Pub Date : 2023-11-06DOI: 10.24425/cpe.2021.138924
{"title":"Jerzy Bałdyga – in memory","authors":"","doi":"10.24425/cpe.2021.138924","DOIUrl":"https://doi.org/10.24425/cpe.2021.138924","url":null,"abstract":"","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"328 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135679050","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/cpe.2021.138923
{"title":"Experimental and numerical investigation of axial and tangential forces in a stirred tank with yield-stress fluids","authors":"","doi":"10.24425/cpe.2021.138923","DOIUrl":"https://doi.org/10.24425/cpe.2021.138923","url":null,"abstract":"","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"34 5","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135679633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/cpe.2021.138938
The use of CaO-based adsorbents has a high potential to capture CO 2 from various systems due to its high reactivity with CO 2 , high capacity, and low cost of naturally derived CaO. The application of CaO-based sorbents to remove carbon dioxide is based on a reversible reaction between CaO and CO 2 . However, multiple carbonation/calcination cycles lead to a rapid reduction in the sorption capacity of natural CaO, and therefore efforts are made to reduce this disadvantage by doping, regenerating, or producing synthetic CaO with stable sorption properties. In this review, the synthesis methods used to obtain CaO-based sorbents were collected, and the latest research on improving their sorption properties was presented. The most commonly used models to describe the CO 2 sorption kinetics on CaO-based sorbents were also introduced. The methods of sorbent regeneration and their effectiveness were summarized. In the last part of this review, the current state of advancement of work on the larger scale, possible problems, and opportunities during scale-up of the calcium looping process were presented. Concluding (i) the presented methods of adsorbent synthesis allow for the production of doped CaO adsorbents on a laboratory scale, characterized by high CO 2 capture efficiency and good cyclic stability, (ii) the most commonly used in practice models describing CO 2 chemisorption are empirical models and the shrinking core model, (iii) the use of sorbent regeneration allows for a significant improvement in sorption capacity, (iv) the scale-up of both the production of new CaO adsorbents and the CO 2 capture technology with their use requires further development
{"title":"CaO-based high temperature CO2 sorbents – Literature review","authors":"","doi":"10.24425/cpe.2021.138938","DOIUrl":"https://doi.org/10.24425/cpe.2021.138938","url":null,"abstract":"The use of CaO-based adsorbents has a high potential to capture CO 2 from various systems due to its high reactivity with CO 2 , high capacity, and low cost of naturally derived CaO. The application of CaO-based sorbents to remove carbon dioxide is based on a reversible reaction between CaO and CO 2 . However, multiple carbonation/calcination cycles lead to a rapid reduction in the sorption capacity of natural CaO, and therefore efforts are made to reduce this disadvantage by doping, regenerating, or producing synthetic CaO with stable sorption properties. In this review, the synthesis methods used to obtain CaO-based sorbents were collected, and the latest research on improving their sorption properties was presented. The most commonly used models to describe the CO 2 sorption kinetics on CaO-based sorbents were also introduced. The methods of sorbent regeneration and their effectiveness were summarized. In the last part of this review, the current state of advancement of work on the larger scale, possible problems, and opportunities during scale-up of the calcium looping process were presented. Concluding (i) the presented methods of adsorbent synthesis allow for the production of doped CaO adsorbents on a laboratory scale, characterized by high CO 2 capture efficiency and good cyclic stability, (ii) the most commonly used in practice models describing CO 2 chemisorption are empirical models and the shrinking core model, (iii) the use of sorbent regeneration allows for a significant improvement in sorption capacity, (iv) the scale-up of both the production of new CaO adsorbents and the CO 2 capture technology with their use requires further development","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"234 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135679899","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/cpe.2019.126114
F. Mikołajczyk, K. Kamiński
It was determined that RuCl2(PPh3)3 obtained with a modified method described by Shaw’s group (Shaw et al., 2007) had the best catalytic properties in the reaction performed under conditions described in Liang Wang’s publication (Wang et al., 2014). It was also determined that for concentration ratio of substrate to RuCl2(PPh3)3 amounting to 250:1 the conversion rate was much higher than that of the reaction performed with a double dose of the catalyst. Results of experiments also show that samples of the post-reaction solution should be analyzed right after the reaction, because even if they are stored in low temperature the amount of product can change up to 3–5% compared to the base sample and this change is not predictable.
在Wang Liang发表的文章(Wang et al.， 2014)所描述的条件下进行的反应中，通过Shaw 's group (Shaw et al.， 2007)描述的改进方法获得的RuCl2(PPh3)3具有最佳的催化性能。实验还发现，当底物与RuCl2(PPh3)3的浓度比为250:1时，转化率远高于催化剂用量为两倍时的转化率。实验结果还表明，反应后溶液的样品应在反应后立即进行分析，因为即使将其保存在低温下，与基础样品相比，产物的量也可能变化3-5%，这种变化是不可预测的。
{"title":"A study of ruthenium-based catalysts used in homogeneous transfer hydrogenation of acetophenone","authors":"F. Mikołajczyk, K. Kamiński","doi":"10.24425/cpe.2019.126114","DOIUrl":"https://doi.org/10.24425/cpe.2019.126114","url":null,"abstract":"It was determined that RuCl2(PPh3)3 obtained with a modified method described by Shaw’s group (Shaw et al., 2007) had the best catalytic properties in the reaction performed under conditions described in Liang Wang’s publication (Wang et al., 2014). It was also determined that for concentration ratio of substrate to RuCl2(PPh3)3 amounting to 250:1 the conversion rate was much higher than that of the reaction performed with a double dose of the catalyst. Results of experiments also show that samples of the post-reaction solution should be analyzed right after the reaction, because even if they are stored in low temperature the amount of product can change up to 3–5% compared to the base sample and this change is not predictable.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"1 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68947056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/CPE.2020.132532
S. Głowacki, M. Jaros, M. Sojak, Weronika Tulej, Andrzej Bryś, Monika Witek
The work presents the process of drying wood biomass after pre-treatment involving either debarking or crushing. The biomass used for research came from a robinia species wood. The material was dried in free-convection, at the drying medium temperatures of 40, 50, 60, 70 and 80 ◦ C, respectively. Pre-treatment proved to have a significant impact on the drying rate, including the time required to reach moisture content of 10%, essential to start further treatment of biomass for power industry purposes. It was found that debarked samples of robinia lost water more quickly than the crushed ones. Samples that did not undergo pre-treatment took the longest time to dry.
{"title":"The impact of mechanical pre-treatment of wood biomasson drying rate","authors":"S. Głowacki, M. Jaros, M. Sojak, Weronika Tulej, Andrzej Bryś, Monika Witek","doi":"10.24425/CPE.2020.132532","DOIUrl":"https://doi.org/10.24425/CPE.2020.132532","url":null,"abstract":"The work presents the process of drying wood biomass after pre-treatment involving either debarking or crushing. The biomass used for research came from a robinia species wood. The material was dried in free-convection, at the drying medium temperatures of 40, 50, 60, 70 and 80 ◦ C, respectively. Pre-treatment proved to have a significant impact on the drying rate, including the time required to reach moisture content of 10%, essential to start further treatment of biomass for power industry purposes. It was found that debarked samples of robinia lost water more quickly than the crushed ones. Samples that did not undergo pre-treatment took the longest time to dry.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"41 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68947730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/cpe.2020.136012
The study aimed to produce nanoand microfibrous materials from polyurethane (ChronoFlex®C75A/ C75D in 1,1,1,3,3,3–hexafluoro–2–propanol) by solution blow spinning. Experiments were carried out in order to determine the impact of solution blow spinning parameters on fibre diameter and quality of produced materials. The following properties of produced fibre scaffolds were investigated: fibre size, porosity and pore size, wettability, and mechanical properties. The results confirmed that produced nanoand microfibrous materials could be potentially used as scaffolds in three-dimensional cell and tissue cultures.
{"title":"Properties of polyurethane fibrous materials produced by solution blow spinning","authors":"","doi":"10.24425/cpe.2020.136012","DOIUrl":"https://doi.org/10.24425/cpe.2020.136012","url":null,"abstract":"The study aimed to produce nanoand microfibrous materials from polyurethane (ChronoFlex®C75A/ C75D in 1,1,1,3,3,3–hexafluoro–2–propanol) by solution blow spinning. Experiments were carried out in order to determine the impact of solution blow spinning parameters on fibre diameter and quality of produced materials. The following properties of produced fibre scaffolds were investigated: fibre size, porosity and pore size, wettability, and mechanical properties. The results confirmed that produced nanoand microfibrous materials could be potentially used as scaffolds in three-dimensional cell and tissue cultures.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"19 2","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135634858","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/cpe.2021.138929
The works presents the application of mass/volume balances of liquid drug converted into the aerosol during atomization in medical nebulizers. The amount of liquid that can be delivered to the respiratory system during inhalation is reduced compared to the nominal dose not only because of drug losses both in the device (the residual volume, RV ) and outside the nebulizer (in the mouthpiece, mask, or tubings), but also to the limitations of the patient (periodic flow with limited capacity). The paper should help to understand the complexity of aerosol therapy widely used in asthma, COPD and other pulmonary diseases
{"title":"Mass and volume balances of nebulization processes for the determination of the expected dose of liquid medicines delivered by inhalation","authors":"","doi":"10.24425/cpe.2021.138929","DOIUrl":"https://doi.org/10.24425/cpe.2021.138929","url":null,"abstract":"The works presents the application of mass/volume balances of liquid drug converted into the aerosol during atomization in medical nebulizers. The amount of liquid that can be delivered to the respiratory system during inhalation is reduced compared to the nominal dose not only because of drug losses both in the device (the residual volume, RV ) and outside the nebulizer (in the mouthpiece, mask, or tubings), but also to the limitations of the patient (periodic flow with limited capacity). The paper should help to understand the complexity of aerosol therapy widely used in asthma, COPD and other pulmonary diseases","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"345 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135635896","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/cpe.2021.137336
The paper presents different approaches to the proper and accurate production and modelling (multi-phase reaction) of CaCO 3 formation in the most popular, different types of reactors, i.e. continuous reactor (STR – stirred tank reactors, MSMPR – mixed suspension, mixed product removal; tube reactor), a bubble column reactor and a thin film reactor. Many different methods of calcium carbonate production and their effect on the various characteristics of the product have been presented and discussed. One of the most important, from the point of view of practical applications, is the morphology and size of the produced particles as well as their agglomerates and size distribution. The size of the obtained CaCO 3 particles and their agglomerates can vary from nanometers to micrometers. It depends on many factors but the most important are the conditions calcium carbonate precipitation and then stored. The experimental research was strongly aided by theoretical considerations on the correct description of the process of calcium carbonate precipitation. More than once, the correct modelling of a specific process contributed to the explanation of the phenomena observed during the experiment (i.e. formation of polyforms, intermediate products, etc.). Moreover, different methods and approaches to the accurate description of crystallization processes as well as main CFD problems has been widely reviewed. It can be used as a basic material to formulation and implementation of new, accurate models describing not only multiphase crystallization processes but also any processes taking place in different chemical reactors.
{"title":"Production and formation modelling of CaCO3 in multiphase reactions – A review","authors":"","doi":"10.24425/cpe.2021.137336","DOIUrl":"https://doi.org/10.24425/cpe.2021.137336","url":null,"abstract":"The paper presents different approaches to the proper and accurate production and modelling (multi-phase reaction) of CaCO 3 formation in the most popular, different types of reactors, i.e. continuous reactor (STR – stirred tank reactors, MSMPR – mixed suspension, mixed product removal; tube reactor), a bubble column reactor and a thin film reactor. Many different methods of calcium carbonate production and their effect on the various characteristics of the product have been presented and discussed. One of the most important, from the point of view of practical applications, is the morphology and size of the produced particles as well as their agglomerates and size distribution. The size of the obtained CaCO 3 particles and their agglomerates can vary from nanometers to micrometers. It depends on many factors but the most important are the conditions calcium carbonate precipitation and then stored. The experimental research was strongly aided by theoretical considerations on the correct description of the process of calcium carbonate precipitation. More than once, the correct modelling of a specific process contributed to the explanation of the phenomena observed during the experiment (i.e. formation of polyforms, intermediate products, etc.). Moreover, different methods and approaches to the accurate description of crystallization processes as well as main CFD problems has been widely reviewed. It can be used as a basic material to formulation and implementation of new, accurate models describing not only multiphase crystallization processes but also any processes taking place in different chemical reactors.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"258 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135678734","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/CPE.2019.126109
K. Wierzchowski, I. Grabowska, M. Pilarek
Typically applied static (i.e. non-agitated) cultures do not provide sufficient conditions for efficient propagation of suspended non-adherent cells, in general. Feasibility of small-scale wave-type agitated single-use bioreactors for gentle agitation underlies applicability of such systems for scaling-up of fragile biomass of animal cells. The basic aim of the study was to compare the results of non-adherent HL-60 cell propagation performed referentially as the batch culture in typical static (i.e. non-agitated) disposable culture flasks (50 cm3 of culture medium) and in ReadyToProcess WAVETM25 bioreactor system (GE Healthcare) equipped with disposable culture bag (300 cm3 of culture medium) subjected to continuous wave-type agitation. The density and viability of HL-60 cells were significantly higher for the bioprocess subjected to wave-type agitation, than in the reference static culture. The values of the specific rate of glucose consumption per cell (rglc/cell) exhibited by HL-60 cells maintained in the system with continuous wave-type agitation was significantly lower (i.e. up to more than 42%) than the values noted for the static culture, for exactly the same time-points of two compared cultures. The results of the studies undoubtedly and comprehensively confirmed the applicability of the studied disposable bioreactor with wave-induced agitation as the right platform for proceeding the propagation of nonadherent HL-60 cells and for providing the culture conditions required by HL-60 cells for sustainable metabolism.
{"title":"Propagation of non-adherent HL-60 cells in batch cultures maintained in staticand wave-type agitated systems","authors":"K. Wierzchowski, I. Grabowska, M. Pilarek","doi":"10.24425/CPE.2019.126109","DOIUrl":"https://doi.org/10.24425/CPE.2019.126109","url":null,"abstract":"Typically applied static (i.e. non-agitated) cultures do not provide sufficient conditions for efficient propagation of suspended non-adherent cells, in general. Feasibility of small-scale wave-type agitated single-use bioreactors for gentle agitation underlies applicability of such systems for scaling-up of fragile biomass of animal cells. The basic aim of the study was to compare the results of non-adherent HL-60 cell propagation performed referentially as the batch culture in typical static (i.e. non-agitated) disposable culture flasks (50 cm3 of culture medium) and in ReadyToProcess WAVETM25 bioreactor system (GE Healthcare) equipped with disposable culture bag (300 cm3 of culture medium) subjected to continuous wave-type agitation. The density and viability of HL-60 cells were significantly higher for the bioprocess subjected to wave-type agitation, than in the reference static culture. The values of the specific rate of glucose consumption per cell (rglc/cell) exhibited by HL-60 cells maintained in the system with continuous wave-type agitation was significantly lower (i.e. up to more than 42%) than the values noted for the static culture, for exactly the same time-points of two compared cultures. The results of the studies undoubtedly and comprehensively confirmed the applicability of the studied disposable bioreactor with wave-induced agitation as the right platform for proceeding the propagation of nonadherent HL-60 cells and for providing the culture conditions required by HL-60 cells for sustainable metabolism.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"40 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68947041","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-11-06DOI: 10.24425/CPE.2019.126112
T. Kiljański
The flow of the investigated fluid in a measuring system of a rheometer – a capillary or a slit between rotating parts – may be disturbed by anisotropic behavior of the fluid near the wall. This phenomenon, so-called wall slip, often takes place in concentrated suspensions and solutions of linear polymers and introduces experimental errors to measurement results. There are methods of correction of these errors in the case of capillary and coaxial cylinders measuring systems. In the cone and plate system the correction seems to be more difficult because the width of the gap between cone and plate changes along the radius and thus the influence of the wall slip on the shear stress varies along the radius in an unpredictable and complicated manner. This dependency of the shear stress on the distance from the axis underlies the presented method of correction of experimental results obtained in the cone and plate system. The method requires several series of measurements of shear stress vs. shear rate performed using one measuring set, at various degrees of filling the gap.
{"title":"A correction method of the wall-slip effect in a cone-plate rheometer","authors":"T. Kiljański","doi":"10.24425/CPE.2019.126112","DOIUrl":"https://doi.org/10.24425/CPE.2019.126112","url":null,"abstract":"The flow of the investigated fluid in a measuring system of a rheometer – a capillary or a slit between rotating parts – may be disturbed by anisotropic behavior of the fluid near the wall. This phenomenon, so-called wall slip, often takes place in concentrated suspensions and solutions of linear polymers and introduces experimental errors to measurement results. There are methods of correction of these errors in the case of capillary and coaxial cylinders measuring systems. In the cone and plate system the correction seems to be more difficult because the width of the gap between cone and plate changes along the radius and thus the influence of the wall slip on the shear stress varies along the radius in an unpredictable and complicated manner. This dependency of the shear stress on the distance from the axis underlies the presented method of correction of experimental results obtained in the cone and plate system. The method requires several series of measurements of shear stress vs. shear rate performed using one measuring set, at various degrees of filling the gap.","PeriodicalId":55267,"journal":{"name":"Chemical and Process Engineering-Inzynieria Chemiczna I Procesowa","volume":"1 1","pages":""},"PeriodicalIF":0.6,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"68947048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
京公网安备 11010802042870号
京ICP备2023020795号-1
扫码关注我们
求助内容：
应助结果提醒方式：