧化过程的重要性。
{"title":"Methane oxidation potential of soils in a rubber plantation in Thailand affected by fertilization","authors":"Jun Murase, Kannika Sajjaphan, Chatprawee Dechjiraratthanasiri, Ornuma Duangngam, Rawiwan Chotiphan, Wutthida Rattanapichai, Wakana Azuma, Makoto Shibata, Poonpipope Kasemsap, Daniel Epron","doi":"10.5194/egusphere-2024-2937","DOIUrl":"https://doi.org/10.5194/egusphere-2024-2937","url":null,"abstract":"<strong>Abstract.</strong> Forest soils, as crucial sinks for atmospheric methane in terrestrial ecosystems, are significantly impacted by changes in ecosystem dynamics due to deforestation and agricultural practices. This study investigated the methane oxidation potential of rubber plantation soils in Thailand, focusing on the effect of fertilization. The methane oxidation activity of the top soils (0–10 cm) in the dry season was found to be extremely low and slightly increased in the wet season, with lower activity for higher fertilization levels. The potential methane oxidation potential of the topsoil was too low to explain the in-situ methane uptake. Soils below 10 cm depth in unfertilized rubber plantations showed higher activity than the surface soils, and methane oxidation was detected at least down to 60 cm depth. In contrast, soils under the high-fertilization treatment exhibited similarly low activity of methane oxidation up to 60 cm depth as surface soils both in dry and wet seasons, indicating that fertilization of para rubber plantation negatively impacts the methane oxidation potential of the soils over the deep profile without recovery in the off-season with no fertilization. Methane uptake per area estimated by integrating the methane oxidation potentials of soil layers was comparable to the field flux data, suggesting that methane oxidation in the soil predominantly occurs in depths below the surface layer. These findings have significant implications for understanding the environmental impacts of tropical forest land uses on methane dynamics and underscore the importance of understanding methane oxidation processes in soils.","PeriodicalId":48610,"journal":{"name":"Soil","volume":"227 1","pages":""},"PeriodicalIF":6.8,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142397785","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Assessing soil fertilization effects using time-lapse electromagnetic induction 利用延时电磁感应评估土壤施肥效果
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-10-10 DOI: 10.5194/egusphere-2024-2889
Manuela S. Kaufmann, Anja Klotzsche, Jan van der Kruk, Anke Langen, Harry Vereecken, Lutz Weihermüller
Abstract. Adding mineral fertilizers and mineral nutrient is a common practice in conventional farming and fundamental to maintain optimal yield and crop quality, whereby nitrogen is the most applied fertilizer often used excessively, leading to adverse environmental impacts. To assist farmers in optimal fertilization and crop management, non-invasive geophysical methods can provide knowledge about the spatial and temporal distributions of nutrients in the soil. In recent years, electromagnetic induction (EMI) is widely used for field characterization, to delineate soil units and management zones or to estimate soil properties and states. Additionally, ground penetrating radar (GPR) and electrical resistivity tomography (ERT) have been used in local studies to measure changes of soil properties. Unfortunately, the measured geophysical signals are confounded by horizontal and vertical changes of soil states and parameters and the single contributions of those states and parameters are not easy to disentangle. Within fields, and also between fields, fertilization management might vary in space and time, and therefore, the differences in pore fluid conductivity caused directly by fertilization, or indirectly by different crop performance, makes the interpretation of large-scale geophysical survey over field borders complicated. To study the direct effect of mineral fertilization and its effects on the soil electrical conductivity, a field experiment was performed on 21 bare soil plots with seven different fertilization treatments. As fertilizers, calcium ammonium nitrate (CAN) and potassium chloride (KCl) were chosen and applied in three dosages. Soil water content, soil temperature, and bulk electrical conductivity were recorded permanently over 450 days. Additionally, 20 EMI, 7 GPR, and 9 ERT surveys were performed and at days of ERT measurements soil samples for nitrate and reference soil electrical conductivity measurements were taken. The results showed that the commonly used CAN application dosage did not impact the geophysical signals significantly. On the other hand, EMI and ERT were able to trace back the temporal changes in nitrate concentrations in the soil profile over more than one year. On the other hand, the results also showed, that both techniques were not able to trace the nitrate concentrations in the very shallow soil layer of 0–10 cm. Irrespectively of the low impact of fertilization on the geophysical signal, the results indicated that past fertilization practices cannot be neglected in EMI studies, especially if surveys are performed over large areas with different fertilization practices or crop grown with different fertilizer demands or uptake.
摘要添加矿物肥料和矿物养分是传统耕作中的常见做法,也是保持最佳产量和作物品质的基础,其中氮肥是施用量最大的肥料,经常被过度使用,导致对环境的不利影响。为了帮助农民优化施肥和作物管理,非侵入式地球物理方法可以提供有关土壤中养分时空分布的知识。近年来,电磁感应(EMI)被广泛用于田间特征描述、划分土壤单元和管理区或估算土壤性质和状态。此外,地面穿透雷达(GPR)和电阻率层析成像(ERT)也被用于测量土壤性质的变化。遗憾的是,测量到的地球物理信号会受到土壤状态和参数的水平和垂直变化的干扰,而且这些状态和参数的单一贡献不易区分。在田块内部以及田块之间,施肥管理可能在空间和时间上存在差异,因此,施肥直接或间接导致的孔隙流体传导性差异,使得对田块边界大规模地球物理勘测的解释变得复杂。为了研究矿物肥料的直接作用及其对土壤导电率的影响,我们在 21 块裸露土壤上进行了田间试验,共采用了 7 种不同的施肥处理。试验选择了硝酸铵钙(CAN)和氯化钾(KCl)作为肥料,以三种剂量施用。对土壤含水量、土壤温度和体积电导率进行了持续 450 天的记录。此外,还进行了 20 次 EMI、7 次 GPR 和 9 次 ERT 勘测,并在 ERT 测量的日子里采集了土壤样本,用于硝酸盐和参考土壤导电率的测量。结果表明,常用的 CAN 应用剂量对地球物理信号没有明显影响。另一方面,EMI 和 ERT 能够追溯土壤剖面中硝酸盐浓度一年多的时间变化。另一方面,结果还显示,这两种技术都无法追踪 0-10 厘米极浅土层的硝酸盐浓度。尽管施肥对地球物理信号的影响较小,但研究结果表明,在电磁干扰研究中不能忽视过去的施肥方法,尤其是在对具有不同施肥方法或具有不同肥料需求量或吸收量的作物种植的大面积区域进行勘测时。
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引用次数: 0
Operationalizing fine-scale soil property mapping with spectroscopy and spatial machine learning 利用光谱学和空间机器学习绘制精细尺度的土壤属性图
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-10-07 DOI: 10.5194/egusphere-2024-2810
Thorsten Behrens, Karsten Schmidt, Felix Stumpf, Simon Tutsch, Marie Hertzog, Urs Grob, Armin Keller, Raphael Viscarra Rossel
Abstract. One challenge in soil mapping is the transfer of new techniques and methods into operational practice, integrating them with traditional field surveys, reducing costs, and increasing the quality of the soil maps. The latter is paramount, as they form the basis for many thematic maps. As part of a novel approach to soil mapping, we integrate various technologies and pedometric methodologies to create soil property maps for soil surveyors, which they can utilize as a reference before beginning their pedological fieldwork. This gives the surveyors considerably more detailed and accurate prior information, reducing the subjectivity inherent in soil mapping. Our approach comprises a novel soil sampling design that effectively captures spatial and feature spaces, mid-infrared spectroscopy, and spatial machine learning based on a comprehensive set of covariates generated through various feature engineering approaches. We employ multi-scale terrain attributes, temporal multi-scale remote sensing, and Euclidean distance fields to account for environmental correlation, spatial non-stationarity, and spatial autocorrelation in machine learning. Methods to reduce the uncertainties inherent to the spectral and spatial data were integrated. The new sampling design is based on a geographical stratification and focuses on the local soil variability. The method identifies spatially local minima and maxima of the feature space, which is fundamental to soil surveys at the specified scale. The k-means and Kennard-Stone algorithms were applied in a sequential manner within each cell of a hexagonal grid overlaying the study area. This approach permits a systematic sub-sampling from each cell to analyze predictive accuracy for varying sampling densities. We tested one to three samples per hectare. Our findings indicate that a sample size of two samples per hectare was sufficient for accurately mapping soil properties across 300 hectares. This markedly reduces the financial burden associated with subsequent projects, given the significant reduction in the time and resources required for surveying. The spectroscopic and spatial models were unbiased and yielded average R2 values of 0.91 and 0.68–0.86, depending on mapping with or without pedotransfer models. Our study highlights the value of integrating robust pedometric technologies in soil surveys.
摘要土壤制图面临的一个挑战是如何将新技术和新方法应用到实际操作中,并将其与传统的实地调查相结合,降低成本,提高土壤地图的质量。后者至关重要,因为它们是许多专题地图的基础。作为土壤制图新方法的一部分,我们整合了各种技术和测步法,为土壤勘测人员绘制土壤属性图,供他们在开始实地土壤学工作前参考。这为勘测人员提供了更为详细和准确的先验信息,减少了土壤制图中固有的主观性。我们的方法包括新颖的土壤采样设计(可有效捕捉空间和特征空间)、中红外光谱以及基于通过各种特征工程方法生成的一整套协变量的空间机器学习。我们采用多尺度地形属性、时间多尺度遥感和欧氏距离场来考虑机器学习中的环境相关性、空间非平稳性和空间自相关性。减少光谱和空间数据固有不确定性的方法被整合在一起。新的采样设计以地理分层为基础,重点关注当地土壤的变异性。该方法可识别特征空间的空间局部最小值和最大值,这对特定尺度的土壤调查至关重要。k-means 算法和 Kennard-Stone 算法在覆盖研究区域的六边形网格的每个单元内依次应用。这种方法允许对每个单元进行系统的子取样,以分析不同取样密度下的预测准确性。我们测试了每公顷一至三个样本。我们的研究结果表明,每公顷两个样本的取样量足以准确绘制 300 公顷的土壤特性图。由于勘测所需的时间和资源大幅减少,这明显减轻了后续项目的经济负担。光谱和空间模型均无偏差,平均 R2 值分别为 0.91 和 0.68-0.86,具体取决于是否使用 pedotransfer 模型绘制地图。我们的研究凸显了在土壤调查中集成强大的计步技术的价值。
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引用次数: 0
Cultivation reduces quantities of mineral-organic associations in the form of amorphous coprecipitates 培养可减少无定形共沉淀形式的矿物-有机结合体的数量
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-09-30 DOI: 10.5194/egusphere-2024-2933
Floriane Jamoteau, Emmanuel Doelsch, Nithavong Cam, Clément Levard, Thierry Woignier, Adrien Boulineau, François Saint-Antonin, Sufal Swaraj, Ghislain Gassier, Adrien Duvivier, Daniel Borschneck, Marie-Laure Pons, Perrine Chaurand, Vladimir Vidal, Nicolas Brouilly, Isabelle Basile-Doelsch
Abstract. Mineral-organic associations are crucial carbon and nutrient reservoirs in soils. However, soil cultivation disrupts these associations, leading to carbon loss and reduced soil fertility. Although, identifying the specific type(s) of mineral-organic associations susceptible to destruction or transformation upon cropping remains challenging, it is essential for devising strategies to preserve organic matter in croplands. Here we aimed to determine the predominant mineral-organic associations and to identify which types of associations are transformed upon cultivation. To achieve this, we sampled an andosol from both a forested and a cultivated area. We then analyzed cultivation-induced changes in soil physicochemical parameters and characterized mineral-organic associations using an array of spectro-microscopic techniques (TEM-EDX, TEM-EELS, and STXM), for comprehensive structural and compositional analysis. At the micro and nanoscale, we observed mineral-organic associations in the form of coprecipitates composed of amorphous oligomers containing Al, Si, and Fe (referred to as nanoCLICs for nanosized coprecipitates of inorganic oligomers with organics). Down to a few hundred nanometers, the nanoCLICs displayed elemental enrichments with C+Al+Si, C+Fe+Al+Si, or Al+Si dominance with less C. In contrast, organic matter exhibited various C speciation without compound-specific enrichments. These findings suggest that mineral-organic associations in andosols are nanoCLICs-type coprecipitates rather than organic matter associated solely with secondary minerals. NanoCLICs were present in both forest and crop andosols, and while cropping led to a 50 % decrease in nanoCLICs, it did not alter their nature. This novel conceptualization of mineral-organic associations as nanoCLICs shifts our understanding of their persistence in andosols and demonstrates their vulnerability to crop-induced changes.
摘要矿物与有机物的结合是土壤中重要的碳库和养分库。然而,土壤耕作会破坏这些结合,导致碳流失和土壤肥力下降。尽管确定在耕作时容易被破坏或转化的矿物-有机结合体的具体类型仍具有挑战性,但这对于制定保护农田有机质的策略至关重要。在此,我们旨在确定主要的矿物-有机结合体,并确定哪些类型的结合体会在种植时发生转变。为此,我们从林地和耕地中分别采集了一块土壤样本。然后,我们使用一系列光谱显微技术(TEM-EDX、TEM-EELS 和 STXM)分析了耕作引起的土壤理化参数变化,并对矿物-有机结合体进行了表征,以进行全面的结构和成分分析。在微米和纳米尺度上,我们观察到矿物与有机物以共沉淀物的形式结合在一起,共沉淀物由含有铝、硅和铁的无定形低聚物组成(无机低聚物与有机物的纳米级共沉淀物被称为 nanoCLICs)。小至几百纳米的纳米CLICs显示出C+Al+Si、C+Fe+Al+Si或Al+Si为主而C较少的元素富集。这些发现表明,气溶胶中的矿物-有机物关联是纳米CLICs类型的共沉淀,而不是仅与次生矿物关联的有机物。森林和作物气溶胶中都存在纳米CLICs,虽然种植导致纳米CLICs减少了50%,但并没有改变它们的性质。这种将矿物-有机物结合为纳米CLIC的新概念改变了我们对它们在气溶胶中的持久性的理解,并证明了它们易受作物引起的变化的影响。
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引用次数: 0
Insights into the prediction uncertainty of machine-learning-based digital soil mapping through a local attribution approach 通过局部归因法洞察基于机器学习的数字土壤制图的预测不确定性
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-09-30 DOI: 10.5194/soil-10-679-2024
Jeremy Rohmer, Stephane Belbeze, Dominique Guyonnet
Abstract. Machine learning (ML) models have become key ingredients for digital soil mapping. To improve the interpretability of their predictions, diagnostic tools such as the widely used local attribution approach known as SHapley Additive exPlanations (SHAP) have been developed. However, the analysis of ML model predictions is only one part of the problem, and there is an interest in obtaining deeper insights into the drivers of the prediction uncertainty as well, i.e. explaining why an ML model is confident given the set of chosen covariate values in addition to why the ML model delivered some particular results. In this study, we show how to apply SHAP to local prediction uncertainty estimates for a case of urban soil pollution – namely, the presence of petroleum hydrocarbons in soil in Toulouse (France), which pose a health risk via vapour intrusion into buildings, direct soil ingestion, and groundwater contamination. Our results show that the drivers of the prediction best estimates are not necessarily the drivers of confidence in these predictions, and we identify those leading to a reduction in uncertainty. Our study suggests that decisions regarding data collection and covariate characterisation as well as communication of the results should be made accordingly.
摘要机器学习(ML)模型已成为数字土壤制图的关键要素。为了提高其预测的可解释性,人们开发了一些诊断工具,如被广泛使用的本地归因方法,即 SHapley Additive exPlanations(SHAP)。然而,对 ML 模型预测的分析只是问题的一部分,人们还有兴趣深入了解预测不确定性的驱动因素,即除了解释为什么 ML 模型会得出某些特定结果之外,还要解释为什么 ML 模型在所选的协变量值集合下是有信心的。在本研究中,我们展示了如何将 SHAP 应用于城市土壤污染案例的局部预测不确定性估计,即图卢兹(法国)土壤中存在的石油碳氢化合物,它通过蒸汽侵入建筑物、直接摄入土壤和地下水污染对健康构成威胁。我们的研究结果表明,预测最佳估计值的驱动因素并不一定是这些预测可信度的驱动因素,我们确定了导致不确定性降低的驱动因素。我们的研究表明,有关数据收集、协变量特征描述以及结果交流的决策应相应作出。
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引用次数: 0
Cr(VI) reduction, electricity production, and microbial resistance variation in paddy soil under microbial fuel cell operation 微生物燃料电池运行下稻田土壤中六价铬的还原、发电量和微生物抗性的变化
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-09-30 DOI: 10.5194/egusphere-2024-2771
Huan Niu, Xia Luo, Peihan Li, Hang Qiu, Liyue Jiang, Subati Maimaitiaili, Minghui Wu, Fei Xu, Heng Xu, Can Wang
Abstract. Microbial fuel cell (MFC) is an efficient in-situ approach to combat pollutants and generate electricity. This study constructed a soil MFC (SMFC) to reduce Cr(VI) in paddy soil and investigate its influence on microbial community and microbial resistance characteristics. Fe3O4 nanoparticle as the cathodic catalyst effectively boosted power generation (0.97 V, 102.0 mW/m2), whose porous structure and reducibility also contributed to Cr reduction and immobilization. After 30 days, 93.67 % of Cr(VI) was eliminated. The bioavailable Cr decreased by 97.44 % while the residual form increased by 88.89 %. SMFC operation greatly changed soil enzymatic activity and microbial structure, with exoelectrogens like Desulfotomaculum (3.32 % in anode) and Cr(VI)-reducing bacteria like Hydrogenophaga (2.07 % in cathode) more than 1000 folds of soil. In particular, SMFC operation significantly enhanced the abundance of heavy metal resistance genes (HRGs). Among them, chrA, chrB, and chrR increased by 99.54~3314.34 % in SMFC anode than control, probably attributed to the enrichment of potential tolerators like Acinetobacter, Limnohabitans, and Desulfotomaculum. These key taxa were positively correlated with HRGs but negatively correlated with pH, EC, and Cr(VI), which could have driven Cr(VI) reduction. This study provided novel evidence for bioelectrochemical system application in contaminated paddy soil, which could be a potential approach for environmental remediation and detoxification.
摘要微生物燃料电池(MFC)是一种有效的就地处理污染物和发电的方法。本研究构建了一种土壤微生物燃料电池(SMFC)来降低稻田土壤中的六(VI)铬,并研究了其对微生物群落和微生物抗性特征的影响。作为阴极催化剂的 Fe3O4 纳米粒子有效地提高了发电量(0.97 V,102.0 mW/m2),其多孔结构和还原性也有助于铬的还原和固定。30 天后,93.67% 的六价铬被清除。生物可利用的铬减少了 97.44%,而残留形式的铬增加了 88.89%。SMFC 的运行极大地改变了土壤中的酶活性和微生物结构,阳极中的脱硫菌(Desulfotomaculum)(3.32%)和阴极中的嗜氢菌(Hydrogenophaga)(2.07%)等外电解质和六价铬还原菌在土壤中的比例超过了 1000 倍。特别是,SMFC 的运行大大提高了重金属抗性基因(HRGs)的丰度。其中,chrA、chrB 和 chrR 在 SMFC 阳极比对照组增加了 99.54%~3314.34%,这可能是由于潜在的耐受基因如 Acinetobacter、Limnohabitans 和 Desulfotomaculum 的富集。这些关键类群与 HRGs 呈正相关,但与 pH 值、EC 值和六价铬呈负相关,这可能是六价铬减少的原因。这项研究为生物电化学系统在受污染稻田土壤中的应用提供了新的证据,这可能是一种潜在的环境修复和解毒方法。
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引用次数: 0
Benchmarking soil multifunctionality 以土壤多功能性为基准
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-09-26 DOI: 10.5194/egusphere-2024-2851
E. R. Jasper Wubs
Abstract. Healthy soils provide multiple functions that importantly contribute to human wellbeing, including primary production, climate and water regulation, and supporting biodiversity. These functions can partially be combined and some functions also clearly trade-off: this motivates soil multifunctionality research. Society needs scientists to help assess which soils are best for which soil functions and to determine appropriate long-term management of any given soil for optimal function delivery. However, for both tasks science lacks coherent tools and in this paper I propose a way forward. Critically, we lack a common measurement framework that pins soil functioning measurements on a common scale. Currently the field is divided with respect to the methods we use to measure and assess soil functioning and indicators thereof. Only three indicator variables (SOM, acidity, and available P) were commonly measured (>70 % of schemes) across 65 schemes that aim to measure soil health or quality, and no biological measure is implemented in more than 30 % of the 65 schemes. This status quo prevents us from systematically comparing across and within soils; we lack a soil multifunctionality benchmark. We can address this limitations systematically by setting a common measurement system. To do this, I propose to use latent variable modelling based on a common set of functional measurements, to develop a common ‘IQ test for soils’. I treat soil functions as latent variables, because they are complex processes that cannot be measured directly, we can only detect drivers and consequences of these complex processes. Latent variable modelling has a long history in social, economic and psychometric fields, where it is known as factor analysis. Factor analysis aims to derive common descriptors – the factors – of hypothesized constructs by linking measurable response variables together on a common scale. Here, I explain why such a new approach to soil multifunctionality and soil health is needed and how it can be operationalized. The framework developed here is only an initial proposal, the issue of soil multifunctionality is too complex and too important to be addressed in one go. It needs to be resolved iteratively by bands of scientist working intensively together. We need to bring our best science together, in a collaborative effort, to develop progressively more refined ways of sustainably managing one of humanity’s most precious resources: our soils.
摘要健康的土壤具有多种功能,对人类福祉有重要贡献,包括初级生产、气候和水调节以及支持生物多样性。这些功能可以部分地结合在一起,有些功能还可以明显地进行权衡:这就是土壤多功能性研究的动机。社会需要科学家帮助评估哪些土壤最适合发挥哪些土壤功能,并决定对任何特定土壤进行适当的长期管理,以实现最佳功能。然而,对于这两项任务,科学界都缺乏统一的工具,因此我在本文中提出了前进的方向。最关键的是,我们缺乏一个共同的测量框架,将土壤功能的测量固定在一个共同的尺度上。目前,该领域在测量和评估土壤功能及其指标的方法上存在分歧。在 65 个旨在测量土壤健康或质量的计划中,只有三个指标变量(SOM、酸度和可利用磷)得到了普遍测量(70% 的计划),而在 65 个计划中,没有超过 30% 的计划采用生物测量方法。这种现状阻碍了我们对不同土壤和土壤内部进行系统比较;我们缺乏一个土壤多功能性基准。我们可以通过建立一个共同的测量系统来系统地解决这一局限性。为此,我建议在一套通用的功能衡量标准的基础上,使用潜变量建模法来开发一套通用的 "土壤智商测试"。我将土壤功能视为潜变量,因为它们是无法直接测量的复杂过程,我们只能检测这些复杂过程的驱动因素和结果。潜变量模型在社会、经济和心理测量领域有着悠久的历史,被称为因子分析。因子分析的目的是通过将可测量的反应变量在一个共同的尺度上联系起来,从而得出假设构造的共同描述符--因子。在此,我将解释为什么需要采用这种新方法来研究土壤多功能性和土壤健康,以及如何将其操作化。这里提出的框架只是一个初步建议,土壤多功能性问题过于复杂和重要,不可能一蹴而就。这个问题需要科学家们共同努力,反复解决。我们需要汇聚最优秀的科学力量,通力合作,逐步完善可持续管理人类最宝贵资源之一--土壤--的方法。
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引用次数: 0
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