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Soil erosion in Mediterranean olive groves: a review 地中海橄榄园土壤侵蚀研究进展
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-08-18 DOI: 10.5194/egusphere-2025-3542
Andres Peñuela, Filippo Milazzo, Emilio Jesús González-Sánchez
Abstract. Olive groves are a defining feature of the Mediterranean landscape, economy, and culture. However, this keystone agroecosystem is under severe threat from soil erosion, a problem exacerbated by the region's unique topographic, climatic conditions and agricultural practices. Although soil erosion in olive groves has been extensively studied, significant uncertainties remain due to the high variability of scales and measurement methods. Knowledge gaps persist regarding the average soil loss rates and runoff coefficients as well as the effects of different management approaches and the influence of triggering factors on soil erosion rates. So far, an effort to quantify this effect on Mediterranean olive cultivation has not been made comprehensively. Therefore, the aim of this literature review is to discern clearer patterns and trends that are often obscured by the overall heterogeneity of the available data. By systematically analysing the data according to measurement methodology, this review provides clear answers to these knowledge gaps and reveals a consistent narrative about the primary drivers of soil loss. While natural factors like topography, rainfall intensity and soil properties establish a baseline risk, this review shows that agricultural management, particularly the presence of groundcovers, is the pivotal factor controlling soil degradation. The long-standing debate on erosion severity is largely reconciled by the finding that reported rates are highly dependent on the measurement methodology, and hence on the spatial and temporal scale. Conservation practices consistently reduce soil loss by more than half, an effect far more pronounced for sediment control than for runoff reduction. Ultimately, the path to sustainability requires a shift away from conventional tillage and bare-soil management towards the widespread adoption of vegetation/groundcover, driven by effective policies and a commitment to multi-scale and multi-proxy research to improve predictive models.
摘要。橄榄林是地中海景观、经济和文化的标志性特征。然而,这一重要的农业生态系统正受到土壤侵蚀的严重威胁,该地区独特的地形、气候条件和农业实践加剧了这一问题。尽管对橄榄园的土壤侵蚀进行了广泛的研究,但由于尺度和测量方法的高度可变性,仍然存在显著的不确定性。关于平均土壤流失率和径流系数,以及不同管理方法的影响和触发因素对土壤侵蚀率的影响,知识差距仍然存在。到目前为止,还没有全面量化这种对地中海橄榄种植的影响。因此,本文献综述的目的是辨别更清晰的模式和趋势,这些模式和趋势往往被可用数据的整体异质性所掩盖。通过根据测量方法系统地分析数据,本综述为这些知识空白提供了明确的答案,并揭示了关于土壤流失主要驱动因素的一致叙述。虽然地形、降雨强度和土壤性质等自然因素确定了基线风险,但这一综述表明,农业管理,特别是地被植物的存在,是控制土壤退化的关键因素。关于侵蚀严重程度的长期争论在很大程度上得到了调和,因为报告的速率高度依赖于测量方法,因此依赖于空间和时间尺度。保护措施始终使土壤流失减少一半以上,控制泥沙的效果远比减少径流的效果明显。最终,可持续发展的道路需要从传统的耕作和裸土管理转向广泛采用植被/地被覆盖,这需要有效的政策和致力于多尺度和多代理研究来改进预测模型。
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引用次数: 0
Portable X-ray fluorescence as a tool for urban soil contamination analysis: accuracy, precision, and practicality 便携式x射线荧光作为城市土壤污染分析的工具:准确性、精密度和实用性
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-08-13 DOI: 10.5194/soil-11-565-2025
Eriell M. Jenkins, John Galbraith, Anna A. Paltseva
Abstract. Urban agriculture has become an essential component of urban sustainability, but it often faces the challenge of soil contamination with heavy metal(loid)s like lead (Pb), arsenic (As), chromium (Cr), copper (Cu), manganese (Mn), nickel (Ni), and zinc (Zn). Traditional laboratory methods for detecting these contaminants, such as atomic absorption spectroscopy and other inductively coupled plasma techniques, are accurate but can be costly and time-consuming and require extensive sample preparation. Portable X-ray fluorescence (PXRF) presents a promising alternative, offering rapid, in situ analysis with minimal sample preparation. The study reviews literature on PXRF analyzers to determine their accuracy and precision in analyzing heavy metal(loid)s in urban soils, with the goal of optimizing sampling, reducing laboratory costs and time, and identifying priority metal contamination hotspots. A literature review was conducted using Web of Science and Google Scholar, focusing on studies that validated PXRF measurements with alternate laboratory methods or certified reference materials (CRMs). This study reviews 84 publications to evaluate the accuracy and precision of PXRF in analyzing heavy metal(loid)s in urban soils. The review covers instrument types, action methods, testing conditions, and sample preparation techniques. Results show that, when properly calibrated, particularly with CRMs, PXRF can achieve reliable accuracy. Ex situ measurements tend to be more precise due to controlled conditions, although in situ measurements offer practical advantages in urban settings. Portable XRF emerges as a viable method for assessing urban soil contamination by balancing accuracy and practicality. Future research should focus on optimizing sample preparation and calibration to further enhance PXRF reliability in urban environments, ultimately strengthening PXRF methodologies and supporting extension efforts through improved, accessible soil-testing tools, facilitating healthier urban soils, safer urban food production, and enhanced community well-being.
摘要。都市农业已成为城市可持续发展的重要组成部分,但它经常面临土壤重金属污染的挑战,如铅(Pb)、砷(As)、铬(Cr)、铜(Cu)、锰(Mn)、镍(Ni)和锌(Zn)。检测这些污染物的传统实验室方法,如原子吸收光谱和其他电感耦合等离子体技术,是准确的,但可能是昂贵和耗时的,需要大量的样品制备。便携式x射线荧光(PXRF)提出了一个有前途的替代方案,提供快速,在原位分析与最少的样品制备。本研究综述了PXRF分析仪的相关文献,以确定其在分析城市土壤中重金属(样态)的准确性和精密度,以优化采样,降低实验室成本和时间,并确定优先的金属污染热点。通过Web of Science和谷歌Scholar进行了文献综述,重点研究了使用替代实验室方法或认证参考物质(crm)验证PXRF测量的研究。本文综述了84篇文献,评价了PXRF分析城市土壤重金属的准确性和精密度。审查内容包括仪器类型、操作方法、测试条件和样品制备技术。结果表明,当正确校准时,特别是使用crm, PXRF可以达到可靠的精度。尽管原位测量在城市环境中具有实际优势,但由于条件可控,非原位测量往往更精确。便携式XRF在平衡准确性和实用性方面成为一种可行的城市土壤污染评估方法。未来的研究应侧重于优化样品制备和校准,以进一步提高PXRF在城市环境中的可靠性,最终加强PXRF方法,并通过改进的、可获得的土壤检测工具支持推广工作,促进更健康的城市土壤,更安全的城市食品生产,增强社区福祉。
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引用次数: 0
Effect of trachyte and basalt rock powders on maize (Zea mays L.) growth and yield on Fluvisols in Cameroon’s Sudano-Sahelian zone (Central Africa) 粗粗纤维和玄武岩粉末对喀麦隆苏丹-萨赫勒地区玉米生长和Fluvisols产量的影响
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-08-08 DOI: 10.5194/egusphere-2025-3474
Bienvenu Sidsi, Claudine Vounba, Simon Djakba Basga, Aubin Nzeugang Nzeukou, Merlin Gountié Dedzo, Désiré Tsozué
Abstract. The Sudano-Sahelian zone of Cameroon, characterized by a low annual rainfall, faces challenges in soil fertility preservation due to agricultural intensification and unsustainable practices. This study aims to evaluate the effect of trachyte and basalt powders inputs on soil and maize yield in Guiring experimental farm. Fieldwork involved collecting and describing samples of trachyte, basalt, and soil and setting up the experimental design. In the laboratory, the ground rock samples underwent geochemical analysis, and the soil samples were analysed for their mineralogical and physicochemical properties. The experiment followed a completely randomized block design with six treatments (T0, T1, T2, T3, T4, and T5) and four replications. Growth and yield parameters of maize, include germination rate, plant height, number of leaves per plant, stem diameter, ear length, ear diameter, ear weight, 100-grain weight, and grain yield (kg ha-1). The soil consists of kaolinite, smectite, sepiolite, and quartz. Its texture is dominated by sand fraction, with a neutral pH (7.0). The organic matter (2.6±0.67 %) and total nitrogen contents (0.1±0.0 %) are relatively low. The concentrations of potassium, magnesium, sodium, and calcium are 0.2±0.1 cmolc kg-1, 2.5±1.6 cmolc kg-1, 0.3±0.2 cmolc kg-1, and 3.9±1.5 cmolc kg-1, respectively. The cation exchange capacity is moderate to high (22.1±2.5 cmolc kg-1), while the available phosphorus content is high (19±7.0 mg kg-1). This soil is classified as Ochric Dystric Fluvisols according to the WRB. These soil characteristics are moderately suitable for maize cultivation. Fertilization trials showed a significant improvement in maize growth and yield, within plots treated with basalt powder yielding higher (2558.6 kg ha-1 and 2931.2 kg ha-1) than those treated with trachyte powder (2362.9 kg ha-1 and 2763.9 kg ha-1) and the control plots (645.8 kg ha-1). Plots treated with NPK fertilizer recorded the highest yield (3164.5 kg ha-1). Although the treatment with conventional fertiliser resulted in a relative higher yield, the advantage of using rock powders lies in their environmental benefits, long-term effectiveness, and more affordable cost.
摘要。喀麦隆的苏丹-萨赫勒地区的特点是年降雨量少,由于农业集约化和不可持续的做法,在土壤肥力保持方面面临挑战。本研究旨在评价粗叶菌粉和玄武岩粉投入量对桂陵试验田土壤和玉米产量的影响。野外工作包括收集和描述粗面岩、玄武岩和土壤样品,并建立实验设计。在实验室中,对地面岩石样品进行了地球化学分析,对土壤样品进行了矿物学和理化性质分析。试验采用完全随机区组设计,6个处理(T0、T1、T2、T3、T4和T5), 4个重复。玉米的生长和产量参数包括发芽率、株高、单株叶数、茎粗、穗长、穗粗、穗重、百粒重和籽粒产量(kg hm -1)。土壤由高岭石、蒙脱石、海泡石和石英组成。其质地以砂粒为主,pH为中性(7.0)。有机质含量(2.6±0.67%)和全氮含量(0.1±0.0%)较低。钾、镁、钠、钙的浓度分别为0.2±0.1 cmolc kg-1、2.5±1.6 cmolc kg-1、0.3±0.2 cmolc kg-1和3.9±1.5 cmolc kg-1。阳离子交换容量中高(22.1±2.5 cmolc kg-1),有效磷含量高(19±7.0 mg kg-1)。根据世界自然保护区的规定,这种土壤被归类为奥克利奇Dystric fluvisol。这些土壤特性适合种植玉米。施肥试验显示,玄武岩粉处理的玉米产量(2558.6 kg ha-1和2931.2 kg ha-1)显著高于粗叶菌粉处理(2362.9 kg ha-1和2763.9 kg ha-1)和对照(645.8 kg ha-1)。施用氮磷钾的地块产量最高(3164.5 kg hm -1)。虽然用常规肥料处理导致相对较高的产量,但使用岩石粉的优势在于其环境效益,长期有效性和更实惠的成本。
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引用次数: 0
Assessing the potential of complex artificial neural networks for modelling small-scale soil erosion by water 评估复杂人工神经网络模拟小规模水土流失的潜力
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-08-08 DOI: 10.5194/egusphere-2025-3583
Nils Barthel, Simone Ott, Benjamin Burkhard, Bastian Steinhoff-Knopp
Abstract. Accurately modelling soil erosion by water is essential for developing effective mitigation strategies and preventing on- and off-site damages in agricultural areas. So far, complex artificial neural networks have rarely been applied in small-scale soil erosion modelling, and their potential still remains unclear. This study compares the performance of different neural network architectures for modelling soil erosion by water at a small spatial scale in agricultural cropland. The analysis is based on erosion rate data at a 5 m × 5 m resolution, derived from a 20-year monitoring programme, and covers 458 hectares of cropland across six investigation areas in northern Germany. Nineteen predictor variables related to topography, climate, management and soil properties were selected as inputs to assess their interrelationships with observed erosion patterns and to predict continuous soil erosion rates. A single-layer neural network (SNN), a deep neural network (DNN), and a convolutional neural network (CNN) were applied and evaluated against a random forest (RF) model used as a benchmark. All machine learning models have successfully captured spatial patterns of soil erosion, with the CNN consistently outperforming the others across all evaluation metrics. The CNN achieves the lowest root mean squared error (RMSE: 1.05) and mean absolute error (MAE: 0.41), outperforming the RF (RMSE: 1.31, MAE: 0.58) and the SNN (RMSE: 1.48, MAE: 0.63), while the DNN performs similarly to the CNN with a slightly higher RMSE (1.1) and MAE (0.45). The CNN notably outperforms the other three approaches when evaluating their capability to accurately predict soil erosion within given classes, achieving a weighted mean F1 score of 0.7. A permutation importance analysis identified the digital elevation model as the most influential predictor variable across all models, contributing between 15 % and 18.3 %, while USLE C and R factors also had significant importance. Overall, these findings highlight the potential of complex neural networks for predicting spatially explicit rates of soil erosion by water.
摘要。水对土壤侵蚀的准确模拟对于制定有效的缓解战略和防止农业地区的现场和场外损害至关重要。到目前为止,复杂的人工神经网络在小尺度土壤侵蚀模型中的应用很少,其潜力仍不明朗。本研究比较了不同神经网络架构在农田小空间尺度上的水土流失模拟的性能。该分析基于5米× 5米分辨率的侵蚀率数据,来自一个20年的监测项目,覆盖了德国北部6个调查区域的458公顷农田。与地形、气候、管理和土壤性质相关的19个预测变量被选择作为输入,以评估它们与观测到的侵蚀模式的相互关系,并预测持续的土壤侵蚀率。应用单层神经网络(SNN)、深度神经网络(DNN)和卷积神经网络(CNN),并对随机森林(RF)模型作为基准进行评估。所有机器学习模型都成功捕获了土壤侵蚀的空间模式,CNN在所有评估指标上的表现都优于其他模型。CNN实现了最低的均方根误差(RMSE: 1.05)和平均绝对误差(MAE: 0.41),优于RF (RMSE: 1.31, MAE: 0.58)和SNN (RMSE: 1.48, MAE: 0.63),而DNN的表现与CNN相似,RMSE(1.1)和MAE(0.45)略高。CNN在评估其准确预测给定类别内土壤侵蚀的能力时,明显优于其他三种方法,其加权平均F1得分为0.7。排列重要性分析表明,数字高程模型是所有模型中最具影响力的预测变量,贡献率在15%至18.3%之间,而USLE C和R因素也具有显著的重要性。总的来说,这些发现突出了复杂神经网络在预测空间明确的水土流失速率方面的潜力。
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引用次数: 0
Soil stoichiometric characteristics and influencing factors in karst forests under micro-topography and microhabitat scales 微地形和微生境尺度下喀斯特森林土壤化学计量特征及其影响因素
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-07-29 DOI: 10.5194/egusphere-2025-3510
Yi Dang, Hua Zhou, Wenjun Zhao, Yingchun Cui, Chengjiang Tan, Fangjun Ding, Yukun Wang, Run Liu, Peng Wu
Abstract. To quantitatively evaluate the stoichiometric characteristics of karst forest soils and their response mechanisms to complex microenvironments, the study systematically investigated soil stoichiometric traits and influencing factors across micro-topography and microhabitat scales in the Maolan karst forest. Key findings include: (1) Soil nutrients (organic carbon, total nitrogen, hydrolyzable nitrogen, available phosphorus, available potassium, total calcium, exchangeable calcium, and exchangeable magnesium) exhibited strong variability with significant spatial heterogeneity; (2) Microhabitat factors significantly influenced nutrient accumulation, though different elements showed distinct response patterns to microhabitat variations; (3) Micro-topographic parameters (slope gradient, aspect, and position) exerted indirect effects through gravity, light exposure, and erosion, driving the formation of gradient patterns in soil stoichiometry; (4) Differential response mechanisms of nutrients to abiotic factors, combined with the differential nutrient regulation and absorption strategies of various plant life forms, collectively shaped the complex stoichiometric characteristics. Synergistic interactions were observed among microhabitat-micro-topography-plant life form factors, with geomorphological abiotic factors playing predominant roles at this scale. Although biotic factors like plant life forms showed relatively weaker direct influences, their regulatory effects were closely interrelated with microhabitat-topographic factors. This multi-dimensional feedback mechanism between biotic and abiotic factors reflects the complexity of nutrient cycling in karst ecosystems.
摘要。为了定量评价喀斯特森林土壤的化学计量特征及其对复杂微环境的响应机制,本研究系统地研究了毛兰喀斯特森林不同微地形和微生境尺度下土壤化学计量特征及其影响因素。主要发现包括:(1)土壤养分(有机碳、全氮、水解氮、速效磷、速效钾、全钙、交换性钙和交换性镁)表现出较强的变异性,且空间异质性显著;(2)微生境因子对养分积累有显著影响,但不同因子对微生境变化的响应模式不同;(3)微地形参数(坡度、坡向和位置)通过重力、光照和侵蚀等间接影响,驱动土壤化学计量梯度格局的形成;(4)营养物质对非生物因子的不同响应机制,加上各种植物生命形式的不同营养调节和吸收策略,共同形成了复杂的化学计量特征。微生境-微地形-植物生命形态因子之间存在协同作用,其中地貌非生物因子在微生境-微地形-植物生命形态因子中起主导作用。虽然植物生命形态等生物因子的直接影响相对较弱,但其调控作用与微生境地形因子密切相关。这种生物因子与非生物因子之间的多维反馈机制反映了喀斯特生态系统养分循环的复杂性。
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引用次数: 0
Mineral-bound organic carbon exposed by hillslope thermokarst terrain: case study in Cape Bounty, Canadian High Arctic 由山坡热岩溶地形暴露的矿物结合有机碳:加拿大高北极邦蒂角的案例研究
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-07-22 DOI: 10.5194/egusphere-2025-3428
Maxime Thomas, Julien Fouché, Hugues Titeux, Charlotte Morelle, Nathan Bemelmans, Melissa J. Lafrenière, Joanne K. Heslop, Sophie Opfergelt
Abstract. Arctic landscapes could add 55–230 Pg of carbon (in CO2 equivalent) to the atmosphere, through CO2 and CH4 emissions, by the end of this century. These estimates could be quantified more accurately by constraining the contribution of rapid thawing processes such as thermokarst landscapes to permafrost carbon loss, and by investigating the exposed organic carbon (OC) interacting with mineral surfaces or metallic cations, i.e., the nature of these interactions and what controls their relative abundance. Here, we investigate two contrasted types of hillslope thermokarst landscapes: an Active Layer Detachment (ALD) which is a one-time event, and a Retrogressive Thaw Slump (RTS) which repeats annually during summer months in the Cape Bounty Arctic Watershed Observatory (Melville Island, Canada). We analyzed mineralogy, total and soluble element concentrations, total OC and mineral-OC interactions within the headwalls of both disturbances, and within corresponding undisturbed profiles. Our results show that OC stabilized by chemical bonds account for 13 ± 5 % of total OC in the form of organo-metallic complexes and up to 6 ± 2 % associated with poorly crystalline iron oxides. If we add the mechanisms of physical protection of particulate organic matter in aggregates and larger molecules stabilized by chemical bonds, we reach 64 ± 10 % of the total OC being stabilized. Importantly, we observe a decrease in the proportion of mineral-bound OC in the deeper layers exposed by the retrogressive thaw slump: the proportion of organo-metallic complexes drops from ~18 % in surface samples to ~1 % in the deepest samples. These results therefore suggest that the OC exposed by thermokarst disturbances at Cape Bounty is protected by interactions with minerals to a certain extent, but that deep thaw features could expose OC more readily accessible to degradation.
摘要。到本世纪末,北极景观可能会通过二氧化碳和甲烷的排放向大气中增加55 - 230pg的碳(二氧化碳当量)。通过限制快速融化过程(如热岩溶景观)对永久冻土碳损失的贡献,以及通过调查暴露的有机碳(OC)与矿物表面或金属阳离子的相互作用,即这些相互作用的性质以及控制它们相对丰度的因素,可以更准确地量化这些估计。在这里,我们研究了两种不同类型的山坡热岩溶景观:一次活动层剥离(ALD),这是一个一次性事件,以及每年夏季在邦蒂角北极分水岭观测站(加拿大梅尔维尔岛)重复发生的退行性融化滑坡(RTS)。我们分析了矿物学、总和可溶性元素浓度、总有机碳和矿物-有机碳相互作用,这些都发生在两种干扰的顶壁和相应的未受干扰的剖面中。我们的研究结果表明,化学键稳定的有机碳以有机金属配合物的形式占总有机碳的13±5%,高达6±2%的有机碳与结晶性差的氧化铁有关。如果加上聚集体和化学键稳定的大分子颗粒有机质的物理保护机制,我们可以达到总OC的64±10%。重要的是,我们观察到,在后退性融化滑坡暴露的较深层中,矿物结合OC的比例有所下降:有机金属配合物的比例从表层样品的~ 18%下降到最深处样品的~ 1%。因此,这些结果表明,在热岩溶扰动下暴露的OC在一定程度上受到矿物相互作用的保护,但深度解冻特征可能使OC更容易暴露于退化。
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引用次数: 0
Using Monte Carlo conformal prediction to evaluate the uncertainty of deep-learning soil spectral models 用蒙特卡罗保形预测方法评价深度学习土壤光谱模型的不确定性
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-07-22 DOI: 10.5194/soil-11-553-2025
Yin-Chung Huang, José Padarian, Budiman Minasny, Alex B. McBratney
Abstract. Uncertainty quantification is a crucial step in the practical application of soil spectral models, particularly in supporting real-world decision making and risk assessment. While machine learning has made remarkable strides in predicting various physiochemical properties of soils using spectroscopy, its practical utility in decision making remains limited without quantified uncertainty. Despite its importance, uncertainty quantification is rarely incorporated into soil spectral models, with existing methods facing significant limitations. Existing methods are either computationally demanding, fail to achieve the desired coverage of observed data, or struggle to handle out-of-domain uncertainty. This study introduces an innovative application of Monte Carlo conformal prediction (MC-CP) to quantify uncertainty in deep-learning models for predicting clay content from mid-infrared spectroscopy. We compared MC-CP with two established methods: (1) Monte Carlo dropout and (2) conformal prediction. Monte Carlo dropout generates prediction intervals for each sample and can address larger uncertainties associated with out-of-domain data. Conformal prediction, on the other hand, guarantees ideal coverage of true values but generates unnecessarily wide prediction intervals, making it overly conservative for many practical applications. Using 39 177 samples from the mid-infrared spectral library of the Kellogg Soil Survey Laboratory to build convolutional neural networks, we found that Monte Carlo dropout itself falls short in achieving the desired coverage – its 90 % prediction intervals only covered the observed values in 74 % of the cases, well below the expected 90 % coverage. In contrast, MC-CP successfully combines the strengths of both methods. It achieved a prediction interval coverage probability of 91 %, closely matching the expected 90 % coverage and far surpassing the performance of the Monte Carlo dropout. Additionally, the mean prediction interval width for MC-CP was 9.05 %, narrower than the conformal prediction's 11.11 %. The success of MC-CP enhances the real-world applicability of soil spectral models, paving the way for their integration into large-scale machine learning models, such as soil inference systems, and further transforming decision making and risk assessment in soil science.
摘要。在土壤光谱模型的实际应用中,特别是在支持现实世界的决策和风险评估方面,不确定性量化是至关重要的一步。虽然机器学习在利用光谱预测土壤的各种理化性质方面取得了显着进步,但它在决策中的实际效用仍然有限,没有量化的不确定性。尽管不确定度量化很重要,但很少将其纳入土壤光谱模型,现有方法存在很大的局限性。现有的方法要么计算量大,要么无法实现观测数据的预期覆盖,要么难以处理域外的不确定性。本研究介绍了蒙特卡罗共形预测(MC-CP)的创新应用,以量化中红外光谱预测粘土含量的深度学习模型中的不确定性。我们将MC-CP与两种已建立的方法(1)Monte Carlo dropout和(2)适形预测进行了比较。蒙特卡罗dropout为每个样本生成预测区间,并且可以处理与域外数据相关的更大的不确定性。另一方面,保形预测保证了真值的理想覆盖,但产生了不必要的宽预测区间,使其在许多实际应用中过于保守。使用来自凯洛格土壤调查实验室中红外光谱库的39177个样本来构建卷积神经网络,我们发现蒙特卡罗dropout本身无法达到期望的覆盖率-其90%的预测区间仅覆盖了74%的情况下的观测值,远低于预期的90%覆盖率。相比之下,MC-CP成功地结合了两种方法的优势。它实现了91%的预测区间覆盖概率,与预期的90%覆盖率非常接近,远远超过了蒙特卡洛dropout的性能。MC-CP的平均预测区间宽度为9.05%,比适形预测的11.11%窄。MC-CP的成功增强了土壤光谱模型在现实世界中的适用性,为将其集成到土壤推理系统等大规模机器学习模型中铺平了道路,并进一步改变了土壤科学的决策和风险评估。
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引用次数: 0
Restorative Mitigation of Contaminated Soil for Ecosystem Services: Influences from Research Enterprise and Sustainable Development Goals 土壤污染恢复性缓解对生态系统服务的影响:来自研究企业和可持续发展目标的影响
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-07-17 DOI: 10.5194/egusphere-2025-271
Isak Rajjak Shaikh, Parveen Rajjak Shaikh
Abstract. Soil is a vital component of the ecosystem, as it provides nutrients needed for the growth of plants and supports all terrestrial life on the planet. The global agricultural sector underwent enormous change after the World Wars, thanks to some important developments in technology transfer that saw increased crop production during the Green Revolution of the 1960s; the initiatives included the use of high yielding variety seeds and also the application of synthetic agrochemicals as nutrient inputs and crop protection agents. This was meant secure food grains for growing human population. Despite all the achievements, the initiatives taken during the Green Revolution are meeting with some harsh criticism now. Soil is under constant pressure due to irresponsible land use and resource exploitation, erosion, escalating climate change, and also the indiscriminate usage of synthetic pesticides and fertilizers. Synthetic pesticides are contaminating soil, and the contaminants are making serious alterations to the content and most importantly to the chemical quality, properties and functions of soil, requiring an immediate risk assessment owing to the hazard and scientific uncertainty surrounding it. Soil pollution is one of the most serious concerns of our time, which not only limits the sustainability of community livelihood but also compromises ecosystem services, causing depletion in its fertility and risks to the environmental and human health. So, the environmentalists, economists, and social scientists have begun advocating more organic amendments to farming and restoration of ecosystems services of soil. Researchers explore physico-chemical and biological methods to mitigate the soil contamination. Research enterprise, local policy making, and globalized discourses on environment at the highest decision-making authority of intergovernmental organizations are being directed towards sustainable future of socio-ecological system.
摘要。土壤是生态系统的重要组成部分,因为它提供植物生长所需的养分,并支持地球上所有的陆地生命。全球农业部门在第二次世界大战之后经历了巨大的变化,这要归功于20世纪60年代绿色革命期间技术转让方面的一些重要发展,这些发展增加了作物产量;这些倡议包括使用高产品种的种子,以及使用合成农用化学品作为营养投入和作物保护剂。这意味着为不断增长的人口提供安全的粮食。尽管取得了所有的成就,但绿色革命期间采取的举措现在遭到了一些严厉的批评。由于不负责任的土地利用和资源开发、侵蚀、不断加剧的气候变化以及滥用合成农药和化肥,土壤面临着持续的压力。合成农药正在污染土壤,这些污染物正在严重改变土壤的含量,最重要的是改变土壤的化学质量、性质和功能,由于其危害和科学上的不确定性,需要立即进行风险评估。土壤污染是我们这个时代最严重的问题之一,它不仅限制了社区生计的可持续性,而且损害了生态系统服务,导致其肥力枯竭,并对环境和人类健康构成风险。因此,环保主义者、经济学家和社会科学家开始提倡对农业进行更多的有机修正,并恢复土壤的生态系统服务。研究人员探索了物理化学和生物方法来减轻土壤污染。政府间组织最高决策权的环境研究事业、地方政策制定和全球化话语正朝着社会生态系统可持续未来的方向发展。
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引用次数: 0
Interplay of coprecipitation and adsorption processes: deciphering amorphous mineral–organic associations under both forest and cropland conditions 共沉淀和吸附过程的相互作用:在森林和农田条件下解读无定形矿物-有机结合
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-07-17 DOI: 10.5194/soil-11-535-2025
Floriane Jamoteau, Emmanuel Doelsch, Nithavong Cam, Clément Levard, Thierry Woignier, Adrien Boulineau, Francois Saint-Antonin, Sufal Swaraj, Ghislain Gassier, Adrien Duvivier, Daniel Borschneck, Marie-Laure Pons, Perrine Chaurand, Vladimir Vidal, Nicolas Brouilly, Isabelle Basile-Doelsch
Abstract. Mineral–organic associations are crucial carbon and nutrient reservoirs in soils. However, conversion from forest to agricultural systems disrupts these associations, leading to carbon loss and reduced soil fertility in croplands. Identifying the types of mineral–organic associations within a single soil is already challenging, and detecting those susceptible to disruption during forest-to-crop conversion is even more complex. Yet, addressing this identification challenge is essential for devising strategies to preserve organic matter in croplands. Here, we aimed to identify the predominant mineral–organic associations within an Andosol (developed on Fe-poor parent material) under both forest and cropland conditions. To achieve this, we collected Andosol samples from both a forested and a cultivated area, located 300 m apart. We then analyzed differences between the two soil profiles in soil physicochemical parameters and characterized mineral–organic associations using an array of spectro-microscopic techniques for comprehensive structural and compositional analysis. At microscale and nanoscale spatial resolution, we observed mineral–organic associations in the form of amorphous coprecipitates, composed of a mix of C+Al+Si and C+Al+Fe+Si nanoCLICs (inorganic oligomers with organics), proto-imogolites and organic matter, some Fe nanophases associated with organic matter, and some metal–organic complexes. This challenges prior conceptions of mineral–organic associations in Andosols by demonstrating the presence of amorphous coprecipitates rather than solely organic matter associated with short-range-order minerals (i.e., imogolite and allophanes). Moreover, chemical mappings suggested that these amorphous coprecipitates may adhere to mineral surfaces (i.e., phyllosilicates and imogolites), revealing secondary interactions of mineral–organic associations in soils. While the presence of similar amorphous coprecipitates in both the forest and crop Andosols was confirmed, the crop soil had 75 % less C in mineral–organic associations (in the 0–30 cm depth). Although the sample size for comparing land use types is limited, these results suggest that the nature of mineral–organic associations remains identical despite quantitative differences. This study highlights the crucial role of amorphous coprecipitates in C stabilization in Andosols and also suggests their vulnerability to disruption after 30 years of a forest-to-crop conversion, thereby challenging our understanding of the persistence of mineral–organic associations in Andosols.
摘要。矿物-有机组合是土壤中重要的碳和养分储存库。然而,从森林向农业系统的转变破坏了这些联系,导致碳损失和农田土壤肥力下降。在单一土壤中识别矿物-有机联系的类型已经具有挑战性,而在森林向作物转化过程中检测易受破坏的类型则更加复杂。然而,解决这一识别挑战对于制定保护农田有机质的策略至关重要。在这里,我们旨在确定在森林和农田条件下Andosol(在贫铁母质上发育)中主要的矿物-有机组合。为了实现这一目标,我们从相隔300米的森林和耕地地区收集了安多酚样本。然后,我们分析了两种土壤剖面在土壤物理化学参数上的差异,并利用一系列光谱显微镜技术进行了全面的结构和成分分析,表征了矿物-有机组合。在微尺度和纳米尺度的空间分辨率下,我们观察到矿物-有机结合以无定形共沉淀的形式存在,由C+Al+Si和C+Al+Fe+Si纳米相(无机低聚物与有机物)、原铁长石和有机物、一些与有机物相关的铁纳米相以及一些金属-有机配合物组成。这一发现挑战了之前关于安多岩中矿物-有机结合的概念,证明了无定形共沉淀物的存在,而不仅仅是与短程矿物(即伊莫长石和allophanes)相关的有机物质。此外,化学映射表明,这些无定形共沉淀可能粘附在矿物表面(即层状硅酸盐和伊莫长石),揭示了土壤中矿物-有机结合的二次相互作用。虽然在森林和作物土壤中都存在类似的无定形共沉淀,但作物土壤在矿物-有机组合中(0-30 cm深度)的碳含量少75%。虽然用于比较土地利用类型的样本量有限,但这些结果表明,尽管数量上存在差异,但矿物-有机组合的性质仍然相同。这项研究强调了无定形共沉淀在安土中碳稳定中的关键作用,也表明它们在30年的森林向作物转化后容易受到破坏,从而挑战了我们对安土中矿物-有机结合持久性的理解。
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引用次数: 0
Drivers and CO2 flux budgets in a Sahelian Faidherbia albida agro-silvo-pastoral parkland: Insights from continuous high-frequency soil chamber measurements and Eddy Covariance 萨赫勒地区大绿农林牧区的驱动因素和CO2通量预算:来自连续高频土壤室测量和涡旋相关方差的见解
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-07-16 DOI: 10.5194/egusphere-2025-2660
Seydina Mohamad Ba, Olivier Roupsard, Lydie Chapuis-Lardy, Frédéric Bouvery, Yélognissè Agbohessou, Maxime Duthoit, Aleksander Wieckowski, Torbern Tagesson, Mohamed Habibou Assouma, Espoir Koudjo Gaglo, Claire Delon, Bienvenu Sambou, Dominique Serça
Abstract. Agroforestry systems — combining trees with crops and/or livestock — are increasingly promoted as sustainable and climate-resilient land-use strategies. Despite their widespread presence in the Sahel, experimental data on their potential as carbon sinks are scarce. This study presents a full-year, high-frequency dataset of CO2 fluxes in a Sahelian agro-silvo-pastoral parkland dominated by F. albida, located in Senegal’s groundnut basin. CO2 fluxes were continuously measured using automated static chambers, allowing the quantification of soil and crop respiration (Rch), gross primary production (GPPch), and net carbon exchange (FCO2ch) under both full sun and shaded (under tree canopies) environments. Seasonal patterns of CO2 fluxes were similar in both environments, with peaks during the rainy season. Rch and GPPch were significantly higher under tree canopies, indicating a ‘fertile island’ effect. CO2 flux variability was primarily driven by soil moisture and leaf area index. Chamber-based GPP estimates closely matched those from Eddy Covariance measurements. On an annual scale, F. albida trees contributed approximately 50 % of total ecosystem GPP, with a carbon use efficiency of 0.48. Net annual CO2 exchange was estimated at −1.4 ± 0.02 and −1.8 ± 0.01 Mg C-CO2 ha⁻¹ using chamber and Eddy Covariance methods, respectively. These findings underscore the role of F. albida-based agroforestry systems as effective carbon sinks in Sahelian landscapes, supporting their potential contribution to climate change mitigation.
摘要。农林复合系统——将树木与作物和/或牲畜结合起来——作为可持续和适应气候变化的土地利用战略日益得到推广。尽管它们在萨赫勒地区广泛存在,但关于它们作为碳汇潜力的实验数据却很少。本研究提出了一个位于塞内加尔花生盆地的萨赫勒地区以albida为主导的农林业-牧区公园的全年高频二氧化碳通量数据集。使用自动化静态室连续测量CO2通量,从而可以在完全阳光和遮荫(树冠下)环境下量化土壤和作物呼吸(Rch)、总初级生产量(GPPch)和净碳交换(FCO2ch)。两种环境中CO2通量的季节模式相似,在雨季达到峰值。Rch和GPPch在树冠下显著较高,表明存在“肥沃岛”效应。CO2通量变异主要受土壤湿度和叶面积指数驱动。基于腔室的GPP估计与涡流协方差测量结果非常吻合。在年尺度上,杉木对生态系统总GPP的贡献约为50%,碳利用效率为0.48。使用室内法和涡流相关法估计,年二氧化碳净交换量分别为- 1.4±0.02和- 1.8±0.01 Mg C-CO2 ha(⁻¹)。这些发现强调了以云杉为基础的农林业系统在萨赫勒地区景观中作为有效碳汇的作用,支持了它们对减缓气候变化的潜在贡献。
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