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Circular economy approach in phosphorus fertilization based on vivianite must be tailored to soil properties 循环经济的磷肥施用方法必须根据土壤特性进行调整
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-06-03 DOI: 10.5194/egusphere-2025-1460
Tolulope Ayeyemi, Ramiro Recena, Ana María García-López, José Manuel Quintero, María Carmen del Campillo, Antonio Delgado
Abstract. Although there is relevant knowledge based on the effect of soil properties on the efficiency of common commercial fertilizers, this effect remains poorly understood for the use of vivianite from water purification as an innovative P fertilizer meeting a circular economy approach. This study aimed to evaluate the effect of soil properties on the efficiency of vivianite recovered from water purification as a P fertilizer and to provide practical recommendations for its effective use. Vivianite and a soluble mineral P fertilizer (superphosphate) were compared at two P application rates (50 and 100 mg P kg–1) in soils ranging widely in properties in a pot experiment using wheat. Soluble P fertilizer provided the best results in terms of dry matter (DM) yield, P uptake, and Olsen P in soils, while vivianite led to the best results of DTPA extractable Fe in soils after crop harvest. The application of vivianite as a P fertilizer was more efficient in acidic soils (pH < 6.6). The effect of vivianite on dry matter (DM) yield was equivalent on average to 26 or 40 %, depending on the rate, of the same amount of soluble fertilizer in these acidic soils (i.e., P fertilizer replacement value –PFRV– on DM basis), it being around 50 % in some cases. The effect on Olsen P in soil was equivalent, on average, to 49 or 61 %, depending on the rate, of the same amount applied as soluble mineral fertilizer in acidic soils. This can be explained by the increased solubility of this fertilizer product under acidic conditions, supported by the highest increase in DTPA extractable Fe in these soils. Acidic soils were those with initial Olsen P below the threshold value for fertilizer response (TV). However, PFRV on different approaches (DM, P uptake, and Olsen P) decreased more consistently with increased values of the difference between initial Olsen P and TV (46 to 87 % of the variance explained) than with increased pH. This reveals that besides soil pH, a low P availability to plants can trigger plant and microbial mobilization mechanisms, leading to increased efficiency of vivianite as a P fertilizer. Further studies are needed to assess the residual effect of vivianite and its effectiveness under field conditions, particularly in soils with low P availability status and an acidic pH.
摘要。虽然有相关的知识是基于土壤性质对普通商业肥料效率的影响,但这种影响对于使用净水中的活菌石作为符合循环经济方法的创新磷肥仍然知之甚少。本研究旨在评价土壤性质对水净化回收的橄榄石作为磷肥效率的影响,并为其有效利用提供实用建议。通过盆栽小麦试验,比较了两种施磷量(50 mg和100 mg P kg-1)下的Vivianite和可溶性无机磷肥(过磷酸磷)在不同性状土壤上的差异。在土壤干物质产量、磷素吸收和奥尔森磷方面,可溶性磷肥的效果最好,而在作物收获后,有机磷在土壤中可提取铁的效果最好。在酸性土壤(pH <;6.6)。在这些酸性土壤中,根据相同数量的可溶性肥料(即P肥替代值- pfrv -以DM为基础)的施用量,vivianite对干物质(DM)产量的影响平均相当于26%或40%,在某些情况下约为50%。对土壤中奥尔森磷的影响平均相当于在酸性土壤中施用相同数量的可溶性矿物肥的49%或61%,具体取决于施用量。这可以解释为这种肥料产品在酸性条件下的溶解度增加,在这些土壤中DTPA可提取铁的增幅最大。酸性土壤是指初始奥尔森磷低于肥料响应阈值的土壤。然而,不同处理方法(DM、P吸收和Olsen P)的PFRV随着初始Olsen P和TV差异值的增加而下降(占解释方差的46%至87%),而不是随着pH值的增加而下降。这表明,除了土壤pH值,植物的低磷可利用性可以触发植物和微生物的动员机制,从而提高了vivianite作为P肥的效率。需要进一步的研究来评估橄榄石的残留效应及其在田间条件下的有效性,特别是在低磷有效状态和酸性土壤中。
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引用次数: 0
Soil contamination in arid environments and assessment of remediation applying surface evaporation capacitor model: a case study from the Judean Desert, Israel 干旱环境下土壤污染及其表面蒸发电容模型的修复评价——以以色列朱迪亚沙漠为例
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-06-03 DOI: 10.5194/soil-11-395-2025
Rotem Golan, Ittai Gavrieli, Roee Katzir, Galit Sharabi, Uri Nachshon
Abstract. Due to the presence of highly pollutant industries in arid areas, many of the globe's arid areas are exposed to severe local soil contamination events. In this work, the nature of solute and contaminant transport in the sandy terraces of an ephemeral stream that was exposed to a severe pollution event was examined. Here, the Ashalim Basin in the Judean Desert, Israel, is utilized as a case study. In order to shed new light on contaminant distribution along the soil profile and on transport mechanisms in arid environments, three complementary approaches were used: (1) periodic on-site soil profile sampling, recording the annual solute transport dynamics; (2) laboratory analyses and controlled experiments in a rain simulator to characterize solute release and transport; and (3) numerical simulation, used to define and understand the main associated processes. The study highlights the persistent nature of the pollutants in these natural settings, which dictates that they remain near the soil surface despite the presence of sporadic rain events. It was shown that a vertical circulation of the contaminates is occurring with soil wetting and drying cycles. The “surface evaporation capacitor” concept of Or and Lehmann (2019) was examined and compared to field measurements and numerical simulations and was found to be a useful tool for predicting the fate of the contaminants along the soil profile.
摘要。由于干旱地区高污染工业的存在,全球许多干旱地区都面临着严重的局部土壤污染事件。在这项工作中,研究了暴露于严重污染事件的短暂溪流的沙质阶地中溶质和污染物运输的性质。这里,以以色列犹太沙漠的阿沙利姆盆地为例进行研究。为了进一步揭示干旱环境中污染物沿土壤剖面分布和运移机制,采用了三种互补的方法:(1)定期现场土壤剖面采样,记录每年的溶质运移动态;(2)在模拟雨中进行室内分析和控制实验,以表征溶质释放和运移;(3)数值模拟,用于定义和理解主要的相关过程。该研究强调了这些自然环境中污染物的持久性,这表明尽管存在零星降雨事件,它们仍保持在土壤表面附近。结果表明,随着土壤干湿循环,污染物呈垂直循环。对Or和Lehmann(2019)的“表面蒸发电容器”概念进行了研究,并与现场测量和数值模拟进行了比较,发现它是预测土壤剖面中污染物命运的有用工具。
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引用次数: 0
Limited effect of organic matter addition on stabilised organic carbon in four tropical arable soils 添加有机质对4种热带耕地土壤稳定有机碳的有限影响
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-05-30 DOI: 10.5194/egusphere-2025-2287
Marijn Van de Broek, Fiona Stewart-Smith, Moritz Laub, Marc Corbeels, Monicah Wanjiku Mucheru-Muna, Daniel Mugendi, Wycliffe Waswa, Bernard Vanlauwe, Johan Six
Abstract. Arable soils are generally characterised by a low soil organic carbon (SOC) content, with negative consequences for soil health, crop yield and global climate. Thus, over the past decades, there has been a focus on how agricultural management practices, such as organic resource addition, can increase the amount of SOC. To sustainably increase SOC stocks, a portion of the organic amendments added to the soil has to be stabilised in persistent fractions such as mineral-associated organic carbon (MAOC). However, there is a lack of research on the magnitude of changes in MAOC in tropical agroecosystems in response to organic resource additions. Here, we show for four long-term field trials in Kenya that the addition of large amounts of organic amendments (farmyard manure or Tithonia diversifolia biomass at 4 t C ha-1 yr-1 for 16 to 19 years) to maize monocropping systems had variable effects on topsoil MAOC stocks (0–15 cm depth), and no significant effect on subsoil MAOC stocks (15–50 cm depth) compared to a control treatment. The addition of mineral N fertiliser did not affect MAOC stocks at any site. Using stable carbon isotopes δ13C, we found that the portion of topsoil MAOC originating from Tithonia biomass was larger in the sandy (25–40 %) compared to the clayey soils (0.5–12 %), while the portion of total added Tithonia biomass that was stabilised over a time period of 16–19 years was below 7 % across all sites, or a SOC stabilisation rate of 0.8–27 g C m-2 yr-1. Using these results, we conclude that while in sandy soils the stabilisation of added OC contributed substantially to limiting SOC losses upon cultivation, this was not the case for clayey soils. These differences were due to the much lower SOC stocks in the sandy soils, compared to the clayey soils. Our results underline the challenges associated with improving soil health in sub-Saharan Africa and stress the need for more research to reliably assess if and how additional SOC can be stabilised over decadal time scales in highly weathered tropical soils.
摘要。耕地土壤通常具有土壤有机碳(SOC)含量低的特点,这对土壤健康、作物产量和全球气候都有负面影响。因此,在过去的几十年里,人们一直关注农业管理实践,如有机资源添加,如何增加有机碳的数量。为了可持续地增加有机碳储量,添加到土壤中的一部分有机改进剂必须稳定在持久性组分中,如矿物相关有机碳(MAOC)。然而,缺乏对热带农业生态系统中MAOC随有机资源添加而变化幅度的研究。在这里,我们在肯尼亚进行了四个长期的田间试验,结果表明,与对照处理相比,在玉米单作系统中添加大量的有机改良剂(农家肥或Tithonia多样性生物量,每公顷4吨,每年1年,持续16至19年)对表层土壤MAOC储量(0-15厘米深度)有不同的影响,对底土MAOC储量(15-50厘米深度)没有显著影响。在任何地点,添加无机氮肥对MAOC存量均无影响。利用稳定碳同位素δ13C分析,我们发现,与粘土土壤(0.5 ~ 12%)相比,沙质土壤中来自铁藻生物量的表层土壤有机碳含量(25 ~ 40%)较大,而在16 ~ 19年的时间内稳定的总添加铁藻生物量的比例在所有样地均低于7%,即SOC稳定率为0.8 ~ 27 g C m-2年-1。利用这些结果,我们得出结论,虽然在沙质土壤中,添加的有机碳的稳定性对限制耕作时的有机碳损失有很大贡献,但在粘性土壤中并非如此。这些差异是由于砂质土壤的有机碳储量远低于粘质土壤。我们的研究结果强调了与改善撒哈拉以南非洲土壤健康相关的挑战,并强调需要更多的研究来可靠地评估在高度风化的热带土壤中是否以及如何在十年时间尺度上稳定额外的有机碳。
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引用次数: 0
High-resolution near-surface electromagnetic mapping for the hydrological modeling of an orange orchard 橙园水文模型的高分辨率近地表电磁测绘
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-05-30 DOI: 10.5194/egusphere-2025-2117
Luca Peruzzo, Ulrike Werban, Marco Pohle, Mirko Pavoni, Benjamin Mary, Giorgio Cassiani, Simona Consoli, Daniela Vanella
Abstract. While above-ground precision agriculture technologies provide spatial and temporal datasets ever-increasing in density and precision, below-ground information lags behind and has been typically limited to time series. As recognized in agrogeophysics, geophysical methods can address the lack of subsurface spatial information. This study focuses on high-resolution Frequency-Domain ElectroMagnetic induction (FDEM) mapping as an ideal complement to above- and below-ground time series that are commonly available in precision agriculture. Focused on a Sicilian orange orchard, this study first investigates some methodological challenges behind seemingly simple FDEM survey choices and processing steps, as well as their interplay with the spatial heterogeneity of agricultural sites. Second, this study shows how the detailed FDEM-based spatial information can underpin a surface/subsurface hydrological model that integrates time series from soil moisture sensors and micro-meteorological sensors. While FDEM has long been recognized as a promising solution in agrogeophysics, this study demonstrates how the approach can be successfully applied in a orchard, whose 3D subsurface variability is a complex combination of root water uptake, irrigation, evapotranspiration, and row-interrow dynamics. The resulting hydrological model reproduces the observed spatiotemporal water dynamics with parameters that agree with the results from soil laboratory analysis, supporting gamma-ray and electrical resistivity tomography datasets. The implementation of a hydrological model positively aligns with the increasing number and variety of methods in precision agriculture, as well as with the need for better predictive capability.
摘要。虽然地面上的精准农业技术提供了密度和精度不断提高的空间和时间数据集,但地下信息滞后,通常仅限于时间序列。正如农业地球物理学所认识到的那样,地球物理方法可以解决地下空间信息的缺乏。本研究的重点是高分辨率频域电磁感应(FDEM)测绘,作为精确农业中常用的地上和地下时间序列的理想补充。本研究以西西里岛的一个橘子园为研究对象,首先探讨了看似简单的FDEM调查选择和处理步骤背后的一些方法挑战,以及它们与农业用地空间异质性的相互作用。其次,该研究展示了基于fdem的详细空间信息如何支撑整合土壤湿度传感器和微气象传感器时间序列的地表/地下水文模型。虽然FDEM长期以来一直被认为是农业地球物理学中很有前途的解决方案,但本研究展示了该方法如何成功地应用于果园,果园的三维地下变化是根系吸水、灌溉、蒸散发和行间动力学的复杂组合。由此产生的水文模型再现了观测到的时空水动力学,其参数与土壤实验室分析结果一致,支持伽马射线和电阻率层析成像数据集。水文模型的实施与精准农业方法的数量和种类的增加以及对更好的预测能力的需求是积极一致的。
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引用次数: 0
Near-continuous observation of soil surface changes at single slopes with high spatial resolution via an automated SfM photogrammetric mapping approach 基于自动SfM摄影测量制图方法的单坡高空间分辨率近连续观测土壤表面变化
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-05-28 DOI: 10.5194/egusphere-2025-2291
Oliver Grothum, Lea Epple, Anne Bienert, Xabier Blanch, Anette Eltner
Abstract. Soil erosion represents a major global threat, necessitating a detailed understanding of its spatial and temporal dynamics. Advanced geospatial technologies such as time-lapse structure-from-motion (SfM) photogrammetry provide high-resolution monitoring of surface changes. This study presents a novel event-driven approach for near-continuous monitoring of hillslope surface dynamics over a multi-annual period. The system employed synchronized DSLR (digital single-lens reflex) cameras at three slope stations, triggered by a rain gauge and a daily timer. Ground control points (GCPs) were surveyed with millimeter accuracy to ensure precise georeferencing. An automated Python-based workflow was developed to synchronize images, detect GCPs using a convolutional neural network (CNN), generate daily digital 3D surface models via SfM, and compute 3D surface models of difference (DoDs). The absolute accuracy of SfM point clouds ranged between 8 mm and 12 mm on average, primarily due to registration errors, with lower deviations (< 5 mm) in central areas after height adjustment. Relative accuracy decreased concentrically with distance from the cameras, with level of detection (LoD) values between 5 mm and 25 mm depending on distance and location. Time series analysis revealed surface changes driven by rainfall, snowmelt, and agricultural activity. The most significant changes often occurred shortly after tillage, even with minimal rainfall, indicating both erosional and non-erosional processes. A strong negative correlation between rainfall and elevation loss was especially evident within the first seven days following tillage. Seasonal surface lowering of 3–5 cm during winter and occasional positive changes due to frost or vegetation growth were also observed. The monitoring system and workflow are transferable, and the resulting high-resolution datasets are valuable for analyzing erosion dynamics and validating soil erosion models.
摘要。土壤侵蚀是一个主要的全球威胁,有必要详细了解其时空动态。先进的地理空间技术,如延时运动结构(SfM)摄影测量,提供了对地表变化的高分辨率监测。本研究提出了一种新的事件驱动方法,用于在多年周期内近连续监测山坡表面动态。该系统在三个斜坡站使用同步数码单反相机,由雨量计和每日计时器触发。对地面控制点(gcp)进行了毫米精度的测量,以确保精确的地理参考。开发了一种基于python的自动化工作流程,用于同步图像,使用卷积神经网络(CNN)检测gcp,通过SfM生成每日数字3D表面模型,并计算3D表面差异模型(DoDs)。SfM点云的绝对精度平均在8 ~ 12 mm之间,主要是由于配准误差,偏差较低(<;高度调整后中央区域为5 mm)。相对精度随距离相机的远近而下降,根据距离和位置的不同,探测水平(LoD)值在5毫米到25毫米之间。时间序列分析揭示了由降雨、融雪和农业活动驱动的地表变化。最显著的变化往往发生在耕作后不久,即使降雨量很少,表明侵蚀和非侵蚀过程。在耕作后的前7天内,降雨量与海拔损失呈显著负相关。冬季地表季节性下降3 ~ 5 cm,偶尔因霜冻或植被生长而出现正变化。监测系统和工作流程是可转移的,由此产生的高分辨率数据集对于分析侵蚀动力学和验证土壤侵蚀模型非常有价值。
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引用次数: 0
Assessing Long-Term Effects of Tea (Camellia sinensis) Cultivation on Soil Quality in Highland Agroecosystems: A Case Study in Lam Dong, Vietnam 高原农业生态系统中茶(Camellia sinensis)种植对土壤质量的长期影响评估——以越南林东地区为例
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-05-27 DOI: 10.5194/egusphere-2025-2048
Tao Anh Khoi
Abstract. Long-term monoculture systems such as tea (Camellia sinensis) plantations can lead to significant changes in soil quality, directly influencing crop productivity and sustainability. This study investigates the impacts of tea cultivation over a 20-year period on key soil quality indicators in Lam Dong province, Vietnam—a major highland tea-growing region. Soils were sampled from plantations of varying ages (5, 10, and 20 years) and compared with native forest soils. Chemical, physical, and biological properties were assessed, including soil organic carbon (SOC), nutrient availability (N, P, K, S), pH, bulk density, plant-available water capacity (PAWC), aggregate stability, and earthworm populations. Results show a significant decline in SOC, available P and K, and PAWC with increasing plantation age, while bulk density and mechanical resistance increased, indicating progressive soil compaction. A multiple regression analysis revealed that SOC, available P, total K, and PAWC were the most predictive indicators of long-term tea productivity. Economic analysis suggests that tea cultivation remains marginally profitable after 20 years, provided that adequate fertilization is maintained. This study proposes critical threshold levels for soil quality indicators to support sustainable tea production in tropical highland systems.
摘要。长期的单一栽培系统,如茶树(Camellia sinensis)种植园,可导致土壤质量发生重大变化,直接影响作物生产力和可持续性。本研究调查了越南林东省一个主要的高原茶叶种植区20年期间茶叶种植对主要土壤质量指标的影响。从不同年龄(5年、10年和20年)的人工林中取样土壤,并与原始森林土壤进行比较。评估了土壤的化学、物理和生物特性,包括土壤有机碳(SOC)、养分有效性(N、P、K、S)、pH、容重、植物有效水量(PAWC)、团聚体稳定性和蚯蚓种群。结果表明:随着人工林年龄的增加,土壤有机碳、速效磷、速效钾和PAWC均显著下降,容重和机械阻力增加,土壤压实程度逐渐加深;多元回归分析表明,土壤有机碳、速效磷、全钾和PAWC是茶叶长期生产力的预测指标。经济分析表明,如果保持足够的施肥,茶叶种植在20年后仍然有利可图。本研究提出了支持热带高原系统可持续茶叶生产的土壤质量指标的临界阈值水平。
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引用次数: 0
Isotopic exchangeability reveals that soil phosphate is mobilised by carboxylate anions, whereas acidification had the reverse effect 同位素交换表明,土壤磷酸盐被羧酸阴离子调动,而酸化则具有相反的效果
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-05-21 DOI: 10.5194/soil-11-389-2025
Siobhan Staunton, Chiara Pistocchi
Abstract. Mineral P is an increasingly scarce resource, and therefore the mobilisation of legacy soil P must be optimised to maintain soil fertility. We have used isotopic exchangeability to probe the lability of native soil P in four contrasting soils following acidification and the addition of carboxylate anions (citrate and oxalate) in soil suspension. Acidification tended to cause immobilisation of soil P, but this was attributed to a salt effect. Addition of both citrate and oxalate led to marked increases in mobilisation of soil P. This would result from both competition between carboxylate and phosphate ions at adsorption sites and chelation of charge-compensating cations. The carboxylate effects were similar at each level of acidification, indicating that effects were largely additive. This is not true for the most calcareous soil where calcium oxalate may have been precipitated at the highest oxalate addition. Promoting carboxylate anions in soil by soil amendment or the use of crops that exude large amounts of such organic anions is a promising approach to improve soil-P availability.
摘要。矿质磷是一种日益稀缺的资源,因此必须优化土壤磷素的利用,以保持土壤肥力。我们使用同位素交换性来探测在酸化和土壤悬浮液中添加羧酸阴离子(柠檬酸盐和草酸盐)后,四种对比土壤中原生土壤P的不稳定性。酸化往往会导致土壤磷的固定,但这是由于盐的影响。柠檬酸盐和草酸盐的添加导致土壤磷的动员显著增加,这可能是由于羧酸盐和磷酸盐离子在吸附位点的竞争以及电荷补偿阳离子的螯合作用。羧酸盐的作用在每个酸化水平上都是相似的,表明这种作用在很大程度上是加性的。这对于大多数钙质土壤来说是不正确的,在那里草酸钙可能在最高的草酸添加下沉淀。通过土壤改良剂或使用大量散发这种有机阴离子的作物来促进土壤中的羧酸阴离子是改善土壤磷素有效性的一种有希望的方法。
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引用次数: 0
Representing soil landscapes from digital soil mapping products – let the map speak for itself 从数字土壤制图产品中呈现土壤景观——让地图为自己说话
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-05-20 DOI: 10.5194/egusphere-2025-1896
David G. Rossiter, Laura Poggio
Abstract. Since the earliest days of soil geography, it has been clear that soils occur in more-or-less clearly mappable bodies, within which soil forming factors have been fairly homogeneous or in a regular pattern, and between which there is usually a clear transition in one or more factors. This has been the basis for polygon-based soil mapping: make a concept map from landscape elements leading to a mental model of the landscape, confirm or modify it with strategically-placed observations, find the transitions, delineate the soil bodies, and characterise them. By contrast, common methods of Digital Soil Mapping (DSM) predict per pixel over a regular grid, from training observations at pedon support. Accuracy assessment of DSM products has been at this “point” support, ignoring the existence of spatial soil bodies and the relations between pixels. Different approaches to DSM – datasets, model forms, analyst choices – result in maps with distinctly different patterns of predicted soil properties or types. Techniques from landscape ecology have been used to characterize spatial patterns of DSM products. The question remains as to how well these products reproduce the actual soil patterns at a given cartographic scale and categorical level of detail. Our approach is to let DSM maps “speak for themselves” to reveal spatial patterns. We do this by grouping pixels, either (1) by aggregation based on property homogeneity using the supercells algorithm, or (2) by segmentation based on within-block property pattern similarity, using the GeoPAT suite of computer programs. Segments can be hierarchically clustered into groups of presumed soil landscape elements. Supercells and segments can be compared to existing soil maps, other land resource maps, and expert judgement. To the extent that presumed soilscape patterns are reproduced, this is evidence that DSM has identified the soil landscape at the chosen scale. Since map users perceive patterns, and most land use decisions are for areas rather than pixels, we propose that DSM products be evaluated by their patterns, as well as by pointwise evaluation statistics.
摘要。从土壤地理学的早期开始,人们就很清楚,土壤是在或多或少可以清晰地绘制的物体中发生的,在这些物体中,土壤形成因素相当均匀或有规则的模式,它们之间通常有一个或多个因素的明显过渡。这是基于多边形的土壤制图的基础:从景观元素制作一个概念图,形成景观的心理模型,通过战略性的观察来确认或修改它,找到过渡,描绘土壤体,并描述它们的特征。相比之下,数字土壤制图(DSM)的常用方法是通过pedon支持的训练观察来预测规则网格上的每像素。DSM产品的精度评价一直在这个“点”上支撑,忽略了空间土体的存在和像元之间的关系。DSM的不同方法——数据集、模型形式、分析人员的选择——产生的地图具有预测土壤性质或类型的明显不同的模式。景观生态学的技术已被用于表征DSM产品的空间格局。问题仍然是,在给定的地图比例尺和分类细节水平上,这些产品如何很好地再现了实际的土壤模式。我们的方法是让DSM地图“为自己说话”来揭示空间模式。我们通过对像素进行分组来做到这一点,或者(1)使用supercells算法基于属性同质性进行聚合,或者(2)使用GeoPAT计算机程序集基于块内属性模式相似性进行分割。区段可以按等级聚类成假定的土壤景观要素组。超级细胞和片段可以与现有的土壤图、其他土地资源图和专家判断进行比较。在某种程度上,假定的土壤景观模式被复制,这证明DSM已经在选定的尺度上确定了土壤景观。由于地图用户感知模式,并且大多数土地利用决策是针对区域而不是像素,我们建议DSM产品通过其模式以及点评估统计来评估。
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引用次数: 0
Calcium is associated with specific soil organic carbon decomposition products 钙与特定的土壤有机碳分解产物有关
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-05-20 DOI: 10.5194/soil-11-381-2025
Mike C. Rowley, Jasquelin Pena, Matthew A. Marcus, Rachel Porras, Elaine Pegoraro, Cyrill Zosso, Nicholas O. E. Ofiti, Guido L. B. Wiesenberg, Michael W. I. Schmidt, Margaret S. Torn, Peter S. Nico
Abstract. Calcium (Ca) may contribute to the preservation of soil organic carbon (SOC) in more ecosystems than previously thought. Here, we provide evidence that Ca is co-located with SOC compounds that are enriched in aromatic and phenolic groups, across different acidic soil types and locations with different ecosystem properties, differing in terms of climate, parent material, soil type, and vegetation. In turn, this co-localised fraction of Ca–SOC is removed through cation exchange, and the association is then only re-established during decomposition in the presence of Ca (Ca addition incubation). Thus, this highlights a causative link between decomposition and the co-location of Ca with a characteristic fraction of SOC. Decomposition increases the relative proportion of negatively charged functional groups, which can increase the propensity for the association between SOC and Ca; in turn, this association can inhibit dissolved organic carbon export or further decomposition. We propose that this mechanism could be driven by Ca hotspots at the microscale shifting local decomposition processes and thereby explaining the co-location of Ca with SOC of a specific composition across different acidic soil environments. Incorporating this biogeochemical process into Earth system models could improve our understanding, predictions, and management of carbon dynamics in soils, as well as accounting for their response to Ca-rich amendments.
摘要。钙(Ca)可能在更多的生态系统中对土壤有机碳(SOC)的保存做出了贡献。本研究表明,在不同的酸性土壤类型和不同的生态系统特征、不同的气候、母质、土壤类型和植被条件下,Ca与富含芳香和酚基的有机碳化合物共存。反过来,这种Ca - soc的共定位部分通过阳离子交换被去除,然后只有在Ca存在的分解过程中(Ca添加孵育)才能重新建立这种关联。因此,这突出了分解和Ca与SOC特征分数的共同定位之间的因果关系。分解增加了带负电官能团的相对比例,增加了SOC与Ca的关联倾向;反过来,这种关联可以抑制溶解的有机碳输出或进一步分解。我们认为这一机制可能是由微尺度局部分解过程中的Ca热点驱动的,从而解释了不同酸性土壤环境中Ca与特定组成的有机碳的共定位。将这一生物地球化学过程纳入地球系统模型可以提高我们对土壤碳动态的理解、预测和管理,并解释它们对富钙修正的反应。
{"title":"Calcium is associated with specific soil organic carbon decomposition products","authors":"Mike C. Rowley, Jasquelin Pena, Matthew A. Marcus, Rachel Porras, Elaine Pegoraro, Cyrill Zosso, Nicholas O. E. Ofiti, Guido L. B. Wiesenberg, Michael W. I. Schmidt, Margaret S. Torn, Peter S. Nico","doi":"10.5194/soil-11-381-2025","DOIUrl":"https://doi.org/10.5194/soil-11-381-2025","url":null,"abstract":"Abstract. Calcium (Ca) may contribute to the preservation of soil organic carbon (SOC) in more ecosystems than previously thought. Here, we provide evidence that Ca is co-located with SOC compounds that are enriched in aromatic and phenolic groups, across different acidic soil types and locations with different ecosystem properties, differing in terms of climate, parent material, soil type, and vegetation. In turn, this co-localised fraction of Ca–SOC is removed through cation exchange, and the association is then only re-established during decomposition in the presence of Ca (Ca addition incubation). Thus, this highlights a causative link between decomposition and the co-location of Ca with a characteristic fraction of SOC. Decomposition increases the relative proportion of negatively charged functional groups, which can increase the propensity for the association between SOC and Ca; in turn, this association can inhibit dissolved organic carbon export or further decomposition. We propose that this mechanism could be driven by Ca hotspots at the microscale shifting local decomposition processes and thereby explaining the co-location of Ca with SOC of a specific composition across different acidic soil environments. Incorporating this biogeochemical process into Earth system models could improve our understanding, predictions, and management of carbon dynamics in soils, as well as accounting for their response to Ca-rich amendments.","PeriodicalId":48610,"journal":{"name":"Soil","volume":"32 1","pages":""},"PeriodicalIF":6.8,"publicationDate":"2025-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144097771","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Gradual drying of permafrost peat decreases carbon dioxide production in drier peat plateaus but not in wetter fens and bogs 永久冻土泥炭的逐渐干燥会减少干燥泥炭高原的二氧化碳产量,而湿润沼泽和沼泽则不会
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2025-05-14 DOI: 10.5194/soil-11-371-2025
Aelis Spiller, Cynthia M. Kallenbach, Melanie S. Burnett, David Olefeldt, Christopher Schulze, Roxane Maranger, Peter M. J. Douglas
Abstract. Permafrost thawing of northern peatlands can cause the local collapse of peat plateaus into much wetter thermokarst bogs and fens, dominated by Sphagnum mosses and graminoids, respectively. However, permafrost thaw can also improve landscape drainage and, thus, lead to the regional drying of peatlands. How gradual drying of these thawing permafrost peatlands affects the subsequent microbial production of carbon dioxide (CO2) and nitrous oxide (N2O) is uncertain because of landscape heterogeneity in moisture, peat quality, and vegetation. Here, we collected near-surface peat samples (5–20 cm) from Alberta, Canada, across transects representing a thaw gradient from peat plateaus to a fen or bog. We incubated the samples for 2 weeks under either field moisture or under gradual drying to reduce moisture by ∼ 80 %. Only the fen sites, which had high moisture and a high percentage of total N, produced N2O (0.06–6.7 µg N2O-N per gram of dry peat), but N2O production was unaffected by the drying treatments. Peat CO2 production was greatest from the fen and the youngest stage of the thermokarst bog, despite them having the most water-saturated field conditions, likely reflecting their more labile plant inputs and, thus, more decomposable peat. We found that CO2 respiration was enhanced by drying at relatively wet sites like the fens and young bog but was suppressed by drying in relatively drier peat plateaus. Further, gradual drying increased 13C-CO2 respiration, suggesting a possible shift to more decomposed, older C being lost with peat drying. Thus, our study suggests that future peat CO2 and N2O production from peatlands will depend on whether peat plateaus thaw into fens or bogs and on their diverging responses of peat respiration to more moisture-limited conditions.
摘要。北部泥炭地的永久冻土融化会导致泥炭高原局部塌陷,变成更湿润的热岩溶沼泽和沼泽,分别以泥炭藓和禾本科植物为主。然而,永久冻土解冻也可以改善景观排水,从而导致泥炭地的区域干燥。这些融化的永久冻土泥炭地的逐渐干燥如何影响随后的二氧化碳(CO2)和氧化亚氮(N2O)的微生物生产是不确定的,因为湿度、泥炭质量和植被的景观异质性。在这里,我们从加拿大阿尔伯塔省收集了近地表泥炭样本(5-20厘米),横跨代表从泥炭高原到沼泽或沼泽的融化梯度的样带。我们将样品在田间湿度或逐渐干燥条件下孵育2周,以减少水分约80%。只有湿度高、总氮含量高的沼泽区产生N2O(每克干泥炭0.06 ~ 6.7µg N2O-N),但N2O产量不受干燥处理的影响。泥炭二氧化碳产量最大的是沼泽和热岩溶沼泽的最年轻阶段,尽管它们具有最饱和的田间条件,可能反映了它们更不稳定的植物输入,因此更容易分解泥炭。我们发现,在相对潮湿的地方,如沼泽和幼沼泽,干燥会增强二氧化碳呼吸,而在相对干燥的泥炭高原,干燥会抑制二氧化碳呼吸。此外,逐渐干燥增加了13C-CO2的呼吸作用,这表明随着泥炭的干燥,可能会发生更分解、更古老的碳流失的转变。因此,我们的研究表明,未来泥炭地的泥炭CO2和N2O产量将取决于泥炭高原是解冻为沼泽还是沼泽,以及它们对更多水分限制条件下泥炭呼吸的不同响应。
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