Bulletin of the Tomsk Polytechnic University Geo Assets Engineering最新文献

{"title":"System for monitoring building heat consumption","authors":"Mikhail V. Kolosov, A. Lipovka, Yuri L. Lipovka","doi":"10.18799/24131830/2024/7/4443","DOIUrl":"https://doi.org/10.18799/24131830/2024/7/4443","url":null,"abstract":"Relevance. Energy consumption and efficient use of district heating networks affect the environment, society and the economy. Solutions are needed that can significantly reduce specific thermal energy losses. Using a technically and economically feasible way to assess energy efficiency allows these decisions to be made. Currently, assessing the energy efficiency of buildings raises significant questions among specialists. There is not much modern specialized literature in this area. The problem of energy efficiency requires more rigorous attention to urban planning issues. Thus, refined methods for assessing the energy efficiency of buildings make it possible to simultaneously save capital investments and ensure efficient consumption of thermal energy. Aim. To develop a system for assessing the real heat consumption of buildings to ensure optimization of dispatching of centralized heat supply systems in real time. Methods. Computer modeling of the state of heat consumption of buildings with various characteristics and schemes for their connection to centralized heat supply networks; methods of geographic information analysis. Results. The authors have proposed the system for monitoring the heat consumption of buildings. This system allows assessing the energy efficiency of buildings through the maximum use of computer and software technologies. It is shown that the calculated heat flows of buildings used to predict savings when modernizing buildings do not always correspond to the actual heat loads, which can lead to an incorrect assessment of investment projects. The authors obtained graphical dependences of the quantities influencing specific heat losses on various primary independent factors. Conclusions. The constructed system for monitoring the heat consumption of buildings allows, together with the use of geoinformation analysis methods, obtaining a fairly complete picture of the state of heat consumption for city areas and an assessment of the energy characteristics of buildings.","PeriodicalId":513946,"journal":{"name":"Bulletin of the Tomsk Polytechnic University Geo Assets Engineering","volume":"17 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141813579","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Technogenic gold deposits of the Trans-Baikal Territory","authors":"Bair N. Abramov","doi":"10.18799/24131830/2024/7/4211","DOIUrl":"https://doi.org/10.18799/24131830/2024/7/4211","url":null,"abstract":"Relevance. The need to expand the mineral resource base of the Trans-Baikal Territory. Aim. To study the geochemical composition of technozems of tailings dumps of gold deposits of the Trans-Baikal Territory, their correspondence, in terms of gold content, to technogenic deposits, to calculate the exceeding the maximum permissible concentrations of toxic elements in technozems of tailings dumps. Objects. Technozems of tailings dumps of gold deposits of the Trans-Baikal Territory. Methods. Silicate, X-ray fluorescence ISP-AES methods in analytical laboratories of the Geological Institute of the SB RAS (Ulan-Ude) and JSC \"SGS Vostok Limited\" (Chita). Results. It was found that in terms of gold content (Au>0.4 g/t), the technozems of the tailings of the gold deposits of the Trans-Baikal Territory, in general, correspond to technogenic gold deposits. The largest volumes and contents of gold (1.2 g/t) are characterized by technozems of the Baleysky tailings dam deposits with insignificant gold contents are technozems of Darasunsky (0.36 g/t) and Kariysky (0.35 g/t) deposits. It is determined that the chemical composition of the technozems of the tailings depends on the composition of the host rocks developed in the areas of deposits. They correspond to the rocks of both basic and medium compositions. The distinctive features of the content of impurity elements in the technozems of tailings are due to the different compositions of the initial ores of gold deposits. These differences are reflected in the values of exceeding the maximum permissible concentrations relative to soils. Among the toxic elements, arsenic is characterized by maximum exceedances of the maximum permissible concentrations. In the technozems of the Lyubavinsky deposit, the excess of the maximum permissible concentrations of arsenic relative to the soil is 933 times, and the Baley deposit is 397 times.","PeriodicalId":513946,"journal":{"name":"Bulletin of the Tomsk Polytechnic University Geo Assets Engineering","volume":"95 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141812542","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Lithium capacity of Kazakhstan mineral resource base","authors":"Malis Absametov, Grigory Yu. Boyarko, Ekaterina M. Dutova, Liudmila M. Bolsunovskaya, N. M. Itemen, Daniyar B. Chenzybaev","doi":"10.18799/24131830/2024/7/4674","DOIUrl":"https://doi.org/10.18799/24131830/2024/7/4674","url":null,"abstract":"Relevance. Weak knowledge of the territory of the Republic of Kazakhstan on lithium raw materials previously mined in the East Kazakhstan region. Aim. To study lithium raw material base in the Republic of Kazakhstan and prospects for the extraction of lithium raw materials. Methods. Content analysis of all information on the subject of the mineral resource base of lithium in the Republic of Kazakhstan. Results. Within the Republic of Kazakhstan, ore deposits of scapolite pegmatites and lithium-bearing greisens-hydrothermal growths are known along alkaline granites. Residual lithium reserves from previously developed rare metal deposits that are equivalent to 36.3 thousand tons of Li2O, predicted resources of known lithium occurrences are estimated at 140 thousand tons of Li2O. It is possible to develop known rare metal deposits with the extraction of tantalum, niobium, beryllium and associated extraction of spodumene concentrate. GRK «Ognevsky Mining and Processing Plant» is already planning to put back to mining of tantalum and beryl (with the associated extraction of spodumene concentrate – up to 2.5 thousand tons/year) at the Bakennoe deposit and processing the resulting ore concentrates at the operating Ulba metallurgical plant of Kazatomprom. With regard to lithium-bearing hydro-mineral resources of the Republic of Kazakhstan, the situation is more complicated, due to the data limitations on the completeness of formation water testing and the reliability of data on surface waters of stagnant lakes. Such oil and gas fields as Karachaganak (up to 196 mg/l Li2O), Kolkuduk (up to 130 mg/l Li2O), Teplovskoe (up to 82.5 mg/l), Urikhtau (up to 52 mg/l) and Western Opak (up to 45 mg/l) are known for high concentration of lithium in formation waters. First two deposits are ready for oil and gas development and production with an annual extraction of up to 1 thousand tons of lithium carbonate. With regard to the lithium content of stagnant lakes of the Republic of Kazakhstan, it should be noted almost total lack of reliable information on sampling their surface waters. Given the fact of finding industrially significant lithium-bearing hydro-mineral lake deposits in adjacent regions of China and Mongolia, it is necessary to intensify the thematic works to assess the lithium content of endorheic lakes throughout the Republic of Kazakhstan, with sampling not only of surface waters, but also of natural brine, lake mud, saline clayey rocks of solonchaks and takyrs.","PeriodicalId":513946,"journal":{"name":"Bulletin of the Tomsk Polytechnic University Geo Assets Engineering","volume":"32 26","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141813997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Impact of woody biomass in the composition of coal-water suspensions on their transportation and combustion","authors":"D. Malyshev, Zhanna A. Kostoreva, M. S. Tamashevich","doi":"10.18799/24131830/2024/7/4646","DOIUrl":"https://doi.org/10.18799/24131830/2024/7/4646","url":null,"abstract":"Relevance. A promising fuel from an environmental point of view is coal-water suspensions. Multiple studies have shown that when they are burned, emissions of anthropogenic gases into the Earth's atmosphere are significantly reduced compared to emissions from coal burning. But the large-scale introduction of coal-water suspensions into the overall balance of energy production is difficult due to a significant delay in their ignition, which can reach several tens of seconds at relatively low oxidizer temperatures (Tg≤1073 K). One of the possible ways to solve this problem is the use of new technologies for preparation for combustion, for example, the use of additional microwave heating of fuel and the introduction of special additives into the composition of coal-water suspensions, which accelerate their ignition. The introduction of such additives into the fuel composition can lead to a significant change in the rheological characteristics. Aim. To determine the degree of impact of the concentration and type of wood additive in the composition of the coal-water suspension on the rheological characteristics of droplets of coal-water fuel, as well as the possibility of reducing the duration of thermal preparation of the latter when exposed to microwave heating. Object. Water-coal suspension based on long-flame thermal coal and on long-flame thermal coal with the addition of sawdust and pine needles (Bio-water-coal suspension). Methods. Experimental studies to determine the time characteristics of water-coal suspension ignition were carried out using a high-speed video camera FASTCAM. Fuel combustion was carried out in a flow-through combustion chamber equipped with magnetrons for additional microwave heating of the fuel. Dynamic viscosity was determined using a Brookfield RVDV-II + Pro viscometer. Results. It has been established that the addition of microwave heating can significantly (up to 15%) reduce the ignition delay of water-coal suspension and Bio-water-coal suspension at relatively low oxidizer temperatures (673 K). Experimental studies shown that the type of biomass affects the time characteristics of fuel ignition at ambient temperatures up to 753 K; with a further increase in the temperature of the oxidizer, the type of additive does not have a significant effect. It is shown that when studying the rheological characteristics of the water-coal suspension, the dynamic viscosity of Bio-water-coal suspension does not go beyond the characteristic value of 1200 Pa s at a shear rate of 100 rpm when no more than 2% of pine sawdust and no more than 6% of pine needles are introduced into the water-coal suspension.","PeriodicalId":513946,"journal":{"name":"Bulletin of the Tomsk Polytechnic University Geo Assets Engineering","volume":"13 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141810693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Accounting for a capillary pressure jump in a saturated porous medium for a more correct calculation of hydrocarbon reserves","authors":"Maksim I. Raikovsky, Alexander Yu. Demyanov, O. Dinariev, D. V. Rudenko","doi":"10.18799/24131830/2024/7/4371","DOIUrl":"https://doi.org/10.18799/24131830/2024/7/4371","url":null,"abstract":"Relevance. The correct calculation of hydrocarbon reserves in various fields (oil, gas, gas condensate) is an important state task, because it allows you to properly organize field development in the future and ensure the rational use of natural resources of the state. In particular, the values of geological and recoverable reserves are assigned to a specific subsurface user and are recorded in departmental documents. Aim. To describe the effect associated with the calculations of the thermodynamic equilibrium of the mixture of hydrocarbons of the Karachaganak oil and gas condensate field at various formation depths with the capillary pressure jump taken into account. This makes it possible to clarify the value of the potential condensate-gas factor of reservoir gas and, as a result, to give a more accurate assessment of the geological reserves of hydrocarbon raw materials. Object. Analysis of the thermodynamic equilibrium of the hydrocarbon mixture of Karachaganak oil and gas condensate field, taking into account the capillary pressure jump, which takes place in a porous medium under reservoir conditions. Methods. Numerical modeling, analytical research. Results. Based on the previously developed methodology for calculating the phase equilibrium with the capillary pressure jump the correction of the potential condensate-gas factor of the formation gas of the Karachaganak oil and gas condensate field was carried out at various formation depths. The range of values of the condensate-gas factor difference for calculations both with and without capillary pressure jump was from 7,04 g/m3, with a condensate-gas factor value equal to 393 g/m3 for formation depth of 4000 m, to 64,47 g/m3, with a condensate-gas factor value equal to 547 g/m3 for formation depth of 4600 m. Based on the updated condensate-gas factor estimate, it is possible to clarify the condensate recovery coefficient during the development of a field without maintaining reservoir pressure or with partial maintaining reservoir pressure.","PeriodicalId":513946,"journal":{"name":"Bulletin of the Tomsk Polytechnic University Geo Assets Engineering","volume":"133 47","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141810943","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mathematical models and algorithms for designing main pipeline for transporting georesources","authors":"G. Toktoshov, D. Migov","doi":"10.18799/24131830/2024/7/4339","DOIUrl":"https://doi.org/10.18799/24131830/2024/7/4339","url":null,"abstract":"Relevance.  The practical importance of the tasks of utility networks design, namely, the problems of optimizing the structure of the main pipeline according to given criteria, such as efficiency, reliability etc., under conditions of limitations, for example, the compatibility of various types of utilities. Since the main pipeline is laid on the ground with various physical and geological factors, natural and situational conditions, it is advisable to take the reliability of its operation as a global criterion. The task of network optimization is proposed in the form of displaying the main pipeline along the selected routes in three-dimensional space, which considers various existing communications and objects, as well as elevation marks of the area. The paper presents the problems of optimizing networks, both in the continuous case and in the discrete case, and also studies various indicators of the reliability of the operation of the main pipeline. Aim. To develop a model for laying the main pipeline in three-dimensional space, considering the reliability of the pipeline transport; to conduct a comparative analysis for various reliability indicators and topologies of the main pipeline. Objects. Utility communications and networks laid in three-dimensional space. Methods. Calculus of variations, discrete optimization methods, graph theory and hypernet theory methods, network reliability analysis methods. Results. The task of optimizing the main pipeline transport is given taking into account its nesting along the route in three-dimensional space with the choice of an optimization criterion (economic efficiency, reliability, etc.). The problem is presented in the form of continuous and discrete formulations, which is important for its development both within the theory of the calculus of variations and discrete optimization. In this work, the problem was studied within the framework of the theory of graphs and hypernets, which allow, firstly, taking into account the nesting of one structure (main pipeline) into another (a discrete analogue of three-dimensional space) and, secondly, clearly illustrating the results of numerical experiments. It is shown that under the conditions of a given variants for laying a secondary network along the primary channels, various optimal structures are obtained when considering various reliability indicators as a criterion, which can be used to implement a design solution for the construction and operation of pipeline transport for various purposes.","PeriodicalId":513946,"journal":{"name":"Bulletin of the Tomsk Polytechnic University Geo Assets Engineering","volume":"128 18","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141811582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Anti-turbulent efficiency of oil-soluble polymer solutions and colloid systems flowing through cylindrical channel","authors":"V. Manzhay","doi":"10.18799/24131830/2024/7/4378","DOIUrl":"https://doi.org/10.18799/24131830/2024/7/4378","url":null,"abstract":"Relevance. The use of anti-turbulent additives for transporting hydrocarbon liquids through main pipelines allows  reducing significantly the energy consumption of pumping power stations. Aim. Comparative analysis of the anti-turbulent efficiency of high-molecular polymers and compositions of surfactants. Methods. Laboratory-scale experimentation aimed to study the flow of dilute polymer solutions and dispersed surfactant systems through a cylindrical channel of a turbulent rheometer. Results. The author has carried out the comparative experimental studies of the anti-turbulent efficiency of extremely dilute solutions of polymers and colloidal systems. The results were obtained that suggest a higher anti-turbulent efficiency of high-molecular-weight polymers compared to micellar surfactant systems. Solutions of high molecular weight polybutadiene and aluminum polyhydroxydicarboxylates in gasoline were used as samples for the experimental comparison of hydrodynamic efficiency. The paper describes the laboratory setup, on which the studies were carried out, and introduces the formulas used for quantitative calculations. The structure of polymer solutions and colloidal systems is considered and a theoretical explanation is given for the preferential use in industrial practice of high-molecular polymers in extremely low concentrations in real pipelines. It was found out that the mechanisms of degradation of antiturbulent properties of polymer solutions and dispersed surfactant systems are different. This is due to the difference in the structure of macromolar coils of polymer with an immobilized solvent and that of micelles from low molecular amphiphilic compounds. The paper introduces the arguments that explain the degradation of the antiturbulent properties of polymers not by the destruction of carbon-chain macromolecules, but by decomposition in a turbulent flow of the original large associates, consisting of a large number of chains, into individual and smaller macromolecular coils with an immobilized solvent.","PeriodicalId":513946,"journal":{"name":"Bulletin of the Tomsk Polytechnic University Geo Assets Engineering","volume":"15 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141813694","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Formation of nanosized copper silicides in a high-speed electric discharge plasma jet","authors":"Dmitry S. Nikitin, Artur R. Nassyrbayev, I. Shanenkov, Y. Vympina, A. A. Sivkov, Evgenia G. Orlova","doi":"10.18799/24131830/2024/7/4487","DOIUrl":"https://doi.org/10.18799/24131830/2024/7/4487","url":null,"abstract":"Relevance. The search for suitable materials for creating a new generation of anodes in lithium-ion batteries that have not only high capacity, but also high electrical conductivity. For this purpose, the attempts have been made to use silicon Si, which has a high specific capacitance, instead of graphite C, but this material does not have high electrical conductivity. Copper silicides, in addition to high specific capacity, have high electrical conductivity values, since they do not react with lithium during operation, and therefore can be used to solve problems in the development of the above-mentioned lithium-ion anodes. Aim. To obtain dispersed materials in a high-speed jet of electric discharge plasma in the Cu-Si-C system. Objects. Dispersed materials obtained in the Cu-Si-C system. Methods. Plasma dynamic synthesis, X-ray diffractometry (X-ray phase analysis), scanning electron microscopy, transmission electron microscopy. Results. The authors have carried out the experimental studies to obtain dispersed materials of the Cu-Si-C system in a high-speed electric-discharge plasma jet and studied the microstructure and composition of the synthesized materials. It was revealed that the product consists of nanodispersed particles, which is confirmed by the results of scanning and electron microscopy. According to the results of X-ray diffractometry, crystalline phases of copper of the cubic system and copper silicides Cu3Si and Cu7Si of the hexagonal system are identified in the composition of the synthesized material.","PeriodicalId":513946,"journal":{"name":"Bulletin of the Tomsk Polytechnic University Geo Assets Engineering","volume":"19 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141810794","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Characteristics of granulated activated carbon from a mixture of plant raw material waste","authors":"R. G. Safin, Viktor G. Sotnikov","doi":"10.18799/24131830/2024/7/4386","DOIUrl":"https://doi.org/10.18799/24131830/2024/7/4386","url":null,"abstract":"Relevance. The need to increase the use of renewable energy sources in the economy to reduce the harmful effects on the environment. Aim. To assess the possibility of obtaining by the thermochemical method high-quality carbon adsorbents from a granular mixture of various wastes of plant origin. Objects. Samples of illiquid lumpy birch wood, walnut shells, sunflower seed husks, flax fires, anthracite coal. Methods. Physical experiments: conductive pyrolysis, water-steam activation and differential thermal analysis. The ash content and moisture content of the samples were determined according to SS R 56881-2016 and SS 33503-2015. Nitrogen adsorption isotherms were measured using a NOVA-1200e analyzer. The equilibrium activity for toluene was determined according to SS 8703-74, the adsorption activity for iodine was determined according to SS 6217-74. The determination of the density of the granules was carried out according to SS 15139-69. Results. The authors have established rational parameters for obtaining carbon adsorbents from granules of vegetable raw materials. The specific yield of pyrolysis products of a mixture of vegetable raw materials with pyrolysis resin was determined. The specific yield of carbonization products of the granular compacted mass showed an increase of 25% in comparison with the non-compacted mixture of vegetable raw materials. Rational parameters for obtaining activated carbon with the highest adsorption capacity are granules with a density of 1200 kg/m3 with a degree of burnout of the carbonization product of 70%. It was established that the obtained samples of adsorbents from granules of plant raw materials have high adsorption characteristics comparable to activated carbons obtained from fossil raw materials.","PeriodicalId":513946,"journal":{"name":"Bulletin of the Tomsk Polytechnic University Geo Assets Engineering","volume":"87 12","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141812620","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Features of determining organometallic compounds in organic matters of black shale using diffuse reflectance infrared Fourier transform spectroscopy","authors":"Vladimir P. Ivanov, Timofey V. Timkin, D. A. Boldina, Marina G. Pakhtaeva","doi":"10.18799/24131830/2024/2/4462","DOIUrl":"https://doi.org/10.18799/24131830/2024/2/4462","url":null,"abstract":"Relevance. The problem of studying organometallic compounds in carbonized and carbonaceous substances is part of the global problem of the structure of natural materials from plant remains and manifestation of ore genesis in organic sedimentary deposits. This problem covers a number of issues. The most pressing one among them is the form of occurrence of finely dispersed gold in the form of organometallic compounds in metal-bearing coals and shales. This is especially true for large gold deposits of black shale strata. Aim. To study the relationship between sedimentation of organic formations and ore genesis in black shale deposits using the example of the Verninskoe deposit (Patom Highlands, Yakutia). Using the SKAUFV hardware and software complex together with ICP-MS and INAA methods, which allow one to assess the degree of Au concentration in organic matter, to substantiate the possibility of determining organometallic compounds of gold that are significant in the processes of sedimentogenesis, lithogenesis and epigenesis. Methods. IR spectroscopy, instrumental neutron activation analysis (INAA) and inductively coupled plasma mass spectrometry (ICP-MS). Results. The authors have determined that the SKAUFV hardware and software complex, together with the ICP-MS and INAA methods, makes it possible to establish the role of organic matter in metasomatism and to identify temperature zonality and the associated gold concentration in the ore zone. To determine the organometallic compounds of Au, structural and genetic indicators  (Pm, Ko, PVt+L, PI) were selected. These indicators reflect the significance of sedimentation, diagenesis, catagenesis and epigenesis on Au concentration of in organic matter. These indicators made it possible to assess the level of temperature impact on sedimentary deposits of regional metamorphism and near-ore metasomatism. In this regard, subzones of Au concentration were established in the ore zone, determined by temperature zoning in the form of a manifestation of local metasomatism. The latter was influenced by the protein-fat composition of plants that form organic matter.","PeriodicalId":513946,"journal":{"name":"Bulletin of the Tomsk Polytechnic University Geo Assets Engineering","volume":"4 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140419383","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}