Pub Date : 2025-11-13DOI: 10.1007/s12155-025-10917-w
Erwan Hermawan, Adiarso Adiarso, Ai Nelly, Danis E. P. Wicaksana, Hari Setiawan, Isyalia D. Handayani, Usman Sudjadi, M. C. Tri Atmodjo, Unik Setiawati
The Indonesian government has consistently expressed its commitment to mitigating greenhouse gas emissions, notably through the partial substitution of fossil fuels with biofuels to increase the share of renewables in the national energy mix. Among the measures introduced is the E5 program, mandating a 5% ethanol blend in gasoline, although its implementation has encountered several technical and logistical barriers. This study examines the feasibility of integrating bioethanol production into the biogas value chain by comparing three development scenarios. The baseline scenario (SC BaU) assumes a stand-alone bioethanol production facility. Scenario 2 considers a biorefinery configuration utilizing wastewater for electricity generation, with two operational sub-cases. SC BIO-TRADE explores the conversion of wastewater into biomethane for commercial distribution. The economic evaluation identifies SC BIO-TRADE as the most feasible option, owing to its relatively lower capital investment of USD 255,314,671 and a projected average annual revenue of USD 126,152,277. At a selling price of USD 6 per MMBTU, this pathway achieves an internal rate of return (IRR) of 14%, outperforming the other scenarios. Moreover, SC BIO-TRADE is particularly suitable for deployment in industrial zones where a reliable gas supply is critical for sustaining production activities.
{"title":"Enhancing the Economic Feasibility of Biogas Production from Bioethanol Wastewater Derived from Empty Fruit Bunches","authors":"Erwan Hermawan, Adiarso Adiarso, Ai Nelly, Danis E. P. Wicaksana, Hari Setiawan, Isyalia D. Handayani, Usman Sudjadi, M. C. Tri Atmodjo, Unik Setiawati","doi":"10.1007/s12155-025-10917-w","DOIUrl":"10.1007/s12155-025-10917-w","url":null,"abstract":"<div><p>The Indonesian government has consistently expressed its commitment to mitigating greenhouse gas emissions, notably through the partial substitution of fossil fuels with biofuels to increase the share of renewables in the national energy mix. Among the measures introduced is the E5 program, mandating a 5% ethanol blend in gasoline, although its implementation has encountered several technical and logistical barriers. This study examines the feasibility of integrating bioethanol production into the biogas value chain by comparing three development scenarios. The baseline scenario (SC BaU) assumes a stand-alone bioethanol production facility. Scenario 2 considers a biorefinery configuration utilizing wastewater for electricity generation, with two operational sub-cases. SC BIO-TRADE explores the conversion of wastewater into biomethane for commercial distribution. The economic evaluation identifies SC BIO-TRADE as the most feasible option, owing to its relatively lower capital investment of USD 255,314,671 and a projected average annual revenue of USD 126,152,277. At a selling price of USD 6 per MMBTU, this pathway achieves an internal rate of return (IRR) of 14%, outperforming the other scenarios. Moreover, SC BIO-TRADE is particularly suitable for deployment in industrial zones where a reliable gas supply is critical for sustaining production activities.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":487,"journal":{"name":"BioEnergy Research","volume":"18 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145511019","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-10DOI: 10.1007/s12155-025-10907-y
Gustavo Amaro Bittencourt, Carlos Osorio-González, Satinder Kaur Brar, Carlos Ricardo Soccol, Luciana Porto de Souza Vandenberghe
Soybean is widely used to produce edible vegetable oils, accounting for 57% of their global production. Soybean hull (SH), a byproduct of this chain, has high polysaccharide content and lower recalcitrance compared to other lignocellulosic biomasses. To enhance oil production in the soybean industrial chain, the present study evaluated an SH enzymatic hydrolysate as a substrate for Rhodosporidium toruloides growth, whose metabolism promotes intracellular lipid accumulation under stress conditions. For the first time, NaCl-induced osmotic stress was evaluated to enhance lipid accumulation in lignocellulosic hydrolysate fermentation by R. toruloides. Adding 1% NaCl led to 36 ± 0.98% lipid accumulation, versus 26 ± 1.72% under unstressed conditions. A two-stage fermentation strategy separating growth and production phases was then applied, yielding a maximum lipid concentration of 5.96 ± 0.55 g/L, and improving lipid yield from 0.096 ± 0.006 to 0.115 ± 0.012 g/g. This strategy revealed significant yield differences between stages (0.102 ± 0.0008 g/g in the first stage, 0.134 ± 0.014 g/g in the second stage), indicating that NaCl supplementation enhanced lipid biosynthesis over biomass production. Fatty acid methyl esters analysis revealed palmitic, stearic, oleic, linoleic, and α-linoleic acids as predominant, aligning with biodiesel requirements. With SH availability estimated at 21.0–33.7 million tons annually, converting only 1% could yield 8204–13,167 tons of microbial lipids annually. This study demonstrates the potential of SH as a suitable substrate for microbial lipids, providing crucial data for novel cultivation and scaling up strategies, aiming to enhance lipid productivity.
{"title":"Induced Osmotic Stress Enhanced Microbial Lipids Production by Rhodosporidium toruloides from Soybean Hull Hydrolysate","authors":"Gustavo Amaro Bittencourt, Carlos Osorio-González, Satinder Kaur Brar, Carlos Ricardo Soccol, Luciana Porto de Souza Vandenberghe","doi":"10.1007/s12155-025-10907-y","DOIUrl":"10.1007/s12155-025-10907-y","url":null,"abstract":"<div><p>Soybean is widely used to produce edible vegetable oils, accounting for 57% of their global production. Soybean hull (SH), a byproduct of this chain, has high polysaccharide content and lower recalcitrance compared to other lignocellulosic biomasses. To enhance oil production in the soybean industrial chain, the present study evaluated an SH enzymatic hydrolysate as a substrate for <i>Rhodosporidium toruloides</i> growth, whose metabolism promotes intracellular lipid accumulation under stress conditions. For the first time, NaCl-induced osmotic stress was evaluated to enhance lipid accumulation in lignocellulosic hydrolysate fermentation by <i>R. toruloides</i>. Adding 1% NaCl led to 36 ± 0.98% lipid accumulation, versus 26 ± 1.72% under unstressed conditions. A two-stage fermentation strategy separating growth and production phases was then applied, yielding a maximum lipid concentration of 5.96 ± 0.55 g/L, and improving lipid yield from 0.096 ± 0.006 to 0.115 ± 0.012 g/g. This strategy revealed significant yield differences between stages (0.102 ± 0.0008 g/g in the first stage, 0.134 ± 0.014 g/g in the second stage), indicating that NaCl supplementation enhanced lipid biosynthesis over biomass production. Fatty acid methyl esters analysis revealed palmitic, stearic, oleic, linoleic, and α-linoleic acids as predominant, aligning with biodiesel requirements. With SH availability estimated at 21.0–33.7 million tons annually, converting only 1% could yield 8204–13,167 tons of microbial lipids annually. This study demonstrates the potential of SH as a suitable substrate for microbial lipids, providing crucial data for novel cultivation and scaling up strategies, aiming to enhance lipid productivity.</p></div>","PeriodicalId":487,"journal":{"name":"BioEnergy Research","volume":"18 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145510643","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-09DOI: 10.1007/s12155-025-10914-z
Lobna M. Abouelmagd, Heba Askr, Ashraf Darwish, Aboul Ella Hassanien
Palm oil, known for its high energy density and wide availability, is a promising resource for sustainable biodiesel production. Biodiesel, derived from renewable sources such as vegetable oils or animal fats, emits fewer pollutants and contributes to reducing environmental issues related to air pollution and climate change. This paper introduces an intelligent, optimized system for estimating biodiesel yield using IoT-based imagery and machine learning (ML) techniques. The proposed system operates in two main phases, which are palm-oil tree detection and biodiesel yield prediction. In the initial phase, palm-oil trees are identified and counted based on input images using the YOLOv9 object detection algorithm. To assess YOLOv9 in various configurations versusYOLOv8, three experiments were carried out. With high-resolution input, YOLOv9 produced the best results with 100% precision and recall and 99.5% mAP50-95. In the second phase, biodiesel yield is predicted using an optimized gradient boosting model based on environmental variables like temperature, humidity, rainfall, and wind speed. With an R2 value of 0.98 and RMSE and MSE values close to zero, the system exhibits high inference quality and a fast inference time of 0.00297 s. The efficacy of the system under various environmental conditions was confirmed by a real-world case study which also confirmed that the system can accurately estimate the production of biodiesel. This system shows how ML and IoT integration can improve the efficiency of biodiesel production providing a scalable and dependable solution for the development of sustainable energy.
{"title":"An Intelligent and Optimized System for Predicting Sustainable Biodiesel Production Using IoT-Based Palm-Oil Trees","authors":"Lobna M. Abouelmagd, Heba Askr, Ashraf Darwish, Aboul Ella Hassanien","doi":"10.1007/s12155-025-10914-z","DOIUrl":"10.1007/s12155-025-10914-z","url":null,"abstract":"<div><p>Palm oil, known for its high energy density and wide availability, is a promising resource for sustainable biodiesel production. Biodiesel, derived from renewable sources such as vegetable oils or animal fats, emits fewer pollutants and contributes to reducing environmental issues related to air pollution and climate change. This paper introduces an intelligent, optimized system for estimating biodiesel yield using IoT-based imagery and machine learning (ML) techniques. The proposed system operates in two main phases, which are palm-oil tree detection and biodiesel yield prediction. In the initial phase, palm-oil trees are identified and counted based on input images using the YOLOv9 object detection algorithm. To assess YOLOv9 in various configurations versusYOLOv8, three experiments were carried out. With high-resolution input, YOLOv9 produced the best results with 100% precision and recall and 99.5% mAP50-95. In the second phase, biodiesel yield is predicted using an optimized gradient boosting model based on environmental variables like temperature, humidity, rainfall, and wind speed. With an <i>R</i><sup>2</sup> value of 0.98 and RMSE and MSE values close to zero, the system exhibits high inference quality and a fast inference time of 0.00297 s. The efficacy of the system under various environmental conditions was confirmed by a real-world case study which also confirmed that the system can accurately estimate the production of biodiesel. This system shows how ML and IoT integration can improve the efficiency of biodiesel production providing a scalable and dependable solution for the development of sustainable energy.</p></div>","PeriodicalId":487,"journal":{"name":"BioEnergy Research","volume":"18 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145510766","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-08DOI: 10.1007/s12155-025-10910-3
K. Ashwini, R. Resmi, Muneer Parayangat, Mohamed Abbas
This study examines the pyrolysis characteristics of wood apple shell as a sustainable biomass feedstock through morphological, elemental, thermal, calorific, and statistical analysis. Scanning electron microscopy revealed that granulated samples exhibited uniform morphology with larger particle sizes and stable porosity, favouring consistent thermal degradation. In contrast, powdered samples displayed irregular particle distribution and higher pore sizes, contributing to faster decomposition. Energy dispersive X-ray spectroscopy confirmed high carbon content in both forms, with powdered samples reaching 72.6% and granulated samples 62.5%, while oxygen ranged from 26.68% to 38.14%. The carbon-to-oxygen ratios were 2.72 for powdered and 1.62 for granulated, directly influencing volatile release and energy yield during pyrolysis. Fourier transform infrared spectroscopy identified hydroxyl, carbonyl, and amine groups favourable for bio-oil and biochar production. Thermogravimetric analysis indicated major mass loss between 250 to 450°C, associated with hemicellulose, cellulose, and lignin degradation, with a peak decomposition rate at 385°C. Higher heating values, calculated from elemental and proximate data, ranged from 6.54 to 7.54 kWh/kg, with powdered samples showing higher conversion efficiency. Statistical validation using Welch’s t-test confirmed significant differences (p < 0.05) between powdered and granulated forms, reinforcing the reliability of the observed trends. The results suggest that powdered samples are advantageous for rapid decomposition and higher energy output, while granulated forms provide structural stability and sustained energy release. Overall, the findings highlight the complementary roles of particle size and feedstock form in optimizing pyrolysis pathways, with granulated wood apple shells being particularly suited for controlled and stable bio-oil production.
{"title":"A Comprehensive Material Analysis for Enhancing Energy Production Through Pyrolysis of Wood Apple Shell","authors":"K. Ashwini, R. Resmi, Muneer Parayangat, Mohamed Abbas","doi":"10.1007/s12155-025-10910-3","DOIUrl":"10.1007/s12155-025-10910-3","url":null,"abstract":"<div><p>This study examines the pyrolysis characteristics of wood apple shell as a sustainable biomass feedstock through morphological, elemental, thermal, calorific, and statistical analysis. Scanning electron microscopy revealed that granulated samples exhibited uniform morphology with larger particle sizes and stable porosity, favouring consistent thermal degradation. In contrast, powdered samples displayed irregular particle distribution and higher pore sizes, contributing to faster decomposition. Energy dispersive X-ray spectroscopy confirmed high carbon content in both forms, with powdered samples reaching 72.6% and granulated samples 62.5%, while oxygen ranged from 26.68% to 38.14%. The carbon-to-oxygen ratios were 2.72 for powdered and 1.62 for granulated, directly influencing volatile release and energy yield during pyrolysis. Fourier transform infrared spectroscopy identified hydroxyl, carbonyl, and amine groups favourable for bio-oil and biochar production. Thermogravimetric analysis indicated major mass loss between 250 to 450°C, associated with hemicellulose, cellulose, and lignin degradation, with a peak decomposition rate at 385°C. Higher heating values, calculated from elemental and proximate data, ranged from 6.54 to 7.54 kWh/kg, with powdered samples showing higher conversion efficiency. Statistical validation using Welch’s <i>t</i>-test confirmed significant differences (<i>p</i> < 0.05) between powdered and granulated forms, reinforcing the reliability of the observed trends. The results suggest that powdered samples are advantageous for rapid decomposition and higher energy output, while granulated forms provide structural stability and sustained energy release. Overall, the findings highlight the complementary roles of particle size and feedstock form in optimizing pyrolysis pathways, with granulated wood apple shells being particularly suited for controlled and stable bio-oil production.</p></div>","PeriodicalId":487,"journal":{"name":"BioEnergy Research","volume":"18 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145456451","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-06DOI: 10.1007/s12155-025-10918-9
Debora Guerino Boico, Salah Din Mahmud Hasan, João Vitor Pessini, Jéssyca Ketterine Carvalho, Edson Antonio da Silva, Emmanuel Zullo Godinho, Fernando de Lima Caneppele
This work deals with the modeling of the enzymatic hydrolysis of pretreated sugarcane bagasse (SB) for fermentable sugars production, where the response surface methodology (RSM) and the adaptive neuro-fuzzy inference system (ANFIS) approach were evaluated. Fuzzy logic is one of the many techniques used by artificial intelligence, which seeks to create intelligent systems capable of solving complex problems and learning from available information. Enzymatic hydrolysis (pH 5.0) of pretreated SB was performed at laboratory (bottles) using commercial cellulase (Sigma, obtained from A. niger with activity of 1.47 U.mg− 1) in a shaker incubator with 120 rpm and 50 °C. Initially, the RSM was used for evaluating the effects of three variables of hydrolysis and subsequently, ANFIS was tested. The input variables considered in the models were hydrolysis time (t), enzyme concentration (E), and substrate concentration (S), while the yield of sugars (glucose) served as the response (output) variable. The RSM modeling showed a good fitting in this work (R2 = 0.9859). The ANFIS tool efficiently predicted the glucose yield (R2 = 0.9992). The optimal response, achieving a glucose yield of 25.0 g L− 1 occurred at process settings of t = 60 h, E = 3.3%, and S = 23.3 g L− 1. In conclusion, the ANFIS methodology represents an interesting alternative for modeling of complex chemical processes, especially in those cases where RSM falls short in achieving satisfactory results in terms of model fitting.
这项工作涉及预处理甘蔗渣(SB)用于发酵糖生产的酶解建模,其中响应面法(RSM)和自适应神经模糊推理系统(ANFIS)方法进行了评估。模糊逻辑是人工智能使用的众多技术之一,旨在创建能够解决复杂问题并从可用信息中学习的智能系统。在实验室(瓶)使用商业纤维素酶(Sigma,从黑曲霉中获得,活性为1.47 U.mg - 1),在摇床培养箱中以120 rpm和50°C进行酶解(pH 5.0)预处理SB。最初,RSM用于评估三个水解变量的影响,随后,ANFIS进行了测试。模型中考虑的输入变量是水解时间(t)、酶浓度(E)和底物浓度(S),而糖(葡萄糖)的产量作为响应(输出)变量。RSM模型拟合效果较好(R2 = 0.9859)。ANFIS工具有效预测葡萄糖产率(R2 = 0.9992)。在t = 60 h, E = 3.3%, S = 23.3 g L−1的工艺设置下,葡萄糖产率达到25.0 g L−1。总之,ANFIS方法代表了复杂化学过程建模的一种有趣的替代方法,特别是在RSM在模型拟合方面达不到令人满意的结果的情况下。
{"title":"Modeling of Enzymatic Hydrolysis of Sugarcane Bagasse for Fermentable Sugar Production Using Response Surface Methodology and Adaptive Neuro-fuzzy Inference System","authors":"Debora Guerino Boico, Salah Din Mahmud Hasan, João Vitor Pessini, Jéssyca Ketterine Carvalho, Edson Antonio da Silva, Emmanuel Zullo Godinho, Fernando de Lima Caneppele","doi":"10.1007/s12155-025-10918-9","DOIUrl":"10.1007/s12155-025-10918-9","url":null,"abstract":"<div><p>This work deals with the modeling of the enzymatic hydrolysis of pretreated sugarcane bagasse (SB) for fermentable sugars production, where the response surface methodology (RSM) and the adaptive neuro-fuzzy inference system (ANFIS) approach were evaluated. Fuzzy logic is one of the many techniques used by artificial intelligence, which seeks to create intelligent systems capable of solving complex problems and learning from available information. Enzymatic hydrolysis (pH 5.0) of pretreated SB was performed at laboratory (bottles) using commercial cellulase (Sigma, obtained from <i>A. niger</i> with activity of 1.47 U.mg<sup>− 1</sup>) in a shaker incubator with 120 rpm and 50 °C. Initially, the RSM was used for evaluating the effects of three variables of hydrolysis and subsequently, ANFIS was tested. The input variables considered in the models were hydrolysis time (t), enzyme concentration (E), and substrate concentration (S), while the yield of sugars (glucose) served as the response (output) variable. The RSM modeling showed a good fitting in this work (R<sup>2</sup> = 0.9859). The ANFIS tool efficiently predicted the glucose yield (R<sup>2</sup> = 0.9992). The optimal response, achieving a glucose yield of 25.0 g L<sup>− 1</sup> occurred at process settings of t = 60 h, E = 3.3%, and S = 23.3 g L<sup>− 1</sup>. In conclusion, the ANFIS methodology represents an interesting alternative for modeling of complex chemical processes, especially in those cases where RSM falls short in achieving satisfactory results in terms of model fitting.</p></div>","PeriodicalId":487,"journal":{"name":"BioEnergy Research","volume":"18 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145456582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-05DOI: 10.1007/s12155-025-10913-0
Edvaldo Pereira Santos Júnior, Luiz Moreira Coelho Junior, Felipe Firmino Diniz, Paulo Rotella Junior, Monica Carvalho, Rômulo Simões Cezar Menezes
This study assesses the economic viability of sustainable forest management plans (SFMPs) for fuelwood production in a semi-arid region of Brazil through a probabilistic assessment, offering insights for financially viable and environmentally sustainable production. Data from operational SFMPs in Pernambuco were used to parameterize the analysis. Net Present Value (NPV), Internal Rate of Return (IRR), Uniform Annual Equivalent Value (UAEV), and Discounted Payback were used as feasibility criteria. After the deterministic analysis, a sensitivity analysis was conducted to determine the riskiest variables, followed by a Monte Carlo simulation to quantify associated risks and uncertainties. The deterministic results showed an average NPV of R$527,101.28 and an IRR of 36.56% in a scenario considering land costs. The average probability of viability was 78.43% and 84.65% for the scenarios with and without land costs. Large properties showed higher returns and a payback period of only two years, highlighting economies of scale. The price of firewood was identified as a critical variable for the attractiveness of the projects. These findings offer concrete support for producers and policymakers, highlighting opportunities to strengthen the regional economy and sustainably expand the use of firewood for energy.
{"title":"Economic Analysis of Firewood Production under Uncertainty in Sustainable Forest Management Plans in the Brazilian Semi-Arid Region","authors":"Edvaldo Pereira Santos Júnior, Luiz Moreira Coelho Junior, Felipe Firmino Diniz, Paulo Rotella Junior, Monica Carvalho, Rômulo Simões Cezar Menezes","doi":"10.1007/s12155-025-10913-0","DOIUrl":"10.1007/s12155-025-10913-0","url":null,"abstract":"<div><p>This study assesses the economic viability of sustainable forest management plans (SFMPs) for fuelwood production in a semi-arid region of Brazil through a probabilistic assessment, offering insights for financially viable and environmentally sustainable production. Data from operational SFMPs in Pernambuco were used to parameterize the analysis. Net Present Value (NPV), Internal Rate of Return (IRR), Uniform Annual Equivalent Value (UAEV), and Discounted Payback were used as feasibility criteria. After the deterministic analysis, a sensitivity analysis was conducted to determine the riskiest variables, followed by a Monte Carlo simulation to quantify associated risks and uncertainties. The deterministic results showed an average NPV of R$527,101.28 and an IRR of 36.56% in a scenario considering land costs. The average probability of viability was 78.43% and 84.65% for the scenarios with and without land costs. Large properties showed higher returns and a payback period of only two years, highlighting economies of scale. The price of firewood was identified as a critical variable for the attractiveness of the projects. These findings offer concrete support for producers and policymakers, highlighting opportunities to strengthen the regional economy and sustainably expand the use of firewood for energy.</p></div>","PeriodicalId":487,"journal":{"name":"BioEnergy Research","volume":"18 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145456508","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-05DOI: 10.1007/s12155-025-10919-8
Benan İnan
The escalating demand for sustainable and carbon-neutral energy sources has intensified research into biodiesel production from renewable feedstocks using environmentally friendly catalysts. This study presents the synthesis and application of a low-cost solid acid catalyst derived from tomato stalk, a widely available agricultural waste, for biodiesel production from microalgal oil. The catalyst was prepared via carbonization and subsequent sulfonation, and its physicochemical characteristics were thoroughly evaluated. The highest sulfonic acid density was achieved at a carbonization temperature of 500 °C and sulfonation at 100 °C for 5 h. Under the conditions of 9:1 methanol/oil molar ratio, 5 wt% catalyst and 60 min resulted with a biodiesel yield of 93%. Statistical analysis confirmed the significant influence of carbonization parameters on catalytic efficiency. Compared to conventional homogeneous acid catalysts, produced biochar based solid acid catalyst offers a greener and reusable alternative for biodiesel synthesis. Moreover, the valorization of tomato stalk waste into high-performance catalysts aligns with circular bioeconomy principles, addressing both agricultural waste management and renewable fuel production. This work shows a promising route toward overcoming key economic and ecological barriers in biofuel technology, thereby contributing to the broader transition toward sustainable energy systems.
{"title":"Agricultural Residue Derived Solid Acid Catalyst: Tomato Stalk Biochar for Biodiesel Production","authors":"Benan İnan","doi":"10.1007/s12155-025-10919-8","DOIUrl":"10.1007/s12155-025-10919-8","url":null,"abstract":"<div><p>The escalating demand for sustainable and carbon-neutral energy sources has intensified research into biodiesel production from renewable feedstocks using environmentally friendly catalysts. This study presents the synthesis and application of a low-cost solid acid catalyst derived from tomato stalk, a widely available agricultural waste, for biodiesel production from microalgal oil. The catalyst was prepared via carbonization and subsequent sulfonation, and its physicochemical characteristics were thoroughly evaluated. The highest sulfonic acid density was achieved at a carbonization temperature of 500 °C and sulfonation at 100 °C for 5 h. Under the conditions of 9:1 methanol/oil molar ratio, 5 wt% catalyst and 60 min resulted with a biodiesel yield of 93%. Statistical analysis confirmed the significant influence of carbonization parameters on catalytic efficiency. Compared to conventional homogeneous acid catalysts, produced biochar based solid acid catalyst offers a greener and reusable alternative for biodiesel synthesis. Moreover, the valorization of tomato stalk waste into high-performance catalysts aligns with circular bioeconomy principles, addressing both agricultural waste management and renewable fuel production. This work shows a promising route toward overcoming key economic and ecological barriers in biofuel technology, thereby contributing to the broader transition toward sustainable energy systems.</p></div>","PeriodicalId":487,"journal":{"name":"BioEnergy Research","volume":"18 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145456506","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-11-05DOI: 10.1007/s12155-025-10905-0
Rana Taşkın, Sıdıka Tuğçe Kalkan, Nuri Azbar
This study aimed to assess the environmental impact of converting biogas to biomethane using ex situ, hydrogenotrophic methods with hydrogen (H₂) sourced from alternative production lines. The base scenario used electricity from the national grid, while scenarios 1 and 2 used solar power via photovoltaic panels and wind power, respectively. A life cycle analysis (LCA) was conducted for the different energy source scenarios. The results were evaluated using the ReCiPe 2016 Midpoint (H) impact assessment method, which considers 18 impact categories. A model was developed based on production data from a real biogas plant in Izmir, for which activity data were obtained directly from the plant’s logs. The LCA analysis revealed that producing hydrogen from grid electricity resulted in 10.3 kg of CO₂ equivalent in the climate change category, a figure that decreased to 1.27 kg of CO₂ equivalent when solar energy was used instead. Overall, the carbon footprint decreased from 8.66 to − 0.494 kg CO₂ eq. In the second scenario, hydrogen was produced using wind energy rather than grid electricity. The analysis indicated that producing hydrogen from grid electricity resulted in 10.3 kg CO₂ eq in the climate change category, whereas using wind energy reduced this figure to 0.199 kg CO₂ eq. The LCA results demonstrate that energy sources and electricity demand play a crucial role in determining GHG emissions and that the LCA can assist companies and governments in decision-making and policy development.
本研究旨在评估利用来自替代生产线的氢(H₂),利用非原位氢化方法将沼气转化为生物甲烷对环境的影响。基本方案使用来自国家电网的电力,而方案1和方案2分别通过光伏板和风力发电使用太阳能。对不同的能源方案进行了生命周期分析。使用ReCiPe 2016 Midpoint (H)影响评估方法对结果进行评估,该方法考虑了18个影响类别。根据伊兹密尔一家真实的沼气厂的生产数据开发了一个模型,其活动数据直接从工厂的日志中获得。LCA分析结果显示,在气候变化范畴中,利用电网发电产生氢气产生的二氧化碳当量为10.3公斤,而利用太阳能产生的二氧化碳当量为1.27公斤。总体而言,碳足迹从8.66 kg CO₂当量减少到- 0.494 kg CO₂当量。在第二种方案中,氢气是利用风能而不是电网电力生产的。分析表明,在气候变化类别中,电网制氢产生10.3 kg CO₂eq,而使用风能则使这一数字减少到0.199 kg CO₂eq。LCA结果表明,能源和电力需求在决定温室气体排放方面起着至关重要的作用,LCA可以帮助企业和政府制定决策和政策。
{"title":"Life Cycle Analysis (LCA) of Hydrogen Boosted Biomethanization with Alternative Power Scenarios","authors":"Rana Taşkın, Sıdıka Tuğçe Kalkan, Nuri Azbar","doi":"10.1007/s12155-025-10905-0","DOIUrl":"10.1007/s12155-025-10905-0","url":null,"abstract":"<div><p>This study aimed to assess the environmental impact of converting biogas to biomethane using ex situ, hydrogenotrophic methods with hydrogen (H₂) sourced from alternative production lines. The base scenario used electricity from the national grid, while scenarios 1 and 2 used solar power via photovoltaic panels and wind power, respectively. A life cycle analysis (LCA) was conducted for the different energy source scenarios. The results were evaluated using the ReCiPe 2016 Midpoint (H) impact assessment method, which considers 18 impact categories. A model was developed based on production data from a real biogas plant in Izmir, for which activity data were obtained directly from the plant’s logs. The LCA analysis revealed that producing hydrogen from grid electricity resulted in 10.3 kg of CO₂ equivalent in the climate change category, a figure that decreased to 1.27 kg of CO₂ equivalent when solar energy was used instead. Overall, the carbon footprint decreased from 8.66 to − 0.494 kg CO₂ eq. In the second scenario, hydrogen was produced using wind energy rather than grid electricity. The analysis indicated that producing hydrogen from grid electricity resulted in 10.3 kg CO₂ eq in the climate change category, whereas using wind energy reduced this figure to 0.199 kg CO₂ eq. The LCA results demonstrate that energy sources and electricity demand play a crucial role in determining GHG emissions and that the LCA can assist companies and governments in decision-making and policy development.</p></div>","PeriodicalId":487,"journal":{"name":"BioEnergy Research","volume":"18 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145456507","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-23DOI: 10.1007/s12155-025-10911-2
Thamires Custódio Jeremias, Ana Carla Sorgato, María Ángeles Lobo-Recio, Flávio Rubens Lapolli
Discharging untreated industrial or municipal wastewater containing high levels of nutrients, such as nitrogen and phosphorus, into aquatic systems poses significant environmental concerns such as eutrophication. In addition, the urgent need to replace fossil fuels with renewable energy sources is crucial for achieving sustainable development. Microbial fuel cells (MFCs) provide an environmentally sustainable approach by utilizing microorganism metabolisms for bioelectricity generation and wastewater treatment. Consequently, MFC technology holds great promise for addressing water and energy issues. MFCs are bioelectrochemical hybrid systems that integrate bioelectricity generation, wastewater treatment, fouling mitigation, and water desalination. Despite the growing interest in MFCs, a critical gap remains in understanding how recent innovations in hybrid configurations impact performance and scalability. This review provides a novel perspective by analyzing the latest technological advancements and their role in overcoming key operational challenges. Recent trends in hybrid systems, such as UASB-MFC (up-flow anaerobic bed-MFC), EMBR-MFC (electro-membrane bioreactor-MFC), CW-MFC (constructed wetland-MFC), and MDC (microbial desalination cell), are thoroughly described. This study highlights the importance of MFCs in providing sustainable, clean, and renewable systems for bioenergy generation and wastewater treatment. Furthermore, it identifies critical knowledge gaps and proposes targeted future research directions to optimize power output, improve efficiency, and enhance long-term system performance. By addressing these gaps, this review contributes to advancing MFC technology towards real-world applications in sustainable energy and wastewater management.
{"title":"Recent Advances and Emerging Trends in Microbial Fuel Cell Toward Sustainable Wastewater Treatment and Bioelectricity Generation: Fundamentals, Applications, and Hybrid Systems","authors":"Thamires Custódio Jeremias, Ana Carla Sorgato, María Ángeles Lobo-Recio, Flávio Rubens Lapolli","doi":"10.1007/s12155-025-10911-2","DOIUrl":"10.1007/s12155-025-10911-2","url":null,"abstract":"<div><p>Discharging untreated industrial or municipal wastewater containing high levels of nutrients, such as nitrogen and phosphorus, into aquatic systems poses significant environmental concerns such as eutrophication. In addition, the urgent need to replace fossil fuels with renewable energy sources is crucial for achieving sustainable development. Microbial fuel cells (MFCs) provide an environmentally sustainable approach by utilizing microorganism metabolisms for bioelectricity generation and wastewater treatment. Consequently, MFC technology holds great promise for addressing water and energy issues. MFCs are bioelectrochemical hybrid systems that integrate bioelectricity generation, wastewater treatment, fouling mitigation, and water desalination. Despite the growing interest in MFCs, a critical gap remains in understanding how recent innovations in hybrid configurations impact performance and scalability. This review provides a novel perspective by analyzing the latest technological advancements and their role in overcoming key operational challenges. Recent trends in hybrid systems, such as UASB-MFC (up-flow anaerobic bed-MFC), EMBR-MFC (electro-membrane bioreactor-MFC), CW-MFC (constructed wetland-MFC), and MDC (microbial desalination cell), are thoroughly described. This study highlights the importance of MFCs in providing sustainable, clean, and renewable systems for bioenergy generation and wastewater treatment. Furthermore, it identifies critical knowledge gaps and proposes targeted future research directions to optimize power output, improve efficiency, and enhance long-term system performance. By addressing these gaps, this review contributes to advancing MFC technology towards real-world applications in sustainable energy and wastewater management.</p></div>","PeriodicalId":487,"journal":{"name":"BioEnergy Research","volume":"18 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145352419","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-10-22DOI: 10.1007/s12155-025-10903-2
Gaurav Kumar, Taraneh Sowlati
As the global demand for fossil-based products increases, biomass offers a sustainable and renewable alternative. However, its utilization faces significant supply chain challenges. The biomass supply chain (BSC) encompasses harvesting, collection, transportation, storage, preprocessing, production, and delivery of bio-products. High moisture content and low calorific value of biomass result in high cost of logistics, and consequently high cost of delivered biomass. Other challenges in BSC are related to uncertainties and variations in biomass availability and quality, weather conditions, demand, prices, costs, and policies. Integrating strategic, tactical, and operational decisions is essential to ensure that high-level plans are implementable at lower levels; however, accounting for uncertainties in such integrated decision-making models requires advanced techniques. This paper reviews existing studies on hybrid simulation optimization techniques—specifically the integration of simulation models (e.g., Discrete Event Simulation) with optimization approaches (e.g., mixed integer linear programming)) in BSC management, focusing on forest-based, agricultural BSC planning, and biomass to biofuel/bioenergy supply chain planning. The studies are further categorized into three subgroups based on their use of hybrid models: (1) manage uncertainties, (2) tackle large-scale problems, and (3) interpret complex interdependencies. We analyzed 31 articles published till July 2025 using a systematic approach that combines bibliometric and descriptive analyses. The most commonly applied simulation and optimization approaches were Monte Carlo, discrete event simulation, mixed integer linear programming, and stochastic modeling. Future research could focus on developing multi-objective hybrid models to address sustainability, using machine learning techniques to address uncertainties, and considering relevant governmental policies in the models. Emphasis on resiliency and use of agent-based simulation can enhance decision-making and sustainability.
{"title":"Hybrid Simulation Optimization Method for Biomass Supply Chain Planning: A Systematic Review","authors":"Gaurav Kumar, Taraneh Sowlati","doi":"10.1007/s12155-025-10903-2","DOIUrl":"10.1007/s12155-025-10903-2","url":null,"abstract":"<div><p>As the global demand for fossil-based products increases, biomass offers a sustainable and renewable alternative. However, its utilization faces significant supply chain challenges. The biomass supply chain (BSC) encompasses harvesting, collection, transportation, storage, preprocessing, production, and delivery of bio-products. High moisture content and low calorific value of biomass result in high cost of logistics, and consequently high cost of delivered biomass. Other challenges in BSC are related to uncertainties and variations in biomass availability and quality, weather conditions, demand, prices, costs, and policies. Integrating strategic, tactical, and operational decisions is essential to ensure that high-level plans are implementable at lower levels; however, accounting for uncertainties in such integrated decision-making models requires advanced techniques. This paper reviews existing studies on hybrid simulation optimization techniques—specifically the integration of simulation models (e.g., Discrete Event Simulation) with optimization approaches (e.g., mixed integer linear programming)) in BSC management, focusing on forest-based, agricultural BSC planning, and biomass to biofuel/bioenergy supply chain planning. The studies are further categorized into three subgroups based on their use of hybrid models: (1) manage uncertainties, (2) tackle large-scale problems, and (3) interpret complex interdependencies. We analyzed 31 articles published till July 2025 using a systematic approach that combines bibliometric and descriptive analyses. The most commonly applied simulation and optimization approaches were Monte Carlo, discrete event simulation, mixed integer linear programming, and stochastic modeling. Future research could focus on developing multi-objective hybrid models to address sustainability, using machine learning techniques to address uncertainties, and considering relevant governmental policies in the models. Emphasis on resiliency and use of agent-based simulation can enhance decision-making and sustainability.</p></div>","PeriodicalId":487,"journal":{"name":"BioEnergy Research","volume":"18 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145352866","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}