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The ghost plume phenomenon and its impact on zenith-facing remote sensing measurements of volcanic SO2 emission rates 幽灵羽流现象及其对天顶面遥感测量火山二氧化硫排放率的影响
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-11-15 DOI: 10.1016/j.jvolgeores.2024.108217
D. Skye Kushner , Taryn Lopez , Christoph Kern , Santiago Arellano , Nemesio M. Pérez , José Barrancos
A large source of error in SO2 emission rates derived from mobile Differential Optical Absorption Spectroscopy (DOAS) of volcanic gas plumes is the uncertainty in atmospheric light paths between the sun and the instrument, particularly under non-ideal atmospheric conditions, such as the presence of low clouds. DOAS instruments measure the SO2 column density along the effective light path, so changes to that pathway directly affect the measured SO2 signal. Due to complex radiative transfer mechanisms when a cloud is between the DOAS viewing position and a volcanic plume, measured plumes can appear spatially offset from their true location, a phenomenon informally referred to as “ghost plumes.” In addition to the appearance of ghost plumes, DOAS measurements recorded in non-ideal conditions have poorly characterized errors and are often discarded, limiting the data available to characterize volcanic degassing. In this study we simulate the radiative transfer associated with zenith-facing mobile DOAS traverses using the McArtim radiative transfer model for scenarios when there is a cloud layer between the instrument and the volcanic plume. In total, 217 permutations of atmospheric optical conditions are considered with varying cloud opacities (AOD = 0, 1, 2, 4, 8, 20), plume opacities (AOD = 0, 1, 2, 4, 8), solar zenith angles (SZA = 1°, 30°, 60°), and cloud thicknesses (200, 400, 800 m). We first develop objective criteria for selecting SO2 baseline absorption levels and plume spatial extents. The simulated plume traverses are then integrated to obtain the SO2 cross-sectional burdens which, after multiplication with the wind speed, yield SO2 emission rates. We find large modification in the shape of the modeled cross-sectional burdens even under translucent (low AOD) cloud conditions in our modeled scenarios. Despite modification of the plume shape, the presence of a low cloud layer is typically not a large source of error in the SO2 cross-sectional burden or emission rate obtained from zenith-facing DOAS traverses. We find that all measured cross-sectional burdens simulated using an aerosol-free plume in the above conditions and SZA ≤ 30° are within ±25% of the true value.
通过移动式差分光学吸收光谱(DOAS)对火山气体羽流进行分析得出的二氧化硫排放率的一大误差来源是太阳和仪器之间的大气光路的不确定性,特别是在非理想大气条件下,如存在低云。DOAS 仪器沿有效光路测量二氧化硫柱密度,因此光路的变化会直接影响测量到的二氧化硫信号。当云层位于 DOAS 观测位置和火山羽流之间时,由于复杂的辐射传递机制,测量到的羽流可能会出现与其真实位置的空间偏移,这种现象被非正式地称为 "幽灵羽流"。除了 "幽灵羽流 "的出现,在非理想条件下记录的 DOAS 测量误差也不明显,通常会被丢弃,从而限制了用于描述火山脱气特征的数据。在这项研究中,我们使用 McArtim 辐射传输模型模拟了仪器与火山羽流之间存在云层时,与天顶面移动 DOAS 穿越相关的辐射传输。我们总共考虑了 217 种大气光学条件的变化,云的不透明性(AOD = 0、1、2、4、8、20)、羽流的不透明性(AOD = 0、1、2、4、8)、太阳天顶角(SZA = 1°、30°、60°)和云的厚度(200、400、800 米)各不相同。我们首先制定了选择二氧化硫基线吸收水平和烟羽空间范围的客观标准。然后对模拟的烟羽穿越进行整合,以获得二氧化硫截面负担,在与风速相乘后,得出二氧化硫排放率。我们发现,即使在模拟场景中的半透明云(低 AOD)条件下,模拟截面负担的形状也会发生很大变化。尽管羽流形状会发生改变,但低云层的存在通常不会对从天顶方向的 DOAS 穿越中获得的二氧化硫截面负荷或排放率造成很大误差。我们发现,在上述条件和 SZA ≤ 30° 的情况下,使用无气溶胶羽流模拟的所有测量截面负荷都在真实值的±25%以内。
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引用次数: 0
Surface deformation caused by the unrest during 2002–2006 of the Changbaishan volcano in China 2002-2006 年中国长白山火山动荡引起的地表变形
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-11-15 DOI: 10.1016/j.jvolgeores.2024.108234
Hongbao Liang , Dan Xu , Jingwei Li
The Changbaishan volcano is recognized as one of China's most potentially dangerous active volcanoes. In response to the unrest event of 2002, GPS technology was utilized to monitor the surface deformation it induced. However, the understanding of the volcano's dynamics and the intricacies of GPS data at the time were limited, which affected the quality of the conclusions. For example, the commencement of GPS observations followed the escalation of seismic activities, leading to the loss of some deformation information. Moreover, observational noise in the GPS coordinate sequences introduced oscillations in the evolution of deformation characteristics. To overcome these limitations, we have developed an advanced GPS data processing methodology. This includes the establishment of a meticulous three-tier control network, the employment of high-precision geophysical models in GAMIT/GLOBK software, the creation of a volcanic regional reference frame, and the formulation of a sophisticated motion model for monitoring stations. With these approaches, we have captured the maximum surface deformation caused by the unrest and have re-evaluated the volume change (25.95× 106 m3/year) of the magma chamber based on Mogi model, yielding results that significantly surpass the mean of previous estimates of 8.58 × 106 m3/year and enhancing our understanding of the magma chamber's dimensions. Additionally, the surface deformation following the unrest displayed a pattern of continuous decay, which is in contrast to the seismic activity that initially rose and then declined, peaking notably after the surface deformation's peak. Considering the geological context of the volcano's formation, we have also provided an extensive dataset of GPS velocity fields. We have preliminarily discussed the possible relationship between the subduction of the Pacific Plate and the unrest in 2002, as well as the recent low-level unrest in 2021, acknowledging that this hypothesis requires further confirmation through stress modeling related to the disturbances. The deformation data resulting from the unrest, as well as the background deformation caused by plate subduction presented in this study, provide essential data constraints for the construction of subsequent stress models.
长白山火山是中国公认的最危险的活火山之一。针对 2002 年的动乱事件,利用 GPS 技术对其引起的地表变形进行了监测。然而,由于当时对火山动态的了解和 GPS 数据的复杂性有限,影响了结论的质量。例如,GPS 观测是在地震活动升级之后开始的,这导致了一些变形信息的丢失。此外,全球定位系统坐标序列中的观测噪声也导致了形变特征演变过程中的振荡。为了克服这些局限性,我们开发了一套先进的 GPS 数据处理方法。这包括建立一个缜密的三级控制网络,在 GAMIT/GLOBK 软件中使用高精度地球物理模型,创建一个火山区域参考框架,以及为监测站制定一个复杂的运动模型。通过这些方法,我们捕捉到了动荡造成的最大地表变形,并根据莫吉模型重新评估了岩浆腔的体积变化(25.95×106 立方米/年),得出的结果大大超过了之前估计的 8.58×106 立方米/年的平均值,增强了我们对岩浆腔尺寸的了解。此外,动荡后的地表形变呈现出持续衰减的模式,这与地震活动形成鲜明对比,地震活动先上升后下降,在地表形变峰值后达到峰值。考虑到火山形成的地质背景,我们还提供了大量 GPS 速度场数据集。我们初步讨论了太平洋板块俯冲与 2002 年动荡以及最近 2021 年低水平动荡之间可能存在的关系,并承认这一假设需要通过与动荡相关的应力模型来进一步证实。本研究中介绍的动荡造成的变形数据以及板块俯冲造成的背景变形为后续应力模型的构建提供了重要的数据约束。
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引用次数: 0
Evolution of eruption rate between two caldera-forming eruptions in the Jemez Mountains volcanic field, New Mexico, USA 美国新墨西哥州杰米斯山脉火山区两次火山口形成喷发之间的喷发率演变
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-11-13 DOI: 10.1016/j.jvolgeores.2024.108216
Nicholas F. Meszaros , Matthew J. Zimmerer , James E. Gardner
Rhyolites that erupted between the Otowi and Tshirege members of the Bandelier Tuff, known as the Valle Toledo Member, were investigated in the Jemez Mountains volcanic field to infer changes in eruptive rate and flux between two caldera-forming eruptions. Our analysis combines high-precision 40Ar/39Ar single-crystal laser-fusion dating of sanidine, matrix glass compositions and mineralogy of pumice, depositional textures, and volumetric estimates of erupted rhyolites to present a revised Valle Toledo Member eruptive chronology that integrates our observations with those of previous studies. With the improved temporal resolution of our high-precision eruption ages (median 2σ uncertainty of ±2.9 ka), the updated Valle Toledo Member eruption chronology consists of at least 42 temporally or mineralogically distinct eruptions that we group into four periods of time based on eruption rate. Within the first 8.1 ± 5.1 kyr (∼1605–1597 ka) that followed the Otowi caldera-forming eruption at 1605.4 ± 2.3 ka, six eruptions are recognized. This suggests an average recurrence interval on the order of 1.4 ± 0.9 kyr. Twenty-seven eruptions occurred during the next 194.4 ± 5.1 kyr (from ∼1597–1403 ka) and the average recurrence interval increased to 7.2 ± 0.2 kyr. Following this second period of slower eruption rate, a previously unrecognized eruption hiatus of up to 162.4 ± 3.1 kyr occurred from 1402.9 ± 2.3 ka to 1240.5 ± 2.1 ka. Resumption of volcanic activity is characterized by a series of at least nine volcanic eruptions during the next 8.6 ± 2.5 kyr, culminating in the eruption of the 400 km3 Tshirege Member of the Bandelier Tuff and formation of Valles caldera at 1231.9 ± 1.3 ka. This last phase of pre-caldera activity has the shortest observed average recurrence interval (1.0 ± 0.3 kyr) and greatest eruptive flux (≥ 0.4 ± 0.2 km3/kyr) that occurred between the two caldera-forming eruptions. We interpret the shifts in eruption rate and flux following the 162.4 ± 3.1 kyr eruption hiatus, in addition to mineralogical changes present in post-hiatus rhyolites, as indicators that the Bandelier system was trending towards another major eruption. The magmatic system may have grown gradually throughout the ca. 162 kyr period of volcanic repose; however, the heightened eruption rate in the ca. 10 kyr before caldera collapse is consistent with relatively rapid growth of the magmatic system before the Tshirege event as previously proposed by other studies. Furthermore, the new dataset is consistent with prior geochronology studies of the region that show the four largest explosive eruptions in the Jemez field were all proceeded by very slow eruptive rates or hiatuses. This demonstrates that sequences of heightened volcanic activity can initiate on rapid geological timescales from states of volcanic quiescence in the Bandelier system.
我们在杰米斯山火山区调查了班德利耶凝灰岩的奥托维(Otowi)和特希尔热(Tshirege)岩体之间喷发的流纹岩,这些流纹岩被称为瓦莱托莱多岩体(Valle Toledo),以推断两次火山口形成喷发之间喷发速度和流量的变化。我们的分析结合了辉绿岩的高精度 40Ar/39Ar 单晶激光熔融测年、浮石的基质玻璃成分和矿物学、沉积纹理以及喷发流纹岩的体积估算,提出了经修订的 Valle Toledo 成员喷发年代学,并将我们的观察结果与之前的研究结果进行了整合。随着我们高精度喷发年龄的时间分辨率的提高(中位数 2σ 不确定性为 ±2.9 ka),更新的 Valle Toledo 成员喷发年代学至少包括 42 次时间上或矿物学上不同的喷发,我们根据喷发率将其分为四个时间段。在1605.4 ± 2.3 ka的奥托维火山口形成喷发之后的前8.1 ± 5.1 kyr (∼1605-1597 ka)内,有六次喷发。这表明平均重现间隔约为 1.4 ± 0.9 千年。在接下来的 194.4 ± 5.1 kyr 期间(从 ∼1597-1403 ka)发生了 27 次喷发,平均重现间隔增加到 7.2 ± 0.2 kyr。在喷发速度减慢的第二个时期之后,从1402.9 ± 2.3 ka到1240.5 ± 2.1 ka,出现了之前未被确认的长达162.4 ± 3.1 kyr的喷发间断期。在接下来的 8.6 ± 2.5 kyr 期间,至少发生了九次火山喷发,最终在 1231.9 ± 1.3 ka 时,Bandelier 凝灰岩的 400 km3 Tshirege 成员火山喷发,并形成了 Valles 破火山口。在火山口形成前的最后一个活动阶段,观测到的平均重现间隔(1.0 ± 0.3 kyr)最短,喷发流量最大(≥ 0.4 ± 0.2 km3/kyr),发生在两次火山口形成喷发之间。我们将 162.4 ± 3.1 千年喷发间歇期后喷发速率和流量的变化,以及间歇期后流纹岩中出现的矿物学变化,解释为班德利尔系统正趋向于另一次大喷发。在大约 162 千年的火山喷发期中,岩浆系统可能是逐渐增长的。然而,火山口坍塌前约 10 千年的喷发速度加快了。然而,火山口坍塌前约 10 千年的喷发率增高与其他研究之前提出的奇希尔热事件之前岩浆系统相对快速的增长是一致的。此外,新的数据集与之前对该地区进行的地质年代学研究相一致,这些研究表明杰米斯岩场四次最大的爆炸性喷发都是以非常缓慢的喷发速度或间断进行的。这表明,班德利埃火山系统中的火山静止状态可以在快速的地质时间尺度上引发一连串的火山活动。
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引用次数: 0
Feeding system beneath active volcanoes in central part of Iturup Island (Kuril Arc) inferred from local earthquake tomography 根据当地地震层析成像推断伊图鲁普岛(千岛弧)中部活火山下的馈源系统
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-11-12 DOI: 10.1016/j.jvolgeores.2024.108233
Ivan Koulakov , Evgeny Ilyich Gordeev , Ilyas Abkadyrov , Olga Bergal-Kuvikas , Danila Chebrov
Iturup is the largest island of the Kuril Arc with more than 20 Holocene volcanoes of which 9 considered active. Here we investigate the central part of the island where we deployed in 2022–2023 a portable network of 12 seismic stations. The data of this network together with several permanent stations in surrounding islands were used to identify almost 300 events and to perform seismic tomography based on the picked arrival times of the P and S seismic waves. A challenging problem was that most of the events were located outside the network, and we performed careful analysis to examine the actual capacity of inversion with such data to recover seismic velocity structures below the network. In the resulting model, we found a dominating high-velocity anomaly below the central part of the study area, which is bounded by zones of low velocities and high Vp/Vs ratio collocated with two active volcano complexes (Chirip to the north and Ivan Grozny to the south). Below the third volcano, Baransky, we observe a change of the Vp/Vs ratio from high at large depths to low at shallow depth, indicating the process of degassing, which is supported by strong fumarolic activity and hydrothermal manifestations around this volcano. At depths of more than 20 km, the feeding paths from Baransky and Ivan Grozny volcanoes seem to be connected in one anomaly representing a common magma source below the center of the island. This seems to be a common feature observed below several volcanic islands, such as Tenerife and El Hierro, where the high-velocity rigid core in a central part is surrounded by low-velocity flows associated with recent volcanic manifestations.
伊图鲁普岛是千岛之弧最大的岛屿,岛上有 20 多座全新世火山,其中 9 座被认为是活火山。在此,我们对该岛中部进行了调查,并于 2022-2023 年在该岛部署了由 12 个地震台站组成的便携式网络。利用该网络的数据以及周边岛屿的几个永久台站的数据,我们确定了近 300 个事件,并根据 P 地震波和 S 地震波的选取到达时间进行了地震层析成像。一个具有挑战性的问题是,大多数地震事件都位于地震台网之外,因此我们进行了仔细分析,以检验利用此类数据进行反演以恢复地震台网下方地震速度结构的实际能力。在由此产生的模型中,我们发现在研究区域的中部下方有一个主要的高速异常,其边界是与两个活火山群(北面的奇里普和南面的伊万-格罗兹尼)相连的低速度和高 Vp/Vs 比值区。在第三座火山--巴兰斯基火山下方,我们观察到 Vp/Vs 比值从大深度的高值变为浅深度的低值,这表明该火山周围强烈的炽热活动和热液表现支持着脱气过程。在 20 多公里深的地方,来自巴兰斯基火山和伊万-格罗兹尼火山的馈源路径似乎连接在一个异常点上,代表着岛屿中心下方的一个共同岩浆源。这似乎是在特内里费岛和埃尔希耶罗岛等几个火山岛下面观察到的一个共同特征,在这些火山岛的中心部分,高速刚性核心被与近期火山表现有关的低速流所包围。
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引用次数: 0
The influence of FeTi oxide microlites on bubble nucleation in rhyolitic melts 氧化铁钛微晶对流纹岩熔体中气泡成核的影响
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-11-08 DOI: 10.1016/j.jvolgeores.2024.108218
Wade L. Aubin , James E. Gardner
We conducted a set of high-temperature decompression experiments to constrain the mechanisms of heterogeneous bubble nucleation in high-silica rhyolitic melt that contained 4.6–4.8 wt% H2O. The melt was seeded with two different size fractions of magnetite crystals: 1–2 μm crystals and large crystals of 32–135 μm (long axis). The number density of bubbles (BND) that nucleated on the small crystals was found to increase from 106.5 to 108.7 cm−3 as H2O increasingly supersaturated (ΔP) in the melt from 3 to 23 MPa. At ΔP >23 MPs, however, the number of bubbles nucleated equals the number of small magnetite and no more nucleated with increased ΔP. At the same conditions, the number of bubbles that nucleated on the large crystals increases, from <1 bubble per crystal at ΔP = 3 MPa to 14 ± 4 bubbles per crystal at 58 MPa. We thus find that ΔP has a significant influence on the mechanisms of heterogenous nucleation, but the observed increases in BND are much greater than would be predicted solely from the increase in ΔP. The discrepancy can be reconciled if there are different sites on the crystals that become activated at greater ΔP, leading to greater numbers of bubbles nucleating. The cumulative BND nucleated on small crystals, however, is capped by the number of crystals present. The BND values generated at ΔP >23 MPa in our experiments overlap with those found in ∼80 % of naturally occurring pumice. Assuming our experiments are representative of natural pumice, this suggests that explosively erupted magmas either become significantly volatile supersaturated before heterogeneously nucleating bubbles, or that the number of nucleation sites in natural magmas greatly exceed 109 cm−3.
我们进行了一组高温减压实验,以确定含 4.6-4.8 wt% H2O 的高硅质流纹岩熔体中的异质气泡成核机制。熔体中加入了两种不同尺寸的磁铁矿晶体:1-2 μm 的晶体和 32-135 μm 的大晶体(长轴)。随着 H2O 在熔体中的过饱和度(ΔP)从 3 兆帕增加到 23 兆帕,在小晶体上成核的气泡密度(BND)从 106.5 厘米-3 增加到 108.7 厘米-3。然而,在 ΔP >23 MPs 时,成核气泡的数量等于小磁铁矿的数量,随着 ΔP 的增加,成核气泡的数量不再增加。在相同条件下,在大晶体上成核的气泡数量增加,从 ΔP = 3 MPa 时的每个晶体 1 个气泡增加到 58 MPa 时的每个晶体 14 ± 4 个气泡。因此,我们发现ΔP 对异质成核机制有重大影响,但观察到的 BND 的增加远大于仅凭 ΔP 的增加所预测的结果。如果晶体上有不同的位点在ΔP增大时被激活,从而导致更多气泡成核,那么这种差异是可以调和的。不过,在小晶体上成核的累积 BND 值受到晶体数量的限制。在我们的实验中,在 ΔP >23 兆帕时产生的 BND 值与天然浮石中 80% 的 BND 值相吻合。假设我们的实验对天然浮石具有代表性,这表明爆炸喷发的岩浆要么在异质成核气泡之前就已显著挥发过饱和,要么天然岩浆中的成核点数量大大超过 109 cm-3。
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引用次数: 0
The dynamic of magmatic system and volcano hazard implications of the Damavand volcano (N. Iran) inferred from the textural data 从纹理数据推断出的达玛旺德火山(伊朗北部)岩浆系统的动态和火山灾害的影响
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-11-03 DOI: 10.1016/j.jvolgeores.2024.108220
Amir Eskandari , Sadraddin Amini , Behnam Sadeghi
The Damavand stratovolcano (N Iran) consists mainly of lavas with trachyandesite-trachyte composition, and subordinate pyroclastic deposits. The intensity of explosive eruptions and the volume of pyroclastic deposits have increased over time, which may be related to increasing viscosity due to the development of crystal-rich magmas. This research integrates microanalytical and quantitative textural measurements to understand the textural evolutions from the old to the young lavas and their relationships with the physical processes occurred in the plumbing system. Age-constrained samples from the lavas were analyzed using crystal size distribution (CSD), the newly proposed multifractal analysis, including the Number-Length of crystals (N-LoC) and the Number-Area of crystals (N-AoC), along with mineral chemistry. Three to five populations of feldspars can be identified, which have undergone evolution and coarsening over time. We propose a textural development sequence established at mid to shallow crustal levels, involving several physicochemical processes, such as cycles of polybaric differentiation and episodic magma recharge into the crystal-rich magma chambers. This, in turn, caused disaggregation of crystal mushes and textural coarsening due to crystal aggregation and temperature cycling. The increasing population of microphenocrysts in younger lavas may be linked to pulsating groundmass crystallization resulting from degassing at a newly formed shallow chamber (0.5–1 kbar) beneath the young cone. The final stages of crystallization occurred during multi-step decompression in the conduits. The comparison of age data from lava samples and their stratigraphic positions suggests that triggering groundmass crystallization might have caused shifts in eruptive behavior.
达马旺德平原火山(伊朗北部)主要由梯状安山岩-梯状岩成分的熔岩和附属的火成碎屑沉积物组成。随着时间的推移,爆炸性喷发的强度和火成碎屑沉积物的体积都在增加,这可能与富含晶体的岩浆发展导致粘度增加有关。这项研究综合了微观分析和定量纹理测量,以了解从老岩浆到年轻岩浆的纹理演变及其与管道系统中发生的物理过程之间的关系。利用晶体尺寸分布(CSD)、新提出的多分形分析(包括晶体数量-长度(N-LoC)和晶体数量-面积(N-AoC))以及矿物化学分析了来自熔岩的年龄限制样本。可以确定三到五个长石群,它们随着时间的推移发生了演变和粗化。我们提出了一个在地壳中浅层建立的纹理发育序列,其中涉及多个物理化学过程,如多巴分化周期和岩浆向富含晶体的岩浆腔的偶发性补给。这反过来又造成了晶体薄层的解离,以及晶体聚集和温度循环导致的纹理粗化。年轻岩浆中微晶的数量不断增加,可能与年轻锥体下方新形成的浅室(0.5-1 千巴)脱气导致的脉动地层结晶有关。结晶的最后阶段发生在导管的多级减压过程中。熔岩样本的年龄数据与其地层位置的比较表明,引发地表结晶可能导致了喷发行为的转变。
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引用次数: 0
Experimental constraints on the behaviour of sulphur in the 2021 Cumbre Vieja (La Palma) basanite 关于 2021 年坎布雷维埃哈(拉帕尔马)玄武岩中硫的行为的实验制约因素
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-11-02 DOI: 10.1016/j.jvolgeores.2024.108219
Diletta Frascerra , Bruno Scaillet , Joan Andújar , Clive Oppenheimer , Stéphane Scaillet , Joan Martí , Ramón Casillas , Carmen López
We performed experiments to constrain the effects of sulphur and oxygen fugacities on magma chamber and outgassing conditions of the La Palma 2021 eruption. Based on a series of controlled experiments on basanitic products carried out at 1040 °C and 200 MPa, we show that sulphur addition affects the stabilities of amphibole and olivine, in particular at high fO2 and elevated S contents which together inhibit amphibole crystallization. We also show that the overriding control on S systematics is oxygen fugacity, with melts capable of dissolving from 1000 up to 8000 ppm S, depending on fO2. Increasing the bulk S content increases the S content of the silicate melt up to ∼2000 ppm for fO2 < NNO + 2, and 7000–8000 ppm at higher fO2. Further increase in dissolved S is prevented by the buffering effects of either sulphide at low fO2 or anhydrite at high fO2. Modelling shows that the observed CO2/SO2 and H2O/SO2 ratios of volcanic gas emissions during the eruption imply a pre-existing >5 wt% exsolved fluid in the reservoir, with fS2 at ∼0.1 MPa at fO2 above NNO. Our work confirms that basaltic magmas may coexist with a significant amount of excess fluid which in turn holds an important part of the sulphur budget emitted to the atmosphere.
我们进行了实验,以确定硫和氧的富集度对拉帕尔马 2021 火山喷发的岩浆室和排气条件的影响。基于在 1040 °C 和 200 MPa 条件下对玄武岩产物进行的一系列受控实验,我们发现硫的添加会影响闪石和橄榄石的稳定性,尤其是在高 fO2 和 S 含量升高的情况下,硫的添加会共同抑制闪石的结晶。我们还表明,对硫系统学的最主要控制因素是逸氧性,根据 fO2 的不同,熔体能够溶解 1000 至 8000 ppm 的硫。在 fO2 < NNO + 2 条件下,增加体积 S 含量可使硅酸盐熔体中的 S 含量达到 ∼ 2000 ppm,而在更高的 fO2 条件下,则可达到 7000-8000 ppm。在低 fO2 条件下,硫化物的缓冲作用阻止了溶解 S 的进一步增加;在高 fO2 条件下,无水石膏的缓冲作用阻止了溶解 S 的进一步增加。建模表明,在喷发过程中观测到的火山气体排放的 CO2/SO2 和 H2O/SO2 比率意味着储层中预先存在 5 wt%的外溶解流体,当 fO2 高于 NNO 时,fS2 为 0.1 MPa。我们的研究证实,玄武质岩浆可能与大量过剩流体共存,而过剩流体又是排放到大气中的硫的重要来源。
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引用次数: 0
Conduit armouring preceding explosive activity at an andesitic stratovolcano, an example from Taranaki Mounga, New Zealand 安山质平原火山爆炸活动前的导管铠装,新西兰塔拉纳基蒙加的一个例子
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-11-01 DOI: 10.1016/j.jvolgeores.2024.108214
Henry Hoult , Ben M. Kennedy , Alexander R.L. Nichols , Shane Cronin , Leighton Watson
The strength and permeability of volcanic conduits can directly influence eruption dynamics via moderating the outgassing of ascending magma and the density of eruption plumes. Lithic clasts in pyroclastic ejecta can be used to understand the dynamic evolution of conduit walls because they are incorporated into the ascending melt-gas-particle mixture during volcanic eruptions. We examine the 1655 CE Burrell eruption of Taranaki Mounga, which transitioned from effusive activity to an explosive sub-Plinian phase and ended in unsteady columns. This episode was followed by a series of effusive eruptions of lower explosivity. Using textural analysis and physical properties, we distinguish five dominant lithic clast types within Burrell deposits that represent different regions of the shallow conduit and vent. Lithic types 1–3 represent juvenile (‘intrusive cognate’) and older (‘intrusive accessory’) conduit-filling plug materials. Lithic type 4 represents juvenile (‘extrusive cognate’) vent-filling lava dome extruded at the eruption onset, while Type 5 lithics (‘extrusive cognate’) represent sintered/compacted cognate material from the shallow vent accumulated during transitions in eruptive style. Crystalline andesite lithics (type 1) show a microlite-dominated groundmass. Hydrothermally altered andesite lithics (type 2) show breakdown of phenocrysts and increased seismic velocity relative to type 1 lithics. Brecciated andesite lithics (type 3) comprise fractured and sintered clasts of crystalline andesite. Glassy andesite lithics (type 4) show sub-rounded vesicles and glass-hosted microlites. Banded vitrophyre lithics (type 5) show bands of varying vesicularity, crystallinity and clast load. Physical property data reveals porosity, fracturing, sintering and alteration extent dictate dynamic changes in conduit permeability and potentially strength. Our results show how, during the explosive phase of the Burrell eruption, the conduit was lined with juvenile and remnant shallow plug material that was variably fractured, sintered and altered before being eroded and ejected. Comparison with previous work on Taranaki and dome-plug material from around the world shows how fracturing and sintering of conduit walls, combined with lining with dense juvenile material, cause overall permeability reduction and strengthening of the conduit. This inhibits outgassing and preserves conduit structure, facilitating the transition to explosive activity and the establishment of a stable eruption column.
火山导管的强度和渗透性可通过调节上升岩浆的排气和喷发羽流的密度直接影响喷发动力学。火成碎屑喷出物中的碎石可用于了解导管壁的动态演化,因为它们在火山喷发过程中被纳入上升的熔融-气体-颗粒混合物中。我们研究了公元 1655 年塔拉纳基蒙加的伯利尔喷发,这次喷发从喷出活动过渡到了亚普林期的爆炸阶段,并以不稳定柱状结束。在这次喷发之后,又发生了一系列爆炸性较低的喷出式喷发。通过纹理分析和物理性质,我们区分了布瑞尔沉积物中的五种主要碎屑岩类型,它们代表了浅层导管和喷口的不同区域。1-3 类岩石代表幼年("侵入同源物")和较老("侵入附属物")的导管填充塞材料。第 4 类岩石代表喷发初期挤出的幼年("挤出同源物")喷口填充熔岩穹丘,而第 5 类岩石("挤出同源物")则代表浅喷口在喷发方式转变期间积累的烧结/压实同源物。结晶安山岩岩屑(类型 1)显示出以微岩为主的地层。经热液蚀变的安山岩岩屑(类型 2)与类型 1 的岩屑相比,显示出表晶的破碎和地震速度的增加。碎屑安山岩岩屑(第 3 类)由碎裂和烧结的结晶安山岩碎屑组成。玻璃质安山岩岩屑(第 4 类)显示出亚圆形泡状体和玻璃质微晶。带状闪长岩(第 5 类)显示出不同泡状、结晶度和碎屑负荷的带状。物理性质数据显示,孔隙度、断裂、烧结和蚀变程度决定了导管渗透性和潜在强度的动态变化。我们的研究结果表明,在布瑞尔火山爆发的爆炸阶段,导管内有幼年和残余的浅层堵塞材料,这些材料在被侵蚀和喷出之前发生了不同程度的断裂、烧结和蚀变。与以前在塔拉纳基进行的研究以及世界各地的穹顶岩塞材料进行的比较表明,导管壁的断裂和烧结,加上内衬致密的幼体材料,是如何导致整体渗透性降低和导管加固的。这就抑制了排气,保护了导管结构,有利于向爆炸活动过渡和建立稳定的喷发柱。
{"title":"Conduit armouring preceding explosive activity at an andesitic stratovolcano, an example from Taranaki Mounga, New Zealand","authors":"Henry Hoult ,&nbsp;Ben M. Kennedy ,&nbsp;Alexander R.L. Nichols ,&nbsp;Shane Cronin ,&nbsp;Leighton Watson","doi":"10.1016/j.jvolgeores.2024.108214","DOIUrl":"10.1016/j.jvolgeores.2024.108214","url":null,"abstract":"<div><div>The strength and permeability of volcanic conduits can directly influence eruption dynamics via moderating the outgassing of ascending magma and the density of eruption plumes. Lithic clasts in pyroclastic ejecta can be used to understand the dynamic evolution of conduit walls because they are incorporated into the ascending melt-gas-particle mixture during volcanic eruptions. We examine the 1655 CE Burrell eruption of Taranaki Mounga, which transitioned from effusive activity to an explosive sub-Plinian phase and ended in unsteady columns. This episode was followed by a series of effusive eruptions of lower explosivity. Using textural analysis and physical properties, we distinguish five dominant lithic clast types within Burrell deposits that represent different regions of the shallow conduit and vent. Lithic types 1–3 represent juvenile (‘intrusive cognate’) and older (‘intrusive accessory’) conduit-filling plug materials. Lithic type 4 represents juvenile (‘extrusive cognate’) vent-filling lava dome extruded at the eruption onset, while Type 5 lithics (‘extrusive cognate’) represent sintered/compacted cognate material from the shallow vent accumulated during transitions in eruptive style. Crystalline andesite lithics (type 1) show a microlite-dominated groundmass. Hydrothermally altered andesite lithics (type 2) show breakdown of phenocrysts and increased seismic velocity relative to type 1 lithics. Brecciated andesite lithics (type 3) comprise fractured and sintered clasts of crystalline andesite. Glassy andesite lithics (type 4) show sub-rounded vesicles and glass-hosted microlites. Banded vitrophyre lithics (type 5) show bands of varying vesicularity, crystallinity and clast load. Physical property data reveals porosity, fracturing, sintering and alteration extent dictate dynamic changes in conduit permeability and potentially strength. Our results show how, during the explosive phase of the Burrell eruption, the conduit was lined with juvenile and remnant shallow plug material that was variably fractured, sintered and altered before being eroded and ejected. Comparison with previous work on Taranaki and dome-plug material from around the world shows how fracturing and sintering of conduit walls, combined with lining with dense juvenile material, cause overall permeability reduction and strengthening of the conduit. This inhibits outgassing and preserves conduit structure, facilitating the transition to explosive activity and the establishment of a stable eruption column.</div></div>","PeriodicalId":54753,"journal":{"name":"Journal of Volcanology and Geothermal Research","volume":"455 ","pages":"Article 108214"},"PeriodicalIF":2.4,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142561203","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Volcanic tremor associated with successive gas emission activity at a boiling pool: Analyses of seismic array and visible image data recorded at Iwo-Yama in Kirishima Volcanic complex, Japan 与沸腾池连续气体排放活动有关的火山震颤:日本雾岛火山群岩尾山记录的地震阵列和可见光图像数据分析
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-11-01 DOI: 10.1016/j.jvolgeores.2024.108212
Masato Hata , Takeshi Nishimura , Takeshi Matsushima , Tomofumi Kozono , Tsutomu Nagatsuma , Ken T. Murata , Kazutaka Kikuta , Dan Muramatsu , Hisashi Nakahara
Volcanic tremors are often observed during volcanic activity and volcanic eruptions, and their generation processes provide clues for understanding volcanic fluid activity underground and eruption dynamics. However, tremors are characterized by continuous oscillations that mask P- and S-waves; hence few studies have precisely located the source, which is the most fundamental information for understanding the generation mechanism. In this study, we focus on volcanic tremors excited by continuous gas emissions occurring at a vent called Y2a in Iwo-Yama, the Kirishima Volcanic Complex, Japan, to clarify the source process of the tremor as well as gas emission activity. We simultaneously observed the volcanic tremor by deploying a small aperture array consisting of six seismometers and the gas emission activity by using a newly developed visual IoT system that can be operated without commercial electricity. MUSIC analysis locates the tremor at depths ranging from the ground surface to approximately 200 m beneath the Y2a and Y2b vents, which are approximately 30 m apart, for approximately four months from November 2021 to February 2022. The source locations of the tremors in the 2 Hz (1.2–2.6 Hz), 4 Hz (3–4 Hz), and 5 Hz (4–5.5 Hz) ranges show some differences and changes with time. The source location tends to become deeper when the 2 Hz amplitude is large. The infrasound generated by gas emission activity is dominant in the tremor signals, which are recognized in the wave propagation velocity with an acoustic velocity of 330 m/s when the 2 Hz amplitude is small. The visual IoT system succeeded in detecting long-term changes in the gas emission activity, and we found that the 2 Hz amplitude of tremor was well correlated with the amount of hot water in the boiling pool of Y2a, which was controlled by precipitation and evaporation during non-rainy days. From these observations, we infer that the volcanic tremor is generated by resonance of volcanic gas and hot water in a crack-like structure beneath Y2a. The resonance was triggered by the counterforces of the gas emissions in the boiling pool, and the infrasound was dominant during periods of hot water depletion in the boiling pool. Temporal changes in the source depths may be caused by changes in the fluid properties, configuration of the resonator and/or the strengths of the underground sources and infrasound. Our simultaneous observations of seismic array and visual IoT system clarify that even the continuous gas emission activity that looks stable is controlled by external sources such as precipitation.
在火山活动和火山喷发期间经常会观测到火山震颤,其产生过程为了解地下火山流体活动和火山喷发动力学提供了线索。然而,震颤的特点是连续振荡,掩盖了 P 波和 S 波,因此很少有研究能精确定位震源,而震源是了解震颤产生机制的最基本信息。在本研究中,我们重点研究了发生在日本雾岛火山群岩尾山 Y2a 喷口的连续气体排放所激发的火山震颤,以明确震颤源过程以及气体排放活动。我们通过部署由六个地震仪组成的小孔径阵列同时观测了火山震颤,并利用新开发的无需商业电力即可运行的可视物联网系统观测了气体排放活动。MUSIC 分析确定了 2021 年 11 月至 2022 年 2 月约四个月期间从地表到相距约 30 米的 Y2a 和 Y2b 喷口下方约 200 米深处的震源位置。2 Hz(1.2-2.6 Hz)、4 Hz(3-4 Hz)和 5 Hz(4-5.5 Hz)范围内的震源位置随着时间的推移出现了一些差异和变化。当 2 赫兹振幅较大时,声源位置会变得更深。气体排放活动产生的次声在震颤信号中占主导地位,当 2 Hz 振幅较小时,可从声速为 330 m/s 的波传播速度中识别出来。视觉物联网系统成功地探测到了气体发射活动的长期变化,我们发现震颤的 2 赫兹振幅与 Y2a 号沸腾池中的热水量密切相关,而热水量在非雨天受降水和蒸发的控制。根据这些观察结果,我们推断火山震颤是由火山气体和热水在 Y2a 地下的裂缝状结构中共振产生的。沸腾池中气体排放的反作用力引发了共振,在沸腾池中热水耗尽期间,次声占主导地位。震源深度的时间变化可能是由流体性质、共振器构造和/或地下震源和次声强度的变化引起的。我们对地震阵列和可视物联网系统的同步观测表明,即使是看似稳定的连续气体排放活动也受到降水等外部来源的控制。
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引用次数: 0
Spread and frequency of explosive silicic volcanism of the Carpathian-Pannonian Region during Early Miocene: Clues from the SW Pannonian Basin and the Dinarides 中新世早期喀尔巴阡山-潘诺尼亚地区爆炸性硅质火山活动的扩散和频率:来自潘诺尼亚盆地西南部和迪纳利山脉的线索
IF 2.4 3区 地球科学 Q2 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-11-01 DOI: 10.1016/j.jvolgeores.2024.108215
Mihovil Brlek , Nina Trinajstić , Sean P. Gaynor , Steffen Kutterolf , Folkmar Hauff , Julie Schindlbeck-Belo , Sanja Šuica , Kuo-Lung Wang , Hao-Yang Lee , Elena Watts , Svetoslav V. Georgiev , Vlatko Brčić , Marko Špelić , Ivan Mišur , Duje Kukoč , Blair Schoene , Réka Lukács
Explosive silicic volcanism of the Carpathian-Pannonian Region (CPR) is increasingly recognized as the primary source of tephra across the Alpine-Mediterranean region during the Early and Middle Miocene. However, the tephrostratigraphic framework for this period of volcanic activity is still incomplete. We present new multi-proxy data from Lower Miocene ignimbrites and tephra fallout deposits from the southwestern CPR and the Dinaride Lake System and integrate them into existing datasets to better resolve the regional extent and scale of these eruptions of the CPR. Volcanic glass geochemistry indicates distal fallout tuffs deposited in the Sinj Basin are correlative with the proximal Ostoros ignimbrites from the Bükkalja Volcanic Field, indicative of regionally extensive volcanism at 17.295 ± 0.028 Ma, based on CA-ID-TIMS UPb zircon geochronology. Based on integrated tephrostratigraphic data, newly identified 17.064 ± 0.010 Ma massive rhyolitic ignimbrite deposits from the Kalnik Volcaniclastic Complex located in the southwestern CPR are correlative with the 17.062 ± 0.010 Ma Mangó massive ignimbrite found in the Bükkalja Volcanic Field located in the northern CPR. Based on these new observations of its potential areal distribution and estimated thicknesses, these two widespread ∼17.1 Ma ignimbrites represent intermediate to large caldera-forming ignimbrites, larger than previously suggested. Finally, volcanic glass geochemistry of fallout deposits from the Dinaridic Sinj and Livno-Tomislavgrad Basins have similar volcanic glass geochemistry as the rhyolitic pumices from the lowermost part of the Bogács ignimbrite unit of the Bükkalja Volcanic Field. However, high-precision geochronology indicates that these distal ashfalls were deposited at 16.9567 ± 0.0074 Ma, significantly predating the 16.824 ± 0.028 Ma emplacement of the fiamme-bearing part of the Bogács ignimbrite. These distinct ages suggest that the Bogács unit represents multiple eruptive events and indicating that further work is required to deconvolve this portion of the CPR volcanic record. Together, these data suggest that large volume CPR ignimbrite volcanism was more frequent and widespread than previously understood, enhancing the existing volcanic framework and history of the source region for this time period.
人们越来越认识到,喀尔巴阡山-潘诺尼亚地区(CPR)的爆发性硅质火山活动是整个阿尔卑斯山-地中海地区早、中新世时期的主要表壳来源。然而,这一时期火山活动的表层构造框架仍不完整。我们展示了来自 CPR 西南部和 Dinaride 湖系的下中新世点火岩和火山灰沉积物的新的多代理数据,并将其整合到现有数据集中,以更好地解析 CPR 这些火山爆发的区域范围和规模。根据 CA-ID-TIMS UPb 锆石地质年代学,火山玻璃地球化学研究表明,沉积在 Sinj 盆地的远端落灰凝灰岩与来自 Bükkalja 火山岩场的近端 Ostoros 火成岩具有相关性,表明在 17.295 ± 0.028 Ma 发生过区域性大范围火山活动。根据综合表层构造数据,从位于中央太平洋火山群西南部的卡尔尼克火山碎屑岩群中新发现的 17.064 ± 0.010 Ma 块状流纹状火云母沉积与位于中央太平洋火山群北部的 Bükkalja 火山岩场中发现的 17.062 ± 0.010 Ma Mangó 块状火云母具有相关性。根据对其潜在区域分布和估计厚度的这些新观察结果,这两个广泛分布的 ∼17.1 Ma 火成岩代表了中型到大型的火山口形成火成岩,比以前认为的要大。最后,Dinaridic Sinj 和 Livno-Tomislavgrad 盆地沉积物的火山玻璃地球化学与 Bükkalja 火山带 Bogács 火成岩单元最下部的流纹岩浮渣的火山玻璃地球化学相似。然而,高精度地质年代学表明,这些远端灰屑沉积于 16.9567 ± 0.0074 Ma,大大早于 Bogács 火成岩含岩部分的 16.824 ± 0.028 Ma。这些不同的年龄表明,Bogács单元代表了多次喷发事件,并表明需要进一步的工作来解构CPR火山记录的这一部分。这些数据共同表明,大体积 CPR 火成岩火山活动比以前所了解的更为频繁和广泛,从而加强了这一时期源区现有的火山框架和历史。
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引用次数: 0
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Journal of Volcanology and Geothermal Research
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