Environmental Science and Pollution Research最新文献

Given the increasing concern about chemical exposure from textiles, our study examines the risks of dermal exposure to bisphenol A (BPA), bisphenol S (BPS), bisphenol B (BPB) and bisphenol F (BPF) from conventional and recycled textiles for adults, aiming to obtain new data, assess exposure, and evaluate the impact of washing on bisphenol levels. A total of 57 textile samples (33 from recycled and 24 from conventional material) were subjected to ultrasound-assisted extraction (UAE) followed by ultra-high performance liquid chromatography with tandem mass spectrometry analysis (UHPLC-MS/MS). The BPA and BPS concentrations varied widely (BPA: < 0.050 to 625 ng/g, BPS: 0.277-2,474 ng/g). The median BPA content in recycled textiles (13.5 ng/g) was almost twice as high as that of 7.66 ng/g in conventional textiles. BPS showed a median of 1.85 ng/g in recycled textiles and 3.42 ng/g in conventional textiles, indicating a shift from BPA to BPS in manufacturing practices. Simulated laundry experiments showed an overall reduction in bisphenols concentrations after washing. The study also assessed potential health implications via dermal exposure to dry and sweat-wet textiles compared to a tolerable daily intake (TDI) of 0.2 ng/kg bw/day for BPA set by the European Food Safety Authority (EFSA). Exposure from dry textiles remained below this threshold, while exposure from wet textiles often exceeded it, indicating an increased risk under conditions that simulate sweating or humidity. By finding the widespread presence of bisphenols in textiles, our study emphasises the importance of being aware of the potential risks associated with recycling materials as well as the benefits.

In the study, the structural parameters of Zichang (ZC) coking coal from northern Shaanxi Province were examined. A theoretical calculation was employed to build a molecular structure model for ZC coal, as well as applying principles of quantum chemistry, the prediction of NMR spectrogram and density for the model was achieved, and the molecular chemical formula was C₁₉₉H₁₅₅O₃₆N₃. The molecular structure optimization and annealing kinetics calculations are based on molecular mechanics (MM) and molecular dynamics (MD). Subsequently, a representative simplified model was constructed using the aromatic structure as the fundamental unit. On this foundation, the electrostatic potential (ESP), atomic charge distribution, and energy level orbitals were analyzed for this simplified model. The outcomes of this research can serve as an essential guide for determining the reaction order of the active categories during the low-temperature oxidation process for ZC coking coal.

Studying the links between environmental pollution and the levels of contamination in food is an important challenge to ensure human health. Matched samples of eggs from free-range hens and vegetables were analysed to investigate the bioaccumulation of PCDD/Fs, PCBs, metals and rare earth elements. Only two egg samples resulted above the limit fixed for PCDD/Fs and the action level set for DL-PCBs. The highest concentrations were found in the eggs from an area situated in a big city affected by strong urbanisation. Although eggs and vegetables were subjected to the same environmental pollution, the PCDD/F and PCB bioaccumulation that occurred in the eggs was much higher than those in vegetables (p < 0.01). In vegetables, the highest PCDD/F and PCB concentrations were found in lettuce and potatoes grown on contaminated soil. Higher bioaccumulation of Fe and Zn occurred in eggs compared to vegetables; La, Pr, Nd, Sm and Eu were found only in lettuce samples. The results of this study may provide important data useful in the risk assessment of human exposure through diet in accidents involving dangerous chemicals. Furthermore, the estimated weekly intakes calculated for PCDD/Fs and PCBs highlighted that, although vegetables accumulate very low concentrations of these contaminants, they contribute more than eggs to human exposure.

Dibutyl phthalate (DBP) is a phthalic compound and is most commonly used as a plasticizer in the polymer industry. It affects the hypothalamus-pituitary-gonadal axis and produces infertility in exposed animals. A total of 366 adult male zebrafish were used to evaluate the toxicological effects of DBP in testes following continuous exposure for 28 days. To evaluate histological changes during phase I of the study, 30 zebrafish were equally divided into five groups viz., control (RO water), vehicle control (0.01% DMSO), T0 (250 µg/L of water), T1 (500 µg/L of water), and T2 group (1000 µg/L of water). The protocol for phase II of the study was decided based on the results of phase I of the study. During phase II, for evaluation of oxidative stress parameters and gene expression profile, a total of 336 fish were equally divided into four groups viz., control, vehicle control, T1 (500 µg/L of water), and T2 (1000 µg/L of water). The activity of SOD, CAT, and TAC was significantly lower in zebrafish from the T2 group; however, a significantly increased level of MDA in the T2 group was recorded as compared to control groups. mRNA expression profile of sod, cat, and nrf2 genes was significantly downregulated in the T2 group as compared to the control group. Histopathology and proliferating cell nuclear antigen immunostaining revealed a reduction in spermatozoa with increased spermatocytes and spermatogonia in testes from T1 and T2 groups. The result indicated that DBP can induce oxidative stress and affect spermatogenesis in zebrafish testes.

The extensive use of pharmaceuticals has increased their presence in the environment, posing significant ecological and public health concerns. The current study reports the magnetic nanocomposite (M-ABAC) synthesis using the algal-bacterial sludge as the precursor for activated carbon and evaluates its potential in fluoroquinolone antibiotics removal. The activated carbon from algal-bacterial sludge was composited with Fe₃O₄ nanoparticles using the co-precipitation method. The M-ABAC was characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX), Brunauer-Emmett-Teller (BET) analysis, and vibrating sample magnetometry (VSM). M-ABAC was employed for antibiotic ciprofloxacin (CIP) removal by combined adsorption and heterogenous Fenton degradation. The adsorption studies reveal that the Langmuir isotherm best fits the experimental data, with a maximum adsorption capacity of 81.6 mg/g. Pseudo-second-order kinetic model well describes adsorption kinetics. Fenton catalytic degradation was performed using H₂O₂ as the activating agent. The optimal H₂O₂ dosage was observed to be 10 mM. A CIP adsorptive removal efficiency of 75% was observed at 2 g/L dosage of M-ABAC in a 200 ppm CIP solution. Simultaneous adsorption and Fenton catalytic degradation further enhanced the removal efficiency to 92%. Radical scavengers experiment revealed that the hydroxyl radical (•OH) was the dominant reactive oxidation species. The degradation products of the CIP were identified using liquid chromatography quadrupole time-of-flight mass spectroscopy (LC-QTOF-MS). The possible CIP degradation mechanisms include decarboxylation, piperazine moiety degradation, defluorination, and hydroxylation.

Under regulations such as REACH, testing of novel and established compounds for their (neuro)toxic potential is a legal requirement in many countries. These are largely based on animal-, cost-, and time-intensive in vivo models, not in line with the 3 Rs' principle of animal experimentation. Thus, the development of alternative test methods has also received increasing attention in neurotoxicology. Such methods focus either on physiological alterations in brain development and neuronal pathways or on behavioral changes. An example of a behavioral developmental neurotoxicity (DNT) assay is the zebrafish (Danio rerio) embryo coiling assay, which quantifies effects of compounds on the development of spontaneous movement of zebrafish embryos. While the importance of embryo-to-embryo contact prior to hatching in response to environmental contaminants or natural threats has been documented for many other clutch-laying fish species, little is known about the relevance of intra-clutch contacts for zebrafish. Here, the model neurotoxin rotenone was used to assess the effect of grouped versus separate rearing of the embryos on the expression of the coiling behavior. Some group-reared embryos reacted with hyperactivity to the exposure, to an extent that could not be recorded effectively with the utilized software. Separately reared embryos showed reduced activity, compared with group-reared individuals when assessing. However, even the control group embryos of the separately reared cohort showed reduced activity, compared with group-reared controls. Rotenone could thus be confirmed to induce neurotoxic effects in zebrafish embryos, yet modifying one parameter in an otherwise well-established neurotoxicity assay such as the coiling assay may lead to changes in behavior influenced by the proximity between individual embryos. This indicates a complex dependence of the outcome of behavior assays on a multitude of environmental parameters.

This review paper provides a comprehensive examination of energy harvesting technologies tailored for electric vehicles (EVs). Against the backdrop of the automotive industry's rapid evolution towards electrification and sustainability, the paper explores a diverse range of techniques. The analysis encompasses the strengths, weaknesses, applicability in various scenarios, and potential implications for the future of EVs. A key finding of the review highlights regenerative braking as a pivotal and highly efficient method for energy recovery, particularly in urban settings. In addition to extending battery life, regenerative braking significantly boosts energy efficiency of EVs. The paper also delves into the challenges associated with integrated solar energy systems, emphasizing issues related to efficiency and weather dependency. Kinetic energy recovery systems (KERS) are discussed for their substantial power boost during acceleration in both motorsports and road cars. Additionally, the review explores regenerative shock absorbers, which capture energy from suspension movement, enhancing ride comfort and increasing vehicle energy economy, especially on uneven terrain. The piezoelectric system, though intriguing, is found to have low power output from mechanical vibration, prompting further exploration for integration into EVs. However, complexities and cost considerations arise in their integration with the vehicle's suspension system.

The existence of natural organic matter (NOM) causes many problems in drinking water treatment processes. The degradation of different fractions of NOM in drinking water was studied using the ultraviolet/persulfate (UV/PS) process. The NOM was separated into hydrophobic (HPO), transition hydrophilic (TPI) and hydrophilic (HPI) fractions by reverse osmosis and XAD series resins. The effects of degradation were evaluated by dissolved organic carbon (DOC), UV₂₅₄, three-dimensional fluorescence-parallel factor analysis (EEM-PARAFAC), and trihalomethane formation potential (THMFP). The results showed that UV/PS process could remove the three fractions of DOC, UV₂₅₄, as well as the fluorescent components humic acid-like (C1 and C2) and protein-like (C3). The maximum removal rates of DOC of HPO, TPI, and HPI fractions were 34.6%, 38.4%, and 73.9%, respectively, and the maximum removal rates of UV₂₅₄ were 72.1%, 86.3%, and 86.8%, respectively. The removal rate of the three fluorescent components can reach 100%, and C3 is easier to remove than C1 and C2 under the low PS dosage conditions. The order of kinetic degradation rate constant of UV₂₅₄ first-order reaction is HPI > TPI > HPO. The optimum pH conditions for the degradation of HPO, TPI, and HPI fractions were acidic, basic, and neutral, respectively. The specific THMFP of HPO was higher than that of TPI and HPI. The specific THMFP of HPO and TPI fractions increased with the increase of radiation time, while the HPI fraction showed the opposite trend. THMFP has different degrees of correlation with DOC, UV₂₅₄, C1, and C2. This study can provide a theoretical basis for the selection of the UV/PS process for drinking water sources containing NOM with different characteristics.

In the pursuit of sustainability and reduced environmental impact, waste-to-energy conversion methods are gaining importance. This study investigates the untapped potential of air-conditioning (AC) condensate as a source of chilled energy in AC systems of varying cooling capacities expressed in tons of refrigeration (TR) including 10 TR, 25 TR, and 50 TR. Field assessments revealed daily condensate generation of 37-148 L at 15 ± 1 °C, indicating significant cooling potential for energy recovery. Waste coconut oil (WCO) is proposed as a phase change material (PCM) for this purpose, aiming to examine its thermal characteristics and effectiveness for energy storage. Characterization of WCO reveals a latent heat of 101 J/g and a phase transition temperature of 22.1 °C. Thermal degradation occurs between 346 and 462 °C, while stability is maintained below 60 °C. WCO exhibits solid thermal conductivity of 0.181 W/mK at 10 °C and liquid conductivity of 0.175 W/mK at 30 °C, with specific heat capacities of 1.19 J/g K (solid) and 2.43 J/g K (liquid), ensuring efficient heat transfer during phase change. A pilot experiment examines the charging and discharging dynamics of WCO. It achieves complete solidification in 160 min at a freezing temperature of 21.3 °C, with 1.1 °C supercooling. During melting at ambient conditions (32 ± 1 °C), it takes 92 min, with a melting temperature of 21.9 °C. The study extends to evaluate the reduction in environmental impact through life cycle assessment (LCA). The significant impact values such as acidification, eutrophication, ozone depletion, fossil depletion, climate change, and metal depletion are calculated using the ecoinvent database. Overall, our study underscores the promise of WCO-based energy recovery systems in advancing sustainability efforts within the realm of air conditioning.

Heavy metal stress poses a significant threat to the productivity of agricultural systems and human health. Silicon (Si) is widely reported to be very effective against the different heavy metal stresses in crops. According to reports, it can help plants that are under cadmium (Cd) and nickel (Ni) stress. The presented work investigated how silicon interacted in Cd- and Ni-stressed wheat and mitigated metal toxicity. A pot experiment was carried out in which wheat crop was irrigated with Cd- and Ni-contaminated water. Application of Cd and Ni-contaminated water to wheat significantly reduced the root and shoot growth parameters and physiological and biochemical factors while increasing the antioxidant enzymatic activity and bioaccumulation of Cd and Ni metal in shoot and root as compared to the control. Application of Si led to an improvement in physiological parameters, i.e., greenness of leaves, i.e., SPAD values (17% and 26%), membrane stability (26% and 25%), and growth parameters i.e., root surface area (42% and 23%), root length (81% and 79%), root dry weight (456% and 190%), root volume (64% and 32%), shoot length (41% and 35%), shoot dry weight of shoot (111% and 117%), and overall grain weight (62% and 72%) under Cd and Ni stress, respectively. It increased the activity of antioxidant activity (max. up to 20%) whereas decreased the metal bioaccumulation of Cd and Ni in the roots and shoot (max. up to 62%) of wheat. It was concluded that the application of Si potentially increases antioxidant activity and metal chelation resulting in decreased oxidative damage and reducing the effect of Cd and Ni stress on wheat which improves growth and physiological parameters as well as inhibits Cd and Ni inclusion in food chain under Cd and Ni toxicity reducing health risks associated with these metals.