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Fluoride removal by hydroxyapatite modified with anhydrous aluminum chloride 用无水氯化铝修饰的羟基磷灰石去除氟化物
Pub Date : 2024-05-21 DOI: 10.2166/ws.2024.117
Mengyue Ren, Xiangling Jia, Tianyin Huang, Bingdang Wu, Jingjing Yang
Efficient and low-cost removal of fluoride from water has attracted wide attention. Here, aluminum-modified hydroxyapatite (Al-HAP) was prepared by a homogeneous hydrothermal co-precipitation method. The physicochemical properties of the Al-HAP surface were characterized by SEM, XRD, FT-IR, BET, and zeta potential, and the adsorption performances were evaluated. It showed that Al-HAP has a larger specific surface area (121.97 m2/g, which is 2.3 times larger than that of HAP), more surface-active hydroxyls and positively charged at pH less than 7, which indicate that Al-HAP is beneficial to the adsorption of negatively charged fluoride. Al-HAP had a higher fluoride adsorption capacity (56.44 mg/g) than that of HAP (28.36 mg/g), and not sensitive to the interference of coexisting ions except CO32-. Based on the adsorption kinetics and adsorption isotherm experiments, the proposed two-stage kinetic model and Freundlich isotherm model can better describe the adsorption process. From the results of XPS and FT-IR, it indicated that the ion exchange between hydroxyl group on the surface and fluoride ions is the main driven force for the adsorption, and electrostatic adsorption is also helpful. The present study provides an improved HAP to effectively remove fluoride from water.
高效、低成本地去除水中的氟引起了广泛关注。本文采用均相水热共沉淀法制备了铝改性羟基磷灰石(Al-HAP)。通过 SEM、XRD、FT-IR、BET 和 zeta 电位对 Al-HAP 表面的理化性质进行了表征,并对其吸附性能进行了评估。结果表明,Al-HAP 具有更大的比表面积(121.97 m2/g,是 HAP 的 2.3 倍)、更多的表面活性羟基以及在 pH 值小于 7 时带正电荷,这表明 Al-HAP 有利于吸附带负电荷的氟化物。Al-HAP 的氟吸附容量(56.44 毫克/克)高于 HAP(28.36 毫克/克),且对除 CO32- 以外的共存离子的干扰不敏感。根据吸附动力学和吸附等温线实验,提出的两阶段动力学模型和 Freundlich 等温线模型能较好地描述吸附过程。从 XPS 和 FT-IR 的结果来看,表面羟基与氟离子之间的离子交换是吸附的主要驱动力,静电吸附也有一定作用。本研究提供了一种改进的 HAP,可有效去除水中的氟。
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引用次数: 0
Toward a water-sensitive precinct with stormwater harvesting: a case study in South Africa 利用雨水收集技术建设水敏感区域:南非案例研究
Pub Date : 2024-05-21 DOI: 10.2166/ws.2024.116
Malesela Michael Mogano, John Okedi
The study assessed static management, i.e., without planned periodic maintenance of the storage (no sediment dredging) denoted as SC1, or with maintenance denoted as SC2. The second approach was dynamic management based on applying Real-Time Control (RTC) techniques to scenario SC1 and scenario SC2 denoted as RTC-1 and RTC-2, respectively. The dynamic management of the UCT dam with RTC-1 and RTC-2 approaches increase yield by 2.1 and 1.1 ml, respectively. Additionally, RTC-1 and RTC-2 approaches increase volumetric reliability by 5.3 and 2.5%, respectively, while maintaining the required level of service of a stormwater harvesting system. SC1 and SC2 results in water savings of up to 21.15 and 21.45 ZAR/kl, respectively, while RTC-1 and RTC-2 could save up to 19.35 and 19.45 ZAR/kl. Thus, static configurations results in water savings approximately 9% in comparison to RTC. In addition, static configurations harvested stormwater at a relatively lowest unit cost in comparison to RTC configurations. Notwithstanding this finding, the RTC system exhibits a great potential in reshaping the stormwater harvesting system to simultaneously deliver water conservation and stormwater management.
该研究评估了静态管理,即没有计划的定期蓄水维护(不疏浚沉积物),称为 SC1,或有维护,称为 SC2。第二种方法是在 SC1 和 SC2 方案中应用实时控制(RTC)技术进行动态管理,分别称为 RTC-1 和 RTC-2。采用 RTC-1 和 RTC-2 方法对 UCT 大坝进行动态管理后,产量分别增加了 2.1 毫升和 1.1 毫升。此外,RTC-1 和 RTC-2 方法在保持雨水收集系统所需服务水平的同时,将容积可靠性分别提高了 5.3% 和 2.5%。SC1 和 SC2 可分别节水 21.15 和 21.45 ZAR/kl,而 RTC-1 和 RTC-2 可分别节水 19.35 和 19.45 ZAR/kl。因此,与 RTC 相比,静态配置可节水约 9%。此外,与 RTC 配置相比,静态配置收集雨水的单位成本相对最低。尽管有这一发现,但 RTC 系统在重塑雨水收集系统以同时实现节水和雨水管理方面展现出巨大的潜力。
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引用次数: 0
Hydrogeochemical evolution and processes based on multivariable statistical and inverse simulation modeling: A coal mine in the Northern Coalfield, China 基于多变量统计和反演模拟模型的水文地质化学演化过程:中国北方煤田的一个煤矿
Pub Date : 2024-05-20 DOI: 10.2166/ws.2024.111
Jingzhong Zhu, Wenping Li, Baoxin Zhao, Qilin Jiang
Considering groundwater from the aquifers overlying the bedrock is an important water source for drinking purposes. As such, the investigation of its property is essential. Based on the spatial structure of aquifers in the study area, the aquifers in the Cenozoic strata are divided into three groups. The multivariate statistical approaches are employed to identify the hydrogeochemical processes and hydro-chemical types, and hydrogeochemical inverse modeling is applied to further validate and elucidate the hydrogeochemical process and water–rock interaction. The results are as follows: (1) The hydro-chemical type of the upper aquifer is dominated by the K + Na-HCO3 type, while others have similar water quality types, which are dominated by the K + Na-Cl type and the K + Na-SO4 type. (2) The saturation index of anhydrite, gypsum, halite, and CO2(g) is below zero in three aquifers, indicating that they are unsaturated. While aragonite, calcite, and dolomite in the middle aquifer remain in the unsaturated–saturated state. (3) The cation exchange process accelerating the reduction of Ca2+ concentration and the increase of SO42− concentration occurs in three aquifers, and the dissolution of calcite and dolomite minerals occurs in most cases. This study supports the fundamental evidence for the hydrogeochemical processes and water resource utilization and has a certain practical significance.
考虑到来自基岩上覆含水层的地下水是重要的饮用水源。因此,对其性质的调查至关重要。根据研究区域含水层的空间结构,将新生代地层中的含水层分为三组。采用多元统计方法确定水文地质化学过程和水化学类型,并应用水文地质化学反演模型进一步验证和阐明水文地质化学过程和水岩相互作用。研究结果如下(1)上部含水层的水化学类型以 K+Na-HCO3 型为主,其他含水层的水质类型相似,均以 K+Na-Cl 型和 K+Na-SO4 型为主。(2) 在三个含水层中,无水石膏、石膏、海泡石和 CO2(g)的饱和指数均低于零,表明这些含水层为非饱和含水层。而中间含水层中的文石、方解石和白云石仍处于非饱和-饱和状态。(3) 三个含水层都出现了阳离子交换过程,加速了 Ca2+ 浓度的降低和 SO42- 浓度的升高,大多数情况下方解石和白云石矿物都发生了溶解。该研究为水文地质化学过程和水资源利用提供了基础证据,具有一定的现实意义。
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引用次数: 0
Coordinated emission reduction strategy of water pollution and carbon emissions in the South-to-North Water Diversion Project based on a differential game model 基于差分博弈模型的南水北调工程水污染与碳排放协调减排策略
Pub Date : 2024-05-17 DOI: 10.2166/ws.2024.115
Junfei Chen, Yusong Cheng, Wentong Yang
This study investigates the green development of the South-to-North Water Diversion Project (SNWDP) by exploring the synergistic reduction of water pollution and carbon emissions. Firstly, a differential game model is constructed to reduce pollution and carbon in the water supply chain. Secondly, the emission reduction strategies of water source and receiving areas under centralized and decentralized decision models are compared and analyzed and a cost-sharing contract is designed to coordinate the supply chain. Finally, numerical analysis is used to compare and analyze the important parameters to draw conclusions. The results show that: (1) Collaboration between water source and receiving areas influences emission reduction efforts, with the highest achieved under the centralized model. (2) The cost-sharing contract improves efforts and addresses ‘free-riding’ in the decentralized model. (3) The SNWDP can achieve a win-win situation in terms of both environmental and economic benefits by promoting the synergy of pollution reduction and carbon reduction.
本研究通过探讨协同减少水污染和碳排放,研究了南水北调工程(SNWDP)的绿色发展。首先,构建了水供应链中的污染减排和碳减排的差异博弈模型。其次,比较分析了集中决策模型和分散决策模型下水源地和受水区的减排策略,并设计了成本分摊合同来协调供应链。最后,通过数值分析对重要参数进行对比分析,得出结论。结果表明(1) 水源地和受水区之间的合作影响减排效果,集中模式下的减排效果最好。(2) 在分散模式下,成本分担合同提高了减排效果,并解决了 "搭便车 "问题。(3)通过促进污染减排和碳减排的协同作用,SNWDP 可实现环境效益和经济效益的双赢。
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引用次数: 0
Sustainable water–ecosystem management using the Bayesian network and variable relationship analysis 利用贝叶斯网络和变量关系分析进行可持续水生态系统管理
Pub Date : 2024-05-15 DOI: 10.2166/ws.2024.109
Pengyu Zhang, Meng Jia, Xiaojuan Wei
Under the pressures of global climate change and human activities, the carrying capacity of water and soil resources in agricultural lands has decreased, and the traditional models of agricultural development are no longer sustainable. Land degradation, groundwater quality reduction and ecosystem instability are the consequences of agricultural development without considering sustainability indicators. This article aims to investigate the use of variable relationship analysis and Bayesian network methods to analyze and investigate the relationship between irrigation in agriculture and the sustainability of the groundwater ecosystem. Descriptive statistics of agriculture including cultivation pattern, time, precipitation, irrigation, and land slope were analyzed and combined with the simulated characteristics of groundwater including specific yield, hydraulic conductivity and hydrodynamic diffusion coefficients. Five crops of wheat, barley, paddy, alfalfa, and potato were studied to evaluate the effect of plants on the pattern of nitrate release due to irrigation and fertilization in agriculture. The results showed that managing the amount of fertilizer and the volume of irrigation can positively affect the nitrate distribution pattern in the groundwater even in a short period of time.
在全球气候变化和人类活动的压力下,农田水土资源承载能力下降,传统的农业发展模式已不再具有可持续性。土地退化、地下水质量下降和生态系统不稳定是农业发展不考虑可持续发展指标的后果。本文旨在研究利用变量关系分析和贝叶斯网络方法分析和研究农业灌溉与地下水生态系统可持续性之间的关系。本文分析了农业的描述性统计数据,包括种植模式、时间、降水量、灌溉量和土地坡度,并结合地下水的模拟特征,包括比产量、水力传导率和水动力扩散系数。研究了小麦、大麦、水稻、苜蓿和马铃薯五种作物,以评估植物对农业灌溉和施肥导致硝酸盐释放模式的影响。结果表明,即使在很短的时间内,对肥料用量和灌溉量的管理也会对硝酸盐在地下水中的分布模式产生积极影响。
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引用次数: 0
Spatial and temporal distribution of nitrogen, phosphorus, and heavy metals loads in Guanshan River Basin based on SWAT modeling 基于 SWAT 模型的关山河流域氮、磷和重金属负荷时空分布研究
Pub Date : 2024-05-15 DOI: 10.2166/ws.2024.110
Wulin Chen, Teng Ma, Liuzhu Chen, Wenhui Liu, Ruihua Shang, Zhanqiang Chen
This study takes Guanshan River Basin, a typical inflow river of the Danjiangkou Reservoir, as the research area, and the nonpoint source (NPS) pollution characteristics of nitrogen and phosphorus from 2013 to 2018 were evaluated by establishing a Soil and Water Assessment Tool (SWAT) model. The pollution characteristics of heavy metals were also evaluated by combining the SWAT and simple output coefficient method. The results show that the pollutant load in Guanshan River Basin contributes significantly to the Danjiangkou Reservoir. Temporally, pollutant loads were primarily concentrated in the flood season, which had a significant positive correlation with precipitation, water yield, and sediments in the abundant period. Among them, sediments were the most important driving factor, followed by water yield. Spatially, pollutant loads were mainly concentrated downstream of the basin, where cultivated land is widespread. In this regard, it is suggested that the input of chemical fertilizers, pesticides, and livestock manure in cultivated land should be controlled and soil erosion downstream of the basin should be prevented to mitigate nitrogen, phosphorus, and heavy metal pollution. This research offers a basis for the formulation and implementation of watershed management for the Danjiangkou Reservoir.
本研究以丹江口水库典型入库河流关山河流域为研究区域,通过建立水土评估工具(SWAT)模型,评价了2013-2018年氮磷非点源污染特征。此外,还结合 SWAT 和简单输出系数法评估了重金属的污染特征。结果表明,关山河流域的污染物负荷对丹江口水库的影响很大。从时间上看,污染物负荷主要集中在汛期,与丰水期的降水量、产水量和泥沙量呈显著正相关。其中,沉积物是最重要的驱动因素,其次是产水量。从空间上看,污染物负荷主要集中在流域下游耕地较多的地方。为此,建议控制耕地中化肥、农药和畜禽粪便的投入,防止流域下游的水土流失,以减轻氮、磷和重金属污染。本研究为制定和实施丹江口水库流域管理提供了依据。
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引用次数: 0
Geochemical characteristics, mechanisms, and suitability of groundwater resource for sustainable water supply in Quetta valley 奎达河谷地下水资源的地球化学特征、机制和可持续供水的适宜性
Pub Date : 2024-05-14 DOI: 10.2166/ws.2024.108
Muhammad Haziq Khan, Yong Xiao, Hongjie Yang, Yuqing Zhang, Liwei Wang, Jie Wang, Wenxu Hu, Feiyu Chen, Rohit Shrestha
Groundwater is a crucial water resource for various usages worldwide. The Quetta Valley of Pakistan was investigated regarding its groundwater quality sustainability based on integrated approaches of hydrochemistry, geographic information system, and multivariate statistics. A total of 29 groundwater samples were collected from monitoring wells to get insights into the hydrochemical suitability of groundwater for sustainable irrigation and drinking utilization. The results indicate groundwater is mainly featured by the hydrochemical facies of HCO3·Cl-Ca. Groundwater hydrochemical composition is dominantly governed by the dissolution of carbonates and silicate minerals in combination with positive cation exchange in the valley. Principal component analysis reveals a significant influence of geogenic factors on groundwater chemistry, further supported by PHREEQC simulation that detects a supersaturation of calcite, dolomite, and sulphate minerals in the aquifer. The irrigation water quality index divides groundwater in the study area into three zones, which signify low restriction and no restriction, except for a severe restriction in the southwestern part of the valley. Groundwater is generally suitable for irrigation across the valley. The entropy-weighted water quality index classifies groundwater as excellent and good quality for drinking. This study can provide crucial insights for authorities on groundwater suitability in Quetta Valley and similar regions worldwide.
地下水是全球各种用途的重要水资源。基于水化学、地理信息系统和多元统计的综合方法,对巴基斯坦奎达山谷的地下水质量可持续性进行了调查。共从监测井中采集了 29 个地下水样本,以深入了解地下水的水化学特性是否适合可持续灌溉和饮用。结果表明,地下水主要以 HCO3-Cl-Ca 的水化学面貌为特征。地下水的水化学组成主要受山谷中碳酸盐和硅酸盐矿物溶解以及阳离子正交换的影响。主成分分析表明,地质因素对地下水化学成分有重大影响,PHREEQC 模拟进一步证实了这一点,该模拟检测到含水层中方解石、白云石和硫酸盐矿物过饱和。灌溉水水质指数将研究区域的地下水划分为三个区域,分别代表低限制和无限制,只有河谷西南部的地下水受到严重限制。整个河谷的地下水总体上适合灌溉。熵加权水质指数将地下水划分为优级和良级饮用水质。这项研究可为奎达河谷和全球类似地区的地下水适宜性当局提供重要的见解。
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引用次数: 0
Characterisation of extreme precipitation changes in the upper reaches of the Yangtze River, China 中国长江上游极端降水变化的特征
Pub Date : 2024-05-09 DOI: 10.2166/ws.2024.106
Ting Chen, Ye Yao, Hui Chen
The paper analyses the spatial and temporal characteristics of extreme precipitation in the upper reaches of the Yangtze River through extreme precipitation indicators based on the trend method, the Mann–Kendall trend test, and the rescaled extreme deviation extreme deviation using daily precipitation data from 1961 to 2021. The following conclusions were obtained: The overall precipitation in the upper reaches of the Yangtze River is reduced, and the number of rainy days is reduced. The frequency of extreme precipitation is generally reduced, but the spatial difference in the intensity of extreme precipitation is greater, which makes the occurrence of extreme precipitation more concentrated and more destructive. Extreme precipitation indicators showed relatively large fluctuations after 2000, especially in terms of extreme precipitation intensity. The frequency of extreme precipitation in the upper reaches of the Yangtze River is the highest in the main stream of the Yangtze River Basin and the Wujiang River Basin, the intensity of extreme precipitation is in the Jialing River and the Wujiang River Basin, and the accumulation of extreme precipitation is the highest in the Jialing River and the Wujiang River Basin, whereas the maximum value of the station extreme precipitation intensity and frequency is in the Minjiang River Basin.
本文利用 1961-2021 年的日降水量数据,通过基于趋势法的极端降水指标、Mann-Kendall 趋势检验和重标定极端偏差极端偏差,分析了长江上游极端降水的时空特征。得出以下结论:长江上游降水总体偏少,雨日偏少。极端降水频次总体减少,但极端降水强度空间差异较大,使得极端降水发生更为集中,破坏性更大。2000 年以后,极端降水指标出现了较大幅度的波动,尤其是极端降水强度。长江上游极端降水频率最高的是长江流域干流和乌江流域,极端降水强度最高的是嘉陵江流域和乌江流域,极端降水累积量最高的是嘉陵江流域和乌江流域,而极端降水强度和频率站最大值均出现在岷江流域。
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引用次数: 0
Enhanced water production in hemispherical solar stills via solar collector and thermal storage integration: experimental validation 通过太阳能集热器和蓄热一体化提高半球形太阳能蒸馏器的产水量:实验验证
Pub Date : 2024-05-09 DOI: 10.2166/ws.2024.107
Kamel Ferhat Benabdelaziz, Abla Chaker, R. Kerfah
In arid regions that face water scarcity, solar distillation offers hope by meeting the increasing need for clean drinking water. This study investigates the integration of a hot water storage system, heated by a flat plate solar collector, into a hemispherical solar still. Placing the storage tank below the still's absorber enhances heat input and efficiently stores excess daytime thermal energy. Conducted in Bouismail from December 2022 to October 2023, the study yielded significant results: the modified solar still outperformed the conventional one, with production increases of 157% in winter and 207% in summer. Moreover, the modified still demonstrated remarkable efficiency improvement in summer, reaching 37.42% compared to 20.38% for the conventional still. The orientation of the fins within the storage tank, with respect to the hot water entrance orifice, significantly impacted water production, with alterations of the angle resulting in decreases of up to 25%. Increasing saltwater depth led to reduced distilled water output, with declines of up to 37.08% for the modified still. Economic analysis showed a slightly higher cost per liter of water produced by the modified still ($0.1897) compared to the simple one ($0.1446).
在缺水的干旱地区,太阳能蒸馏为满足日益增长的清洁饮用水需求带来了希望。本研究探讨了将平板太阳能集热器加热的热水储存系统与半球形太阳能蒸馏器的整合问题。将储水罐置于蒸馏器吸收器下方可提高热量输入,并有效储存白天多余的热能。这项研究于 2022 年 12 月至 2023 年 10 月在布伊斯梅尔进行,取得了显著成果:改良型太阳能蒸馏器的性能优于传统型蒸馏器,冬季产量增加了 157%,夏季增加了 207%。此外,改良型蒸馏器在夏季的效率显著提高,达到 37.42%,而传统蒸馏器仅为 20.38%。相对于热水入口孔而言,储水箱中鳍片的方向对产水量有很大影响,角度的改变导致产水量下降达 25%。盐水深度的增加导致蒸馏水产量的减少,改良蒸馏器的产量减少达 37.08%。经济分析表明,改良蒸馏器每升水的成本(0.1897 美元)略高于简单蒸馏器(0.1446 美元)。
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引用次数: 0
Optimization of water supply reservoir scheduling with insufficient regulating capacity 调节能力不足情况下的供水水库调度优化
Pub Date : 2024-05-08 DOI: 10.2166/ws.2024.102
Yujun Wang, Zeyu Li, Yixuan Lu, Xiping Zhao
To make use of a limited regulating reservoir capacity to provide a small amount of water supply benefits, a multiobjective optimal model that considers the water demand and regulating capacity of the pumping station was established, by combining the maximum sequence similarity (F1), maximum pumping station suitability (F2), maximum ecological flow satisfaction (F3) and maximum number of continuous water supply periods (F4), which were solved by NSGA-II algorithm, K-means clustering, and EW-TOPSIS method were used to select the optimal scheme. The results showed that the results of the combination of F1 and F2 were better than that of the list method, with a multiannual average water supply of 3.88 × 107 m3; the occupation of ecological flow significantly increased the water supply efficiency, with a multiannual average water supply of 4.49 × 107 m3, with a multiannual average ecological satisfaction degree of 10.84; the interruption periods were gathered between January and May by accepting the interruption periods regularly occurred, the water supply was 1.10 × 107 m3 with 95% guarantee rate by taking June–December as the water supply period. Our data indicated that reservoirs with insufficient regulation capacity can produce certain water supply benefits, and there were competitive relationships between objectives, and competitiveness increases with the increase of pumping station regulation capacity.
为利用有限的调节库容提供少量的供水效益,建立了考虑泵站需水量和调节库容的多目标优化模型,将最大序列相似度(F1)、最大泵站适宜度(F2)、最大生态流量满足度(F3)和最大连续供水期数(F4)结合起来,采用NSGA-II算法求解,K-均值聚类,EW-TOPSIS法选择最优方案。结果表明,F1 和 F2 的组合结果优于列表法,多年平均供水量为 3.88×107 m3;生态流量的占用显著提高了供水效率,多年平均供水量为 4.49×107 m3,多年平均生态满意度为 10.84;通过接受定期发生的中断期,将中断期集中在 1-5 月,以 6-12 月为供水期,供水量为 1.10×107 m3,保证率为 95%。数据表明,调节能力不足的水库也能产生一定的供水效益,且各目标之间存在竞争关系,竞争性随泵站调节能力的增加而增强。
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引用次数: 0
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Water Supply
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