Parent material, landform, and climate strongly influence soil properties, yet their combined effects remain underexplored in Malawi. This study analysed B horizon samples from 41 soil profiles developed on diverse parent materials, landforms (rift valley floor, escarpments, mid- and high-altitude plateaus), and climatic zones across northern and central Malawi. Total elemental composition was used to infer parent material origin and weathering intensity, while effective precipitation (EP; precipitation minus potential evapotranspiration) ranged from −362 to 954 mm. Based on total elemental composition, soils were grouped into four categories: silica-rich (356.0 g kg−1 Si), iron-rich (92.4 g kg−1 Fe), intermediate (297.1 g kg−1 Si, 55.0 g kg−1 Fe), and CaMgK enriched (7.0, 4.6, and 20.0 g kg−1, respectively). Silica-rich soils exhibited high sand, Al3+, kaolinite, and quartz contents but low pH, total exchangeable bases (TEB), cation exchange capacity (CEC), total reserve bases (TRB), and mica—reflecting felsic parent materials and advanced weathering. These soils, mainly from stable mid-plateaus, were classified as Lixisols, with few Acrisols and Arenosols from the rift valley floor. Iron-rich soils, predominantly from escarpments, had high clay, pH, TEB, CEC (soil and clay), TRB, and mica, indicating not advanced weathering and the presence of weatherable primary minerals. These were mostly Luvisols, Cambisols, and Alisols. Intermediate soils from mid- and high-altitude plateaus showed transitional properties; those from mid-altitude plateau developed into Luvisols and Lixisols, while those from high plateaus under higher EP formed Acrisols. CaMgK enriched soils, common in unstable rift valley and escarpment zones, had the highest pH, TEB, CEC, TRB, and mica but low kaolinite, indicating limited weathering linked to erosion–deposition processes. These were mainly Luvisols, Cambisols, and Vertisols. Increasing EP corresponded with declining pH, TEB, and base saturation, and rising Al3+, reflecting leaching and Acrisol formation under wetter and in stable conditions. Overall, parent material, landform, and climate collectively shaped soil properties and classification, with iron-rich soils appearing less weathered than expected, likely due to ongoing tectonic rejuvenation within the Malawi Rift Valley.
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