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Augmentation in fragrant agarwood oil quality by fermentation with a microbial consortium of bacterium (Microbacterium oxydans) and fungus (Penicillium aethiopicum) 利用由细菌(氧单胞菌)和真菌(青霉)组成的微生物联合体进行发酵,提高香沉香油的质量
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2024-05-10 DOI: 10.1007/s00107-024-02089-9
Pearlin Shabna Naziz, Runima Das, Supriyo Sen

Agarwood oil is considered to be one of the costliest essential oils, produced by hydro-distillation of agarwood chips from resin impregnated wood from Aquilaria spp. Prior to distillation, the traditional production process involves a prolonged (up to 90 days) soaking of the wood in water filled basins. This natural fermentation step exposes the wood to interactions with different types of microorganisms like in mixed culture fermentation. Reports have suggested a definite role of fermentation on the qualitative and quantitative properties of the distilled oil. However, these studies relied on single organism led fermentation. The present study explores the consortia approach as a method to enhance the aroma of the oil, simulating natural fermentation. Enzyme activity based screening and co-culture interaction studies were employed to develop three (3) fungal and seven (7) microbial (bacteria-fungi) two-member consortia from microorganisms isolated from traditional agarwood fermentation basins located in Assam, India. The effect of consortia on agarwood oil was validated by fermentation with agarwood chips. Among the fungal consortia, 20PW (Pupureocillium lilacinum) with PG120 (Penicillium aethiopicum) and among bacteria- fungi consortia NH7 (Microbacterium oxydans) with PG120 (Penicillium aethiopicum), showed promising results. GC–MS analysis revealed qualitative enhancement of oil by all consortia compared to the control for key aroma compounds such as Agarospirol, Guaiol, 10S, 11SHimachala-3(12), 4-diene and Aristol-1(10)-en-9-ol. This is the first report where microbial consortia were used for the fermentation of agarwood chips, which enhance the quality of agarwood essential oil.

沉香精油被认为是最昂贵的精油之一,它是通过水蒸馏沉香木碎片生产出来的,沉香木碎片取自浸渍树脂的 Aquilaria 树属木材。 在蒸馏之前,传统的生产工艺需要将木材长时间(长达 90 天)浸泡在装满水的盆中。这一自然发酵步骤使木材与不同类型的微生物相互作用,就像混合培养发酵一样。有报告表明,发酵对蒸馏油的质量和数量特性有一定的影响。不过,这些研究都是以单一微生物为主导的发酵。本研究探索了一种模拟自然发酵的方法,即联合体方法来提高油的香气。通过基于酶活性的筛选和共培养相互作用研究,从印度阿萨姆邦传统琼脂木发酵池中分离的微生物中培养出三(3)个真菌和七(7)个微生物(细菌-真菌)双成员联合体。用沉香木屑发酵验证了菌群对沉香油的影响。在真菌联合菌群中,20PW(紫丁香毛霉)与 PG120(青霉),以及细菌-真菌联合菌群 NH7(氧单胞菌)与 PG120(青霉),都显示出良好的效果。气相色谱-质谱分析表明,与对照组相比,所有菌群都提高了油中主要芳香化合物的质量,如 Agarospirol、Guaiol、10S、11SHimachala-3(12), 4-diene 和 Aristol-1(10)-en-9-ol。这是首次报道利用微生物群对沉香木屑进行发酵,从而提高沉香精油的质量。
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引用次数: 0
A systematic approach to obtain optimized low-cost balsa wood structure subjected to the effects of uncertainties: A FEM approach 受不确定性影响的低成本轻木结构优化系统方法:有限元方法
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2024-05-07 DOI: 10.1007/s00107-024-02083-1
Izadora Aparecida Ramos, Francisco Scinocca, Fábio Lúcio Santos, Wander Gustavo Rocha Vieira

Lightweight structures are of paramount importance in engineering applications. Optimal designs combining various optimization techniques can maximize desired mechanical characteristics while minimizing undesired static or dynamic behaviors. However, these optimized structures usually have low safety factors, which makes it necessary to consider uncertainties in project design to ensure their reliability. This paper presents a systematic approach to quantify uncertainties in an optimized structural member of an unmanned aerial vehicle (UAV) wing used in remote sensing. The UAV wing structural member was optimized using the Multi-Objective Genetic Algorithm, and balsa wood, a lightweight and ecological material with high variability in mechanical properties, was used for its manufacture. To analyze the structural integrity of the UAV wing, the present study quantified parametric uncertainties in material properties and manufacturing processes using stochastic models. A probabilistic approach was adopted, which revealed a 37% reduction in the structure's safety coefficient. Various conclusions were drawn from this research, which highlights the importance of considering uncertainties in the design of optimized structures to ensure their reliability.

轻质结构在工程应用中至关重要。结合各种优化技术的最佳设计可以最大限度地提高所需的机械特性,同时最大限度地减少不希望出现的静态或动态行为。然而,这些优化结构的安全系数通常较低,因此有必要考虑项目设计中的不确定性,以确保其可靠性。本文介绍了一种系统方法,用于量化遥感无人机(UAV)机翼优化结构部件中的不确定性。采用多目标遗传算法对无人飞行器机翼结构件进行了优化,并使用了轻质、生态、机械性能变化大的巴尔萨木材进行制造。为了分析无人机机翼的结构完整性,本研究使用随机模型量化了材料属性和制造过程中的参数不确定性。采用的概率方法显示,结构的安全系数降低了 37%。本研究得出了各种结论,强调了在优化结构设计中考虑不确定性以确保其可靠性的重要性。
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引用次数: 0
Identification and localization of veneer knot defects based on parallel structure fusion approach 基于平行结构融合方法的单板结缺陷识别和定位
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2024-05-04 DOI: 10.1007/s00107-024-02086-y
Lihui Zhong, Zhengquan Dai, Zhuobin Zhang, Yongke Sun, Yong Cao, Leiguang Wang

Veneer knots are the main indicator of plywood quality. Existing veneer knot identification algorithms have a high identification accuracy rate of over 90%. However, the convolutional neural network (CNN) model is complex and requires laborious data labeling. The localization algorithm produces veneer knot bounding boxes, except for the Mask Region-based CNN (Mask R-CNN) model, which is not accurate and has error transmission. Additionally, the calculation of defect size (area and diameter) has not been addressed. This paper proposes a parallel structured fusion algorithm. One branch employs a classical simple CNN, specifically the Inception V3 network, to identify veneer knot defects. The other branch proposes an improved K-means clustering algorithm to localize veneer knot defects. After identification and localization are achieved, the actual area of the defect is calculated. The proposed method for identifying veneer knot defects has an accuracy rate of 99.61%. The size accuracy localization rate is 94%, with an under-sized localization rate of 2%, an over-sized localization rate of 3%, and the knot localization error rate is 1%. Additionally, the algorithm also calculates the area and diameter of the knot, with a mean absolute error of the diameter of 3.23 mm. This paper presents an algorithm with low complexity, fast speed, high accuracy, and no error transmission, making it suitable for identifying and localizing other defects.

单板节是胶合板质量的主要指标。现有单板节识别算法的识别准确率高达 90% 以上。然而,卷积神经网络(CNN)模型比较复杂,需要费力地标注数据。除基于掩码区域的 CNN(掩码 R-CNN)模型外,定位算法可生成单板结边界框,但该模型并不准确,且存在误差传输。此外,缺陷大小(面积和直径)的计算也没有得到解决。本文提出了一种并行结构化融合算法。其中一个分支采用经典的简单 CNN,特别是 Inception V3 网络,来识别单板结缺陷。另一个分支提出了一种改进的 K-means 聚类算法来定位单板结缺陷。在实现识别和定位后,再计算缺陷的实际面积。所提出的单板结缺陷识别方法的准确率为 99.61%。尺寸精确定位率为 94%,尺寸不足定位率为 2%,尺寸过大定位率为 3%,木结定位错误率为 1%。此外,该算法还能计算绳结的面积和直径,直径的平均绝对误差为 3.23 毫米。本文提出的算法具有复杂度低、速度快、精度高、无误差传输等特点,适用于其他缺陷的识别和定位。
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引用次数: 0
Application of the TOPSIS decision-making method for selecting a manufacturing technique for children’s furniture elements with therapeutic functions 应用 TOPSIS 决策方法为具有治疗功能的儿童家具元件选择制造技术
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2024-05-03 DOI: 10.1007/s00107-024-02082-2
Grzegorz Struzikiewicz, Marek Misiniec, Kinga Misiniec, Anna Myrda

Making furniture or furniture elements that account for the needs of children at various stages of development or with psychomotor dysfunctions is very difficult. From the point of view of exploitation and production technology, it is difficult to select a specific material and manufacturing technique. In this article, the results of using the APEKS method, which is a type of Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) method, are presented to select the best solution for the production of children’s furniture elements with surface structures similar to those of natural materials. Wood bark was selected as a material that, due to the sensory tactile sensations of dysfunctional children, could contribute to therapy and education. Comparative analysis was performed on the basis of the subtractive and additive methods used for manufacturing furniture products. Precise multiaxis milling of ash wood and 3D printing with fused filament fabrication technology using wood PLA filaments were carried out. The method used to select the best option considered quantitative and qualitative criteria in the assessment. Various parameters characterizing the surfaces were analyzed, such as geometric dimensions, hill heights, valley depths, and 3D surface parameters. The quality and surface roughness (Sa, Sz, Ssk, Sku, Sp, and Sv) parameters obtained based on 3D microscope measurements were determined. A scale of 1 to 10 was used to assess qualitative factors (i.e., usability and aesthetics). Based on the critical values obtained from the coefficient Kcri = 79.36, it was assumed that multiaxis wood milling was the best method for producing furniture elements with the required surface characteristics for use as therapeutic and educational tools for children with dysfunctions. The applied method allowed an effective evaluation of the compared variants of the production of furniture elements for customized applications.

根据处于不同发育阶段或有心理运动障碍的儿童的需要制作家具或家具部件是非常困难的。从开发和生产技术的角度来看,很难选择特定的材料和制造技术。本文介绍了使用 APEKS 方法的结果,该方法是一种通过与理想解决方案相似性进行排序偏好的技术(TOPSIS)方法,旨在为生产表面结构类似于天然材料的儿童家具元件选择最佳解决方案。由于功能障碍儿童的感官触觉,木皮被选为一种有助于治疗和教育的材料。根据用于制造家具产品的减法和加法方法进行了比较分析。对白蜡木进行了精确的多轴铣削,并使用木质聚乳酸长丝通过熔融长丝制造技术进行了三维打印。选择最佳方案的方法在评估中考虑了定量和定性标准。分析了表征表面特征的各种参数,如几何尺寸、山丘高度、山谷深度和三维表面参数。根据三维显微镜测量结果确定了质量和表面粗糙度(Sa、Sz、Ssk、Sku、Sp 和 Sv)参数。定性因素(即可用性和美观度)的评估采用 1-10 分制。根据系数 Kcri = 79.36 得出的临界值,可以认为多轴木材铣削是生产具有所需表面特征的家具元件的最佳方法,可用作功能障碍儿童的治疗和教育工具。采用这种方法可以有效地评估用于定制应用的家具元件生产的比较变体。
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引用次数: 0
Enhancing the fire resistance properties of thermally modified Robinia pseudoacacia wood with natural and synthetic flame retardants: chemical characterisation and fire behaviour 用天然和合成阻燃剂提高热改性洋槐木材的耐火性能:化学特征和火灾行为
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2024-05-03 DOI: 10.1007/s00107-024-02079-x
Salvio Marino, Milan Gaff, Anil Kumar Sethy, Gourav Kamboj, Fatemeh Rezaei, František Kačík, S. Behnam Hosseini, Haitao Li, David Hui

The increasing demand for wood with enhanced flame retardant characteristics in construction applications necessitates strategic interventions. This study explores the fire behaviour and chemical characterisation of Robinia pseudoacacia wood subjected to thermal modification and flame retardant treatments. Thermal modification was carried out at three different temperatures (160 °C, 180 °C and 240 °C). The fire properties of wood coated with Flame Gard (F), a commercial flame retardant, arabinogalactan (A), a natural flame retardant, melamine adhesive (MF) with ammonium polyphosphate (AP), nanosilica (NS), nanoclay (NC) (MF-AP-NS and MF-AP-NC) and arabinogalactan with AP, NS and NC (A-AP-NS and A-AP-NC), were assessed using cone calorimetry in terms of the weight loss rate, ignition time and heat release rate. The commercial flame retardant Flame Gard outperformed the natural and fortified flame retardants in terms of the weight loss rate, heat release rate (HRR) and ignition time (tig). Unmodified samples exhibited superior fire properties in terms of tig and HRR compared to thermally modified samples. The peak heat release rate (kW.m− 2) and time to peak heat release rate (s) showed a moderate degree of dependency on the chemical constituents of the wood.

在建筑应用中,对具有增强阻燃特性的木材的需求日益增长,因此有必要采取战略性干预措施。本研究探讨了经过热改性和阻燃处理的刺槐木材的燃烧行为和化学特性。热改性在三种不同的温度(160 ℃、180 ℃ 和 240 ℃)下进行。涂有商用阻燃剂 Flame Gard (F)、天然阻燃剂阿拉伯半乳聚糖 (A)、三聚氰胺粘合剂 (MF) 和聚磷酸铵 (AP)、纳米二氧化硅 (NS)、纳米粘土 (NC) 的木材的防火性能、采用锥形量热仪评估了三聚氰胺粘合剂(MF)与聚磷酸铵(AP)、纳米二氧化硅(NS)、纳米粘土(NC)(MF-AP-NS 和 MF-AP-NC)以及阿拉伯半乳聚糖与 AP、NS 和 NC(A-AP-NS 和 A-AP-NC)的失重率、点燃时间和热释放率。商用阻燃剂 Flame Gard 在失重率、热释放率(HRR)和点火时间(tig)方面均优于天然阻燃剂和强化阻燃剂。与热改性样品相比,未改性样品在 tig 和 HRR 方面表现出更优越的防火性能。峰值热释放率(kW.m- 2)和达到峰值热释放率的时间(s)在一定程度上取决于木材的化学成分。
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引用次数: 0
Energy and structural optimization of mid-rise light-frame timber buildings for different climates and seismic zones in Chile 针对智利不同气候和地震带对中层轻型木结构建筑进行能源和结构优化
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2024-05-03 DOI: 10.1007/s00107-024-02085-z
Alexander Wenzel, Sergio Vera, Pablo Guindos

Location determines not only the climatic condition but also the structural loads that the structure must withstand. Given the broad variety of climatic and seismic requirements of Chile, the design of lightweight timber buildings considering both energy and seismic design parameters and boundary conditions becomes a difficult task. The main objective of this research is to analyze and quantify the effect of climates, seismic loads, lateral anchorage, and story number on the optimal energy design solutions, including the seismic behavior in a light-frame timber building. Furthermore, the optimal design was parametrically analyzed considering five Chilean cities that consider different climates, seismic zone, number of stories, and lateral anchorage systems to prevent rocking (overturning) due to lateral seismic forces. The optimal wall insulation thickness, stud spacing, and thermal mass exhibited significant variations depending on the buildings' number of stories, lateral anchorage system, climate, and seismic zone. Therefore, the results of this investigation reinforce the necessity of integrating energy and seismic designs for light-frame timber buildings. The optimal designs obtained in this investigation showed considerable variations depending on the combination of climatic and seismic loads as well as the number of stories and anchoring systems. The article's main contributions are the evidence of the structural and energy design interconnection of light-frame timber buildings and how design variables, such as stud spacing, floor concrete thickness layer, and wall insulation thickness, are related and change according to the different climates, seismic loads, lateral anchorage, and story number.

地理位置不仅决定了气候条件,还决定了结构必须承受的结构荷载。智利的气候和抗震要求多种多样,因此,在设计轻型木结构建筑时要同时考虑能耗和抗震设计参数以及边界条件,这就成为了一项艰巨的任务。本研究的主要目的是分析和量化气候、地震荷载、侧向锚固和层数对最佳节能设计方案的影响,包括轻型木结构建筑的抗震性能。此外,考虑到智利五个城市的不同气候、地震带、层数和侧向锚固系统,对最佳设计进行了参数分析,以防止侧向地震力引起的摇晃(倾覆)。根据建筑物的层数、侧向锚固系统、气候和地震带的不同,最佳墙体保温层厚度、墙螺栓间距和热质量都有显著差异。因此,本次调查的结果加强了对轻型木结构建筑进行综合节能和抗震设计的必要性。根据气候荷载和地震荷载的组合以及层数和锚固系统的不同,本次研究获得的最佳设计方案也有很大差异。文章的主要贡献在于证明了轻型木结构建筑的结构设计与能源设计之间的相互联系,以及诸如墙柱间距、楼板混凝土厚度层和墙体保温层厚度等设计变量是如何根据不同的气候、地震荷载、侧向锚固和层数而相互关联和变化的。
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引用次数: 0
Effect of heat treatment at mild temperatures on the composition and physico-chemical properties of Scots pine resin 低温热处理对苏格兰松树树脂的成分和物理化学特性的影响
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2024-05-03 DOI: 10.1007/s00107-024-02087-x
Errj Sansonetti, Dace Cirule, Edgars Kuka, Ingeborga Andersone, Bruno Andersons, Kristine Meile, Laima Vevere

A major function of resin in trees is to provide defense against external attacks by releasing the resin flow in the attacked or damaged area. Nonetheless, leakage of resin on the surface can have negative aesthetic and economic impacts on wood materials. The aim of this study was to investigate how heat treatment affects the physico-chemical properties of the resin of Pinus sylvestris L. to hinder exudation on wood surfaces during service. To reduce the fluidity of the resin, it is necessary to remove the volatile fraction of resin, and several studies have been carried out in this direction, providing useful information about this process. The results from thermal analyses (DSC, TGA) confirmed that heat treatment at mild temperatures, 80 °C, 90 °C and 100 °C had a positive effect on increasing the glass transition temperature Tg and that the Tg and the residual volatile content were strongly correlated. FTIR spectroscopy, before and after heat treatment, did not reveal major changes in chemical structure, while UHPLC-DAD-MS analysis revealed significant differences in the ratios of compounds, which are the result of possible chemical reactions, such as dehydrogenation, oxidation and isomerization.

树木树脂的一个主要功能是通过释放受攻击或受损区域的树脂流来抵御外部攻击。然而,表面树脂的渗漏会对木质材料的美观和经济产生负面影响。本研究旨在探讨热处理如何影响欧洲赤松树脂的物理化学特性,以阻止其在使用过程中渗出到木材表面。为了降低树脂的流动性,有必要去除树脂中的挥发性成分,在这方面已经开展了多项研究,提供了有关这一过程的有用信息。热分析(DSC、TGA)的结果证实,在 80 ℃、90 ℃ 和 100 ℃ 等温和温度下进行热处理对提高玻璃化转变温度 Tg 有积极作用,而且 Tg 与残余挥发物含量密切相关。热处理前后的傅立叶变换红外光谱分析没有发现化学结构的重大变化,而超高压液相色谱-DAD-MS 分析则发现化合物的比例存在显著差异,这是可能发生脱氢、氧化和异构化等化学反应的结果。
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引用次数: 0
Correction: Study on vibration performance and comfort of glulam beam and deck floor 更正:胶合梁和甲板地板的振动性能和舒适性研究
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2024-04-27 DOI: 10.1007/s00107-024-02084-0
Yifan Zhang, Changqing Miao, Zheng Wang, Zhaodong Xu
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引用次数: 0
Local stability of glued laminated bamboo columns with box sections under axial compression 箱形截面胶合层压竹柱在轴向压缩下的局部稳定性
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2024-04-26 DOI: 10.1007/s00107-024-02066-2
Yi Su, Jun Zou

Laminated bamboo columns with box sections are favored by designers because they overcome the disadvantage of small elastic modulus, but local buckling behavior caused by an excessive width-to-thickness ratio will lead to a non-uniform distribution of stress. The discontinuous cracks at the glued joints and waveform deformation indicate that the local buckling has a significant effect on the bearing capacity of columns with box sections. However, few studies have been reported on the evaluation of bearing capacity considering local stability due to non-uniformity and discontinuity. The experiments on 5 glued laminated bamboo columns with box sections (GLBCs) with different length-to-width ratios under axial compression were carried out. The test results showed that the waveform bulging failure occurred on the surface of GLBCs before the overall buckling, and an obvious debonding failure occurred between the bamboo plates. These failures aggravated the local buckling failure. As the length-to-width ratio increased, the number of waveforms buckling increased, the lower the bearing capacity. To evaluate the local stability of GLBCs accurately, a new anisotropic plate model considering the width correction coefficient and material anisotropy for the critical buckling load of GLBC was proposed. Furthermore, it can be found that an appropriate width-to-thickness ratio can effectively avoid local buckling failure. A formula for the critical width-to-thickness ratio of GLBCs under different slenderness ratios was proposed. In this paper, the anisotropic plate model proposed can accurately evaluate the bearing capacity considering the local stability of GLBCs under axial compression.

箱形截面的层压竹柱因克服了弹性模量小的缺点而受到设计人员的青睐,但过大的宽厚比引起的局部屈曲行为会导致应力分布不均匀。胶接处的不连续裂缝和波形变形表明,局部屈曲对箱形截面柱的承载能力有很大影响。然而,考虑到非均匀性和不连续性导致的局部稳定性而对承载能力进行评估的研究报告很少。本文对 5 根不同长宽比的箱形截面胶合层压竹柱(GLBC)进行了轴向压缩试验。试验结果表明,在整体屈曲之前,GLBC 的表面出现了波形隆起失效,竹板之间出现了明显的脱粘失效。这些失效加剧了局部屈曲失效。随着长宽比的增大,波形屈曲的次数增加,承载能力降低。为了准确评估 GLBC 的局部稳定性,提出了一种新的各向异性板模型,该模型考虑了宽度修正系数和材料各向异性,用于计算 GLBC 的临界屈曲载荷。此外,还发现适当的宽厚比可以有效避免局部屈曲破坏。本文提出了不同纤度比下 GLBC 临界宽厚比的计算公式。本文提出的各向异性板模型可以准确评估考虑了轴向压缩下 GLBC 局部稳定性的承载能力。
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引用次数: 0
Development of bentonite-based organo-geopolymer hybrid wood binder 开发基于膨润土的有机土工聚合物混合木材粘结剂
IF 2.4 3区 农林科学 Q1 FORESTRY Pub Date : 2024-04-26 DOI: 10.1007/s00107-024-02078-y
Oktay Gonultas

The study addresses concerns associated with formaldehyde-based adhesives in wood panel board production by proposing geopolymer-based wood binders as promising, formaldehyde-free alternatives. Using bentonite, the research delves into the development and performance properties of this geopolymer wood binder. The BET method was employed for the surface characterization of precursor raw materials for binder preparation. Si and Al elements identified through XRF analysis were correlated with characteristic bands in the FTIR spectrum. Alkaline activation solutions, employing sodium silicate and sodium hydroxide with a molar ratio range of 0.5 to 2.5 (SiO2:Na2O), revealed that binders with a molar ratio of 2.5 exhibited lower pH and higher adhesion strength. Different geopolymer formulations at solution to powder ratios (s/p) of 1.33, 3, and 3.5 determined s/p 3.5 as optimal for bentonite-based organo-geopolymer binders. Viscosity, gel time, pH, and solids content were examined, showing the effectiveness of substituting 10% silica fume to enhance the geopolymerization process and improve adhesion. Modifications using citric acid, sucrose, paraffin, pMDI, triacetin, and resorcinol demonstrated wet bonding strength comparable to urea formaldehyde adhesive. Analytical techniques, including FTIR spectroscopy, XRD analysis, and SEM EDX analysis, provided insights into functional groups, crystallographic properties, and microstructural characteristics. The concentration of Si and Al compounds on the bonding line, coupled with Na element diffusion, was observed through these analyses. Light microscopy of lap shear samples revealed a thinner bonding line, affirming effective binder penetration into wood cell lumens in bentonite-based organo-geopolymer binder formulations.

该研究提出了以土工聚合物为基础的木材粘合剂作为前景广阔的无甲醛替代品,从而解决了人造板生产中与甲醛基粘合剂相关的问题。研究使用膨润土,深入探讨了这种土工聚合物木材粘合剂的开发和性能特性。研究采用 BET 方法对制备粘合剂的前体原材料进行表面表征。通过 XRF 分析确定的硅和铝元素与傅立叶变换红外光谱中的特征谱带相关联。采用硅酸钠和氢氧化钠摩尔比范围为 0.5 至 2.5(SiO2:Na2O)的碱性活化溶液显示,摩尔比为 2.5 的粘结剂具有较低的 pH 值和较高的粘结强度。溶液与粉末的比率(s/p)分别为 1.33、3 和 3.5 时,不同的土工聚合物配方确定 s/p 3.5 为膨润土基有机土工聚合物粘结剂的最佳比率。对粘度、凝胶时间、pH 值和固体含量进行了检测,结果表明用 10% 的硅灰替代硅粉可有效增强土工聚合过程并提高粘附性。使用柠檬酸、蔗糖、石蜡、pMDI、三醋精和间苯二酚进行改性后,湿粘合强度与脲醛粘合剂相当。傅立叶变换红外光谱、XRD 分析和 SEM EDX 分析等分析技术有助于深入了解官能团、晶体学特性和微观结构特征。通过这些分析,可以观察到结合线上硅和铝化合物的浓度,以及 Na 元素的扩散情况。搭接剪切样品的光学显微镜检查发现,粘合线更细,这证明膨润土基有机土工聚合物粘合剂配方中的粘合剂能有效渗入木材细胞腔。
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European Journal of Wood and Wood Products
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