Pub Date : 2024-06-08DOI: 10.1007/s00396-024-05275-6
Thi Minh Hang Tran, Thi Duyen Tran, T. Dinh, Manh Khai Nguyen, Nguyen Thi Ngoc Anh, Nguyen Kim Nga, Thi Hai Yen Doan, Tien Duc Pham
{"title":"Adsorption characteristics of individual and binary mixtures of ciprofloxacin and Cr(VI) in water using MnO2 colloidal particles","authors":"Thi Minh Hang Tran, Thi Duyen Tran, T. Dinh, Manh Khai Nguyen, Nguyen Thi Ngoc Anh, Nguyen Kim Nga, Thi Hai Yen Doan, Tien Duc Pham","doi":"10.1007/s00396-024-05275-6","DOIUrl":"https://doi.org/10.1007/s00396-024-05275-6","url":null,"abstract":"","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":null,"pages":null},"PeriodicalIF":2.4,"publicationDate":"2024-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141369686","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-08DOI: 10.1007/s00396-024-05279-2
Yuya Doi, Jürgen Allgaier, Stephan Förster, Shin-ichi Takata, Michael Ohl
{"title":"Chain dimensions of poly(ethylene carbonate/ethylene oxide) copolymer with salt addition studied by SANS","authors":"Yuya Doi, Jürgen Allgaier, Stephan Förster, Shin-ichi Takata, Michael Ohl","doi":"10.1007/s00396-024-05279-2","DOIUrl":"https://doi.org/10.1007/s00396-024-05279-2","url":null,"abstract":"","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":null,"pages":null},"PeriodicalIF":2.4,"publicationDate":"2024-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141368454","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-03DOI: 10.1007/s00396-024-05278-3
Xu Hou, Le Chang, Chenxuan Zheng, Huarong Liu
High internal phase emulsions (HIPEs) are commonly stabilized by a large amount of surfactants that should be removed after the polymerization of the continuous phase, and the resulting polyHIPEs from W/O HIPEs are usually brittle and chalky. Herein we report on an amphiphilic polymerizable polyurethane (PPU) macromolecular surfactant synthesized by polyaddition reaction of diisocyanates and polyols, which can well stabilize up to 88% internal phase volume of W/O HIPE with a content of only 5 wt% based the oil phase. Compared with the HIPEs stabilized by traditional surfactant Span 80, HIPEs stabilized by PPU at either room temperature or 70 °C are much more stable owing to the increased viscosity which can inhibit droplet coalescence. Moreover, the resulting polyHIPEs not only have several times higher mechanical properties than those stabilized by Span 80 but also have higher elasticity. The effects of concentration of PPU on the morphology and mechanical properties of the resulting polyHIPEs were investigated. It was found that with the increase of PPU content, the average void and window sizes decreased, while the compression strength increased. Cyclic compression tests were performed to examine reversible compressibility and durability of these polyHIPEs.
Graphical abstract
The polymerizable polyurethane macromolecular surfactant (PPU) synthesized through the polyaddition reaction of diisocyanates and polyols can solely stabilize high internal phase emulsions (HIPEs), and highly interconnected macroporous polymer produced by the polymerization of HIPE stabilized with PPU, known as polyHIPE, can withstand large deformation compression with no visible cracks.
{"title":"Synthesis and characterization of polyHIPEs using a polymerizable polyurethane macromolecular surfactant","authors":"Xu Hou, Le Chang, Chenxuan Zheng, Huarong Liu","doi":"10.1007/s00396-024-05278-3","DOIUrl":"https://doi.org/10.1007/s00396-024-05278-3","url":null,"abstract":"<p>High internal phase emulsions (HIPEs) are commonly stabilized by a large amount of surfactants that should be removed after the polymerization of the continuous phase, and the resulting polyHIPEs from W/O HIPEs are usually brittle and chalky. Herein we report on an amphiphilic polymerizable polyurethane (PPU) macromolecular surfactant synthesized by polyaddition reaction of diisocyanates and polyols, which can well stabilize up to 88% internal phase volume of W/O HIPE with a content of only 5 wt% based the oil phase. Compared with the HIPEs stabilized by traditional surfactant Span 80, HIPEs stabilized by PPU at either room temperature or 70 °C are much more stable owing to the increased viscosity which can inhibit droplet coalescence. Moreover, the resulting polyHIPEs not only have several times higher mechanical properties than those stabilized by Span 80 but also have higher elasticity. The effects of concentration of PPU on the morphology and mechanical properties of the resulting polyHIPEs were investigated. It was found that with the increase of PPU content, the average void and window sizes decreased, while the compression strength increased. Cyclic compression tests were performed to examine reversible compressibility and durability of these polyHIPEs.</p><h3 data-test=\"abstract-sub-heading\">Graphical abstract</h3><p>The polymerizable polyurethane macromolecular surfactant (PPU) synthesized through the polyaddition reaction of diisocyanates and polyols can solely stabilize high internal phase emulsions (HIPEs), and highly interconnected macroporous polymer produced by the polymerization of HIPE stabilized with PPU, known as polyHIPE, can withstand large deformation compression with no visible cracks.</p>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":null,"pages":null},"PeriodicalIF":2.4,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141258440","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-06-03DOI: 10.1007/s00396-024-05273-8
Vasily I. Mikhaylov, Mikhail A. Torlopov, Irina N. Vaseneva, Ilia S. Martakov, Philipp V. Legki, Kirill A. Cherednichenko, Nikita M. Paderin, Petr A. Sitnikov
This study investigated the use of cellulose nanocrystals (CNC)/chitosan (Chit) polyelectrolyte complex as a stabilizing agent for Pickering emulsions. We demonstrated that chitosan reduces the surface charge of CNC improving the emulsification process. An optimal stabilizing complex containing 1% chitosan results in emulsions with minimal zeta potential (3.2 ± 0.3 mV), droplet size (2.8 ± 0.8 μm), and creaming index (19.8 ± 1.0%) values, along with high stability during storage, a change in pH, and high centrifugal forces (up to 2000 g). The study also showed that the maximum neutralized surface charge of the CNC in the CNC-Chit complex allows for effective adsorption on the surface of sunflower oil droplets, producing a denser stabilizing layer with a smaller droplet size. Additionally, chitosan addition is linked to improved stability and higher viscosity, with little dependence on ionic strength and temperature. Potentiometric titration revealed that compared with sulfated CNCs, five times less chitosan is needed to neutralize the negative surface charge of acetylated CNC. The wettability of a hydrophilic surface depends on the surface charge of the complex, and the wettability and adhesion performance increase with increasing chitosan content. Additionally, we showed that tuning the stabilizer composition can change the bioaccessibility of lipophilic compounds during oral administration.
{"title":"Cellulose nanocrystal/chitosan ratio in Pickering stabilizers regulates vitamin D3 release","authors":"Vasily I. Mikhaylov, Mikhail A. Torlopov, Irina N. Vaseneva, Ilia S. Martakov, Philipp V. Legki, Kirill A. Cherednichenko, Nikita M. Paderin, Petr A. Sitnikov","doi":"10.1007/s00396-024-05273-8","DOIUrl":"https://doi.org/10.1007/s00396-024-05273-8","url":null,"abstract":"<p>This study investigated the use of cellulose nanocrystals (CNC)/chitosan (Chit) polyelectrolyte complex as a stabilizing agent for Pickering emulsions. We demonstrated that chitosan reduces the surface charge of CNC improving the emulsification process. An optimal stabilizing complex containing 1% chitosan results in emulsions with minimal zeta potential (3.2 ± 0.3 mV), droplet size (2.8 ± 0.8 μm), and creaming index (19.8 ± 1.0%) values, along with high stability during storage, a change in pH, and high centrifugal forces (up to 2000 g). The study also showed that the maximum neutralized surface charge of the CNC in the CNC-Chit complex allows for effective adsorption on the surface of sunflower oil droplets, producing a denser stabilizing layer with a smaller droplet size. Additionally, chitosan addition is linked to improved stability and higher viscosity, with little dependence on ionic strength and temperature. Potentiometric titration revealed that compared with sulfated CNCs, five times less chitosan is needed to neutralize the negative surface charge of acetylated CNC. The wettability of a hydrophilic surface depends on the surface charge of the complex, and the wettability and adhesion performance increase with increasing chitosan content. Additionally, we showed that tuning the stabilizer composition can change the bioaccessibility of lipophilic compounds during oral administration.</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":null,"pages":null},"PeriodicalIF":2.4,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141258302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Three kinds of multiblock polyethylene oxide-polypropylene oxide (PEOm-PPOn for short) were synthesized using ethylene glycol as the initiated core via the living anionic polymerization. Respectively, the multiblock polyethers were named E340, E540, and E740 based on the block number (3, 5, 7) and the content of ethylene oxide (EO, 40 wt%), which were confirmed by the Fourier transform infrared (FT-IR), hydrogen nuclear magnetic resonance (1H NMR), and gel permeation chromatography (GPC). Moreover, their bulk and solution properties, including dynamic modulus, rheological characteristic, viscosity, aggregation behavior, surface tension, steady-state fluorescence, solubility, and microemulsion performance were determined. The test results of rheological properties showed that these multiblock copolyethers behaved as the pseudo-plastic non-Newtonian fluids. Furthermore, it was found that their solubility and surface tension were gradually decreased with an increase of block numbers. Nevertheless, the dynamic modulus tended contrary trends. Research on the aggregation and micro-emulsion properties in aqueous solutions indicated that the value of critical micelle concentration (CMC) increased, and meanwhile the ability of solubilization and micro-emulsion formation deteriorated with increasing block numbers. In conclusion, their aggregation mechanism in aqueous solution was also given.