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Non-Newtonian behaviors of ferrofluid Couette–Poiseuille flows in time-varying magnetic fields 时变磁场中铁流体库埃特-普绪耶流动的非牛顿行为
IF 2.7 2区 工程技术 Q2 MECHANICS Pub Date : 2024-08-25 DOI: 10.1016/j.jnnfm.2024.105306
Wenming Yang , Yifan Li , Jiantuo Ren , Xiaolong Yang

We analyze the fully developed Couette–Poiseuille flows of ferrofluids between two parallel flat walls subject to three types of time-varying magnetic fields. In these scenarios, ferrofluids exhibit diverse non-Newtonian characteristics such as distinct flow velocity distribution, apparent viscosity and shear stress compared to ordinary Couette–Poiseuille flows. The influence of spin viscosity is explored first through the solution of the governing equations with zero and non-zero spin viscosities. It shows that although the value of the spin viscosity is very small, its inviscid limit would have great influence over the velocity and spin velocity distributions. The assumption of zero spin viscosity leads to an exaggerated non-Newtonian behavior induced by time-varying magnetic fields in the ferrofluid Couette–Poiseuille flows. Then the solutions of equations with non-zero spin viscosity are utilized to delve into non-Newtonian behaviors of ferrofluid Couette–Poiseuille flow under the application of the three time-varying magnetic fields. The results indicate that negative rotational viscosity will occur if the dimensionless frequency lies in the range 1–10, which is a distinguishing feature compared with Newtonian flows. At this point, non-Newtonian flow induced by magnetic field arises, although this effect is very tiny. Within the same frequency range, reversed tangential stress appears in strong uniform alternating magnetic fields. The minimum negative rotational viscosity may arrive at up to 20 % of the intrinsic viscosity in the rotating magnetic field when the magnetization relaxation time is 4 ms.

我们分析了在三种时变磁场作用下,铁流体在两平行平壁之间完全发展的库埃特-普瓦耶流。在这些情况下,与普通库埃特-普瓦耶流相比,铁流体表现出多种非牛顿特性,如不同的流速分布、表观粘度和剪应力。我们首先通过求解自旋粘度为零和非零的控制方程,探讨了自旋粘度的影响。结果表明,虽然自旋粘度值非常小,但其不粘性极限会对速度和自旋速度分布产生很大影响。自旋粘度为零的假设导致铁流体库埃特-普绪耶流中由时变磁场引起的夸张非牛顿行为。然后,利用非零自旋粘度方程的解,深入研究了铁流体在三个时变磁场作用下的非牛顿流体行为。结果表明,如果无量纲频率在 1-10 范围内,就会出现负旋转粘度,这是与牛顿流体相比的一个显著特点。此时,磁场诱导的非牛顿流会出现,尽管这种影响非常微小。在同一频率范围内,强均匀交变磁场中会出现反切应力。当磁化弛豫时间为 4 毫秒时,旋转磁场中的最小负旋转粘度可达固有粘度的 20%。
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引用次数: 0
Preface to Special Visual Issue: E Mitsoulis 视觉特刊序言:E Mitsoulis
IF 2.7 2区 工程技术 Q2 MECHANICS Pub Date : 2024-08-06 DOI: 10.1016/j.jnnfm.2024.105297
Yannis E. Dimakopoulos , Georgios C. Georgiou
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引用次数: 0
Micro-PIV of viscoelastic fluid flow in microporous media 微孔介质中粘弹性流体流动的微观 PIV 分析
IF 2.7 2区 工程技术 Q2 MECHANICS Pub Date : 2024-08-05 DOI: 10.1016/j.jnnfm.2024.105295
Victor C. Ibezim , David J.C. Dennis , Robert J. Poole

The present experimental investigation combines the bulk flow properties of polymer solutions and measurable rheological parameters as they flow through a distinctive micro-porous structure, with micro-PIV (micro-particle image velocimetry) to measure the velocity distribution and velocity fluctuations within individual pores of a novel porous glass structure. To investigate the effects of fluid elasticity at pore scale, aqueous solutions of a polyacrylamide (PAA) & polyethylene oxide (PEO) in the concentration range of 50–200 ppm, which were characterized in both shear and extensional flows using shear and capillary break-up extensional rheometers (CaBER) respectively, were used as working fluids. The velocity field measurement includes the velocity magnitude and fluctuation intensity in several different pores within the porous material across a Weissenberg number Wi range of approximately 0.01 to 1 for each of the test fluids. The global averaged fluctuation intensity increases with Wi but the critical value, which indicates the onset of significant unsteadiness (i.e. well above noise floor/Newtonian baseline) within the flow at pore scale gives an approximately constant value of Wi0.4, which is almost 40 times higher than the value that is observed in the pressure-drop measurements for the data to rise above the Newtonian base line. We therefore postulate that the enhanced pressure-drop behaviour of the bulk flow may not be due to local velocity fluctuations within the pores but due to mean flow effects, at least over a significant portion of the data (up to Wi0.4).

本实验研究将聚合物溶液流经独特微孔结构时的体积流动特性和可测量的流变参数与微颗粒图像测速仪(micro-PIV)相结合,测量新型多孔玻璃结构单个孔隙内的速度分布和速度波动。为了研究孔隙尺度上流体弹性的影响,使用了浓度范围为 50-200 ppm 的聚丙烯酰胺(PAA)和样品;聚环氧乙烷(PEO)的水溶液作为工作流体,并分别使用剪切流变仪和毛细管破裂扩展流变仪(CaBER)对剪切流和扩展流进行了表征。速度场测量包括多孔材料内多个不同孔隙中的速度大小和波动强度,每种测试流体的魏森伯格数 Wi 范围约为 0.01 到 1。全局平均波动强度随 Wi 值的增加而增加,但临界值表明孔隙尺度上的流动开始出现明显的不稳定性(即远高于噪声底线/牛顿基线),其近似恒定值为 Wi≈0.4,比在压降测量中观察到的数据高于牛顿基线的值高出近 40 倍。因此,我们推测,大量流动的压降行为增强可能不是由于孔隙内的局部速度波动,而是由于平均流动效应,至少在数据的很大一部分(Wi≈0.4以下)是这样。
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引用次数: 0
Editorial for XXI International Workshop on Numerical Methods for non-Newtonian Flows 2023 为 2023 年第 XXI 届非牛顿流体数值方法国际研讨会撰稿
IF 2.7 2区 工程技术 Q2 MECHANICS Pub Date : 2024-08-05 DOI: 10.1016/j.jnnfm.2024.105296
Mónica S.N. Oliveira , Konstantinos Zografos , Marco Ellero , Patrick D. Anderson , Robert J. Poole
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引用次数: 0
The life and work of Ken Walters FRS (1934-2022) 肯尼斯-沃尔特斯 1934-2022
IF 2.7 2区 工程技术 Q2 MECHANICS Pub Date : 2024-08-01 DOI: 10.1016/j.jnnfm.2024.105258

Ken Walters was one of the most prominent rheologists of recent times. He brought his mathematical training to rheology and pioneered analysis of many common test procedures. In order to do this he contributed to the formation of nonlinear constitutive equations for viscoelastic fluids and he was an early exponent of computational studies in rheology. He also applied his skills in fruitful collaborations with industry - notably the oil and china clay industries. He was born in Swansea, South Wales, in 1934 and he remained a devoted Welshman despite travelling widely. His academic studies in Swansea with James Oldroyd led to the PhD degree in 1959. In 1960, after a stint in the U.S.A., he was appointed as a Lecturer at Aberystwyth, and he remained there until his death in 2022. He built a very strong research team at Aberystwyth which became a dominant factor in the rheological scene in the United Kingdom.

He was a keen promoter of rheology and he assisted in the organisation of many conferences and meetings. He was the founding Editor of the Journal of Non-Newtonian Fluid Mechanics (JNNFM). He authored or co-authored four well-known books on rheology plus several tracts of a religious nature - Ken was always a devoted Christian. He was also a very able sportsman especially at cricket and golf. He is survived by his wife Mary, three children and seven grandchildren.

Ken Walters 是近代最杰出的流变学家之一。他将自己的数学训练带入了流变学领域,并率先对许多常见的测试程序进行了分析。为此,他为粘弹性流体非线性结构方程的形成做出了贡献,同时他也是流变学计算研究的早期倡导者。他还运用自己的技能与工业界--特别是石油和瓷土工业--进行了卓有成效的合作。他于 1934 年出生于南威尔士的斯旺西,尽管四处游历,但他仍然是一个忠实的威尔士人。他在斯旺西跟随詹姆斯-奥尔德罗伊德学习,并于 1959 年获得博士学位。1960 年,在美国工作一段时间后,他被任命为阿伯里斯特威斯大学讲师,直到 2022 年去世。他在阿伯里斯特维斯建立了一支非常强大的研究团队,成为英国流变学领域的主导因素。他热衷于推广流变学,协助组织了许多会议。他是《非牛顿流体力学杂志》(JNNFM)的创刊编辑。他撰写或与人合著了四本著名的流变学书籍,还有几本宗教性质的小册子--Ken 始终是一位虔诚的基督徒。他还是一名出色的运动员,尤其擅长板球和高尔夫球。他的妻子玛丽(Mary)、三个孩子和七个孙子孙女都健在。
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引用次数: 0
Capillarity-driven thinning and breakup of weakly rate-thickening fluids 弱速率增稠流体的毛细管驱动稀化和破裂
IF 2.7 2区 工程技术 Q2 MECHANICS Pub Date : 2024-07-26 DOI: 10.1016/j.jnnfm.2024.105294
Jianyi Du , Hiroko Ohtani , Kevin Ellwood , Gareth H. McKinley

A number of commercial fluids, including synthetic automotive oils, food and consumer products containing polymer additives exhibit weakly rate-thickening responses in the final stages of capillarity-driven thinning, where a large accumulated strain and high extensional strain rate alter the thinning dynamics of the slender liquid filament. Consequently, measurements of capillarity-driven thinning dynamics typically feature two distinct regions at the early and late stages of the filament breakup process, each dominated by distinct mechanisms. These features have been incorporated in a simple Inelastic Rate-Thickening (IRT) model with linear and quadratic contributions to the constitutive stress–strain rate relationship, in which the apparent extensional viscosity slowly thickens at high strain rates. We numerically compute the thinning dynamics of the IRT model assuming an axially-slender axisymmetric filament and no fluid inertia. The computational results motivate a similarity transformation and we obtain a new self-similar solution in which the second-order stress is balanced by capillarity. The new asymptotic solution leads to a self-similar filament shape that is more slender than the Newtonian counterpart and, close to singularity, results in a quadratic dependence of the mid-point radius of the filament with time to breakup. A new and distinct asymptotic geometric correction factor, X0.5827 is derived and we show that a more accurate value of the true extensional viscosity in a rate-thickening fluid can be recovered from an interpolated time-varying geometric correction factor based on the magnitudes of different stress components. Finally, we propose a statistically data-driven protocol to select the best-fit constitutive model using a parameter-free information criterion. This enables us to more accurately quantify the extensional rheological behavior of complex rate-thickening viscoelastic fluids using capillarity-driven thinning dynamics.

许多商用液体(包括合成汽车机油、食品和含有聚合物添加剂的消费品)在毛细管驱动稀化的最后阶段表现出弱速率增稠响应,此时大量累积应变和高延伸应变速率会改变细长液丝的稀化动力学。因此,毛细管驱动的稀化动力学测量通常在丝状物断裂过程的早期和晚期阶段有两个不同的区域,每个区域都由不同的机制主导。这些特征已被纳入一个简单的非弹性速率-增稠(IRT)模型中,该模型的应力-应变速率构成关系具有线性和二次贡献,其中表观延伸粘度在高应变速率下缓慢增稠。我们对 IRT 模型的减薄动力学进行了数值计算,假设轴向细长的轴对称丝状体没有流体惯性。计算结果激发了相似性转换,我们得到了一个新的自相似解,其中二阶应力通过毛细管平衡。新的渐近解导致了比牛顿对应解更加细长的自相似长丝形状,并且在接近奇点时,长丝中点半径与断裂时间呈二次函数关系。我们还推导出了一个新的、独特的渐近几何校正因子,并表明可以根据不同应力分量的大小,从内插的时变几何校正因子中恢复出更准确的速率增稠流体中的真实伸展粘度值。最后,我们提出了一种统计数据驱动的方案,利用无参数信息准则选择最拟合的构成模型。这使我们能够利用毛细管驱动的稀化动力学,更准确地量化复杂的速率增稠粘弹性流体的扩展流变行为。
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引用次数: 0
On more insightful dimensionless numbers for computational viscoelastic rheology 关于计算粘弹性流变学的更具洞察力的无量纲数
IF 2.7 2区 工程技术 Q2 MECHANICS Pub Date : 2024-07-24 DOI: 10.1016/j.jnnfm.2024.105282
Rafael A. Figueiredo , Cassio M. Oishi , Fernando T. Pinho , Roney L. Thompson

Abrupt contraction flows involving viscoelastic fluids represent a longstanding computational challenge within the field of non-Newtonian fluid mechanics. Despite the apparent simplicity of the geometry, these flows have given rise to intricate discussions in the study of viscoelastic phenomena. This study aims to re-examine the numerical solutions for flows through abrupt contractions, offering a fresh interpretation through the lens of reformulated dimensionless numbers. These numbers are designed to consider the characteristic shear rate of the problem, providing a more comprehensive understanding of the underlying dynamics.

When investigating models with intermediate levels of complexity, such as the Giesekus and Phan-Thien-Tanner constitutive equations, the usual comparison with the corresponding Oldroyd-B model becomes inadequate because it tends to rely on the nominal relaxation time (λ) and the nominal total viscosity (η) instead of their effective counterparts when defining the Reynolds number (Re), the Weissenberg number (Wi) and the ratio of solvent to total viscosities (β) (β plays a role only in rheological models involving a solvent contribution). If these dimensionless numbers are tailored to account for the characteristic shear rate specific to the problem under investigation, the choice of the corresponding Oldroyd-B flow, at the adequate values of Re, Wi, and β allows for significantly better quantification of the correct effects of nonlinear viscoelasticity of the original model.

We show the conventional approach tends to overemphasize the role of the nonlinear parameter in nonlinear constitutive equations, like the Giesekus and PTT models, when examining standard abrupt contraction flow outputs such as the Couette correction and vortex size. This overestimation occurs because the conventional method does not allow the Reynolds and Weissenberg numbers (and possibly β) to carry the portion of the nonlinear effect that can potentially be captured by the linear Oldroyd-B model through the use of characteristic shear rate-based values. We believe the present approach provides a better perspective of the role played by the nonlinear parameter and its extension to more general flows is also discussed.

涉及粘弹性流体的突然收缩流动是非牛顿流体力学领域长期存在的计算难题。尽管这些流动的几何形状看似简单,但在粘弹性现象的研究中却引起了错综复杂的讨论。本研究旨在重新审查通过突然收缩的流动的数值解,通过重新制定的无量纲数提供全新的解释。这些数值旨在考虑问题的特征剪切率,从而更全面地了解基本动态。在研究中等复杂程度的模型(如 Giesekus 和 Phan-Thien-Tanner 构成方程)时,通常与相应的 Oldroyd-B 模型进行比较是不够的,因为在定义雷诺数 (Re)、魏森伯格数 (Wi) 和溶剂粘度与总粘度之比 (β)(β 仅在涉及溶剂贡献的流变模型中起作用)时,往往依赖于标称松弛时间 (λ) 和标称总粘度 (η),而不是它们的有效对应值。如果对这些无量纲数进行调整,以考虑到所研究问题特有的特征剪切速率,那么在适当的 Re、Wi 和 β 值下选择相应的 Oldroyd-B 流量,就能更好地量化原始模型非线性粘弹性的正确影响。我们的研究表明,在研究标准的突然收缩流动输出(如库埃特校正和涡旋大小)时,传统方法往往会过分强调非线性构成方程(如 Giesekus 和 PTT 模型)中非线性参数的作用。之所以会出现这种高估,是因为传统方法不允许雷诺数和韦森伯格数(可能还有 β)承载非线性效应的部分,而线性奥尔德罗伊德-B 模型可以通过使用基于特征剪切速率的值来捕捉到这部分效应。我们相信,目前的方法为非线性参数所起的作用提供了一个更好的视角,我们还讨论了将其扩展到更一般流动的问题。
{"title":"On more insightful dimensionless numbers for computational viscoelastic rheology","authors":"Rafael A. Figueiredo ,&nbsp;Cassio M. Oishi ,&nbsp;Fernando T. Pinho ,&nbsp;Roney L. Thompson","doi":"10.1016/j.jnnfm.2024.105282","DOIUrl":"10.1016/j.jnnfm.2024.105282","url":null,"abstract":"<div><p>Abrupt contraction flows involving viscoelastic fluids represent a longstanding computational challenge within the field of non-Newtonian fluid mechanics. Despite the apparent simplicity of the geometry, these flows have given rise to intricate discussions in the study of viscoelastic phenomena. This study aims to re-examine the numerical solutions for flows through abrupt contractions, offering a fresh interpretation through the lens of reformulated dimensionless numbers. These numbers are designed to consider the characteristic shear rate of the problem, providing a more comprehensive understanding of the underlying dynamics.</p><p>When investigating models with intermediate levels of complexity, such as the Giesekus and Phan-Thien-Tanner constitutive equations, the usual comparison with the corresponding Oldroyd-B model becomes inadequate because it tends to rely on the nominal relaxation time (<span><math><mi>λ</mi></math></span>) and the nominal total viscosity (<span><math><mi>η</mi></math></span>) instead of their effective counterparts when defining the Reynolds number (<span><math><mrow><mi>R</mi><mi>e</mi></mrow></math></span>), the Weissenberg number (<span><math><mrow><mi>W</mi><mi>i</mi></mrow></math></span>) and the ratio of solvent to total viscosities (<span><math><mi>β</mi></math></span>) (<span><math><mi>β</mi></math></span> plays a role only in rheological models involving a solvent contribution). If these dimensionless numbers are tailored to account for the characteristic shear rate specific to the problem under investigation, the choice of the corresponding Oldroyd-B flow, at the adequate values of <span><math><mrow><mi>R</mi><mi>e</mi></mrow></math></span>, <span><math><mrow><mi>W</mi><mi>i</mi></mrow></math></span>, and <span><math><mi>β</mi></math></span> allows for significantly better quantification of the correct effects of nonlinear viscoelasticity of the original model.</p><p>We show the conventional approach tends to overemphasize the role of the nonlinear parameter in nonlinear constitutive equations, like the Giesekus and PTT models, when examining standard abrupt contraction flow outputs such as the Couette correction and vortex size. This overestimation occurs because the conventional method does not allow the Reynolds and Weissenberg numbers (and possibly <span><math><mi>β</mi></math></span>) to carry the portion of the nonlinear effect that can potentially be captured by the linear Oldroyd-B model through the use of characteristic shear rate-based values. We believe the present approach provides a better perspective of the role played by the nonlinear parameter and its extension to more general flows is also discussed.</p></div>","PeriodicalId":54782,"journal":{"name":"Journal of Non-Newtonian Fluid Mechanics","volume":"331 ","pages":"Article 105282"},"PeriodicalIF":2.7,"publicationDate":"2024-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141852465","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rheo-optics of giant micelles: SALS patterns of cetyltrimethylammonium tosylate solutions in presence of sodium bromide 巨型胶束的流变光学:存在溴化钠时十六烷基三甲基对甲苯磺酸铵溶液的 SALS 图样
IF 2.7 2区 工程技术 Q2 MECHANICS Pub Date : 2024-07-22 DOI: 10.1016/j.jnnfm.2024.105286
Moisés Romero-Ureña , Luis Medina-Torres , Octavio Manero , J. Esteban López-Aguilar
<div><p>In this work, we present a systematic study based on Small-Angle Light Scattering (SALS) patterns of the simple shear flow response of semi-diluted solutions of cetyltrimethylammonium tosylate (CTAT; 5.5 <span><math><mrow><mi>w</mi><mi>t</mi><mo>.</mo><mtext>%</mtext></mrow></math></span> - 0.12 M) in the presence of sodium bromide (NaBr) at different <span><math><mrow><mrow><mo>[</mo><mi>N</mi><mi>a</mi><mi>B</mi><mi>r</mi><mo>]</mo></mrow><mo>=</mo><mrow><mo>{</mo><mn>0</mn><mo>,</mo><mn>0</mn><mo>.</mo><mn>12</mn><mo>,</mo><mn>0</mn><mo>.</mo><mn>19</mn><mo>,</mo><mn>0</mn><mo>.</mo><mn>25</mn><mo>,</mo><mn>0</mn><mo>.</mo><mn>3</mn><mo>}</mo></mrow></mrow></math></span> M concentrations. We evidence a relationship between rheological and light scattering data that reveals a transition into a fast-breaking regime in the dynamics of wormlike micelles formed by the CTAT/NaBr system (Macías et al., 2011; Fierro et al., 2021). This transition into a micellar fast-breaking regime with salt addition (<span><math><mrow><mrow><mo>[</mo><mi>N</mi><mi>a</mi><mi>B</mi><mi>r</mi><mo>]</mo></mrow><mo>≥</mo><mn>0</mn></mrow></math></span>) appears marked by the following features: (i) a decrease in the relaxation time of the material <span><math><msub><mrow><mi>λ</mi></mrow><mrow><mn>0</mn></mrow></msub></math></span>, accompanied by (ii) a decrease of the viscosity level at low shear rates <span><math><msub><mrow><mi>η</mi></mrow><mrow><mn>0</mn></mrow></msub></math></span> (Macías et al., 2011; Fierro et al., 2021; Schubert et al., 2003; Alkschbirs et al., 2015; Bandyopadhyay et al., 2003). With these, (iii) the formation of butterfly-like patterns is recorded originating from concentration fluctuations, evolution that is accompanied by: (iv) shear banding in the form of non-monotonic flow curves and (v) slow oscillatory transient responses in start-up flow tests captured theoretically with the Bautista–Manero–Puig (BMP) model. In addition, the Cox–Merz rule is fulfilled at molar salt-to-surfactant ratios of <span><math><mrow><mi>R</mi><mo>≥</mo><mn>1</mn><mo>.</mo><mn>5</mn></mrow></math></span>. This results in shorter structure-recovery time-scales than the characteristic-time of the flow (Macías et al., 2011; Fierro et al., 2021; Manero et al., 2002). In the case of the elastic modulus <span><math><msub><mrow><mi>G</mi></mrow><mrow><mn>0</mn></mrow></msub></math></span>, the variation was small, which suggests a transition from an entangled to a multiconnected network, as suggested by Kadoma & van Egmond (1997), Kadoma et al. (1997) and Fierro et al. (2021). <em>From a theoretical perspective</em>, we provide predictions for the shear–stress and the first normal-stress growth coefficients in transient start-up simple shear flow using the BMP model. Here, banding <span><math><mi>R</mi></math></span>=1.5 solutions display overshot responses at relatively high shear rates (<span><math><mrow><mover><mrow><mi>γ</mi></mrow><mrow><mo>̇</mo></mrow
在这项工作中,我们基于小角光散射(SALS)模式对不同 M 浓度的十六烷基三甲基对甲苯磺酸盐(CTAT;5.5 - 0.12 M)半稀释溶液在溴化钠(NaBr)存在下的简单剪切流响应进行了系统研究。我们证明了流变学数据与光散射数据之间的关系,这种关系揭示了 CTAT/NaBr 系统形成的蠕虫状胶束在动力学上向快速破碎体系的过渡(Macías 等人,2011 年;Fierro 等人,2021 年)。随着盐的添加()而过渡到胶束快速断裂机制的过程具有以下特征:(i) 材料的松弛时间缩短,同时 (ii) 低剪切速率下的粘度水平降低(Macías 等人,2011 年;Fierro 等人,2021 年;Schubert 等人,2003 年;Alkschbirs 等人,2015 年;Bandyopadhyay 等人,2003 年)。在此基础上,(iii) 记录到由浓度波动形成的蝴蝶状图案,同时伴随着以下演变:(iv) 在 "蝶形 "中形成剪切带:(iv) 非单调流动曲线形式的剪切带,以及 (v) 启动流动试验中的缓慢振荡瞬态响应,这些都是用 Bautista-Manero-Puig (BMP) 模型从理论上捕捉到的。此外,当摩尔盐与表面活性剂的比率为...时,Cox-Merz 规则将得到满足,这将导致结构恢复的时间尺度短于流动的特征时间(Macías 等人,2011 年;Fierro 等人,2021 年;Manero 等人,2002 年)。就弹性模量而言,变化很小,这表明正如 Kadoma & van Egmond (1997)、Kadoma 等人 (1997) 和 Fierro 等人 (2021) 所指出的那样,存在从缠结网络向多连接网络的过渡。因此,我们利用 BMP 模型对瞬态启动简单剪切流中的剪应力和第一法向应力增长系数进行了预测。在这里,带状 =1.5 溶液在相对较高的剪切速率()下显示出过射响应,这与蠕虫状胶束溶液启动流的实验结果一致(Soltero 等人,1999 年;Lerouge 等人,2004 年;Hu & Lips,2005 年;Pipe 等人,2010 年;Mohammadigoushki 等人,2019 年)。我们的结果与其他调查报告的结果一致(Macías 等人,2011 年;Fierro 等人,2021 年;Schubert 等人,2003 年;Alkschbirs 等人,2015 年;Bandyopadhyay 等人,2003 年;Kadoma 等人,1997 年;Soltero 等人,1999 年;Lerouge 等人,2004 年;Hu & Lips 2005 年;Pipe 等人,2010 年;Mohammadigoushki 等人,2019 年)、1997;Soltero 等人,1999;Lerouge 等人,2004;Hu & Lips 2005;López-Barrón 等人,2014),并揭示了所使用的硼离子对 CTAT-NaBr 系统的机械和光学响应的影响。
{"title":"Rheo-optics of giant micelles: SALS patterns of cetyltrimethylammonium tosylate solutions in presence of sodium bromide","authors":"Moisés Romero-Ureña ,&nbsp;Luis Medina-Torres ,&nbsp;Octavio Manero ,&nbsp;J. Esteban López-Aguilar","doi":"10.1016/j.jnnfm.2024.105286","DOIUrl":"10.1016/j.jnnfm.2024.105286","url":null,"abstract":"&lt;div&gt;&lt;p&gt;In this work, we present a systematic study based on Small-Angle Light Scattering (SALS) patterns of the simple shear flow response of semi-diluted solutions of cetyltrimethylammonium tosylate (CTAT; 5.5 &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;w&lt;/mi&gt;&lt;mi&gt;t&lt;/mi&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mtext&gt;%&lt;/mtext&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; - 0.12 M) in the presence of sodium bromide (NaBr) at different &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mrow&gt;&lt;mo&gt;[&lt;/mo&gt;&lt;mi&gt;N&lt;/mi&gt;&lt;mi&gt;a&lt;/mi&gt;&lt;mi&gt;B&lt;/mi&gt;&lt;mi&gt;r&lt;/mi&gt;&lt;mo&gt;]&lt;/mo&gt;&lt;/mrow&gt;&lt;mo&gt;=&lt;/mo&gt;&lt;mrow&gt;&lt;mo&gt;{&lt;/mo&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;mo&gt;,&lt;/mo&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;12&lt;/mn&gt;&lt;mo&gt;,&lt;/mo&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;19&lt;/mn&gt;&lt;mo&gt;,&lt;/mo&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;25&lt;/mn&gt;&lt;mo&gt;,&lt;/mo&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;3&lt;/mn&gt;&lt;mo&gt;}&lt;/mo&gt;&lt;/mrow&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; M concentrations. We evidence a relationship between rheological and light scattering data that reveals a transition into a fast-breaking regime in the dynamics of wormlike micelles formed by the CTAT/NaBr system (Macías et al., 2011; Fierro et al., 2021). This transition into a micellar fast-breaking regime with salt addition (&lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mrow&gt;&lt;mo&gt;[&lt;/mo&gt;&lt;mi&gt;N&lt;/mi&gt;&lt;mi&gt;a&lt;/mi&gt;&lt;mi&gt;B&lt;/mi&gt;&lt;mi&gt;r&lt;/mi&gt;&lt;mo&gt;]&lt;/mo&gt;&lt;/mrow&gt;&lt;mo&gt;≥&lt;/mo&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;) appears marked by the following features: (i) a decrease in the relaxation time of the material &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;λ&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;, accompanied by (ii) a decrease of the viscosity level at low shear rates &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;η&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt; (Macías et al., 2011; Fierro et al., 2021; Schubert et al., 2003; Alkschbirs et al., 2015; Bandyopadhyay et al., 2003). With these, (iii) the formation of butterfly-like patterns is recorded originating from concentration fluctuations, evolution that is accompanied by: (iv) shear banding in the form of non-monotonic flow curves and (v) slow oscillatory transient responses in start-up flow tests captured theoretically with the Bautista–Manero–Puig (BMP) model. In addition, the Cox–Merz rule is fulfilled at molar salt-to-surfactant ratios of &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mi&gt;R&lt;/mi&gt;&lt;mo&gt;≥&lt;/mo&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;mo&gt;.&lt;/mo&gt;&lt;mn&gt;5&lt;/mn&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;. This results in shorter structure-recovery time-scales than the characteristic-time of the flow (Macías et al., 2011; Fierro et al., 2021; Manero et al., 2002). In the case of the elastic modulus &lt;span&gt;&lt;math&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mi&gt;G&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/math&gt;&lt;/span&gt;, the variation was small, which suggests a transition from an entangled to a multiconnected network, as suggested by Kadoma &amp; van Egmond (1997), Kadoma et al. (1997) and Fierro et al. (2021). &lt;em&gt;From a theoretical perspective&lt;/em&gt;, we provide predictions for the shear–stress and the first normal-stress growth coefficients in transient start-up simple shear flow using the BMP model. Here, banding &lt;span&gt;&lt;math&gt;&lt;mi&gt;R&lt;/mi&gt;&lt;/math&gt;&lt;/span&gt;=1.5 solutions display overshot responses at relatively high shear rates (&lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mover&gt;&lt;mrow&gt;&lt;mi&gt;γ&lt;/mi&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mo&gt;̇&lt;/mo&gt;&lt;/mrow","PeriodicalId":54782,"journal":{"name":"Journal of Non-Newtonian Fluid Mechanics","volume":"331 ","pages":"Article 105286"},"PeriodicalIF":2.7,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141784724","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Simulation of the fiber orientation through a finite element approach to solve the Fokker–Planck equation 通过有限元方法模拟纤维取向,求解福克-普朗克方程
IF 2.7 2区 工程技术 Q2 MECHANICS Pub Date : 2024-07-14 DOI: 10.1016/j.jnnfm.2024.105284
Nazih Assaad Al Ayoubi , Hugues Digonnet , Luisa Silva , Christophe Binetruy , Thierry Renault , Sebastien Comas-Cardona

This work aims to introduce a groundbreaking approach by directly computing the Fokker–Planck equation, providing a mesoscopic scale orientation indicator based on the 2D-probability density function (PDF) of the fibers’ orientation state. Unlike conventional methods that rely on pre-averaged quantities and closure approximations, our method offers enhanced accuracy and information preservation. The model’s enhanced accuracy can be served as a foundational tool for future studies, enabling the development of comprehensive models describing the fluid-flow coupling problem with precision. Consequently, this advancement facilitates the simulation of real-case scenarios, such as the dynamic motion of fibers during the injection phase of molten thermoplastics within a mold cavity. The novelty of this work lies in its application of the Streamline-Upwind/Petrov–Galerkin (SUPG) finite element method, on both orientation and physical spaces. Our model shows the potential to improve the understanding and prediction of fiber behavior in industrial applications, offering valuable insights into process optimization and design. Implemented within a finite element framework, a comprehensive investigation is conducted into the effects of mesh refinement, time scheme, and time stepping on the computational modeling of the PDF evolution, aiming to strike an optimal balance between model precision and computational efficiency. The validation tests were conducted for the case of simple shear flow to examine the influence of the interaction coefficient CI and the fiber shape factor λ on the resolution of the probability distribution function. The numerical results demonstrate the evolution of fiber orientation over time under Poiseuille flow conditions.

这项工作旨在引入一种开创性的方法,通过直接计算福克-普朗克方程,提供基于纤维取向状态的二维概率密度函数(PDF)的中观尺度取向指标。与依赖预平均量和闭合近似值的传统方法不同,我们的方法具有更高的精度和信息保存能力。该模型精度的提高可作为未来研究的基础工具,从而开发出精确描述流体-流动耦合问题的综合模型。因此,这一进步有助于模拟实际情况,如熔融热塑性塑料在模腔内注射阶段纤维的动态运动。这项工作的新颖之处在于将流线-上风/Petrov-Galerkin(SUPG)有限元方法应用于定向和物理空间。我们的模型显示了在工业应用中提高对纤维行为的理解和预测的潜力,为工艺优化和设计提供了宝贵的见解。我们在有限元框架内对网格细化、时间方案和时间步长对 PDF 演化计算建模的影响进行了全面研究,旨在实现模型精度和计算效率之间的最佳平衡。在简单剪切流的情况下进行了验证测试,以检验相互作用系数 CI 和纤维形状系数 λ 对概率分布函数分辨率的影响。数值结果表明了在波瓦流条件下纤维取向随时间的演变。
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引用次数: 0
Ken Walters: Reflections Ken Walters:反思
IF 2.7 2区 工程技术 Q2 MECHANICS Pub Date : 2024-07-07 DOI: 10.1016/j.jnnfm.2024.105285
H A Barnes , I A Frigaard , G H McKinley , T N Phillips , R J Poole , R I Tanner

In this short Editorial to support the Commemorative Special Issue in honour of our founding Editor, Professor Ken Walters FRS, we draw together a series of informal “reflections” from current (and previous) Editors of the Journal, together with a number of his key collaborators.

为了支持纪念创刊编辑肯-沃尔特斯教授(Ken Walters FRS)的纪念特刊,我们在这篇简短的社论中汇集了期刊现任(和前任)编辑以及他的一些主要合作者的一系列非正式 "反思"。
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引用次数: 0
期刊
Journal of Non-Newtonian Fluid Mechanics
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