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Effects of meteoric water–rock interaction on the quality of the Middle Jurassic reservoirs along the Hongciliang tectonic belt, Yabulai Basin, NW China 大气水岩相互作用对亚布莱盆地红次梁构造带中侏罗统储层质量的影响
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-22 DOI: 10.1016/j.jseaes.2025.106936
Shuangqi Feng , Hancheng Ji , Liang Chen , Xuegui Jiang , Pengfei Xiang , Yanqing Shi , Chunfu Liao , Ying Liu , Ling Li
In recent years, the penetration of meteoric water through unconformities and porous sandstones, and its subsequent dissolution effects within deep-seated reservoirs, has attracted widespread attention. Assessing whether a diagenetic system is open or closed is crucial for evaluating how dissolution influences reservoir quality. However, for structural uplifts with large-scale, deep-seated faults, how dissolution from meteoric water leaching varies spatially from the structural high to the downdip slope, and the resulting reservoir characteristics, remain poorly understood. To address this, we conducted an integrated analysis of diagenetic mineral assemblages and the associated paragenetic sequence in the Middle Jurassic reservoir of the Hongciliang tectonic belt, Yabulai Basin. Methods included thin-section petrography, scanning electron microscopy (SEM), isotopic testing, X-ray diffraction (XRD), reservoir porosity–permeability measurements, and computerized tomography (CT) scanning. Results demonstrate that the medium- to fine-grained arkoses in the Hongciliang tectonic belt were deposited under similar sedimentary environments. Nevertheless, differential dissolution, coupled with mass transfer and re-precipitation of dissolved materials, results in substantial differences between the structural high and downdip slope. These differences are manifested in the development of dissolution pores, as well as in the types and abundances of authigenic minerals within dissolution pores. Specifically, on the structural high, where well-developed faults define an open geochemical system, extensive dissolution is observed with only limited precipitation of byproducts (e.g., quartz and feldspar overgrowth). Notably, the dissolution of intergranular calcite cements is more prevalent than that of feldspar grains. Reservoir spaces are dominated by interconnected, poorly-cemented intergranular enlarged pores and intragranular dissolution pores. In contrast, on the downdip slope, where the geochemical system is relatively closed, moderate dissolution of both feldspar and calcite cements occurred concurrently with substantial precipitation of byproducts. There, pore systems consist mainly of inter-crystalline pores and poorly connected dissolution pores, with most dissolution pores being occluded by kaolinite, quartz overgrowth and other dissolution-related byproducts. This study indicates that under progressively closed geochemical conditions, the dissolution capacity of meteoric water infiltrating downward through faults and porous sandstones is markedly weakened. Concurrently, the re-precipitation of dissolved cations within the system is enhanced. These coupled diagenetic processes ultimately control the distribution of high-quality reservoirs in uplifted structural belts.
近年来,大气水通过不整合面和多孔砂岩的渗透作用及其对深层储层的溶蚀作用引起了广泛的关注。评价成岩系统是开放的还是封闭的,对于评价溶蚀作用对储层质量的影响至关重要。然而,对于具有大规模深部断裂的构造隆升,从构造高坡到构造下坡,大气水淋溶作用如何在空间上发生变化,以及由此产生的储层特征尚不清楚。为此,对亚布莱盆地红次梁构造带中侏罗统储层成岩矿物组合及其共生序列进行了综合分析。方法包括薄层岩相、扫描电镜(SEM)、同位素测试、x射线衍射(XRD)、储层孔隙度-渗透率测量和计算机断层扫描(CT)。结果表明,红次梁构造带中、细粒粗砂岩是在相似的沉积环境下形成的。然而,不同的溶解作用,再加上传质和溶解物质的再沉淀,导致了构造高斜坡和下倾斜坡的本质差异。这些差异表现在溶蚀孔的发育以及溶蚀孔内自生矿物的类型和丰度上。具体来说,在构造高地,发育良好的断层定义了一个开放的地球化学系统,广泛的溶解被观察到,只有有限的副产物沉淀(例如石英和长石过度生长)。值得注意的是,晶间方解石胶结物的溶解比长石颗粒的溶解更为普遍。储集空间以连通、胶结不良的粒间扩孔和粒内溶蚀孔为主。而在地球化学系统相对封闭的下倾坡上,长石和方解石胶结物均发生适度溶解,副产物大量沉淀。孔系主要由晶间孔和连接不良的溶蚀孔组成,溶蚀孔大多被高岭石、石英过长等溶蚀副产物遮挡。研究表明,在地球化学逐渐封闭的条件下,大气水通过断裂和多孔砂岩向下渗透的溶解能力明显减弱。同时,系统内溶解阳离子的再沉淀得到加强。这些耦合成岩作用最终控制了隆升构造带优质储层的分布。
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引用次数: 0
Early Paleozoic magmatism and Au mineralization in the central Truong Son Belt: Insights from geochronology and lead isotope at the Me Xi gold deposit, Vietnam 越南美溪金矿床早古生代岩浆作用与金成矿作用的年代学和铅同位素研究
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-22 DOI: 10.1016/j.jseaes.2025.106938
Truong Xuan Le , Khin Zaw , Hai Thanh Tran , Sebastien Meffre , Pham Trung Hieu , Nguyen Dinh Luyen , Luong Quang Khang , Dinh Trong Tuong
The Me Xi Au deposit lies within the central Truong Son Belt, which is the largest geological structure in the Indochina Block. This region was primarily shaped by the Ordovician-Silurian (O-S) Caledonian and Permian-Early Triassic (P-T1) Indosinian orogenies. In this study, LA-ICP-MS apatite and zircon ages, along with lead isotopic composition obtained from galena and pyrite at the Me Xi Au deposit using Aqua Regia digestion and LA-ICP-MS techniques have been analysed. The results confirmed that: (1) the porphyritic dolerite yields an apatite U-Pb age of 448 ± 33 Ma. However, considering the stratigraphic constraints, this likely represents an emplacement age of ∼430–415 Ma within the analytical uncertainty range. Combined with the geochemical signatures (e.g., Zr/TiO2 and Ti/V ratios) of an extensional setting and the historical geology, this indicates a post-collision magmatism related to the Caledonian Orogeny between the Truong Son Belt and Kon Tum Massif; (2) the early Au-mineralization event (Stage 2) has predominantly upper-crustal lead sources with Paleozoic model ages. This is possibly linked to the ∼430–415 Ma post-collision dolerite of the Caledonian Orogeny; (3) the late Au-mineralization event (Stage 3) has mixed magmatic-upper crustal lead sources and Mesozoic model ages, possibly marks a metallogenic event during the post-collision phase of the Indosinian Orogeny; (4) host rocks at Me Xi comprising siltstone and sandstone are constrained by a maximum depositional age of ∼580 Ma (i.e., youngest detrital zircon) and the minimum age of ∼430–415 Ma (i.e., ages of dolerite crosscutting metasedimentary rocks). These results highlight the significance of Ordovician-Silurian magmatism in the regional tectonic framework and metallogenic evolution of the central Truong Son Belt.
美西金矿床位于中南地块最大的地质构造——中南带中部。该地区主要受奥陶—志留纪加里东期(O-S)和二叠—早三叠世(P-T1)印支造山运动的影响。本研究利用王水消解和LA-ICP-MS技术对Me Xi金矿方铅矿和黄铁矿的磷灰石和锆石年龄以及铅同位素组成进行了分析。结果表明:(1)斑岩白云石产磷灰石U-Pb年龄为448±33 Ma。然而,考虑到地层的限制,这可能代表了在分析不确定范围内的~ 430-415 Ma的就位年龄。结合伸展环境的地球化学特征(如Zr/TiO2和Ti/V比值)和历史地质特征,表明张子带和Kon - Tum地块之间存在与加里东期造山运动有关的碰撞后岩浆活动;(2)早期金成矿事件(第2阶段)以上地壳铅源为主,具有古生代模式年龄。这可能与加里东造山期碰撞后的~ 430-415 Ma白云岩有关;(3)晚期金成矿事件(第3阶段)具有岩浆-上地壳铅混合源和中生代模式年龄,可能标志着印支造山后碰撞期的成矿事件;(4)由粉砂岩和砂岩组成的美溪寄主岩石受最大沉积年龄~ 580 Ma(即最年轻的碎屑锆石)和最小沉积年龄~ 430 ~ 415 Ma(即白云岩横切变质沉积岩年龄)的制约。这些结果突出了奥陶系—志留系岩浆活动在张子带中部区域构造格局和成矿演化中的重要意义。
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引用次数: 0
Microtremor-based site characterization for Gujarat broadband seismological network established in an intraplate setting 基于微震的古吉拉特邦宽带地震台网在板内设置的站点特征
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-22 DOI: 10.1016/j.jseaes.2025.106934
Harsh Limbachiya , Sumer Chopra , Tarun Solanki
A network of broadband seismic stations has been deployed across the Gujarat region in western India, covering diverse geological settings. Microtremor data obtained at these stations are used to characterize the sites through horizontal to vertical spectral ratio (HVSR) analysis. The HVSR curves are modeled to derive 1D shear-wave velocity (VS) profile beneath each site. The fundamental frequency (f0) across the Gujarat varies between 0.2 and 17.7 Hz with values of 0.2–0.5 Hz and 0.9–1.2 Hz observed for sites located on Quaternary and Rann sediments, respectively. Most sites underlain by Tertiary and Cretaceous formations exhibit flat HVSR curves, while Deccan Trap sites show similarly flat responses up to 10 Hz. The VS30, a key parameter for site characterization, varies from 228 to 743 m/s across Gujarat. At sites underlain by Quaternary sediments, the average VS30 is 288 ± 34 m/s. For Tertiary, Jurassic, Cretaceous and Proterozoic formations, the average VS30 values are 413 ± 85 m/s, 478 ± 76 m/s, 435 ± 56 m/s and 680 ± 28 m/s, respectively. In Deccan Traps, an average VS30 of 585 ± 64 m/s is observed. The VS30 values obtained from the HVSR modelling show good agreement with those obtained from active seismic methods such as multi-channel analysis of surface waves (MASW). This study presents the first region-wide site characterization of Gujarat using microtremor data. It demonstrates the efficacy of HVSR-based modeling in capturing geology-controlled variations in site response across a tectonically active and lithologically complex region. The results provide essential inputs for seismic hazard assessment, engineering design, and future microzonation studies in western India.
一个宽带地震台站网络已经在印度西部的古吉拉特邦地区部署,覆盖了不同的地质环境。在这些站点获得的微震数据被用来通过水平与垂直频谱比(HVSR)分析来表征这些站点。对HVSR曲线进行建模,得出每个站点下的一维横波速度(VS)剖面。古吉拉特邦的基频(f0)在0.2 ~ 17.7 Hz之间变化,第四纪沉积物和Rann沉积物的观测值分别为0.2 ~ 0.5 Hz和0.9 ~ 1.2 Hz。大多数位于第三纪和白垩纪地层之下的地点显示出平坦的HVSR曲线,而德干圈闭的地点也显示出类似的平坦响应,最高可达10 Hz。VS30是场地特征的关键参数,在古吉拉特邦从228到743米/秒不等。在第四纪沉积物下垫点,平均VS30为288±34 m/s。第三系、侏罗系、白垩纪和元古代的平均VS30分别为413±85 m/s、478±76 m/s、435±56 m/s和680±28 m/s。在德干圈闭中,观测到的平均VS30为585±64 m/s。HVSR模拟得到的VS30值与多道面波分析(MASW)等主动地震方法得到的VS30值吻合良好。这项研究提出了古吉拉特邦使用微震数据的第一个区域范围的站点特征。它证明了基于hvrr的建模在构造活跃和岩性复杂地区捕捉现场响应的地质控制变化方面的有效性。研究结果为印度西部地震危险性评估、工程设计和未来的微区划研究提供了必要的投入。
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引用次数: 0
Fluid evolution in the Naxi Fe polymetallic deposit, Eastern Kunlun, China: Insights from in-situ trace element and sulfur isotope compositions of pyrite and pyrrhotite 东昆仑纳西铁多金属矿床流体演化:黄铁矿和磁黄铁矿的原位微量元素和硫同位素组成
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-22 DOI: 10.1016/j.jseaes.2025.106932
Rongqiang Guo , Shijiong Han , Chenggang Cao , Kaizhang Shi , Yurui Yuan , Mingyu Tang , Jinxin Yuan , Yongkun Fang , Yushan Jia
The genesis of the Nalinguolehexi (Naxi) skarn Fe polymetallic deposit, Eastern Kunlun, China, remains poorly constrained. This study presents in-situ LA-ICP-MS trace element and sulfur isotope analyses of pyrite and pyrrhotite to decipher its fluid evolution. Four sulfide generations (Py1, Py2, Po, Py3) were identified. Early pyrite (Py1, Py2) is enriched in Co and Ni (Co/Ni > 1), indicating a hydrothermal origin, whereas late-stage Py3 shows pronounced enrichment in As, Pb, Bi, and Sb. Sulfur isotopes (δ34S = −5.9 ‰ to 8.2 ‰) display a decreasing trend from early (avg. 6.6 ‰) to late generations (avg. −5.3 ‰). Elevated early δ34S values suggest magmatic sulfur mixed with crustal or limestone-derived sulfur. Porous textures in Py3, trace element signatures, and principal component analysis collectively indicate a late-stage fluid boiling event. This boiling increased oxygen fugacity and pH, triggering base metal precipitation and inducing kinetic sulfur isotope fractionation responsible for the negative δ34S values. The Naxi deposit is classified as a typical skarn-type system formed by contact metasomatism between magmatic-hydrothermal fluids and the Dagangou Formation limestone. Fluid cooling and boiling were the pivotal mechanisms controlling metal precipitation and isotopic variation. This study identifies geochemical proxies for boiling in skarn systems, offering critical insights for exploring concealed deposits in the Qimantage belt and similar intracontinental settings.
东昆仑纳林郭勒河西(纳西)夕卡岩型铁多金属矿床成因尚未明确。本文对黄铁矿和磁黄铁矿进行了原位LA-ICP-MS微量元素和硫同位素分析,以揭示其流体演化规律。鉴定出4代硫化物(Py1、Py2、Po、Py3)。早期黄铁矿(Py1、Py2)富集Co和Ni (Co/Ni > 1),表明黄铁矿为热液成因,而晚期黄铁矿(Py3)富集As、Pb、Bi和Sb。硫同位素(δ34S = - 5.9‰~ 8.2‰)从早期(平均6.6‰)到晚期(平均- 5.3‰)呈下降趋势。早期δ34S值升高表明岩浆硫与地壳硫或石灰岩硫混合。Py3的多孔结构、微量元素特征和主成分分析共同表明了晚期流体沸腾事件。这种沸腾增加了氧逸度和pH值,引发了贱金属的析出,并诱发了导致负δ34S值的硫同位素动力学分馏。纳西矿床是岩浆热液与大干沟组灰岩接触交代形成的典型夕卡岩型矿床。流体冷却和沸腾是控制金属析出和同位素变化的关键机制。本研究确定了夕卡岩体系沸腾的地球化学指标,为探索奇曼塔格带和类似陆内环境的隐伏矿床提供了重要见解。
{"title":"Fluid evolution in the Naxi Fe polymetallic deposit, Eastern Kunlun, China: Insights from in-situ trace element and sulfur isotope compositions of pyrite and pyrrhotite","authors":"Rongqiang Guo ,&nbsp;Shijiong Han ,&nbsp;Chenggang Cao ,&nbsp;Kaizhang Shi ,&nbsp;Yurui Yuan ,&nbsp;Mingyu Tang ,&nbsp;Jinxin Yuan ,&nbsp;Yongkun Fang ,&nbsp;Yushan Jia","doi":"10.1016/j.jseaes.2025.106932","DOIUrl":"10.1016/j.jseaes.2025.106932","url":null,"abstract":"<div><div>The genesis of the Nalinguolehexi (Naxi) skarn Fe polymetallic deposit, Eastern Kunlun, China, remains poorly constrained. This study presents in-situ LA-ICP-MS trace element and sulfur isotope analyses of pyrite and pyrrhotite to decipher its fluid evolution. Four sulfide generations (Py1, Py2, Po, Py3) were identified. Early pyrite (Py1, Py2) is enriched in Co and Ni (Co/Ni &gt; 1), indicating a hydrothermal origin, whereas late-stage Py3 shows pronounced enrichment in As, Pb, Bi, and Sb. Sulfur isotopes (δ<sup>34</sup>S = −5.9 ‰ to 8.2 ‰) display a decreasing trend from early (avg. 6.6 ‰) to late generations (avg. −5.3 ‰). Elevated early δ<sup>34</sup>S values suggest magmatic sulfur mixed with crustal or limestone-derived sulfur. Porous textures in Py3, trace element signatures, and principal component analysis collectively indicate a late-stage fluid boiling event. This boiling increased oxygen fugacity and pH, triggering base metal precipitation and inducing kinetic sulfur isotope fractionation responsible for the negative δ<sup>34</sup>S values. The Naxi deposit is classified as a typical skarn-type system formed by contact metasomatism between magmatic-hydrothermal fluids and the Dagangou Formation limestone. Fluid cooling and boiling were the pivotal mechanisms controlling metal precipitation and isotopic variation. This study identifies geochemical proxies for boiling in skarn systems, offering critical insights for exploring concealed deposits in the Qimantage belt and similar intracontinental settings.</div></div>","PeriodicalId":50253,"journal":{"name":"Journal of Asian Earth Sciences","volume":"298 ","pages":"Article 106932"},"PeriodicalIF":2.4,"publicationDate":"2025-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145842642","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Phosphogenesis of Kakul Garlaniyan phosphorites during the early Cambrian in northeastern Pakistan 巴基斯坦东北部早寒武世Kakul Garlaniyan磷矿的成磷作用
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-21 DOI: 10.1016/j.jseaes.2025.106927
Massam Ali , Haifeng Fan , Danish Khan , Fang Zhang , Ishfaq Ahmad , Muhammad Asif Sherliyat , Yuhan Ma , Jibran Hussain , Hanjie Wen
The largest phosphogenesis event in Earth’s history occurred during the Precambrian-Cambrian transition, characterized by the formation of extensive global phosphorite deposits. One of the most notable examples is the Kakul Garlaniyan phosphorite, located at the topmost part of the Sirban member of the Abbottabad Formation in the Hazara region of northeastern Pakistan, dating to the Early Cambrian (∼541 Ma, Terreneuvian). Despite its significance, limited studies have addressed the origin and formation processes of the phosphorite deposits in this area. To enhance our understanding, we conducted petrographic and geochemical analyses on samples from three intercalated phosphorite layers within the Sirban Member. The phosphorite comprises both primary and reworked grains, with quartz supplied by terrestrial input. The grains are derived from a marine origin, enriched by upwelling of nutrient-rich bottom seawater. Additionally, the radiogenic 87Sr/86Sr isotope ratios (0.7113–0.7129) indicate terrestrial flux to the inner shelf environment through the chemical weathering of continental rocks. Rare earth and yttrium (REY) patterns exhibit a seawater-like, post-Archean Australian Shale (PAAS)-normalized REY distribution, with significant negative Ce/Ce* anomalies (0.40–0.54) and super-chondritic Y/Ho ratios (∼50–60), indicating a hydrogenous origin and supporting oxic conditions. The (La/Yb)N and (La/Sm)N ratios in Kakul Garlaniyan phosphorite layer suggest REY adsorption during early diagenesis, consistent with modern seawater conditions. Based on these findings, we propose a phosphogenesis depositional model: phosphorite formed via upwelling and reworking rather than hydrothermal activity under mainly oxic (with rarely anoxic conditions) and abiotic conditions. Winnowing and transgression events transformed pre-existing phosphate mud into reworked grains, occurring in the absence of microbial mediation. These findings provide new insights into the processes governing phosphorite formation during the Early Cambrian period in the Abbottabad region.
地球历史上最大的产磷事件发生在前寒武纪-寒武纪过渡时期,其特征是形成了广泛的全球磷矿矿床。最著名的例子之一是Kakul Garlaniyan磷矿,位于巴基斯坦东北部哈扎拉地区Abbottabad组的Sirban成员的顶部,可追溯到早寒武纪(~ 541 Ma, Terreneuvian)。尽管具有重要意义,但对该地区磷矿床成因和形成过程的研究有限。为了加强我们的理解,我们对来自Sirban成员的三个插层磷矿层的样品进行了岩石学和地球化学分析。磷矿包括原生颗粒和改造颗粒,石英由陆源输入提供。这些谷物来自海洋,由于营养丰富的海底海水上涌而变得更加丰富。87Sr/86Sr同位素比值(0.7113 ~ 0.7129)表明陆相通过陆相岩石的化学风化作用进入陆架内部环境。稀土和钇(REY)模式呈海水状,后太古代澳大利亚页岩(PAAS)标准化REY分布,具有显著的负Ce/Ce*异常(0.40-0.54)和超球球体Y/Ho比(~ 50-60),表明其氢成因和支持氧条件。Kakul Garlaniyan磷矿层的(La/Yb)N和(La/Sm)N比值表明,在早期成岩作用中吸附了REY,与现代海水条件一致。基于这些发现,我们提出了一种磷矿沉积模式:磷矿主要在氧(很少缺氧)和非生物条件下,通过上升流和改造而不是热液活动形成。筛选和海侵事件将先前存在的磷酸盐泥浆转化为重新加工的颗粒,发生在没有微生物中介的情况下。这些发现为阿伯塔巴德地区早寒武世磷矿形成过程提供了新的认识。
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引用次数: 0
Genesis and evolution of ore-forming fluids in the Liushashan Mo deposit, Inner Mongolia: Insights from fluid inclusions and C–H–O–S isotopes 内蒙古柳沙山钼矿成矿流体的成因与演化:流体包裹体和C-H-O-S同位素的启示
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-21 DOI: 10.1016/j.jseaes.2025.106930
Shuopu Yuan , Jianping Wang , Jichun Wang , Dongxing Wang , Jinghao Sun , Degao Zhai , Jiajun Liu , Fangfang Zhang , Zhenjiang Liu
The Liushashan molybdenum deposit is located in the northern Beishan orogenic belt. The orebodies are predominantly hosted within Late Paleozoic granodiorite and quartz diorite. Two distinct mineralization types have been identified: porphyry-style mineralization and quartz-vein-style mineralization, which are characterized by stockwork-disseminated and massive quartz-vein features, respectively. Mineralization includes four paragenetic stages: (1) quartz-K-feldspar, (2) quartz-polymetallic sulfide, (3) quartz-molybdenite, and (4) quartz-calcite. Integrated fluid inclusions microthermometry and C–H–O–S stable isotope analyses were performed to constrain the properties, sources, and evolution of the ore-forming fluids, as well as the metallogenic mechanisms. Three types of fluid inclusions were identified: liquid-rich two-phase (LV-type), vapor-rich two-phase (VL-type), and pure liquid-phase (PL-type) inclusions, with LV-type constituting over 90 % of the total. Microthermometric analyses of fluid inclusions assemblages in quartz from different stages indicate homogenization temperatures of 331–431°C (Stage I), 273–367 °C (Stage II), 206–299 °C (Stage III), and 172–207 °C (Stage IV), with fluid salinities of 2.4–9.5 wt% NaCl equiv., 3.6–13.0 wt% NaCl equiv., 2.4–10.0 wt% NaCl equiv., and 2.4–7.6 wt% NaCl equiv., respectively. Combined C–H–O–S stable isotope data suggest that the ore-forming fluids were derived from deep-seated magmatic-hydrothermal systems and progressively mixed with meteoric water in later stages. Fluid boiling and mixing are the dominant ore precipitation mechanisms. Based on geological, fluid inclusions, and isotopic features, the Liushashan deposit is classified as a subduction-related porphyry Mo deposit.
柳山山钼矿床位于北山造山带北部。矿体主要赋存于晚古生代花岗闪长岩和石英闪长岩中。发现斑岩型矿化和石英脉型矿化两种不同的成矿类型,分别以网状浸染型和块状石英脉型为特征。成矿包括四个共生阶段:(1)石英-钾长石、(2)石英-多金属硫化物、(3)石英-辉钼矿和(4)石英-方解石。综合流体包裹体显微测温和C-H-O-S稳定同位素分析,对成矿流体的性质、来源、演化及成矿机制进行了约束。鉴定出富液两相(lv型)、富气两相(lv型)和纯液相(pl型)包裹体3种类型,其中lv型占90%以上。石英中不同阶段流体包裹体组合的显微测温分析表明,均一温度为331-431°C(第一阶段)、273-367°C(第二阶段)、206-299°C(第三阶段)和172-207°C(第四阶段),流体盐度分别为2.4-9.5 wt% NaCl当量、3.6-13.0 wt% NaCl当量、2.4-10.0 wt% NaCl当量和2.4-7.6 wt% NaCl当量。C-H-O-S稳定同位素资料表明成矿流体来源于深部岩浆-热液系统,并在后期逐渐与大气水混合。流体沸腾和混合是主要的矿石沉淀机制。综合地质、流体包裹体和同位素特征,将柳沙山矿床划分为与俯冲有关的斑岩型钼矿床。
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引用次数: 0
Petrogenesis of Himalayan NYF-type granitic pegmatites: Constraints from accessory minerals in the beryl-bearing pegmatite, Kangmar Dome, China 喜马拉雅nyf型花岗质伟晶岩的岩石成因:来自康玛山含绿柱石伟晶岩副矿物的制约
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-20 DOI: 10.1016/j.jseaes.2025.106926
Qiaoli Wang , Lei Xie , Rucheng Wang , Zhichao Liu
The Kangmar Dome is located in the eastern Tethyan-Himalayan leucogranite belt. A distinctive feature of this dome is the absence of leucogranite outcrops, but numerous beryl-bearing granitic pegmatite veins (hereafter referred to as beryl pegmatite) intrude the granitic gneiss host rocks. Distinct from the LCT-type pegmatite found in Himalaya, the Kangmar beryl pegmatites (pegmatite I) contain large numbers of Nb-Y-Ti oxide minerals and fluorite, which are the typical minerals of NYF-type pegmatite. Whereas, pegmatite II is characterized by abundant beryl (16 vol%) and Ta-enriched oxide minerals. Hafnian zircon (0.1 < Hf#<0.5) are commonly present in pegmatite I whereas hafnon (Hf#>0.5) is only found in pegmatite II, indicating extreme fractional crystallization and intense hydrothermal fluid activity of pegmatite II. The beryl pegmatites yielded zircon 206Pb/238U ages, monazite 208Pb/232Th ages and muscovite Rb-Sr isochron ages of 26–25 Ma. Zircons within beryl pegmatites generally exhibit Paleozoic cores (∼499 Ma), consistent with the age of the host granitic gneisses. However, εNd(t) values of the beryl pegmatites have a wider range (−16.8 to −7.7) as compared with the narrow range (−12.1 to −10.6) for the granitic gneisses. Consequently, we suggest that the Kangmar NYF-type pegmatites are genetically related to A-type granites that are possibly hidden at depth in a post-orogenic extensional setting. The granite was likely derived from Higher Himalayan Crystallines, with additional contribution from an undefined source that characterized by depleted isotopic signature. The melts experienced contamination by the host granitic gneiss during the emplacement. Our results highlight the unique type of rare-metal pegmatites of the Tethyan Himalaya.
康玛尔穹窿位于特提斯—喜马拉雅浅花岗带东部。该圆顶的一个显著特征是没有亮花岗岩露头,但大量含绿柱石的花岗质伟晶岩脉(以下简称绿柱石伟晶岩)侵入花岗质片麻岩为主岩。与喜马拉雅地区发现的lct型伟晶岩不同,康玛绿柱石伟晶岩(I型伟晶岩)含有大量的Nb-Y-Ti氧化物矿物和萤石,是nyf型伟晶岩的典型矿物。而伟晶岩II则具有丰富的绿柱石(16 vol%)和富ta的氧化矿物。半晶锆石(0.1 < Hf#<0.5)普遍存在于伟晶岩I中,而半晶锆石(Hf# <0.5)仅存在于伟晶岩II中,说明伟晶岩II具有极强的分馏结晶和强烈的热液活动。绿柱伟晶岩锆石年龄为206Pb/238U,独居石年龄为208Pb/232Th,白云母Rb-Sr等时年龄为26 ~ 25 Ma。绿柱石伟晶岩中的锆石一般具有古生代(~ 499 Ma)的岩心,与寄主花岗质片麻岩的年龄一致。绿柱石伟晶岩的εNd(t)值范围较宽(−16.8 ~−7.7),而花岗质片麻岩的εNd(t)值范围较窄(−12.1 ~−10.6)。因此,我们认为康玛nyf型伟晶岩可能与a型花岗岩有遗传关系,a型花岗岩可能隐藏在造山后伸展环境中。花岗岩可能来自高喜马拉雅结晶岩,另外还有一个未确定的来源,其特征是耗尽同位素特征。熔体在就位过程中受到寄主花岗岩片麻岩的污染。我们的结果突出了特提斯喜马拉雅地区稀有金属伟晶岩的独特类型。
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引用次数: 0
Hydrocarbon generation and evolution of shale and mudstone: Insights from the Triassic Chang 7 Member in the Ordos Basin, NW China 鄂尔多斯盆地三叠系长7段页岩泥岩生烃与演化
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-20 DOI: 10.1016/j.jseaes.2025.106929
Ruihui Zheng , Zhihuan Zhang , Yuan Bao , Zhipeng Li , Wenhao Li , Jiao Xue
Shale and mudstone are critical source rocks in continental basins, however, systematic studies on the differences in hydrocarbon generation and evolution processes between these two lithologies remain limited. This paper investigates the shale and mudstone of the seventh member of the Triassic Yanchang Formation (Chang 7 Member) in the Ordos Basin. The Chang 7 Member shale demonstrates a relatively high hydrocarbon generation threshold, rapid conversion rates, and a short generation cycle. Whereas mudstone is characterized by a low generation threshold, slower conversion rates, and a longer generation cycle. The maturity values (Ro) required for the oil generation threshold (conversion ≥ 20 %) are 0.68 % for shale and 0.58 % for mudstone. The onset, peak, and termination maturity values for oil generation are 0.63 %, 0.97 %, and 1.61 %, respectively, for shale, compared to 0.43 %, 1.05 %, and 1.68 % for mudstone. The optimal maturity ranges for oil generation are 0.68 %–1.21 % for shale and 0.58 %–1.33 % for mudstone. Spatial variations in burial depth and thermal evolution history across the Ordos Basin result in a progressive northward increase in the depth intervals corresponding to peak oil generation for both lithologies within the Chang 7 Member. Notably, the Chang 7 Member shale and mudstone in the Jiyuan area exhibit higher oil generation conversion efficiency, indicating significant potential for shale oil exploration. These findings provide valuable insights for advancing shale oil resource exploration and determining optimal temperature conditions for in-situ shale pyrolysis in the Ordos Basin.
页岩和泥岩是陆相盆地重要的烃源岩,但对这两种岩性生烃演化差异的系统研究仍然有限。本文对鄂尔多斯盆地三叠系延长组7段(长7段)页岩和泥岩进行了研究。长7段页岩具有生烃门槛高、转化速率快、生烃周期短的特点。而泥岩的特点是生成阈值低,转化率较慢,生成周期较长。页岩和泥岩形成生油阈值(转化率≥20%)所需的Ro值分别为0.68%和0.58%。页岩生油的起始、峰值和终止成熟度值分别为0.63%、0.97%和1.61%,泥岩生油的起始、峰值和终止成熟度分别为0.43%、1.05%和1.68%。页岩的最佳生油成熟度范围为0.68% ~ 1.21%,泥岩为0.58% ~ 1.33%。鄂尔多斯盆地埋深和热演化史的空间差异导致长7段两种岩性的生油高峰对应的深度区间逐渐向北增加。特别是姬塬地区长7段页岩、泥岩生油转化效率较高,页岩油勘探潜力巨大。这些研究结果为进一步推进鄂尔多斯盆地页岩油资源勘探和确定页岩原位热解的最佳温度条件提供了有价值的见解。
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引用次数: 0
Multi-proxy provenance records from the Yanyuan Basin reveal the Cenozoic tectonic evolution along the southeastern Tibetan Plateau 盐源盆地的多代物源记录揭示了青藏高原东南部新生代构造演化
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-20 DOI: 10.1016/j.jseaes.2025.106928
Yuquan Jiang , Linlin Li , Xiangjiang Yu , Zhongtai He , Dewen Li , Yingying Li
The timing of surface uplift and the evolution of paleodrainage systems in the southeastern Tibetan Plateau remain highly debated. The Yanyuan Basin on the southeastern margin of the Tibetan Plateau preserves key sedimentary archives of the Cenozoic tectonic evolution. This study integrates detrital zircon U-Pb geochronology with single-grain geochemical analyses of tourmaline, garnet, and rutile to reconstruct provenance changes from the Eocene Hongyazi Formation to the Pliocene–Early Pleistocene Xigeda Formation. The Eocene strata along the western margin were mainly derived from weakly metamorphosed Triassic clastic rocks of the southern Yidun Terrane, together with Neoproterozoic toTriassic intermediate–acidic intrusions exposed along the basin margins, whereas the southern margin was dominated by detritus from the Emeishan basalts. In contrast, the Xigeda Formation records a markedly different sedimentary source-to-sink system: both the western and northern margins were primarily supplied by proximal sources exhumed from the Jinhe–Qinghe and Muli thrust faults, particularly Neoproterozoic intermediate–acidic plutons. This transition reflects a fundamental reorganization of drainage networks and catchment boundaries, associated with the shift from early-stage plateau uplift and regionally integrated paleodrainage to late-stage tectonic compartmentalization under thrusting and strike-slip deformation. The combined zircon age spectra and detrital heavy mineral geochemistry provide robust constraints on sediment provenance, paleogeographic reconfiguration, and the mechanisms of tectonic transformation along the southeastern margin of the Tibetan Plateau during the Cenozoic.
青藏高原东南部地表隆升的时间和古水系的演化至今仍有争议。青藏高原东南缘盐源盆地保存了新生代构造演化的重要沉积档案。结合碎屑锆石U-Pb年代学和电气石、石榴石、金红石的单粒地球化学分析,重建了始新世洪崖子组至上新世—早更新世西格达组的物源变化。西缘始新世地层主要来自南一顿地系三叠系弱变质碎屑岩,以及盆地边缘暴露的新元古代至三叠系中酸性侵入岩,而南缘则以峨眉山玄武岩碎屑岩为主。西格达组沉积源-汇体系明显不同,西缘和北缘主要由金河-清河和木里逆冲断层的近端源供给,特别是新元古代中酸性岩体。这种转变反映了流域网络和流域边界的根本性重组,与早期高原隆升和区域综合古排水向晚期逆冲和走滑变形作用下的构造分区化转变有关。结合锆石年龄谱和碎屑重矿物地球化学特征,对青藏高原东南缘新生代沉积物源、古地理重构和构造转化机制提供了强有力的约束。
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引用次数: 0
Evolution of non-colinear fault systems from extension to transtension: Northern Dongying Sag, Bohai Bay Basin, East China 非共线断裂体系从伸展到张拉的演化:渤海湾盆地东营凹陷北部
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2025-12-20 DOI: 10.1016/j.jseaes.2025.106925
Meng Zhang , Kuihua Zhang , Shuang Song , Yanjun Cheng , Zhiping Wu
Many rift basins present non-colinear fault systems; however, different mechanisms can contribute to such fault patterns. Understanding the evolution of non-colinear faults is crucial for evaluating the paleo-stress and kinematics of rift basins. Using well-constrained 3D seismic data, we demonstrate the evolution of a basin-bounding fault and non-colinear minor faults over 40 Myr in the northern Dongying Sag, Bohai Bay Basin, East China. During the Paleocene–Middle Eocene (66–42.7 Ma), an E–W-striking basin-bounding fault and many minor faults with the same strike developed in response to regional extension. A small number of NW–SE-striking minor faults also developed, attributed to the reactivation of pre-Cenozoic faults. In the subsequent ∼ 2 Myr, the through-going basin-bounding fault surface bifurcated upwards into two overlapping master faults, accompanied with the development of splay faults. Depocentres started to migrate towards hanging walls of the splay faults. At ∼ 40.9 Ma, splay faults with a left-stepping configuration along the NE–SW direction developed and linked with the main fault plane, leading to a transition of sedimentary distribution from E–W to NE–SW. Meanwhile, E–W-, NE–SW- and NW–SE-striking minor faults synchronously developed, and some of the NE–SW-striking minor faults present a left-stepping, en-echelon arrangement. The non-colinear faults are likely to correspond to subsidiary structures in a dextral transtensional setting, associated with the right-lateral movement of a continental-scale fault, Tan-Lu Fault Zone. The Bohai Bay Basin may be suitable for a kinematic model of extension followed by dextral transtension during the Paleogene.
许多断陷盆地呈现非共线断裂体系;然而,不同的机制可能导致这样的故障模式。了解非共线断裂的演化对裂谷盆地古应力和运动学的评价具有重要意义。利用约束良好的三维地震资料,研究了渤海湾盆地东营凹陷北部40 Myr以上的盆界断裂和非共线小断裂的演化过程。古新世—中始新世(66 ~ 42.7 Ma),受区域伸展影响,发育了一条东西向的盆地边界断裂和多条相同走向的小断裂。少量北西-东向的小断裂也发育,这是由于前新生代断裂的活化所致。在随后的~ 2 Myr中,贯穿式盆地边界断裂面向上分叉成两条重叠的主断裂,并伴有展张断裂的发育。沉积中心开始向展斜断层上盘迁移。在~ 40.9 Ma时,沿NE-SW方向发育左步状断层,并与主断平面相连接,沉积分布由东西向北东向西西过渡。同时,东西向、北东向、西南向和北西向小断裂同步发育,部分北东向、西南向小断裂呈左步进、阶梯式排列。非共线断层可能对应于右旋张性背景下的附属构造,与大陆尺度断层郯庐断裂带的右向运动有关。渤海湾盆地可能适合古近纪伸展后右向张拉的运动学模式。
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引用次数: 0
期刊
Journal of Asian Earth Sciences
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