Iva Palatinuš, Katarina Gobo, Karmen Fio Firi, Frane Marković, J. Sremac
The multicoloured ‘Košna’ conglomerates are investigated in the area of the Košna Voda spring, in the Brušane area of Velebit Mt., Croatia. The studied conglomerates consist of red-coloured matrix and clasts of various lithologies (sandstones, limestones, chert and quartz pebbles) and sizes, suggesting provenance from different areas. Average clast size and their percentage was determined by the Udden-Wentworth classification with estimation of the matrix content. Clasts and matrix lithological and mineralogical characteristics were determined using petrographic, ore microscopy, and X-ray diffraction analysis. Sandstone clasts in the studied conglomerates are classified as lithic arenites, subarkoses and arkoses. Limestone clasts are mostly wackestones to packstones with foraminifera, ostracods, echinoid and bryozoan fragments that derive from late Carboniferous/early Permian shallow-marine limestones. Calcispheres and incipient growth forms of Microcodium are also present, suggesting different sediment sources and resedimentation processes. Fragments of fusulinid foraminifera were identified in the matrix of the ‘Košna’ conglomerates. Based on the analyses performed, and field observations, the ‘Košna’ conglomerates are described as early Permian (Cisuralian) polymictic clast-supported to matrix-supported conglomerates and breccia-conglomerates that share structural and textural similarities with conglomerates from other areas in the Dinarides, as well as in the Eastern and Southern Alps. The ‘Košna’ conglomerates are younger than the Sakmarian and are comparable with the Trogkofel limestones of the Carnic Alps and the Karavanke Mts. in Slovenia. We suggest that the studied deposits originated from the uplifted Variscan Mountains during the Variscan and Saalian orogenic movements, and were finally deposited from tractive flows and occasional debris flows in a shallow marine environment of the Palaeo-Tethys, possibly in fan deltas.
对克罗地亚韦莱比特山布鲁萨内地区 Košna Voda 泉水区域的多色 "Košna "砾岩进行了调查。所研究的砾岩由红色基质和不同岩性（砂岩、石灰岩、燧石和石英鹅卵石）和大小的碎屑组成，表明来自不同地区。根据 Udden-Wentworth 分类法确定了碎屑的平均大小及其百分比，并对基质含量进行了估算。通过岩石学、矿石显微镜和 X 射线衍射分析确定了碎屑和基质的岩性和矿物学特征。所研究的砾岩中的砂岩碎屑被划分为石质 arenites、subarkoses 和 arkoses。石灰岩碎屑主要是有孔虫、浮游动物、回声虫和贝类碎片的腊石和包石，来自石炭纪晚期/二叠纪早期的浅海石灰岩。此外，还发现了钙球和初生形态的微钠，这表明沉积物的来源和再沉积过程各不相同。在 "科什纳 "砾岩的基质中发现了有孔虫碎片。根据所做的分析和实地观察，"科什纳 "砾岩被描述为早二叠世（西苏拉维亚）多岩相碎屑岩支撑到基质支撑的砾岩和角砾岩砾岩，在结构和纹理上与迪纳里德斯山脉其他地区以及东阿尔卑斯山和南阿尔卑斯山的砾岩有相似之处。Košna "砾岩比萨克马里岩年轻，可与斯洛文尼亚卡尼阿尔卑斯山和卡拉万克山的 Trogkofel 灰岩相媲美。我们认为，所研究的沉积物起源于瓦利斯坎和萨里安造山运动期间隆起的瓦利斯坎山脉，最后由古泰西浅海环境中的牵引流和偶尔出现的碎屑流沉积而成，可能位于扇形三角洲。
{"title":"Lower Permian Košna conglomerates of the Velebit Mt. (Croatia): modal composition, provenance and depositional environment","authors":"Iva Palatinuš, Katarina Gobo, Karmen Fio Firi, Frane Marković, J. Sremac","doi":"10.4154/gc.2024.02","DOIUrl":"https://doi.org/10.4154/gc.2024.02","url":null,"abstract":"The multicoloured ‘Košna’ conglomerates are investigated in the area of the Košna Voda spring, in the Brušane area of Velebit Mt., Croatia. The studied conglomerates consist of red-coloured matrix and clasts of various lithologies (sandstones, limestones, chert and quartz pebbles) and sizes, suggesting provenance from different areas. Average clast size and their percentage was determined by the Udden-Wentworth classification with estimation of the matrix content. Clasts and matrix lithological and mineralogical characteristics were determined using petrographic, ore microscopy, and X-ray diffraction analysis. Sandstone clasts in the studied conglomerates are classified as lithic arenites, subarkoses and arkoses. Limestone clasts are mostly wackestones to packstones with foraminifera, ostracods, echinoid and bryozoan fragments that derive from late Carboniferous/early Permian shallow-marine limestones. Calcispheres and incipient growth forms of Microcodium are also present, suggesting different sediment sources and resedimentation processes. Fragments of fusulinid foraminifera were identified in the matrix of the ‘Košna’ conglomerates. Based on the analyses performed, and field observations, the ‘Košna’ conglomerates are described as early Permian (Cisuralian) polymictic clast-supported to matrix-supported conglomerates and breccia-conglomerates that share structural and textural similarities with conglomerates from other areas in the Dinarides, as well as in the Eastern and Southern Alps. The ‘Košna’ conglomerates are younger than the Sakmarian and are comparable with the Trogkofel limestones of the Carnic Alps and the Karavanke Mts. in Slovenia. We suggest that the studied deposits originated from the uplifted Variscan Mountains during the Variscan and Saalian orogenic movements, and were finally deposited from tractive flows and occasional debris flows in a shallow marine environment of the Palaeo-Tethys, possibly in fan deltas.","PeriodicalId":55108,"journal":{"name":"Geologia Croatica","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140421369","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. Garašić, Boško Lugović †, Mirjana Krsnik, Š. Bilić, Hans-Peter Meyer, Ralf Schuster, M. Vrkljan
In this article, dumortierite from Croatia is described for the first time. Dumortierite formed in a pegmatite dyke cutting through Cretaceous two-mica leucogranite of the magmatic-metamorphic complex of Mt. Moslavačka Gora. The pegmatite dyke shows a magmatic mineral association of coarse-grained quartz, orthoclase, microcline and albite, less abundant muscovite, biotite, pinkish andalusite and blue-coloured prismatic dumortierite I crystals. Subsequent alteration by titanium-rich hydrothermal fluids led to partial replacement of dumortierite I and andalusite by secondary fibrous to acicular purple dumortierite II enriched in Mg and Ti. During temperature decrease perthite developed in feldspars and at a still later stage, sericite partially replaced not only feldspars but also andalusite and both types of dumortierite along grain boundaries and cracks. Final alteration at very low temperatures caused formation of clay minerals at the expense of feldspars. According to mineral chemical analyses, the feldspars are represented by albite and K-feldspar with a low albite component. Biotite corresponds to annite and its subhedral shape and chemical composition point to magmatic crystallisation from a peraluminous melt derived from a crustal source. Coarse muscovite flakes contain 1.31-1.48 wt.% FeO and 0.56-0.70 wt.% TiO2. Their Na/(Na+K) ratios (0.08–0.09) prove a magmatic origin, whereas lower ratios in sericite (0.04–0.06) indicate formation during retrogression. Magmatic muscovite is in textural equilibrium with andalusite, also implying an igneous origin for the latter, which belongs to the S3 textural type of andalusite in felsic igneous rocks. Electron microprobe analyses clearly show a strong positive correlation between Si tetrahedral deficiency (3-Si) and the sum of Al+Ti, (R2= 0.85) in both types of dumortierite, implying Al replacement by Ti. However, Al replacement by Ti is not restricted to Al in the octahedral position, as generally accepted, but most probably also in the tetrahedral position. Distinct pleochroic colours in dumortierite are usually explained by the [Fe/(Fe+Ti)]x100 factor, but according to this study, elevated Mg contents stabilize red to violet coloured dumortierite at higher [Fe/(Fe+Ti)] x100 factors than those previously suggested.
本文首次描述了克罗地亚的杜姆铁矿。杜姆铁矿形成于一条伟晶岩堤内，该伟晶岩堤切割于白垩纪莫斯拉瓦奇卡戈拉山岩浆-变质复合体的双云母白花岗岩中。伟晶岩堤显示出岩浆矿物组合，包括粗粒石英、正长石、微斜长石和白云石，以及含量较少的黝帘石、生物黄铁矿、粉红色安山岩和蓝色棱柱形杜莫斯特岩 I 晶体。随后富含钛的热液蚀变导致团铁矿 I 和安山岩部分被富含镁和钛的次生纤维状至针状紫色团铁矿 II 所取代。在温度降低的过程中，长石中出现了透辉石，而在更晚的阶段，绢云母不仅部分取代了长石，还沿着晶界和裂缝取代了安达拉石和两种杜姆铁矿。在极低温度下进行的最终蚀变形成了粘土矿物，牺牲了长石。根据矿物化学分析，长石以白云石和 K 长石为代表，其中白云石成分较少。黑云母与黝帘石相对应，它的近面体形状和化学成分表明它是由地壳来源的过铝熔体岩浆结晶而成的。粗云母片含有 1.31-1.48 重量%的氧化铁和 0.56-0.70 重量%的二氧化钛。它们的 Na/（Na+K）比率（0.08-0.09）证明其来源于岩浆，而绢云母中较低的比率（0.04-0.06）则表明其形成于逆冲过程中。岩浆麝香石与安山岩在质地上处于平衡状态，这也意味着后者起源于火成岩，属于长粒火成岩中安山岩的 S3 质地类型。电子微探针分析清楚地表明，在这两种类型的杜姆铁矿中，硅的四面体缺失（3-Si）与 Al+Ti 的总和（R2= 0.85）之间存在很强的正相关性，这意味着 Al 被 Ti 替代。然而，钛对铝的置换并不像一般认为的那样仅限于八面体位置上的铝，很可能还包括四面体位置上的铝。通常用[Fe/(Fe+Ti)]x100 因子来解释杜姆铁矿中不同的多色性颜色，但根据这项研究，在[Fe/(Fe+Ti)]x100 因子比以前提出的更高的情况下，镁含量升高会使红色至紫色杜姆铁矿稳定下来。
{"title":"First occurrence of dumortierite in Croatia: its chemical composition and appearance as an igneous mineral in leucogranite-hosted pegmatite","authors":"V. Garašić, Boško Lugović †, Mirjana Krsnik, Š. Bilić, Hans-Peter Meyer, Ralf Schuster, M. Vrkljan","doi":"10.4154/gc.2024.01","DOIUrl":"https://doi.org/10.4154/gc.2024.01","url":null,"abstract":"In this article, dumortierite from Croatia is described for the first time. Dumortierite formed in a pegmatite dyke cutting through Cretaceous two-mica leucogranite of the magmatic-metamorphic complex of Mt. Moslavačka Gora. The pegmatite dyke shows a magmatic mineral association of coarse-grained quartz, orthoclase, microcline and albite, less abundant muscovite, biotite, pinkish andalusite and blue-coloured prismatic dumortierite I crystals. Subsequent alteration by titanium-rich hydrothermal fluids led to partial replacement of dumortierite I and andalusite by secondary fibrous to acicular purple dumortierite II enriched in Mg and Ti. During temperature decrease perthite developed in feldspars and at a still later stage, sericite partially replaced not only feldspars but also andalusite and both types of dumortierite along grain boundaries and cracks. Final alteration at very low temperatures caused formation of clay minerals at the expense of feldspars. According to mineral chemical analyses, the feldspars are represented by albite and K-feldspar with a low albite component. Biotite corresponds to annite and its subhedral shape and chemical composition point to magmatic crystallisation from a peraluminous melt derived from a crustal source. Coarse muscovite flakes contain 1.31-1.48 wt.% FeO and 0.56-0.70 wt.% TiO2. Their Na/(Na+K) ratios (0.08–0.09) prove a magmatic origin, whereas lower ratios in sericite (0.04–0.06) indicate formation during retrogression. Magmatic muscovite is in textural equilibrium with andalusite, also implying an igneous origin for the latter, which belongs to the S3 textural type of andalusite in felsic igneous rocks. Electron microprobe analyses clearly show a strong positive correlation between Si tetrahedral deficiency (3-Si) and the sum of Al+Ti, (R2= 0.85) in both types of dumortierite, implying Al replacement by Ti. However, Al replacement by Ti is not restricted to Al in the octahedral position, as generally accepted, but most probably also in the tetrahedral position. Distinct pleochroic colours in dumortierite are usually explained by the [Fe/(Fe+Ti)]x100 factor, but according to this study, elevated Mg contents stabilize red to violet coloured dumortierite at higher [Fe/(Fe+Ti)] x100 factors than those previously suggested.","PeriodicalId":55108,"journal":{"name":"Geologia Croatica","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140418581","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This paper presents the first results of palynological research from the Spila nad Procjepom cave, situated in the Mljet National Park, Croatia. The palynological data obtained, enables a partial insight into the local vegetation cover, temporal changes in the vegetation during the accumulation of studied deposits (at ca. 3500 cal years BP), and post-depositional processes that influenced the palynomorph assemblage. Results of palynofacies analysis indicate changes from fluvial (channel deposits), through palustrine to terrestrial environments. Although the interpretation of changes in plant cover, due to the lack of statistical significance, should be taken with caution, preserved pollen types confirm the dominance of the Mediterranean evergreen forest vegetation on Mljet island. Moreover, a high proportion of non-arboreal pollen (NAP) indicates some level of forest degradation, ranging from Mediterranean open forest to degraded maquis. Abundant charcoal additionaly confirms that the cave was inhabited by humans.
本文介绍了位于克罗地亚姆列特国家公园内的 Spila nad Procjepom 洞穴的首批古生物学研究成果。所获得的古动物学数据有助于部分了解当地的植被覆盖情况、所研究沉积物（约公元前 3500 年）堆积过程中植被的时间变化以及影响古动物组合的沉积后过程。古乐彩网分析结果表明了从河道沉积到古河道沉积再到陆地环境的变化。虽然由于缺乏统计意义，对植物覆盖率变化的解释需要谨慎，但保存下来的花粉类型证实了地中海常绿森林植被在姆列特岛的主导地位。此外，高比例的非荒野花粉（NAP）表明了某种程度的森林退化，从地中海疏林到退化的灌木丛不等。丰富的木炭也证实了洞穴曾有人类居住。
{"title":"First palynological results from Spila nad Procjepom cave, Mljet island (Croatia)","authors":"K. Bakrač, Olena Sirenko, Dario Hruševar, Ivona Baniček, Vibor Novak, Nataša Kletečki, Ankica Oros Sršen","doi":"10.4154/gc.2024.04","DOIUrl":"https://doi.org/10.4154/gc.2024.04","url":null,"abstract":"This paper presents the first results of palynological research from the Spila nad Procjepom cave, situated in the Mljet National Park, Croatia. The palynological data obtained, enables a partial insight into the local vegetation cover, temporal changes in the vegetation during the accumulation of studied deposits (at ca. 3500 cal years BP), and post-depositional processes that influenced the palynomorph assemblage. Results of palynofacies analysis indicate changes from fluvial (channel deposits), through palustrine to terrestrial environments. Although the interpretation of changes in plant cover, due to the lack of statistical significance, should be taken with caution, preserved pollen types confirm the dominance of the Mediterranean evergreen forest vegetation on Mljet island. Moreover, a high proportion of non-arboreal pollen (NAP) indicates some level of forest degradation, ranging from Mediterranean open forest to degraded maquis. Abundant charcoal additionaly confirms that the cave was inhabited by humans.","PeriodicalId":55108,"journal":{"name":"Geologia Croatica","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140420630","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Up to the present, no terrestrial vertebrate fauna has been published from the pre-Pannonian Miocene of SW Hungary. In 2022 a microvertebrate assemblage was unearthed from a lime mud bed of the Middle Miocene Hidas Formation, in an abandoned coal mining field close to Hidas in the Mecsek Mts. The herpetofauna and the rodent material are described here. Fossil findings point to the Late Badenian MN 7+8 Zone, which, together with the earlier results based on the marine mollusc fauna, narrows the age of the unit to ~13.5–13.3 Ma. The amphibians and reptiles are aquatic, semiaquatic or periaquatic forms. Sedimentary features and the accompanying freshwater gastropod fauna are indicative of a shallow pond or a paludal depositional environment. Crocodylian finds reported earlier from the Hidas Formation indicate a subtropical climate, just before the end of the Miocene warm period in Central Europe. Among the rodents, glirids and flying squirrels as well as Democricetodon and Megacricetodon indicate the presence of humid arboreal vegetation around the site. The rodent taxa are well known from the Middle Miocene faunas of northern Hungary, western Romania and from the Upper Freshwater Molasse of southern Germany and Switzerland. The rodent material does not show characteristics of an insular fauna, e.g. gigantism or endemism. Consequently, although the coeval palaeogeography of the region has been described as an archipelago in the Central Paratethys, with the Mecsek Mts. being one of the islands, the area must have had ecological connections towards the northern and eastern parts of the Pannonian Basin, and the marine areas within the archipelago did not form a barrier against the distribution of microvertebrates. The corridor could have been located towards the NE from the Mecsek Mts., across the elevated basement blocks of central Hungary.
{"title":"Middle Miocene (Late Badenian) microvertebrates from Hidas, SW Hungary","authors":"J. Hír, M. Venczel, Krisztina Sebe","doi":"10.4154/gc.2024.03","DOIUrl":"https://doi.org/10.4154/gc.2024.03","url":null,"abstract":"Up to the present, no terrestrial vertebrate fauna has been published from the pre-Pannonian Miocene of SW Hungary. In 2022 a microvertebrate assemblage was unearthed from a lime mud bed of the Middle Miocene Hidas Formation, in an abandoned coal mining field close to Hidas in the Mecsek Mts. The herpetofauna and the rodent material are described here. Fossil findings point to the Late Badenian MN 7+8 Zone, which, together with the earlier results based on the marine mollusc fauna, narrows the age of the unit to ~13.5–13.3 Ma. The amphibians and reptiles are aquatic, semiaquatic or periaquatic forms. Sedimentary features and the accompanying freshwater gastropod fauna are indicative of a shallow pond or a paludal depositional environment. Crocodylian finds reported earlier from the Hidas Formation indicate a subtropical climate, just before the end of the Miocene warm period in Central Europe. Among the rodents, glirids and flying squirrels as well as Democricetodon and Megacricetodon indicate the presence of humid arboreal vegetation around the site. The rodent taxa are well known from the Middle Miocene faunas of northern Hungary, western Romania and from the Upper Freshwater Molasse of southern Germany and Switzerland. The rodent material does not show characteristics of an insular fauna, e.g. gigantism or endemism. Consequently, although the coeval palaeogeography of the region has been described as an archipelago in the Central Paratethys, with the Mecsek Mts. being one of the islands, the area must have had ecological connections towards the northern and eastern parts of the Pannonian Basin, and the marine areas within the archipelago did not form a barrier against the distribution of microvertebrates. The corridor could have been located towards the NE from the Mecsek Mts., across the elevated basement blocks of central Hungary.","PeriodicalId":55108,"journal":{"name":"Geologia Croatica","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140422412","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The studied rock collapse structure is located on the Liburnian coast (Rijeka Bay, channel zone of the NE Adriatic). The relief of the southern part of this coast, with a length of 6.5 km, is a large escarpment with very steep to vertical slopes reaching heights of 100 m above sea level, as a result of tectonic movements along the Kvarner fault zone. These events probably led to a sudden relaxation of the highly fractured rock mass. The progressive expansion occurred at locations where previously favourably oriented faults and fissures had formed a polygonal rock collapse resembling a rock-slide which is the focus of this study. Another aim of this study is to reconstruct and explain the complex morphological evolution of the studied landslide, from the pre-failure deformations, through the failure itself, to post-failure displacements, as well as possible future instabilities. Recent techniques to survey the instability, location and to analyse the evolution of the rupture surface and its dimensions were combined (Unmanned Aerial Vehicle, Side Scan Sonar and Remotely Operated Vehicles). The estimated total volume of displaced rock mass is 950,000 m3. The lower part of the instability phenomenon was submerged during the Holocene sea level rise. Since then, a large part of the displaced rock mass has been in a stable position, with sporadic rock falls. However, given unfavourable orientation and discontinuity characteristics, as well as unfavourable environmental influences, possible instabilities might also be expected in the future.
{"title":"Large gravitational collapse structure on a rocky coast (Kvarner, NE Adriatic Sea)","authors":"Čedomir Benac, Sanja Dugonjić Jovančević, Dražen Navratil, Andrea Tadić, Lovro Maglić","doi":"10.4154/gc.2023.10","DOIUrl":"https://doi.org/10.4154/gc.2023.10","url":null,"abstract":"The studied rock collapse structure is located on the Liburnian coast (Rijeka Bay, channel zone of the NE Adriatic). The relief of the southern part of this coast, with a length of 6.5 km, is a large escarpment with very steep to vertical slopes reaching heights of 100 m above sea level, as a result of tectonic movements along the Kvarner fault zone. These events probably led to a sudden relaxation of the highly fractured rock mass. The progressive expansion occurred at locations where previously favourably oriented faults and fissures had formed a polygonal rock collapse resembling a rock-slide which is the focus of this study. Another aim of this study is to reconstruct and explain the complex morphological evolution of the studied landslide, from the pre-failure deformations, through the failure itself, to post-failure displacements, as well as possible future instabilities. Recent techniques to survey the instability, location and to analyse the evolution of the rupture surface and its dimensions were combined (Unmanned Aerial Vehicle, Side Scan Sonar and Remotely Operated Vehicles). The estimated total volume of displaced rock mass is 950,000 m3. The lower part of the instability phenomenon was submerged during the Holocene sea level rise. Since then, a large part of the displaced rock mass has been in a stable position, with sporadic rock falls. However, given unfavourable orientation and discontinuity characteristics, as well as unfavourable environmental influences, possible instabilities might also be expected in the future.","PeriodicalId":55108,"journal":{"name":"Geologia Croatica","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136183879","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lidija Galović, Stjepan Husnjak, Ajka Šorša, Jasmina Martinčević Lazar
The aim was to determine possible local differences between the parent materials of recent leoss-derived soils in eastern Croatia (Dalj, Zmajevac). Furthermore, it highlights the existence of chernozem and chernozem-like soils in Croatia and describes their basic physical, chemical and mineral properties. For this purpose, two soil profiles (P-3 and P-6) south of the Dalj settlement and one soil profile (P-10) near the Zmajevac settlement were excavated. The investigation included a detailed pedological analysis, a modal analysis of the heavy and light mineral fraction and a mineralogical analysis of bulk samples (the < 2 mm fraction) and the fraction < 2 μm. By comparing the obtained results with the criteria of the Croatian Soil Classification and the World Reference Base for Soil Resources, the soil profiles P-3 and P-6 can be defined as Chernozem on Loess or Hortic Calcic chernozem (Epiloamic, Endosiltic, Aric, Humic). The systematic unit for profile P-10 was defined as Rendzina according to the Croatian Soil Classification or Calcic Chernozem (Siltic) according to the WRB. Based on the results of the pedological analysis of the soil profile horizons, a gradual degradation of the chernozem was observed as a result of anthropogenic influence, but also due to recent climate change. The degradation is particularly evident in the form of a reduction in organic matter and the relocation of carbonates from the surface to deeper zones. Due to the increasing degree of weathering caused by recent climate changes, some differences in the mineralogical composition of the studied soils were also observed. The progressive degradation of the chernozem due to the effects of recent weathering processes is indicated mainly by the presence of goethite in the fraction < 2 μm as a weathering product of iron minerals (magnetite, pyroxenes…). Although the parent material of all three profiles is loess sediments, the reason why the soil material of profile P-10 has not developed a chernic horizon is the constant contribution of aeolian material and a short period of exposure to pedogenetic processes.
{"title":"Evidence and mineralogical and physico-chemical properties of chernozem and chernozem-like soils in Croatia","authors":"Lidija Galović, Stjepan Husnjak, Ajka Šorša, Jasmina Martinčević Lazar","doi":"10.4154/gc.2023.08","DOIUrl":"https://doi.org/10.4154/gc.2023.08","url":null,"abstract":"The aim was to determine possible local differences between the parent materials of recent leoss-derived soils in eastern Croatia (Dalj, Zmajevac). Furthermore, it highlights the existence of chernozem and chernozem-like soils in Croatia and describes their basic physical, chemical and mineral properties. For this purpose, two soil profiles (P-3 and P-6) south of the Dalj settlement and one soil profile (P-10) near the Zmajevac settlement were excavated. The investigation included a detailed pedological analysis, a modal analysis of the heavy and light mineral fraction and a mineralogical analysis of bulk samples (the < 2 mm fraction) and the fraction < 2 μm. By comparing the obtained results with the criteria of the Croatian Soil Classification and the World Reference Base for Soil Resources, the soil profiles P-3 and P-6 can be defined as Chernozem on Loess or Hortic Calcic chernozem (Epiloamic, Endosiltic, Aric, Humic). The systematic unit for profile P-10 was defined as Rendzina according to the Croatian Soil Classification or Calcic Chernozem (Siltic) according to the WRB. Based on the results of the pedological analysis of the soil profile horizons, a gradual degradation of the chernozem was observed as a result of anthropogenic influence, but also due to recent climate change. The degradation is particularly evident in the form of a reduction in organic matter and the relocation of carbonates from the surface to deeper zones. Due to the increasing degree of weathering caused by recent climate changes, some differences in the mineralogical composition of the studied soils were also observed. The progressive degradation of the chernozem due to the effects of recent weathering processes is indicated mainly by the presence of goethite in the fraction < 2 μm as a weathering product of iron minerals (magnetite, pyroxenes…). Although the parent material of all three profiles is loess sediments, the reason why the soil material of profile P-10 has not developed a chernic horizon is the constant contribution of aeolian material and a short period of exposure to pedogenetic processes.","PeriodicalId":55108,"journal":{"name":"Geologia Croatica","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136183880","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Bojana Đorđević, Hans-Jürgen Gawlick, Nevenka Djerić, Felix Schlagintweit, Miloš Radonjić
Lower Cretaceous (Aptian) shallow-marine limestones with intercalated polymictic conglomerates were investigated with respect to their biostratigraphic age and their microfacies. They are the younger part of the generally carbonate-siliciclastic Lower Cretaceous deep-water (max. few hundred metres) turbiditic sequences (“Paraflysch”) of the so-called East Vardar zone in the Belgrade area. The biostratigraphic age of the limestones was determined by orbitolinid foraminifera: the co-occurrence of Dictyoconus? pachymarginalis SCHROEDER and Mesorbitolina texana (ROEMER) besides various other microfossils suggest a biostratigraphic age of this shallow- marine limestone succession as middle Aptian (Gargasian). Radiolarite components in the conglomerates are Triassic in age and were derived from the obducted Middle Triassic to Middle Jurassic Neo-Tethys ophiolites and/or their ophiolitic mélanges on the wider Adria plate. From both the first precise biostratigraphic age dating as middle Aptian combined with microfacies analysis of these shallow-marine limestones and the component spectrum in the intercalated conglomerates, it can be concluded that the Lower Cretaceous turbiditic “Paraflysch” succession was deposited on the eastern rim of the Dinarides. The results will allow a better comparison of the different Lower Cretaceous sedimentary successions deposited on the eastern margin of the Dinarides.
{"title":"Middle Aptian Orbitolinid limestones in Belgrade (Serbia): microfacies and depositional environment","authors":"Bojana Đorđević, Hans-Jürgen Gawlick, Nevenka Djerić, Felix Schlagintweit, Miloš Radonjić","doi":"10.4154/gc.2023.09","DOIUrl":"https://doi.org/10.4154/gc.2023.09","url":null,"abstract":"Lower Cretaceous (Aptian) shallow-marine limestones with intercalated polymictic conglomerates were investigated with respect to their biostratigraphic age and their microfacies. They are the younger part of the generally carbonate-siliciclastic Lower Cretaceous deep-water (max. few hundred metres) turbiditic sequences (“Paraflysch”) of the so-called East Vardar zone in the Belgrade area. The biostratigraphic age of the limestones was determined by orbitolinid foraminifera: the co-occurrence of Dictyoconus? pachymarginalis SCHROEDER and Mesorbitolina texana (ROEMER) besides various other microfossils suggest a biostratigraphic age of this shallow- marine limestone succession as middle Aptian (Gargasian). Radiolarite components in the conglomerates are Triassic in age and were derived from the obducted Middle Triassic to Middle Jurassic Neo-Tethys ophiolites and/or their ophiolitic mélanges on the wider Adria plate. From both the first precise biostratigraphic age dating as middle Aptian combined with microfacies analysis of these shallow-marine limestones and the component spectrum in the intercalated conglomerates, it can be concluded that the Lower Cretaceous turbiditic “Paraflysch” succession was deposited on the eastern rim of the Dinarides. The results will allow a better comparison of the different Lower Cretaceous sedimentary successions deposited on the eastern margin of the Dinarides.","PeriodicalId":55108,"journal":{"name":"Geologia Croatica","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136183601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Saja Mohammad Abutaha, Janos Geiger, Ferenc Fedor, Sandor Gulyas
Continuous Wavelet Transformation (CWT) was applied to study the small-scale repetitive oscillations of porosity distribution patterns in a 5 m silty-claystone core sample of the Boda Claystone Formation. We handled the fluctuations in voxel porosity averages over unequal depth distributions as signals over uneven time intervals. The strength of wavelet analysis lies in the ability to study the fluctuation of a signal in detail, i.e., the wavelet transforms permit automatic localization of the cyclic attributes' sequences both in time (the depth domain) and according to their frequency (the frequency domain). Thereupon, three main frequency branches (cycles) were discerned: small scale (5, 6.67, and 11 cm), intermediate scale (20, 30 cm), and large scale (66.67 cm). Depending on the CWT coefficients magnitude plot, we were able to detect the developments of porosity oscillation according to the depth variable. Thus, small-scale cycles were seen throughout the core sample., the intermediate-scale cycles were strong in the upper parts of the core sample and dwindled toward greater depths, and the large cycle was predominant in the lower part of the core sample. The cross-correlation of the wavelet coefficients of porosity and rock-forming components allows a detailed study of the inter-dependence of such parameters as their relationship changes over time. The distinct peaks at zero lag indicates that the measured wavelet coefficient series were contemporaneously correlated; their strong positive correlations suggest that both examined series respond similarly and simultaneously to other exogenous factors. The results emphasize that cyclical porosity fluctuations at all scales would concern three main factors; sediment deposition, diagenetic processes, and structural deformation (i.e., convolute laminations).
{"title":"Continuous Wavelet Transformation to Quantify small-scale Cycles of Petrophysical Properties; a New Approach Applied in a Potential Disposal Repository of Nuclear Waste, SW Hungary","authors":"Saja Mohammad Abutaha, Janos Geiger, Ferenc Fedor, Sandor Gulyas","doi":"10.4154/gc.2023.11","DOIUrl":"https://doi.org/10.4154/gc.2023.11","url":null,"abstract":"Continuous Wavelet Transformation (CWT) was applied to study the small-scale repetitive oscillations of porosity distribution patterns in a 5 m silty-claystone core sample of the Boda Claystone Formation. We handled the fluctuations in voxel porosity averages over unequal depth distributions as signals over uneven time intervals. The strength of wavelet analysis lies in the ability to study the fluctuation of a signal in detail, i.e., the wavelet transforms permit automatic localization of the cyclic attributes' sequences both in time (the depth domain) and according to their frequency (the frequency domain). Thereupon, three main frequency branches (cycles) were discerned: small scale (5, 6.67, and 11 cm), intermediate scale (20, 30 cm), and large scale (66.67 cm). Depending on the CWT coefficients magnitude plot, we were able to detect the developments of porosity oscillation according to the depth variable. Thus, small-scale cycles were seen throughout the core sample., the intermediate-scale cycles were strong in the upper parts of the core sample and dwindled toward greater depths, and the large cycle was predominant in the lower part of the core sample. The cross-correlation of the wavelet coefficients of porosity and rock-forming components allows a detailed study of the inter-dependence of such parameters as their relationship changes over time. The distinct peaks at zero lag indicates that the measured wavelet coefficient series were contemporaneously correlated; their strong positive correlations suggest that both examined series respond similarly and simultaneously to other exogenous factors. The results emphasize that cyclical porosity fluctuations at all scales would concern three main factors; sediment deposition, diagenetic processes, and structural deformation (i.e., convolute laminations).","PeriodicalId":55108,"journal":{"name":"Geologia Croatica","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136183878","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Šorša, G. Durn, A. Grizelj, J. Halamić, Lucija Prša Gazilj
Within the framework of the pan-European project “URban GEochemistry (URGE) in Europe – Soil, children, health”, pedological and geochemical investigations of the soils of the city of Sisak and its adjacent surroundings were carried out, and three urban and two rural soil profiles were examined. The mineralogical composition and concentration of selected potentially toxic elements (PTEs) Cr, Cu, Ni, Pb and Zn in the soil were determined. The Community Reference Bureau of Reference (BCR) sequential extraction procedure (SEP) of these PTEs was undertaken and the potential risk to human health and the environment was assessed. The concentrations of Cr and Ni are generally similar in urban and rural soil profiles, while the concentrations of Cu, Pb and Zn in soil horizons/layers are higher in urban profiles. The extracted fractions of PTEs gave the following general distribution: in urban soil profiles residual (RES) > reducible (ORG) or oxidisable (FEMN) > exchangeable (CARB), except for Cu where ORG > RES > FEMN > CARB, while in rural soil profiles RES > FEMN or ORG > CARB, except for Pb where FEMN > RES or ORG > CARB. The differences between soils in urban and rural profiles depend mainly on the historical land use, i.e. on the duration and intensity of anthropogenic influences on the soil and, to a lesser extent, on the geogenic origin of the parent material and the pedogenic processes. The studied elements in the urban soil profiles are predominantly of anthropogenic origin, indicating a possible influence of the ancient settlements of Segestica and Siscia and of heavy industry in the 20th century. The anthropogenic influences on the rural profiles are low and geogenic influences dominate. Risks to the environment were assessed in the soil profiles based on PTE concentrations in the CARB fraction and the sum of the CARB, ORG and FEMN fractions from BCR SEP. All calculated risks to human health and the environment were rated as no-risk, very low risk and low risk.
{"title":"Comparison of urban and rural soils based on speciation of heavy metals by BCR sequential extraction procedure: A case study in the historical and industrial city of Sisak, Croatia","authors":"A. Šorša, G. Durn, A. Grizelj, J. Halamić, Lucija Prša Gazilj","doi":"10.4154/gc.2023.06","DOIUrl":"https://doi.org/10.4154/gc.2023.06","url":null,"abstract":"Within the framework of the pan-European project “URban GEochemistry (URGE) in Europe – Soil, children, health”, pedological and geochemical investigations of the soils of the city of Sisak and its adjacent surroundings were carried out, and three urban and two rural soil profiles were examined. The mineralogical composition and concentration of selected potentially toxic elements (PTEs) Cr, Cu, Ni, Pb and Zn in the soil were determined. The Community Reference Bureau of Reference (BCR) sequential extraction procedure (SEP) of these PTEs was undertaken and the potential risk to human health and the environment was assessed. The concentrations of Cr and Ni are generally similar in urban and rural soil profiles, while the concentrations of Cu, Pb and Zn in soil horizons/layers are higher in urban profiles. The extracted fractions of PTEs gave the following general distribution: in urban soil profiles residual (RES) > reducible (ORG) or oxidisable (FEMN) > exchangeable (CARB), except for Cu where ORG > RES > FEMN > CARB, while in rural soil profiles RES > FEMN or ORG > CARB, except for Pb where FEMN > RES or ORG > CARB. The differences between soils in urban and rural profiles depend mainly on the historical land use, i.e. on the duration and intensity of anthropogenic influences on the soil and, to a lesser extent, on the geogenic origin of the parent material and the pedogenic processes. The studied elements in the urban soil profiles are predominantly of anthropogenic origin, indicating a possible influence of the ancient settlements of Segestica and Siscia and of heavy industry in the 20th century. The anthropogenic influences on the rural profiles are low and geogenic influences dominate. Risks to the environment were assessed in the soil profiles based on PTE concentrations in the CARB fraction and the sum of the CARB, ORG and FEMN fractions from BCR SEP. All calculated risks to human health and the environment were rated as no-risk, very low risk and low risk.","PeriodicalId":55108,"journal":{"name":"Geologia Croatica","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2023-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46235198","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
T. Lukić, M. Radaković, Rastko S. Marković, W. Thompson, Tanja Micić Ponjiger, B. Basarin, N. Tomić, V. Tomović, J. Popov Raljić, M. Gavrilov, A. Valjarević, G. Sipos, D. Filipović, C. Morar, S. Marković
n this study we present an in-depth description of the colorimetric values for the lowest section of the Dukatar Loess Palaeosol Sequence (LPS) pedocomplex S5. Formed during the Marine Isotope Stage (MIS) 13-15, it represents the oldest pedocomplex exposed at the base of the Titel loess plateau (TLP), near the confluence of the Tisa and Danube rivers in Vojvodina (northern Serbia). The results of low-field magnetic susceptibility measurements (χlf) were compared to colour properties (obtained by conventional methods as well as instrumental measuring) and quantified Soil Development Indices (SDI). Of these measurements we found that the Redness Index (RI1) yielded the most useful results, as this index appears most sensitive to lithological changes and soil development intensity. It was also observed that a high level of correlation existed between χlf, and a* chromaticity. The initial results of this study highlight the utility of colorimetric methods as an interdisciplinary tool when evaluating the presence of ferromagnetics, and the application of rock magnetism to the Middle and Upper Pleistocene LPS of the Middle Danube Basin. The presented approach can be used to observe the evolution of climatic and ecological conditions in the given study area, and for establishing correlations between sites extending over the Eurasian LPS provinces.
{"title":"Initial results of the colorimetric indices of the oldest exposed pedocomplex (Titel loess plateau, Serbia)","authors":"T. Lukić, M. Radaković, Rastko S. Marković, W. Thompson, Tanja Micić Ponjiger, B. Basarin, N. Tomić, V. Tomović, J. Popov Raljić, M. Gavrilov, A. Valjarević, G. Sipos, D. Filipović, C. Morar, S. Marković","doi":"10.4154/gc.2023.05","DOIUrl":"https://doi.org/10.4154/gc.2023.05","url":null,"abstract":"n this study we present an in-depth description of the colorimetric values for the lowest section of the Dukatar Loess Palaeosol Sequence (LPS) pedocomplex S5. Formed during the Marine Isotope Stage (MIS) 13-15, it represents the oldest pedocomplex exposed at the base of the Titel loess plateau (TLP), near the confluence of the Tisa and Danube rivers in Vojvodina (northern Serbia). The results of low-field magnetic susceptibility measurements (χlf) were compared to colour properties (obtained by conventional methods as well as instrumental measuring) and quantified Soil Development Indices (SDI). Of these measurements we found that the Redness Index (RI1) yielded the most useful results, as this index appears most sensitive to lithological changes and soil development intensity. It was also observed that a high level of correlation existed between χlf, and a* chromaticity. The initial results of this study highlight the utility of colorimetric methods as an interdisciplinary tool when evaluating the presence of ferromagnetics, and the application of rock magnetism to the Middle and Upper Pleistocene LPS of the Middle Danube Basin. The presented approach can be used to observe the evolution of climatic and ecological conditions in the given study area, and for establishing correlations between sites extending over the Eurasian LPS provinces.","PeriodicalId":55108,"journal":{"name":"Geologia Croatica","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2023-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47259909","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
京公网安备 11010802042870号
京ICP备2023020795号-1
扫码关注我们
求助内容：
应助结果提醒方式：