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Altering the distribution of Pd nano particles on ferroelectric substrate: Dissipative particle dynamics simulation 改变铁电衬底上钯纳米粒子的分布:耗散粒子动力学模拟
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2018-11-02 DOI: 10.1080/07315171.2018.1537334
Yue Liu, Jiaxi Tang, Chengzhi Hua, Jiuyang Li, K. Fu, Haonan Zhu
Abstract Pd nano particles have been widely used as catalyst in chemical industry. However, the catalytic efficiency has been limited by the Aggregation of the Pd. In this paper, the surface aggregation dynamics of Pd on different ferroelectric polarization surface and temperature were reported. Meanwhile, reducing the particle size to obtain the dispersed morphology of Pd was discussed by the dissipative particle dynamics method and density functional theory. The negatively poled surface offered dispersed Pd morphology, the temperature influence will be discussed in the simulation.
摘要钯纳米颗粒作为催化剂在化工领域有着广泛的应用。然而,钯的聚集限制了催化效率。本文报道了钯在不同铁电极化表面和温度下的表面聚集动力学。同时,利用耗散粒子动力学方法和密度泛函理论,讨论了减小粒子尺寸以获得分散形貌的方法。在负极表面提供分散的钯形态,温度的影响将在模拟中讨论。
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引用次数: 1
Switching related activation field for polarization-reversal and for polarization-saturation in NaNO2-PVA thin composite films NaNO2-PVA复合薄膜中极化反转和极化饱和的开关相关激活场
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2018-11-02 DOI: 10.1080/07315171.2018.1564874
Lakhbir Singh, Baljinder Kaur, T. Garg, N. Dabra, J. Hundal
Abstract The remanant polarization in ferroelectric materials appear due to some lattice hindrances which do not allow the domains and their constituting unit cells to relax back to their previous orientations at zero value of sweeping field. This tendency appears in the form of capacitance due to shaking-up of the positive and negative charge centers of the structural unit cells in every domain leading to movement of charges throughout the system. It is this kind of movement and not the permanent dipole moment of the charges in the ferroelectric sample which becomes the cause of capacitance and hence helps the system to store energy from the applied electric field over there; the stored energy in the ferroelectric sample can be stripped off with the application of some minimum reverse field called activation field for polarization reversal. Landauer modeled average polarization current over the switching time and related rate of polarization switching with some minimum applied field below which polarization switching shall be too slow to attain saturation stage of polarization during the life time of the experiment designed for the purpose and accordingly the sample, in spite of being ferroelectric, shall not translate to ferroelectric hysteresis loop. In this paper ferroelectric switching analysis of equal wt% NaNO2-PVA composite fabricated at elevated temperature is carried.
摘要铁电材料中的剩余极化是由于某些晶格阻碍导致畴及其构成单元胞在扫场为零时不能松弛回原来的方向而产生的。这种趋势以电容的形式出现,这是由于结构单元胞的正电荷和负电荷中心在每个区域的震动导致整个系统中的电荷运动。正是这种运动,而不是铁电样品中电荷的永久偶极矩,成为电容的原因,从而帮助系统从外加电场中储存能量;铁电样品中储存的能量可以通过施加最小的反场(称为极化反转激活场)来剥离。Landauer用最小的外加场来模拟随开关时间的平均极化电流和相关的极化开关速率,在这个最小的外加场下,在为此目的设计的实验寿命期间,极化开关将太慢而无法达到极化的饱和阶段,因此,样品虽然是铁电的,但不会转化为铁电磁滞回线。本文对高温制备的等wt% NaNO2-PVA复合材料进行了铁电开关分析。
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引用次数: 3
Pyroelectric performance of (Ba0.825+xCa0.175-x)(Ti1-xSnx)O3 lead free ceramics (Ba0.825+xCa0.175-x)(Ti1-xSnx)O3无铅陶瓷的热释电性能
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2018-11-02 DOI: 10.1080/07315171.2018.1537336
Moolchand Sharma, S. Singh, Bhim Singh
Abstract The pyroelectric properties of (Ba0.825+xCa0.175-x)(Ti1-xSnx)O3 ceramics with x = 0.0625, 0.0875 and 0.100 were investigated. Samples were fabricated using solid state reaction route and were exposed to IR lamp periodically to recorded open circuit voltage. Peak value of open circuit voltage was 0.8 V, 0.70 V and 0.53 V for x = 0.0625, 0.0875 and 0.1 samples, respectively. P–E loops were recorded for all the compositions under study. Further pyroelectric coefficient was estimated using P–E loops data. The values of pyroelectric coefficient estimated as 5.70 × 10−4C/m2 K, 5.5 × 10−4C/m2 K and 5 × 10−4C/m2 K for x = 0.0625,0.0875 and 0.1 samples.
研究了x = 0.0625、0.0875和0.100的(Ba0.825+xCa0.175-x)(Ti1-xSnx)O3陶瓷的热释电性能。采用固态反应法制备样品,并定期在红外光下照射至记录的开路电压。当x = 0.0625、0.0875和0.1样品时,开路电压峰值分别为0.8 V、0.70 V和0.53 V。记录了所研究的所有成分的P-E环。利用P-E环数据进一步估算热释电系数。对于x = 0.0625、0.0875和0.1样品,热释电系数分别为5.70 × 10−4C/m2 K、5.5 × 10−4C/m2 K和5 × 10−4C/m2 K。
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引用次数: 0
Exothermic effect of entropy change in second-order phase transition ferroelectrics 二阶相变铁电体中熵变的放热效应
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2018-11-02 DOI: 10.1080/07315171.2018.1537335
S. Qu, Ming Mei, W. Cao, R. K. Pan, Y. Qi, Lei Zhang, Xunzhong Shang
Abstract Exothermic effect of entropy change by dipole orintation upon E in T-C second order phase transition ferroelectrics is modeled with statistic method. Formula of entropy change and temperature change were derived, showing sharp drop of entropy in higher temperature for higher E, exothermic peak shifts to high temperature with E, and 180° turning of dipole with a critical electric field prevails entropy change in ferroelectric phase, while 180° turning dominates entropy change in paraelectric phase. The results of numerical simulation can explain regulation of heating effect of the ferroelectrics. Morphotropic phase boundary will possess giant exothermic effect in principle.
用统计方法模拟了T-C二阶相变铁电体中偶极子取向熵变对E的放热效应。推导了熵变和温度变化的公式,表明随着E的增大,熵在温度越高时急剧下降,放热峰随着E的增大而向高温移动,铁电相的熵变以偶极子在临界电场作用下的180°转向为主,而准电相的熵变以180°转向为主。数值模拟的结果可以解释铁电体热效应的规律。从原理上讲,相变边界具有巨大的放热效应。
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引用次数: 3
Effects of Li and Cu dopants on the crystal structure of Ba0.65Sr0.35TiO3 thin films Li和Cu掺杂剂对Ba0.65Sr0.35TiO3薄膜晶体结构的影响
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2018-11-02 DOI: 10.1080/07315171.2018.1537333
Irzaman, M. Dahrul, B. Yuliarto, K. Hammam, H. Alatas
Abstract A barium strontium titanate Ba0.65Sr0.35TiO3 and its lithium (Li) and copper (Cu) doped thin films have fabricated on quartz substrates based on sol-gel and spin-coating method. Chemical solution deposition with spin-coating technique deposited the thin films. The addition of Li and Cu dopants lead to the change of lattice constant and the change of grain size. From Scherrer’s equation, it found that BLST and BCST thin films have larger and smaller grain size than that of BST, respectively. It also revealed that the crystal structures formed in a phase between cubic and tetragonal structure. Scanning electron microscopy was confirmed homogenous surfaces of thin film and energy dispersive x-ray was showed chemical composition according to the considered stoichiometry.
摘要采用溶胶-凝胶和旋涂法制备了钛酸锶钡Ba0.65Sr0.35TiO3及其掺杂锂(Li)和铜(Cu)薄膜。采用旋涂技术进行化学溶液沉积。Li和Cu掺杂剂的加入导致了晶格常数的变化和晶粒尺寸的变化。由Scherrer’s方程可知,BLST和BCST薄膜的晶粒尺寸分别比BST大和小。结果表明,晶体结构形成于立方结构和四边形结构之间。扫描电镜证实薄膜表面均匀,能量色散x射线显示化学成分符合所考虑的化学计量学。
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引用次数: 8
Rietveld refinement and multiferroic properties of Gd and Ti co-doped BiFeO3 Gd和Ti共掺BiFeO3的Rietveld细化和多铁性
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2018-08-31 DOI: 10.1080/07315171.2018.1499357
Fei Xue, Yahui Tian, Lu Tang, Pengwei Guo, Zhe Luo, Wang Li
Abstract Bi0.8Gd0.2Fe0.95Ti0.05O3 (BGFT) multiferroic ceramics were prepared by a solid-state reaction, and their sintering, microstructure, dielectric and magnetic properties were studied. Experimental results show that BGFT ceramics sintered at 980 °C possess a pure orthorhombic (space group, Pnma) structure, and these ceramics possess high relative theoretical density (∼95%), low leakage current density (10−6 A/cm2). The magnetic and electric measurements show the coexistence of ferroelectric and weak ferromagnetic in BGFT ceramics. The results of the Rietveld refinement for BGFT ceramics reveal the existence of bismuth and oxygen vacancies, and these vacancies have an important influence on the electric and magnetic properties.
摘要:采用固相反应法制备了Bi0.8Gd0.2Fe0.95Ti0.05O3 (BGFT)多铁陶瓷,对其烧结、微观结构、介电性能和磁性能进行了研究。实验结果表明,在980℃下烧结的BGFT陶瓷具有纯正交(空间群,Pnma)结构,具有较高的相对理论密度(~ 95%)和较低的漏电流密度(10−6 a /cm2)。磁学和电学测量表明,BGFT陶瓷中存在铁电和弱铁磁共存现象。BGFT陶瓷的Rietveld细化结果揭示了铋和氧空位的存在,这些空位对BGFT陶瓷的电、磁性能有重要影响。
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引用次数: 5
Piezoelectric sensitivity and electromechanical coupling in a novel corundum-containing 3–0-type composite 新型含刚玉3 - 0型复合材料的压电灵敏度与机电耦合
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2018-08-31 DOI: 10.1080/07315171.2018.1499360
P. A. Borzov, S. Filippov, V. Topolov, O. E. Brill, A. Panich
Abstract A novel 3–0-type composite, that contains ferroelectric (PZT-type) and corundum ceramics, is studied to show features of the piezoelectric response and anisotropy of electromechanical coupling factors. The corundum ceramic is applied as a component with a large elastic stiffness. Almost equal volume fractions of corundum mc and air pores mp are detected at 0.05 < mc < 0.18, and this has no analogies among the studied piezo-active 3–0-type composites. Experimental results on the piezoelectric coefficients , thickness electromechanical coupling factor , planar electromechanical coupling factor , and anisotropy (and ) are interpreted in terms of a model that takes into account features of the composite microgeometry and an interaction between the 3–0 ferroelectric ceramic/corundum and 3–0 ferroelectric ceramic/air regions. The studied 3–0-type composite can be of interest as an active element of piezoelectric transducers, sensors, and other piezotechnical devices.
研究了一种新型的3 - 0型铁电(pzt型)和刚玉陶瓷复合材料的压电响应特性和机电耦合因子的各向异性。刚玉陶瓷作为弹性刚度较大的构件。在0.05 < mc < 0.18时,刚玉mc和气孔mp的体积分数几乎相等,这在所研究的压电活性3 - 0型复合材料中没有相似之处。利用考虑复合材料微观几何特征以及3-0铁电陶瓷/刚玉区和3-0铁电陶瓷/空气区相互作用的模型,对压电系数、厚度机电耦合因子、平面机电耦合因子和各向异性(和)的实验结果进行了解释。所研究的3 - 0型复合材料可作为压电换能器、传感器和其他压电器件的有源元件。
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引用次数: 3
Dual friction-drive SAW motor utilizing cylindrical shaft as external load driver 采用圆柱轴作为外部负载驱动器的双摩擦驱动SAW电机
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2018-08-31 DOI: 10.1080/07315171.2018.1499359
Basudeba Behera, Hashal B. Nemade
Abstract This work presents an ingenious mechanism using dual frictional-drive (DFD) for surface acoustic wave (SAW) linear motor resulting in significantly compact and lightweight design. The device uses two synchronous Rayleigh waves propagating on two 128° rotated y-cut x-propagated lithium niobate (LiNbO3) piezoelectric stators facing each other and driving a cylindrical slider held tightly between the stators in translational motion. By reversing the direction of propagation of both the SAWs, the direction of motion of the slider can be reversed. The experimental results of the proposed SAW motor demonstrate the novel mechanism to form the device where the slider is attaining a steady state velocity of 1.28 m/s for a continuous wave excitation of frequency 13.5 MHz.
摘要:本研究提出了一种巧妙的双摩擦驱动(DFD)表面声波(SAW)直线电机的机制,从而实现了显著的紧凑和轻量化设计。该装置使用两个同步瑞利波在两个128°旋转的y切x传播铌酸锂(LiNbO3)压电定子上传播,并驱动一个圆柱形滑块,该滑块紧靠在定子之间进行平移运动。通过反转两个saw的传播方向,滑块的运动方向可以反转。实验结果表明,在频率为13.5 MHz的连续波激励下,该滑块达到1.28 m/s的稳态速度。
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引用次数: 6
Excellent piezoelectric properties and high Tc in Fe2O3-doped PMW-PNN-PZT ceramics fe2o3掺杂PMW-PNN-PZT陶瓷具有优异的压电性能和高Tc
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2018-08-31 DOI: 10.1080/07315171.2018.1499358
Juhyun Yoo
Abstract In this work, in order to develop piezoelectric ceramics sintered at low temperature with high piezoelectric d31 coefficient, Pb(Mg1/2W1/2)0.03(Ni1/3Nb2/3)0.09(Zr0.5Ti0.5)0.88O3 ceramics were fabricated as a function of the amount of Fe2O3 addition using a conventional mixed oxide method. The microstructure, dielectric and piezoelectric properties were systematically investigated as a function of amount of Fe2O3 addition. At the sintering temperature of 920 °C, the excellent values of density = 7.94 (g/cm3), piezoelectric coefficient (d31) = 246 pC/N, planar electromechanical coupling coefficient (kp) = 0.69, mechanical quality factor (Qm) = 213, dielectric constant (εr) = 2,682 and high Curie temperature =366 °C were obtained from the ceramics doped with 0.3 wt% Fe2O3, respectively.
摘要为了制备高压电d31系数的低温烧结压电陶瓷,采用传统的混合氧化物法,制备了以Fe2O3添加量为函数的Pb(mg1 / 2w /2)0.03(Ni1/3Nb2/3)0.09(Zr0.5Ti0.5)0.88O3陶瓷。系统地研究了Fe2O3添加量对材料微观结构、介电和压电性能的影响。在烧结温度为920℃时,掺量为0.3 wt% Fe2O3的陶瓷分别获得了密度7.94 (g/cm3)、压电系数(d31) = 246 pC/N、平面机电耦合系数(kp) = 0.69、机械品质因子(Qm) = 213、介电常数(εr) = 2682和高居里温度366℃的优异值。
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引用次数: 5
Optical properties and crystal structure of lithium doped Ba0.55Sr0.45TiO3 (BLST) thin films 掺锂Ba0.55Sr0.45TiO3 (BLST)薄膜的光学性质和晶体结构
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2018-08-31 DOI: 10.1080/07315171.2018.1499361
Irzaman, A. Nuraisah, Aminullah, K. A. Hamam, H. Alatas
Abstract Lithium (0, 1, 3, 5%) doped Ba0.55Sr0.45TiO3 (BLST) thin films have been successfully manufactured by growing Li2O-doped Ba0.55Sr0.45TiO3 on the surface of p-type Si (111) substrate. Concentration of 1 M with annealing temperature of 850 °C for 15 hours was used in BST and BLST films. The Li dopant addition induced smaller lattice paramater, film thickness, gap energy, and greater refractive index. These results were supported by imaging surface morphology which Li+ ion can replace Sr2+ ion in the structure due to its small radius. Characterization of BST and BLST films structural showed they have cubic structure.
摘要通过在p型Si(111)衬底表面生长li20掺杂Ba0.55Sr0.45TiO3,成功制备了掺杂Ba0.55Sr0.45TiO3 (BLST)薄膜。BST和BLST薄膜的退火温度为850℃,浓度为1m,退火时间为15小时。Li掺杂剂的加入使晶格参数、薄膜厚度、间隙能变小,折射率增大。这些结果得到了成像表面形貌的支持,Li+离子由于其半径小,可以在结构中取代Sr2+离子。BST和BLST薄膜的结构表征表明它们具有立方结构。
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引用次数: 2
期刊
Ferroelectrics Letters Section
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