Pub Date : 2023-11-06DOI: 10.24425/cpe.2022.142296
{"title":"142296","authors":"","doi":"10.24425/cpe.2022.142296","DOIUrl":"https://doi.org/10.24425/cpe.2022.142296","url":null,"abstract":"","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135635068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/cpe.2020.132536
This paper aims to show the effect of activation method of tyre pyrolysis char (TPC) on adsorption of bisphenol A (BPA) from aqueous solutions. The TPC was produced from end-of-life-tyres (ELT) feedstock in a pilot plant at 773 K. Activation was accomplished using two classical methods: physical activation with CO 2 and chemical activation with KOH. The two produced adsorbents had pores ranging from micro-to macropores. Distinct differences in the BET surface areas and pore volumes between the adsorbents were displayed showing better performance of the chemically activated adsorbent for adsorption of BPA from water. The results of the kinetic studies showed that the adsorption of BPA followed pseudo-second-order kinetic model. The Freundlich, Langmuir, Langmuir–Freundlich and Redlich–Peterson isotherm equations were used for description of the adsorption data. The Langmuir–Freundlich isotherm model best fits the experimental data for the BPA adsorption on both adsorbents. The Langmuir–Freundlich monolayer adsorption capacity, q mLF , obtained for the CO 2 -activated tyre pyrolysis char (AP-CO 2 ) and KOH-activated tyre pyrolysis char (AP-KOH) were 0.473 and 0.969 mmol g (cid:0) 1 , respectively.
{"title":"Adsorption of bisphenol a from aqueous solutions by activated tyre pyrolysis char – Effect of physical and chemical activation","authors":"","doi":"10.24425/cpe.2020.132536","DOIUrl":"https://doi.org/10.24425/cpe.2020.132536","url":null,"abstract":"This paper aims to show the effect of activation method of tyre pyrolysis char (TPC) on adsorption of bisphenol A (BPA) from aqueous solutions. The TPC was produced from end-of-life-tyres (ELT) feedstock in a pilot plant at 773 K. Activation was accomplished using two classical methods: physical activation with CO 2 and chemical activation with KOH. The two produced adsorbents had pores ranging from micro-to macropores. Distinct differences in the BET surface areas and pore volumes between the adsorbents were displayed showing better performance of the chemically activated adsorbent for adsorption of BPA from water. The results of the kinetic studies showed that the adsorption of BPA followed pseudo-second-order kinetic model. The Freundlich, Langmuir, Langmuir–Freundlich and Redlich–Peterson isotherm equations were used for description of the adsorption data. The Langmuir–Freundlich isotherm model best fits the experimental data for the BPA adsorption on both adsorbents. The Langmuir–Freundlich monolayer adsorption capacity, q mLF , obtained for the CO 2 -activated tyre pyrolysis char (AP-CO 2 ) and KOH-activated tyre pyrolysis char (AP-KOH) were 0.473 and 0.969 mmol g (cid:0) 1 , respectively.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"378 2","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135636151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/cpe.2019.126118
Katarzyna Samborska, Alicja Barańska, Daria Bodel, Aleksandra Jedlińska
Linden honey ultrafiltration (15 kDa MWCO ceramic membrane) was performed as honey solution pre-treatment before spray drying. Feed and retentate solutions with the addition of maltodextrin as a carrier were spray dried. Drying yield and physical properties of powders were studied (after drying and after 12 weeks of storage). During ultrafiltration it was possible to remove some amount of sugars responsible for honey low glass transition temperature, while keeping protein compounds. Yet, it did not have a significant impact on the drying performance and improvement of powder physical properties immediately after drying and after storage. However, the possibility to remove sugars from honey solution by ultrafiltration can be an encouragement for further research.
{"title":"Investigation on the possibility to enhancing honey spray drying process and powders properties by ultrafiltration pre-treatment","authors":"Katarzyna Samborska, Alicja Barańska, Daria Bodel, Aleksandra Jedlińska","doi":"10.24425/cpe.2019.126118","DOIUrl":"https://doi.org/10.24425/cpe.2019.126118","url":null,"abstract":"Linden honey ultrafiltration (15 kDa MWCO ceramic membrane) was performed as honey solution pre-treatment before spray drying. Feed and retentate solutions with the addition of maltodextrin as a carrier were spray dried. Drying yield and physical properties of powders were studied (after drying and after 12 weeks of storage). During ultrafiltration it was possible to remove some amount of sugars responsible for honey low glass transition temperature, while keeping protein compounds. Yet, it did not have a significant impact on the drying performance and improvement of powder physical properties immediately after drying and after storage. However, the possibility to remove sugars from honey solution by ultrafiltration can be an encouragement for further research.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"375 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135636157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/cpe.2021.138920
The non-stationary problem of temperature distribution in a circular cylindrical channel of infinite length filled with a homogeneous biomass material moving with a constant velocity in the axial direction was investigated. The heat source was a shaftless helical screw (or auger), which was heated with an electric current due to the Joule–Lenz effect and rotated uniformly around the axis of symmetry of the channel. Similar problems arise in the thermal processing of biomaterials using screw conveyor in pyrolysis and mass sterilization and pasteurization of food products. The problem is solved using the expansion of given and required functions in Fourier series over angular coordinate and integral Fourier and Laplace transforms over axial coordinate and time, respectively. As a result, the temperature field is obtained as the sum of two components, one of which, global, is proportional to time, and the other, which forms the microstructure of the temperature profile, is given by Fourier–Bessel series. The coefficients of the series are determined by the integrals calculated using the Romberg method. Based on the numerical calculations, the analysis of the space-time microstructure of the temperature field in the canal was performed. A significant dependence of the features of this microstructure on the geometric, kinematic and thermodynamic characteristics of the filling biomass and the screw was revealed.
{"title":"Analysis of non-stationary temperature field generated by a shaftless screw conveyor heated by Joule–Lenz effect","authors":"","doi":"10.24425/cpe.2021.138920","DOIUrl":"https://doi.org/10.24425/cpe.2021.138920","url":null,"abstract":"The non-stationary problem of temperature distribution in a circular cylindrical channel of infinite length filled with a homogeneous biomass material moving with a constant velocity in the axial direction was investigated. The heat source was a shaftless helical screw (or auger), which was heated with an electric current due to the Joule–Lenz effect and rotated uniformly around the axis of symmetry of the channel. Similar problems arise in the thermal processing of biomaterials using screw conveyor in pyrolysis and mass sterilization and pasteurization of food products. The problem is solved using the expansion of given and required functions in Fourier series over angular coordinate and integral Fourier and Laplace transforms over axial coordinate and time, respectively. As a result, the temperature field is obtained as the sum of two components, one of which, global, is proportional to time, and the other, which forms the microstructure of the temperature profile, is given by Fourier–Bessel series. The coefficients of the series are determined by the integrals calculated using the Romberg method. Based on the numerical calculations, the analysis of the space-time microstructure of the temperature field in the canal was performed. A significant dependence of the features of this microstructure on the geometric, kinematic and thermodynamic characteristics of the filling biomass and the screw was revealed.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"374 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135636160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/cpe.2018.124975
{"title":"Acknowledgments to Reviewers 2018","authors":"","doi":"10.24425/cpe.2018.124975","DOIUrl":"https://doi.org/10.24425/cpe.2018.124975","url":null,"abstract":"","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"371 2","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135636166","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/cpe.2019.126115
The aim of the paper was to develop determination methods of sedimentation characteristics using PIV image anemometry and suspension image analysis. Two methods of the investigation of sedimentation process based on visualization techniques were developed. In the first one, using PIV method, vector fields of the velocity of settling particles are determined and then average particle velocities are calculated to establish the so called sedimentation dynamics curve. In the second one, the methods of suspension image analysis are utilized to determine the positions of the upper discontinuity and to establish the sedimentation curve. Laboratory research on the sedimentation of agalit particles suspended in glycerine was conducted (using PIV method). Additionally, industrial research on the sedimentation of water-absorbing granular material used after the first carbonation (carbonation I) was conducted in a sugar factory (using the second method). The research consisted of photographic registration of images of the settling suspension by means of the time-lapse photography technique. A laboratory study was conducted for four values of the volume concentration of agalit particles in glycerine (0.5; 1.0; 1.5 and 2.0 vol%). The research methodology, the scope of the conducted measurements and sample research results together with conclusions are presented in this paper.
{"title":"Investigation of the sedimentation process using flow visualization methods","authors":"","doi":"10.24425/cpe.2019.126115","DOIUrl":"https://doi.org/10.24425/cpe.2019.126115","url":null,"abstract":"The aim of the paper was to develop determination methods of sedimentation characteristics using PIV image anemometry and suspension image analysis. Two methods of the investigation of sedimentation process based on visualization techniques were developed. In the first one, using PIV method, vector fields of the velocity of settling particles are determined and then average particle velocities are calculated to establish the so called sedimentation dynamics curve. In the second one, the methods of suspension image analysis are utilized to determine the positions of the upper discontinuity and to establish the sedimentation curve. Laboratory research on the sedimentation of agalit particles suspended in glycerine was conducted (using PIV method). Additionally, industrial research on the sedimentation of water-absorbing granular material used after the first carbonation (carbonation I) was conducted in a sugar factory (using the second method). The research consisted of photographic registration of images of the settling suspension by means of the time-lapse photography technique. A laboratory study was conducted for four values of the volume concentration of agalit particles in glycerine (0.5; 1.0; 1.5 and 2.0 vol%). The research methodology, the scope of the conducted measurements and sample research results together with conclusions are presented in this paper.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"311 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135679077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/cpe.2021.138933
This perspective paper focuses on the changes in teaching chemical engineering in Europe triggered by new challenges and megatrends observed in the chemical and related industries. Among the new teaching areas to address those challenges and megatrends, process intensification, digitalization and advanced materials are expected to play the most important role and are discussed in more detail. The discussion on incorporation of those new areas in the university curricula is illustrated with a comparison of educational approaches to the chemical engineering teaching at two universities – Delft University of Technology and Warsaw University of Technology. The aim of this paper is to focus the attention of university teachers and potential decision makers on the most important challenges for contemporary teaching of chemical engineering.
{"title":"Teaching chemical engineering in Europe – developments, dilemmas and practical examples","authors":"","doi":"10.24425/cpe.2021.138933","DOIUrl":"https://doi.org/10.24425/cpe.2021.138933","url":null,"abstract":"This perspective paper focuses on the changes in teaching chemical engineering in Europe triggered by new challenges and megatrends observed in the chemical and related industries. Among the new teaching areas to address those challenges and megatrends, process intensification, digitalization and advanced materials are expected to play the most important role and are discussed in more detail. The discussion on incorporation of those new areas in the university curricula is illustrated with a comparison of educational approaches to the chemical engineering teaching at two universities – Delft University of Technology and Warsaw University of Technology. The aim of this paper is to focus the attention of university teachers and potential decision makers on the most important challenges for contemporary teaching of chemical engineering.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"156 2","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135679225","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/cpe.2022.142295
{"title":"142295","authors":"","doi":"10.24425/cpe.2022.142295","DOIUrl":"https://doi.org/10.24425/cpe.2022.142295","url":null,"abstract":"","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"154 2","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135679230","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/cpe.2019.130209
Arkadiusz Białek, Katarzyna Skrzypczyńska, Krzysztof Kuśmierek, Artur Świątkowski
Carbon paste electrode (CPE) was modified with F-300 commercial activated carbon or Norit SX-2 powdered activated carbon. CPEs were prepared for detection of 2,4-dichlorophenoxyacetic acid (2,4-D), 2,6-dichlorophenoxyacetic acid (2,6-D) and 2,4,6-trichlorophenoxyacetic acid (2,4,6-T). The electrochemical behavior of these materials was investigated employing cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The modifier was found to enhance the electroactive surface area and the peak current in comparison to the bare (unmodified) carbon paste electrode. The intensity of the signal increased with the increase in adsorption ability of the modifiers. Compared to the unmodified electrode, all the new paste electrodes showed a much greater sensitivity for detection of chlorinated phenoxyacetic acids in water samples.
{"title":"Sensitivity change of the modified carbon paste electrodes for detection of chlorinated phenoxyacetic acids","authors":"Arkadiusz Białek, Katarzyna Skrzypczyńska, Krzysztof Kuśmierek, Artur Świątkowski","doi":"10.24425/cpe.2019.130209","DOIUrl":"https://doi.org/10.24425/cpe.2019.130209","url":null,"abstract":"Carbon paste electrode (CPE) was modified with F-300 commercial activated carbon or Norit SX-2 powdered activated carbon. CPEs were prepared for detection of 2,4-dichlorophenoxyacetic acid (2,4-D), 2,6-dichlorophenoxyacetic acid (2,6-D) and 2,4,6-trichlorophenoxyacetic acid (2,4,6-T). The electrochemical behavior of these materials was investigated employing cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The modifier was found to enhance the electroactive surface area and the peak current in comparison to the bare (unmodified) carbon paste electrode. The intensity of the signal increased with the increase in adsorption ability of the modifiers. Compared to the unmodified electrode, all the new paste electrodes showed a much greater sensitivity for detection of chlorinated phenoxyacetic acids in water samples.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"206 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135679710","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/cpe.2021.138928
This paper presents the results of investigations into dry methane reforming (DMR). The process was aimed at obtaining synthesis gas required for the production of dimethyl ether (DME). The effect of temperature, pressure and inlet gas composition on the process was determined in the experimental part of this work. The tests were carried out in a laboratory tubular reactor over a Ni/CaO–Al 2 O 3 catalyst. The obtained experimental results were used to verify literature kinetic data and to develop a mathematical model of the DMR process.
{"title":"Modelling of methane dry reforming over Ni/CaO–Al2O3 catalyst","authors":"","doi":"10.24425/cpe.2021.138928","DOIUrl":"https://doi.org/10.24425/cpe.2021.138928","url":null,"abstract":"This paper presents the results of investigations into dry methane reforming (DMR). The process was aimed at obtaining synthesis gas required for the production of dimethyl ether (DME). The effect of temperature, pressure and inlet gas composition on the process was determined in the experimental part of this work. The tests were carried out in a laboratory tubular reactor over a Ni/CaO–Al 2 O 3 catalyst. The obtained experimental results were used to verify literature kinetic data and to develop a mathematical model of the DMR process.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"199 2‐3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135679726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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