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An All-In-One Rapid Prediction of Ground Motion Intensity Measures Hybrid Network for Multi-Task in the North-South Seismic Belt of China 中国南北地震带多任务地震动强度一体化快速预测措施混合网络
IF 2.9 3区 地球科学 Q2 ASTRONOMY & ASTROPHYSICS Pub Date : 2024-10-08 DOI: 10.1029/2024EA003664
Qingxu Zhao, Mianshui Rong, Bin Zhang, Xiaojun Li

The north-south seismic belt of China poses a high risk of earthquakes, necessitating the need for accurate and rapid prediction of intensity measures (IMs) to prevent and mitigate potential damage. We have developed a new multi-task model, CRAQuake, to predict IMs for the north-south seismic belt of China. Using initial arrival seismic waves recorded at a single station as input, CRAQuake simultaneously predicts six IMs without relying on pre-configured parameters such as earthquake source, path, and location. The model was trained on 4,281 sets of strong motion records data sets at 822 stations and tested to show highly correlated results with the target IMs. The prediction performance continues to improve as the input initial arrival seismic wave time window increases. CRAQuake promises to enhance the accuracy and timeliness of IMs prediction in the north-south seismic belt of China.

中国南北地震带的地震风险很高,因此需要准确、快速地预测烈度措施(IMs),以预防和减轻潜在的破坏。我们开发了一种新的多任务模型 CRAQuake,用于预测中国南北地震带的烈度措施。CRAQuake 使用单个台站记录的初至地震波作为输入,同时预测六种 IM,而无需依赖预先配置的参数,如震源、路径和位置。该模型在 822 个台站的 4281 组强运动记录数据集上进行了训练,并通过测试显示出与目标 IM 高度相关的结果。随着输入初至地震波时间窗的增加,预测性能不断提高。CRAQuake 有望提高中国南北地震带强震预测的准确性和及时性。
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引用次数: 0
Improvement of Source Spectrum Fall-Off for Simulating Ground Motion Using Stochastic Green’s Function Method 使用随机格林函数法模拟地动时源谱衰减的改进
IF 2.9 3区 地球科学 Q2 ASTRONOMY & ASTROPHYSICS Pub Date : 2024-10-07 DOI: 10.1029/2024EA003597
Xu Xie, Xu Hao, Longfei Ji

The stochastic Green's function method (SGFM), which simulates the source spectra of small earthquakes based on the ω−2 model and follows the scaling law of earthquakes to synthesize into a large earthquake, is a practical ground motion simulation method in areas lacking suitable small earthquake records. However, one of the problems in the application of the SGFM is that the source spectrum synthesized from small earthquakes shows a fall-off in the mid-frequency band, as the number of fault divisions of the large earthquake increases. To solve this problem, this study proposes an improved method, which introduces a correction coefficient for the source spectrum according to the ω−2 model and considers the variation of subfault rise time with the rupture process. Taking the 1994 Northridge earthquake as an example, the ground motion simulation results of the improved method are compared with observed records. The results show that only introducing the correction coefficient causes larger amplitude of simulation results than observed records. Only considering the variation of subfault rise time can improve the fall-off problem to some extent, but the accuracy of ground motion simulation at observation points has no significant improvement. By simultaneously introducing the correction coefficient and considering the variation of subfault rise time, the simulation results are in good agreement with observed records and are able to reproduce the directivity effect at the forward observation points. Therefore, the improved SGFM proposed in this study is an effective and reliable tool for ground motion simulation.

随机格林函数法(SGFM)基于ω-2 模型模拟小地震的震源谱,并遵循地震的缩放规律合成大地震,是缺乏合适小地震记录地区的一种实用地面运动模拟方法。然而,SGFM 在应用中存在的一个问题是,随着大地震断层数的增加,由小地震合成的震源谱在中频段会出现衰减。为解决这一问题,本研究提出了一种改进方法,即根据 ω-2 模型为震源频谱引入修正系数,并考虑子断层上升时间随破裂过程的变化。以 1994 年北岭地震为例,将改进方法的地面运动模拟结果与观测记录进行了比较。结果表明,仅引入修正系数会导致模拟结果的振幅大于观测记录。只考虑子断层上升时间的变化可以在一定程度上改善落差问题,但观测点的地动模拟精度没有明显改善。通过同时引入修正系数和考虑子断层上升时间的变化,模拟结果与观测记录十分吻合,并且能够再现前方观测点的指向性效应。因此,本研究提出的改进型 SGFM 是一种有效、可靠的地动模拟工具。
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引用次数: 0
Optimizing ExoMars Rover Remote Sensing Multispectral Science II: Choosing and Using Multispectral Filters for Dynamic Planetary Surface Exploration With Linear Discriminant Analysis 优化 ExoMars 火星漫游车遥感多光谱科学 II:利用线性判别分析为行星表面动态探测选择和使用多光谱滤波器
IF 2.9 3区 地球科学 Q2 ASTRONOMY & ASTROPHYSICS Pub Date : 2024-10-07 DOI: 10.1029/2023EA003398
R. B. Stabbins, P. M. Grindrod, S. Motaghian, E. J. Allender, C. R. Cousins

In this paper we address two problems associated with data-limited dynamic spacecraft exploration: data-prioritization for transmission, and data-reduction for interpretation, in the context of ESA ExoMars rover multispectral imaging. We present and explore a strategy for selecting and combining subsets of spectral channels captured from the ExoMars Panoramic Camera, and attempt to seek hematite against a background of phyllosilicates and basalts as a test case scenario, anticipated from orbital studies of the rover landing site. We compute all available dimension reductions on the material reflectance spectra afforded by 4 spectral parameter types, and consider all possible paired combinations of these. We then find the optimal linear combination of each pair whilst evaluating the resultant target-vs.-background separation in terms of the Fisher Ratio and classification accuracy, using Linear Discriminant Analysis. We find ∼50,000 spectral parameter combinations with a classification accuracy >95% that use 6-or-less filters, and that the highest accuracy score is 99.6% using 6 filters, but that an accuracy of >99% can still be achieved with 2 filters. We find that when the more computationally efficient Fisher Ratio is used to rank the combinations, the highest accuracy is 99.1% using 4 filters, and 95.1% when limited to 2 filters. These findings are applicable to the task of time-constrained planning of multispectral observations, and to the evaluation and cross-comparison of multispectral imaging systems at specific material discrimination tasks.

在本文中,我们以欧空局 ExoMars 火星漫游车多光谱成像为背景,探讨了与数据有限的动态航天器探测相关的两个问题:传输数据时的数据优先排序和解释数据时的数据缩减。我们提出并探索了一种策略,用于选择和组合从 ExoMars 火星全景照相机捕获的光谱通道子集,并尝试在植硅体和玄武岩背景下寻找赤铁矿,将此作为一个测试案例场景,这是漫游车着陆点轨道研究的预期结果。我们计算了 4 种光谱参数类型提供的材料反射光谱的所有可用维度还原,并考虑了所有可能的配对组合。然后,我们利用线性判别分析法找到每对组合的最佳线性组合,同时从费舍尔比和分类准确性的角度评估目标与背景的分离结果。我们发现使用 6 个或更少滤波器的分类准确率为 95% 的光谱参数组合有 50,000 个,使用 6 个滤波器的最高准确率为 99.6%,但使用 2 个滤波器仍可达到 99% 的准确率。我们发现,如果使用计算效率更高的费舍尔比率对组合进行排序,使用 4 个过滤器的最高准确率为 99.1%,而仅限于 2 个过滤器的准确率为 95.1%。这些发现适用于多光谱观测的时间限制规划任务,也适用于特定物质鉴别任务中多光谱成像系统的评估和交叉比较。
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引用次数: 0
Comprehensive Study of Large-Scale Traveling Ionospheric Disturbances (LSTIDs) Observed Over Iran 伊朗上空观测到的大规模移动电离层扰动(LSTIDs)综合研究
IF 2.9 3区 地球科学 Q2 ASTRONOMY & ASTROPHYSICS Pub Date : 2024-10-04 DOI: 10.1029/2024EA003811
M. Vazifehkhah Hafteh, A. Mahmoudian

A dense network of GNSS receivers is employed to study temporal and spatial characteristics of large-scale traveling ionospheric disturbances (LSTIDs) in Iran. Three geomagnetic storms in 2021 are selected. To determine LSTID propagation, an eighth-order Butterworth bandpass filter was applied to the data to remove the diurnal variability of the total electron content (TEC). Moreover, two-dimensional TEC perturbation maps are provided to explore the meridional and zonal structures of the LSTIDs. Analysis of a major storm on November 4 (Kp = 7, Dst = −99 nT) revealed two single LSTIDs and three groups of multiple LSTIDs. The phase velocity and wavelength of LSTIDs in this event varied between 190 and 930 m/s and 1,030–5,022 km, respectively. Southward propagating LSTIDs appeared to be more frequent than northward. The complex propagation of two simultaneous LSTIDs is resolved. A large-amplitude mixed front showing broadening both latitudinally and meridionally is revealed. No nighttime propagating LSTID is reported. In addition, global differential TEC data are explored to examine the detection of LSTID propagation. The global data validates the timing, direction of propagation, and strength of LSTIDs detected over Iran. The auroral oval extension is consistent with generating and propagating reported LSTIDs. The second storm studied occurred on August 27 (Kp = 4, Dst = −82 nT). This storm exhibited weaker LSTIDs in terms of both observed numbers and amplitude. Finally, the storm case of May 12 (Kp = 7, Dst = −61 nT) was examined. The results underscores the vital role of the Dst index in studying LSTIDs.

利用密集的全球导航卫星系统接收器网络研究伊朗大尺度巡回电离层扰动的时空特征。选取了 2021 年的三次地磁暴。为确定 LSTID 的传播情况,对数据采用了八阶巴特沃斯带通滤波,以消除电子总含量 (TEC)的日变化。此外,还提供了二维 TEC 扰动图,以探索 LSTID 的经向和带状结构。对 11 月 4 日的一次大风暴(Kp = 7,Dst = -99 nT)的分析显示了两个单 LSTID 和三组多 LSTID。在这次事件中,LSTID 的相位速度和波长分别在 190 至 930 米/秒和 1,030 至 5,022 公里之间。向南传播的 LSTID 似乎比向北传播的更频繁。两个同时出现的 LSTID 的复杂传播得到了解决。一个大振幅的混合锋在纬度和经度上都出现了扩展。没有报告夜间传播的 LSTID。此外,还探索了全球差异 TEC 数据,以检查 LSTID 传播的探测情况。全球数据验证了在伊朗上空探测到的 LSTID 的时间、传播方向和强度。极光椭圆的延伸与所报告的 LSTID 的产生和传播是一致的。研究的第二个风暴发生在 8 月 27 日(Kp = 4,Dst = -82 nT)。这次风暴在观测到的数量和振幅方面都表现出较弱的 LSTID。最后,研究了 5 月 12 日的风暴(Kp = 7,Dst = -61 nT)。结果表明,Dst 指数在研究 LSTIDs 方面起着至关重要的作用。
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引用次数: 0
Comprehensive Comparison of Two Global Multis-Species MHD Models of Mars 两种火星全球多物种 MHD 模型的综合比较
IF 2.9 3区 地球科学 Q2 ASTRONOMY & ASTROPHYSICS Pub Date : 2024-10-04 DOI: 10.1029/2024EA003698
Wenyi Sun, Ryoya Sakata, Yingjuan Ma, Kanako Seki, Christopher T. Russell, Naoki Terada, Shotaro Sakai, Hiroyuki Shinagawa, David Brain, Gabor Toth

Understanding the interaction between Mars and the solar wind is crucial for comprehending the atmospheric evolution and climate change on Mars. To gain a comprehensive understanding of the Martian plasma environment, global numerical simulations are essential in addition to spacecraft observations. However, there are still discrepancies among different simulation models. This study investigates how these discrepancies stem from the considered physical processes and numerical implementations. We compare two global multispecies MHD models: the “Sun model” based on the BATS-R-US code and the “Sakata model” based on a newly developed multifluid model MAESTRO. By employing the same typical upstream conditions and the same neutral atmosphere for current Mars, along with similar numerical implementations such as inner boundary conditions, we obtain simulation results that exhibit unprecedented agreement between the two models. The dayside results are nearly identical, especially along the subsolar line, indicating the robustness of MHD models to predict dayside interaction under given upstream conditions and ionosphere assumptions. The escape rates of planetary ions are also in good agreement. However, discrepancies remain in the terminator and nightside regions. Detailed numerical implementations, including inner boundary conditions, magnetic field divergence control methods, and radial resolutions, are shown to influence certain aspects of the results greatly, such as magnetotail configuration and ion diffusion.

了解火星与太阳风之间的相互作用对于理解火星大气演变和气候变化至关重要。要全面了解火星等离子体环境,除了航天器观测之外,全球数值模拟也必不可少。然而,不同的模拟模型之间仍然存在差异。本研究探讨了这些差异如何源于所考虑的物理过程和数值实现。我们比较了两个全球多物种 MHD 模型:基于 BATS-R-US 代码的 "太阳模型 "和基于新开发的多流体模型 MAESTRO 的 "坂田模型"。通过采用相同的典型上游条件和当前火星的相同中性大气,以及类似的数值实现(如内边界条件),我们获得了两个模型之间前所未有的一致的模拟结果。日侧结果几乎完全相同,尤其是沿太阳系下线,这表明在给定的上游条件和电离层假设下,MHD 模型在预测日侧相互作用方面的稳健性。行星离子的逃逸率也非常一致。然而,在终结者和夜侧区域仍存在差异。详细的数值实现,包括内部边界条件、磁场发散控制方法和径向分辨率,都会对结果的某些方面产生很大影响,例如磁尾构造和离子扩散。
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引用次数: 0
Structural and Dynamical Quality Assessment of Gap-Filled Sea Surface Temperature Products 填隙式海面温度产品的结构和动力学质量评估
IF 2.9 3区 地球科学 Q2 ASTRONOMY & ASTROPHYSICS Pub Date : 2024-10-02 DOI: 10.1029/2023EA003088
Cristina González-Haro, Jordi Isern-Fontanet, Antonio Turiel, Christopher J. Merchant, Peter Cornillon

Previous studies that intercompared global Level-4 (L4) sea surface temperature (SST) analyses were centered on the assessment of the accuracy and bias of SST by comparing them with independent near-surface Argo profile temperature data. This type of assessment is centered on the absolute value of SST rather than on SST spatial properties (gradients), which is more relevant to the study of oceanographic features (e.g., fronts, eddies, etc.) and ocean dynamics. Here, we use, for the first time, the spectrum of singularity exponents to assess the structural and dynamical quality of different L4 gap-filled products based on the multifractal theory of turbulence. Singularity exponents represent the geometrical projection of the turbulence cascade, and its singular spectrum can be related to the probability density function of the singularity exponents normalized by the scale. Our results reveal that the different schemes used to produce the L4 SST products generate different singularity spectra, which are then used to identify a potential loss of dynamical information or structural coherence. This new diagnostic constitutes a valuable tool to assess the structural quality of SST products and can support data satellite SST producers efforts to improve the interpolation schemes used to generate gap-filled SST products.

以往对全球四级海面温度(SST)分析进行相互比较的研究,主要是通过与独立的近地表 Argo 剖面温度数据进行比较,评估 SST 的准确性和偏差。这类评估的核心是海表温度的绝对值,而不是海表温度的空间特性(梯度),后者与海洋学特征(如锋面、漩涡等)和海洋动力学研究更为相关。在此,我们根据湍流的多分形理论,首次使用奇异指数谱来评估不同 L4 缺口填充产品的结构和动力学质量。奇异指数代表了湍流级联的几何投影,其奇异谱可以与奇异指数按尺度归一化的概率密度函数相关联。我们的研究结果表明,用于生成 L4 SST 产物的不同方案会产生不同的奇异谱,然后利用这些奇异谱来识别动态信息或结构一致性的潜在损失。这一新的诊断方法是评估 SST 产品结构质量的宝贵工具,可为数据卫星 SST 制作者提供支持,帮助他们改进用于生成间隙填充 SST 产品的插值方案。
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引用次数: 0
Tsunami Data Assimilation Using High-Frequency Radar-Derived Surface Currents by Considering Beam Angle-Dependent Measurement Error Distributions 通过考虑光束角度相关的测量误差分布,利用高频雷达得出的海面洋流进行海啸数据同化
IF 2.9 3区 地球科学 Q2 ASTRONOMY & ASTROPHYSICS Pub Date : 2024-10-02 DOI: 10.1029/2024EA003561
Muhammad Irham Sahana, Ryotaro Fuji, Tomoyuki Takahashi, Hirofumi Hinata

The application of high-frequency radar as an instrument for assimilating tsunami-induced current fields is garnering increasing interest. The performance of surface current velocity measurements depends on the azimuthal differences between the crossing radar beams at the measurement points. This study aimed to incorporate the measurement error distributions of the east-west and north-south velocity components into tsunami data assimilation based on an optimal interpolation method, assuming Gaussian noise with the time-invariant and a uniform standard deviation (STD = 5 cm/s) of radial velocity measurements. Through the empirical orthogonal function (EOF) analysis of radar-derived surface currents in the Kii Channel, Japan, the velocities reconstructed using higher modes (EOFs 16–274) were associated with measurement errors, portraying nonuniform distribution depending on the crossing beam angle of two radar beams. Based on independent fifteen-time assimilation experiments for two different tsunami scenarios, for a uniform water depth of 500 m, we observed a significant improvement of up to 29% and 0.9% in the assimilation performance (on average) over the along-coast stations for scenarios with 1- and 5-m maximum initial sea surface heights, respectively. The measurement errors dependent on the crossing beam angle reduced the error-induced tsunamis, resulting in stable assimilations, with lower STDs in the fifteen-time assimilation performances. When the STD of Gaussian noise varies with time, it is important to consider the temporal change in the radial velocity measurement errors and/or noise-filtering techniques, to maintain a certain level of noise intensity.

应用高频雷达作为同化海啸引起的海流场的仪器正引起越来越多的兴趣。海面流速测量的性能取决于测量点处雷达波束交叉的方位角差异。本研究的目的是,在假设高斯噪声具有时间不变性和径向速度测量具有均匀标准偏差(STD = 5 cm/s)的情况下,基于最优插值法将东西向和南北向速度分量的测量误差分布纳入海啸数据同化。通过对日本纪伊海峡的雷达海流进行经验正交函数(EOF)分析,利用较高模式(EOF 16-274)重建的速度与测量误差有关,其分布不均匀,取决于两个雷达波束的交叉波束角。在均匀水深为 500 米的情况下,我们对两种不同的海啸情景进行了独立的 15 次同化试验,观察到在最大初始海面高度为 1 米和 5 米的情景下,同化性能(平均)比沿岸站分别显著提高了 29% 和 0.9%。与穿越波束角相关的测量误差减少了误差引起的海啸,从而使同化结果稳定,15 次同化性能的 STD 较低。当高斯噪声的 STD 随时间变化时,必须考虑径向速度测量误差和/或噪声过滤技术的时间变化,以保持一定的噪声强度。
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引用次数: 0
Observed Correlation Between Local Topography and Passive Neutron Measurements From the Dynamic Albedo of Neutrons (DAN) Instrument on the Mars Science Laboratory (MSL) Rover 火星科学实验室(MSL)探测器上的动态中子反照率(DAN)仪器观测到的当地地形与被动中子测量值之间的相关性
IF 2.9 3区 地球科学 Q2 ASTRONOMY & ASTROPHYSICS Pub Date : 2024-10-02 DOI: 10.1029/2023EA003130
Steven D. Dibb, Craig Hardgrove, Jack Lightholder, Lena Heffern, Bent Ehresmann

The Dynamic Albedo of Neutrons (DAN) instrument on the Mars Science Laboratory Curiosity rover primarily measures neutrons that have undergone interactions with rocks and materials in the rover's local environment. As the rover ascends Aeolis Mons, it may encounter more extreme local topography (e.g., cliffs, gullies, canyons). We present three parts of the rover's traverse in which local topography, expressed as the average local relief relative to the rover, is moderately to strongly correlated with an increase in passive thermal neutron count rates. These increases in count rates are consistent with results from radiation transport models of the instrument's performance near simulated topographic features. Additional DAN measurements in areas of high average local relief (>0.25 m) within 5 m of the instrument could bolster this correlation. DAN's sensitivity to topography in its passive mode could be utilized as a new measurement capability and has implications for the operation of future landed missions carrying neutron spectrometers (e.g., VIPER, MoonRanger, Lunar-VISE).

好奇号火星科学实验室漫游车上的动态中子反照率(DAN)仪器主要测量与漫游车当地环境中的岩石和材料发生相互作用的中子。随着漫游车登上艾奥利斯山,它可能会遇到更极端的当地地形(如悬崖、沟壑、峡谷)。我们介绍了漫游车穿越过程中的三个部分,在这三个部分中,当地地形(用相对于漫游车的平均地势表示)与被动热中子计数率的增加呈中度到高度相关。这些计数率的增加与模拟地形特征附近仪器性能的辐射传输模型的结果一致。在仪器周围 5 米范围内平均地形起伏较大(0.25 米)的区域进行更多的 DAN 测量,可以加强这种相关性。DAN 在被动模式下对地形的敏感性可作为一种新的测量能力加以利用,并对未来携带中子分光计的着陆任务(例如,VIPER、MoonRanger、Lunar-VISE)的运行产生影响。
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引用次数: 0
Deep-Focus Earthquake Mechanisms at the Subducting Nazca Plate (Peru-Brazil Border): Cold Slab Behavior in a Warm Plate 俯冲纳斯卡板块(秘鲁-巴西边界)的深焦地震机制:暖板块中的冷板块行为
IF 2.9 3区 地球科学 Q2 ASTRONOMY & ASTROPHYSICS Pub Date : 2024-09-30 DOI: 10.1029/2024EA003617
G. S. Leite Neto, J. Julià, G. A. Prieto

We calculate focal mechanisms and centroid depths for deep-focus earthquakes (DFEs) along the Peru-Brazil border. We obtained a total of 28 focal solutions for events with magnitudes between 4.2 and 7.5 Mw and occurring between 2014 and 2022. Focal mechanisms indicate predominance of normal faulting, demonstrating a rather uniform down-dip compression (DDC) regime within the plate. The orientations of the nodal planes suggest that earthquakes tend to occur along faults parallel to the local slab strike, although other fault types are documented. Stress orientations derived from the focal mechanisms agree with patterns expected if faulting were initiated by transformational faulting on a metastable olivine wedge (MOW) under DDC. Centroid depths range between 557 and 659 km, defining a narrow seismic zone within the lower portion of the subducting plate and an aseismic upper portion. We suggest that DFEs nucleate through transformational faulting within a narrow MOW preserved at a colder slab segment right above the lower mantle and juxtaposed to a shallower, warmer segment at around 500 km depth. This thermal complexity was possibly produced through flat subduction initiated by the subduction of the Nazca Ridge. We speculate that subduction of other aseismic ridges is possibly controlling the thermal state of the Nazca slab as a whole and, consequently, the depth distribution of DFEs along the South America subduction front.

我们计算了秘鲁-巴西边境深焦点地震(DFEs)的焦点机制和中心点深度。我们共获得了 2014 至 2022 年间发生的 28 次震级在 4.2 至 7.5 兆瓦之间的地震的焦点解决方案。病灶机制表明,正断层占主导地位,显示了板块内相当均匀的下倾压缩(DDC)机制。节点平面的方向表明,地震往往沿着与当地板块走向平行的断层发生,但也有其他类型断层的记录。从病灶机制得出的应力方向与如果断层是由 DDC 条件下的可变质橄榄石楔(MOW)上的转换断层引发的预期模式一致。中心点深度在 557 至 659 千米之间,在俯冲板块的下部定义了一个狭窄的地震带,上部为无地震带。我们认为,DFE 是在下地幔正上方较冷的板块区段与深度约 500 千米的较浅、较热的板块区段并置的狭窄 MOW 内通过转换断层形成的。这种热的复杂性可能是由纳斯卡海脊的俯冲所引发的平面俯冲造成的。我们推测,其他地震海脊的俯冲可能控制了纳斯卡板块的整体热状态,从而控制了南美洲俯冲前沿 DFE 的深度分布。
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引用次数: 0
Geochemistry by Laser-Induced Breakdown Spectroscopy on the Moon: Accuracy, Detection Limits, and Realistic Constraints on Interpretations 月球上的激光诱导击穿光谱地球化学:准确性、探测极限和对解释的现实限制
IF 2.9 3区 地球科学 Q2 ASTRONOMY & ASTROPHYSICS Pub Date : 2024-09-28 DOI: 10.1029/2024EA003635
M. D. Dyar, C. R. Ytsma, K. Lepore

After its successful implementation on the surface of Mars, laser-induced breakdown spectroscopy (LIBS) is likely to be employed on a diverse array of other solid bodies in our Solar System. Here we address the accuracy and quantification limits of LIBS under the vacuum conditions found on the Moon relative to what is known about its geochemistry. The interplay among accuracy as represented by root mean-squared errors (RMSE), the median concentration, and quantification limits (LOQ) of LIBS analyses for each of 69 elements is evaluated. This comparison shows that several key elements in lunar geochemistry cannot be well-studied with LIBS, including K2O, S, Rb, Br, and C. Conversely, highly accurate analyses of SiO2, CaO, and many minor and trace elements such as Mn, Yb, and Zn are possible under conditions found on the Moon. Use of LIBS must always be considered in the context of the geochemistry and geology of the target materials.

激光诱导击穿光谱(LIBS)在火星表面成功应用之后,很可能会在太阳系的其他各种固体天体上应用。在此,我们将根据对月球地球化学的了解,探讨在月球真空条件下激光诱导击穿光谱的精度和量化极限。我们评估了以均方根误差 (RMSE) 表示的准确度、中位数浓度以及对 69 种元素进行 LIBS 分析的定量限 (LOQ) 之间的相互作用。比较结果表明,LIBS 无法很好地研究月球地球化学中的几种关键元素,包括 K2O、S、Rb、Br 和 C。相反,在月球条件下,可以对 SiO2、CaO 以及 Mn、Yb 和 Zn 等许多微量元素进行高精度分析。必须始终结合目标材料的地球化学和地质学来考虑使用 LIBS。
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引用次数: 0
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