Zijuan Hu, Chongyuan Zhang, Lei Zhang, Derek Elsworth, Fengshou Zhang, Quan Gan, Huiru Lei, Manchao He, Leihua Yao
As a particularly common mineral in granites, the presence of feldspar and feldspar-chlorite gouges at hydrothermal conditions has important implications in fault strength and reactivation. We present laboratory observations of frictional strength and stability of feldspar (K-feldspar and albite) and feldspar-chlorite gouges under conditions representative of deep geothermal reservoirs to evaluate the impact on fault stability. Velocity-stepping experiments are performed at a confining stress of 95 MPa, pore pressures of 35–90 MPa, and temperatures of 120–400°C representative of in situ conditions for such reservoirs. Our experiment results indicate that the feldspar gouge exhibits strong friction (μ ∼ 0.71) at all experimental temperatures (∼120–400°C) but when T > 120°C, the frictional response transitions from velocity-strengthening to slightly velocity-weakening. At constant confining pressure and temperature, increasing the pore pressure increases the friction coefficient (∼0.70–0.85) and the gouge remains slightly velocity weakening. The presence of alteration-sourced chlorite leads to a transition from velocity weakening to velocity strengthening in the mixed gouge at experimental temperatures and pore pressures. As a ubiquitous mineral in reservoir rocks, feldspar is shown to potentially contribute to unstable sliding over ranges in temperature and pressure typical in deep hydrothermal reservoirs. These findings emphasize that feldspar minerals may increase the potential for injection-induced seismicity on pre-existing faults if devoid of chloritization.
{"title":"Frictional Properties of Feldspar-Chlorite Gouges and Implications for Fault Reactivation in Hydrothermal Systems","authors":"Zijuan Hu, Chongyuan Zhang, Lei Zhang, Derek Elsworth, Fengshou Zhang, Quan Gan, Huiru Lei, Manchao He, Leihua Yao","doi":"10.1029/2023EA003492","DOIUrl":"10.1029/2023EA003492","url":null,"abstract":"<p>As a particularly common mineral in granites, the presence of feldspar and feldspar-chlorite gouges at hydrothermal conditions has important implications in fault strength and reactivation. We present laboratory observations of frictional strength and stability of feldspar (K-feldspar and albite) and feldspar-chlorite gouges under conditions representative of deep geothermal reservoirs to evaluate the impact on fault stability. Velocity-stepping experiments are performed at a confining stress of 95 MPa, pore pressures of 35–90 MPa, and temperatures of 120–400°C representative of in situ conditions for such reservoirs. Our experiment results indicate that the feldspar gouge exhibits strong friction (<i>μ</i> ∼ 0.71) at all experimental temperatures (∼120–400°C) but when <i>T</i> > 120°C, the frictional response transitions from velocity-strengthening to slightly velocity-weakening. At constant confining pressure and temperature, increasing the pore pressure increases the friction coefficient (∼0.70–0.85) and the gouge remains slightly velocity weakening. The presence of alteration-sourced chlorite leads to a transition from velocity weakening to velocity strengthening in the mixed gouge at experimental temperatures and pore pressures. As a ubiquitous mineral in reservoir rocks, feldspar is shown to potentially contribute to unstable sliding over ranges in temperature and pressure typical in deep hydrothermal reservoirs. These findings emphasize that feldspar minerals may increase the potential for injection-induced seismicity on pre-existing faults if devoid of chloritization.</p>","PeriodicalId":54286,"journal":{"name":"Earth and Space Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2023EA003492","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141847410","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ci-Jian Yang, Jens M. Turowski, Qi Zhou, Ron Nativ, Hui Tang, Jui-Ming Chang, Wen-Sheng Chen
Bedload transport is a natural process that strongly affects the Earth's surface system. An important component of quantifying bedload transport flux and establishing early warning systems is the identification of the onset of bedload motion. Bedload transport can be monitored with high temporal resolution using passive acoustic methods, for example, hydrophones. Yet, an efficient method for identifying the onset of bedload transport from long-term continuous acoustic data is still lacking. Benford's Law defines a probability distribution of the first-digit of data sets and has been used to identify anomalies. Here, we apply Benford's law to continuous acoustic recordings from Baiyang hydrometric station, a tributary of Liwu River, Taroko National Park, Taiwan at the frequency of 32 kHz from stationary hydrophones deployed for 3 years since 2019. We construct a workflow to parse sound combinations of bedload transportation and analyze them in the context of hydrometric sensing constraining the onset, and recession of bedload transport. We identified three separate sound classes in the data related to the noise produced by the motion of pebbles, water flow, and air. We identify two bedload transport events that lasted 17 and 45 hr, respectively, covering about 0.35% of the total recorded time. The workflow could be transferred to other different catchments, events, or data sets. Due to the influence of instrument and background noise on the regularity of the residuals of the first-digit, we recommend identifying the first-digit distribution of the background noise and ruling it out before implementing this workflow.
{"title":"Measuring Bedload Motion Time at Second Resolution Using Benford's Law on Acoustic Data","authors":"Ci-Jian Yang, Jens M. Turowski, Qi Zhou, Ron Nativ, Hui Tang, Jui-Ming Chang, Wen-Sheng Chen","doi":"10.1029/2023EA003416","DOIUrl":"10.1029/2023EA003416","url":null,"abstract":"<p>Bedload transport is a natural process that strongly affects the Earth's surface system. An important component of quantifying bedload transport flux and establishing early warning systems is the identification of the onset of bedload motion. Bedload transport can be monitored with high temporal resolution using passive acoustic methods, for example, hydrophones. Yet, an efficient method for identifying the onset of bedload transport from long-term continuous acoustic data is still lacking. Benford's Law defines a probability distribution of the first-digit of data sets and has been used to identify anomalies. Here, we apply Benford's law to continuous acoustic recordings from Baiyang hydrometric station, a tributary of Liwu River, Taroko National Park, Taiwan at the frequency of 32 kHz from stationary hydrophones deployed for 3 years since 2019. We construct a workflow to parse sound combinations of bedload transportation and analyze them in the context of hydrometric sensing constraining the onset, and recession of bedload transport. We identified three separate sound classes in the data related to the noise produced by the motion of pebbles, water flow, and air. We identify two bedload transport events that lasted 17 and 45 hr, respectively, covering about 0.35% of the total recorded time. The workflow could be transferred to other different catchments, events, or data sets. Due to the influence of instrument and background noise on the regularity of the residuals of the first-digit, we recommend identifying the first-digit distribution of the background noise and ruling it out before implementing this workflow.</p>","PeriodicalId":54286,"journal":{"name":"Earth and Space Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2023EA003416","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141851292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lori Magruder, Ann Rackley Reese, Aimée Gibbons, James Dietrich, Tom Neumann
The ICESat-2 (Ice, Cloud and Land Elevation Satellite-2) photon-counting laser altimeter technology required the design and development of very sophisticated onboard algorithms to collect, store and downlink the observations. These algorithms utilize both software and hardware solutions for meeting data volume requirements and optimizing the science achievable via ICESat-2 measurements. Careful planning and dedicated development were accomplished during the pre-launch phase of the mission in preparation for the 2018 launch. Once on-orbit all of the systems and subsystems were evaluated for performance, including the receiver algorithms, to ensure compliance with mission standards and satisfy the mission science objectives. As the mission has progressed and the instrument performance and data volumes were better understood, there have been several opportunities to enhance ICESat-2's contributions to Earth observation science initiated by NASA and the ICESat-2 science community. We highlight multiple updates to the flight receiver algorithms, the onboard software for signal processing, that have extended ICESat-2's data capabilities and allowed for advanced science applications beyond the original mission objectives.
{"title":"ICESat-2 Onboard Flight Receiver Algorithms: On-Orbit Parameter Updates the Impact on Science Driven Observations","authors":"Lori Magruder, Ann Rackley Reese, Aimée Gibbons, James Dietrich, Tom Neumann","doi":"10.1029/2024EA003551","DOIUrl":"10.1029/2024EA003551","url":null,"abstract":"<p>The ICESat-2 (Ice, Cloud and Land Elevation Satellite-2) photon-counting laser altimeter technology required the design and development of very sophisticated onboard algorithms to collect, store and downlink the observations. These algorithms utilize both software and hardware solutions for meeting data volume requirements and optimizing the science achievable via ICESat-2 measurements. Careful planning and dedicated development were accomplished during the pre-launch phase of the mission in preparation for the 2018 launch. Once on-orbit all of the systems and subsystems were evaluated for performance, including the receiver algorithms, to ensure compliance with mission standards and satisfy the mission science objectives. As the mission has progressed and the instrument performance and data volumes were better understood, there have been several opportunities to enhance ICESat-2's contributions to Earth observation science initiated by NASA and the ICESat-2 science community. We highlight multiple updates to the flight receiver algorithms, the onboard software for signal processing, that have extended ICESat-2's data capabilities and allowed for advanced science applications beyond the original mission objectives.</p>","PeriodicalId":54286,"journal":{"name":"Earth and Space Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024EA003551","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141842241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Elise M. B. Olson, Jasmin G. John, John P. Dunne, Charles Stock, Elizabeth J. Drenkard, Adrienne J. Sutton
Global Earth system models are often enlisted to assess the impacts of climate variability and change on marine ecosystems. In this study, we compare high frequency (daily) outputs of potential ecosystem stressors, such as sea surface temperature and surface pH, and associated variables from an Earth system model (GFDL ESM4.1) with high frequency time series from a global network of moorings to directly assess the capacity of the model to resolve local biogeochemical variability on time scales from daily to interannual. Our analysis indicates variability in surface temperature is most consistent between ESM4.1 and observations, with a Pearson correlation coefficient of 0.93 and bias of 0.40°C, followed by variability in surface salinity. Physical variability is reproduced with greater accuracy than biogeochemical variability, and variability on seasonal and longer time scales is more consistent between the model and observations than higher frequency variability. At the same time, the well-resolved seasonal and longer timescale variability is a reasonably good predictor, in many cases, of the likelihood of extreme events. Despite limited model representation of high frequency variability, model and observation-based assessments of the fraction of days experiencing surface T-pH and T-Ωarag multistressor conditions show reasonable agreement, depending on the stressor combination and threshold definition. We also identify circumstances in which some errors could be reduced by accounting for model biases.
{"title":"Site-Specific Multiple Stressor Assessments Based on High Frequency Surface Observations and an Earth System Model","authors":"Elise M. B. Olson, Jasmin G. John, John P. Dunne, Charles Stock, Elizabeth J. Drenkard, Adrienne J. Sutton","doi":"10.1029/2023EA003357","DOIUrl":"10.1029/2023EA003357","url":null,"abstract":"<p>Global Earth system models are often enlisted to assess the impacts of climate variability and change on marine ecosystems. In this study, we compare high frequency (daily) outputs of potential ecosystem stressors, such as sea surface temperature and surface pH, and associated variables from an Earth system model (GFDL ESM4.1) with high frequency time series from a global network of moorings to directly assess the capacity of the model to resolve local biogeochemical variability on time scales from daily to interannual. Our analysis indicates variability in surface temperature is most consistent between ESM4.1 and observations, with a Pearson correlation coefficient of 0.93 and bias of 0.40°C, followed by variability in surface salinity. Physical variability is reproduced with greater accuracy than biogeochemical variability, and variability on seasonal and longer time scales is more consistent between the model and observations than higher frequency variability. At the same time, the well-resolved seasonal and longer timescale variability is a reasonably good predictor, in many cases, of the likelihood of extreme events. Despite limited model representation of high frequency variability, model and observation-based assessments of the fraction of days experiencing surface T-pH and T-Ω<sub><i>arag</i></sub> multistressor conditions show reasonable agreement, depending on the stressor combination and threshold definition. We also identify circumstances in which some errors could be reduced by accounting for model biases.</p>","PeriodicalId":54286,"journal":{"name":"Earth and Space Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2023EA003357","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141840910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Chih-Ting Hsu, Tomoko Matsuo, Helen Kershaw, Nicholas Dietrich, Marlee Smith, Jeffrey Anderson, Katherine Garcia-Sage, Jia Yue, Yuta Hozumi, Min-Yang Chou
Observing System Simulation Experiments (OSSEs) provide an effective way to evaluate the impact of assimilating data from a specific observing system on hindcasting, nowcasting, and forecasting of environmental systems. The NSF NCAR's Data Assimilation (DA) Research Testbed/Thermosphere-Ionosphere-Electrodynamics General Circulation Model (DART/TIEGCM) tool, to be hosted at the NASA Community Coordinated Modeling Center, serves as a valuable and accessible community resource for quantitatively evaluating the impact of observations from both current and future ionosphere-thermosphere (IT) observing systems. This study demonstrates the utility of DART/TIEGCM as an IT OSSE tool, using synthetic observations simulated using a currently planned NASA Geospace Dynamics Constellation (GDC) observing system design. Five sets of OSSEs are carried out to compare the effects of assimilating various combinations of prospective GDC observations (e.g., neutral temperature, neutral wind, neutral composition, atomic oxygen ion density, and ion and electron temperature) during a major geomagnetic storm period of the St Patrick's Day Storm on 17 March 2013. The maximum error reduction in neutral temperature and atomic ion oxygen density is 24.6% and 43.3% compared to the control experiment. These OSSEs indicate the benefits of coupled IT DA approaches implemented in DART/TIEGCM to maximize the impact of multi-parameter IT observations, such as those expected from the GDC mission. Although more work is required to draw any definitive conclusion on the GDC data impact, the study provides an illustrative example of how the DART/TIEGCM community tool can be used to evaluate observational impacts of planned or existing missions for geospace research and applications.
观测系统模拟实验(OSSE)是评估从特定观测系统吸收数据对环境系统的后报、现报和预报的影响的有效方法。美国国家科学基金会 NCAR 的数据同化(DA)研究试验台/热层-电离层-电动力学大气环流模式(DART/TIEGCM)工具将由 NASA 社区协调建模中心托管,是定量评估当前和未来电离层-热层(IT)观测系统观测结果影响的宝贵且可访问的社区资源。本研究利用目前计划中的 NASA Geospace Dynamics Constellation (GDC) 观测系统设计模拟的合成观测结果,展示了 DART/TIEGCM 作为 IT OSSE 工具的实用性。在 2013 年 3 月 17 日圣帕特里克节风暴的主要地磁暴期间,进行了五组 OSSE,以比较同化各种预期 GDC 观测组合(如中性温度、中性风、中性成分、原子氧离子密度以及离子和电子温度)的效果。与对照实验相比,中性温度和原子氧离子密度的最大误差分别减少了 24.6% 和 43.3%。这些 OSSE 表明了在 DART/TIEGCM 中实施的耦合 IT DA 方法的好处,可以最大限度地发挥多参数 IT 观测的影响,例如 GDC 任务的预期影响。虽然还需要做更多的工作才能对 GDC 数据的影响得出明确的结论,但这项研究提供了一个示例,说明如何利用 DART/TIEGCM 社区工具来评估计划中或现有任务对地球空间研究和应用的观测影响。
{"title":"A Community Ionosphere-Thermosphere Observing System Simulation Experiment (OSSE) Tool: Geospace Dynamics Constellation Example","authors":"Chih-Ting Hsu, Tomoko Matsuo, Helen Kershaw, Nicholas Dietrich, Marlee Smith, Jeffrey Anderson, Katherine Garcia-Sage, Jia Yue, Yuta Hozumi, Min-Yang Chou","doi":"10.1029/2024EA003684","DOIUrl":"10.1029/2024EA003684","url":null,"abstract":"<p>Observing System Simulation Experiments (OSSEs) provide an effective way to evaluate the impact of assimilating data from a specific observing system on hindcasting, nowcasting, and forecasting of environmental systems. The NSF NCAR's Data Assimilation (DA) Research Testbed/Thermosphere-Ionosphere-Electrodynamics General Circulation Model (DART/TIEGCM) tool, to be hosted at the NASA Community Coordinated Modeling Center, serves as a valuable and accessible community resource for quantitatively evaluating the impact of observations from both current and future ionosphere-thermosphere (IT) observing systems. This study demonstrates the utility of DART/TIEGCM as an IT OSSE tool, using synthetic observations simulated using a currently planned NASA Geospace Dynamics Constellation (GDC) observing system design. Five sets of OSSEs are carried out to compare the effects of assimilating various combinations of prospective GDC observations (e.g., neutral temperature, neutral wind, neutral composition, atomic oxygen ion density, and ion and electron temperature) during a major geomagnetic storm period of the St Patrick's Day Storm on 17 March 2013. The maximum error reduction in neutral temperature and atomic ion oxygen density is 24.6% and 43.3% compared to the control experiment. These OSSEs indicate the benefits of coupled IT DA approaches implemented in DART/TIEGCM to maximize the impact of multi-parameter IT observations, such as those expected from the GDC mission. Although more work is required to draw any definitive conclusion on the GDC data impact, the study provides an illustrative example of how the DART/TIEGCM community tool can be used to evaluate observational impacts of planned or existing missions for geospace research and applications.</p>","PeriodicalId":54286,"journal":{"name":"Earth and Space Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024EA003684","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141842878","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Amy E. East, Joshua B. Logan, Helen W. Dow, Douglas P. Smith, Pat Iampietro, Jonathan A. Warrick, Thomas D. Lorenson, Leticia Hallas, Benjamin Kozlowicz
In a warming climate, an intensifying fire regime and higher likelihood of extreme rain are expected to increase watershed sediment yield in many regions. Understanding regional variability in landscape response to fire and post-fire rainfall is essential for managing water resources and infrastructure. We measured sediment yield resulting from sequential wildfire and extreme rain and flooding in the upper Carmel River watershed (116 km2), on the central California coast, USA, using changes in sediment volume mapped in a reservoir. We determined that the sediment yield after fire and post-fire flooding was 854–1,100 t/km2/yr, a factor of 3.5–4.6 greater than the long-term yield from this watershed and more than an order of magnitude greater than during severe drought conditions. In this first large-scale field validation test of the WEPPcloud/wepppy framework for the Water Erosion Prediction Project (WEPP) model on a burned landscape, WEPP predicted 81%–106% of the measured sediment yield. These findings will facilitate assessing and predicting future fire effects in steep watersheds with a Mediterranean climate and indicate that the increasingly widespread use of WEPP is appropriate for evaluating post-fire hillslope erosion even across 100-km2 scales under conditions without debris flows.
{"title":"Post-Fire Sediment Yield From a Central California Watershed: Field Measurements and Validation of the WEPP Model","authors":"Amy E. East, Joshua B. Logan, Helen W. Dow, Douglas P. Smith, Pat Iampietro, Jonathan A. Warrick, Thomas D. Lorenson, Leticia Hallas, Benjamin Kozlowicz","doi":"10.1029/2024EA003575","DOIUrl":"https://doi.org/10.1029/2024EA003575","url":null,"abstract":"<p>In a warming climate, an intensifying fire regime and higher likelihood of extreme rain are expected to increase watershed sediment yield in many regions. Understanding regional variability in landscape response to fire and post-fire rainfall is essential for managing water resources and infrastructure. We measured sediment yield resulting from sequential wildfire and extreme rain and flooding in the upper Carmel River watershed (116 km<sup>2</sup>), on the central California coast, USA, using changes in sediment volume mapped in a reservoir. We determined that the sediment yield after fire and post-fire flooding was 854–1,100 t/km<sup>2</sup>/yr, a factor of 3.5–4.6 greater than the long-term yield from this watershed and more than an order of magnitude greater than during severe drought conditions. In this first large-scale field validation test of the WEPPcloud/<i>wepppy</i> framework for the Water Erosion Prediction Project (WEPP) model on a burned landscape, WEPP predicted 81%–106% of the measured sediment yield. These findings will facilitate assessing and predicting future fire effects in steep watersheds with a Mediterranean climate and indicate that the increasingly widespread use of WEPP is appropriate for evaluating post-fire hillslope erosion even across 100-km<sup>2</sup> scales under conditions without debris flows.</p>","PeriodicalId":54286,"journal":{"name":"Earth and Space Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-07-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024EA003575","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141736842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
B. M. S. Giambastiani, N. Greggio, G. Carloni, M. Molducci, M. Antonellini
This study examines the accumulation, distribution, and mobility of Potentially Toxic Elements (PTEs) in the sediments of a low-lying coastal drainage network (Ravenna, Italy). The aim is to understand the geochemical processes occurring between drainage water and canal bed sediments and assess factors affecting and driving PTE distribution and enrichment in these environments. A geochemical database resulting from the analysis of 203 drainage sediment samples was analyzed using Principal Component Analysis and compared to undisturbed near-surface sediment samples from the same depth and depositional environment. The results reveal PTEs exceeding national regulation limits. Distance from the sea, electrical conductivity of drainage water, and fertilizer use were identified as the main driving factors. The primary mechanisms for PTE precipitation (As, Co, Mo) and subsequent enrichment in the sediments is attributed to the absorption on Fe- and Mn-oxyhydroxides (HFO and HMO), particularly in high salinity areas near the coast. While Cu, Zn, Pb, Cr, and V also have affinity for HFO and HMO, their adsorption efficiency decreases due to the competition with salt-derived cations during ongoing salinization processes. Anthropogenic sources, including agriculture, hunting activities, traffic dust, and railways, contribute to the local abundance of other elements (Cr, Ni, Cu, Zn, Pb, and Sn). This paper's significant progress lies in assessing the concurrent interactions of chemical and physical processes that drive PTE distribution and accumulation in reclaimed low-lying coastal plains. The findings are significant for assessing PTE accumulation risks and sediment toxicity in coastal areas affected by water salinization, drainage, and subsidence, providing valuable information to water management institutions globally.
{"title":"Potentially Toxic Elements (PTEs) Distribution in Drainage Canal Sediments of a Low-Lying Coastal Area","authors":"B. M. S. Giambastiani, N. Greggio, G. Carloni, M. Molducci, M. Antonellini","doi":"10.1029/2023EA003145","DOIUrl":"https://doi.org/10.1029/2023EA003145","url":null,"abstract":"<p>This study examines the accumulation, distribution, and mobility of Potentially Toxic Elements (PTEs) in the sediments of a low-lying coastal drainage network (Ravenna, Italy). The aim is to understand the geochemical processes occurring between drainage water and canal bed sediments and assess factors affecting and driving PTE distribution and enrichment in these environments. A geochemical database resulting from the analysis of 203 drainage sediment samples was analyzed using Principal Component Analysis and compared to undisturbed near-surface sediment samples from the same depth and depositional environment. The results reveal PTEs exceeding national regulation limits. Distance from the sea, electrical conductivity of drainage water, and fertilizer use were identified as the main driving factors. The primary mechanisms for PTE precipitation (As, Co, Mo) and subsequent enrichment in the sediments is attributed to the absorption on Fe- and Mn-oxyhydroxides (HFO and HMO), particularly in high salinity areas near the coast. While Cu, Zn, Pb, Cr, and V also have affinity for HFO and HMO, their adsorption efficiency decreases due to the competition with salt-derived cations during ongoing salinization processes. Anthropogenic sources, including agriculture, hunting activities, traffic dust, and railways, contribute to the local abundance of other elements (Cr, Ni, Cu, Zn, Pb, and Sn). This paper's significant progress lies in assessing the concurrent interactions of chemical and physical processes that drive PTE distribution and accumulation in reclaimed low-lying coastal plains. The findings are significant for assessing PTE accumulation risks and sediment toxicity in coastal areas affected by water salinization, drainage, and subsidence, providing valuable information to water management institutions globally.</p>","PeriodicalId":54286,"journal":{"name":"Earth and Space Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2023EA003145","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141732547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shuqi Lin, Donald C. Pierson, Robert Ladwig, Benjamin M. Kraemer, Fenjuan R. S. Hu
As a key water quality parameter, dissolved oxygen (DO) concentration, and particularly changes in bottom water DO is fundamental for understanding the biogeochemical processes in lake ecosystems. Based on two machine learning (ML) models, Gradient Boost Regressor (GBR) and long-short-term-memory (LSTM) network, this study developed three ML model approaches: direct GBR; direct LSTM; and a 2-step mixed ML model workflow combining both GBR and LSTM. They were used to simulate multi-year surface and bottom DO concentrations in five lakes. All approaches were trained with readily available environmental data as predictors. Indices of lake thermal structure and mixing provided by a one-dimensional (1-D) hydrodynamic model were also included as predictors in the ML models. The advantages of each ML approach were not consistent for all the tested lakes, but the best one of them was defined that can estimate DO concentration with coefficient of determination (R2) up to 0.6–0.7 in each lake. All three approaches have normalized mean absolute error (NMAE) under 0.15. In a polymictic lake, the 2-step mixed model workflow showed better representation of bottom DO concentrations, with a highest true positive rate (TPR) of hypolimnetic hypoxia detection of over 90%, while the other workflows resulted in, TPRs are around 50%. In most of the tested lakes, the predicted surface DO concentrations and variables indicating stratified conditions (i.e., Wedderburn number and the temperature difference between surface and bottom water) are essential for simulating bottom DO. The ML approaches showed promising results and could be used to support short- and long-term water management plans.
溶解氧(DO)浓度,尤其是底层水溶解氧的变化是了解湖泊生态系统生物地球化学过程的关键水质参数。基于梯度提升回归模型(GBR)和长短期记忆网络(LSTM)这两种机器学习(ML)模型,本研究开发了三种 ML 模型方法:直接 GBR;直接 LSTM;以及结合 GBR 和 LSTM 的两步混合 ML 模型工作流。这些方法被用于模拟五个湖泊的多年表层和底层溶解氧浓度。所有方法都使用现成的环境数据作为预测因子进行训练。由一维(1-D)水动力模型提供的湖泊热结构和混合指数也作为预测因子纳入了 ML 模型。在所有测试的湖泊中,每种 ML 方法的优势并不一致,但其中最好的一种方法可以估算出每个湖泊的溶解氧浓度,其判定系数(R2)可达 0.6-0.7。所有三种方法的归一化平均绝对误差(NMAE)均小于 0.15。在一个多水体湖泊中,两步混合模型工作流程能更好地反映湖底溶解氧浓度,下沉缺氧检测的最高真阳性率(TPR)超过 90%,而其他工作流程的真阳性率约为 50%。在大多数测试湖泊中,预测的表层溶解氧浓度和表明分层条件的变量(即 Wedderburn 数和表层与底层水之间的温差)对于模拟底层溶解氧至关重要。ML 方法显示出良好的效果,可用于支持短期和长期的水管理计划。
{"title":"Multi-Model Machine Learning Approach Accurately Predicts Lake Dissolved Oxygen With Multiple Environmental Inputs","authors":"Shuqi Lin, Donald C. Pierson, Robert Ladwig, Benjamin M. Kraemer, Fenjuan R. S. Hu","doi":"10.1029/2023EA003473","DOIUrl":"https://doi.org/10.1029/2023EA003473","url":null,"abstract":"<p>As a key water quality parameter, dissolved oxygen (DO) concentration, and particularly changes in bottom water DO is fundamental for understanding the biogeochemical processes in lake ecosystems. Based on two machine learning (ML) models, Gradient Boost Regressor (GBR) and long-short-term-memory (LSTM) network, this study developed three ML model approaches: direct GBR; direct LSTM; and a 2-step mixed ML model workflow combining both GBR and LSTM. They were used to simulate multi-year surface and bottom DO concentrations in five lakes. All approaches were trained with readily available environmental data as predictors. Indices of lake thermal structure and mixing provided by a one-dimensional (1-D) hydrodynamic model were also included as predictors in the ML models. The advantages of each ML approach were not consistent for all the tested lakes, but the best one of them was defined that can estimate DO concentration with coefficient of determination (<i>R</i><sup>2</sup>) up to 0.6–0.7 in each lake. All three approaches have normalized mean absolute error (NMAE) under 0.15. In a polymictic lake, the 2-step mixed model workflow showed better representation of bottom DO concentrations, with a highest true positive rate (TPR) of hypolimnetic hypoxia detection of over 90%, while the other workflows resulted in, TPRs are around 50%. In most of the tested lakes, the predicted surface DO concentrations and variables indicating stratified conditions (i.e., Wedderburn number and the temperature difference between surface and bottom water) are essential for simulating bottom DO. The ML approaches showed promising results and could be used to support short- and long-term water management plans.</p>","PeriodicalId":54286,"journal":{"name":"Earth and Space Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2023EA003473","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141730321","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Iris Thurnherr, Harald Sodemann, Tim Trent, Martin Werner, Hartmut Bösch
Satellite observations of column-averaged water isotopes are relatively new retrieval products that are in need of further in situ evaluation. Such evaluation studies are generally difficult to perform due to the wide mismatch in temporal and spatial scales between the satellite observations based on instantaneous pixel averages during an overpass and airborne in situ measurements ranging up to several hours over a km-scale. In addition, topography, weather conditions and in particular cloudiness impose severe constraints on an exact collocation between satellite and airborne in situ measurement platforms. Here we present a new method that allows a comparison between in situ measurements and satellite observations of δD on a broader statistical basis. We use regional isotope-enabled model simulations as intermediate information to identify the area for best comparisons. Applying our methodology to TROPOMI total column δD retrievals for the L-WAIVE campaign in Annecy, France, during June 2019 increases the number of satellite pixels for comparison despite widespread cloudiness on average by a factor of 20. In addition, the comparison of simulated and observed δD revealed a dependency of the satellite evaluation on the structure of the middle and upper troposphere. We conclude that our method provides a more robust statistic basis for in situ evaluation of δD satellite retrievals. The method will thus be useful in planning and executing forthcoming validation and evaluation campaigns, and can potentially be used for the evaluation of other satellite products.
{"title":"Evaluating TROPOMI δD Column Retrievals With In Situ Airborne Field Campaign Measurements Using Expanded Collocation Criterion","authors":"Iris Thurnherr, Harald Sodemann, Tim Trent, Martin Werner, Hartmut Bösch","doi":"10.1029/2023EA003400","DOIUrl":"https://doi.org/10.1029/2023EA003400","url":null,"abstract":"<p>Satellite observations of column-averaged water isotopes are relatively new retrieval products that are in need of further in situ evaluation. Such evaluation studies are generally difficult to perform due to the wide mismatch in temporal and spatial scales between the satellite observations based on instantaneous pixel averages during an overpass and airborne in situ measurements ranging up to several hours over a km-scale. In addition, topography, weather conditions and in particular cloudiness impose severe constraints on an exact collocation between satellite and airborne in situ measurement platforms. Here we present a new method that allows a comparison between in situ measurements and satellite observations of <i>δ</i>D on a broader statistical basis. We use regional isotope-enabled model simulations as intermediate information to identify the area for best comparisons. Applying our methodology to TROPOMI total column <i>δ</i>D retrievals for the L-WAIVE campaign in Annecy, France, during June 2019 increases the number of satellite pixels for comparison despite widespread cloudiness on average by a factor of 20. In addition, the comparison of simulated and observed <i>δ</i>D revealed a dependency of the satellite evaluation on the structure of the middle and upper troposphere. We conclude that our method provides a more robust statistic basis for in situ evaluation of <i>δ</i>D satellite retrievals. The method will thus be useful in planning and executing forthcoming validation and evaluation campaigns, and can potentially be used for the evaluation of other satellite products.</p>","PeriodicalId":54286,"journal":{"name":"Earth and Space Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2023EA003400","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141730211","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This study evaluates the coded aperture imaging method for pitch angle observations of magnetospheric energetic electrons in the solar, Earth, and planetary space environments. We present a review of key previous energetic electron instruments with pitch angle-resolved observations across a range of electron energies. We describe the coded aperture imaging method, typically used for high angular resolution X-ray and gamma ray observations, and evaluate design parameters in the context of energetic electron observations. We present the results of simulations of energetic electrons in Geant4 and evaluate the method's ability to resolve sources with high angular and temporal resolution. We also evaluate the impact of secondary radiation produced from electron interactions in the tungsten coded aperture, as well as the impact of artifacts from the decoding process. With these simulated results, we identify key areas in magnetospheric science that would benefit from high angular resolution observations of energetic electrons. We find that coded aperture imaging may be well-suited for high-resolution observations of intense localized structures, such as low energy (tens of eV to several keV) field-aligned electron beams or the electron strahl wind.
本研究评估了在太阳、地球和行星空间环境中对磁层高能电子进行俯仰角观测的编码孔径成像方法。我们回顾了以往在电子能量范围内进行俯仰角分辨观测的主要高能电子仪器。我们介绍了通常用于高角度分辨率 X 射线和伽马射线观测的编码孔径成像方法,并结合高能电子观测对设计参数进行了评估。我们介绍了在 Geant4 中模拟高能电子的结果,并评估了该方法以高角度和时间分辨率分辨源的能力。我们还评估了钨编码孔径中电子相互作用产生的二次辐射的影响,以及解码过程中产生的伪影的影响。通过这些模拟结果,我们确定了磁层科学中将受益于高能电子高角度分辨率观测的关键领域。我们发现,编码孔径成像可能非常适合于高分辨率观测高能局部结构,如低能量(几十 eV 到几 keV)场对齐电子束或电子斯特拉风。
{"title":"Coded Aperture Imaging for Electron Pitch Angle Observations","authors":"Riley A. Reid, Grant Berland, Robert Marshall","doi":"10.1029/2024EA003641","DOIUrl":"https://doi.org/10.1029/2024EA003641","url":null,"abstract":"<p>This study evaluates the coded aperture imaging method for pitch angle observations of magnetospheric energetic electrons in the solar, Earth, and planetary space environments. We present a review of key previous energetic electron instruments with pitch angle-resolved observations across a range of electron energies. We describe the coded aperture imaging method, typically used for high angular resolution X-ray and gamma ray observations, and evaluate design parameters in the context of energetic electron observations. We present the results of simulations of energetic electrons in Geant4 and evaluate the method's ability to resolve sources with high angular and temporal resolution. We also evaluate the impact of secondary radiation produced from electron interactions in the tungsten coded aperture, as well as the impact of artifacts from the decoding process. With these simulated results, we identify key areas in magnetospheric science that would benefit from high angular resolution observations of energetic electrons. We find that coded aperture imaging may be well-suited for high-resolution observations of intense localized structures, such as low energy (tens of eV to several keV) field-aligned electron beams or the electron strahl wind.</p>","PeriodicalId":54286,"journal":{"name":"Earth and Space Science","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1029/2024EA003641","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141730200","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}