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Synergistic effect of self-poled fibre based flexible lead-free KNN/P(VDF-HFP) nanofiber mat for scavenging piezoelectric energy 自极性纤维基柔性无铅KNN/P(VDF-HFP)纳米纤维垫清除压电能量的协同效应
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2022-11-02 DOI: 10.1080/07315171.2022.2122412
G. Kaur, Pratiksha, Mamta Shandilya, Sahil Kumar
Abstract KNN/P(VDF-HFP) based nanofiber composite was developed by using the electrospinning technique. The significant enhanced value of β-phase content on addition of KNN is evident from the XRD and FTIR spectrum. FE-SEM micrographs reveal the formation of dense and compact nanofillers and their embedment within polymer matrix results in homogenous, smooth and uniform nanofibers without any agglomeration. The piezoelectric response of the nanofiber mat was improved by enhancing the induced charge of P(VDF-HFP) and β-phase content on incorporating KNN within the matrix, which holds great potential to improve the self-power generation performance of piezoelectric nano-generators.
摘要采用静电纺丝技术制备了KNN/P(VDF-HFP)基纳米纤维复合材料。XRD和FTIR分析表明,加入KNN后,β相含量显著提高。FE-SEM显微图显示,纳米填料致密致密的形成及其在聚合物基体中的嵌入使纳米纤维均匀、光滑、均匀,无团聚现象。通过在基体中加入KNN,提高P(VDF-HFP)的诱导电荷和β相含量,改善了纳米纤维垫的压电响应,这对提高压电纳米发电机的自发电性能具有很大的潜力。
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引用次数: 1
CdSe thin films prepared by the homemade and cost effective spray pyrolysis technique 采用喷雾热解技术制备了具有成本效益的CdSe薄膜
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2022-11-02 DOI: 10.1080/07315171.2022.2076470
A. D. Kanwate, V. R. Panse, E. U. Masumdar, E. Palupi, R. Umam, Ardimas, G. Antarnusa
Abstract The CdSe thin film was deposited on glass substrate by homemade spray pyrolysis technique at substrate temperature 3000C. Further the film was characterized through X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM), Energy dispersive X-ray analysis (EDAX), UV-Visible optical spectroscopy and Electrical. The XRD pattern of CdSe film shows polycrystalline hexagonal crystal structure with average crystalline size of the film was 16.3 nm. The SEM micrograph shows the film was uniform, adherent, without pin-hole and crack free. From EDAX analysis conform that the presence of Cd and Se in prepared film with elemental stoichiometry of Cd and Se was 49.30% and 50.70%, respectively. The optical band gap was direct band gap and it was found 1.78 eV. The electrical resistivity of the film at room temperature was 6.9 × 106 Ωcm.
摘要:采用自制的喷雾热解技术,在3000℃的温度下将CdSe薄膜沉积在玻璃基板上。通过x射线衍射(XRD)、场发射扫描电镜(FESEM)、能量色散x射线分析(EDAX)、紫外可见光谱学和电学等手段对薄膜进行了表征。CdSe膜的XRD谱图显示为多晶六方晶体结构,膜的平均晶粒尺寸为16.3 nm。SEM显微照片显示膜层均匀、黏附、无针孔、无裂纹。EDAX分析表明,制备膜中Cd和Se的元素化学计量量分别为49.30%和50.70%。光学带隙为直接带隙,为1.78 eV。薄膜在室温下的电阻率为6.9 × 106 Ωcm。
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引用次数: 0
Structural and Electrical Properties of Pb (Mg1 / 3Nb2 / 3) O3-Pb (Yb1 / 2Nb1 / 2) O3-PbTiO3 Ternary Ceramic for Energy Storage Application 储能用Pb (Mg1 / 3Nb2 / 3) O3-Pb (Yb1 / 2Nb1 / 2) O3-PbTiO3三元陶瓷的结构与电学性能
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2022-11-02 DOI: 10.1080/07315171.2022.2122415
Venkatraj Athikesavan, S. Bhuvana, G. Thilakavathi
Abstract The polycrystalline ternary ferroelectric ceramic of PMN-PYN-PT (PMN = PbMg1/3Nb2/3O3, PYN = PbYbl/3Nb2/3O3, PT = PbTiO3) were synthesized by conventional solid state reaction technique. The structural, electrical and energy-storage properties of the ceramic were investigated. X-ray diffraction studies reveal that the ceramic has a coexistence of both tetragonal and rhombohedral phases. Dielectric studies of the sintered samples were studied as a function of temperature ranging from room temperature to 400 °C and in the wide frequency range of 1–50 kHz which shows good relaxor behavior. P-E hysteresis loops for the ceramic confirm good ferroelectric properties, exhibiting at (Pr ∼ 17.5 µC cm−2, Ec ∼ 36.5 and Pm ∼ 20.3) were obtained for PMN-PYN-PT. Energy storage density (W) of 0.13 Jcm−3 was achieved at 50 kV/cm1. The optimum piezoelectric coefficient and piezoelectric voltage coefficient (d33 ∼ 412 pC/N, g33 ∼1.6) measured on the poled sample for PMN-PYN-PT, respectively. From these analyses, the reported ceramic is a promising candidate for energy-storage capacitor applications.
摘要采用常规固相反应法制备了PMN-PYN-PT (PMN = PbMg1/3Nb2/3O3, PYN = PbYbl/3Nb2/3O3, PT = PbTiO3)多晶三元铁电陶瓷PMN-PYN-PT。研究了陶瓷的结构、电学和储能性能。x射线衍射研究表明,该陶瓷具有四面体相和菱形体相共存的特点。在1 ~ 50 kHz的宽频率范围内,研究了烧结样品的介电特性与室温~ 400℃温度的关系,显示出良好的弛豫特性。陶瓷的P-E磁滞回线证实了良好的铁电性能,PMN-PYN-PT在(Pr ~ 17.5µC cm−2,Ec ~ 36.5和Pm ~ 20.3)处得到。在50 kV/ cm2下实现了0.13 Jcm−3的储能密度(W)。PMN-PYN-PT极化样品的最佳压电系数和压电电压系数分别为d33 ~ 412 pC/N, g33 ~ 1.6。从这些分析来看,所报道的陶瓷是储能电容器应用的有前途的候选者。
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引用次数: 3
The failure probability assessment model of piezoelectric materials under electric fatigue load 压电材料在电疲劳载荷下的失效概率评估模型
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2022-11-02 DOI: 10.1080/07315171.2022.2122414
Xianghua Chen, Qun Li, Chunguang Wang
Abstract The service life of piezoelectric devices is significantly affected by the electric fatigue load. The randomness of loads and nonuniformity of material properties caused by random distribution of internal defects in piezoelectric body will lead to the dispersion of the failure life of piezoelectric devices. Predicting failure probability of piezoelectric materials under electric fatigue load is essential for the reliability and life prediction of piezoelectric structures and devices. In this paper, the initial damage of piezoelectric materials is modeled as a random variable. Based on the methods of probability theory and statistics, the failure probability assessment model of piezoelectric materials under electric fatigue load is proposed. The probability density function of initial damage is obtained by observation and statistics of initial defect area. The failure probability assessment model of piezoelectric materials under electric fatigue load can be obtained by probability theory and integral method. Meanwhile, the failure probability evolution of piezoelectric materials under various electric fatigue loads is considered. The results show that the failure life and dispersion of piezoelectric materials is significantly affected by electric fatigue load, and the variation of failure probability under various electric loads is similar. Based on the proposed failure probability assessment models, the randomness of the electric load and randomly distributed initial defects of materials are considered in the damage evolution and performance prediction of piezoelectric structures, which is an important supplement to the reliability prediction and application of piezoelectric devices.
电疲劳载荷对压电器件的使用寿命影响很大。压电体内部缺陷的随机分布所引起的载荷的随机性和材料性能的非均匀性将导致压电器件失效寿命的分散。预测压电材料在电疲劳载荷作用下的失效概率对压电结构和器件的可靠性和寿命预测至关重要。本文将压电材料的初始损伤建模为随机变量。基于概率论和统计学方法,提出了压电材料在电疲劳载荷作用下的失效概率评估模型。通过对初始缺陷面积的观察和统计,得到了初始损伤的概率密度函数。利用概率论和积分法建立了压电材料在电疲劳载荷作用下的失效概率评估模型。同时考虑了压电材料在不同电疲劳载荷作用下的失效概率演化。结果表明:电疲劳载荷对压电材料的失效寿命和分散性有显著影响,且不同电载荷下的失效概率变化相似;基于所提出的失效概率评估模型,在压电结构损伤演化和性能预测中考虑了电载荷的随机性和材料初始缺陷的随机分布,是压电器件可靠性预测和应用的重要补充。
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引用次数: 0
Effect of microwave sintering on KNN-based lead free ceramics 微波烧结对knn基无铅陶瓷的影响
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2022-05-04 DOI: 10.1080/07315171.2022.2076467
Yang Zhang, Qing-Wen Dai, Jiarui Huang, J. Zhai
Abstract Microwave sintering has been known as the effective method to prepare ceramics. In this study, the microwave sintering method was used to synthesize 0.96(K0.5Na0.5)0.95Li0.05Nb0.93Sb0.07O3-0.04CaZrO3 ceramics. The effect of holding time on the properties of ceramics was investigated. With the holding time of 30 min, the excellent piezoelectric properties (d 33 = 286 pC/N) can be achieved.
微波烧结是制备陶瓷的有效方法。本研究采用微波烧结法合成了0.96(K0.5Na0.5)0.95 li0.05 nb0.93 sb0.070 o3 -0.04 cazro3陶瓷。研究了保温时间对陶瓷性能的影响。保温时间为30 min时,可获得优异的压电性能(d33 = 286 pC/N)。
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引用次数: 1
Influence of sample thickness and cross-sectional area on flexoelectric effect under one-dimensional impact 一维冲击下试样厚度和截面积对挠曲电效应的影响
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2022-05-04 DOI: 10.1080/07315171.2022.2076471
Taotao Hu, Yu Li, Peng Tu
Abstract The shock wave generates the strain gradient and consequent electric polarization in samples due to the flexoelectric effect during the impact process. At present, some scholars have studied the influence law of different impact velocities, but the influence of different thickness and cross-sectional area of samples on flexoelectric effect is still blank. In this letter, we have studied the voltage variation of barium titanate samples with different thickness and cross-sectional area under a certain impact velocity. The results show that the maximum voltage value caused by flexoelectric effect increases as the thickness increases, which is basically in positive proportion; it decreases with the increase of diameter, which is in inverse proportion. This research will lay a theoretical foundation for the fabrication of flexoelectricity sensor.
摘要冲击波在冲击过程中由于挠曲电效应在试样中产生应变梯度和相应的电极化。目前已有学者研究了不同冲击速度的影响规律,但不同试样厚度和横截面积对挠曲电效应的影响仍是空白。在这封信中,我们研究了不同厚度和横截面积的钛酸钡样品在一定冲击速度下的电压变化。结果表明:挠曲电效应引起的最大电压值随厚度的增加而增大,且基本成正比;它随直径的增大而减小,两者成反比。本研究为柔性电传感器的研制奠定了理论基础。
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引用次数: 0
Phase transition and ferroelectricity of composites based on ferroelectric metal-organic framework of [NH4][Zn(HCOO)3] 铁电金属-有机骨架[NH4][Zn(HCOO)3]复合材料的相变与铁电性
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2022-05-04 DOI: 10.1080/07315171.2022.2076465
H. Nguyen, M. T. Chau, Thi Bich Thao Phan, A. Milinskiy, S. Baryshnikov
Abstract The study suggests a simple approach to improve phase transition properties and ferroelectricity of a typical ferroelectric metal-organic framework of [NH4][Zn(HCOO)3] (AmZn) using silicon dioxides nanoparticles (nSiO2). It is shown that the first-order transition type of AmZn is not changed under the influence of nSiO2. Moreover, the phase transition temperature of AmZn significantly increased with increasing the nSiO2 content from 0 to 40 wt%. Besides, the addition of small nSiO2 content (< 11%) led to rising spontaneous saturation and remnant polarizations. The study also indicated difficulties in obtaining the saturation P-E loops at high nSiO2 content.
摘要提出了一种利用二氧化硅纳米颗粒(nSiO2)改善典型铁电金属-有机骨架[NH4][Zn(HCOO)3] (AmZn)的相变性能和铁电性的简单方法。结果表明,在nSiO2的影响下,AmZn的一阶过渡类型没有发生改变。随着nSiO2含量从0 wt%增加到40 wt%, AmZn的相变温度显著升高。此外,添加少量nSiO2(< 11%)导致自发饱和度和残余极化率上升。研究还表明,在nSiO2含量高的情况下,很难获得饱和P-E环。
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引用次数: 2
Structural and photoluminescence properties of a trivalent rare earth Sm ion-doped PVA/PVP blend polymer films 三价稀土Sm离子掺杂PVA/PVP共混聚合物薄膜的结构和光致发光性能
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2022-05-04 DOI: 10.1080/07315171.2022.2076464
C. Salma, B. H. Rudramadevi
Abstract Transparent polyvinyl alcohol (PVA)/polyvinylpyrrolidone (PVP) and various concentrations of Sm3+ ion-doped PVA/PVP blend-polymer films were prepared using the solution cast method. The structural properties were studied by using XRD and FTIR. Optical UV-Vis, photoluminescence, and decay studies were carried out for prepared PVA/PVP blend polymer films. The XRD confirms the structural change in PVA/PVP blend-polymer with the doping of Sm3+ ion. From FTIR, Sm3+ ion forms the complex formation within the PVA/PVP polymer structure. The allowed band gap decreased from 5 to 4.6 eV, and the refractive index increased from 2.4 to 2.45, increasing Sm3+ ion concentration. From the energy band gap, the bonding parameters ( and δ) were calculated to find the covalent/ionic bond nature of the prepared polymer films. The emission spectra were measured for Sm3+: PVA/PVP with the excitation of 402 nm wavelength (6H5/2→4F7/2). 4G5/2→ 6H7/2 shows maximum intensity at 0.4 wt % of Sm3+, and beyond concentration, quenching was noticed. It is observed from the decay curve that the lifetime of PVA/PVP samples doped with Sm3+ at all concentrations decreases with the increase of Sm3+ ion concentration. It was noticed from CIE chromaticity that Sm3+: PVA/PVP blend polymer films are more appropriate for enhancing reddish-orange photonic emission. Based on the above results, Sm3+: PVA/PVP blend polymer films are suitable for reddish-orange luminescent applications.
摘要采用溶液浇铸法制备了透明聚乙烯醇(PVA)/聚乙烯吡罗烷酮(PVP)和不同浓度Sm3+离子掺杂的PVA/PVP共混聚合物薄膜。采用XRD和FTIR对其结构性能进行了研究。对制备的PVA/PVP共混聚合物薄膜进行了紫外-可见、光致发光和衰减研究。XRD证实了Sm3+离子掺杂后PVA/PVP共混聚合物的结构变化。从FTIR看,Sm3+离子在PVA/PVP聚合物结构内形成络合物。允许带隙从5 eV减小到4.6 eV,折射率从2.4增加到2.45,Sm3+离子浓度增加。从能带隙中计算成键参数(和δ),以确定聚合物薄膜的共价键/离子键性质。测量了Sm3+: PVA/PVP在402 nm激发波长(6H5/2→4F7/2)下的发射光谱。4G5/2→6H7/2在Sm3+浓度为0.4 wt %时强度最大,超过浓度后出现淬灭现象。从衰减曲线上可以看出,随着Sm3+离子浓度的增加,掺杂Sm3+的PVA/PVP样品的寿命均呈下降趋势。CIE色度分析表明,Sm3+: PVA/PVP共混聚合物薄膜更适合增强红橘色光子发射。基于以上结果,Sm3+: PVA/PVP共混聚合物薄膜适用于红橙色发光应用。
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引用次数: 1
Stress induced potential barriers in composite piezoelectric semiconductor fibers in extension 复合压电半导体纤维中应力诱发电位势垒的扩展
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2021-11-01 DOI: 10.1080/07315171.2021.1971007
Shuai Ju, Haifeng Zhang, Jia-shi Yang
Abstract We study the extension of composite fibers with piezoelectric dielectric layers and nonpiezoelectric semiconductor layers. A theoretical analysis is performed using the one-dimensional macroscopic model of piezoelectric semiconductor fibers. An analytical solution is obtained for a fiber with a uniform nonpiezoelectric semiconductor layer and piecewise uniform piezoelectric dielectric layers. Numerical results show that an electric potential barrier forms near the junction between the piecewise uniform piezoelectric layers. The potential barrier depends on the extensional stress. It may be used to manipulate the electrical behaviors such as the conduction in the fiber mechanically and thus has potential applications in piezotronics.
摘要研究了具有压电介质层和非压电半导体层的复合纤维的拉伸性能。利用压电半导体光纤的一维宏观模型进行了理论分析。得到了具有均匀非压电半导体层和分段均匀压电介电层的光纤的解析解。数值结果表明,在片状均匀压电层之间的连接处附近形成了电势势垒。势垒取决于拉伸应力。它可以用于机械地操纵纤维中的导电等电学行为,因此在压电电子学中具有潜在的应用。
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引用次数: 3
Optical induction in K0.5Na0.5NbO3 ferroelectric ceramic at low calcination temperature by sol-gel route 低煅烧温度下K0.5Na0.5NbO3铁电陶瓷的光感应
IF 0.4 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER Pub Date : 2021-11-01 DOI: 10.1080/07315171.2021.1971012
Shammi Kumar, Mamta Shandilya, N. Thakur
Abstract K0.5Na0.5NbO3 ceramic was synthesized at low calcination temperature by sol-gel route. Structural properties of ceramic were investigated by X-ray diffractometer, FESEM and FTIR spectrometer. Electro-optical properties of ceramic were investigated by UV-Vis and PL spectrometer. Dielectric nature of ceramic was studied at different frequencies and temperatures which disclosed that ceramic has maximum dielectric permittivity at 500 KHz. AC conductivity analysis shows negative temperature coefficient of resistance behavior. Leakage current was studied up to 180 V which shows low value of leakage current at room temperature. Ferroelectric nature was analyzed at different electric fields (5–20 kVcm−1) at 50 Hz.
摘要采用溶胶-凝胶法制备了K0.5Na0.5NbO3陶瓷。用x射线衍射仪、FESEM和FTIR光谱仪研究了陶瓷的结构特性。用紫外可见光谱和PL谱仪研究了陶瓷的电光性能。研究了陶瓷在不同频率和温度下的介电性质,发现陶瓷在500 KHz时介电常数最大。交流电导率分析显示电阻行为为负温度系数。对180 V以下的泄漏电流进行了研究,结果表明室温下的泄漏电流值较低。在50 Hz的不同电场(5-20 kVcm−1)下分析铁电性质。
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引用次数: 5
期刊
Ferroelectrics Letters Section
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