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Changes in the content of extractives in silver fir (Abies alba Mill.) bark due to different storage conditions 不同贮藏条件对银杉树皮提取物含量的影响
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-10-24 DOI: 10.1007/s00107-025-02338-5
Peter Hrovatič, Ida Poljanšek, Urša Osolnik, Primož Oven, Viljem Vek

The circular economy promotes the use of industrial by-products as raw materials for high-quality products. Silver fir bark (Abies alba Mill.), a low-value residue from wood processing, is a rich source of polyphenols with antioxidant properties. This study investigated how bark preparation (particle size) and storage conditions affect the content of total extractives, polyphenols, and condensed tannins in aqueous extracts over a 10-month period. Bark samples of two particle sizes were stored either outdoors (exposed to precipitation) or indoors (dry, dark conditions). The extracts were analyzed monthly by gravimetry and UV-Vis spectrophotometry. The results showed that both particle size and storage conditions significantly influenced the retention of extractives and polyphenols in the samples. The highest losses occurred in ground bark samples stored outdoors, while the best retention was achieved with larger bark particles stored in a covered, dry environment. These findings highlight the importance of optimized storage strategies for the preservation of bark quality as a source of bioactive compounds.

循环经济促进利用工业副产品作为高质量产品的原料。银杉树皮(Abies alba Mill.)是木材加工的低价值残留物,是具有抗氧化特性的多酚的丰富来源。本研究在10个月的时间里研究了树皮制备(粒度)和储存条件对水浸提取物中总提取物、多酚和缩合单宁含量的影响。两种粒径的树皮样品被存放在室外(暴露于降水)或室内(干燥,黑暗的条件)。每个月用重量法和紫外-可见分光光度法对提取物进行分析。结果表明,粒径和贮存条件对提取液和多酚的保留率有显著影响。在室外储存的地面树皮样品损失最大,而在有盖的干燥环境中储存的较大树皮颗粒的保留效果最好。这些发现强调了优化储存策略作为生物活性化合物来源对树皮质量保存的重要性。
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引用次数: 0
Valorization of orange peel waste: activated carbon production and its role in enhancing particleboard performance 橘皮废料的增值:活性炭的生产及其在提高刨花板性能中的作用
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-10-22 DOI: 10.1007/s00107-025-02337-6
Mehmet Emin Ergün, Filiz Koyuncu, Abdullah İstek, İsmail Özlüsoylu

The valorization of agricultural waste has gained increasing attention in recent years, with orange peel waste emerging as a promising precursor for activated carbon (AC) production. This study investigates the production of AC from orange peel waste using zinc chloride (ZnCl₂) as a chemical activator and evaluates its impact on the physical, mechanical, and environmental properties of three-layer particleboards. AC was incorporated into the urea–formaldehyde (UF) adhesive at 0.5–1.5% by weight and applied to both surface and core chips, ensuring its distribution across all three layers of the particleboard. The AC exhibited a specific surface area of 572.14 m²/g and a total pore volume of 0.280 cm³/g, demonstrating its high porosity and adsorption capabilities. Mechanical test results of particleboard indicate that the inclusion of 1.5% AC increased MOR by 26% (from 10.02 N/mm² to 12.65 N/mm²) and MOE by 52% (from 1083.83 N/mm² to 1645.33 N/mm²), while IB rose from 0.41 N/mm² to 0.53 N/mm². Additionally, formaldehyde emissions of particleboard decreased significantly from 11.25 mg/100 g (control) to 8.01 mg/100 g at production (0th month) and further to 3.20 mg/100 g after 12 months. Based on TS EN 312 (2012) classification, the AC-modified panels at 1.0–1.5% met the requirements of P2 boards for general-purpose use in dry conditions, while also complying with the E1 formaldehyde emission standard. The orange peel waste-derived AC can serve as an effective additive in composite materials, simultaneously improving mechanical performance and meeting international environmental and safety standards.

近年来,农业废弃物的再生利用受到越来越多的关注,橘皮废弃物成为生产活性炭(AC)的有前途的前体。本研究以氯化锌(ZnCl 2)为化学活化剂,研究了从橘子皮废料中生产AC的方法,并评估了其对三层刨花板的物理、机械和环境性能的影响。AC以0.5-1.5%的重量加入到脲醛(UF)粘合剂中,并应用于表面和核心芯片,确保其分布在刨花板的所有三层。活性炭的比表面积为572.14 m²/g,总孔体积为0.280 cm³/g,具有较高的孔隙率和吸附能力。刨花板力学试验结果表明,加入1.5%的AC可使MOR提高26%(从10.02 N/mm²提高到12.65 N/mm²),MOE提高52%(从1083.83 N/mm²提高到1645.33 N/mm²),IB从0.41 N/mm²提高到0.53 N/mm²。此外,刨花板的甲醛释放量从11.25 mg/100 g(对照)显著下降到生产时(第0个月)的8.01 mg/100 g, 12个月后进一步下降到3.20 mg/100 g。根据TS EN 312(2012)分类,1.0-1.5%的交流改性板满足P2板在干燥条件下通用使用的要求,同时也符合E1甲醛释放标准。橙皮废料衍生的AC可以作为复合材料的有效添加剂,同时提高机械性能并符合国际环保和安全标准。
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引用次数: 0
Impact resistance of birch plywood sheets - experimental and numerical approaches 桦木胶合板的抗冲击性。试验和数值方法
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-10-16 DOI: 10.1007/s00107-025-02336-7
Tomasz Jankowiak, Alexis Rusinek, Amine Bendarma

This study presents both experimental tests and numerical analyses to predict the dynamic structural behavior of birch plywood sheets under impact conditions. The comparison between the ballistic curves and ballistic limits obtained numerically and experimentally highlights the accuracy of the model in simulating the material response. Birch plywood, with its multilayer cross-laminated structure, demonstrates excellent impact resistance, effectively distributing and dissipating the applied forces. This configuration significantly reduces crack propagation and enhances energy absorption, making it a robust material for dynamic loading conditions. The paper introduces a detailed model for the ply fabric material of birch plywood, along with a comprehensive set of material parameters, providing a solid foundation for further research and application. The numerical analysis of the average impact force across the range of impact velocities considered offers valuable insights into the material performance. These findings further validate the suitability of birch plywood for structural applications requiring impact resistance. This work contributes to a deeper understanding of the material dynamic behavior and advances the knowledge of engineered wood products in impact-related contexts, paving the way for more informed decisions in material selection for demanding structural applications.

本文采用试验试验和数值分析相结合的方法对桦木胶合板在冲击条件下的结构动力性能进行了预测。数值和实验得到的弹道曲线和弹道极限的比较,突出了该模型在模拟材料响应方面的准确性。桦木胶合板具有多层交叉层合结构,具有优异的抗冲击性能,能有效地分散和消散所施加的力。这种结构大大减少了裂纹扩展,增强了能量吸收,使其成为动态加载条件下的坚固材料。本文详细介绍了桦木胶合板层织物材料的模型,并给出了一套较为全面的材料参数,为进一步的研究和应用奠定了坚实的基础。在考虑的冲击速度范围内的平均冲击力的数值分析为材料性能提供了有价值的见解。这些发现进一步验证了桦木胶合板在要求抗冲击的结构应用中的适用性。这项工作有助于更深入地了解材料的动态行为,并在与冲击相关的环境中推进工程木制品的知识,为要求苛刻的结构应用的材料选择铺平了道路。
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引用次数: 0
Experimental assessment of glulam beams made by European beech from Spain 西班牙山毛榉胶合木梁的试验评价
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-10-13 DOI: 10.1007/s00107-025-02333-w
Carlos Martins, Cláudio Ferreira, Mario Azaña, Gonzalo Cabrera, Vanesa Baño, Alfredo M. P. G. Dias

The demand for engineered wood products for construction and the climate change affecting some forest plantations impacts the need for diversifying the matrix of wood species apt for structural applications, which is nowadays focused on a few softwood species. Hardwoods have been considered all over the World by the scientific community and industry players with a special focus on hardwoods such as chestnut, oak, birch, maple, and beech. The present article addresses the experimental assessment of the mechanical and bonding performance of glulam beams made by European beech (Fagus sylvatica L.) from Spain. A total of 48 glulam beams (homogeneous and combined) have been produced at the laboratory facilities (20 without finger joints and 28 with finger joints). Non-destructive tests were previously considered to characterize the raw material using a longitudinal vibration method (Machine Timber Grader), also applied to the glulam beams before the failure test. For the prediction of the mechanical properties (modulus of elasticity), the Transformed Section Method and Longitudinal Vibration Method were considered. Correlation coefficients of 0.90 or higher have been obtained. Additionally, 41 lamellas with finger joints have been characterized by tension, resulting in a characteristic tensile value of 50.8 MPa. Its influence on the bending properties of the glulam beams has been evaluated, obtaining a characteristic bending strength value of 52.9 MPa. In general, a good bonding performance has been obtained for both Method A and Method C protocols from the European standard of glulam manufacturing (EN 14080).

建筑工程木材产品的需求和影响一些森林人工林的气候变化影响了对适于结构应用的木材品种基质多样化的需求,目前主要集中在几种软木品种上。世界各地的科学界和工业界人士都认为硬木是一种特别关注的硬木,如栗木、橡树、桦木、枫木和山毛榉。本文讨论了用西班牙欧洲山毛榉(Fagus sylvatica L.)制成的胶合木梁的力学性能和粘结性能的实验评估。在实验室设施中共生产了48根胶合木梁(均质和组合)(20根没有手指关节,28根有手指关节)。以前考虑使用纵向振动法(机器木材分级机)进行无损测试,以表征原材料,在破坏测试之前也适用于胶合木梁。对于力学性能(弹性模量)的预测,考虑了截面变换法和纵向振动法。相关系数为0.90或更高。此外,41个具有指节的薄片具有张力特征,其特征张力值为50.8 MPa。对其对胶合木梁抗弯性能的影响进行了评价,得到了其抗弯强度特征值为52.9 MPa。总的来说,根据欧洲胶合木制造标准(EN 14080),方法a和方法C协议都获得了良好的粘合性能。
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引用次数: 0
Sound absorption performance of wood: influence of porosity, gas permeability, and back air cavities in five wood species 木材的吸声性能:孔隙率、透气性和后气孔对五种木材的影响
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-10-13 DOI: 10.1007/s00107-025-02335-8
Haradhan Kolya, Chun-Won Kang

Noise pollution is a growing concern in urban environments, driving the need for sustainable and effective acoustic materials. Wood, a naturally abundant and lingocellulosic material, exhibits sound absorption properties influenced by its porosity, gas permeability, and structural integrity. This study aimed to investigate the relationship between these properties and the sound absorption coefficient (SAC) of five wood types: Coconut (Cocos nucifera L.), Hackberry (Carya ovata), Malas (Homalium foetidum Roxb.), Oak (Quercus mongolica Fisch.), and Paulownia (Paulownia tomentosa). Using the two-microphone transfer function method, SAC was measured across a frequency range of 250–4000 Hz, both with and without back air cavities (0–4 cm). Additional analyses included porosity determination via helium pycnometer, gas permeability using a capillary flow porometer, and surface morphology assessment with a 3D optical profilometer. Results showed that back air cavities significantly enhanced low-frequency SAC. Hackberry and Oak achieved the highest Noise Reduction Coefficients (NRC) values (0.55 and 0.53, respectively at a 4 cm cavity depth). Porosity was critical for low-frequency absorption in Coconut (80.91%) and Paulownia (55.56%), while high permeability and large pore sizes favored low-frequency performance in Oak and Hackberry. Malas demonstrated balanced acoustic properties across frequencies due to its intermediate porosity and diffuse pore structure. This research highlights the novelty of correlating wood anatomy with acoustic behavior and optimizing back air cavity depth to tailor performance. The findings provide valuable insights for developing eco-friendly, wood-based acoustic materials for applications in construction, interior design, and noise mitigation solutions.

噪音污染在城市环境中日益受到关注,推动了对可持续和有效声学材料的需求。木材是一种天然丰富的纤维素材料,其吸声性能受其孔隙度、透气性和结构完整性的影响。研究了椰子(Cocos nucifera L.)、黑莓(Carya ovata)、马来树(Homalium foetidum Roxb.)、橡树(Quercus mongolica Fisch.)和泡桐(Paulownia tomentosa) 5种木材吸声系数与这些特性的关系。使用双传声器传递函数法,在250-4000 Hz的频率范围内测量SAC,包括有和没有后气腔(0-4 cm)。其他分析包括通过氦气体积计测定孔隙度,使用毛细管流动孔隙度计测定气体渗透率,以及使用3D光学剖面仪评估表面形貌。结果表明,后空腔明显增强了低频SAC。在4 cm空腔深度处,水杨树和橡树的降噪系数(NRC)最高,分别为0.55和0.53。孔隙度对椰子(80.91%)和泡桐(55.56%)的低频吸收至关重要,而高渗透率和大孔径有利于橡树和Hackberry的低频吸收。由于其中等孔隙度和弥漫性孔隙结构,Malas在不同频率下表现出平衡的声学特性。这项研究强调了将木材解剖与声学行为联系起来的新颖性,并优化了后空腔深度以定制性能。研究结果为开发环保的木质隔音材料提供了宝贵的见解,可用于建筑、室内设计和噪音缓解解决方案。
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引用次数: 0
Exploring tannin and caffeine for enhanced performance of oriented strand boards under varied conditions 探索单宁和咖啡因在不同条件下增强定向刨花板性能的作用
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-09-25 DOI: 10.1007/s00107-025-02334-9
Yeray Manuel López‑Gómez, Antti Haapala, Alain Cloutier

This study explores tannin and caffeine, natural compounds with inherent antifungal properties, as scalable treatments to enhance the physical and mechanical performance of oriented strand board (OSB). Unlike previous research that primarily focused on durability, this work evaluates the effects of these bio-based treatments on leaching resistance, internal bond strength (IB), bending properties, water absorption, thickness swelling, and vertical density profile (VDP). The results demonstrate significant improvements over commercially available OSB, particularly in mechanical performance. Post-leaching, both treatments exhibited superior IB, with tannin-treated panels achieving the highest IB value (0.27 MPa). The bending analysis revealed that caffeine-treated panels that were not subjected to leaching achieved the highest modulus of rupture (MOR, 62.54 MPa) and modulus of elasticity (MOE, 10.36 GPa). Both treatments retained significantly higher MOR and MOE values post-leaching compared to the industrial reference and untreated panels. Water absorption and thickness swelling were comparable among tannin-treated, caffeine-treated, and untreated panels but were significantly lower than those of the industrial reference, which was included for general benchmarking purposes alongside the laboratory-made control. VDP analysis showed caffeine-treated panels had the lowest density prior to leaching, whereas tannin-treated panels maintained the highest density after leaching. These findings highlight tannin and caffeine as effective and scalable treatments, providing a sustainable alternative as functional additives for industrial engineered wood product manufacturing.

本研究探讨了单宁和咖啡因这两种具有固有抗真菌特性的天然化合物,作为可扩展的处理方法来提高定向刨花板(OSB)的物理和机械性能。与之前主要关注耐久性的研究不同,这项工作评估了这些生物基处理对抗浸出性、内部粘结强度(IB)、弯曲性能、吸水率、厚度膨胀和垂直密度剖面(VDP)的影响。结果表明,与市售OSB相比,该材料有了显著的改进,特别是在机械性能方面。浸出后,两种处理均表现出优异的IB,单宁处理的面板达到最高的IB值(0.27 MPa)。弯曲分析表明,未经浸出的咖啡因处理板获得了最高的断裂模量(MOR, 62.54 MPa)和弹性模量(MOE, 10.36 GPa)。与工业参考和未经处理的面板相比,两种处理在浸出后都保留了显着更高的MOR和MOE值。在单宁处理、咖啡因处理和未经处理的面板中,吸水率和厚度膨胀率相当,但明显低于工业参考面板,工业参考面板与实验室制作的对照板一起用于一般基准测试目的。VDP分析显示,咖啡因处理的面板在浸出前密度最低,而单宁处理的面板在浸出后保持最高密度。这些发现强调了单宁和咖啡因作为有效和可扩展的处理方法,为工业工程木制品制造提供了可持续的功能性添加剂替代品。
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引用次数: 0
Resistance drilling: the effect of needle wear 阻力钻:针磨损的影响
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-09-25 DOI: 10.1007/s00107-025-02332-x
Vilius Gendvilas, David J. Lee, Geoffrey M. Downes, Marco Lausberg, Jonathan J. Harrington

Semi-non-destructive drilling resistance instruments have been widely adopted for timber testing and forestry for wood quality assessments. The accuracy of a drilling resistance tool for predicting wood density may be affected by needle (drill) wear, and there is limited information regarding the wear behaviour of drill bits in wood resistance drilling. It is unknown when changes in needle sharpness and diameter become critical for quantifying wood density. To measure the effect of Resi needle wear, an IML Resi PD 500 was used to obtain cross-sectional traces of Southern Pine (Pinus elliottii var. elliottii (Engelm) × Pinus caribaea var. hondurensis (Sénéclauze)) average outerwood density: 519 kg/m³ and Spotted Gum (Corymbia citriodora subsp. variegata (F. Muell.)) average outerwood density: 779 kg/m³ logs. Southern Pine was tested with feed speeds of 200 cm/min at 3500 rpm and 100 cm/min at 5000 rpm. Spotted Gum was tested with a feed speed of 70 cm/min at 5000 rpm. A new needle was used for each setting. The effect of needle wear was tested after 0, 100, 200, 300, 400, 500, and 600 m of drilling depth. There was no effect on drilling resistance values up to 600 m of drilling length with feed speed 200 cm/min and 3500 rpm settings for Southern Pine. This would result in 2000 drilling measurements of 30 cm diameter trees. With alternative setting for Southern Pine with a setting of 100 cm/min feed speed and 5000 rpm, the increase in amplitudes was not significant until 300 m of drilling, after which, at 400 m, the amplitude increased by 2% (9.8 kg/m3), and after 600 m, the amplitude increased by 3.1% (15.2 kg/m3). For the hardwood Spotted Gum, the amplitude decreased by 0.9% (2.3 kg/m3) after 100 m, and after 300 m, the amplitude decreased by 3.3% (8.2 kg/m3). After 300 m, it was not possible to drill Spotted Gum due to extensive needle wear. The study highlighted the importance of needle wear in resistance drilling, providing guidance for reliable needle use to improve measurement accuracy and wood quality assessment.

半无损钻阻仪已广泛应用于木材检测和林业木材质量评价。用于预测木材密度的钻井阻力工具的准确性可能会受到针(钻)磨损的影响,而且关于木材阻力钻井中钻头磨损行为的信息有限。尚不清楚何时针尖和直径的变化对量化木材密度至关重要。为了测量Resi针磨损的影响,使用IML Resi PD 500获得了南松(Pinus elliottii var. elliottii (Engelm)) × Pinus caribaea var. hondurensis (ssamnsamuze))的横截面痕迹,平均外木密度为519 kg/m³,斑点胶(Corymbia citriodora subsp.)。variegata (F. Muell.))平均外层木材密度:779 kg/m³。南松在3500转时的进料速度为200厘米/分钟,5000转时的进料速度为100厘米/分钟。斑点胶在5000 rpm下以70 cm/min的进料速度进行测试。每次注射都用一根新针。在钻进深度为0、100、200、300、400、500和600 m时,测试了针磨损的影响。在进给速度为200厘米/分钟、3500转/分钟的情况下,在600米的钻进长度内,对南松的钻进阻力值没有影响。这将导致2000个直径为30厘米的树木的钻井测量。南松的备选设置为100 cm/min的进给速度和5000 rpm,振幅的增加在钻孔300 m之前并不显著,之后,在400 m时,振幅增加了2% (9.8 kg/m3),在600 m之后,振幅增加了3.1% (15.2 kg/m3)。硬木斑胶在100 m后振幅下降0.9% (2.3 kg/m3),在300 m后振幅下降3.3% (8.2 kg/m3)。钻进300米后,由于钻针磨损严重,无法钻出斑纹胶。该研究强调了针磨损在阻力钻孔中的重要性,为针的可靠使用提供了指导,以提高测量精度和木材质量评估。
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引用次数: 0
Enhancing properties of fast-grown poplar wood by impregnating nano hexagonal boron nitride fortified polyvinyl acetate resin 浸渍纳米六方氮化硼强化聚醋酸乙烯树脂增强速生杨木性能
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-09-20 DOI: 10.1007/s00107-025-02331-y
Priya Nagraik, S. R. Shukla

Fast-grown plantation wood species such as poplar (Populus deltoides) are widely available but inherently possess poor decay resistance and limited mechanical strength which restricts its end-use applications. This study focuses on enhancing the properties by impregnating poplar wood with polyvinyl acetate (PVAc) resin fortified with nano hexagonal boron nitride (h-BN). The vacuum-pressure impregnation process was followed for treatment and the treated samples were evaluated for fungal decay resistance against brown rot and white rot fungi, as well as density, water absorption, surface hardness, compressive strength and thermal stability. Nanoparticles distribution within the wood microstructure was analysed using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) mapping. Results showed that h-BN fortification of PVAc with different concentrations further improved the properties of poplar wood. These findings demonstrate that h-BN-PVAc impregnation is a promising modification method for producing a wood with enhanced properties for indoor wood products from fast-grown species which can be promising material towards sustainable development.

快速生长的人工林树种如杨树(Populus deltoides)广泛使用,但固有地具有较差的耐腐性和有限的机械强度,这限制了其最终用途。研究了用纳米六方氮化硼(h-BN)强化的聚醋酸乙烯酯(PVAc)树脂浸渍杨木的性能。采用真空-压力浸渍法对样品进行处理,并对处理后的样品进行抗褐腐和白腐真菌腐蚀性能、密度、吸水性、表面硬度、抗压强度和热稳定性等方面的评价。利用扫描电子显微镜(SEM)和能量色散x射线能谱(EDS)图分析了纳米颗粒在木材微观结构中的分布。结果表明,不同浓度的PVAc强化h-BN可进一步改善杨木的性能。这些发现表明,h-BN-PVAc浸渍是一种很有前途的改性方法,可以生产出具有增强性能的室内速生木材产品,是一种有前途的可持续发展材料。
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引用次数: 0
European beech potential for agricultural land afforestation: an anatomical and wood quality perspective 欧洲山毛榉在农业用地造林方面的潜力:解剖学和木材质量的观点
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-09-12 DOI: 10.1007/s00107-025-02328-7
Karol Tomczak, Jan Cukor, Przemysław Mania, Zdeněk Vacek, Arkadiusz Tomczak

The European beech (Fagus sylvatica L.) is one of the most economically and ecologically important deciduous tree species in Europe. However, there is a lack of scientific knowledge regarding quality of wood growing on former agricultural land exists in the case of European beech. Therefore, this study aimed to evaluate the wood properties of European beech growing on former agricultural land compared to standard forest stands in north-western Poland. In total 2457 specimens were tested in mechanical strength and around 1000 for dimensions of micro and macrostructural wood elements. In the case of the most important parameter – the wood density, no significant differences were found between values observed in standard forest land (0.722 g/cm3) and afforested farmland (0.701 g/cm3). Land use did not significantly influence MOR nor MOE. However, higher values for these parameters were observed on forest land. The annual ring width was significantly wider on trees that grew on former agricultural land. The high variability with significant differences was obtained within the dimensions of vessels and fibers. The presented results have confirmed that European beech species is highly suitable for former agricultural land afforestation with high-quality wood production. These findings challenge the assumption that wood on afforested agricultural land has worse quality and support its viability for industrial purposes.

欧洲山毛榉(Fagus sylvatica L.)是欧洲最重要的经济和生态落叶树种之一。然而,在欧洲山毛榉的情况下,缺乏关于在前农业用地上生长的木材质量的科学知识。因此,本研究旨在评估生长在波兰西北部前农业用地上的欧洲山毛榉的木材特性,并将其与标准林分进行比较。总共有2457个样本进行了机械强度测试,大约1000个样本进行了微观和宏观结构木材元素的尺寸测试。在最重要的参数—木材密度的情况下,在标准林地(0.722 g/cm3)和造林农田(0.701 g/cm3)中观察到的值之间没有显着差异。土地利用对MOR和MOE均无显著影响。然而,这些参数在林地上观测到更高的值。在原农用地上生长的树木年轮宽度明显更宽。在血管和纤维的尺寸范围内获得了显著差异的高变异性。结果表明,欧洲山毛榉非常适合用于原农用地造林,生产优质木材。这些发现挑战了造林农业用地上的木材质量较差的假设,并支持其用于工业目的的可行性。
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引用次数: 0
Use of NIR spectroscopy and partial least squares regression for prediction of chemical properties of Salix clones 利用近红外光谱和偏最小二乘回归预测柳属无性系的化学性质
IF 2.5 3区 农林科学 Q1 FORESTRY Pub Date : 2025-09-11 DOI: 10.1007/s00107-025-02320-1
Bilel Bouaziz, Ahmed Koubaa, Cyriac Mvolo, Sana Koubaa, Richard Krygier

The chemical wood properties characterization of biomass feedstocks is important since it determines their potential for various chemical and energy applications. Willow (Salix sp.), a short-rotation hardwood species, is an interesting feedstock for such applications. It can represent an alternative raw material for non-sustainable resources, long-rotation trees, and agricultural biological materials. This research aimed to characterize the chemical properties of different wood tissues of willow and to develop a nondestructive method for their prediction. Wood, bark, and twig samples were sampled from six willow clones (Alberta, Canada). Extractives, cellulose, hemicellulose, and lignin contents were measured in sampled tissues by destructive chemical analysis tests using TAPPI standard test methods. The surface chemistry of the samples was analyzed by near-infrared spectroscopy. Partial least squares regression models were developed for quantitatively predicting wood chemical components. The coefficients of determination (R² calibration, R² cross-validation, and R² prediction) ranged from 0.66 to 0.99 for extractives, lignin, cellulose, and hemicelluloses. Carbohydrates (glucose, xylose, arabinose, and mannose) ranged between 0.98 and 0.99, demonstrating excellent predictive capability for these components. These results confirm the applicability of the developed models to predict the chemical properties of willow biomass. Furthermore, the prediction models apply to all investigated tissues, emphasizing consistency. These results provide the possibility to characterize the chemical properties of willow biomass using easily implemented, cost-effective, nondestructive, and rapid NIR equipment.

生物质原料的化学木材特性表征很重要,因为它决定了它们在各种化学和能源应用方面的潜力。柳树(Salix sp.)是一种短周期的硬木树种,是这种应用的一种有趣的原料。它可以替代非可持续资源、长轮树木和农业生物材料。本研究旨在表征柳树不同木材组织的化学性质,并开发一种无损预测方法。从六个柳树无性系(加拿大阿尔伯塔)中采集了木材、树皮和树枝样本。通过破坏性化学分析测试,采用TAPPI标准测试方法,测量样品组织中的提取物、纤维素、半纤维素和木质素含量。用近红外光谱分析了样品的表面化学性质。建立了偏最小二乘回归模型,用于定量预测木材化学成分。萃取物、木质素、纤维素和半纤维素的测定系数(R²校准、R²交叉验证和R²预测)范围为0.66 ~ 0.99。碳水化合物(葡萄糖、木糖、阿拉伯糖和甘露糖)的范围在0.98和0.99之间,表明这些成分具有良好的预测能力。这些结果证实了所建立的模型在预测柳树生物量化学性质方面的适用性。此外,预测模型适用于所有研究组织,强调一致性。这些结果提供了使用易于实施,具有成本效益,非破坏性和快速近红外设备表征柳树生物质化学特性的可能性。
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European Journal of Wood and Wood Products
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