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In-situ citric acid-glycerol esterification: a novel bio-based modification for high-performance and durable poplar wood 原位柠檬酸-甘油酯化:一种高性能耐用杨木的新型生物基改性方法
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-12-19 DOI: 10.1007/s00107-025-02355-4
Yuqing Mu, Xuan Wang, Dunrui Cui, Yawen Wang, Lei Yu, Ao Li, Wang Wang

Fast-growing poplar wood is limited by poor dimensional stability and biological durability, while conventional treatment methods (such as involving toxic wood preservatives) often raise environmental and health concerns. Furthermore, some emerging chemical modification techniques, such as acetylation and furfurylation, are relatively expensive, which increases the final product cost. To address these challenges, we propose a bio-based sustainable approach: impregnating poplar wood with a hybrid system (GCA) composed of two lower-cost bio-based chemicals, citric acid (CA) and glycerol (G), to induce in-situ esterification without generating harmful by-products. The modification mechanism involves the formation of a robust, cross-linked GCA polyester network within the wood cell wall, leading to comprehensive performance enhancements. The dimensional stability was substantially improved, with a 64% anti-swelling efficiency. This is primarily attributed to the network restricting the wood’s interaction with moisture, particularly cell-wall-associated bound water, as confirmed by LFNMR analysis. The reinforcing network also significantly enhanced mechanical properties, including a 65% increase in modulus of elasticity and a 57% increase in compressive strength. Moreover, the GCA-modified wood demonstrated exceptional durability, exhibiting enhanced ultraviolet resistance with greater color stability, a remarkable reduction in mass loss against decay fungi, and complete inhibition of mold growth. This environmentally friendly and effective strategy presents a promising pathway for converting low-grade wood into a high-performance, durable material suitable for demanding construction and outdoor applications.

速生杨木受到尺寸稳定性和生物耐久性差的限制,而传统的处理方法(例如涉及有毒木材防腐剂)往往引起环境和健康问题。此外,一些新兴的化学改性技术,如乙酰化和糠化,相对昂贵,这增加了最终产品的成本。为了应对这些挑战,我们提出了一种基于生物的可持续方法:用由两种低成本生物基化学品柠檬酸(CA)和甘油(G)组成的混合体系(GCA)浸渍杨木,以诱导原位酯化而不产生有害副产物。改性机制涉及在木材细胞壁内形成坚固的交联GCA聚酯网络,从而导致全面的性能增强。尺寸稳定性显著提高,抗膨胀率达64%。正如LFNMR分析证实的那样,这主要归因于限制木材与水分相互作用的网络,特别是细胞壁相关的结合水。增强网络还显著提高了机械性能,包括弹性模量增加65%,抗压强度增加57%。此外,gca改性木材表现出优异的耐久性,表现出更高的抗紫外线能力和更大的颜色稳定性,显著减少了对腐烂真菌的质量损失,并完全抑制了霉菌的生长。这种环保和有效的策略为将低等级木材转化为高性能,耐用的材料提供了一条有希望的途径,适合苛刻的建筑和户外应用。
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引用次数: 0
Enhancing moisture exclusion in wood through cell wall bulking via whey ultrafiltration permeate and citric acid modification 通过乳清超滤渗透和柠檬酸改性,通过细胞壁膨胀增强木材的防潮性
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-12-15 DOI: 10.1007/s00107-025-02344-7
Assira Keralta, Jérémy Winninger, Julien Chamberland, Yoshiharu Nishiyama, Véronic Landry

Wood modification through polyesterification enhances its dimensional stability and reduces its moisture uptake. The efficacy of this modification depends on the placement of the polymeric networks within the wood. When these networks are situated within the cell wall, they cause cell wall bulking, thereby reducing the potential volume for moisture, which improves dimensional stability and water repellence capacity. The anti-swelling efficiency is typically calculated by comparing the dimensions of untreated and treated samples in both saturated and anhydrous states. The definition of the saturated state can influence the anti-swelling efficiency value. While it is established that polyesterification reduces wood moisture uptake, the kinetics of moisture absorption before and after modification have not been extensively studied. In this study, we demonstrate that the modification of four North American wood species with a mixture of whey ultrafiltration permeate and citric acid significantly enhances their physical properties as previously studied, as evidenced by increased anti-swelling efficiency. We also show that while wood modification deeply alters the kinetics of moisture uptake, it effectively reduces overall moisture absorption.

木材改性通过聚酯增强其尺寸稳定性和减少其吸湿性。这种改性的效果取决于聚合物网络在木材中的位置。当这些网络位于细胞壁内时,它们会导致细胞壁膨胀,从而减少水分的潜在体积,从而提高尺寸稳定性和防水能力。抗膨胀效率通常通过比较未处理和处理过的样品在饱和和无水状态下的尺寸来计算。饱和状态的定义会影响抗膨胀效率值。虽然聚酯降低了木材的吸湿率,但改性前后的吸湿动力学尚未得到广泛研究。在这项研究中,我们证明了用乳清超滤渗透剂和柠檬酸的混合物对四种北美木材进行改性,如前所述,显著提高了它们的物理性能,证明了抗膨胀效率的提高。我们还表明,虽然木材改性深刻地改变了吸湿动力学,但它有效地减少了整体吸湿。
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引用次数: 0
Colorimetric variation in wood species from the caatinga biome in function of the trunk axial position caatinga生物群系中不同树种的比色随树干轴向位置的变化
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-12-13 DOI: 10.1007/s00107-025-02358-1
Silvana Nisgoski, Helena Cristina Vieira, Joielan Xipaia dos Santos, Stephanie Hellen Barbosa Gomes, Rosimeire Cavalcante dos Santos, Graciela Inés Bolzon de Muñiz

Trees of the species Anadenanthera colubrina (Vell.) Brenan, Cenostigma pyramidale (Tul.) E. Gagnon & G.P. Lewis, Capparidastrum frondosum (Jacq.) Cornejo & Iltis, Commiphora leptophloeos (Mart) J.B. Gillett, Mimosa tenuiflora (Willd.) Poir., Manihot baccata Allem, Guapira sp. and Aspidosperma pyrifolium Mart. & Zucc (Pereiro) were collected in the municipality of Santa Cruz, Rio Grande do Norte State, Brazil. Discs were cut at 0% (10 cm above ground), 25%, 50%, 75% and 100% of commercial height, and at diameter at breast height. Reflectance spectra and data on luminosity (L*) and chromatic coordinates of green-red axis (a*) and blue-yellow axis (b*) were obtained and chroma (C*) and hue angle (h) were calculated. Mean values and standard deviations of color parameters by species indicated Capparidastrum frondosum, Commiphora leptophloeos, Manihot baccata, Guapira sp. and Aspidosperma pyrifolium as light species, and Anadenanthera colubrina, Cenostigma pyramidale and Mimosa tenuiflora as dark species. Colorimetric parameters and reflectance spectra of the wood of eight Caatinga species varied in axial trunk position, from tree base to top, but not in a linear pattern and there was no influence on species discrimination. Parameters L* and a* showed more potential for distinction of wood from evaluated Caatinga trees. Tree height, commercial and total, had correlation from − 0.51 to -0.64, with parameter b* and − 0.56 to -0.61 with C*, and DBH had low correlation (maximum of -0.26) with colorimetric parameters.

黄花楸属(Anadenanthera colubrina)树种Brenan, Cenostigma pyramidale(图图)e.g agnon & G.P. Lewis,《灰树花》(Jacq.)J.B.吉列特,含羞草(野生)Poir。瓜皮拉属和梨叶蚜属。Zucc (Pereiro)采集于巴西北格兰德州圣克鲁斯市。在离地0% (10cm)、25%、50%、75%和100%的商业高度以及胸围高度处的直径处切割圆盘。获得反射光谱、光度(L*)、绿红轴(a*)、蓝黄轴(b*)色坐标数据,并计算色度(C*)和色相角(h)。各种颜色参数的平均值和标准差表明,浅色种为枫香(Capparidastrum frondosum)、花栗草(Commiphora leptophloeos)、马尼奥特(Manihot baccata)、瓜皮(Guapira sp.)和梨叶(Aspidosperma pyrifolium),深色种为褐花(Anadenanthera colubrina)、锥体柱头(Cenostigma pyramidale)和含羞草(Mimosa tenuflora)。8种树种木材的比色参数和反射率随树干轴向位置从树底到树顶的变化而变化,但不呈线性变化,对树种识别没有影响。参数L*和a*表现出更大的区分潜力。树高和总树高与参数b*的相关性为- 0.51 ~ -0.64,与参数C*的相关性为- 0.56 ~ -0.61,胸径与比色参数的相关性较低,最大值为-0.26。
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引用次数: 0
Copper tolerance of Fomitopsis ostreiformis: implications for above-ground timber applications ostreiformis对铜的耐受性:对地上木材应用的影响
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-12-11 DOI: 10.1007/s00107-025-02360-7
Juan Roberto Vargas, Luis Yermán, Kyra C. Wood, Tripti Singh

Copper-based preservatives remain crucial for protecting timber from fungal decay for wood in direct soil contact, yet the presence of copper tolerant brown-rot fungi poses a risk to long-term service life, especially where treatment penetration is shallow. Fomitopsis ostreiformis is an aggressive brown rot species found across Australian field trials but lacks established copper tolerance thresholds. This study used in vitro petri dish growth assays and soil jar decay tests to assess the copper tolerance of F. ostreiformis. Fungal growth on amended malt extract agar was not inhibited at 1000 ppm of copper. Soil block tests of copper sulphate treated Pinus radiata suggested a copper threshold of approximately 1760 ppm to inhibit this fungus. In the soil jar decay tests, leached samples had lower mass losses than non-leached samples, suggesting that the leaching process potentially improved copper redistribution. These findings highlight the copper tolerance of F. ostreiformis, with implications for the effectiveness of shallow treatments against this fungus. Further tests using copper with a co-biocide are recommended.

铜基防腐剂对于保护木材免受直接接触土壤的真菌腐烂至关重要,但耐铜褐腐真菌的存在对长期使用寿命构成风险,特别是在处理渗透较浅的地方。foitopsis ostreiformis是一种侵略性的褐腐病物种,在澳大利亚的田间试验中发现,但缺乏确定的铜耐受阈值。本研究采用体外培养皿生长试验和土罐腐蚀试验来评价产铜的F. ostreiformis。在1000 ppm的铜浓度下,真菌在改良的麦芽提取物琼脂上的生长不受抑制。用硫酸铜处理的辐射松的土壤块试验表明,铜的阈值约为1760 ppm,可以抑制这种真菌。在土罐腐蚀试验中,浸出样品的质量损失低于未浸出样品,这表明浸出过程可能改善了铜的再分配。这些发现突出了f.s ostreiformis对铜的耐受性,这意味着浅层处理对这种真菌的有效性。建议使用铜和共生杀菌剂进行进一步试验。
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引用次数: 0
The potential of the fungus Phellinus linteus (Berk. & M.A. Curt.) in wood biopulping of Eucalyptus sp. and Pinus sp. 真菌黄菌(Phellinus linteus)& M.A. Curt.)在桉树和松树木材生物制浆方面的研究。
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-12-11 DOI: 10.1007/s00107-025-02357-2
Cíntia Gonçalves Escobar, Flávia Alves Pereira, Andréia Anschau, Alan Sulato de Andrade, Wescley Viana Evangelista

The aim of this study was to assess the potential of the fungus Phellinus linteus in the biopulping process of Pinus sp. and Eucalyptus sp. woods chips. The physical and chemical properties of wood chips, their behavior during the Kraft pulping process, as well as the quality of the cellulose pulp and paper produced, were evaluated. Basic density, extractive content, and lignin content were lower in the biotreated wood chips compared to the control. Eucalyptus and Pinus woods treated with Phellinus linteus required less active alkali for cooking, with 20.8% active alkali for Eucalyptus and 21.1% for Pinus, respectively. A higher gross yield was observed in the treated Eucalyptus sp. chips, while Pinus sp. chips showed no significant difference compared to the control. Paper strength was greater in the biotreated Eucalyptus, whereas in Pinus, the untreated chips exhibited higher strength. The fungus Phellinus linteus shows potential for use in the biopulping process, with reduced chemical consumption and benefits in yield and paper quality.

本研究的目的是评估真菌Phellinus linteus在松树和桉树木屑生物制浆过程中的潜力。对木屑的理化性质、在硫酸盐制浆过程中的表现以及纤维素纸浆和纸张的质量进行了评价。与对照相比,生物处理木屑的基本密度、萃取物含量和木质素含量较低。桉木和松木蒸煮所需活性碱较少,桉木和松木蒸煮所需活性碱分别为20.8%和21.1%。处理过的桉树叶片毛产量高于对照,而处理过的松木叶片毛产量与对照无显著差异。经生物处理的桉树的纸张强度更大,而未经处理的松木的纸张强度更高。木耳在生物制浆过程中显示出潜在的应用潜力,减少了化学品的消耗,并在产量和纸张质量方面有好处。
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引用次数: 0
A new dimension in wood anatomy education: exploring softwood and hardwood structures in 3D 木材解剖教育的新维度:探索三维软木和硬木结构
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-12-06 DOI: 10.1007/s00107-025-02329-6
Tim Koddenberg

Understanding the hierarchical and three-dimensional (3D) anatomy of wood is crucial for applications and advanced studies in wood science. However, teaching and learning this intricate anatomy can be challenging at times when relying solely on traditional two-dimensional (2D) teaching materials. To address this challenge, this article introduces a comprehensive 3D in situ visualization of softwood and hardwood structures using X-ray micro-computed tomography. Two types of visualization, full-structure and lumen-based 3D renderings, were used to exemplify the spatial morphology and features of the main anatomical structures, including tracheids, parenchyma cells, vessels, fibers, and inorganic inclusions. To complement these illustrations, selected features were also measured in 3D to describe their shape and dimensions. This article is intended as a reference resource for students, providing insights into how wood structures appear in three dimensions, and for lecturers as a supplement resource to create engaging teaching materials. Supplementary images and 3D models of wood structures are included in this article, which can be used as an advanced and supplementary toolkit for interactive viewing or 3D printing in various educational settings. This approach aims to foster the greater accessibility, interest, and understanding of the 3D wood anatomy for both students and lecturers.

了解木材的层次和三维(3D)解剖结构对于木材科学的应用和高级研究至关重要。然而,当仅仅依靠传统的二维(2D)教材时,教授和学习这种复杂的解剖学有时可能具有挑战性。为了解决这一挑战,本文介绍了使用x射线微计算机断层扫描对软木和硬木结构进行全面的三维原位可视化。采用全结构和基于腔体的三维渲染两种可视化方式,展示了主要解剖结构的空间形态和特征,包括管胞、薄壁细胞、血管、纤维和无机包裹体。为了补充这些插图,选择的特征也在3D中测量,以描述它们的形状和尺寸。本文旨在作为学生的参考资源,提供有关木结构如何在三维空间中出现的见解,并作为讲师创建引人入胜的教材的补充资源。本文中包含了木结构的补充图像和3D模型,可以作为各种教育环境中交互式观看或3D打印的高级和补充工具包。这种方法旨在为学生和讲师培养更大的可访问性,兴趣和对3D木材解剖的理解。
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引用次数: 0
Shear capacity and slip modulus prediction of LVL and LVL-C nailed connections for LVL-I-beams LVL- i梁LVL- c钉接抗剪承载力及滑移模量预测
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-12-05 DOI: 10.1007/s00107-025-02346-5
Angelo Aloisio, Dag Pasquale Pasca, Yuri De Santis, Massimo Fragiacomo

Banded laminated-veneer lumber (LVL-C) is an engineered wood product valued for its high bending, tensile and compressive strength along the grain, making it well-suited for long-span, high-load members such as composite LVL I-beams. In these beams, the web is usually a unidirectional LVL, whereas the flanges are fabricated from cross-banded LVL-C to improve dimensional stability and rolling-shear resistance. This study investigates the mechanical performance of nailed LVL–LVL-C connections that link the flange to the web. Sixty push-out shear tests were carried out on eight configurations, varying (i) nail type, (ii) nail spacing (45 mm vs. 75 mm), and (iii) flange thickness (19 mm vs. 37 mm). The experiments show that flange thickness is the governing parameter: specimens with the thinner flange reached, on average, 18–20 % higher load capacity, whereas the thicker-flange specimens exhibited greater initial and secant stiffness. Two characteristic failure mechanisms were observed: single-hinge web yielding, in which one plastic hinge develops in the weak (web) member, and double-hinge composite yielding, in which a second plastic hinge forms in the strong (flange) member. These mechanisms correspond to Johansen modes (e) and (f). A nonlinear beam-on-foundation (BOF) model was developed for the nails; the model reproduces both observed failure mechanisms and the full load–slip response. Calibrating the model yields embedment strengths roughly three times the values predicted by prEN 1995-1-1, reducing the mean error in capacity prediction from 46 % to less than 1 %. A complementary linear BOF formulation confirms that the slip modulus is highly sensitive to the effective embedment depth, explaining the marked stiffness difference between the two flange thicknesses. In summary, the combined experimental–numerical programme (i) provides revised embedment parameters for spruce LVL and LVL-C, (ii) shows that current Eurocode provisions are overly conservative for these materials, and (iii) offers a validated BOF framework for designing nailed connections in LVL I-beams.

带状层压单板木材(LVL- c)是一种工程木材产品,因其沿纹理的高弯曲,拉伸和抗压强度而受到重视,使其非常适合大跨度,高负荷构件,如复合LVL工字梁。在这些梁中,腹板通常是单向LVL,而法兰是由交叉带状LVL- c制成的,以提高尺寸稳定性和抗滚剪能力。本研究探讨了连接翼缘与腹板的钉钉式LVL-LVL-C连接的力学性能。在8种配置下进行了60次推出剪切试验,包括(i)钉类型,(ii)钉间距(45 mm vs. 75 mm)和(iii)法兰厚度(19 mm vs. 37 mm)。试验表明,翼缘厚度是控制参数,翼缘较薄的试件的承载能力平均提高18 - 20%,而翼缘较厚的试件的初始刚度和割线刚度更高。观察到两种典型的破坏机制:单铰腹板屈服,在弱(腹板)构件中形成一个塑性铰;双铰复合屈服,在强(翼缘)构件中形成第二个塑性铰。这些机制对应于Johansen模态(e)和(f)。建立了锚杆非线性基础梁(BOF)模型;该模型再现了观察到的破坏机制和完整的荷载-滑移响应。校准模型产生的嵌入强度大约是prEN 1995-1-1预测值的三倍,将容量预测的平均误差从46%降低到不到1%。互补线性转炉公式证实,滑移模量对有效嵌入深度高度敏感,解释了两种法兰厚度之间明显的刚度差异。总之,结合实验-数值程序(i)为云杉LVL和LVL- c提供了修订的嵌入参数,(ii)表明当前的欧洲规范规定对这些材料过于保守,(iii)为设计LVL i型梁的钉接连接提供了一个经过验证的BOF框架。
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引用次数: 0
Oriental beech (Fagus orientalis L.) steaming condensate: phenolic composition and functional activities 东方山毛榉(Fagus orientalis L.)蒸凝物:酚类成分及功能活性
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-12-01 DOI: 10.1007/s00107-025-02352-7
Osman Akmeşe, Hüseyin Sivrikaya, Cemalettin Baltacı

This study presents a comprehensive investigation of the bioactive properties of the condensate formed during the steaming treatment of beech wood (Fagus orientalis L.). The phenolic compound profile, antioxidant capacity, enzyme inhibition, and antimicrobial activity of the condensate were evaluated using multiple analytical methods. Rich in total phenolic content (339.20 mg GAE/g) and flavonoid levels (79.74 mg QE/g), the condensate exhibited strong reducing power in the ferric reducing antioxidant power assay (FRAP), while demonstrating moderate radical scavenging activity in the DPPH (2,2-diphenyl-1-picrylhydrazyl) and ABTS (2,2′-azinobis (3-ethylbenzothiazoline 6-sulfonic acid)) tests. In antimicrobial assessments, the condensate was found to be effective against Gram-positive bacteria, Staphylococcus aureus and Bacillus cereus as well as Candida albicans as a pathogen fungus, while showing lower activity against Gram-negative bacteria. Its antifungal efficacy was found to be notable when compared to nystatin. Although the IC₅₀ value of the condensate in α-amylase inhibition assays (1320.00 µg/mL) was weaker than that of the reference inhibitor acarbose (33.26 µg/mL), the results indicate its potential as a plant-based enzyme inhibitor candidate. Fourier transform infrared (FTIR) spectroscopy revealed characteristic peaks associated with lignin derivatives, carbohydrates, and ester bonds in the condensate. LC–MS/MS analyses identified chlorogenic acid (1581.65 µg/g) as the major phenolic compound, along with ferulic acid and rosmarinic acid. Beech steaming condensate stands out as a valuable bioactive resource in the context of industrial by-product valorization. With its antioxidant, antimicrobial, and enzyme-inhibitory properties, it holds promising potential for applications in the food preservation, pharmaceutical, and cosmetic industries. These findings may contribute to the sustainability of the forest industry from a circular economy perspective.

本研究对山毛榉木(Fagus orientalis L.)蒸处理过程中形成的冷凝物的生物活性特性进行了全面的研究。采用多种分析方法对其酚类化合物特征、抗氧化能力、酶抑制和抗菌活性进行了评价。该浓缩物具有丰富的总酚含量(339.20 mg GAE/g)和类黄酮含量(79.74 mg QE/g),在铁还原抗氧化能力试验(FRAP)中表现出较强的还原能力,而在DPPH(2,2-二苯基-1-吡啶肼)和ABTS (2,2 ' -azinobis(3-乙基苯并噻唑啉6-磺酸))试验中表现出中等的自由基清除能力。在抗菌评估中,发现冷凝物对革兰氏阳性细菌,金黄色葡萄球菌和蜡样芽孢杆菌以及白色念珠菌作为病原体真菌有效,而对革兰氏阴性细菌的活性较低。与制霉菌素相比,其抗真菌效果显著。虽然α-淀粉酶抑制实验中冷凝物的IC₅0值(1320.00µg/mL)弱于参考抑制剂阿卡波糖(33.26µg/mL),但结果表明其作为植物基酶抑制剂的候选潜力。傅里叶变换红外光谱(FTIR)揭示了与木质素衍生物、碳水化合物和酯键相关的特征峰。LC-MS /MS分析鉴定绿原酸(1581.65µg/g)为主要酚类化合物,阿魏酸和迷迭香酸也为主要酚类化合物。山毛榉蒸汽冷凝水作为一种有价值的生物活性资源,在工业副产品增值的背景下脱颖而出。由于其抗氧化、抗菌和抑制酶的特性,它在食品保鲜、制药和化妆品工业中具有广阔的应用前景。从循环经济的角度来看,这些发现可能有助于森林工业的可持续性。
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引用次数: 0
Phytochemical composition and biological activities of bark extracts from seven industrially relevant tree species 七种工业相关树种树皮提取物的植物化学成分和生物活性
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-12-01 DOI: 10.1007/s00107-025-02349-2
Mehmet Akca, Mahmut Gur, Aytaç Guder

This study presents a comprehensive analysis of the phytochemical profiles and biological activities of bark extracts from seven industrially significant tree species: Pinus sylvestris, Pinus nigra, Pinus brutia, Picea orientalis, Abies nordmanniana subsp. equi-trojani, Fagus orientalis, and Quercus robur. Bioactive compounds, including phenolics, flavonoids, and alkyl esters, were identified and quantified using GC-MS and HPLC techniques. A methanol: water mixture (65:35, v/v) was found to be the most effective solvent, yielding the highest total phenolic content in Abies nordmanniana and the highest flavonoid concentration in Pinus brutia. GC-MS analysis revealed species-specific distributions of key compounds such as 2-ethylhexanol, methyl stearate, and mono(2-ethylhexyl) adipate, reflecting the chemical diversity among the species. The extracts were further evaluated for their antioxidant, antimicrobial, and enzyme-inhibitory activities. Notably, inhibition of PPO and PON1 enzymes was observed, and DNA protection assays confirmed the ability of extracts to mitigate oxidative damage. These findings highlight the potential of industrial tree bark, typically a waste product of the wood industry, as a valuable source of bioactive compounds. The study advocates for its integration into the circular economy by developing high-value products for pharmaceutical, industrial, and environmental use.

摘要本研究综合分析了7种工业重要树种:西洋松(Pinus sylvestris)、黑松(Pinus nigra)、野松(Pinus brutia)、东方云杉(Picea orientalis)和北冷杉(Abies nordmanniana subsp)树皮提取物的化学特征和生物活性。山核桃、山毛榉和栎树。利用GC-MS和HPLC技术对酚类、类黄酮和烷基酯等生物活性化合物进行了鉴定和定量。甲醇:水的混合物(65:35,v/v)是最有效的溶剂,在冷杉中总酚含量最高,在油松中总黄酮浓度最高。GC-MS分析揭示了2-乙基己醇、硬脂酸甲酯和己二酸单(2-乙基己基)等关键化合物的物种特异性分布,反映了物种间的化学多样性。进一步评价提取物的抗氧化、抗菌和酶抑制活性。值得注意的是,观察到PPO和PON1酶的抑制作用,DNA保护实验证实了提取物减轻氧化损伤的能力。这些发现突出了工业树皮(通常是木材工业的废物)作为生物活性化合物的宝贵来源的潜力。该研究倡导通过开发用于制药、工业和环境用途的高价值产品,将其融入循环经济。
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引用次数: 0
Engineered laminated bamboo sandwich panels: a lightweight, cost-effective and carbon-negative solution for sustainable construction 工程叠层竹夹芯板:一种轻量级、经济高效、负碳的可持续建筑解决方案
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-12-01 DOI: 10.1007/s00107-025-02354-5
Xizhi Peng, Zhifeng Wang, Licheng Zhou, Zhongfeng Zhang, Lisheng Xie, Jianying Chen

A laminated bamboo sandwich panel with a grid core was developed, utilizing bamboo veneers for both surface and core layers. Four-point bending tests evaluated the effects of structural parameters—processing methods, grid count, and layer thickness—on ultimate load-carrying, deflection, strain, specific stiffness, and specific strength. The empirical results indicated that grid core processing significantly influences performance, with partition sandwich panels exhibiting 108.9% higher specific strength than interlocked sandwich panels. Increasing long grid numbers enhanced ultimate load-carrying capacity by 68.4% and specific strength by 41.7%, while short grids had minimal impact. Reducing lower layer thickness from 8 mm to 4 mm decreased specific strength by 24.2%, and reducing core thickness from 48 mm to 32 mm led to a 31.2% decline. Nonlinear load-deflection and load-strain behaviors were observed, and a simulation model successfully predicted structural performance. Compared to traditional materials, the laminated bamboo sandwich panel offers superior structural performance, reduced environmental impact, and cost reduction, making it highly suitable for construction applications such as flooring, wallboards, and bridge decks.

开发了带有网格芯的层压竹夹芯板,在表层和芯层都使用了竹单板。四点弯曲试验评估了结构参数——处理方法、网格数和层厚度——对极限承载、挠度、应变、比刚度和比强度的影响。实验结果表明,网格芯处理对夹层板的性能有显著影响,隔断夹层板的比强度比互锁夹层板高108.9%。增加长网格数量可使极限承载能力提高68.4%,比强度提高41.7%,而短网格数量的影响最小。下层厚度从8 mm减少到4 mm,比强度下降24.2%,岩心厚度从48 mm减少到32 mm,比强度下降31.2%。观察了非线性荷载-挠曲和荷载-应变行为,并建立了模拟模型,成功地预测了结构性能。与传统材料相比,竹材夹层板具有优越的结构性能,减少对环境的影响,降低成本,非常适合用于地板、墙板和桥面等建筑应用。
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European Journal of Wood and Wood Products
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