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Quantification of solubility trapping in natural and engineered CO2 reservoirs 自然和工程CO2储层溶解度捕获的量化
IF 1.7 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2021-07-13 DOI: 10.1144/petgeo2020-120
Rory Leslie, A. Cavanagh, R. Haszeldine, G. Johnson, S. Gilfillan
Secure retention of CO2 in geological reservoirs is essential for effective storage. Solubility trapping, the dissolution of CO2 into formation water, is a major sink on geological timescales in natural CO2 reservoirs. Observations during CO2 injection, combined with models of CO2 reservoirs, indicate the immediate onset of solubility trapping. There is uncertainty regarding the evolution of dissolution rates between the observable engineered timescale of years and decades, and the >10 kyr state represented by natural CO2 reservoirs. A small number of studies have constrained dissolution rates within natural analogues. The studies show that solubility trapping is the principal storage mechanism after structural trapping, removing 10–50% of CO2 across whole reservoirs. Natural analogues, engineered reservoirs and model studies produce a wide range of estimates on the fraction of CO2 dissolved and the dissolution rate. Analogue and engineered reservoirs do not show the high fractions of dissolved CO2 seen in several models. Evidence from natural analogues supports a model of most dissolution occurring during emplacement and migration, before the establishment of a stable gas–water contact. A rapid decline in CO2 dissolution rate over time suggests that analogue reservoirs are in dissolution equilibrium for most of the CO2 residence time. Supplementary material: Dissolution rate for all plots and exponential function curves for scenarios A and B are available at https://doi.org/10.6084/m9.figshare.c.5476199 Thematic collection: This article is part of the Geoscience for CO2 storage collection available at: https://www.lyellcollection.org/cc/geoscience-for-co2-storage
地质储层中二氧化碳的安全保留对于有效储存至关重要。溶解性捕获,即CO2溶解到地层水中,是天然CO2储层地质时间尺度上的一个主要汇点。CO2注入期间的观察结果,结合CO2储层的模型,表明溶解性捕获立即开始。在可观察到的几年到几十年的工程时间尺度和>10之间,溶解速率的演变存在不确定性 以天然CO2储层为代表的kyr状态。少数研究限制了天然类似物的溶出速率。研究表明,溶解性捕集是结构捕集之后的主要储存机制,可在整个储层中去除10-50%的CO2。天然类似物、工程油藏和模型研究对CO2的溶解分数和溶解速率进行了广泛的估计。模拟和工程油藏没有显示出在几个模型中看到的溶解CO2的高分数。来自天然类似物的证据支持了一个模型,即在建立稳定的气水接触之前,大多数溶解发生在侵位和迁移过程中。CO2溶解速率随时间的快速下降表明,在CO2停留的大部分时间里,类似储层处于溶解平衡状态。补充材料:方案A和B的所有曲线图和指数函数曲线的溶解速率可在https://doi.org/10.6084/m9.figshare.c.5476199专题收藏:本文是二氧化碳储存地球科学收藏的一部分,可在:https://www.lyellcollection.org/cc/geoscience-for-co2-storage
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引用次数: 9
Geology and petroleum prospectivity of the Sea of Hebrides Basin and Minch Basin, offshore NW Scotland 苏格兰西北近海赫布里底群岛盆地和明奇盆地的地质和石油远景
IF 1.7 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2021-05-19 DOI: 10.1144/petgeo2021-003
Laura-Jane C. Fyfe, N. Schofield, S. Holford, A. Hartley, A. Heafford, D. Muirhead, J. Howell
The Sea of Hebrides Basin and Minch Basin are late Paleozoic–Mesozoic rift basins located to the NW of the Scottish mainland. The basins were the target of small-scale petroleum exploration from the late 1960s to the early 1990s, with a total of three wells drilled within the two basins between 1989 and 1991. Although no commercially viable petroleum discoveries were made, numerous petroleum shows were identified within both basins, including a gas show within the Upper Glen 1 well in Lower Jurassic limestones. Organic-rich shales have been identified throughout the Jurassic succession within the Sea of Hebrides Basin, with one Middle Jurassic (Bajocian–Bathonian) shale exhibiting a total organic carbon content of up to 15 wt%. The focus of this study is to review the historical petroleum exploration within these basins, and to evaluate whether the conclusions drawn in the early 1990s of a lack of prospectivity remains the case. This was undertaken by analysis of seismic reflection data, gravity and aeromagnetic data, and sedimentological data from both onshore and offshore wells, boreholes and previously published studies. The key findings from our study suggest that there is a low probability of commercially sized petroleum accumulations within either the Sea of Hebrides Basin or the Minch Basin. Ineffective source rocks, likely to be due to low maturities (due to lack of burial) and the fact that the encountered Jurassic and Permian–Triassic reservoirs are of poor quality (low porosity and permeability), has led to our interpretation of future exploration being high risk, with any potential accumulations being small in size. While petroleum accumulations are unlikely within the basin, applying the knowledge obtained from this study could provide additional datasets and insight into petroleum exploration within other NE Atlantic margin basins, such as the Rockall Trough and the Faroe–Shetland Basin.
赫布里底海盆地和明奇盆地是位于苏格兰大陆西北方向的晚古生代—中生代裂谷盆地。从1960年代末到1990年代初,这两个盆地是小规模石油勘探的目标,1989年至1991年期间在这两个盆地内共钻了3口井。虽然没有商业上可行的石油发现,但在两个盆地中都发现了许多石油显示,包括下侏罗统灰岩中的Upper Glen 1井中的天然气显示。富有机质页岩在赫布里底海盆地的整个侏罗纪演替中都被发现,其中一个中侏罗世(巴约世-巴底世)页岩显示出总有机碳含量高达15%。本研究的重点是回顾这些盆地内的石油勘探历史,并评价20世纪90年代初得出的缺乏前景的结论是否仍然存在。这是通过分析地震反射数据、重力和航磁数据、陆上和海上井、钻孔和先前发表的研究的沉积学数据来完成的。我们研究的主要发现表明,在赫布里底海盆地或明奇盆地内,存在商业规模石油聚集的可能性很低。无效烃源岩可能是由于低成熟度(由于缺乏埋藏)以及所遇到的侏罗系和二叠系-三叠系储层质量差(低孔隙度和渗透率),这导致我们对未来勘探的解释是高风险的,任何潜在的聚集规模都很小。虽然盆地内不太可能有石油聚集,但应用本研究获得的知识可以为其他东北大西洋边缘盆地(如Rockall槽和Faroe-Shetland盆地)的石油勘探提供额外的数据集和见解。
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引用次数: 0
Depositional conditions at the Aptian pre-salt margins: evidence from quantitative petrography and textural analysis of the Mucuri Member, Espírito Santo Basin, Brazil 阿普田盐下边缘沉积条件:来自巴西Espírito Santo盆地Mucuri段定量岩石学和结构分析的证据
IF 1.7 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2021-05-04 DOI: 10.1144/petgeo2020-112
G. Pantopoulos, Gustavo Kenji Lacerda Orita, G. Armelenti, Camila Eliza Althaus, J. Kuchle, C. Scherer, A. G. Rodrigues, L. F. De Ros
Aptian siliciclastic onshore deposits of the Mucuri Member are important reservoirs in the Espírito Santo Basin (eastern Brazil). A detailed quantitative petrographical and textural analysis of well core samples was performed in order to unravel their depositional processes and conditions, in relation to previously proposed depositional models. The results allowed differentiation between two groups of sandstone samples, characterized by different textural characteristics associated to different depositional processes and environments within the Mucuri depositional system. Fluvial sandstones are represented by medium- to coarse-grained, poorly sorted arkoses, rich in plutonic rock fragments and feldspar grains, mainly transported by traction. Coastal-lacustrine sandstones correspond to very fine- to fine-grained, moderately sorted micaceous arkoses, mainly transported in suspension. The application of a discriminant function based on grain-size parameters validated previously proposed depositional settings for the studied sample groups. The combination of grain-size and shape data revealed differences in hydraulic equivalence and shape between grains from different depositional settings. In terms of hydraulic equivalence, micas in the fluvial sediments present lower settling velocity values, in contrast to the relatively large mica grains in the coastal sediments, which are hydraulically equivalent with the associated quartz and feldspar grains. The results of this study provide key information regarding depositional conditions (transportation mechanisms, grain-settling velocity and mineral hydraulic fractionation) at the margins of the Aptian pre-salt system, which can constrain the hydrological conditions and the sediment type available for distal lacustrine areas.
Mucuri成员的Aptian硅屑碎屑陆上矿床是Espírito Santo盆地(巴西东部)的重要储层。对岩心样品进行了详细的定量岩石学和结构分析,以揭示其沉积过程和沉积条件,并与先前提出的沉积模型相关联。结果表明,两组砂岩样品具有不同的结构特征,与穆库里沉积体系中不同的沉积过程和环境有关。河流砂岩以中粗粒、分选差的长石为代表,富含深成岩碎片和长石颗粒,主要受牵引搬运作用。海岸湖相砂岩对应于极细至细粒、中等分选的云母砂岩,主要以悬浮形式搬运。基于粒度参数的判别函数的应用验证了先前提出的研究样本组的沉积设置。粒度和形状数据的结合揭示了不同沉积背景下颗粒的水力等效性和形状的差异。在水力等效方面,河流沉积物中的云母沉降速度值较低,而沿海沉积物中的云母颗粒相对较大,与伴生的石英和长石颗粒水力等效。本研究结果提供了阿普田盐下系统边缘沉积条件(搬运机制、颗粒沉降速度和矿物水力分异)的关键信息,这些信息可以约束远湖区水文条件和沉积物类型。
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引用次数: 1
Gas Permeability Change with Deformation and Cracking of a Sandstone under Triaxial Compression 砂岩在三轴压缩下的气体渗透率随变形和破裂的变化
IF 1.7 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2021-04-29 DOI: 10.21203/rs.3.rs-392045/v1
Yuan-Jian Lin, Jiang-feng Liu, Tao Chen, Shimin Ma, Pei-Lin Wang, H. Bai
In this paper, a THMC multi-field coupling triaxial cell was used to systematically study the evolution of gas permeability and the deformation characteristics of sandstone. The effects of confining pressure, axial pressure and air pressure on gas permeability characteristics were fully considered in the test. The gas permeability of sandstone decreases with increasing confining pressure. When the confining pressure is low, the variation of gas permeability is greater than the variation of gas permeability at high confining pressure. The gas injection pressure has a significant effect on the gas permeability evolution of sandstone. As the gas injection pressure increases, the gas permeability of sandstone tends to decrease. At the same confining pressure, the gas permeability of the sample during the unloading path is less than the gas permeability of the sample in the loading path. When axial pressure is applied, the axial stress has a significant influence on the permeability evolution of sandstone. When the axial pressure is less than 30 MPa, the gas permeability of the sandstone increases as the axial pressure increases. At axial pressures greater than 30 MPa, the permeability decreases as the axial pressure increases. Finally, the micro-pore/fracture structure of the sample after the gas permeability test was observed using 3D X-ray CT imaging.
本文利用THMC多场耦合三轴单元系统地研究了砂岩的透气性演化和变形特征。试验充分考虑了围压、轴压和气压对气体渗透特性的影响。砂岩的透气性随围压的增加而降低。围压较低时,气体渗透率的变化大于围压较高时的气体渗透率变化。注气压力对砂岩的渗透率演化有显著影响。随着注气压力的增加,砂岩的透气性有降低的趋势。在相同围压下,样品在卸载路径期间的气体渗透率小于样品在加载路径中的气体渗透率。当施加轴向压力时,轴向应力对砂岩的渗透率演化有显著影响。当轴向压力小于30MPa时,砂岩的气体渗透率随着轴向压力的增加而增加。在大于30MPa的轴向压力下,渗透率随着轴向压力的增加而降低。最后,使用3D X射线CT成像观察了透气性测试后样品的微孔/裂缝结构。
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引用次数: 0
CO2 mineral trapping comparison in different regions: predicted geochemical reactivity of the Precipice Sandstone reservoir and overlying Evergreen Formation 不同地区CO2矿物捕集比较:预测沉积砂岩储层和上覆长荣组的地球化学反应
IF 1.7 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2021-04-23 DOI: 10.1144/petgeo2020-106
J. Pearce, A. L. La Croix, F. Brink, P. Hayes, J. Underschultz
Injected CO2 streams may have geochemical reactivity to different rock types in a CO2 storage complex depending on solubility and formation water chemistry. The Precipice Sandstone and Evergreen Formation are a low-salinity reservoir–seal pair in the Surat Basin, Australia, targeted for potential CO2 storage. The kinetic geochemical CO2 reactivity of different rock facies from three regions were predicted over 30 and 1000 year time periods. No material CO2 mineral trapping in the quartz-rich Precipice Sandstone reservoir was predicted, owing to the low rock reactivity. Predicted CO2 mineral trapping in the Evergreen Formation was more variable due to different amounts of more reactive feldspars, clays, calcite and siderite. Predicted mineral trapping as siderite and ankerite was between 0.03 and 8.4 kg m−3 CO2, and mainly depends on chlorite and plagioclase content. Predicted pH was between 5 and 7.5 after 1000 years. Pyrite precipitation was also predicted with SO2 present in the injectate. QEMSCAN and SEM-EDS (scanning electron microscopy and energy-dispersive spectroscopy) spot imaging of samples from the seal containing natural fractures filled by siderite, pyrite, clays, ankerite, calcite, barite and apatite represent a natural analogue for natural mineral trapping. These are in good agreement with our model predictions. This study suggests that, from a geochemical perspective, the Precipice Sandstone is a suitable storage reservoir, whereas mineral trapping would occur in the overlying Evergreen Formation. Supplementary material: Additional model inputs, characterization and model images, and an excel file of QEMSCAN mineral and porosity components, are available at https://doi.org/10.6084/m9.figshare.c.5395393 Thematic collection: This article is part of the Geoscience for CO2 storage collection available at: https://www.lyellcollection.org/cc/geoscience-for-co2-storage
注入的CO2流可能对CO2储存复合体中的不同岩石类型具有地球化学反应性,这取决于溶解度和地层水化学性质。沉淀砂岩和长荣组是澳大利亚苏拉特盆地的一对低盐度储层-封存层,旨在储存潜在的二氧化碳。预测了三个地区不同岩相的动力学地球化学CO2反应性,预测值分别为30和1000 年时间段。由于岩石反应性低,预测富含石英的沉淀砂岩储层中没有物质CO2矿物捕获。由于不同数量的反应性更强的长石、粘土、方解石和菱铁矿,预测的长荣组CO2矿物捕获变化更大。作为菱铁矿和铁白云石的预测矿物捕获在0.03到8.4之间 公斤 m−3 CO2,主要取决于绿泥石和斜长石的含量。1000后预测pH值在5和7.5之间 年。在注入物中存在SO2的情况下,还预测了黄铁矿沉淀。QEMSCAN和SEM-EDS(扫描电子显微镜和能量色散光谱)对来自由菱铁矿、黄铁矿、粘土、铁白云石、方解石、重晶石和磷灰石填充的含有天然裂缝的密封层的样品进行斑点成像,代表了天然矿物捕集的天然类似物。这些与我们的模型预测非常一致。这项研究表明,从地球化学角度来看,沉淀砂岩是一个合适的储层,而矿物捕获将发生在上覆的常青组中。补充材料:其他模型输入、表征和模型图像,以及QEMSCAN矿物和孔隙度成分的excel文件,可在https://doi.org/10.6084/m9.figshare.c.5395393专题收藏:本文是二氧化碳储存地球科学收藏的一部分,可在:https://www.lyellcollection.org/cc/geoscience-for-co2-storage
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引用次数: 12
Upscaling of outcrop information for improved reservoir modelling – exemplified by a case study on chalk 扩大露头信息以改进储层建模——以白垩岩为例
IF 1.7 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2021-04-14 DOI: 10.1144/petgeo2020-126
D. Qu, P. Frykman, L. Stemmerik, K. Mosegaard, L. Nielsen
Outcrops are valuable for analogous subsurface reservoirs in supplying knowledge of fine-scale spatial heterogeneity pattern and stratification types, which are difficult to obtain from subsurface reservoir cores, well logs or seismic data. For petrophysical properties in a domain where the variations are relatively continuous and not dominated by abrupt contrasts, the spatial heterogeneity pattern can be characterized by a semivariogram model. The outcrop information therefore has the potential to constrain the semivariogram for subsurface reservoir modelling, even though it represents different locations and depths, and the petrophysical properties may differ in magnitude or variance. However, the use of outcrop-derived spatial correlation information for petrophysical property modelling in practice has been challenged by the scale difference between the small support volume of the property measurements from outcrops and the typically much larger grid cells used in reservoir models. With an example of modelling the porosity of an outcrop chalk unit in eastern Denmark, this paper illustrates how the fine-scale spatial correlation information obtained from the sampling of outcrops can be transferred to coarser-scale models of analogue rocks. The workflow can be applied to subsurface reservoirs and ultimately improves the representation of geological patterns in reservoir models.
露头对于类似的地下储层提供精细尺度空间非均质性模式和分层类型的知识是有价值的,而这些知识很难从地下储层岩心、测井或地震数据中获得。对于变化相对连续且不受突然对比支配的领域中的岩石物理性质,空间非均质性模式可以通过半变差函数模型来表征。因此,露头信息有可能限制地下储层建模的半变差函数,即使它代表不同的位置和深度,并且岩石物理性质的大小或变化可能不同。然而,在实践中,将露头衍生的空间相关性信息用于岩石物理性质建模受到了露头性质测量的小支撑体积与储层模型中使用的通常大得多的网格单元之间的比例差异的挑战。本文以丹麦东部一个露头白垩单元的孔隙度建模为例,说明了如何将从露头采样中获得的精细尺度空间相关性信息转换为模拟岩石的粗尺度模型。该工作流程可以应用于地下储层,并最终改进储层模型中地质模式的表示。
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引用次数: 1
The impact of heterogeneous salt velocity models on the gross rock volume estimation: an example from the Santos Basin pre-salt, Brazil 非均质盐速模型对总岩石体积估算的影响——以巴西桑托斯盆地盐前区为例
IF 1.7 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2021-04-12 DOI: 10.1144/petgeo2020-105
A. Maul, M. Cetale, C. Guizan, P. Corbett, J. Underhill, L. Teixeira, R. Pontes, María González
The thick and heterogeneous salt section in the Santos Basin, offshore Brazil, imposes great challenges in accessing the pre-salt hydrocarbon reservoirs, especially in relation to seismic imaging, signal quality and depth positioning. Some problems arise from the current velocity models for the salt section, which, for the majority, assume that the salt is a homogeneous halite layer. In the Santos Basin, the commonly assumed salt – halite – only makes up to 80% of the mineral in this section. The inclusion of other salts as stratification in the velocity models, based on seismic attributes, has achieved good results in the last decade, especially for depth resolution. In this work, we analyse the benefits of different velocity models, considering presence/absence of salt stratification and comparing the gross rock volume above the oil–water contact. The results show a significant effect on the depth resolution of the events, as well as on volume estimation, indicating that the greater the reliability captured by the complex velocity models, the greater the confidence in the resulting volumetric information.
巴西近海桑托斯盆地的厚盐和非均质盐段在获取盐前油气藏方面带来了巨大挑战,尤其是在地震成像、信号质量和深度定位方面。盐段的当前速度模型产生了一些问题,大多数情况下,该模型假设盐是均匀的石盐层。在桑托斯盆地,通常认为的盐——岩盐——只占该段矿物的80%。在过去的十年里,基于地震属性,在速度模型中加入其他盐类作为分层,取得了良好的效果,尤其是在深度分辨率方面。在这项工作中,我们分析了不同速度模型的好处,考虑到盐分层的存在/不存在,并比较了油水接触上方的总岩石体积。结果显示,对事件的深度分辨率以及体积估计都有显著影响,表明复杂速度模型捕获的可靠性越高,对所得体积信息的置信度就越高。
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引用次数: 3
Intra-salt structure and strain partitioning in layered evaporites: implications for drilling through Messinian salt in the eastern Mediterranean 层状蒸发岩中的盐内结构和应变分配:对地中海东部梅西尼亚盐钻探的启示
IF 1.7 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2021-04-07 DOI: 10.1144/petgeo2020-072
S. Evans, C. Jackson
We use 3D seismic reflection data from the Levant margin, offshore Lebanon to investigate the structural evolution of the Messinian evaporite sequence, and how intra-salt structure and strain varies within a thick salt sheet during early-stage salt tectonics. Intra-Messinian reflectivity reveals lithological heterogeneity within the otherwise halite-dominated sequence. This leads to rheological heterogeneity, with the different mechanical properties of the various units controlling strain accommodation within the deforming salt sheet. We assess the distribution and orientation of structures, and show how intra-salt strain varies both laterally and vertically along the margin. We argue that units appearing weakly strained in seismic data may in fact accommodate considerable subseismic or cryptic strain. We also discuss how the intra-salt stress state varies through time and space in response to the gravitational forces driving deformation. We conclude that efficient drilling through thick, heterogeneous salt requires a holistic understanding of the mechanical and kinematic development of the salt and its overburden. This will also enable us to build better velocity models that account for intra-salt lithological and structural complexity in order to accurately image sub-salt geological structures.
我们使用黎巴嫩近海黎凡特边缘的3D地震反射数据来研究梅西尼亚蒸发岩序列的结构演化,以及早期盐构造期间盐内结构和应变在厚盐层内的变化。墨西阶内部反射率揭示了以石盐岩为主的层序中的岩性不均匀性。这导致流变不均匀性,不同单元的不同机械性能控制变形盐层内的应变调节。我们评估了结构的分布和方向,并展示了盐内应变如何沿边缘横向和垂直变化。我们认为,在地震数据中表现出弱应变的单元实际上可能容纳相当大的亚地震应变或隐应变。我们还讨论了盐内应力状态如何随时间和空间变化,以响应驱动变形的重力。我们得出的结论是,在厚的、不均匀的盐中进行有效的钻探需要对盐及其覆盖层的力学和运动学发展有一个全面的了解。这也将使我们能够建立更好的速度模型,考虑盐内岩性和结构的复杂性,以便准确地成像盐下地质结构。
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引用次数: 8
Open fractures in pre-salt silicified carbonate reservoirs in block BM-C-33, the Outer Campos Basin, offshore Brazil 巴西外海Campos盆地BM-C-33区块盐下硅化碳酸盐岩储层开放裂缝研究
IF 1.7 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2021-03-18 DOI: 10.1144/petgeo2020-125
O. P. Wennberg, G. McQueen, P. H. Vieira de Luca, F. Lapponi, D. Hunt, A. S. Chandler, A. Waldum, G. Nery Camargo, E. Castro, L. Loures
Natural open fractures are present in sidewall cores and in whole-core samples from pre-salt reservoirs in the licence block BM-C-33 in the Campos Basin, Brazil. Open fractures are also observed in borehole image logs, and fracture densities are in general high. The highest density of open fractures is seen in the damage zones above and below larger cavities (amalgamated cavern damage zones (ACDZs)). Outside the ACDZs the fracture density is high in silicified carbonates, where it tends to increase with decreasing porosity. Clean dolomites are less fractured than the silicified interval, while the less brittle argillaceous dolomites have the lowest fracture density. Some fractures appear vuggy on borehole image logs, and fracture densities are high close to vugs and larger cavities. The positive correlation between fractures and vugs is caused by flow of dissolving fluids through open fractures, and fracturing at stress concentrations around vugs. Two major fault zones have been interpreted from borehole image logs that have damage zones with very high fracture density. The well-test permeability is much greater than the matrix permeability estimated from sidewall core and log measurements. This excess permeability is attributed to fractures, in combination with caverns and intervals with frequent vugs.
天然开放裂缝存在于巴西坎波斯盆地BM-C-33许可区块盐前储层的侧壁岩心和全岩心样本中。在钻孔图像测井中也观察到开放裂缝,并且裂缝密度通常很高。最大密度的开放裂缝出现在较大洞穴上方和下方的损伤区(合并洞穴损伤区(ACDZ))。在ACDZ之外,硅化碳酸盐的裂缝密度很高,随着孔隙度的降低,裂缝密度往往会增加。清洁白云岩的裂缝性比硅化层段小,而脆性较小的泥质白云岩具有最低的裂缝密度。一些裂缝在钻孔图像日志上显示为洞穴状,靠近洞穴和较大洞穴的裂缝密度较高。裂缝和洞穴之间的正相关性是由溶解流体通过开放裂缝的流动以及洞穴周围应力集中时的压裂引起的。根据钻孔图像测井解释了两个主要的断层带,这些断层带具有非常高的裂缝密度。试井渗透率远大于根据侧壁岩心和测井测量估算的基质渗透率。这种过度渗透性归因于裂缝、洞穴和频繁洞穴的间隔。
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引用次数: 5
Potential Pb2+ mobilization, transport, and sequestration in shallow aquifers impacted by multiphase CO2 leakage: a natural analogue study from the Virgin River Basin in SW Utah 受多相CO2泄漏影响的浅含水层中Pb2+的潜在动员、运输和封存:来自犹他州西南部维珍河流域的自然模拟研究
IF 1.7 4区 地球科学 Q1 Earth and Planetary Sciences Pub Date : 2021-03-15 DOI: 10.1144/petgeo2020-109
Michelle R. Plampin, M. Blondes, E. Sonnenthal, W. Craddock
Geological carbon sequestration (GCS) is necessary to help meet goals for emissions reduction, but groundwater contamination may occur if CO2 and/or brine were to leak out of deep storage formations into the shallow subsurface. For this study, a natural analogue was investigated: in the Virgin River Basin of SW Utah, water with moderate salinity and high CO2 concentrations is leaking upwards into shallow aquifers that contain heavy-metal-bearing concretions. The aquifer system is comprised of the Navajo and Kayenta formations, which are pervasive across southern Utah and have been considered as a potential GCS injection unit where they are sufficiently deep. Numerical models of the site were constructed based on measured water chemistry and head distributions from previous studies. Simulations were used to improve understanding of the rate and distribution of the upwelling flow into the aquifers, and to assess the reactive transport processes that may occur if the upwelling fluids were to interact with a zone of iron oxide and other heavy metals, representing the concretions that are common in the area. Various mineralogies were tested, including one in which Pb2+ was adsorbed onto ferrihydrite, and another in which it was bound within a solid mixture of litharge (PbO) and hematite (Fe2O3). Results indicate that metal mobilization depends strongly on the source-zone composition and that Pb2+ transport can be naturally attenuated by gas-phase formation and carbonate-mineral precipitation. These findings could be used to improve risk assessment and mitigation strategies at geological carbon sequestration sites. Thematic collection: This article is part of the Geoscience for CO2 storage collection available at: https://www.lyellcollection.org/cc/geoscience-for-co2-storage
地质碳封存(GCS)对于实现减排目标是必要的,但如果二氧化碳和/或盐水从深层储层泄漏到浅层地下,可能会造成地下水污染。在这项研究中,研究人员研究了一个自然模拟:在犹他州西南部的维珍河流域,中等盐度和高浓度二氧化碳的水向上泄漏到含有重金属固结物的浅层含水层。该含水层系统由Navajo和Kayenta地层组成,它们遍布犹他州南部,在足够深的地方被认为是潜在的GCS注入单元。基于实测的水化学和前人研究的水头分布,建立了该地点的数值模型。模拟是为了更好地了解流入含水层的上升流的速率和分布,并评估如果上升流与氧化铁和其他重金属(代表该地区常见的固结物)区相互作用可能发生的反应性输运过程。测试了不同的矿物学,包括Pb2+被吸附在铁水合物上的矿物学,以及Pb2+被结合在锂矿(PbO)和赤铁矿(Fe2O3)的固体混合物中的矿物学。结果表明,金属的迁移很大程度上取决于源区组成,而Pb2+的输运可以通过气相形成和碳酸盐矿物沉淀而自然减弱。这些发现可用于改进地质碳封存地点的风险评估和缓解战略。专题合集:本文是地球科学CO2储存合集的一部分,可在:https://www.lyellcollection.org/cc/geoscience-for-co2-storage上获得
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引用次数: 1
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Petroleum Geoscience
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