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Effect of preparation method of pyrolysis liquid mixed with coal on its ignition and combustion characteristics 热解液与煤混合的制备方法对其着火和燃烧特性的影响
Pub Date : 2024-02-28 DOI: 10.18799/24131830/2024/2/4458
K. Slyusarsky, A. Asilbekov
Relevance. The need to develop technological solutions to increase the competitiveness of pyrolysis processing of various wastes. Combustion of pyrolysis liquid in a mixture with coal is one of these solutions, which makes it possible to stabilize the properties of the obtained fuel and use in standard energy equipment. Aim. To determine the influence of the method of preparing a mixture of pyrolysis liquid and low-grade coal on its ignition and combustion characteristics, as well as on composition of the released gas-phase products, depending on the temperature of heating medium and concentration of the additive. Methods. Pyrolysis and oxidation characteristics were studied using thermogravimetric analysis, and formal kinetic constants were calculated using the Coates–Radfern method. Samples of mixed fuels were prepared by the methods of homogeneous mixing and surface wetting of pyrolysis liquid of rubber processing and low-grade coal. Ignition and combustion characteristics were determined using an experimental stand, and composition of gas-phase combustion products was determined using once-through gas analyzer. Results. The authors have determined the features of pyrolysis and oxidation of the pyrolysis liquid as well as the values of formal kinetics constants, indicating the physical nature of the factors that defining the rate of these processes. It was found that at 600 °C the ignition of the studied mixtures weakly depended on concentration of the additive, while at 700 and 800 °C the dependence was linear, and the differences between the samples prepared using different methods were insignificant. For samples obtained by the method of surface wetting, combustion of the additive occurred in the gas phase near the surface of the sample. For the samples obtained by the method of uniform mixing, it occurred predominantly in the bulk of the backfill. This led to more intense and complete coal combustion in these compositions due to more uniform releasing of heat and initiation of coal particles. The concentration curves of the NO, CO and CO2 release demonstrated, that behavior of the fuel mixture components was additive in terms of released gas-phase combustion products, as well as the absence of significant nonlinear effects over the entire studied range of temperatures and additive concentrations.
相关性。需要开发技术解决方案,以提高各种废物热解处理的竞争力。将热解液与煤混合燃烧就是其中一种解决方案,这样可以稳定所获燃料的性质,并将其用于标准能源设备。目的根据加热介质的温度和添加剂的浓度,确定热解液和劣质煤混合物的制备方法对其点火和燃烧特性的影响,以及对释放的气相产物成分的影响。方法使用热重分析法研究了热解和氧化特性,并使用 Coates-Radfern 法计算了形式动力学常数。混合燃料样品是通过橡胶加工热解液和劣质煤的均匀混合和表面润湿方法制备的。使用实验台测定了点火和燃烧特性,并使用一次性气体分析仪测定了气相燃烧产物的成分。结果。作者确定了热解液的热解和氧化特征以及形式动力学常数的值,表明了决定这些过程速率的因素的物理本质。研究发现,在 600 °C 时,所研究混合物的点火与添加剂的浓度关系不大,而在 700 和 800 °C 时则呈线性关系,而且用不同方法制备的样品之间的差异也不大。对于采用表面润湿法制备的样品,添加剂的燃烧发生在样品表面附近的气相中。而采用均匀混合法制备的煤样,燃烧主要发生在回填土的主体中。由于热量释放更均匀,煤炭颗粒也更均匀,因此这些成分中的煤炭燃烧更强烈、更完全。氮氧化物、一氧化碳和二氧化碳的释放浓度曲线表明,就释放的气相燃烧产物而言,燃料混合物成分的行为是相加的,而且在整个研究的温度和添加剂浓度范围内没有明显的非线性效应。
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引用次数: 0
Evaluation of the effect of acid additives on rheological properties and technological efficiency of zwitterionic and anionic surfactant mixtures 评估酸添加剂对齐聚硅氧烷和阴离子表面活性剂混合物流变特性和技术效率的影响
Pub Date : 2024-02-28 DOI: 10.18799/24131830/2024/2/4221
Ali Mohammed Abdullah Mohsen, Viktor V. Konovalov, Prokofy V. Sklyuev
Relevance. Various acid additives such corrosion inhibitors, iron stabilizers, demulsifiers, anti-precipitation agents are usually used to provide necessary technological properties to acid compositions. Adding the additives into the acid composition based on viscoelastic surfactants can have a significant impact on the efficiency of their subsequent use, since micelle formation and, consequently, rheology of their solutions are particularly sensitive to the presence of additional components in the system. Accordingly, determination of the acid additives influence on rheological properties and technological efficiency of acid compositions with surfactants is a vital task. Aim. To evaluate the effect of acid additives on rheological behavior of viscoelastic surfactants-based acid compositions (mixture of cocamidopropyl betaine and ethoxylated fatty alcohol sulfosuccinate). Object. Acidic composition based on viscoelastic surfactants (a mixture of anionic and zwitterionic surfactants) and a package of acidic additives – corrosion inhibitor, iron stabilizer, demulsifier and antisludge agent. Methods. Investigation of rheological properties using an MCR52 rheometer (Anton Paar GmBH) in the shear rate range from 1 to 100 s–1 at temperatures from 20 to 90°C, standard tests for selecting acid additives.  Results. The authors have determined the effect of acid additives on rheological properties of the developed self-diverting acid solution based on the viscoelastic surfactant (a mixture of anionic and zwitterionic surfactants). The obtained results confirmed that adding the acid additives into solutions leads to a decrease in partially neutralized solution viscosity. However, it expands the range of manifestation of viscoelastic properties. This will increase the efficiency of the developed composition during acid treatment. Also, the addition of acid additives reduces the initial viscosity, which facilitates acid injection into formation. A viscoelastic gel is not formed with hydrocarbons, which indicates that the treatment is effective in cleaning up the area after acidizing. The temperature test showed that the additives do not affect the temperature range of acid solution application.
相关性。各种酸添加剂(如缓蚀剂、铁稳定剂、破乳剂、抗沉淀剂)通常用于为酸组合物提供必要的技术特性。在以粘弹性表面活性剂为基础的酸组合物中加入添加剂会对其后续使用的效率产生重大影响,因为胶束的形成及其溶液的流变性对系统中存在的其他成分特别敏感。因此,确定酸添加剂对含有表面活性剂的酸组合物的流变特性和技术效率的影响是一项至关重要的任务。目的评估酸添加剂对以粘弹性表面活性剂为基础的酸组合物(椰油酰胺丙基甜菜碱和乙氧基化脂肪醇磺基琥珀酸酯混合物)流变行为的影响。对象: 基于粘弹性表面活性剂的酸性组合物。基于粘弹性表面活性剂(阴离子和齐聚物表面活性剂的混合物)和一揽子酸性添加剂--缓蚀剂、铁稳定剂、破乳剂和抗污泥剂--的酸性组合物。方法。使用 MCR52 流变仪(Anton Paar GmBH)在 1 至 100 s-1 的剪切速率范围内、20 至 90°C 的温度条件下对流变特性进行调查,这是选择酸性添加剂的标准测试。 结果。作者确定了酸添加剂对基于粘弹性表面活性剂(阴离子和齐聚物表面活性剂的混合物)开发的自分散酸溶液流变特性的影响。研究结果证实,在溶液中加入酸添加剂会导致部分中和溶液粘度下降。不过,它扩大了粘弹性的表现范围。这将提高所开发的组合物在酸处理过程中的效率。此外,添加酸添加剂可降低初始粘度,从而有利于将酸注入地层。碳氢化合物不会形成粘弹性凝胶,这表明酸化后的处理能有效清理该区域。温度测试表明,添加剂不会影响酸溶液的使用温度范围。
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引用次数: 0
Changes in conditions of interaction of ground, river and swamp water during swamping of the West Siberian plain in the Holocene 全新世西西伯利亚平原沼泽化期间地下水、河水和沼泽水相互作用条件的变化
Pub Date : 2024-02-28 DOI: 10.18799/24131830/2024/2/4535
Oleg G. Savichev
Relevance. The need to understand and long-term forecast the conditions of interaction between groundwater, river and swamp waters in the Ob River basin. Aim. To identify patterns of changes in the conditions of interaction of groundwater, river and swamp waters during swamping of the flat part of the Ob River basin in the Holocene. Methods. Mathematical modeling methods, statistical methods, geographical-hydrological method. Results and conclusions. The author has carried out an analysis of materials from long-term hydrogeological and hydrological observations in the wetlands of the Ob basin and studied the hydrodynamic and geochemical conditions for interaction of groundwater, river and swamp waters. It is shown that the emergence and evolution of swamp ecosystems in the territory under consideration is a complex of erosion-accumulation processes, the development of which until the modern period took place in three stages: 1) from the beginning of intense degradation of glaciation to 4...6 thousand years ago is the formation of a primary hydrographic network approximately modern appearance, distribution of peat bogs; the groundwater regime is close to the groundwater regime of the permafrost zone in the north of modern Western Siberia; 2) from 4...6 thousand years ago to 1.5...3 thousand years ago is large-scale distribution of lowland swamps and degradation of part of the primary river network; groundwater levels in river watersheds are generally lower than at present, but the amplitude of their fluctuations is high; a significant part of the watersheds are flooded during high water and floods, and underflooded during low water periods; 3) from 1.5...3 thousand years ago is degradation of a significant part of the primary river network, wide distribution of raised swamps, formation of a secondary hydrographic network in the swamps; at watersheds, groundwater levels rise, but the amplitude of their fluctuations decreases, and water exchange with swamps is significantly reduced; in the valleys of medium and large rivers, water exchange between surface and groundwater is most intense, which causes the flow of significant amounts of organic substances and products of their transformation into river and groundwater from swamps. Scenarios of possible changes in the conditions of interaction between surface and groundwater were assessed.
相关性。需要了解并长期预测鄂毕河流域地下水、河水和沼泽水之间的相互作用状况。目的确定全新世鄂毕河流域平坦地区沼泽化过程中地下水、河水和沼泽水相互作用条件的变化规律。方法。数学模型方法、统计方法、地理水文方法。结果和结论。作者对鄂毕河流域湿地长期水文地质和水文观测资料进行了分析,并研究了地下水、河水和沼泽水相互作用的水动力和地球化学条件。研究结果表明,该地区沼泽生态系统的出现和演变是一个复杂的侵蚀-积累过程,其发展直至现代经历了三个阶段:1) 从冰川强烈退化开始到距今 4...6 千年前,形成了近似现代外观的初级水文网络,泥炭沼泽分布;地下水系统接近现代西西伯利亚北部永久冻土带的地下水系统;2) 从距今 4...6 千年前到距今 1.5...3 千年前,是泥炭沼泽大规模分布的时期。3 000 年前,低地沼泽大规模分布,部分一级河网退化;河流流域的地下水位普遍低于现在,但波动幅度较大;相当一部分流域在丰水期和洪水期被淹没,在枯水期被淹没;3) 1.5...3 000 年前,大部分一级河网退化,高起的沼泽广泛分布,在沼泽中形成二级水文网;在流域,地下水位上升,但波动幅度减小,与沼泽的水交换显著减少;在大中型河流的河谷,地表水和地下水之间的水交换最为频繁,导致大量有机物质及其转化产物从沼泽流入河流和地下水。对地表水和地下水之间相互作用条件可能发生变化的情况进行了评估。
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引用次数: 0
Influence of mechanical impurities composition on formation of organic deposits 机械杂质成分对有机沉积物形成的影响
Pub Date : 2024-02-28 DOI: 10.18799/24131830/2024/2/4568
P. Ilyushin, K. Vyatkin, A. Kozlov, D. V. Andreev
Relevance. The need to study the effect of solid particles in the oil stream on formation, composition and structure of deposits. Modern models of formation of asphalt-resin-paraffin deposits, based on correlation dependencies or empirical data, do not take into account the influence of the content of solid particles in oil to the proper extent. Recent studies show that various solid particles in oil can affect both the critical velocity and the structure of the formed deposits, but the effect of various particles on the intensity of formation of asphalt-resin-paraffin deposits remains unexplored. Aim. To study the effect of various sand fractions on the intensity of formation, composition and structure of asphalt-resin-paraffin deposits Methods. Modeling of formation of asphalt-resin-paraffin deposits at the laboratory installation “Cold Finger” when adding various sand fractions to oil; studying composition and structure of deposits after the conducted investigations using a microscope. Results. According to the research results, there is a significant increase in the intensity of formation of asphalt-resin-paraffin deposits when large fractions of sand are added to oil at a concentration of 5% or higher. It is worth noting that small fractions have almost no effect on the amount of deposits formed. Also, if various fractions are added to oil in equal proportions, there is almost no effect on the intensity of formation of asphalt-resin-paraffin deposits. When analyzing the deposits images from a microscope, it can be concluded that paraffin molecules, when interacting with sand particles of a dimension greater than 0.05 mm, form homols, and with an increase in the fraction, their structural strength grows. Conclusions. The study of modern models of formation of asphalt-resin-paraffin deposits and current articles made it possible to understand that the issue of studying the factors of formation of asphalt-resin-paraffin deposits, in particular the effect of the presence of solid particles in oil, remains open. The results of this article can be aimed at improving existing technologies in the field of modeling paraffin formation, as well as contribute to the further work of researchers in this direction.
相关性。需要研究油流中固体颗粒对沉积物的形成、组成和结构的影响。基于相关性或经验数据的沥青-树脂-石蜡沉积物形成的现代模型,并没有在适当程度上考虑油中固体颗粒含量的影响。最近的研究表明,油中的各种固体颗粒会影响临界速度和所形成沉积物的结构,但各种颗粒对沥青-树脂-石蜡沉积物形成强度的影响仍未得到探讨。研究目的研究各种砂分对沥青-树脂-石蜡沉积形成强度、组成和结构的影响 方法:建立沥青-树脂-石蜡沉积形成模型。在 "冷手指 "实验室设备上模拟在石油中添加各种砂馏分时沥青-树脂-石蜡沉积物的形成过程;使用显微镜研究调查后沉积物的成分和结构。结果。研究结果表明,当在油中加入浓度为 5%或更高的大颗粒沙子时,沥青-树脂-石蜡沉积物的形成强度会显著增加。值得注意的是,小馏分对沉积物的形成量几乎没有影响。此外,如果将各种馏分以相同比例添加到油中,也几乎不会影响沥青-树脂-石蜡沉积物的形成强度。通过显微镜对沉积物图像进行分析,可以得出结论:石蜡分子与尺寸大于 0.05 毫米的沙粒相互作用时,会形成均聚物,随着馏分的增加,其结构强度也会增加。结论通过对沥青-树脂-石蜡沉积物形成的现代模型和当前文章的研究,我们可以了解到,研究沥青-树脂-石蜡沉积物形成的因素,特别是石油中固体颗粒存在的影响,仍然是一个有待解决的问题。本文的研究成果旨在改进石蜡形成建模领域的现有技术,并为研究人员在该领域的进一步工作做出贡献。
{"title":"Influence of mechanical impurities composition on formation of organic deposits","authors":"P. Ilyushin, K. Vyatkin, A. Kozlov, D. V. Andreev","doi":"10.18799/24131830/2024/2/4568","DOIUrl":"https://doi.org/10.18799/24131830/2024/2/4568","url":null,"abstract":"Relevance. The need to study the effect of solid particles in the oil stream on formation, composition and structure of deposits. Modern models of formation of asphalt-resin-paraffin deposits, based on correlation dependencies or empirical data, do not take into account the influence of the content of solid particles in oil to the proper extent. Recent studies show that various solid particles in oil can affect both the critical velocity and the structure of the formed deposits, but the effect of various particles on the intensity of formation of asphalt-resin-paraffin deposits remains unexplored. Aim. To study the effect of various sand fractions on the intensity of formation, composition and structure of asphalt-resin-paraffin deposits Methods. Modeling of formation of asphalt-resin-paraffin deposits at the laboratory installation “Cold Finger” when adding various sand fractions to oil; studying composition and structure of deposits after the conducted investigations using a microscope. Results. According to the research results, there is a significant increase in the intensity of formation of asphalt-resin-paraffin deposits when large fractions of sand are added to oil at a concentration of 5% or higher. It is worth noting that small fractions have almost no effect on the amount of deposits formed. Also, if various fractions are added to oil in equal proportions, there is almost no effect on the intensity of formation of asphalt-resin-paraffin deposits. When analyzing the deposits images from a microscope, it can be concluded that paraffin molecules, when interacting with sand particles of a dimension greater than 0.05 mm, form homols, and with an increase in the fraction, their structural strength grows. Conclusions. The study of modern models of formation of asphalt-resin-paraffin deposits and current articles made it possible to understand that the issue of studying the factors of formation of asphalt-resin-paraffin deposits, in particular the effect of the presence of solid particles in oil, remains open. The results of this article can be aimed at improving existing technologies in the field of modeling paraffin formation, as well as contribute to the further work of researchers in this direction.","PeriodicalId":513946,"journal":{"name":"Bulletin of the Tomsk Polytechnic University Geo Assets Engineering","volume":"44 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140421611","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adjustment of a reservoir model by the material balance method in the petroleum experts MBAL program. Setting up the integrated model in GAP 用石油专家 MBAL 程序中的物料平衡法调整储层模型。在 GAP 中建立综合模型
Pub Date : 2024-02-28 DOI: 10.18799/24131830/2024/2/4434
Roman N. Korotkov, Diana M. Ovcharenko, Vladimir I. Erofeev
Relevance. Modern approach to development of oil and gas fields. Digitalization and automation of hydrocarbon production allow not only to reducing the response time to possible deviations from the operating level of production, but also quickly making decisions on its further normalization. The use of modern software to create a reservoir model using the material balance method allows you to calculate current and predicted reservoir pressures depending on the amount of selected and injected fluid. With high-quality adaptation, the integration of the reservoir model, wells and collection system, in its turn, allows you to correctly approach the choice of a field development system, as well as correctly assess the possible potential of the field. Forecast calculations performed on an integrated model can form the basis for budget planning, as well as the basis for carrying out geological and technical activities on wells, commissioning new wells, and modernizing equipment and infrastructure. Moreover, group optimization calculation allows us to maximize additional oil production, taking into account all geological and technical constraints. Aim. Formation and analysis of an approach to setting up a reservoir model by adapting parameters using the material balance method; formation of a solution for adapting the integrated model, reconciliation of the results with actual data; carrying out an optimization calculation and obtaining additional oil production. Methods. Adjustment and adaptation of reservoir models using the material balance method; adjustment and adaptation of the integrated model of a field/group of fields; calculation of the forecast for a period of 30/90 days; optimization calculations. Results. The obtained results make it possible to adapt the components of the integrated model with an accuracy of ±5 %, which makes it possible to simulate the operating mode of the field. As a result of the analysis, tuning criteria were identified, and the minimum required set of parameters for a qualitative adaptation of the reservoir model and the collection system was presented. The effectiveness and accuracy of the tool are also proven by comparing actual data on operating modes with synthetic ones. Based on the work done, it can be concluded that the use of the integrated model shows us a high convergence with real data, which allows us to optimally approach the field development mode. Moreover, an optimization calculation was carried out to obtain additional oil production using the proposed solution, and a forecast for oil production for a period of 90 days was calculated, which was later confirmed when compared with actual data.
相关性。油气田开发的现代方法。碳氢化合物生产的数字化和自动化不仅可以缩短对生产运行水平可能出现的偏差做出反应的时间,还可以快速做出进一步正常化的决定。使用现代软件,利用物料平衡法创建储层模型,可以根据选定和注入的流体量计算当前和预测的储层压力。通过高质量的调整,将储层模型、油井和集输系统集成在一起,就能正确选择油田开发系统,并正确评估油田的可能潜力。在综合模型上进行的预测计算可以作为预算规划的基础,也可以作为在油井上开展地质和技术活动、启用新油井、更新设备和基础设施的基础。此外,考虑到所有地质和技术限制因素,分组优化计算还能使我们最大限度地提高额外的石油产量。目标通过使用物料平衡法调整参数,形成并分析建立储油层模型的方法;形成调整综合模型的解决方案,将结果与实际数据进行协调;进行优化计算并获得额外的石油产量。方法。使用物料平衡法调整和适应储油层模型;调整和适应一个油田/一组油田的综合模型;计算 30/90 天的预测;优化计算。结果。根据所获得的结果,可以对综合模型的各组成部分进行调整,调整精度为±5%,从而可以模拟油田的运行模式。通过分析,确定了调整标准,并提出了水库模型和收集系统定性调整所需的最小参数集。通过比较运行模式的实际数据和合成数据,也证明了该工具的有效性和准确性。根据已完成的工作,可以得出结论,使用综合模型可以显示出与实际数据的高度趋同性,从而使我们能够以最佳方式接近油田开发模式。此外,还进行了优化计算,以利用建议的解决方案获得额外的石油产量,并计算出 90 天的石油产量预测,随后与实际数据进行比较,证实了这一点。
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引用次数: 0
Assessment of radiation environmental risks for fish fauna of the cooling pools of a number of operating nuclear power plants 评估辐射环境对一些运行中核电站冷却池中鱼类的风险
Pub Date : 2024-02-28 DOI: 10.18799/24131830/2024/2/4242
V. G. Gorodetsky, Aleksandr V. Trapeznikov, V. Trapeznikova, A. V. Korzhavin
Relevance. The need to assess radiation risks for the main types of fish in pools that are under the constant influence of the nuclear power plants. Aim. To assess the radiation environmental risks for the ichthyofauna of cooling pools of the operating nuclear power plants, to analyze the sources and features of formation of the radiation risks at different stages of their operation. Objects: monitoring studies of radiation environmental risks for reference fish species in cooling reservoirs of the Leningrad, Beloyarsk and Novovoronezh NPP. Methods. Calculation of the exposure dose rate and quantitative assessment of the risk of exposure to technogenic radionuclides of the ichthyofauna of the cooling pools of the Beloyarskaya, Leningradskaya and Novovoronezhskaya NPPs were carried out using the international computer complex of the updated version of ERICA Tool 2.0. Results. The paper demonstrates that the radiation ecological risks for the ichthyofauna in the cooling pools of the operating nuclear power plants are caused by the combined effect of radioisotopes of the different origin. The features of the formation of the radiation risks for each pool are specific and depend on the current radiation situation. The cooling pool of the Beloyarskaya NPP is characterized by a pronounced dependence of the radiation load on the types of operating power units. The ichthyofauna experienced the greatest radiation risks during the operation of the first two power units with thermal reactors AMB-100 and AMB-200. The decommissioning of the first power units and the construction of the units with the fast neutron reactors (BN-600 and BN-800) led to a significant reduction in the radiation load on the ichthyofauna of the cooling pool. At present, the radiation risks are caused mainly by the influence of 90Sr, which is almost not discharged from the Beloyarskaya NPP into the cooling pools, but has a predominantly global origin. Therefore, the formation of the risks is more associated with atmospheric fallout of 90Sr, and not with the operation of the nuclear power plant. The radiation risks for the ichthyofauna of the Leningradskaya NPP cooling pool are caused by the combined effect of 137Cs as a result of the radiation accident at the Chernobylskaya NPP and radionuclides with induced activity (14C; 60Co; 3H 54Mn and 65Zn), the origin of which may be associated with the operation of the nuclear reactors of the NPP. The level of radiation risk for the fish fauna of the Novovoronezhskaya NPP cooling pool for 2009–2019 increased 2.2 times due to an increase in the content of 60Co in many components of the pool. As a result, 81.7% of the radiation risks in demersal fish species were formed by the influence of 60Co. It cannot be ruled out that the increase in the 60Co content in the cooling pool of the Novovoronezhskaya NPP is a consequence of radioactive contamination of the groundwater as a result of the 1985 accident. The ecological risks for the fish fauna in al
相关性。需要评估核电站持续影响下的水池中主要鱼类的辐射风险。目的。评估运行中核电站冷却水池中鱼类的辐射环境风险,分析核电站运行不同阶段辐射风险的来源和形成特点。目标:对列宁格勒、别洛亚尔斯克和新沃罗涅日核电站冷却池中的参考鱼种进行辐射环境风险监测研究。方法。利用ERICA工具2.0更新版的国际计算机综合系统,对别洛亚尔斯卡娅、列宁格勒和新沃罗涅日核电厂冷却水池中鱼类受技术放射性核素照射的风险进行了剂量率计算和定量评估。研究结果论文证明,运行中核电站冷却池中鱼类的辐射生态风险是由不同来源的放射性同位素共同作用造成的。每个水池辐射风险的形成都有其特点,并取决于当前的辐射情况。Beloyarskaya 核电站冷却池的特点是辐射负荷明显取决于运行机组的类型。在 AMB-100 和 AMB-200 热反应堆的前两个机组运行期间,鱼类面临的辐射风险最大。随着第一批机组的退役和快中子反应堆机组(BN-600 和 BN-800)的建成,冷却池鱼类的辐射负荷显著降低。目前,辐射风险主要是由 90Sr 的影响造成的,这种物质几乎没有从 Beloyarskaya 核电站排入冷却池,而是主要来自全球。因此,风险的形成更多地与大气中的 90Sr 降尘有关,而与核电站的运行无关。列宁格勒核电厂冷却池中鱼类的辐射风险是由切尔诺贝利核电站辐射事故造成的 137Cs 和具有诱导活度的放射性核素(14C、60Co、3H 54Mn 和 65Zn)共同造成的,其来源可能与核电厂核反应堆的运行有关。由于新沃罗涅日斯卡娅核电站冷却池中许多成分的 60Co 含量增加,2009-2019 年期间该冷却池鱼类的辐射风险水平增加了 2.2 倍。因此,底栖鱼类中 81.7% 的辐射风险是受 60Co 的影响而形成的。不能排除新沃罗涅日核电厂冷却池中 60Co 含量增加是 1985 年事故造成地下水放射性污染的结果。所有冷却池中的鱼类动物所面临的生态风险都比最大允许危害系数低 2 至 3 个数量级。因此,核电站的正常运行不会造成不可接受的辐射风险,不会对冷却池中的鱼类构成真正的环境威胁。
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引用次数: 0
Comparative estimation of a random error component of automatic well level gauges based on processing measurements of earth-tidal level of groundwater 基于地下水地潮水位测量的自动水位计随机误差成分的比较估算
Pub Date : 2024-02-28 DOI: 10.18799/24131830/2024/2/4341
Taras Yu. Zavedy, Nikita R. Adonin, Oleg N. Kokorev, Alexander A. Shchipkov
Relevance. Introduction of autonomous digital level gauges allows significantly expanding the range of tasks solved in various fields of geology and ecology, by increasing the frequency of measurements and applying mathematical processing methods to avoid distortions of different nature. The expansion of the field of application of downhole level meters makes it a topical issue to choose a particular type of device to ensure the required measurement accuracy. Aim. To consider the approaches to comparative estimation of random error of several types of automatic level gauges based on their recording of earth-tidal variations of groundwater level. Methods. Methods of compensating the influence of variations in atmospheric pressure on groundwater levels; methods of calculating tidal level variations; methods of correlation and frequency analysis of the calculated and experimental data. Results. The authors have carried out a comparative assessment of the accuracy in readings of several digital level gauges, installed in one well, by comparing the measured values of earth-tidal variations of the groundwater level with the calculated ones. Based on the experimental data, tidal variations of the groundwater level were obtained by eliminating distortions from variations in atmospheric pressure and then filtering with the moving mean. From correlation and amplitude-frequency analysis of the calculated and experimental data, indicators were determined for making a comparative assessment of a random component of the error of the tested level gauges. Conclusions. The approach suggested allows choosing independent digital level gauges with a minimum random error component using the totality of calculated parameters. The most promising way to eliminate the distorting effects of tidal variation of groundwater level is the method based on the cutter frequency filtering of the level signal measured by the level gauge.
相关性。通过提高测量频率和应用数学处理方法来避免不同性质的失真,采用自主数字液位计可以显著扩大地质和生态学各领域的任务范围。随着井下液位计应用领域的扩大,如何选择特定类型的设备以确保所需的测量精度成为一个热门话题。目的根据自动水位计对地下水位潮汐变化的记录,研究几种自动水位计随机误差的比较估算方法。方法。补偿大气压力变化对地下水位影响的方法;潮汐水位变化的计算方法;计算和实验数据的相关性和频率分析方法。结果。作者通过比较地下水位潮汐变化的测量值和计算值,对安装在一口井中的几个数字水位计的读数精度进行了比较评估。根据实验数据,通过消除大气压力变化造成的失真,然后用移动平均值进行过滤,得到了地下水位的潮汐变化。通过对计算数据和实验数据的相关性和振幅频率分析,确定了对测试水位计误差的随机成分进行比较评估的指标。得出结论。根据所建议的方法,可以利用计算参数的整体性选择随机误差最小的独立数字液位计。消除地下水位潮汐变化扭曲影响的最有前途的方法是对水位计测量的水位信号进行切频滤波。
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引用次数: 0
Development of a system for controlling a diamond drilling mode in terms of rock fault resistance 开发从岩石断层阻力角度控制金刚石钻孔模式的系统
Pub Date : 2024-02-28 DOI: 10.18799/24131830/2024/2/4230
V. V. Neskoromnykh, Marina S. Popova, Ksenia V. Laletina, D. V. Lysakov
Relevance. Resistance to rock-cutting elements in rock destruction largely determines the effectiveness of drilling results. Information about the drag coefficient allows you to correctly and timely adjust the intensity of a drilling tool impact on the bottom of the well. To control the force contact of the drilling tool cutters with the bottom of the well, it is necessary to have a methodological apparatus that allows determining the rock destruction mechanism, taking into account the resistance forces. The existing methods for selecting combinations of diamond drilling mode parameters according to the known RPI index or according to the criterion of energy intensity of rock destruction N/vm , where N is the bottomhole power to overcome the resistance during rock destruction at the bottom hole; vm – mechanical drilling speed, have a number of disadvantages. They consist, for example, in occurrence of tool wear or the need to obtain a bottomhole power value in the current time mode, which is difficult under modern drilling conditions. Therefore, the study of rock resistance to destruction by a diamond cutter, based on application of the full factorial experiment method with obtaining mathematical models of factors and their graphical interpretation in combination with process control systems using computer technology in the current time mode, is a relevant topic. The disclosure of this topic will determine the direction of increasing technical and economic indicators of drilling. Aim. To develop a methodological apparatus that allows determining the mechanism of rock destruction taking into account the resistance forces to ensure optimal control of diamond drilling. Objects. Mechanism of rock resistance to destruction by a diamond cutter. Methods. Analysis, analytical research, full factorial experiment. Results. The paper presents an analytical analysis of the possibility of controlling drilling modes in order to achieve the greatest effect from drilling by estimating the drag coefficient as a function of the intensity of destruction or deepening per one revolution. Based on the analytical studies and the mode of drilling control by a computer in the real time mode, the authors have proposed a method for selecting the parameters of the drilling mode according to a given optimal value of the resistance index during drilling, and a way for its automatic implementation.
相关性。岩石破坏过程中的岩石切割阻力在很大程度上决定了钻井效果。有关阻力系数的信息可以正确及时地调整钻具对井底的冲击强度。为了控制钻具刀具与井底的接触力,必须有一种方法装置,可以在考虑阻力的情况下确定岩石破坏机制。现有的根据已知的 RPI 指数或根据岩石破坏能量强度 N/vm 标准选择金刚石钻进模式参数组合的方法有许多缺点,其中 N 是井底岩石破坏时克服阻力的井底功率;vm - 机械钻速。例如,它们包括工具磨损或需要在当前时间模式下获得井底动力值,而这在现代钻探条件下很难实现。因此,研究金刚石铣刀破坏岩石的阻力是一个相关的课题,其基础是应用全因子实验方法,结合当前时间模式下使用计算机技术的过程控制系统,获得各因子的数学模型及其图形解释。该课题的揭示将决定钻探技术和经济指标的增长方向。目标开发一种方法装置,在考虑阻力的情况下确定岩石破坏的机理,以确保金刚石钻探的最佳控制。目标。岩石抵抗金刚石铣刀破坏的机理。方法。分析、分析研究、全因子实验。结果。本文对控制钻进模式的可能性进行了分析,通过估算阻力系数与每转破坏或加深强度的函数关系,实现钻进的最大效果。在分析研究和计算机实时控制钻孔模式的基础上,作者提出了一种根据钻孔过程中阻力指数的给定最佳值选择钻孔模式参数的方法,以及自动实施的方法。
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引用次数: 0
Distribution of stable Н, О and С isotopes in natural waters in the area of the Taz oil and gas condensate field (Yamalo-Nenets autonomous region) 塔兹(Taz)油气凝析气田(亚马尔-涅涅茨自治区)自然水域中稳定Н、О和С同位素的分布情况
Pub Date : 2024-02-28 DOI: 10.18799/24131830/2024/2/4466
O. Lepokurova, I.S. Ivanova, A. N. Pyrayev, Oleg A. Ismagulov
Relevance. The study of isotopic composition of water and dissolved substances makes it possible to determine not only their genesis, but also the fractionation processes occurring in the “water–rock–gas–organic matter” system over time, i. e. as different stages of the evolution of water composition pass through. Interest in the groundwater of the Arctic regions of Western Siberia is additionally associated with the widespread occurrence of oil deposits at the depths of formation waters and the possible influence of cryogenic metamorphization processes on composition of near-surface waters. Aim. To study and compare the isotopic composition of oxygen, hydrogen and carbon in natural waters of the Yamalo-Nenets autonomous region to identify conditional isotopic markers, as well as to be able to trace the evolution of the isotopic composition of waters along a vertical section in the area of the Taz oil and gas condensate field. Objects. Surface (river, soil and lake), underground waters of the active water exchange zone of the Yamalo-Nenets autonomous region and formation waters of oil and gas deposits of the Taz field. Methods. The study of the isotopic composition of oxygen, hydrogen, and carbon of water-dissolved carbon dioxide was carried out in the Research Equipment Sharing Center at the Institute of Geology and Mineralogy SB RAS using Isotope Ratio Mass Spectrometer FinniganTM MAT 253 equipped with H/Device and GasBench II for sample preparation. Results and conclusions. The paper introduces the data on isotopic composition of O, H and C for natural waters of the Yamalo-Nenets autonomous region. The authors have determined the characteristic trends in changes in the isotopic composition of water and dissolved carbon dioxide for various water bodies. Surface and underground waters with active water exchange in terms of isotopic composition (δD and δ18О) are infiltration. As water moves down the section, with an increase in the time of interaction of the “water–rock” system and increase in temperatures, the isotopic composition becomes significantly heavier with a slope from the GMWL to the right. The authors compiled the diagram of the evolution of water-dissolved carbon isotopic composition in the region according to the obtained and some literature data. Despite the wide range of δ13C values from –30.4 to 23.6 ‰, there are, obviously, only two sources of carbon dioxide in the region: biogenic and atmospheric, with biogenic being predominant for groundwater.
相关性。通过研究水和溶解物质的同位素组成,不仅可以确定其成因,还可以确定 "水-岩石-气体-有机物 "系统随时间发生的分馏过程,即水组成演变的不同阶段。对西西伯利亚北极地区地下水的兴趣还与地层水深处广泛存在的石油沉积以及低温变质过程对近地表水成分可能产生的影响有关。研究目的研究和比较亚马尔-涅涅茨自治区天然水中氧、氢和碳的同位素组成,以确定有条件的同位素标记,并能够沿着塔兹石油和天然气凝析气田地区的垂直剖面追踪水体同位素组成的演变。对象。亚马尔-涅涅茨自治区活跃水交换区的地表水(河流、土壤和湖泊)、地下水以及塔兹油气田油气储藏的地层水。研究方法使用配备 H/Device 和 GasBench II 的同位素比质谱仪 FinniganTM MAT 253(用于样品制备),在俄罗斯科学院地质矿产研究所研究设备共享中心对水溶二氧化碳中氧、氢和碳的同位素组成进行了研究。结果和结论。本文介绍了亚马尔-涅涅茨自治区天然水的 O、H 和 C 同位素组成数据。作者确定了各种水体的水和溶解二氧化碳同位素组成变化的特征趋势。从同位素组成(δD 和 δ18О)来看,地表水和地下水的水交换活跃,是渗透的结果。随着 "水-岩 "系统相互作用时间的增加和温度的升高,水沿着断面向下流动,同位素组成明显变重,斜率从全球最大降水量向右倾斜。作者根据所获得的数据和一些文献数据,编制了该地区水溶解碳同位素组成演变图。尽管δ13C 值的范围很广,从-30.4 ‰到 23.6 ‰不等,但该地区的二氧化碳显然只有两种来源:生物源和大气源,而生物源在地下水中占主导地位。
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引用次数: 0
Waste management in potash mining companies 钾盐开采公司的废物管理
Pub Date : 2024-01-31 DOI: 10.18799/24131830/2024/1/4387
A. Perevoshchikova, R. Perevoshchikov, E. E. Malyshkina, N. Mitrakova
Relevance. Related to the need to carry out environmental protection measures in potash mining areas exposed to the environmental consequences of the impact of multi-tonnage salt waste. Aim. To summarise and analyse the geography of potash mining operations, the environmental impact of these operations, and potash waste management practices. Object. Potash mining waste. Methods. Theoretical and logical analysis of the data. Results. The research considers the geographical distribution of potash deposits and presents the characteristics of potash mining waste using the example of the Verkhnekamskoe Potash Deposit. The paper provides both domestic and foreign analyses of ecological consequences of waste storage on the day surface. Several options for potash mining waste management are analysed. For the management of clay-salt slurry, the most effective approach is its injection into underground horizons, which includes the use of saturated solutions as a fertiliser component, as a part of a product in construction, and in the oil industry. A more comprehensive approach to halite waste management is needed. Waste disposal to waste dumps is relevant due to the presence of mined-out areas on the territory of long-operating enterprises. Reclamation of the salt dump will help to isolate it from atmospheric precipitation, thereby reducing the inflow of saturated water into the environment. Utilising waste for production of construction materials is the most economically and environmentally favourable option. Extracting valuable components, producing fertilisers, concentrates, etc. from waste is the least practical approach due to the ecological and economic expenses involved in acquiring extraction equipment and the repeated generation of waste. The most challenging aspect of reducing waste generation in terms of technology lies in improving mining operations and implementing selective mining.
相关性。在受到多吨盐废料影响的钾盐开采区采取环境保护措施的必要性。目的。总结和分析钾盐开采作业的地理位置、这些作业对环境的影响以及钾盐废物管理方法。对象。钾盐开采废物。方法。对数据进行理论和逻辑分析。结果。研究考虑了钾盐矿床的地理分布,并以上卡姆斯基钾盐矿床为例介绍了钾盐开采废料的特点。论文提供了国内外对废物在日表面储存的生态后果的分析。分析了钾盐开采废料管理的几种方案。对于粘土盐浆的管理,最有效的方法是将其注入地下地层,包括将饱和溶液用作肥料成分、建筑产品的一部分以及石油工业。需要采取更全面的方法来管理海泡石废物。由于在长期运营的企业的领土上存在开采过的区域,因此将废物弃置到废物堆中具有相关性。对盐堆进行复垦将有助于使其与大气降水隔离,从而减少饱和水流入环境。利用废物生产建筑材料是最经济、最环保的选择。从废弃物中提取有价值的成分、生产肥料、浓缩物等是最不实用的方法,因为需要购买提取设备和重复产生废弃物,涉及生态和经济支出。在技术方面,减少废物产生最具挑战性的方面在于改进采矿作业和实施选择性采矿。
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引用次数: 0
期刊
Bulletin of the Tomsk Polytechnic University Geo Assets Engineering
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