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A thermo-hydro-mechanical-chemical coupled phase field framework for modeling fractures in porous rocks: the dual-fracture model 模拟多孔岩石裂缝的热-水-力-化学耦合相场框架:双裂缝模型
IF 5.7 1区 工程技术 Q1 ENGINEERING, GEOLOGICAL Pub Date : 2025-08-05 DOI: 10.1007/s11440-025-02713-9
Rui Liu, Shuwei Zhou, Shikang Qin, Shanpeng Cao, Xiaoying Zhuang, Timon Rabczuk

A THMC coupled phase field framework for modeling fractures in porous rocks is proposed in this study. The framework introduces additionally the damage variable governed synergistically by the phase field and chemical field to account for dual-fracture mechanisms. Through this damage variable, full coupling of the temperature, hydraulic, mechanical, chemical, and phase fields is achieved. Implemented on the COMSOL Multiphysics platform, this multi-field coupling framework is solved by using a staggered iteration algorithm. The proposed framework was verified through fracture propagation induced by various factors. Furthermore, two-dimensional case studies are conducted to investigate the effects of acid concentration, heterogeneity, injection rate, specific surface area, and scale parameters on fracture morphology, fluid pressure distribution, temperature distribution, pressure evolution, and fracture propagation range. Numerical results demonstrate that the predictions of the proposed THMC coupled phase field model for fracture evolution and acid breakthrough consumption align with existing studies, while effectively characterizing the influence of sensitivity parameters.

本文提出了一种模拟多孔岩石裂缝的THMC耦合相场框架。该框架还引入了由相场和化学场协同控制的损伤变量,以解释双断裂机制。通过这个损伤变量,实现了温度、液压、机械、化学和相场的完全耦合。该多场耦合框架在COMSOL Multiphysics平台上实现,采用交错迭代算法求解。通过各种因素诱导的断裂扩展验证了所提出的框架。通过二维实例研究,探讨了酸浓度、非均质性、注入速率、比表面积和尺度参数对裂缝形态、流体压力分布、温度分布、压力演化和裂缝扩展范围的影响。数值结果表明,提出的THMC耦合相场模型对裂缝演化和酸突破消耗的预测与已有研究一致,同时有效表征了敏感性参数的影响。
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引用次数: 0
Test and DEM study on cyclic shear behavior of sand–irregular concrete interface under dynamic normal loading 动法向荷载作用下砂-不规则混凝土界面循环剪切特性试验与DEM研究
IF 5.7 1区 工程技术 Q1 ENGINEERING, GEOLOGICAL Pub Date : 2025-08-04 DOI: 10.1007/s11440-025-02723-7
Shixun Zhang, Feiyu Liu, Weixiang Zeng, Mengjie Ying

To explore the dynamic response of sand–irregular concrete interface, a series of cyclic direct shear tests were conducted under dynamic normal loading, with different joint roughness coefficient ((it {text{JRC}})) and dynamic normal loading frequency. DEM models were developed to analyze its microscopic behavior. Research results indicate that there was a critical (it {text{JRC}}) that maximized the interface shear strength. Maintaining a constant frequency of dynamic horizontal loading, changing the dynamic normal loading frequency resulted in changes in the shape of the shear stress–displacement hysteresis loops. The increase in dynamic normal loading frequency led to an increase in energy dissipation coefficient, which ranged from approximately 0.85 to 0.95. Energy introduced into the system by shearing was predominantly dissipated by internal mechanisms, mainly through slip and rolling slip. Dynamic horizontal loading would result in a decrease in the average force chain length and strength. As shearing, the anisotropy of the contact normal direction and tangential contact force of specimens significantly decreased. When the specimens were at shear stress reversal point, the anisotropic orientation of contact normal direction, normal contact force, and tangential contact force rotated toward the shear direction, and the rotation angle increased with the increase in (it {text{JRC}}).

为探讨砂-不规则混凝土界面在动法向荷载作用下的动力响应,在不同节点粗糙度系数((it {text{JRC}}))和动法向荷载频率下进行了一系列循环直剪试验。建立DEM模型分析其微观行为。研究结果表明,存在一个使界面抗剪强度最大化的临界(it {text{JRC}})。保持动水平加载频率不变,改变动法向加载频率,导致剪应力-位移滞回线形状发生变化。动法向加载频率的增加导致耗能系数的增加,其范围约为0.85 ~ 0.95。通过剪切引入系统的能量主要通过内部机制耗散,主要通过滑移和滚动滑移。动态水平加载会导致平均力链长度和强度的减小。剪切作用下,试件接触法向各向异性和切向接触力均显著降低。当试件处于剪应力反转点时,接触法向、法向接触力、切向接触力的各向异性取向均向剪切方向旋转,且旋转角度随着(it {text{JRC}})的增大而增大。
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引用次数: 0
Investigation of particle breakage along phase transition points using the particle partition potential (P3) and the loading intensity (LI) factor 利用颗粒分配势(P3)和加载强度因子(LI)研究颗粒沿相变点的破碎
IF 5.7 1区 工程技术 Q1 ENGINEERING, GEOLOGICAL Pub Date : 2025-08-04 DOI: 10.1007/s11440-025-02725-5
Andrzej Głuchowski, Magued Iskander

This study investigates the impacts of shearing and volume change on the evolution of particle size distribution in silica (Ottawa) and calcareous (Fiji Pink) sands, during the direct shear test. Results reveal Fiji sand's higher shear resistance and extensive grain crushing compared to Ottawa sand, due to differences in mineralogy and grain shape. The findings provide insights into granular soil behavior under increasing stress denoted as phase transition points that naturally occur with increasing shear. It was observed in the particle size distribution (PSD) of both sands that grain crushing initially increases the shear fraction of fines but then gradually reduces the percentage of larger grain diameters. The analysis of PSD evolution during shear was conducted using Hardin's Br, Lade's B10, and Marsal's Bm breakage index frameworks. The micro- and macro-mechanical aspects of direct shear show that to model shear effects on grain breakage, the effects of dilation (− v/dεh), internal grain friction (μ), and vertical effective stress (σ′v) conditions must be considered. The combination of these effects leads to the proposition of the particle partition potential (P3) parameter, which represents the average stress conditions acting on sand during shear. P3 can be computed from stress, strain, and volumetric change data only, but it nevertheless shows a strong linear correlation with Hardin’s Br parameter, which is measured by comparing pre- and post-test PSDs. Particle breakage was also related to the loading intensity (LI) parameter which combines the magnitude of force chains formed within particles and the duration of loading. P3 is linearly correlated with both P3 and Br, thus pointing to the effectiveness of LI in quantifying particle breakage across different sands. Finally, three additional datasets from the literature were used to calculate LI and P3 from stress–strain data and compute Br. The computed and measured Br values were well correlated with R2 = 0.91.

研究了剪切和体积变化对直剪试验中二氧化硅砂(渥太华砂)和钙质砂(斐济粉砂)粒度分布演化的影响。结果表明,由于矿物学和颗粒形状的差异,斐济砂比渥太华砂具有更高的抗剪切性和广泛的颗粒破碎性。这些发现提供了对颗粒土在增加应力下的行为的见解,这些应力表示为随着剪切增加而自然发生的相变点。从两种砂的粒度分布(PSD)中可以观察到,颗粒破碎最初增加了细粒的剪切比例,但随后逐渐降低了大粒径的剪切比例。采用Hardin’s Br、Lade’s B10和Marsal’s Bm破碎指数框架分析剪切过程中PSD的演化。直接剪切的微观和宏观力学方面表明,为了模拟剪切对颗粒破碎的影响,必须考虑膨胀(- dεv/dεh)、颗粒内摩擦(μ)和垂直有效应力(σ ' v)条件的影响。这些影响的结合导致了颗粒分配势(P3)参数的提出,该参数表示剪切过程中作用在砂土上的平均应力条件。P3只能从应力、应变和体积变化数据中计算出来,但它与Hardin’s Br参数(通过比较测试前和测试后的psd来测量)具有很强的线性相关性。颗粒破碎还与加载强度(LI)参数有关,该参数结合了颗粒内部形成的力链大小和加载时间。P3与P3和Br均呈线性相关,表明LI在量化不同砂体颗粒破碎方面是有效的。最后,利用文献中另外三个数据集计算应力应变数据中的LI和P3,并计算Br。计算和测量的Br值呈良好的相关,R2 = 0.91。
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引用次数: 0
Uplift capacity of pipelines in unsaturated ground with different groundwater levels: experiments and theory 不同地下水位非饱和地基中管道的上拔能力:试验与理论
IF 5.7 1区 工程技术 Q1 ENGINEERING, GEOLOGICAL Pub Date : 2025-08-02 DOI: 10.1007/s11440-025-02724-6
Xu Fang, Mamoru Kikumoto, Ying Cui, Trong Nghia-Nguyen

Shallow-buried pipelines are susceptible to uplift buckling when the vertical stress exceeds the overburden pressure, particularly in unsaturated soils where uplift capacity remains poorly understood. This study investigates the uplift behavior of pipelines in unsaturated ground through uplift trapdoor tests and proposes a limit equilibrium theory to evaluate uplift capacity under unsaturated conditions. The proposed theory, validated against experimental results, reveals that uplift capacity increases as the groundwater level becomes deeper due to enhanced shear strength in unsaturated soils. Application of the theory to sand, silty clay, and loam soils with realistic pipeline dimensions showed that fine-graded soils exhibit higher uplift capacity than sand, indicating greater risks for pipeline stability. These findings advance the understanding of uplift mechanisms in unsaturated soils and provide practical insights for pipeline design and safety assessment.

当垂直应力超过覆盖层压力时,浅埋管道容易发生上拔屈曲,特别是在对上拔能力了解甚少的非饱和土中。通过抬升活板门试验研究了管道在非饱和地基中的抬升行为,提出了非饱和条件下管道抬升能力的极限平衡理论。本文提出的理论与实验结果相对照,揭示了由于非饱和土抗剪强度的增强,随着地下水位的增加,抬升能力增加。将该理论应用于具有实际管道尺寸的砂土、粉质粘土和壤土,结果表明,细级配土比砂土具有更高的抬升能力,表明管道稳定风险更大。这些发现促进了对非饱和土壤隆升机制的理解,并为管道设计和安全评估提供了实用的见解。
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引用次数: 0
Large-scale model tests of monotonic response of lateral loaded hybrid pile–bucket foundation in unsaturated clay 非饱和粘土中横向荷载桩桶混合基础单调响应的大尺度模型试验
IF 5.7 1区 工程技术 Q1 ENGINEERING, GEOLOGICAL Pub Date : 2025-07-29 DOI: 10.1007/s11440-025-02714-8
Haoran OuYang, Zhiyu Gong, Chonglin Dai, Wei Qin, Weiming Gong, Guoliang Dai

Owing to the insufficient bearing capacity of monopile foundations in the deep sea, pile–bucket foundations, which consist of a traditional monopile and a wide-shallow bucket and can effectively improve lateral performance, are receiving increasing attention. This paper describes the results obtained from a large-scale model testing campaign on laterally loaded pile–bucket foundations in clay. The results obtained from monotonic tests performed on pile–bucket foundations with three different bucket sizes are presented, and a monopile is used as a comparison. The pile–soil interaction was investigated in terms of the overall load–displacement behavior, distribution of the bending moment, pile (bucket) deflection, net soil resistance, and py curves. The monotonic test results show that with the addition of the bucket, the ultimate bearing capacity and initial stiffness of the hybrid foundation obviously increase. Compared with that of the monopile foundation, the displacement at the mud surface of the hybrid foundation is 80–90% lower under the same load, and the peak soil resistance of the hybrid foundation is approximately 12–15 times greater than that of the monopile foundation. Furthermore, supplementary 3D FEM analyses were also performed to reveal the foundation failure mode and soil flow mechanism of pile–bucket foundations. This study provides design references for further practical applications of hybrid foundations.

由于单桩基础在深海中承载能力不足,由传统的单桩和宽浅桶组成并能有效提高横向性能的桩桶基础越来越受到重视。本文介绍了粘土中横向荷载桩桶基础的大型模型试验结果。本文介绍了三种不同桶型桩桶基础的单调试验结果,并以单桩为例进行了比较。从总体荷载-位移特性、弯矩分布、桩(斗)挠度、净土阻力和p-y曲线等方面研究了桩-土相互作用。单调试验结果表明,随着桶形结构的加入,混合动力基础的极限承载力和初始刚度明显提高。与单桩基础相比,在相同荷载作用下,混合地基的泥面位移减小80-90%,峰值土阻力约为单桩基础的12-15倍。此外,还对桩桶基础进行了三维有限元分析,揭示了桩桶基础的破坏模式和土流机理。本研究为今后混合地基的实际应用提供了设计参考。
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引用次数: 0
Optimizing dredged clay treatment with superabsorbent polymer: a new phase relationship approach and geotechnical implications 用高吸水性聚合物优化疏浚粘土处理:一种新的相关系方法及其岩土工程意义
IF 5.7 1区 工程技术 Q1 ENGINEERING, GEOLOGICAL Pub Date : 2025-07-29 DOI: 10.1007/s11440-025-02720-w
Yupeng Cao, Wei Liu, Mingdong Li, Yufan Song, Nuo Xu, Jie Yin

This study presents a modified two-phase relationship model to effectively predict changes in soil structure and consolidation behavior when superabsorbent polymer (SAP) is introduced. Laboratory experiments are conducted to examine the effects of SAP on water retention, compressibility, and permeability under different conditions. The findings indicate that a 0.6% SAP dosage forms a gel-like matrix that enhances soil structure, increases drainage efficiency, and improves consolidation performance in high-water-content dredged clay. Key factors influencing these changes, such as SAP dosage, initial water content, and particle interactions, are analyzed. The traditional phase relationship model is modified to incorporate the unique properties of SAP, revealing how it alters the distribution and connectivity of solid, liquid, and void phases within the soil. This refined model provides improved accuracy in predicting soil behavior under varying initial water contents and consolidation stresses, addressing limitations in conventional methods. Additionally, the study highlights the nonlinear relationship between water absorption and volume expansion of SAP, emphasizing its role in enhancing pore structure and soil stability. Overall, this study provides a reliable predictive framework for SAP-treated soils and offers valuable guidance for sustainable sediment treatment in geotechnical engineering applications.

提出了一种改进的两相关系模型,可以有效地预测高吸水性聚合物(SAP)对土壤结构和固结行为的影响。通过室内实验研究了不同条件下SAP对保水、压缩性和渗透性的影响。研究结果表明,0.6%的SAP添加量可形成凝胶状基质,增强土壤结构,提高排水效率,改善高含水量疏浚粘土的固结性能。分析了影响这些变化的关键因素,如SAP用量、初始含水量和颗粒相互作用。传统的相关系模型进行了修改,以纳入SAP的独特性质,揭示了它如何改变土壤中固体、液体和空隙相的分布和连通性。这种改进的模型提高了预测不同初始含水量和固结应力下土壤行为的准确性,解决了传统方法的局限性。此外,研究还强调了SAP吸水率与体积膨胀之间的非线性关系,强调了其在增强孔隙结构和土壤稳定性方面的作用。总的来说,本研究为sap处理土壤提供了可靠的预测框架,并为岩土工程应用中的可持续沉积物处理提供了有价值的指导。
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引用次数: 0
Theoretical solutions of lateral response of a scoured fixed-head pile in elastoplastic soil considering plastic hinging 考虑塑性铰的弹塑性土中冲刷固定头桩横向响应的理论解
IF 5.7 1区 工程技术 Q1 ENGINEERING, GEOLOGICAL Pub Date : 2025-07-29 DOI: 10.1007/s11440-025-02716-6
Cheng-En Ho, Jiunn-Shyang Chiou

This study derives theoretical solutions for the lateral response of a scoured fixed-head pile in elastoplastic soil and investigates the effects of soil nonlinearity and foundation exposure on the pile’s ductile behavior. The theoretical model considers both pile plastic hinging, assuming the pile section follows a bilinear moment–curvature relationship, and soil plasticity, assuming elastoplastic behavior. The ultimate state of the pile–soil system is determined by either pile-head bending failure or in-ground plastic hinging. Examples are presented to demonstrate the application of the proposed solutions to derive theoretical pushover curves, the accuracy of which is validated by comparing them with numerical and experimental results. In addition, the examples show that with increasing scour depth, the possibility of the occurrence of in-ground plastic hinging increases, but the effect of soil nonlinearity decreases. This study further conducts a parametric investigation to examine the effect of soil nonlinearity on the displacement ductility capacity and system overstrength ratio. The results indicate that the normalized yield moment can be regarded as a factor normalizing the effect of soil nonlinearity. A higher normalized yield moment value indicates a more significant effect of soil nonlinearity. This can cause increased displacement ductility capacity and a reduced system overstrength ratio.

本文推导了弹塑性土中冲刷固定头桩横向响应的理论解,并研究了土体非线性和基础暴露对桩塑性行为的影响。该理论模型同时考虑了桩塑性铰(假设桩截面遵循双线性弯矩-曲率关系)和土体塑性(假设桩的弹塑性行为)。桩土体系的极限状态是由桩顶弯曲破坏和桩内塑性铰共同决定的。举例说明了所提解在推导理论推覆曲线中的应用,并通过与数值和实验结果的比较验证了所提解的准确性。此外,算例表明,随着冲刷深度的增加,土内塑性铰发生的可能性增大,但土壤非线性的影响减小。本研究进一步进行参数化研究,探讨土体非线性对位移延性能力和体系超强比的影响。结果表明,归一化屈服矩可视为土壤非线性效应的归一化因子。归一化屈服矩值越高,表明土壤非线性效应越显著。这可以增加位移延展性和降低系统的超强度比。
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引用次数: 0
Influence of hematite film and loading pattern on the mechanics of particle and proppant-shale rock systems 赤铁矿膜和加载方式对颗粒和支撑剂-页岩体系力学的影响
IF 5.7 1区 工程技术 Q1 ENGINEERING, GEOLOGICAL Pub Date : 2025-07-29 DOI: 10.1007/s11440-025-02705-9
Siyue Li, Kostas Senetakis, Kai-Chung Lau

We examine the tribological behavior of particle–particle and particle-shale rock systems in the presence of hematite film (iron oxide nanoparticles) simulating iron oxide development on the surfaces of geological materials. By applying different boundary conditions and loading patterns to the samples, we examined the interfaces in both full and partial slip as well as under the influence of a sudden change of the normal load during shearing. We observed that the influence of hematite film (iron oxide nanoparticles) on the normal contact stiffness may alter depending on whether shear stresses are induced or not. In steady-state sliding, the data show that the hematite film (iron oxide nanoparticles) has a greater influence in grain-rock than that in grain-grain systems; however, both the normal contact and shearing behavior depend, primarily, not on the presence of the iron oxide nanoparticles alone, but the combination of surface film and loading pattern. In part of our grain-scale data, we could provide inferences on previous macroscopic test results as we observed similar patterns of behavior at different scales.

我们研究了赤铁矿膜(氧化铁纳米颗粒)存在时颗粒-颗粒和颗粒-页岩岩石系统的摩擦学行为,模拟了地质材料表面氧化铁的发育。通过对试样施加不同的边界条件和加载模式,我们研究了完全滑移和部分滑移以及剪切过程中法向载荷突然变化的影响下的界面。我们观察到赤铁矿膜(氧化铁纳米颗粒)对法向接触刚度的影响可能会随着剪切应力的产生而改变。在稳态滑动中,赤铁矿膜(氧化铁纳米颗粒)对颗粒-岩石的影响大于颗粒-颗粒体系;然而,正常的接触和剪切行为主要不取决于氧化铁纳米颗粒的单独存在,而是取决于表面膜和加载模式的结合。在我们的部分粒度数据中,我们可以提供先前宏观测试结果的推论,因为我们在不同尺度上观察到相似的行为模式。
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引用次数: 0
Mesoscale numerical investigation of fines detachment, migration, and erosion mechanisms in gas hydrate extraction 天然气水合物提取过程中细颗粒剥离、迁移和侵蚀机制的中尺度数值研究
IF 5.7 1区 工程技术 Q1 ENGINEERING, GEOLOGICAL Pub Date : 2025-07-29 DOI: 10.1007/s11440-025-02706-8
Pengwei Zhang, Wenzhe Gao, Yanlu Ding, Baoguo Liu

Fines detachment, migration, and settling leads to internal erosion of the skeleton structure and clogging of pores, which is an intricate process during the extraction of gas hydrate from marine sediments. Particularly, fines cemented around gas hydrate particles may detach during the dissociation process. The intricacy of this process has not been well characterized in current mathematical models or numerical modeling. In this paper, a mesoscale numerical model coupling solid particle and fluid seepage for gas hydrate-bearing sediments is developed and employed to simulate the fines erosion process, revealing three different mechanisms for the erosion of fines. Fines detach from the soil or gas hydrate particles during the hydrate phase transition and are subject to the Stokes drag force, frictional force, buoyancy force, capillary force, and interparticle interactions within pore space. Based on the established model, the pore clogging due to either physical aggregation or bridging can be clearly identified. The numerical model was initially calibrated with microfluidics experiments, followed by a series of sensitivity analyses to assess the impacts of porosity, fines content, gas hydrate saturation, and pressure gradient on gas and sand production. Results indicate that the interparticle forces play a significant role in pore clogging, which is crucial for gas hydrate-bearing silty sands. The sand production or physical pore clogging is a multi-stage process due to the dissociation of gas hydrates.

细颗粒的脱离、迁移和沉降导致骨架结构内部侵蚀和孔隙堵塞,是海洋沉积物中天然气水合物提取过程中一个复杂的过程。特别是,在解离过程中,气体水合物颗粒周围胶结的细颗粒可能会分离。这一过程的复杂性在目前的数学模型或数值模拟中尚未得到很好的表征。本文建立了含天然气水合物沉积物固体颗粒与流体渗流耦合的中尺度数值模型,对细粒侵蚀过程进行了模拟,揭示了细粒侵蚀的三种不同机制。在水合物相变过程中,颗粒从土壤或气体水合物颗粒中分离出来,并受到斯托克斯阻力、摩擦力、浮力、毛细力和孔隙空间内颗粒间相互作用的影响。基于所建立的模型,可以清楚地识别由物理聚集或桥接引起的孔隙堵塞。数值模型首先通过微流体实验进行校准,然后进行一系列敏感性分析,以评估孔隙度、细颗粒含量、天然气水合物饱和度和压力梯度对气砂产量的影响。结果表明,颗粒间力在孔隙堵塞中起着重要作用,这对含气水合物粉质砂岩至关重要。由于天然气水合物的解离作用,出砂或物理孔隙堵塞是一个多阶段的过程。
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引用次数: 0
Physico-mechanical performance and micro–mechanism analysis on urban sludge modified with a low carbon binder 低碳粘结剂改性城市污泥的物理力学性能及微观机理分析
IF 5.7 1区 工程技术 Q1 ENGINEERING, GEOLOGICAL Pub Date : 2025-07-28 DOI: 10.1007/s11440-025-02708-6
J.-F. Zhu, Y.-N. Xia, L.-Y. Ju, H. Yang, Z.-Q. Wang, J.-Y. Jin, Y.-C. Zou, Y.-C. Liao

Urban sludge, characterized by its large volume and poor engineering properties, has become a significant environmental issue in the southeastern coastal regions of China. This research investigates a method for transforming urban sludge into a usable soil resource through the utilization of a low–carbon binder (CFS), providing a novel approach for sludge treatment and resource recycling. To achieve this, multi–scale experimental research and mechanistic analysis were conducted, focusing on the unit and microscopic experiments of industrial waste slag in collaboration with CFS solidification of engineering waste sludge. The materials used in CFS included Portland cement (PC), fly ash (FA), and steel slag (SS), with the incorporation of response surface methodology (RSM). The findings indicate that the singular addition of FA and SS exhibits a limited solidification effect on the sludge. However, significant synergistic interactions were observed between PC and FA, and between FA and SS. Based on the unconfined compressive strength test results of sludge cured for 7 days, the optimal ratio of the CFS was determined to be PC: FA = 40.7%:40.7%:18.6%, demonstrating the most effective sludge enhancement. The falling head permeability test results showed that the stabilized sludge had permeability approximately two orders lower in magnitude than the untreated sludge. Characterization techniques, including X–ray diffraction (XRD), scanning electron microscopy (SEM), energy–dispersive spectroscopy (EDS), thermogravimetric analysis (TGA) and identified the primary products within the stabilized sludge matrix as ettringite (Aft), calcium–silicate–hydrate (C–S–H) gel, and calcite. Additionally, cured sludge had a lower pore volume than its raw counterpart, according to mercury intrusion porosimetry (MIP) data, which suggests a stronger microstructural structure after stabilization. The improvement in sludge properties attributed to CFS is primarily due to the hydration reaction, pozzolanic reaction, ion exchange, and carbonation. Compared to traditional Portland cement, the CFS curing agent offers comparable economic benefits and substantial environmental advantages.

城市污泥体积大,工程性能差,已成为中国东南沿海地区一个重要的环境问题。本研究探讨了一种利用低碳粘结剂(CFS)将城市污泥转化为可用土壤资源的方法,为污泥处理和资源循环利用提供了一种新的途径。为此,开展了多尺度试验研究和机理分析,重点开展了工业废渣的单元和微观试验,协同工程废渣的CFS固化。采用响应面法(RSM),采用波特兰水泥(PC)、粉煤灰(FA)和钢渣(SS)作为CFS材料。结果表明,单一添加FA和SS对污泥的凝固效果有限。但PC与FA、FA与SS之间存在显著的协同作用。根据固化7天污泥无侧限抗压强度试验结果,确定CFS的最佳配比为PC: FA = 40.7%:40.7%:18.6%,污泥强化效果最佳。降头渗透试验结果表明,稳定污泥的渗透率比未处理污泥低约两个数量级。表征技术包括x射线衍射(XRD)、扫描电子显微镜(SEM)、能量色散光谱(EDS)、热重分析(TGA),并确定了稳定污泥基质中的主要产物为钙矾石(Aft)、水合硅酸钙(C-S-H)凝胶和方解石。此外,根据汞侵入孔隙率(MIP)数据,固化污泥的孔隙体积比原始污泥小,这表明稳定化后的微观结构更强。CFS对污泥性能的改善主要是由于水化反应、火山灰反应、离子交换和碳化作用。与传统的波特兰水泥相比,CFS固化剂具有相当的经济效益和可观的环境优势。
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引用次数: 0
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Acta Geotechnica
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