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A Stochastic Techno-Economic Analysis of Forest Biomass Feedstock Supply Chains: Clean and Dirty Chips for Bioenergy Applications 森林生物质原料供应链的随机技术经济分析:生物能源应用中的清洁和肮脏木片
IF 3.6 3区 工程技术 Q1 Agricultural and Biological Sciences Pub Date : 2024-05-02 DOI: 10.1007/s12155-024-10764-1
HakSoo Ha, Tristan R. Brown, Ryan J. Quinn, Timothy A. Volk, Robert W. Malmsheimer, Marie-Odile P. Fortier, Steven Bick, Jenny R. Frank

This study reports results from a stochastic techno-economic analysis (TEA) model that assessed the financial feasibility of forest biomass harvest for low-carbon bioenergy feedstocks in the hardwood region of the Northeast United States. It analyzed three 24-year scenarios based on primary data collected from the mixed product harvest with whole tree harvesting systems that primarily produce clean chips, dirty chips, or pulpwood and dirty chips. Using a joint product costing approach, proportional costs of shared processes were allocated to different products on a mass basis. Uncertainty associated with key stochastic variables was incorporated into the model to generate net present values (NPV), benefit–cost ratios (BCR), and minimum selling prices (MSP) via Monte Carlo simulation. The clean chip scenario produced an NPV of $1.36 million and a BCR of 1.03, while the pulpwood scenario’s NPV and BCR ($0.06 million and 1.02) were lower, and the dirty chip scenario generated negative NPV (− $0.02 million) and a BCR of 0.99. The probabilities of achieving positive NPVs for all three scenarios fell between 47 and 56%. The mean MSP for one clean chip scenario was $94.03/dry Mg, while the mean MSPs for two dirty chip scenarios were $74.79/dry Mg and $75.93/dry Mg. NPV results were most sensitive to forest biomass feedstock harvesting production levels, transportation distances, and delivered prices, followed by diesel fuel consumption for in-wood harvest and diesel fuel price.

本研究报告了一个随机技术经济分析(TEA)模型的结果,该模型评估了在美国东北部硬木地区采伐森林生物质作为低碳生物能源原料的经济可行性。该模型根据从混合产品采伐中收集的原始数据,分析了三种为期 24 年的情景,即主要生产清洁木片、脏木片或纸浆材和脏木片的整树采伐系统。采用联合产品成本计算法,将共享流程的比例成本按质量分配给不同产品。与关键随机变量相关的不确定性被纳入模型,通过蒙特卡罗模拟生成净现值 (NPV)、效益成本比 (BCR) 和最低销售价格 (MSP)。清洁木片方案产生了 136 万美元的净现值和 1.03 的 BCR,而纸浆材方案的净现值和 BCR(6 万美元和 1.02)较低,肮脏木片方案产生了负净现值(-0.2 万美元)和 0.99 的 BCR。所有三种方案实现正净现值的概率介于 47% 和 56% 之间。一种清洁木片方案的平均 MSP 为 94.03 美元/干 Mg,而两种不清洁木片方案的平均 MSP 分别为 74.79 美元/干 Mg 和 75.93 美元/干 Mg。净现值结果对森林生物质原料采伐生产水平、运输距离和交货价格最为敏感,其次是林内采伐的柴油消耗量和柴油价格。
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引用次数: 0
Solvent-Mediated Extraction of Phenolics from Mid-level Oxygen Content Pyrolysis Oils 以溶剂为媒介萃取中等含氧量热解油中的酚类物质
IF 3.6 3区 工程技术 Q1 Agricultural and Biological Sciences Pub Date : 2024-04-25 DOI: 10.1007/s12155-024-10756-1
Y. Elkasabi, Charles A. Mullen, G. Strahan
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引用次数: 0
Comprehensive Evaluation of Biofuels from the Fermentation of Poplar Wood and the Gasification of Fermentation Residue 杨木发酵和发酵残渣气化产生的生物燃料综合评估
IF 3.6 3区 工程技术 Q1 Agricultural and Biological Sciences Pub Date : 2024-04-24 DOI: 10.1007/s12155-024-10760-5
Wei Wang, Zhaoping Zhong, Xiaoming Bao, Xiaotian Pan, Xiang Zheng, Yuxuan Yang, Zhaocheng Shen
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引用次数: 0
Assessing the Application of Near-Infrared Spectroscopy to Determine Saccharification Efficiency of Corn Biomass 评估应用近红外光谱测定玉米生物质的糖化效率
IF 3.6 3区 工程技术 Q1 Agricultural and Biological Sciences Pub Date : 2024-04-23 DOI: 10.1007/s12155-024-10761-4
S. Pereira-Crespo, Noemi Gesteiro, A. López-Malvar, Leonardo Gómez, Rogelio Santiago
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引用次数: 0
Bio-Oil Production from Fish Processing Waste Residues Using Oleaginous Rhodotorula sp. R1 After Conventional Oil Extraction 利用传统榨油后的含油藻 R1 从鱼类加工废料中生产生物油
IF 3.6 3区 工程技术 Q1 Agricultural and Biological Sciences Pub Date : 2024-04-22 DOI: 10.1007/s12155-024-10749-0
Fernanda Dias De Ávila, B. Okeke, Josiane Pinheiro Farias, Marcela da Silva Afonso, Márcio Santos Silva, F. A. de Oliveira Camargo, F. Bento, S. Pieniz, R. Andreazza
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引用次数: 0
Enhancing Biodegradability of Coffee Husk and Water Hyacinth Using Food Waste: Synergistic and Kinetic Evaluation Under Co-digestion 利用厨余提高咖啡渣和水葫芦的生物降解性:协同消化下的协同效应和动力学评估
IF 3.6 3区 工程技术 Q1 Agricultural and Biological Sciences Pub Date : 2024-04-20 DOI: 10.1007/s12155-024-10750-7
Mohammed Kelif Ibro, Venkata Ramayya Ancha, Dejene Beyene Lemma, Marcel Pohl

Considering the difficulty of digesting coffee husk (CH) and water hyacinth (WH) due to the lignin content, the present study investigated the influence of feedstock mixing ratios on the co-digestion performance of CH and WH with food waste (FW) at 38 ± 1 °C and its kinetics. Food waste was considered as co-substrate due to its ease of digestion. Batch experiments were conducted using CH/WH/FW ratios (100:0:0, 0:100:0, 35:35:30, 30:30:40, 25:25:50, 20:20:60, and 0:0:100 w/w) with total solids (TS) content of about 9.5% (w/v). The results indicated that the addition of FW significantly enhanced WH and CH digestion performance, with the maximum biogas yield of 572.60 (pm) 2.30 mL/gVS, best synergistic effect of 1.5, highest biodegradability of 89.22%, and a biodegradation rate of 57.82% obtained at a mix ratio of 25:25:50, which was improved by 179.71% compared to CH mono-digestion. In addition, the organic conversion efficiency of TS and volatile solids reached 69.86 and 81.48%, respectively. Conversely, CH mono-digestion yielded the lowest biogas yield of 204.71 ± 10.74 mL/g VS, highlighting its unfeasibility. The modified logistic equation showed the best fit to the experimental data. The optimum CH/WH/FW ratio of 25:25:50 demonstrated the highest biogas yield and methane content at 66.30 ± 0.76%.

Graphical Abstract

考虑到咖啡壳(CH)和水葫芦(WH)因含有木质素而难以消化,本研究调查了原料混合比对咖啡壳和水葫芦与厨余(FW)在 38 ± 1 °C下协同消化性能的影响及其动力学。由于厨余易于消化,因此将其视为共底物。使用 CH/WH/FW比例(100:0:0、0:100:0、35:35:30、30:30:40、25:25:50、20:20:60 和 0:0:100,总固体(TS)含量约为 9.5%(w/v))进行了批量实验。结果表明,FW的添加能显著提高WH和CH的消化性能,在混合比为25:25:50时,最大沼气产率为572.60/(pm/)2.30 mL/gVS,最佳协同效应为1.5,最高生物降解率为89.22%,生物降解率为57.82%,与CH单消化相比提高了179.71%。此外,TS 和挥发性固体的有机转化效率分别达到 69.86% 和 81.48%。相反,CH 单消化产生的沼气产量最低,仅为 204.71 ± 10.74 mL/g VS,凸显了其不可行性。修正的逻辑方程显示出与实验数据的最佳拟合。25:25:50 的最佳 CH/WH/FW 比率显示出最高的沼气产量和甲烷含量(66.30 ± 0.76%)。
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引用次数: 0
Bioethanol Production from Paper Sludge by Subcritical Water Pretreatment and Semi-simultaneous Saccharification and Fermentation 通过亚临界水预处理和半同步糖化发酵从造纸污泥中生产生物乙醇
IF 3.6 3区 工程技术 Q1 Agricultural and Biological Sciences Pub Date : 2024-04-19 DOI: 10.1007/s12155-024-10755-2
Idzumi Okajima, Masato Muto, Shingo Morimoto, Kazuki Nauchi, Yuta Kodama, Enoch Y. Park, Takeshi Sako

Paper sludge (PS) from paper mills has a significant potential for bioethanol production. In this study, waste-paper-containing PS is used as the raw material for bioethanol production because the annual waste paper utilization rate has increased globally. Although PS does not require delignification, the antiseptics and deinking agents in waste paper-containing PS inhibit enzymatic reactions such as saccharification and fermentation. Their removal is important, but it has not yet been reported. Using subcritical water pretreatment, the selective decomposition of enzyme inhibitors in PS is examined without the generation of other enzyme inhibitors. The optimum pretreatment conditions are identified as 240 °C, 3.3 MPa, 3 min, and pH 4.5. Glucose was obtained in 71% yield from pretreated 5 wt% PS using cellulase, which is 5.5 times higher than that from unpretreated PS. This is because the reactivity of the pretreated PS increases with increasing surface area of the cellulose fibers, and the cellulase inhibitors are decomposed by subcritical water. Next, semi-simultaneous saccharification and fermentation treatments are performed to produce bioethanol from waste-paper-containing PS. The bioethanol yield based on cellulose after 96 h is 68% for PS pretreated with subcritical water, whereas the bioethanol yield is 6% for unpretreated PS. Therefore, subcritical water pretreatment increases the bioethanol yield by 11 times. The proposed method may enable the use of large amounts of PS as ethanol feedstock in future.

造纸厂产生的造纸污泥(PS)具有生产生物乙醇的巨大潜力。在本研究中,由于全球每年的废纸利用率不断提高,因此使用含废纸的 PS 作为生物乙醇生产的原料。虽然 PS 不需要脱木素,但含废纸 PS 中的防腐剂和脱墨剂会抑制糖化和发酵等酶促反应。去除这些物质非常重要,但目前还没有相关报道。利用亚临界水预处理,研究了如何在不产生其他酶抑制剂的情况下选择性地分解 PS 中的酶抑制剂。最佳预处理条件为 240°C、3.3 兆帕、3 分钟和 pH 值 4.5。使用纤维素酶预处理 5 wt% PS 后,葡萄糖的产率为 71%,是未预处理 PS 产率的 5.5 倍。这是因为预处理过的 PS 的反应活性随着纤维素纤维表面积的增加而增加,而且纤维素酶抑制剂会被亚临界水分解。接下来,进行半同步糖化和发酵处理,从含废纸的 PS 中生产生物乙醇。经亚临界水预处理的 PS 在 96 小时后的纤维素生物乙醇产量为 68%,而未经预处理的 PS 的生物乙醇产量为 6%。因此,亚临界水预处理可将生物乙醇产量提高 11 倍。所提出的方法可在未来将大量 PS 用作乙醇原料。
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引用次数: 0
Anaerobic Digestion Enhancement of Brewery Sludge Assisted by Exogenous Hydrogen 外源氢气辅助啤酒厂污泥的厌氧消化强化作用
IF 3.6 3区 工程技术 Q1 Agricultural and Biological Sciences Pub Date : 2024-04-19 DOI: 10.1007/s12155-024-10758-z
Shiyue Liu, Xingdi Ma, Sue Yao, Xingyun Zhu, Yongguang Ma, Zhiqiang Chen, Jiyan Liang

The purification of biogas as a product of anaerobic digestion has gradually become a research focus. In situ hydrogen-assisted biogas purification is an effective way to enhance the reaction rate, but the solubility and mass transfer efficiency of hydrogen are the difficulties that constrain the technology. Thus, four continuous hydrogen injection modes M1: 1 mL/min, M2: 2 mL/min, M3: 5 mL/min, and M4: 10 mL/min and two intermittent hydrogen injection modes A: 4 mL/min ( interval 20 min ) and B: 6 mL/min ( interval 40 min ) were designed to explore the effect of different hydrogen injection modes on in situ biogas upgrading of upflow anaerobic sludge bed (UASB) in the research. The results showed that the methane production showed a trend of increasing first and then decreasing in continuous hydrogenation experiment. The CH4 production reached its peak at 86.2% in the M2 stage. In the two batch hydrogenation tests, group A showed better hydrogenation effect with a CH4 production of about 92%, which was 4% higher than that of group B. The hydrogenotrophic methanogens (HMs) in group A archaea community were more effectively enriched, with an abundance of 52.83% of Methanobacterium. The results illustrate that proper hydrogen injection can enhance anaerobic digestion and promote biogas purification, and the effect of short-term intermittent hydrogen injection is more significant.

沼气作为厌氧消化的产物,其净化已逐渐成为研究重点。原位氢气辅助沼气净化是提高反应速率的有效途径,但氢气的溶解度和传质效率是制约该技术的难点。因此,四种连续氢气注入模式 M1: 1 mL/min、M2: 2 mL/min、M3:研究设计了四种连续注氢模式 M1:1 mL/min、M2:2 mL/min、M3:5 mL/min、M4:10 mL/min,以及两种间歇注氢模式 A:4 mL/min(间隔 20 分钟)和 B:6 mL/min(间隔 40 分钟),以探讨不同注氢模式对上流式厌氧污泥床(UASB)沼气原位升级的影响。结果表明,在连续加氢实验中,甲烷产量呈先增后减的趋势。在 M2 阶段,CH4 产量达到峰值,为 86.2%。在两次批量加氢试验中,A 组的加氢效果更好,CH4 产率约为 92%,比 B 组高出 4%;A 组古细菌群落中的亲氢甲烷菌(HMs)得到了更有效的富集,其中甲烷杆菌的丰度为 52.83%。结果表明,适当注氢可提高厌氧消化率,促进沼气净化,而短期间歇注氢的效果更为显著。
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引用次数: 0
The Assessment of the Operational Performance of a Dry Anaerobic Reactor of Cambuci Husks to Bioenergy Potential and Biorefinery Integration 评估干式厌氧反应器的生物能源和生物精炼一体化潜力
IF 3.6 3区 工程技术 Q1 Agricultural and Biological Sciences Pub Date : 2024-04-17 DOI: 10.1007/s12155-024-10759-y
Luana R. R. Fröner-Lacerda, Vinícius F. Lacerda, Larissa C. Ampese, Henrique D. D. Ziero, Montserrat Pérez, Tânia Forster-Carneiro

Anaerobic digestion plays a significant role in obtaining renewable energy through biogas production, reducing greenhouse gas emissions, helping with waste management, and bringing economic and social benefits. This work aims to examine approaches for the treatment and use of cambuci bagasse, identifying typical problems and proposing solutions concerning the application of the technique, control of operational parameters, management in dry regime conditions, optimization of efficiency, and increased productivity, using anaerobic digestion as a fundamental and central technology. The results showed the potential of electric energy and heat that could be generated by burning the biomass in a CHP system. Also, they presented the respective avoided greenhouse gas emissions in situations where biogas is applied to replace conventional heat or electricity sources. The biogas average production ratio was 102.69 m³/ton of cambuci by-product with a methane composition of around 60% in the 24th to 30th days. The experimental data obtained was subjected to calculations that indicate an electric generation of 202.98 kWh/ton of cambuci biomass and heat generation of 913.40 MJ/ton of cambuci biomass. In this theoretical scenario, for each ton of cambuci, it is possible to produce 913.4 MJ of thermal energy and 202.98 kWh of electric energy, considering the biogas burning into a CHP system. In the analysis of types of substrates regarding growth capacity, it was concluded that the substrate with a 30% dilution of the digested end was the one that showed the best growth of the cultivar’s stem, obtaining a CEC of 9.1516 mol/g.

Graphical Abstract

厌氧消化在通过生产沼气获得可再生能源、减少温室气体排放、帮助废物管理以及带来经济和社会效益方面发挥着重要作用。这项工作旨在研究处理和利用甘蔗渣的方法,找出典型问题,并提出解决方案,涉及技术应用、运行参数控制、干燥条件下的管理、效率优化和提高生产率,将厌氧消化作为一项基础和核心技术。研究结果表明,在热电联产系统中燃烧生物质可以产生电能和热能。此外,他们还介绍了在用沼气替代传统热源或电源的情况下各自避免的温室气体排放量。在第 24 至 30 天,沼气平均生产率为 102.69 立方米/吨沼气副产品,甲烷成分约为 60%。对获得的实验数据进行计算后发现,每吨沼渣生物质可产生 202.98 千瓦时的电能,每吨沼渣生物质可产生 913.40 兆焦耳的热量。在这种理论情况下,考虑到将沼气燃烧到热电联产系统中,每吨沼气可产生 913.4 兆焦耳的热能和 202.98 千瓦时的电能。在对基质类型的生长能力进行分析后得出的结论是,消化末稀释 30% 的基质对栽培品种的茎干生长最有利,其 CEC 为 9.1516 mol/g。
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引用次数: 0
Zero-Waste Bioenergy to Lower Energy Transition Risks in Indonesia — A Circular Economy Practice on Methane Capture in Biogas Production from POME 零废弃生物能源降低印度尼西亚能源转型风险--利用 POME 生产沼气过程中的甲烷捕获的循环经济实践
IF 3.6 3区 工程技术 Q1 Agricultural and Biological Sciences Pub Date : 2024-04-16 DOI: 10.1007/s12155-024-10754-3
Arnita Rishanty, Maxensius Tri Sambodo, Mesnan Silalahi, Erliza Hambali

Driven by the urgent need to address climate change, Indonesia, as the world’s largest palm oil producer, faces the challenge of ensuring the sustainability of this industry. This study addresses a critical gap in knowledge by examining the technological advancements in methane capture for bioenergy from palm oil mill effluent (POME), exploring business development applications, and assessing the potential role of methane capture in advancing Indonesia’s Enhanced Nationally Determined Contribution (NDC) targets. Employing both quantitative and qualitative methodologies, the study reveals three key findings. Firstly, a systematic literature review highlights a dearth of research on the social and economic aspects of utilizing biomethane gas, particularly in modeling contexts. Secondly, through case studies, the utilization of methane gas as an energy source is shown to significantly reduce electricity expenditures, diminish reliance on fossil fuels, mitigate carbon emissions, and expand access to clean energy for both companies and households. Thirdly, the scenario of converting POME waste into energy can help to reach the target on carbon emissions, but it depends on the level of waste utilization and capacity factor. By repurposing palm oil industry waste for clean energy production instead of expanding land use, which poses risks to biodiversity, Indonesia can mitigate the challenges of the energy transition and foster a more sustainable future.

由于迫切需要应对气候变化,作为世界上最大的棕榈油生产国,印度尼西亚面临着确保该行业可持续发展的挑战。本研究通过考察从棕榈油厂废水(POME)中捕获甲烷用于生物能源的技术进步、探索业务发展应用以及评估甲烷捕获在推进印尼 "增强型国家确定贡献"(NDC)目标方面的潜在作用,填补了知识方面的重大空白。本研究采用定量和定性方法,揭示了三个主要发现。首先,系统性文献综述显示,有关生物甲烷气体利用的社会和经济方面的研究十分匮乏,尤其是在建模环境下。其次,通过案例研究表明,利用甲烷气体作为能源可显著降低电费支出,减少对化石燃料的依赖,减少碳排放,并扩大公司和家庭获得清洁能源的途径。第三,将 POME 废弃物转化为能源的方案有助于实现碳排放目标,但这取决于废弃物的利用水平和能力因素。通过将棕榈油行业废物重新用于清洁能源生产,而不是扩大土地使用(这会给生物多样性带来风险),印度尼西亚可以减轻能源转型的挑战,并促进更可持续的未来。
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引用次数: 0
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