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Depth extrapolation of field-scale soil moisture time series derived with cosmic-ray neutron sensing (CRNS) using the soil moisture analytical relationship (SMAR) model 利用土壤水分分析关系(SMAR)模型对宇宙射线中子传感(CRNS)得出的实地尺度土壤水分时间序列进行深度外推
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-09-20 DOI: 10.5194/soil-10-655-2024
Daniel Rasche, Theresa Blume, Andreas Güntner
Abstract. Ground-based soil moisture measurements at the field scale are highly beneficial for different hydrological applications, including the validation of space-borne soil moisture products, landscape water budgeting, or multi-criteria calibration of rainfall–runoff models from field to catchment scale. Cosmic-ray neutron sensing (CRNS) allows for the non-invasive monitoring of field-scale soil moisture across several hectares around the instrument but only for the first few tens of centimeters of the soil. Many of these applications require information on soil water dynamics in deeper soil layers. Simple depth-extrapolation approaches often used in remote sensing may be used to estimate soil moisture in deeper layers based on the near-surface soil moisture information. However, most approaches require a site-specific calibration using depth profiles of in situ soil moisture data, which are often not available. The soil moisture analytical relationship (SMAR) is usually also calibrated to sensor data, but due to the physical meaning of each model parameter, it could be applied without calibration if all its parameters were known. However, its water loss parameter in particular is difficult to estimate. In this paper, we introduce and test a simple modification of the SMAR model to estimate the water loss in the second layer based on soil physical parameters and the surface soil moisture time series. We apply the model with and without calibration at a forest site with sandy soils. Comparing the model results with in situ reference measurements down to depths of 450 cm shows that the SMAR models both with and without modification as well as the calibrated exponential filter approach do not capture the observed soil moisture dynamics well. While, on average, the latter performs best over different tested scenarios, the performance of the SMAR models nevertheless meets a previously used benchmark RMSE of ≤ 0.06 cm3 cm−3 in both the calibrated original and uncalibrated modified version. Different transfer functions to derive surface soil moisture from CRNS do not translate into markedly different results of the depth-extrapolated soil moisture time series simulated by SMAR. Despite the fact that the soil moisture dynamics are not well represented at our study site using the depth-extrapolation approaches, our modified SMAR model may provide valuable first estimates of soil moisture in a deeper soil layer derived from surface measurements based on stationary and roving CRNS as well as remote sensing products where in situ data for calibration are not available.
摘要。实地尺度的地基土壤水分测量对不同的水文应用非常有益,包括验证空间土壤水分产品、景观水预算或从实地到流域尺度的降雨-径流模型的多标准校准。宇宙射线中子传感(CRNS)可对仪器周围数公顷的田野尺度土壤湿度进行非侵入式监测,但只能监测土壤的前几十厘米。许多此类应用都需要更深土层的土壤水动态信息。遥感中常用的简单深度外推法可用于根据近地表土壤水分信息估算更深土层的土壤水分。不过,大多数方法都需要使用原地土壤水分数据的深度剖面图进行特定地点校准,而这些数据往往无法获得。土壤水分分析关系(SMAR)通常也根据传感器数据进行校准,但由于每个模型参数的物理意义,如果已知其所有参数,则无需校准即可应用。然而,其失水参数尤其难以估计。在本文中,我们介绍并测试了对 SMAR 模型的简单修改,以根据土壤物理参数和地表土壤水分时间序列估算第二层的水分损失。我们在一个沙质土壤的林地应用了该模型并进行了校准。将模型结果与深度达 450 厘米的原位参考测量结果进行比较后发现,经过和未经过修正的 SMAR 模型以及经过校准的指数滤波方法都不能很好地捕捉观测到的土壤水分动态。虽然平均而言,后者在不同的测试方案中表现最佳,但无论是校准过的原始模型还是未校准的修正版模型,SMAR 模型的性能都达到了先前使用的 RMSE ≤ 0.06 cm3 cm-3 的基准。从 CRNS 导出地表土壤水分的转移函数不同,SMAR 模拟的深度外推土壤水分时间序列结果并无明显差异。尽管使用深度外推法不能很好地反映我们研究地点的土壤水分动态,但我们改进的 SMAR 模型可以在没有原位数据进行校准的情况下,通过基于固定和巡回 CRNS 的地表测量以及遥感产品,对较深土壤层的土壤水分进行有价值的初步估算。
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引用次数: 0
Effects of moss restoration on soil erosion and soil water content in a temperate vineyard 苔藓恢复对温带葡萄园土壤侵蚀和土壤含水量的影响
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-09-18 DOI: 10.5194/egusphere-2024-2504
Corinna Gall, Silvana Oldenburg, Martin Nebel, Thomas Scholten, Steffen Seitz
Abstract. Soil erosion is a serious problem worldwide, as it jeopardizes soil fertility and thus food security. At the same time, agriculture itself is one of the biggest drivers of soil erosion, and vineyards in particular are vulnerable due to often steep slopes, fragile soils, and management practices. Therefore, the search for alternative management practices becomes vital. Since soil erosion is reduced by vegetation cover, this also applies to moss cover. However, research on the restoration and protection of bare soil using mosses as erosion control is still in its infancy. In this study, the restoration of mosses was investigated by applying artificially cultivated moss mats in a temperate vineyard. The effects of moss restoration on surface runoff and sediment discharge were examined compared to bare soil and cover crops using rainfall simulations at three measurement times during one year (April, June, and October). Additionally, soil water content was monitored for each treatment during all rainfall simulations. Mosses initially showed considerable desiccation in summer, whereupon their growth declined. In October, the mosses recovered and re-established themselves in the vineyard, showing a high level of resistance. Moss restoration significantly reduced surface runoff by 71.4 % and sediment discharge by 75.8 % compared to bare soils. While moss restoration had a slightly better effect on reducing runoff and a slightly lower effect on reducing erosion than cover crops (68.1 % and 87.7 %, respectively), these differences were not statistically significant. Sediment discharge varied seasonally for moss restoration, especially from April to June, which is most likely due to the decline in moss cover and the foliage of the vines in June, as concentrated canopy drip points have formed on the leaves and woody surfaces of the vines, increasing erosion. In April and June, the different treatments do not significantly impact soil water content, while in October, bare soil had the highest and moss restoration the lowest soil water content. According to this, the influence of soil cover varies seasonally, with moss restoration not having a detrimental effect on the soil water content in the drier summer months, but retaining the least water in October. Overall, moss restoration proved to be an appropriate and low-maintenance alternative for erosion control, as it requires no mowing and does not reduce near-surface soil water content during summer.
摘要水土流失是世界范围内的一个严重问题,因为它危及土壤肥力,进而危及粮食安全。与此同时,农业本身也是造成水土流失的最大因素之一,尤其是葡萄园,由于山坡陡峭、土壤脆弱和管理方法不当,很容易造成水土流失。因此,寻找替代管理方法变得至关重要。植被覆盖可以减少土壤侵蚀,这一点同样适用于苔藓覆盖。然而,利用苔藓作为侵蚀控制手段来恢复和保护裸露土壤的研究仍处于起步阶段。本研究通过在温带葡萄园中应用人工栽培的苔藓垫,对苔藓的恢复进行了调查。在一年中的三个测量时间(4 月、6 月和 10 月),通过模拟降雨,考察了苔藓恢复对地表径流和沉积物排放的影响,并与裸土和覆盖作物进行了比较。此外,在所有降雨模拟过程中,还对每种处理的土壤含水量进行了监测。苔藓最初在夏季表现出相当程度的干燥,随后生长速度下降。到了 10 月份,苔藓恢复并重新在葡萄园中生长,表现出很强的抵抗力。与裸露的土壤相比,苔藓的恢复大大减少了 71.4% 的地表径流和 75.8% 的沉积物排放。与覆盖作物相比(分别为 68.1% 和 87.7%),苔藓修复在减少径流方面的效果略好,而在减少侵蚀方面的效果略低,但这些差异在统计学上并不显著。苔藓恢复的沉积物排放量随季节而变化,尤其是在 4 月至 6 月,这很可能是由于 6 月苔藓覆盖率下降和藤本植物叶片减少,藤本植物叶片和木质表面形成了集中的树冠滴点,加剧了侵蚀。在 4 月和 6 月,不同处理对土壤含水量的影响不大,而在 10 月,裸土的土壤含水量最高,苔藓修复的土壤含水量最低。由此可见,土壤覆盖的影响因季节而异,在较干旱的夏季,苔藓恢复对土壤含水量没有不利影响,但在 10 月份,土壤含水量最少。总体而言,苔藓恢复被证明是一种合适且维护成本低的侵蚀控制替代方法,因为它不需要修剪,也不会降低夏季近地表的土壤含水量。
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引用次数: 0
Using 3D observations with high spatio-temporal resolution to calibrate and evaluate a process-focused cellular automaton model of soil erosion by water 利用高时空分辨率的三维观测数据,校准和评估以过程为重点的水蚀土壤细胞自动机模型
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-09-12 DOI: 10.5194/egusphere-2024-2648
Anette Eltner, David Favis-Mortlock, Oliver Grothum, Martin Neumann, Tomas Laburda, Petr Kavka
Abstract. Future global change is likely to give rise to novel combinations of the factors which enhance or inhibit soil erosion by water. Thus there is a need for erosion models, necessarily process-focused, which are able to reliably represent rates and extents of soil erosion under unprecedented circumstances. The process-focused cellular automaton erosion model RillGrow is, given initial soil surface microtopography on a plot-sized area, able to predict the emergent patterns produced by runoff and erosion. This study explores the use of Structure-from-Motion photogrammetry as a means to calibrate and validate this model by capturing detailed, time-lapsed data for soil surface height changes during erosion events. Temporally high-resolution monitoring capabilities (i.e. 3D models of elevation change at 0.1 Hz frequency) permit validation of erosion models in terms of the sequence of formation of erosional features. Here, multi-objective functions, using three different spatio-temporal averaging approaches, are assessed for their suitability in calibrating and evaluating the model's output. We used two sets of data, from field- and laboratory-based rainfall simulation experiments lasting 90 and 30 minutes, respectively. By integrating 10 different calibration metrics, the output of 2000 and 2400 RillGrow runs for the field and laboratory experiments respectively, were analysed. No single model run was able to adequately replicate all aspects of either field and laboratory experiments. The multi-objective approaches highlight different aspects of model performance, indicating that no single objective function can capture the full complexity of erosion processes. They also highlight different strengths and weaknesses of the model. Depending on the focus of the evaluation, an ensemble of objective functions may not always be necessary. These results underscore the need for more nuanced evaluation of erosion models, e.g. by incorporating spatial pattern comparison techniques to provide a deeper understanding of the model’s capabilities. Such evaluations are an essential complement to the development of erosion models which are able to forecast the impacts of future global change.
摘要未来的全球变化很可能会导致各种增强或抑制水对土壤侵蚀的因素出现新的组合。因此,有必要建立水土流失模型,这些模型必须以过程为重点,能够在前所未有的情况下可靠地表示土壤侵蚀的速率和程度。以过程为重点的细胞自动机侵蚀模型 RillGrow 能够在给定小块面积的初始土壤表面微地形的情况下,预测径流和侵蚀产生的新模式。本研究通过捕捉侵蚀过程中土壤表面高度变化的详细时滞数据,探索了使用结构-运动摄影测量法校准和验证该模型的方法。高分辨率的时间监测能力(即频率为 0.1 Hz 的三维高程变化模型)允许根据侵蚀特征的形成顺序对侵蚀模型进行验证。在此,使用三种不同的时空平均方法对多目标函数进行了评估,以确定其是否适合校准和评估模型的输出结果。我们使用了两组数据,分别来自持续 90 分钟和 30 分钟的野外和实验室降雨模拟实验。通过整合 10 种不同的校准指标,分别对 2000 和 2400 次 RillGrow 运行的实地和实验室实验输出结果进行了分析。没有一个单一的模型运行能够充分复制实地和实验室实验的所有方面。多目标方法突出了模型性能的不同方面,表明没有任何一个单一的目标函数可以捕捉到侵蚀过程的全部复杂性。它们还突出了模型的不同优缺点。根据评估重点的不同,目标函数的组合不一定总是必要的。这些结果突出表明,需要对侵蚀模型进行更细致的评估,例如,通过采用空间模式比较技术,更深入地了解模型的能力。这种评估是对开发能够预测未来全球变化影响的侵蚀模型的重要补充。
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引用次数: 0
Gully rehabilitation in southern Ethiopia – value and impacts for farmers 埃塞俄比亚南部的沟壑恢复--对农民的价值和影响
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-09-10 DOI: 10.5194/soil-10-637-2024
Wolde Mekuria, Euan Phimister, Getahun Yakob, Desalegn Tegegne, Awdenegest Moges, Yitna Tesfaye, Dagmawi Melaku, Charlene Gerber, Paul D. Hallett, Jo U. Smith
Abstract. Gully erosion can be combatted in severely affected regions like sub-Saharan Africa using various low-cost interventions that are accessible to affected farmers. For successful implementation, however, biophysical evidence of intervention effectiveness needs to be validated against the interests and priorities of local communities. Working with farmers in a watershed in southern Ethiopia, we investigated (a) the effectiveness of low-cost gully rehabilitation measures to reduce soil loss and upward expansion of gully heads; (b) how farmers and communities view gully interventions; and (c) whether involving farmers in on-farm field trials to demonstrate gully interventions improves uptake, knowledge, and perceptions of their capacity to act. On-farm field experiments, key-informant interviews, focus group discussions, and household surveys were used to collect and analyse data. Three gully treatments were explored, all with riprap, one with grass planting, and one with grass planting and check-dam integration. Over a period of 26 months, these low-cost practices ceased measurable gully head expansion, whereas untreated gullies had a mean upward expansion of 671 cm, resulting in a calculated soil loss of 11.0 t. Farmers had a positive view of all gully rehabilitation measures explored. Ongoing rehabilitation activities and on-farm trials influenced the knowledge and understanding of similar gully treatments among survey respondents. On-farm experiments and field day demonstrations empowered farmers to act, addressing pessimism from some respondents about their capacity to do so.
摘要。在撒哈拉以南非洲等受影响严重的地区,可以利用受影响农民可以获得的各种低成本干预措施来防治沟壑侵蚀。然而,要成功实施干预措施,需要根据当地社区的利益和优先事项来验证干预措施有效性的生物物理证据。通过与埃塞俄比亚南部一个流域的农民合作,我们调查了:(a) 低成本沟壑恢复措施在减少土壤流失和沟头向上扩展方面的有效性;(b) 农民和社区如何看待沟壑干预措施;(c) 让农民参与农田实地试验以展示沟壑干预措施是否能提高农民的接受程度、知识水平以及对其行动能力的看法。收集和分析数据的方法包括农场实地试验、主要信息提供者访谈、焦点小组讨论和家庭调查。共探讨了三种沟壑处理方法,一种是使用护坡,一种是植草,还有一种是植草与拦水坝相结合。在 26 个月的时间里,这些低成本的做法停止了可测量的沟头扩张,而未经处理的沟壑平均向上扩张了 671 厘米,计算得出的土壤流失量为 11.0 吨。农民对所探讨的所有沟壑恢复措施都持积极态度。正在进行的修复活动和农场试验影响了调查对象对类似沟壑处理方法的认识和理解。农田试验和田间日示范增强了农民的行动能力,消除了一些调查对象对其行动能力的悲观情绪。
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引用次数: 0
An ensemble estimate of Australian soil organic carbon using machine learning and process-based modelling 利用机器学习和基于过程的建模对澳大利亚土壤有机碳进行集合估算
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-09-10 DOI: 10.5194/soil-10-619-2024
Lingfei Wang, Gab Abramowitz, Ying-Ping Wang, Andy Pitman, Raphael A. Viscarra Rossel
Abstract. Spatially explicit prediction of soil organic carbon (SOC) serves as a crucial foundation for effective land management strategies aimed at mitigating soil degradation and assessing carbon sequestration potential. Here, using more than 1000 in situ observations, we trained two machine learning models (a random forest model and a k-means coupled with multiple linear regression model) and one process-based model (the vertically resolved MIcrobial-MIneral Carbon Stabilization, MIMICS, model) to predict the SOC stocks of the top 30 cm of soil in Australia. Parameters of MIMICS were optimised for different site groupings using two distinct approaches: plant functional types (MIMICS-PFT) and the most influential environmental factors (MIMICS-ENV). All models showed good performance with respect to SOC predictions, with an R2 value greater than 0.8 during out-of-sample validation, with random forest being the most accurate; moreover, it was found that SOC in forests is more predictable than that in non-forest soils excluding croplands. The performance of continental-scale SOC predictions by MIMICS-ENV is better than that by MIMICS-PFT especially in non-forest soils. Digital maps of terrestrial SOC stocks generated using all of the models showed a similar spatial distribution, with higher values in south-eastern and south-western Australia, but the magnitude of the estimated SOC stocks varied. The mean ensemble estimate of SOC stocks was 30.3 t ha−1, with k-means coupled with multiple linear regression generating the highest estimate (mean SOC stocks of 38.15 t ha−1) and MIMICS-PFT generating the lowest estimate (mean SOC stocks of 24.29 t ha−1). We suggest that enhancing process-based models to incorporate newly identified drivers that significantly influence SOC variation in different environments could be the key to reducing the discrepancies in these estimates. Our findings underscore the considerable uncertainty in SOC estimates derived from different modelling approaches and emphasise the importance of rigorous out-of-sample validation before applying any one approach in Australia.
摘要土壤有机碳(SOC)的空间明确预测是有效土地管理战略的重要基础,旨在缓解土壤退化和评估固碳潜力。在此,我们利用 1000 多个原位观测数据,训练了两个机器学习模型(随机森林模型和 k-means 耦合多元线性回归模型)和一个基于过程的模型(垂直解析的微生物-矿物碳稳定模型 MIMICS),以预测澳大利亚土壤顶部 30 厘米的 SOC 储量。利用两种不同的方法:植物功能类型(MIMICS-PFT)和最有影响的环境因素(MIMICS-ENV),对不同地点分组的 MIMICS 参数进行了优化。所有模型在 SOC 预测方面都表现良好,在样本外验证中 R2 值大于 0.8,其中随机森林最为准确;此外,研究还发现森林中的 SOC 比非森林土壤(不包括耕地)中的 SOC 更可预测。MIMICS-ENV 的大陆尺度 SOC 预测性能优于 MIMICS-PFT,尤其是在非森林土壤中。利用所有模型生成的陆地 SOC 储量数字地图显示出相似的空间分布,澳大利亚东南部和西南部的数值较高,但估计的 SOC 储量大小不一。SOC 储量的平均集合估计值为 30.3 吨/公顷,其中 k-means 结合多元线性回归得出的估计值最高(SOC 储量平均值为 38.15 吨/公顷),而 MIMICS-PFT 得出的估计值最低(SOC 储量平均值为 24.29 吨/公顷)。我们认为,加强基于过程的模型,纳入新发现的对不同环境中 SOC 变化有显著影响的驱动因素,可能是减少这些估计值差异的关键。我们的研究结果强调了不同建模方法得出的 SOC 估算值存在很大的不确定性,并强调了在澳大利亚应用任何一种方法之前进行严格的样本外验证的重要性。
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引用次数: 0
Addressing soil data needs and data gaps in catchment-scale environmental modelling: the European perspective 解决流域尺度环境建模中的土壤数据需求和数据缺口:欧洲视角
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-09-09 DOI: 10.5194/soil-10-587-2024
Brigitta Szabó, Piroska Kassai, Svajunas Plunge, Attila Nemes, Péter Braun, Michael Strauch, Felix Witing, János Mészáros, Natalja Čerkasova
Abstract. To effectively guide agricultural management planning strategies and policy, it is important to simulate water quantity and quality patterns and to quantify the impact of land use and climate change on soil functions, soil health, and hydrological and other underlying processes. Environmental models that depict alterations in surface and groundwater quality and quantity at the catchment scale require substantial input, particularly concerning movement and retention in the unsaturated zone. Over the past few decades, numerous soil information sources, containing structured data on diverse basic and advanced soil parameters, alongside innovative solutions to estimate missing soil data, have become increasingly available. This study aims to (i) catalogue open-source soil datasets and pedotransfer functions (PTFs) applicable in simulation studies across European catchments; (ii) evaluate the performance of selected PTFs; and (iii) present compiled R scripts proposing estimation solutions to address soil physical, hydraulic, and chemical data needs and gaps in catchment-scale environmental modelling in Europe. Our focus encompassed basic soil properties, bulk density, porosity, albedo, soil erodibility factor, field capacity, wilting point, available water capacity, saturated hydraulic conductivity, and phosphorus content. We aim to recommend widely supported data sources and pioneering prediction methods that maintain physical consistency and present them through streamlined workflows.
摘要为有效指导农业管理规划战略和政策,必须模拟水量和水质模式,量化土地利用和气候变化对土壤功能、土壤健康、水文和其他基本过程的影响。在集水区范围内描述地表水和地下水水质和水量变化的环境模型需要大量输入,特别是有关非饱和带的移动和滞留。在过去的几十年中,包含各种基本和高级土壤参数结构化数据的众多土壤信息源,以及用于估算缺失土壤数据的创新解决方案,已经变得越来越多。本研究旨在:(i) 对适用于欧洲流域模拟研究的开源土壤数据集和土壤转移函数(PTF)进行编目;(ii) 评估所选 PTF 的性能;(iii) 提出 R 脚本汇编,提出估算解决方案,以解决欧洲流域尺度环境建模中的土壤物理、水力和化学数据需求和缺口。我们的重点包括基本土壤特性、容重、孔隙度、反照率、土壤侵蚀系数、田间容重、萎蔫点、可用水容量、饱和导水率和磷含量。我们的目标是推荐得到广泛支持的数据源和开创性的预测方法,以保持物理上的一致性,并通过简化的工作流程加以呈现。
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引用次数: 0
Status and influential factors of soil nutrients and acidification in Chinese tea plantations 中国茶园土壤养分与酸化现状及影响因素
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-08-28 DOI: 10.5194/egusphere-2024-2498
Dan Wang, Fei Li, Benjuan Liu, Zhihui Wang, Jianfeng Hou, Rui Cao, Yuqian Zheng, Wanqin Yang
Abstract. The knowledge of the status and influential factors of soil nutrients including soil organic matter (SOM), nitrogen (N), potassium (K) and phosphorus (P), and acidification is the basis for sustainable management of tea plantations and thus the sustainability of tea industry. However, a study addressing this topic at a national level is lack. Thereby, we assessed the status, spatial variations, and influential factors of soil nutrients and acidification in China’s tea plantations based on 1,843 data pairs collected from 379 published articles. The results showed that only 40.90 % of the observed tea plantations could meet the standards of high-quality tea plantations and most tea plantations were facing soil acidification, and nutrient deficiencies and imbalance. Furthermore, the status of soil nutrients and pH varied among cultivation zones due to the impacts of geolocations, climate, and soil types. Specifically, tea plantations in the southern zone showed the lowest concentrations of soil available N and K and total K but the highest stoichiometric ratios of soil nutrients (P<0.05). The status of soil nutrients and pH was also significantly shaped by management practices (e.g., rotational life cycle and fertilization strategies). Applying organic fertilizer, extending rotational life cycle duration of cultivation, planting shading trees were recommended to improve the soil nutrient availability and balance and to mitigate soil acidification. Specifically, applying K fertilizer to tea plantations in the southern zone and/or at high altitudes was recommended.
摘要了解包括土壤有机质(SOM)、氮(N)、钾(K)和磷(P)在内的土壤养分的状况和影响因素以及酸化是茶园可持续管理的基础,因此也是茶产业可持续发展的基础。然而,在国家层面对这一问题的研究还很缺乏。因此,我们根据从 379 篇已发表文章中收集的 1843 对数据,评估了中国茶园土壤养分和酸化的现状、空间变化和影响因素。结果表明,只有40.90%的茶园达到了优质茶园的标准,大部分茶园面临土壤酸化、养分缺乏和失衡的问题。此外,受地理位置、气候和土壤类型的影响,不同种植区的土壤养分和酸碱度状况也不尽相同。具体而言,南部茶园的土壤可利用氮、钾和总钾浓度最低,但土壤养分的化学计量比最高(P<0.05)。管理方法(如轮作周期和施肥策略)也对土壤养分和 pH 值状况有显著影响。建议施用有机肥、延长轮作周期、种植遮荫树,以改善土壤养分供应和平衡,缓解土壤酸化。具体而言,建议在南部地区和/或高海拔地区的茶园施用钾肥。
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引用次数: 0
Organic Pollutant Oxidation on Manganese Oxides in Soils – The Role of Calcite Indicated by Geoelectrical and Chemical Analyses 有机污染物对土壤中氧化锰的氧化作用--地质电学和化学分析显示的方解石的作用
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-08-22 DOI: 10.5194/egusphere-2024-2101
Sonya Sara Altzitser, Yael Golda Mishael, Nimrod Schwartz
Abstract. Understanding phenolic pollutants interaction with soil colloids has been a focus of extensive research, primarily under controlled conditions. This study addresses the need to explore these processes in a more natural, complex soil environment. We aim to enlighten the underlying mechanisms of hydroquinone (a representative phenolic pollutant) oxidation in ambient, MnO2-rich sandy soil within soil columns designed for breakthrough experiments. Our innovative approach combines noninvasive electrical measurements, crystallographic and microscopic analyses, and chemical profiling to comprehensively understand soil-pollutant interactions. Our study reveals that hydroquinone oxidation by MnO2 initiates a cascade of reactions, altering local pH, calcite dissolution, and precipitating amorphous Mn-oxides, showcasing a complex interplay of chemical processes. Our analysis, combining insights from chemistry and electrical measurements, reveals the oxidation process led to a constant decrease in polarizing surfaces, as indicated by quadrature conductivity monitoring. Furthermore, dynamic shifts in the soil solution chemistry (changes in the calcium and manganese concentrations, pH, and EC) correlated with the non-monotonous behavior of the in-phase conductivity. Our findings conclusively demonstrate that the noninvasive electrical method allows real-time monitoring of calcite dissolution, serving as a direct cursor to the oxidation process of hydroquinone, enabling the observation of soil surface processes, and chemical interactions.
摘要了解酚类污染物与土壤胶体的相互作用一直是广泛研究的重点,主要是在受控条件下。本研究旨在满足在更自然、更复杂的土壤环境中探索这些过程的需要。我们旨在揭示对苯二酚(一种代表性酚类污染物)在为突破性实验而设计的土壤柱中富含 MnO2 的环境沙质土壤中氧化的基本机制。我们的创新方法结合了非侵入式电学测量、晶体学和显微分析以及化学剖析,以全面了解土壤与污染物之间的相互作用。我们的研究揭示了 MnO2 氧化对苯二酚会引发一系列反应,改变局部 pH 值、溶解方解石并沉淀出无定形的锰氧化物,展示了化学过程的复杂相互作用。我们结合化学和电学测量结果进行的分析表明,氧化过程导致极化表面不断减少,正交电导率监测也表明了这一点。此外,土壤溶液化学的动态变化(钙和锰浓度、pH 值和导电率的变化)与相位电导率的非单调行为相关。我们的研究结果最终证明,非侵入式电学方法可对方解石溶解进行实时监测,作为对苯二酚氧化过程的直接指示器,可对土壤表面过程和化学相互作用进行观测。
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引用次数: 0
Luminescence dating approaches to reconstruct the formation of plaggic anthrosols 用发光测年法重建块状炭溶胶的形成过程
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-08-22 DOI: 10.5194/soil-10-567-2024
Jungyu Choi, Roy van Beek, Elizabeth L. Chamberlain, Tony Reimann, Harm Smeenge, Annika van Oorschot, Jakob Wallinga
Abstract. Plaggic anthrosols demonstrate the significant and widespread influence of agriculture on the landscape of northern Europe and testify to increased land-use intensity over the last millennium. However, a lack of established chronologic methods to interrogate these soils has hindered research on their formation history, so the timing and process of plaggic anthrosol development remain poorly quantified. Recently, luminescence dating methods have emerged as a tool for tracing the past movement of grains, including within the soil column. This study combines two primary luminescence methods – single-grain feldspar infrared stimulated luminescence (IRSL) along with post-infrared infrared stimulated luminescence (pIRIR) measurements and small-aliquot (or multi-grain) quartz optically stimulated luminescence (OSL) – to reconstruct the formation of a plaggic anthrosol at Braakmankamp (eastern Netherlands). Toward this aim, we present a new method to identify well-bleached single grains of feldspar using the ratio of the grain's IRSL and pIRIR signals as a filter. The results provide both methodological and applied archaeological insights. Both small-aliquot quartz OSL and single-grain feldspar pIRIR ages yield reliable ages for plaggen deposits when the new filtering approach is used to remove poorly bleached feldspar grains from the analysis. Single-grain pIRIR feldspar has the added benefit of revealing complex soil formation histories for naturally bioturbated deposits, including those at the base of the plaggen layer. Augmenting this information with conventional quartz OSL dating builds confidence in the geo-chronologic record and allows us to reconstruct the timing and processes of plaggic anthrosol formation in Braakmankamp. According to the luminescence dating results, land clearance occurred around 900–1000 years ago, and accumulation of plaggen material began around 700–800 years ago. The average accumulation rate of plaggen material is estimated at ∼ 1.1 mm yr−1.
摘要。Plaggic anthrosols 显示了农业对北欧景观的重要而广泛的影响,并证明了在过去的一千年中土地使用强度的增加。然而,由于缺乏成熟的年代学方法来研究这些土壤,阻碍了对其形成历史的研究,因此,对plaggic anthrosol形成的时间和过程的量化程度仍然很低。最近,发光测年法作为一种工具出现,可用于追踪颗粒过去的移动,包括在土壤柱内的移动。本研究结合了两种主要的发光方法--单晶粒长石红外激发发光(IRSL)以及后红外激发发光(pIR)测量和小等比(或多晶粒)石英光学激发发光(OSL)--来重建 Braakmankamp(荷兰东部)地层岩溶的形成过程。为此,我们提出了一种新方法,利用长石晶粒的 IRSL 和 pIRIR 信号的比值作为滤光器,来识别漂白良好的单个长石晶粒。研究结果提供了方法论和应用考古学方面的启示。当使用新的过滤方法从分析中剔除漂白不良的长石颗粒时,小当量石英OSL和单颗粒长石pIRIR年龄都能为plaggen沉积提供可靠的年龄。单粒长石红外光谱分析的另一个好处是可以揭示天然生物扰动沉积物(包括 plaggen 层底部的沉积物)复杂的土壤形成历史。用传统的石英 OSL 测定法来补充这一信息,可以增强我们对地质年代记录的信心,并使我们能够重建布拉克曼坎普的钙钛矿形成时间和过程。根据发光测年结果,土地清理发生在大约 900-1000 年前,而 plaggen 物质的堆积开始于大约 700-800 年前。Plaggen 物质的平均积累率估计为 1.1 毫米/年-1。
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引用次数: 0
Long-term legacy of phytoremediation on plant succession and soil microbial communities in petroleum-contaminated sub-Arctic soils 植物修复对受石油污染的亚北极土壤中植物演替和土壤微生物群落的长期影响
IF 6.8 2区 农林科学 Q1 SOIL SCIENCE Pub Date : 2024-08-19 DOI: 10.5194/soil-10-551-2024
Mary-Cathrine Leewis, Christopher Kasanke, Ondrej Uhlik, Mary Beth Leigh
Abstract. Phytoremediation can be a cost-effective method of restoring contaminated soils using plants and associated microorganisms. Most studies follow the impacts of phytoremediation solely across the treatment period and have not explored long-term ecological effects. In 1995, a phytoremediation study was initiated near Fairbanks, Alaska, to determine how the introduction of annual grasses and/or fertilizer would influence degradation of petroleum hydrocarbons (PHCs). After 1 year, grass and/or fertilizer-treated soils showed greater decreases in PHC concentrations compared to untreated plots. The site was then left for 15 years with no active site management. In 2011, we re-examined the site to explore the legacy of phytoremediation on contaminant disappearance, as well as on plant and soil microbial ecology. We found that the recruited vegetation and the current bulk soil microbial community structure and functioning were all heavily influenced by initial phytoremediation treatment. The number of diesel-degrading microorganisms (DDMs) was positively correlated with the percentage cover of vegetation at the site, which was influenced by initial treatment. Even 15 years later, the initial use of fertilizer had significant effects on microbial biomass, community structure, and activity. We conclude that phytoremediation treatment has long-term, legacy effects on the plant community, which, in turn, impact microbial community structure and functioning. It is therefore important to consider phytoremediation strategies that not only influence site remediation rates in the short-term but also prime the site for the restoration of vegetation over the long-term.
摘要植物修复是利用植物和相关微生物恢复受污染土壤的一种经济有效的方法。大多数研究仅跟踪植物修复在处理期间产生的影响,而没有探讨长期的生态效应。1995 年,在阿拉斯加费尔班克斯附近启动了一项植物修复研究,以确定引入一年生草类和/或肥料将如何影响石油碳氢化合物 (PHC) 的降解。1 年后,与未经处理的地块相比,经过草和/或肥料处理的土壤显示出更大的 PHC 浓度下降。之后,我们将该场地放置了 15 年,没有进行任何积极的场地管理。2011 年,我们重新考察了该地点,以探索植物修复对污染物消失以及植物和土壤微生物生态的影响。我们发现,新加入的植被和当前的大体积土壤微生物群落结构和功能都受到最初植物修复处理的严重影响。柴油降解微生物(DDMs)的数量与现场植被覆盖率呈正相关,而植被覆盖率又受初始处理的影响。即使在 15 年后,最初使用肥料对微生物的生物量、群落结构和活性也有显著影响。我们的结论是,植物修复处理会对植物群落产生长期、遗留的影响,进而影响微生物群落的结构和功能。因此,重要的是要考虑植物修复策略,不仅要在短期内影响场地修复率,还要为长期植被恢复做好准备。
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