Pub Date : 2024-08-25DOI: 10.1016/j.jnnfm.2024.105306
Wenming Yang , Yifan Li , Jiantuo Ren , Xiaolong Yang
We analyze the fully developed Couette–Poiseuille flows of ferrofluids between two parallel flat walls subject to three types of time-varying magnetic fields. In these scenarios, ferrofluids exhibit diverse non-Newtonian characteristics such as distinct flow velocity distribution, apparent viscosity and shear stress compared to ordinary Couette–Poiseuille flows. The influence of spin viscosity is explored first through the solution of the governing equations with zero and non-zero spin viscosities. It shows that although the value of the spin viscosity is very small, its inviscid limit would have great influence over the velocity and spin velocity distributions. The assumption of zero spin viscosity leads to an exaggerated non-Newtonian behavior induced by time-varying magnetic fields in the ferrofluid Couette–Poiseuille flows. Then the solutions of equations with non-zero spin viscosity are utilized to delve into non-Newtonian behaviors of ferrofluid Couette–Poiseuille flow under the application of the three time-varying magnetic fields. The results indicate that negative rotational viscosity will occur if the dimensionless frequency lies in the range 1–10, which is a distinguishing feature compared with Newtonian flows. At this point, non-Newtonian flow induced by magnetic field arises, although this effect is very tiny. Within the same frequency range, reversed tangential stress appears in strong uniform alternating magnetic fields. The minimum negative rotational viscosity may arrive at up to 20 % of the intrinsic viscosity in the rotating magnetic field when the magnetization relaxation time is 4 ms.
{"title":"Non-Newtonian behaviors of ferrofluid Couette–Poiseuille flows in time-varying magnetic fields","authors":"Wenming Yang , Yifan Li , Jiantuo Ren , Xiaolong Yang","doi":"10.1016/j.jnnfm.2024.105306","DOIUrl":"10.1016/j.jnnfm.2024.105306","url":null,"abstract":"<div><p>We analyze the fully developed Couette–Poiseuille flows of ferrofluids between two parallel flat walls subject to three types of time-varying magnetic fields. In these scenarios, ferrofluids exhibit diverse non-Newtonian characteristics such as distinct flow velocity distribution, apparent viscosity and shear stress compared to ordinary Couette–Poiseuille flows. The influence of spin viscosity is explored first through the solution of the governing equations with zero and non-zero spin viscosities. It shows that although the value of the spin viscosity is very small, its inviscid limit would have great influence over the velocity and spin velocity distributions. The assumption of zero spin viscosity leads to an exaggerated non-Newtonian behavior induced by time-varying magnetic fields in the ferrofluid Couette–Poiseuille flows. Then the solutions of equations with non-zero spin viscosity are utilized to delve into non-Newtonian behaviors of ferrofluid Couette–Poiseuille flow under the application of the three time-varying magnetic fields. The results indicate that negative rotational viscosity will occur if the dimensionless frequency lies in the range 1–10, which is a distinguishing feature compared with Newtonian flows. At this point, non-Newtonian flow induced by magnetic field arises, although this effect is very tiny. Within the same frequency range, reversed tangential stress appears in strong uniform alternating magnetic fields. The minimum negative rotational viscosity may arrive at up to 20 % of the intrinsic viscosity in the rotating magnetic field when the magnetization relaxation time is 4 ms.</p></div>","PeriodicalId":54782,"journal":{"name":"Journal of Non-Newtonian Fluid Mechanics","volume":"332 ","pages":"Article 105306"},"PeriodicalIF":2.7,"publicationDate":"2024-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142095341","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-06DOI: 10.1016/j.jnnfm.2024.105297
Yannis E. Dimakopoulos , Georgios C. Georgiou
{"title":"Preface to Special Visual Issue: E Mitsoulis","authors":"Yannis E. Dimakopoulos , Georgios C. Georgiou","doi":"10.1016/j.jnnfm.2024.105297","DOIUrl":"10.1016/j.jnnfm.2024.105297","url":null,"abstract":"","PeriodicalId":54782,"journal":{"name":"Journal of Non-Newtonian Fluid Mechanics","volume":"331 ","pages":"Article 105297"},"PeriodicalIF":2.7,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141993115","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-05DOI: 10.1016/j.jnnfm.2024.105295
Victor C. Ibezim , David J.C. Dennis , Robert J. Poole
The present experimental investigation combines the bulk flow properties of polymer solutions and measurable rheological parameters as they flow through a distinctive micro-porous structure, with micro-PIV (micro-particle image velocimetry) to measure the velocity distribution and velocity fluctuations within individual pores of a novel porous glass structure. To investigate the effects of fluid elasticity at pore scale, aqueous solutions of a polyacrylamide (PAA) & polyethylene oxide (PEO) in the concentration range of 50–200 ppm, which were characterized in both shear and extensional flows using shear and capillary break-up extensional rheometers (CaBER) respectively, were used as working fluids. The velocity field measurement includes the velocity magnitude and fluctuation intensity in several different pores within the porous material across a Weissenberg number range of approximately 0.01 to 1 for each of the test fluids. The global averaged fluctuation intensity increases with but the critical value, which indicates the onset of significant unsteadiness (i.e. well above noise floor/Newtonian baseline) within the flow at pore scale gives an approximately constant value of 0.4, which is almost 40 times higher than the value that is observed in the pressure-drop measurements for the data to rise above the Newtonian base line. We therefore postulate that the enhanced pressure-drop behaviour of the bulk flow may not be due to local velocity fluctuations within the pores but due to mean flow effects, at least over a significant portion of the data (up to 0.4).
本实验研究将聚合物溶液流经独特微孔结构时的体积流动特性和可测量的流变参数与微颗粒图像测速仪(micro-PIV)相结合,测量新型多孔玻璃结构单个孔隙内的速度分布和速度波动。为了研究孔隙尺度上流体弹性的影响,使用了浓度范围为 50-200 ppm 的聚丙烯酰胺(PAA)和样品;聚环氧乙烷(PEO)的水溶液作为工作流体,并分别使用剪切流变仪和毛细管破裂扩展流变仪(CaBER)对剪切流和扩展流进行了表征。速度场测量包括多孔材料内多个不同孔隙中的速度大小和波动强度,每种测试流体的魏森伯格数 Wi 范围约为 0.01 到 1。全局平均波动强度随 Wi 值的增加而增加,但临界值表明孔隙尺度上的流动开始出现明显的不稳定性(即远高于噪声底线/牛顿基线),其近似恒定值为 Wi≈0.4,比在压降测量中观察到的数据高于牛顿基线的值高出近 40 倍。因此,我们推测,大量流动的压降行为增强可能不是由于孔隙内的局部速度波动,而是由于平均流动效应,至少在数据的很大一部分(Wi≈0.4以下)是这样。
{"title":"Micro-PIV of viscoelastic fluid flow in microporous media","authors":"Victor C. Ibezim , David J.C. Dennis , Robert J. Poole","doi":"10.1016/j.jnnfm.2024.105295","DOIUrl":"10.1016/j.jnnfm.2024.105295","url":null,"abstract":"<div><p>The present experimental investigation combines the bulk flow properties of polymer solutions and measurable rheological parameters as they flow through a distinctive micro-porous structure, with micro-PIV (micro-particle image velocimetry) to measure the velocity distribution and velocity fluctuations within individual pores of a novel porous glass structure. To investigate the effects of fluid elasticity at pore scale, aqueous solutions of a polyacrylamide (PAA) & polyethylene oxide (PEO) in the concentration range of 50–200 ppm, which were characterized in both shear and extensional flows using shear and capillary break-up extensional rheometers (CaBER) respectively, were used as working fluids. The velocity field measurement includes the velocity magnitude and fluctuation intensity in several different pores within the porous material across a Weissenberg number <span><math><mrow><mi>W</mi><mi>i</mi></mrow></math></span> range of approximately 0.01 to 1 for each of the test fluids. The global averaged fluctuation intensity increases with <span><math><mrow><mi>W</mi><mi>i</mi></mrow></math></span> but the critical value, which indicates the onset of significant unsteadiness (i.e. well above noise floor/Newtonian baseline) within the flow at pore scale gives an approximately constant value of <span><math><mrow><mi>W</mi><mi>i</mi><mo>≈</mo></mrow></math></span>0.4, which is almost 40 times higher than the value that is observed in the pressure-drop measurements for the data to rise above the Newtonian base line. We therefore postulate that the enhanced pressure-drop behaviour of the bulk flow may not be due to local velocity fluctuations within the pores but due to mean flow effects, at least over a significant portion of the data (up to <span><math><mrow><mi>W</mi><mi>i</mi><mo>≈</mo></mrow></math></span>0.4).</p></div>","PeriodicalId":54782,"journal":{"name":"Journal of Non-Newtonian Fluid Mechanics","volume":"332 ","pages":"Article 105295"},"PeriodicalIF":2.7,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0377025724001113/pdfft?md5=a43a620daf8334c96025b7999426f7b0&pid=1-s2.0-S0377025724001113-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141990463","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-05DOI: 10.1016/j.jnnfm.2024.105296
Mónica S.N. Oliveira , Konstantinos Zografos , Marco Ellero , Patrick D. Anderson , Robert J. Poole
{"title":"Editorial for XXI International Workshop on Numerical Methods for non-Newtonian Flows 2023","authors":"Mónica S.N. Oliveira , Konstantinos Zografos , Marco Ellero , Patrick D. Anderson , Robert J. Poole","doi":"10.1016/j.jnnfm.2024.105296","DOIUrl":"10.1016/j.jnnfm.2024.105296","url":null,"abstract":"","PeriodicalId":54782,"journal":{"name":"Journal of Non-Newtonian Fluid Mechanics","volume":"332 ","pages":"Article 105296"},"PeriodicalIF":2.7,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142171858","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-08-01DOI: 10.1016/j.jnnfm.2024.105258
Ken Walters was one of the most prominent rheologists of recent times. He brought his mathematical training to rheology and pioneered analysis of many common test procedures. In order to do this he contributed to the formation of nonlinear constitutive equations for viscoelastic fluids and he was an early exponent of computational studies in rheology. He also applied his skills in fruitful collaborations with industry - notably the oil and china clay industries. He was born in Swansea, South Wales, in 1934 and he remained a devoted Welshman despite travelling widely. His academic studies in Swansea with James Oldroyd led to the PhD degree in 1959. In 1960, after a stint in the U.S.A., he was appointed as a Lecturer at Aberystwyth, and he remained there until his death in 2022. He built a very strong research team at Aberystwyth which became a dominant factor in the rheological scene in the United Kingdom.
He was a keen promoter of rheology and he assisted in the organisation of many conferences and meetings. He was the founding Editor of the Journal of Non-Newtonian Fluid Mechanics (JNNFM). He authored or co-authored four well-known books on rheology plus several tracts of a religious nature - Ken was always a devoted Christian. He was also a very able sportsman especially at cricket and golf. He is survived by his wife Mary, three children and seven grandchildren.
{"title":"The life and work of Ken Walters FRS (1934-2022)","authors":"","doi":"10.1016/j.jnnfm.2024.105258","DOIUrl":"10.1016/j.jnnfm.2024.105258","url":null,"abstract":"<div><p>Ken Walters was one of the most prominent rheologists of recent times. He brought his mathematical training to rheology and pioneered analysis of many common test procedures. In order to do this he contributed to the formation of nonlinear constitutive equations for viscoelastic fluids and he was an early exponent of computational studies in rheology. He also applied his skills in fruitful collaborations with industry - notably the oil and china clay industries. He was born in Swansea, South Wales, in 1934 and he remained a devoted Welshman despite travelling widely. His academic studies in Swansea with James Oldroyd led to the PhD degree in 1959. In 1960, after a stint in the U.S.A., he was appointed as a Lecturer at Aberystwyth, and he remained there until his death in 2022. He built a very strong research team at Aberystwyth which became a dominant factor in the rheological scene in the United Kingdom.</p><p>He was a keen promoter of rheology and he assisted in the organisation of many conferences and meetings. He was the founding Editor of the Journal of Non-Newtonian Fluid Mechanics (JNNFM). He authored or co-authored four well-known books on rheology plus several tracts of a religious nature - Ken was always a devoted Christian. He was also a very able sportsman especially at cricket and golf. He is survived by his wife Mary, three children and seven grandchildren.</p></div>","PeriodicalId":54782,"journal":{"name":"Journal of Non-Newtonian Fluid Mechanics","volume":"330 ","pages":"Article 105258"},"PeriodicalIF":2.7,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141024695","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-26DOI: 10.1016/j.jnnfm.2024.105294
Jianyi Du , Hiroko Ohtani , Kevin Ellwood , Gareth H. McKinley
A number of commercial fluids, including synthetic automotive oils, food and consumer products containing polymer additives exhibit weakly rate-thickening responses in the final stages of capillarity-driven thinning, where a large accumulated strain and high extensional strain rate alter the thinning dynamics of the slender liquid filament. Consequently, measurements of capillarity-driven thinning dynamics typically feature two distinct regions at the early and late stages of the filament breakup process, each dominated by distinct mechanisms. These features have been incorporated in a simple Inelastic Rate-Thickening (IRT) model with linear and quadratic contributions to the constitutive stress–strain rate relationship, in which the apparent extensional viscosity slowly thickens at high strain rates. We numerically compute the thinning dynamics of the IRT model assuming an axially-slender axisymmetric filament and no fluid inertia. The computational results motivate a similarity transformation and we obtain a new self-similar solution in which the second-order stress is balanced by capillarity. The new asymptotic solution leads to a self-similar filament shape that is more slender than the Newtonian counterpart and, close to singularity, results in a quadratic dependence of the mid-point radius of the filament with time to breakup. A new and distinct asymptotic geometric correction factor, is derived and we show that a more accurate value of the true extensional viscosity in a rate-thickening fluid can be recovered from an interpolated time-varying geometric correction factor based on the magnitudes of different stress components. Finally, we propose a statistically data-driven protocol to select the best-fit constitutive model using a parameter-free information criterion. This enables us to more accurately quantify the extensional rheological behavior of complex rate-thickening viscoelastic fluids using capillarity-driven thinning dynamics.
{"title":"Capillarity-driven thinning and breakup of weakly rate-thickening fluids","authors":"Jianyi Du , Hiroko Ohtani , Kevin Ellwood , Gareth H. McKinley","doi":"10.1016/j.jnnfm.2024.105294","DOIUrl":"10.1016/j.jnnfm.2024.105294","url":null,"abstract":"<div><p>A number of commercial fluids, including synthetic automotive oils, food and consumer products containing polymer additives exhibit weakly rate-thickening responses in the final stages of capillarity-driven thinning, where a large accumulated strain and high extensional strain rate alter the thinning dynamics of the slender liquid filament. Consequently, measurements of capillarity-driven thinning dynamics typically feature two distinct regions at the early and late stages of the filament breakup process, each dominated by distinct mechanisms. These features have been incorporated in a simple Inelastic Rate-Thickening (IRT) model with linear and quadratic contributions to the constitutive stress–strain rate relationship, in which the apparent extensional viscosity slowly thickens at high strain rates. We numerically compute the thinning dynamics of the IRT model assuming an axially-slender axisymmetric filament and no fluid inertia. The computational results motivate a similarity transformation and we obtain a new self-similar solution in which the second-order stress is balanced by capillarity. The new asymptotic solution leads to a self-similar filament shape that is more slender than the Newtonian counterpart and, close to singularity, results in a quadratic dependence of the mid-point radius of the filament with time to breakup. A new and distinct asymptotic geometric correction factor, <span><math><mrow><mi>X</mi><mo>≈</mo><mn>0</mn><mo>.</mo><mn>5827</mn></mrow></math></span> is derived and we show that a more accurate value of the true extensional viscosity in a rate-thickening fluid can be recovered from an interpolated time-varying geometric correction factor based on the magnitudes of different stress components. Finally, we propose a statistically data-driven protocol to select the best-fit constitutive model using a parameter-free information criterion. This enables us to more accurately quantify the extensional rheological behavior of complex rate-thickening viscoelastic fluids using capillarity-driven thinning dynamics.</p></div>","PeriodicalId":54782,"journal":{"name":"Journal of Non-Newtonian Fluid Mechanics","volume":"331 ","pages":"Article 105294"},"PeriodicalIF":2.7,"publicationDate":"2024-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141865149","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-24DOI: 10.1016/j.jnnfm.2024.105282
Rafael A. Figueiredo , Cassio M. Oishi , Fernando T. Pinho , Roney L. Thompson
Abrupt contraction flows involving viscoelastic fluids represent a longstanding computational challenge within the field of non-Newtonian fluid mechanics. Despite the apparent simplicity of the geometry, these flows have given rise to intricate discussions in the study of viscoelastic phenomena. This study aims to re-examine the numerical solutions for flows through abrupt contractions, offering a fresh interpretation through the lens of reformulated dimensionless numbers. These numbers are designed to consider the characteristic shear rate of the problem, providing a more comprehensive understanding of the underlying dynamics.
When investigating models with intermediate levels of complexity, such as the Giesekus and Phan-Thien-Tanner constitutive equations, the usual comparison with the corresponding Oldroyd-B model becomes inadequate because it tends to rely on the nominal relaxation time () and the nominal total viscosity () instead of their effective counterparts when defining the Reynolds number (), the Weissenberg number () and the ratio of solvent to total viscosities () ( plays a role only in rheological models involving a solvent contribution). If these dimensionless numbers are tailored to account for the characteristic shear rate specific to the problem under investigation, the choice of the corresponding Oldroyd-B flow, at the adequate values of , , and allows for significantly better quantification of the correct effects of nonlinear viscoelasticity of the original model.
We show the conventional approach tends to overemphasize the role of the nonlinear parameter in nonlinear constitutive equations, like the Giesekus and PTT models, when examining standard abrupt contraction flow outputs such as the Couette correction and vortex size. This overestimation occurs because the conventional method does not allow the Reynolds and Weissenberg numbers (and possibly ) to carry the portion of the nonlinear effect that can potentially be captured by the linear Oldroyd-B model through the use of characteristic shear rate-based values. We believe the present approach provides a better perspective of the role played by the nonlinear parameter and its extension to more general flows is also discussed.
{"title":"On more insightful dimensionless numbers for computational viscoelastic rheology","authors":"Rafael A. Figueiredo , Cassio M. Oishi , Fernando T. Pinho , Roney L. Thompson","doi":"10.1016/j.jnnfm.2024.105282","DOIUrl":"10.1016/j.jnnfm.2024.105282","url":null,"abstract":"<div><p>Abrupt contraction flows involving viscoelastic fluids represent a longstanding computational challenge within the field of non-Newtonian fluid mechanics. Despite the apparent simplicity of the geometry, these flows have given rise to intricate discussions in the study of viscoelastic phenomena. This study aims to re-examine the numerical solutions for flows through abrupt contractions, offering a fresh interpretation through the lens of reformulated dimensionless numbers. These numbers are designed to consider the characteristic shear rate of the problem, providing a more comprehensive understanding of the underlying dynamics.</p><p>When investigating models with intermediate levels of complexity, such as the Giesekus and Phan-Thien-Tanner constitutive equations, the usual comparison with the corresponding Oldroyd-B model becomes inadequate because it tends to rely on the nominal relaxation time (<span><math><mi>λ</mi></math></span>) and the nominal total viscosity (<span><math><mi>η</mi></math></span>) instead of their effective counterparts when defining the Reynolds number (<span><math><mrow><mi>R</mi><mi>e</mi></mrow></math></span>), the Weissenberg number (<span><math><mrow><mi>W</mi><mi>i</mi></mrow></math></span>) and the ratio of solvent to total viscosities (<span><math><mi>β</mi></math></span>) (<span><math><mi>β</mi></math></span> plays a role only in rheological models involving a solvent contribution). If these dimensionless numbers are tailored to account for the characteristic shear rate specific to the problem under investigation, the choice of the corresponding Oldroyd-B flow, at the adequate values of <span><math><mrow><mi>R</mi><mi>e</mi></mrow></math></span>, <span><math><mrow><mi>W</mi><mi>i</mi></mrow></math></span>, and <span><math><mi>β</mi></math></span> allows for significantly better quantification of the correct effects of nonlinear viscoelasticity of the original model.</p><p>We show the conventional approach tends to overemphasize the role of the nonlinear parameter in nonlinear constitutive equations, like the Giesekus and PTT models, when examining standard abrupt contraction flow outputs such as the Couette correction and vortex size. This overestimation occurs because the conventional method does not allow the Reynolds and Weissenberg numbers (and possibly <span><math><mi>β</mi></math></span>) to carry the portion of the nonlinear effect that can potentially be captured by the linear Oldroyd-B model through the use of characteristic shear rate-based values. We believe the present approach provides a better perspective of the role played by the nonlinear parameter and its extension to more general flows is also discussed.</p></div>","PeriodicalId":54782,"journal":{"name":"Journal of Non-Newtonian Fluid Mechanics","volume":"331 ","pages":"Article 105282"},"PeriodicalIF":2.7,"publicationDate":"2024-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141852465","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-22DOI: 10.1016/j.jnnfm.2024.105286
Moisés Romero-Ureña , Luis Medina-Torres , Octavio Manero , J. Esteban López-Aguilar
<div><p>In this work, we present a systematic study based on Small-Angle Light Scattering (SALS) patterns of the simple shear flow response of semi-diluted solutions of cetyltrimethylammonium tosylate (CTAT; 5.5 <span><math><mrow><mi>w</mi><mi>t</mi><mo>.</mo><mtext>%</mtext></mrow></math></span> - 0.12 M) in the presence of sodium bromide (NaBr) at different <span><math><mrow><mrow><mo>[</mo><mi>N</mi><mi>a</mi><mi>B</mi><mi>r</mi><mo>]</mo></mrow><mo>=</mo><mrow><mo>{</mo><mn>0</mn><mo>,</mo><mn>0</mn><mo>.</mo><mn>12</mn><mo>,</mo><mn>0</mn><mo>.</mo><mn>19</mn><mo>,</mo><mn>0</mn><mo>.</mo><mn>25</mn><mo>,</mo><mn>0</mn><mo>.</mo><mn>3</mn><mo>}</mo></mrow></mrow></math></span> M concentrations. We evidence a relationship between rheological and light scattering data that reveals a transition into a fast-breaking regime in the dynamics of wormlike micelles formed by the CTAT/NaBr system (Macías et al., 2011; Fierro et al., 2021). This transition into a micellar fast-breaking regime with salt addition (<span><math><mrow><mrow><mo>[</mo><mi>N</mi><mi>a</mi><mi>B</mi><mi>r</mi><mo>]</mo></mrow><mo>≥</mo><mn>0</mn></mrow></math></span>) appears marked by the following features: (i) a decrease in the relaxation time of the material <span><math><msub><mrow><mi>λ</mi></mrow><mrow><mn>0</mn></mrow></msub></math></span>, accompanied by (ii) a decrease of the viscosity level at low shear rates <span><math><msub><mrow><mi>η</mi></mrow><mrow><mn>0</mn></mrow></msub></math></span> (Macías et al., 2011; Fierro et al., 2021; Schubert et al., 2003; Alkschbirs et al., 2015; Bandyopadhyay et al., 2003). With these, (iii) the formation of butterfly-like patterns is recorded originating from concentration fluctuations, evolution that is accompanied by: (iv) shear banding in the form of non-monotonic flow curves and (v) slow oscillatory transient responses in start-up flow tests captured theoretically with the Bautista–Manero–Puig (BMP) model. In addition, the Cox–Merz rule is fulfilled at molar salt-to-surfactant ratios of <span><math><mrow><mi>R</mi><mo>≥</mo><mn>1</mn><mo>.</mo><mn>5</mn></mrow></math></span>. This results in shorter structure-recovery time-scales than the characteristic-time of the flow (Macías et al., 2011; Fierro et al., 2021; Manero et al., 2002). In the case of the elastic modulus <span><math><msub><mrow><mi>G</mi></mrow><mrow><mn>0</mn></mrow></msub></math></span>, the variation was small, which suggests a transition from an entangled to a multiconnected network, as suggested by Kadoma & van Egmond (1997), Kadoma et al. (1997) and Fierro et al. (2021). <em>From a theoretical perspective</em>, we provide predictions for the shear–stress and the first normal-stress growth coefficients in transient start-up simple shear flow using the BMP model. Here, banding <span><math><mi>R</mi></math></span>=1.5 solutions display overshot responses at relatively high shear rates (<span><math><mrow><mover><mrow><mi>γ</mi></mrow><mrow><mo>̇</mo></mrow
{"title":"Rheo-optics of giant micelles: SALS patterns of cetyltrimethylammonium tosylate solutions in presence of sodium bromide","authors":"Moisés Romero-Ureña , Luis Medina-Torres , Octavio Manero , J. Esteban López-Aguilar","doi":"10.1016/j.jnnfm.2024.105286","DOIUrl":"10.1016/j.jnnfm.2024.105286","url":null,"abstract":"<div><p>In this work, we present a systematic study based on Small-Angle Light Scattering (SALS) patterns of the simple shear flow response of semi-diluted solutions of cetyltrimethylammonium tosylate (CTAT; 5.5 <span><math><mrow><mi>w</mi><mi>t</mi><mo>.</mo><mtext>%</mtext></mrow></math></span> - 0.12 M) in the presence of sodium bromide (NaBr) at different <span><math><mrow><mrow><mo>[</mo><mi>N</mi><mi>a</mi><mi>B</mi><mi>r</mi><mo>]</mo></mrow><mo>=</mo><mrow><mo>{</mo><mn>0</mn><mo>,</mo><mn>0</mn><mo>.</mo><mn>12</mn><mo>,</mo><mn>0</mn><mo>.</mo><mn>19</mn><mo>,</mo><mn>0</mn><mo>.</mo><mn>25</mn><mo>,</mo><mn>0</mn><mo>.</mo><mn>3</mn><mo>}</mo></mrow></mrow></math></span> M concentrations. We evidence a relationship between rheological and light scattering data that reveals a transition into a fast-breaking regime in the dynamics of wormlike micelles formed by the CTAT/NaBr system (Macías et al., 2011; Fierro et al., 2021). This transition into a micellar fast-breaking regime with salt addition (<span><math><mrow><mrow><mo>[</mo><mi>N</mi><mi>a</mi><mi>B</mi><mi>r</mi><mo>]</mo></mrow><mo>≥</mo><mn>0</mn></mrow></math></span>) appears marked by the following features: (i) a decrease in the relaxation time of the material <span><math><msub><mrow><mi>λ</mi></mrow><mrow><mn>0</mn></mrow></msub></math></span>, accompanied by (ii) a decrease of the viscosity level at low shear rates <span><math><msub><mrow><mi>η</mi></mrow><mrow><mn>0</mn></mrow></msub></math></span> (Macías et al., 2011; Fierro et al., 2021; Schubert et al., 2003; Alkschbirs et al., 2015; Bandyopadhyay et al., 2003). With these, (iii) the formation of butterfly-like patterns is recorded originating from concentration fluctuations, evolution that is accompanied by: (iv) shear banding in the form of non-monotonic flow curves and (v) slow oscillatory transient responses in start-up flow tests captured theoretically with the Bautista–Manero–Puig (BMP) model. In addition, the Cox–Merz rule is fulfilled at molar salt-to-surfactant ratios of <span><math><mrow><mi>R</mi><mo>≥</mo><mn>1</mn><mo>.</mo><mn>5</mn></mrow></math></span>. This results in shorter structure-recovery time-scales than the characteristic-time of the flow (Macías et al., 2011; Fierro et al., 2021; Manero et al., 2002). In the case of the elastic modulus <span><math><msub><mrow><mi>G</mi></mrow><mrow><mn>0</mn></mrow></msub></math></span>, the variation was small, which suggests a transition from an entangled to a multiconnected network, as suggested by Kadoma & van Egmond (1997), Kadoma et al. (1997) and Fierro et al. (2021). <em>From a theoretical perspective</em>, we provide predictions for the shear–stress and the first normal-stress growth coefficients in transient start-up simple shear flow using the BMP model. Here, banding <span><math><mi>R</mi></math></span>=1.5 solutions display overshot responses at relatively high shear rates (<span><math><mrow><mover><mrow><mi>γ</mi></mrow><mrow><mo>̇</mo></mrow","PeriodicalId":54782,"journal":{"name":"Journal of Non-Newtonian Fluid Mechanics","volume":"331 ","pages":"Article 105286"},"PeriodicalIF":2.7,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141784724","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-14DOI: 10.1016/j.jnnfm.2024.105284
Nazih Assaad Al Ayoubi , Hugues Digonnet , Luisa Silva , Christophe Binetruy , Thierry Renault , Sebastien Comas-Cardona
This work aims to introduce a groundbreaking approach by directly computing the Fokker–Planck equation, providing a mesoscopic scale orientation indicator based on the 2D-probability density function (PDF) of the fibers’ orientation state. Unlike conventional methods that rely on pre-averaged quantities and closure approximations, our method offers enhanced accuracy and information preservation. The model’s enhanced accuracy can be served as a foundational tool for future studies, enabling the development of comprehensive models describing the fluid-flow coupling problem with precision. Consequently, this advancement facilitates the simulation of real-case scenarios, such as the dynamic motion of fibers during the injection phase of molten thermoplastics within a mold cavity. The novelty of this work lies in its application of the Streamline-Upwind/Petrov–Galerkin (SUPG) finite element method, on both orientation and physical spaces. Our model shows the potential to improve the understanding and prediction of fiber behavior in industrial applications, offering valuable insights into process optimization and design. Implemented within a finite element framework, a comprehensive investigation is conducted into the effects of mesh refinement, time scheme, and time stepping on the computational modeling of the PDF evolution, aiming to strike an optimal balance between model precision and computational efficiency. The validation tests were conducted for the case of simple shear flow to examine the influence of the interaction coefficient and the fiber shape factor on the resolution of the probability distribution function. The numerical results demonstrate the evolution of fiber orientation over time under Poiseuille flow conditions.
这项工作旨在引入一种开创性的方法,通过直接计算福克-普朗克方程,提供基于纤维取向状态的二维概率密度函数(PDF)的中观尺度取向指标。与依赖预平均量和闭合近似值的传统方法不同,我们的方法具有更高的精度和信息保存能力。该模型精度的提高可作为未来研究的基础工具,从而开发出精确描述流体-流动耦合问题的综合模型。因此,这一进步有助于模拟实际情况,如熔融热塑性塑料在模腔内注射阶段纤维的动态运动。这项工作的新颖之处在于将流线-上风/Petrov-Galerkin(SUPG)有限元方法应用于定向和物理空间。我们的模型显示了在工业应用中提高对纤维行为的理解和预测的潜力,为工艺优化和设计提供了宝贵的见解。我们在有限元框架内对网格细化、时间方案和时间步长对 PDF 演化计算建模的影响进行了全面研究,旨在实现模型精度和计算效率之间的最佳平衡。在简单剪切流的情况下进行了验证测试,以检验相互作用系数 CI 和纤维形状系数 λ 对概率分布函数分辨率的影响。数值结果表明了在波瓦流条件下纤维取向随时间的演变。
{"title":"Simulation of the fiber orientation through a finite element approach to solve the Fokker–Planck equation","authors":"Nazih Assaad Al Ayoubi , Hugues Digonnet , Luisa Silva , Christophe Binetruy , Thierry Renault , Sebastien Comas-Cardona","doi":"10.1016/j.jnnfm.2024.105284","DOIUrl":"10.1016/j.jnnfm.2024.105284","url":null,"abstract":"<div><p>This work aims to introduce a groundbreaking approach by directly computing the Fokker–Planck equation, providing a mesoscopic scale orientation indicator based on the 2D-probability density function (PDF) of the fibers’ orientation state. Unlike conventional methods that rely on pre-averaged quantities and closure approximations, our method offers enhanced accuracy and information preservation. The model’s enhanced accuracy can be served as a foundational tool for future studies, enabling the development of comprehensive models describing the fluid-flow coupling problem with precision. Consequently, this advancement facilitates the simulation of real-case scenarios, such as the dynamic motion of fibers during the injection phase of molten thermoplastics within a mold cavity. The novelty of this work lies in its application of the Streamline-Upwind/Petrov–Galerkin (SUPG) finite element method, on both orientation and physical spaces. Our model shows the potential to improve the understanding and prediction of fiber behavior in industrial applications, offering valuable insights into process optimization and design. Implemented within a finite element framework, a comprehensive investigation is conducted into the effects of mesh refinement, time scheme, and time stepping on the computational modeling of the PDF evolution, aiming to strike an optimal balance between model precision and computational efficiency. The validation tests were conducted for the case of simple shear flow to examine the influence of the interaction coefficient <span><math><msub><mrow><mi>C</mi></mrow><mrow><mi>I</mi></mrow></msub></math></span> and the fiber shape factor <span><math><mi>λ</mi></math></span> on the resolution of the probability distribution function. The numerical results demonstrate the evolution of fiber orientation over time under Poiseuille flow conditions.</p></div>","PeriodicalId":54782,"journal":{"name":"Journal of Non-Newtonian Fluid Mechanics","volume":"331 ","pages":"Article 105284"},"PeriodicalIF":2.7,"publicationDate":"2024-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0377025724001009/pdfft?md5=850e214e156a14bfa4e6229f1726263d&pid=1-s2.0-S0377025724001009-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141689187","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-07DOI: 10.1016/j.jnnfm.2024.105285
H A Barnes , I A Frigaard , G H McKinley , T N Phillips , R J Poole , R I Tanner
In this short Editorial to support the Commemorative Special Issue in honour of our founding Editor, Professor Ken Walters FRS, we draw together a series of informal “reflections” from current (and previous) Editors of the Journal, together with a number of his key collaborators.
{"title":"Ken Walters: Reflections","authors":"H A Barnes , I A Frigaard , G H McKinley , T N Phillips , R J Poole , R I Tanner","doi":"10.1016/j.jnnfm.2024.105285","DOIUrl":"10.1016/j.jnnfm.2024.105285","url":null,"abstract":"<div><p>In this short Editorial to support the Commemorative Special Issue in honour of our founding Editor, Professor Ken Walters FRS, we draw together a series of informal “reflections” from current (and previous) Editors of the Journal, together with a number of his key collaborators.</p></div>","PeriodicalId":54782,"journal":{"name":"Journal of Non-Newtonian Fluid Mechanics","volume":"331 ","pages":"Article 105285"},"PeriodicalIF":2.7,"publicationDate":"2024-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141708135","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}