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Effect of mixing water on early-stage properties and hydration mechanisms of alkali-activated materials containing slag and desulfurization gypsum 掺水对含矿渣和脱硫石膏碱活性材料早期性能及水化机理的影响
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-09-22 DOI: 10.1007/s43452-025-01343-y
Chunxue Wang, Xiaoyu Zang, Jingbo Zhu, Chaofeng Hu, Meng Liang, Yingjun Jiang, Hongbo Zhao, Jiaolong Ren

Alkali-activated materials have gained increasing popularity due to their advantages in reducing carbon emissions and promoting environmental sustainability. To gain a comprehensive understanding of the early-stage properties and mechanisms of alkali-activated materials when mixed with various types of water, a study was conducted to investigate the impact of seawater, deionized water, and freshwater on the setting time, fluidity time, strength, and drying shrinkage rate of a slag and desulfurization gypsum composite alkali-activated material (SD-AAM). Additionally, the hydration products and microstructures of the SD-AAM were examined using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), and thermogravimetric–differential scanning calorimetry (TG–DSC) to uncover the mechanisms by which mixing water influences these properties. The results indicate that seawater significantly enhances the strength of the SD-AAM after a 7-day curing age compared to deionized water. However, it also reduces fluidity, setting time, and drying shrinkage rate. This phenomenon can be attributed to the ability of seawater to accelerate the hydration process and facilitate the formation of Friedel’s salt. The strengthening effect of the seawater becomes increasingly pronounced as the curing age extends. Furthermore, Friedel’s salt is gradually enveloped by C–(A)–S–H gel, leading to a decrease in the ({text{Cl/Al}}) ratio when seawater is utilized, as evidenced by the combined results of SEM and EDS. In contrast, freshwater consistently exerts a detrimental effect on early-stage strength across various curing ages. These findings are significant for expanding the applications of alkali-activated materials in specialized engineering contexts.

碱活性材料因其在减少碳排放和促进环境可持续性方面的优势而越来越受到人们的欢迎。为全面了解碱活性材料与不同类型水混合后的早期性能和机理,研究了海水、去离子水和淡水对矿渣-脱硫石膏复合碱活性材料(SD-AAM)凝结时间、流动时间、强度和干燥收缩率的影响。此外,利用扫描电子显微镜(SEM)、能量色散x射线能谱(EDS)、x射线衍射(XRD)和热重-差示扫描量热法(TG-DSC)对SD-AAM的水化产物和微观结构进行了研究,以揭示混合水影响这些性质的机制。结果表明,与去离子水相比,海水在养护7 d后显著提高了SD-AAM的强度。然而,它也会降低流动性、凝固时间和干燥收缩率。这一现象可归因于海水加速水化过程,促进弗里德尔盐形成的能力。随着龄期的延长,海水的强化作用越来越明显。此外,Friedel 's盐逐渐被C - (A) - s - h凝胶包裹,导致利用海水时({text{Cl/Al}})比降低,SEM和EDS的综合结果也证明了这一点。相反,淡水在不同龄期对早期强度的影响都是不利的。这些发现对于扩大碱活化材料在特殊工程环境中的应用具有重要意义。
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引用次数: 0
The impact of accelerated weathering exposure on the mechanical, thermal and chemical properties of natural insulators: natural cork, agglomerated cork and expanded cork 加速风化暴露对天然绝缘体:天然软木、凝聚软木和膨胀软木的机械、热学和化学性能的影响
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-09-21 DOI: 10.1007/s43452-025-01339-8
Guilherme J. A. Sousa, Fábio A. O. Fernandes, Sara Figueiredo, Ana P. F. Caetano, Rui M. Novais, Ricardo J. Alves de Sousa, António B. Pereira

Cork materials, valued for their sustainability and thermal insulating properties, are gaining use as eco-friendly alternatives to synthetic insulation in building facades, among other architectural, construction, and building applications. However, the ageing effects caused by weathering exposure are yet to be investigated. Understanding how these materials respond to outdoor environmental stressors is essential to ensure their long-term performance in facade systems and other exposed building elements. Therefore, this study examines the effects of accelerated ultraviolet (UV) ageing and freeze–thaw (FT) cycles on natural, agglomerated, and expanded cork’s structure, mechanical, thermal, and chemical properties. Each cork type underwent UV and FT ageing, simulating seasonal environmental conditions, and was subsequently analysed through scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), compressive mechanical testing, and thermal analysis. UV exposure leads to the degradation of the cellular structure in all types of cork, with particularly significant in expanded cork. On the other hand, FT cycles primarily affect agglomerated cork. FTIR analysis corroborates these structural changes from SEM observations, showing spectral changes associated with suberin and lignin degradation in UV-exposed cork. However, only expanded cork exhibits changed or erased bands when exposed to FT cycles. Mechanical testing indicates that UV exposure reduces the compressive strength of natural cork, whereas FT cycles led to a slight increase in the agglomerated one and a significant decline for natural and expanded cork. Thermal tests reveal that UV exposure increases thermal conductivity and specific heat in natural cork but reduces diffusivity, while agglomerated cork experiences an increase in conductivity and diffusivity for the same conditions. FT cycles generally increase the conductivity of all cork types, while thermal diffusivity decreases for expanded cork and decreases for both natural and agglomerated cork.

软木材料因其可持续性和隔热性能而受到重视,在建筑立面以及其他建筑、施工和建筑应用中,作为合成隔热材料的环保替代品,软木材料的使用越来越多。然而,风化暴露引起的老化效应尚未得到研究。了解这些材料如何应对室外环境压力对于确保它们在立面系统和其他暴露的建筑元素中的长期性能至关重要。因此,本研究考察了加速紫外线(UV)老化和冻融(FT)循环对天然、凝聚和膨胀软木的结构、机械、热和化学性能的影响。每种软木塞都经过了UV和FT老化,模拟季节环境条件,随后通过扫描电子显微镜(SEM)、傅里叶变换红外光谱(FTIR)、压缩力学测试和热分析进行了分析。紫外线暴露会导致所有类型软木塞的细胞结构退化,尤其是膨胀软木塞。另一方面,FT周期主要影响凝聚软木。FTIR分析证实了SEM观察的这些结构变化,显示了紫外线暴露软木中木质素和木质素降解的光谱变化。然而,当暴露于FT循环时,只有膨胀软木表现出改变或擦除的条带。力学测试表明,UV暴露降低了天然软木塞的抗压强度,而FT循环导致凝聚软木塞的抗压强度略有增加,而天然软木塞和膨胀软木塞的抗压强度则显著下降。热测试表明,暴露在紫外线下会增加天然软木塞的导热系数和比热,但会降低扩散系数,而在相同条件下,聚合软木塞的传导系数和扩散系数会增加。FT循环通常会增加所有软木塞类型的导电性,而膨胀软木塞的热扩散率会降低,天然软木塞和凝聚软木塞的热扩散率都会降低。
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引用次数: 0
Influence of palm oil ash and palm leaf ash on the properties of ultra-high-performance concrete incorporating ceramic waste as fine aggregate 棕榈油灰和棕榈叶灰对陶瓷废料细骨料超高性能混凝土的影响
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-09-21 DOI: 10.1007/s43452-025-01340-1
Abdullah M. Zeyad, Ashraf M. Heniegal, Mohamed Amin, Ibrahim Saad Agwa, Mahmoud H. Abd-Elrahman

This research describes the formulation and experimental assessment of an environmentally sustainable ultra-high-performance concrete (UHPC) embedding both agricultural and industrial by-products. Although individual use of agricultural or ceramic waste in concrete has been explored, the combined effect of palm-based ashes and ceramic waste as fine aggregates (CWFA) on UHPC’s properties remains insufficiently investigated. Palm oil ash (POA) and palm leaf ash (PLA) were incorporated as partial substitutes for Portland cement (PC) in proportions of 10%, 20%, 30%, 40%, and 50%; concurrently, CWFA substituted quartz sand at replacement levels of 25%, 50%, 75%, and 100%. Nineteen distinct concrete mixtures were thus prepared and evaluated. Performance metrics comprised slump flow, compressive strength, permeability, scanning electron microscopy (SEM) analysis, and compressive strength retention under elevated-temperature conditions. Data revealed that the introduction of POA and PLA to an extent of 30% generally elevated the compressive strength in comparison to the reference matrix. The most effective mixture, POA30-C100, attained a peak compressive strength of 205.5 MPa at 90 days, exceeding the reference strength of 172.4 MPa. These results underscore the viability of repurposing agricultural and industrial residues for the sustainable fabrication of high-performance UHPC, thereby enhancing both material performance and ecological stewardship.

本研究描述了一种环境可持续的超高性能混凝土(UHPC)的配方和实验评估,该混凝土包含农业和工业副产品。虽然已经探索了农业或陶瓷废物在混凝土中的单独使用,但棕榈基灰烬和陶瓷废物作为细集料(CWFA)对UHPC性能的综合影响仍未得到充分研究。分别以10%、20%、30%、40%和50%的比例加入棕榈油灰(POA)和棕榈叶灰(PLA)作为波特兰水泥(PC)的部分替代品;同时,CWFA对石英砂的替代率分别为25%、50%、75%和100%。19种不同的混凝土混合物因此制备和评估。性能指标包括坍落度流动、抗压强度、渗透率、扫描电子显微镜(SEM)分析和高温条件下的抗压强度保持。数据显示,与参考矩阵相比,引入30%的POA和PLA总体上提高了抗压强度。最有效的混合料POA30-C100在90天后达到了205.5 MPa的峰值抗压强度,超过了参考强度172.4 MPa。这些结果强调了重新利用农业和工业残留物可持续制造高性能UHPC的可行性,从而提高材料性能和生态管理。
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引用次数: 0
Influence of strain rate on the mechanical behaviour of high-manganese TWIP steel tested using a flywheel machine 应变速率对高锰TWIP钢力学性能的影响
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-09-16 DOI: 10.1007/s43452-025-01334-z
Michał Kostka, Marek Tkocz, Artur Cichański, Magdalena Barbara Jabłońska

The present study investigates the dynamic tensile behaviour of a high-manganese austenitic TWIP steel (X45MnAl20-4) using a flywheel-based testing system, with emphasis on strain rate effects. Dynamic tensile tests with strain rates ranging from approximately 300 to 950 s−1. The force vs. time signals were recorded during the course of tests. This allowed the true stress–true strain diagrams to be determined. It has been established that the propagation of elastic stress waves within the test stand construction caused oscillations in the σtruetrue curves. The smoothing of these oscillations has been approached through the utilisation of a power function as an approximation. The influence of strain rate on the tested steel characteristics such as flow stress, plastic deformation work, and absorbed energy (SEA and VEA) was quantitatively evaluated on the basis of the obtained σtruetrue curves. Microscopic observations confirmed that mechanical twinning is the predominant deformation mechanism in the steel studied, with increased twinning density and multisystem twinning under dynamic conditions. A comparison of the X45MnAl20-4 steel with other TWIP steels and DP steel has shown that it exhibits a competitive specific SEA value. This confirms its suitability for use in structural components operating under dynamic loading conditions. The findings of the study underscore the significance of accurate measurement data interpretation and selection of suitable correction methods when analysing the dynamic mechanical responses of TWIP steels by means of a flywheel machine.

本研究利用飞轮测试系统研究了高锰奥氏体TWIP钢(X45MnAl20-4)的动态拉伸行为,重点研究了应变率效应。动态拉伸试验,应变率范围约为300至950 s−1。在测试过程中记录力与时间的信号。这使得真正的应力-真应变图得以确定。研究发现,弹性应力波在试验台结构内部的传播引起了σtrue-εtrue曲线的振荡。这些振荡的平滑是通过利用幂函数作为近似来实现的。根据得到的σtrue-εtrue曲线,定量评价了应变速率对试验钢流变应力、塑性变形功和吸收能(SEA和VEA)的影响。显微观察证实,机械孪晶是所研究钢的主要变形机制,在动态条件下孪晶密度增加和多系统孪晶。X45MnAl20-4钢与其他TWIP钢和DP钢的比较表明,它具有竞争力的比SEA值。这证实了它适用于在动态载荷条件下运行的结构部件。研究结果强调了在利用飞轮机分析TWIP钢的动态力学响应时,准确的测量数据解释和选择合适的校正方法的重要性。
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引用次数: 0
Synergizing TWIP and TRIP effects for optimized mechanical performance via stacking fault energy control in austenitic steels 通过层错能控制协同TWIP和TRIP效应优化奥氏体钢的力学性能
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-09-15 DOI: 10.1007/s43452-025-01333-0
Jiahua Yuan, Lingyu Wang, Chenchong Wang, Guangqi Dong, Jinliang Wang, Yizhuang Li, Jun Hu, Wei Xu

The stacking fault energy (SFE)-governed synergy between twinning-induced plasticity (TWIP) and transformation-induced plasticity (TRIP) mechanisms delivers superior mechanical properties compared to either effect alone. However, precise knowledge of an optimal TWIP and TRIP balance remains elusive and holistic understanding on the contributions from both TWIP and TRIP effects to the mechanical properties is still lacking. In this study, we show that by carefully tailoring the SFE to approximately 10 mJ·m−2 through adjustment of grain size and deformation temperatures, an optimal synergy between strength and ductility can be achieved in Fe–Cr–Ni austenitic steels with a variety of compositions. This synergy arises from the intricate manipulation of the sustained TWIP and TRIP effects. The optimal combination characterized by approximately 18% deformation twins and 50% strain-induced martensite is revealed by an SFE-dependent physical model which models the austenite → twin → α′-martensite transformation sequence. These findings offer valuable insights for the fast and cost-effective design of austenitic steels.

叠错能(SFE)控制的孪晶诱导塑性(TWIP)和相变诱导塑性(TRIP)机制之间的协同作用比单独的任何一种作用都具有更好的力学性能。然而,关于TWIP和TRIP的最佳平衡的精确知识仍然难以捉摸,对TWIP和TRIP效应对力学性能的贡献的整体理解仍然缺乏。在这项研究中,我们表明,通过调整晶粒尺寸和变形温度,精心地将SFE调整到大约10 mJ·m−2,可以在具有各种成分的Fe-Cr-Ni奥氏体钢中实现强度和塑性之间的最佳协同作用。这种协同作用源于对持续TWIP和TRIP效应的复杂操纵。通过模拟奥氏体→孪晶→α′-马氏体相变序列的sfe依赖物理模型,揭示了由约18%变形孪晶和50%应变诱发马氏体组成的最佳组合。这些发现为奥氏体钢的快速和低成本设计提供了有价值的见解。
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引用次数: 0
Influence of progressive deposition on microstructure and mechanical properties of ER70S-6 in wire arc additive manufacturing process 电弧增材制造过程中渐进沉积对ER70S-6合金组织和力学性能的影响
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-09-13 DOI: 10.1007/s43452-025-01320-5
Harpal, Gurraj Singh, M. K. Gupta

This study experimentally investigated the correlation between crystallographic, microstructural, and mechanical properties of Wire arc additive manufacturing (WAAM) fabricated ER70S-6 steel, especially focusing on the effects of layer height on the fabricated samples. To examine these properties, the samples were tested at different heights, i.e., bottom segment (BS), middle segment (MS) and top segment (TS). Then, the microstructure, grain scale boundaries, microhardness, and phase transformations were analyzed with scanning electron microscope (SEM), Energy-Dispersive X-ray Spectroscopy (EBSD), microhardness tester, and X-ray Diffractometer. Similarly, the mechanical behavior of ER70S-6 manufactured parts was measured along a vertical direction, i.e., building direction with a universal testing machine (UTM). The research shows that the mechanical properties of the same parts at different heights were not similar. The average microhardness and ultimate tensile strength of the constructed sample were reduced by 13.21% and 6.18%, respectively, from the bottom to the top of the sample. Based on this, it was found that changes in the cooling rate at different levels resulted in considerable variation in the microstructure. It is also concluded that a coarse-grained zone exists in samples along the building axis, with its growth toward the topmost part causing various changes in mechanical attributes such as ductility and strength.

实验研究了电弧增材制造(WAAM)制备的ER70S-6钢的晶体学、显微组织和力学性能之间的关系,重点研究了层高对制备样品的影响。为了检验这些特性,样品在不同的高度,即底部段(BS),中间段(MS)和顶部段(TS)进行了测试。利用扫描电子显微镜(SEM)、能量色散x射线能谱仪(EBSD)、显微硬度计和x射线衍射仪分析了材料的显微组织、晶粒边界、显微硬度和相变。同样,采用通用试验机(UTM)沿垂直方向(即建筑方向)测量ER70S-6制件的力学行为。研究表明,同一零件在不同高度时的力学性能并不相似。从底部到顶部,试样的平均显微硬度和极限抗拉强度分别降低了13.21%和6.18%。在此基础上,发现不同水平冷却速率的变化导致了组织的较大变化。试样沿建筑轴方向存在粗粒区,粗粒区向顶部扩展,导致塑性、强度等力学属性发生各种变化。
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引用次数: 0
Optimization of self-compacting mortars with olive pomace bottom ash using central composite design approach 橄榄渣底灰自密实砂浆的中心复合设计优化
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-09-12 DOI: 10.1007/s43452-025-01327-y
Besma Belaidi, Cherif Belebchouche, Abdelkader Hammoudi, Abdellah Douadi, Kamel Hebbache, Mourad Boutlikht, Adrian Chajec, Slawomir Czarnecki

This study investigates the potential use of Olive Pomace Bottom Ash (OPBA) as a partial cement replacement in self-compacting mortars (SCMs) to enhance sustainability in construction while addressing environmental concerns. A Central Composite Design (CCD) approach was used to investigate the effect of OPBA content (0–20%), limestone filler content (10–20%), and water-to-binder (W/B) ratio (0.4–0.5) on fresh properties, mechanical behavior, and water absorption potential of SCM. The results indicate that increasing the OPBA content typically decreased workability and strength while at the same time increasing water absorption potential. However, this effect can be mitigated by optimizing the filler content and W/B ratio. With low additions of OPBA (up to 10%), incorporating limestone filler showed a regular increase in strength. Statistical analyses using the central composite design method confirm that complex non-linear relationships among variables exist and that advanced optimization techniques are needed in mix design. An optimal mix was found to have 6.66% OPBA, 20% filler, and a W/B ratio of 0.42, with a desirability value of 0.927. This optimal mixture recorded a slump of 26.3 cm, flow time of 11.85 s, compressive strength of 48.66 MPa, flexural strength of 5.47 MPa, and water absorption of 11%. The above study indicates that OPBA is feasible in SCMs and could improve sustainability in the construction industry without compromising performance. These findings highlight OPBA feasibility in SCMs, promoting waste valorization and reducing cement consumption without compromising performance.

本研究探讨了橄榄渣底灰(OPBA)作为自密实砂浆(SCMs)中部分水泥替代品的潜在用途,以提高建筑的可持续性,同时解决环境问题。采用中心复合设计(CCD)方法研究了OPBA含量(0-20%)、石灰石填料含量(10-20%)和水胶比(W/B)(0.4-0.5)对SCM新鲜性能、力学行为和吸水势的影响。结果表明,增加OPBA含量会降低材料的和易性和强度,同时提高材料的吸水势。然而,这种影响可以通过优化填料含量和W/B比来缓解。在OPBA掺量较低(10%)的情况下,石灰石填料的强度有规律地增加。采用中心组合设计方法进行的统计分析证实了变量之间存在复杂的非线性关系,混合设计需要先进的优化技术。优选出的最佳配合比为:OPBA 6.66%,填料20%,W/B比0.42,理想值为0.927。该混合料坍落度为26.3 cm,流动时间为11.85 s,抗压强度为48.66 MPa,抗折强度为5.47 MPa,吸水率为11%。上述研究表明,OPBA在scm中是可行的,可以在不影响绩效的情况下提高建筑业的可持续性。这些发现强调了OPBA在scm中的可行性,在不影响性能的情况下促进废物增值和减少水泥消耗。
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引用次数: 0
The role of particle size optimisation of waste granite powder in cementitious composites 花岗石废粉粒度优化在胶凝复合材料中的作用
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-09-12 DOI: 10.1007/s43452-025-01330-3
Adrian Chajec

The utilisation of granite powder (GP) waste in cementitious composites is limited by its low reactivity and adverse effects on mechanical performance. This study investigates the mechanical activation of GP through grinding (GP-M) and sieving (GP-S) to optimise its physical properties and sustainability potential. The modified powders were characterised in terms of specific surface area (SSA), reactivity, loss on ignition, and alkali leachability. Cementitious composites were prepared with 20% and 40% cement replacement and evaluated for slump flow, setting time, strength development, and bulk density. Results show that grinding increases the SSA from 2890 cm2/g (raw GP) to 4290 cm2/g (GP-M), improving particle packing and enhancing compressive strength by up to 20% compared to unprocessed GP. Despite its low pozzolanic reactivity, GP-M acts as an effective filler, improving microstructure and maintaining compressive strengths above 40 MPa at 28 days for 20% replacement. Alkali leachability was also reduced, supporting long-term durability. A Life Cycle Assessment (LCA) indicates that replacing 40% of cement with GP-M reduces CO2 emissions by over 50%, while maintaining acceptable mechanical properties. The proposed Mechanical Performance Ratio (MPR) and Environmental Performance Ratio (EPR) demonstrate that the most balanced performance was achieved in the GP-M20 and GP-S20 series, offering up to 12% CO2 savings with minimal strength reduction. This study confirms that mechanically valorised granite powder is a viable, sustainable SCM, capable of reducing cement content while satisfying structural and environmental requirements in construction applications.

花岗岩粉(GP)废料在胶凝复合材料中的利用受到其低反应性和对力学性能不利影响的限制。本研究通过研磨(GP- m)和筛分(GP- s)对GP进行机械活化,以优化其物理性能和可持续性潜力。改性粉末在比表面积(SSA)、反应性、着火损失和碱浸出性方面进行了表征。分别以20%和40%的水泥替代量制备了胶凝复合材料,并对坍落度流动、凝结时间、强度发展和容重进行了评价。结果表明,与未加工的GP相比,磨削使SSA从2890 cm2/g(粗GP)增加到4290 cm2/g (GP- m),改善颗粒堆积,抗压强度提高20%。尽管GP-M的火山灰反应性较低,但它可以作为有效的填料,改善微观结构,并在更换20%后的28天内保持40 MPa以上的抗压强度。碱浸出性也降低了,支持长期耐用性。生命周期评估(LCA)表明,用GP-M替代40%的水泥可减少50%以上的二氧化碳排放,同时保持可接受的机械性能。建议的机械性能比(MPR)和环境性能比(EPR)表明,GP-M20和GP-S20系列实现了最平衡的性能,在最小强度降低的情况下可节省高达12%的二氧化碳。这项研究证实,机械增值花岗岩粉是一种可行的、可持续的SCM,能够减少水泥含量,同时满足建筑应用中的结构和环境要求。
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引用次数: 0
The effect of annealing on the growth of Al3Ni and Al3Ni2 intermetallics at the interface of explosively welded Al/Ni clads 退火对爆炸焊接Al/Ni包层界面Al3Ni和Al3Ni2金属间化合物生长的影响
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-09-12 DOI: 10.1007/s43452-025-01325-0
Izabella Kwiecien, Sylwia Terlicka, Agnieszka Bigos, Katarzyna Stan-Glowinska, Anna Wierzbicka-Miernik, Zygmunt Szulc, Joanna Wojewoda-Budka

Explosive welding is an effective method for joining metals with dissimilar physicochemical properties. The Al/Ni system is particularly interesting due to the formation of intermetallic phases with unique mechanical and thermal properties, which makes these welds potentially applicable in industries, such as aerospace, energy, and chemical. Diffusion processes occurring at the interface between these metals play a significant role and can impact the durability of the connections. Therefore, this research focuses on the analysis of diffusion phenomena in Al/Ni welds formed by explosive welding and subjected to further annealing. It was investigated whether the technological parameters of the joining process, such as detonation velocity, which varied from 2000 to 2800 m/s or mutual localization of the colliding plates during the explosion, influence post-annealing interface transformations, in particular the sequence of the intermetallic phase formation, their thickness and growth mechanism. Welded clads underwent annealing at 500 °C for periods ranging from 0.5 to 168 h. After the heat treatment, microstructure and phase characterization of the interface zone were performed, with scanning and transmission electron microscopy, thanks to which the mechanisms and growth kinetics of the forming phases were determined. Additionally, for the first time, the anisotropy of the thermal expansion in explosively welded Al/Ni was examined with respect to the shock wave propagation and the accompanying microstructure evolution, providing a significant contribution to the engineering design of welds subjected to the thermal cycling. The thermal expansion coefficient was measured over the temperature range from ambient temperature to 500 °C and analyzed in relation to the welding conditions. Differences in the thickness of the two forming Al3Ni and Al3Ni2 layers and their dominant growth mechanisms were observed for the individual clads. The effect of detonation velocity was particularly significant at 2000 m/s, where prolonged annealing led to weld degradation, thus limiting strength due to unfavorable welding conditions. The presence of porosity identified at the Al1050/Al3Ni2 interface was attributed to the Kirkendall effect accompanying the annealing procedure. Measurements of the thermal expansion coefficient revealed minor differences between samples, with the largest discrepancies observed for clads produced at 2400 m/s, which may be due to the less uniform initial microstructure of the interface. The obtained results indicate a relationship between explosive welding conditions and changes in the microstructure and physical properties of Al/Ni welds after heat treatment.

爆炸焊接是连接物理化学性质不同的金属的一种有效方法。Al/Ni体系特别有趣,因为它形成了具有独特机械和热性能的金属间相,这使得这些焊缝在航空航天、能源和化工等行业中具有潜在的应用前景。在这些金属之间的界面上发生的扩散过程起着重要的作用,并且会影响连接的耐久性。因此,本研究重点分析了爆炸焊接形成的Al/Ni焊缝中进一步退火后的扩散现象。研究了连接过程的工艺参数(如爆轰速度(2000 ~ 2800 m/s)或爆炸过程中碰撞板的相互局部化)对退火后界面转变的影响,特别是金属间相形成的顺序、厚度和生长机制。焊接熔覆层在500℃下退火0.5 ~ 168 h。热处理后,使用扫描电镜和透射电镜对界面区进行微观组织和相表征,从而确定形成相的机制和生长动力学。此外,首次研究了爆炸焊接Al/Ni中热膨胀的各向异性,以及冲击波传播和伴随的微观组织演变,为热循环焊缝的工程设计提供了重要贡献。在从环境温度到500°C的温度范围内测量了热膨胀系数,并分析了与焊接条件的关系。观察了不同覆层形成的Al3Ni和Al3Ni2层的厚度差异及其主要生长机制。爆轰速度的影响在2000 m/s时尤为显著,长时间的退火导致焊缝退化,从而由于不利的焊接条件而限制了强度。在Al1050/Al3Ni2界面上发现孔隙度的存在归因于退火过程中的Kirkendall效应。热膨胀系数的测量显示样品之间的差异很小,在2400 m/s的速度下产生的包层差异最大,这可能是由于界面的初始微观结构不均匀所致。结果表明,爆炸焊接条件与热处理后Al/Ni焊缝组织和物理性能的变化存在一定的关系。
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引用次数: 0
Thermo-dependent dynamic analysis of imperfect shear-deformable nanocomposite conical micro shells 不完全剪切变形纳米复合材料锥形微壳热相关动力学分析
IF 4.4 3区 工程技术 Q1 ENGINEERING, CIVIL Pub Date : 2025-09-11 DOI: 10.1007/s43452-025-01328-x
Ehsan Arshid, Saeed Amir, Iman Dadoo, Ömer Civalek

In the present research, free vibration of a truncated conical shell is investigated. The shell consists of three layers: a porous core and two carbon nanotube-reinforced nanocomposite (CNTs-RNC) facesheets. The structure is inserted in a thermal environment and also, is also subjected to a longitudinal magnetic field. The structure’s kinematics is modelled based on the first-order shear deformation theory (FSDT), and the modified coupled stress theory (MCST) is used to consider the scale effect. The equations of motion are derived using Hamilton’s principle, and then, the generalized differential quadrature method (GDQM) is employed to solve them under various combinations of boundary conditions. The effects of several parameters, including geometry, porosity coefficient, porosity distribution patterns, CNTs’ mass fraction and types, agglomeration coefficients, boundary conditions, and small-scale parameter are investigated. The results demonstrate that the natural frequency increases with increasing CNTs’ mass fraction and decreases with increasing porosity. These structures have a wide range of potential applications and can be used in microelectromechanical and nanoelectromechanical systems.

本文研究了截顶锥形壳的自由振动问题。外壳由三层组成:多孔核心和两个碳纳米管增强纳米复合材料(CNTs-RNC)表面。该结构被插入热环境中,也受到纵向磁场的影响。基于一阶剪切变形理论(FSDT)对结构进行运动学建模,并采用修正耦合应力理论(MCST)考虑尺度效应。利用Hamilton原理推导了运动方程,然后利用广义微分正交法(GDQM)在各种边界条件组合下求解了运动方程。研究了几何形状、孔隙率系数、孔隙率分布模式、CNTs的质量分数和类型、团聚系数、边界条件和小尺度参数等参数的影响。结果表明:固有频率随CNTs质量分数的增加而增加,随孔隙率的增加而降低;这些结构具有广泛的潜在应用,可用于微机电和纳米微机电系统。
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引用次数: 0
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Archives of Civil and Mechanical Engineering
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