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Current Opinion in Green and Sustainable Chemistry最新文献

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Toward a more sustainable photocatalysis using copper and iron 用铜和铁进行更可持续的光催化
IF 9.3 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Current Opinion in Green and Sustainable Chemistry
Pub Date : 2025-01-11 DOI: 10.1016/j.cogsc.2025.100998
Youssef Abderrazak, Oliver Reiser
Shifting from rare and precious metal catalysts in photochemical systems, such as ruthenium and iridium, to abundant and sustainable ones is still challenging. Copper and iron are fascinating, given their relative abundance and economic advantage. While the conception of copper and iron luminophores for the application in catalysis is faced with the undesirable rapid deactivation of photoactive states, making intermolecular redox exchange inefficient, the harnessing of copper and iron's propensity to perform fast ligand exchange and accommodation of radical intermediates enabled their successful implementation in photocatalysis. This review underscores the rapid growth of copper and iron in photocatalysis as green and sustainable alternatives, highlighting the unique catalytic features they offer.
从光化学系统中的稀有和贵重金属催化剂，如钌和铱，转向丰富和可持续的催化剂仍然是一个挑战。考虑到铜和铁的相对储量和经济优势，它们很吸引人。虽然用于催化的铜和铁发光团的概念面临着光活性态的快速失活，使分子间氧化还原交换效率低下的问题，但利用铜和铁的倾向进行快速配体交换和自由基中间体的调节使其在光催化中成功实现。这篇综述强调了铜和铁作为绿色和可持续的替代品在光催化中的快速发展，突出了它们所提供的独特的催化特性。
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引用次数: 0
IF 9.4 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Current Opinion in Green and Sustainable Chemistry
Pub Date : 2025-01-01
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引用次数: 0
IF 9.4 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Current Opinion in Green and Sustainable Chemistry
Pub Date : 2025-01-01
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引用次数: 0
IF 9.4 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Current Opinion in Green and Sustainable Chemistry
Pub Date : 2025-01-01
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引用次数: 0
IF 9.4 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Current Opinion in Green and Sustainable Chemistry
Pub Date : 2025-01-01
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引用次数: 0
IF 9.4 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Current Opinion in Green and Sustainable Chemistry
Pub Date : 2025-01-01
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引用次数: 0
IF 9.4 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Current Opinion in Green and Sustainable Chemistry
Pub Date : 2025-01-01
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引用次数: 0
IF 9.4 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Current Opinion in Green and Sustainable Chemistry
Pub Date : 2025-01-01
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引用次数: 0
IF 9.4 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Current Opinion in Green and Sustainable Chemistry
Pub Date : 2025-01-01
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引用次数: 0
IF 9.4 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Current Opinion in Green and Sustainable Chemistry
Pub Date : 2025-01-01
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引用次数: 0
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