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Synthetic auxotrophs accelerate cell factory development through growth-coupled models 合成辅助营养体通过生长耦合模型加速细胞工厂的发展
IF 4.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-06-06 DOI: 10.1007/s11705-024-2454-9
Liangpo Li, Linwei Yu, Xinxiao Sun, Qipeng Yuan, Xiaolin Shen, Jia Wang

The engineering of microbial cell factories for the production of high-value chemicals from renewable resources presents several challenges, including the optimization of key enzymes, pathway fluxes and metabolic networks. Addressing these challenges involves the development of synthetic auxotrophs, a strategy that links cell growth with enzyme properties or biosynthetic pathways. This linkage allows for the improvement of enzyme properties by in vivo directed enzyme evolution, the enhancement of metabolic pathway fluxes under growth pressure, and remodeling of metabolic networks through directed strain evolution. The advantage of employing synthetic auxotrophs lies in the power of growth-coupled selection, which is not only high-throughput but also labor-saving, greatly simplifying the development of both strains and enzymes. Synthetic auxotrophs play a pivotal role in advancing microbial cell factories, offering benefits from enzyme optimization to the manipulation of metabolic networks within single microbes. Furthermore, this strategy extends to coculture systems, enabling collaboration within microbial communities. This review highlights the recently developed applications of synthetic auxotrophs as microbial cell factories, and discusses future perspectives, aiming to provide a practical guide for growth-coupled models to produce value-added chemicals as part of a sustainable biorefinery.

利用可再生资源生产高价值化学品的微生物细胞工厂工程设计面临着一些挑战,包括关键酶、途径通量和代谢网络的优化。要应对这些挑战,就需要开发合成辅助营养体,这是一种将细胞生长与酶特性或生物合成途径联系起来的策略。这种联系可以通过体内定向酶进化改善酶的特性,在生长压力下提高代谢途径通量,并通过定向菌株进化重塑代谢网络。利用合成营养辅助体的优势在于生长耦合选择的力量,这不仅具有高通量的特点,而且节省人力,大大简化了菌株和酶的开发。合成辅助营养体在推动微生物细胞工厂的发展方面发挥着举足轻重的作用,可提供从酶优化到操纵单个微生物内部代谢网络的各种益处。此外,这种策略还可扩展到共培养系统,实现微生物群落内部的协作。本综述重点介绍了最近开发的合成辅助营养体作为微生物细胞工厂的应用,并讨论了未来的前景,旨在为生长耦合模型提供实用指南,以生产增值化学品,作为可持续生物炼制的一部分。
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引用次数: 0
Enhanced bioethanol production from sugarcane bagasse: combination of liquid hot water and deep eutectic solvent pretreatment for optimized enzymatic saccharification 提高甘蔗渣的生物乙醇产量:结合液态热水和深层共晶溶剂预处理优化酶法糖化过程
IF 4.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-06-04 DOI: 10.1007/s11705-024-2438-9
Xiaoling Xian, Biying Li, Shiyong Feng, Jiale Huang, Xinyuan Fu, Ting Wu, Xiaoqing Lin

In the present study, a sustainable pretreatment methodology combining liquid hot water and deep eutectic solvent is proposed for the efficient fractionation of hemicellulose, cellulose, and lignin from sugarcane bagasse, thereby facilitating the comprehensive utilization of both C5 and C6 sugars. The application of this combined pretreatment strategy to sugarcane bagasse led to notable enhancements in enzymatic saccharification and subsequent fermentation. Experiment results demonstrate that liquid hot water-deep eutectic solvent pretreatment yielded 85.05 ± 0.66 g·L−1 of total fermentable sugar (glucose: 60.96 ± 0.21 g·L−1, xylose: 24.09 ± 0.87 g·L−1) through enzymatic saccharification of sugarcane bagasse. Furthermore, fermentation of the pretreated sugarcane bagasse hydrolysate yielded 34.33 ± 3.15 g·L−1 of bioethanol. These findings confirm the effectiveness of liquid hot water-deep eutectic solvent pretreatment in separating lignocellulosic components, thus presenting a sustainable and promising pretreatment method for maximizing the valuable utilization of biomass resources.

本研究提出了一种结合液态热水和深层共晶溶剂的可持续预处理方法,用于高效分馏甘蔗渣中的半纤维素、纤维素和木质素,从而促进 C5 和 C6 糖的综合利用。对甘蔗渣采用这种联合预处理策略可显著提高酶糖化和后续发酵的效果。实验结果表明,通过对甘蔗渣进行酶法糖化,液态热水-深共晶溶剂预处理可产生 85.05 ± 0.66 g-L-1 的总发酵糖(葡萄糖:60.96 ± 0.21 g-L-1,木糖:24.09 ± 0.87 g-L-1)。此外,发酵经预处理的甘蔗渣水解物可产生 34.33 ± 3.15 g-L-1 的生物乙醇。这些研究结果证实了液态热水-深共晶溶剂预处理在分离木质纤维素成分方面的有效性,从而为最大限度地利用生物物质资源提供了一种可持续的、有前途的预处理方法。
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引用次数: 0
Interfacing biosynthetic CdS with engineered Rhodopseudomonas palustris for efficient visible light-driven CO2–CH4 conversion 将生物合成的 CdS 与工程化的古朴红假单胞菌(Rhodopseudomonas palustris)结合起来,实现可见光驱动的 CO2-CH4 高效转化
IF 4.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-06-03 DOI: 10.1007/s11705-024-2460-y
Yu Zhang, Yulei Qian, Zhenye Tong, Su Yan, Xiaoyu Yong, Yang-Chun Yong, Jun Zhou

Engineered photosynthetic bacterium Rhodo-pseudomonas palustris is excellent at one-step CO2 biomethanation and can use near-infrared light sources, overcoming the limitations of conventional photosynthetic systems. The current study constructed a biohybrid system that deposited CdS nanoparticles on R. palustris. This biohybrid system broadens the capture of sustainable solar energy, achieving a 155 nmol·mL−1 biological CH4 production under full visible light irradiation, 13.4-fold of that by the pure R. palustris. The transcriptome profiles revealed that gene expression related to photosynthetic electron transfer chain, nitrogenase, nanofilaments, and redox stress defense was activated. Accordingly, we attributed the much-enhanced CO2 biomethanation in the biohybrid system to the remarkable increase in the intracellular reducing power and the stronger rigidity of the cells assisted by photoexcited electrons from CdS nanoparticles. Our discovery offers insight and a promising strategy for improving the current CO2–CH4 biomanufacturing system.

工程光合细菌 Rodo-pseudomonas palustris 在一步法二氧化碳生物甲烷化方面表现出色,并且可以使用近红外光源,克服了传统光合系统的局限性。本研究构建了一个生物杂交系统,在 R. palustris 上沉积了 CdS 纳米粒子。该生物杂交系统拓宽了对可持续太阳能的捕获,在完全可见光照射下实现了 155 nmol-mL-1 的生物甲烷产量,是纯 R. palustris 产量的 13.4 倍。转录组图谱显示,与光合电子传递链、氮酶、纳米纤维和氧化还原胁迫防御相关的基因表达被激活。因此,我们将生物杂交系统中二氧化碳生物甲烷化能力的大幅提高归因于细胞内还原能力的显著提高,以及在 CdS 纳米粒子的光激发电子帮助下细胞刚性的增强。我们的发现为改进当前的二氧化碳-CH4 生物制造系统提供了启示和有前途的策略。
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引用次数: 0
Inter-chromosomal insertions into wild-type chromosomes induced by SCRaMbLE SCRaMbLE 诱导的野生型染色体染色体间插入
IF 4.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-06-03 DOI: 10.1007/s11705-024-2458-5
Sijie Zhou, Junyanrui Li, Xichen Cui, Ying Wang, Ying-Jin Yuan

Genomic rearrangements play a crucial role in shaping biological phenotypic diversity and driving species evolution. Synthetic chromosome rearrangement and modification by LoxP-mediated evolution (SCRaMbLE) has been applied to explore large-scale genomic rearrangements, yet it has been observed that these rearrangements occur exclusively in genomic regions containing loxPsym sites. Here, we found that SCRaMbLE of synthetic yeast harboring synthetic chromosome V and X can generate a variety of synthetic segment insertions into wild-type chromosomes, ranging from 1 to 300 kb. Furthermore, it was revealed that the novel insertions impacted the transcriptional level of neighboring regions and affected the production of exemplar pathway of zeaxanthin. Collectively, our results improve the understanding of the ability of SCRaMbLE to generate complex structural variations in nonsynthetic regions and provide a potential model to explore genomic transposable events.

基因组重排在形成生物表型多样性和驱动物种进化方面起着至关重要的作用。由 LoxP 介导的合成染色体重排和修饰进化(SCRaMbLE)已被用于探索大规模的基因组重排,然而据观察,这些重排只发生在含有 loxPsym 位点的基因组区域。在这里,我们发现对携带合成染色体 V 和 X 的合成酵母进行 SCRaMbLE 可在野生型染色体上产生各种合成片段插入,范围从 1 kb 到 300 kb 不等。此外,研究还发现,新插入的片段会影响邻近区域的转录水平,并影响玉米黄质模范途径的产生。总之,我们的研究结果加深了人们对 SCRaMbLE 在非合成区域产生复杂结构变异的能力的理解,并为探索基因组转座事件提供了一个潜在的模型。
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引用次数: 0
Construction of spinel/biochar film/honeycomb monolithic catalyst for photothermal catalytic oxidation of VOCs 构建用于 VOC 光热催化氧化的尖晶石/生物炭薄膜/蜂窝状整体催化剂
IF 4.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-05-31 DOI: 10.1007/s11705-024-2453-x
Xikai Lu, Chunyan Zhang, Meng Wu, Wenjie Liu, Bin Xue, Chao Yao, Xiazhang Li

Photothermal catalytic oxidation emerges as a promising method for the removal of volatile organic compounds (VOCs). Herein, via sol-gel impregnation method, spinel CuMn2O4 was coated on attapulgite honeycombs with integrating biochar (BC) film as the second carrier, using chestnut shell as complexation agent. Various mass ratios of CuMn2O4 to chestnut shell was modulated to investigate the catalytic toluene degradation performance. Results indicated that the monolithic CuMn2O4/BC/honeycomb catalyst demonstrated superior photothermal catalytic toluene degradation with a low T90 (temperature at 90% degradation) of 263 °C when the mass ratio of CuMn2O4 to biomass was 1:4. The addition of BC film substantially increased the honeycomb’s specific surface area and improved the photothermal conversion of spinel, leading to enhanced photothermal catalytic activity. This study presents a cost-effective strategy for eliminating industrial VOCs using clay-biomass based monolithic catalyst.

光热催化氧化是一种去除挥发性有机化合物(VOC)的有效方法。在此,通过溶胶-凝胶浸渍法,将尖晶石 CuMn2O4 涂覆在阿塔蓬石蜂窝上,并以栗壳作为络合剂,以整合生物炭(BC)薄膜作为第二载体。通过调节 CuMn2O4 与栗壳的不同质量比来研究甲苯的催化降解性能。结果表明,当 CuMn2O4 与生物质的质量比为 1:4 时,整体式 CuMn2O4/BC/ 蜂窝催化剂表现出优异的光热催化甲苯降解性能,T90(90% 降解温度)低至 263 ℃。BC 膜的加入大大增加了蜂窝的比表面积,提高了尖晶石的光热转化率,从而增强了光热催化活性。这项研究提出了一种利用基于粘土-生物质的整体催化剂消除工业挥发性有机化合物的经济有效的策略。
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引用次数: 0
Post-treatment of Ti-MWW zeolite with potassium fluoride for propylene epoxidation 用氟化钾对 Ti-MWW 沸石进行丙烯环氧化后处理
IF 4.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-05-30 DOI: 10.1007/s11705-024-2441-1
Xintong Li, Xianchen Gong, Jilong Wang, Shengbo Jin, Hao Xu, Peng Wu

Epoxidation of propylene to propylene oxide (PO) with hydrogen peroxide (HPPO) is an environmentally friendly and cost-efficient process in which titanosilicates are used as catalysts. Ti-MWW is a potential industrial catalyst for this process, which involves the addition of HPPO to PO. The silanol groups generated during secondary crystallization unavoidably result in ring-opening of PO and inefficient decomposition of HPPO, which diminish the PO selectivity and the lifespan of Ti-MWW. To address this issue, we conducted post-treatment modifications of the structured Bf-Ti-MWW catalyst with potassium fluoride aqueous solutions. By quenching the silanol groups with potassium fluoride and implanting electron-withdrawing fluoride groups into the Ti-MWW framework, both the catalytic activity and HPPO utilization efficiency were increased. Moreover, the ring opening reaction of PO was prohibited. In a continuous fixed-bed liquid-phase propylene epoxidation reaction, the KF-treated structured Ti-MWW catalyst displayed an exceptionally long lifespan of 2700 h, with a PO yield of 590 g·kg−1·h−1.

用过氧化氢(HPPO)将丙烯环氧化成环氧丙烷(PO)是一种环境友好且具有成本效益的工艺,其中钛硅酸盐可用作催化剂。Ti-MWW 是该工艺的一种潜在工业催化剂,该工艺涉及将 HPPO 加入到 PO 中。二次结晶过程中产生的硅烷醇基团不可避免地会导致 PO 的开环和 HPPO 的低效分解,从而降低了 PO 的选择性和 Ti-MWW 的使用寿命。为了解决这个问题,我们用氟化钾水溶液对结构化 Bf-Ti-MWW 催化剂进行了后处理改性。通过用氟化钾淬灭硅烷醇基团并在 Ti-MWW 框架中植入电子吸收氟化基团,催化活性和 HPPO 利用效率都得到了提高。此外,还禁止了 PO 的开环反应。在连续固定床液相丙烯环氧化反应中,经 KF 处理的结构化 Ti-MWW 催化剂的寿命长达 2700 h,PO 产率为 590 g-kg-1-h-1。
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引用次数: 0
Enzymatic C1 reduction using hydrogen in cofactor regeneration 利用氢在辅助因子再生中进行酶促 C1 还原
IF 4.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-05-30 DOI: 10.1007/s11705-024-2431-3
Ruishuang Sun, Chenqi Cao, Qingyun Wang, Hui Cao, Ulrich Schwaneberg, Yu Ji, Luo Liu, Haijun Xu

Carbon dioxide fixation presents a potential solution for mitigating the greenhouse gas issue. During carbon dioxide fixation, C1 compound reduction requires a high energy supply. Thermodynamic calculations suggest that the energy source for cofactor regeneration plays a vital role in the effective enzymatic C1 reduction. Hydrogenase utilizes renewable hydrogen to achieve the regeneration and supply cofactor nicotinamide adenine dinucleotide (NADH), providing a driving force for the reduction reaction to reduce the thermodynamic barrier of the reaction cascade, and making the forward reduction pathway thermodynamically feasible. Based on the regeneration of cofactor NADH by hydrogenase, and coupled with formaldehyde dehydrogenase and formolase, a favorable thermodynamic mode of the C1 reduction pathway for reducing formate to dihydroxyacetone (DHA) was designed and constructed. This resulted in accumulation of 373.19 µmol·L−1 DHA after 2 h, and conversion reaching 7.47%. These results indicate that enzymatic utilization of hydrogen as the electron donor to regenerate NADH is of great significance to the sustainable and green development of bio-manufacturing because of its high economic efficiency, no by-products, and environment-friendly operation. Moreover, formolase efficiently and selectively fixed the intermediate formaldehyde (FALD) to DHA, thermodynamically pulled formate to efficiently reduce to DHA, and finally stored the low-grade renewable energy into chemical energy with high energy density.

二氧化碳固定是缓解温室气体问题的一个潜在解决方案。在二氧化碳固定过程中,C1 化合物还原需要高能量供应。热力学计算表明,辅助因子再生的能量来源对有效的酶促 C1 还原起着至关重要的作用。氢化酶利用可再生氢实现辅助因子烟酰胺腺嘌呤二核苷酸(NADH)的再生和供应,为还原反应提供动力,从而降低反应级联的热力学障碍,使正向还原途径在热力学上可行。在氢化酶再生辅助因子 NADH 的基础上,结合甲醛脱氢酶和甲醇酶,设计并构建了将甲酸酯还原为二羟基丙酮(DHA)的 C1 还原途径的有利热力学模式。2 小时后,DHA 的累积量达到 373.19 µmol-L-1,转化率达到 7.47%。这些结果表明,酶法利用氢气作为电子供体再生 NADH 具有经济效益高、无副产物、操作环保等优点,对生物制造的可持续绿色发展具有重要意义。此外,甲醇酶能高效、选择性地将中间体甲醛(FALD)固定为 DHA,并通过热力学拉动甲酸酯高效还原为 DHA,最终将低品位可再生能源储存为能量密度高的化学能。
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引用次数: 0
Ultralong hydroxyapatite-based forward osmosis membrane for freshwater generation 用于淡水发电的超长羟基磷灰石正渗透膜
IF 4.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-05-24 DOI: 10.1007/s11705-024-2450-0
Mohamed Gamal Gomaa, Hamdy Maamoun Abdel-Ghafar, Francesco Galiano, Francesca Russo, Alberto Figoli, El-Sayed Ali Abdel-Aal, Abdel-Hakim Taha Kandil, Bahaa Ahmed Salah

Increasing global water shortages are accelerating the pace of membrane manufacturing, which generates many environmentally harmful solvents. Such challenges need a radical rethink of developing innovative membranes that can address freshwater production without generating environmentally harmful solvents. This work utilized the synthesized ultra-long hydroxyapatite (UHA) by the solvothermal method using the green solvent oleic acid in preparing UHA-based forward osmosis membranes. The membranes were developed using different loading ratios of graphene oxide (GO) by vacuum-assisted filtration technique. The prepared GO/UHA membranes were identified using X-ray diffraction, scanning electron microscope, Fourier-transform infrared spectroscopy, and X-ray photoelectron spectroscopy. Water contact angle and pore size distribution were determined for the obtained GO/UHA membranes. The obtained hierarchical porous structure in the prepared membranes with interconnected channels results in a stable water flux with reverse salt flux. The best water flux rate of 42 ± 2 L·m−2·h−1 was achieved using the 50 mg GO/UHA membrane, which is 3.3 times higher than the pristine membrane, and a reverse salt flux of 67 g·m−2·h−1. The obtained results showed a promising capability of a new generation of sustainable inorganic-based membranes that can be utilized in freshwater generation by energy-efficient techniques such as forward osmosis.

全球水资源日益短缺,加快了膜制造的步伐,而膜制造会产生许多对环境有害的溶剂。面对这样的挑战,我们需要重新思考,开发既能解决淡水生产问题,又不会产生对环境有害溶剂的创新膜。这项研究利用绿色溶剂油酸,通过溶热法合成了超长羟基磷灰石(UHA),用于制备基于 UHA 的正渗透膜。通过真空辅助过滤技术,使用不同的氧化石墨烯(GO)负载率开发了膜。利用 X 射线衍射、扫描电子显微镜、傅立叶变换红外光谱和 X 射线光电子能谱对制备的 GO/UHA 膜进行了鉴定。测定了所获得的 GO/UHA 膜的水接触角和孔径分布。制备的膜具有相互连接的通道,其分层多孔结构可实现稳定的水通量和反向盐通量。50 mg GO/UHA 膜的最佳水通量为 42 ± 2 L-m-2-h-1,是原始膜的 3.3 倍,反向盐通量为 67 g-m-2-h-1。研究结果表明,新一代可持续无机基膜具有良好的性能,可通过正渗透等节能技术用于淡水生产。
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引用次数: 0
Continuous flow pyrolysis of virgin and waste polyolefins: a comparative study, process optimization and product characterization 原生聚烯烃和废弃聚烯烃的连续流热解:比较研究、工艺优化和产品特性分析
IF 4.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-05-20 DOI: 10.1007/s11705-024-2429-x
Ecrin Ekici, Güray Yildiz, Magdalena Joka Yildiz, Monika Kalinowska, Erol Şeker, Jiawei Wang

Under optimal process conditions, pyrolysis of polyolefins can yield ca. 90 wt % of liquid product, i.e., combination of light oil fraction and heavier wax. In this work, the experimental findings reported in a selected group of publications concerning the non-catalytic pyrolysis of polyolefins were collected, reviewed, and compared with the ones obtained in a continuously operated bench-scale pyrolysis reactor. Optimized process parameters were used for the pyrolysis of waste and virgin counterparts of high-density polyethylene, low-density polyethylene, polypropylene and a defined mixture of those (i.e., 25:25:50 wt %, respectively). To mitigate temperature drops and enhance heat transfer, an increased feed intake is employed to create a hot melt plastic pool. With 1.5 g·min−1 feed intake, 1.1 L·min−1 nitrogen flow rate, and a moderate pyrolysis temperature of 450 °C, the formation of light hydrocarbons was favored, while wax formation was limited for polypropylene-rich mixtures. Pyrolysis of virgin plastics yielded more liquid (maximum 73.3 wt %) than that of waste plastics (maximum 66 wt %). Blending polyethylenes with polypropylene favored the production of liquids and increased the formation of gasoline-range hydrocarbons. Gas products were mainly composed of C3 hydrocarbons, and no hydrogen production was detected due to moderate pyrolysis temperature.

在最佳工艺条件下,聚烯烃热解可产生约 90 wt % 的液体产品,即轻油馏分和较重蜡的组合。在这项工作中,我们收集、审查并比较了一些出版物中有关聚烯烃非催化热解的实验结果,以及在连续运行的台式热解反应器中获得的结果。优化的工艺参数用于热解高密度聚乙烯、低密度聚乙烯、聚丙烯的废料和原料以及这些材料的特定混合物(即重量百分比分别为 25:25:50)。为了缓解温度下降并加强热传导,采用了增加进料量的方法来形成热熔塑料池。在进料量为 1.5 g-min-1、氮气流速为 1.1 L-min-1、热解温度为 450 °C 的适度条件下,有利于形成轻烃,而对于富含聚丙烯的混合物,则限制了蜡的形成。原生塑料热解产生的液体(最多 73.3 wt%)多于废塑料(最多 66 wt%)。将聚乙烯与聚丙烯混合有利于产生液体,并增加了汽油范围碳氢化合物的形成。气体产品主要由 C3 碳氢化合物组成,由于热解温度适中,没有检测到氢的产生。
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引用次数: 0
Petroleum pitch derived hard carbon via NaCl-template as anode materials with high rate performance for sodium ion battery 通过氯化钠模板提取的石油沥青硬碳作为钠离子电池的高倍率负极材料
IF 4.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-05-20 DOI: 10.1007/s11705-024-2430-4
Baoyu Wu, Hao Sun, Xiaoxue Li, Yinyi Gao, Tianzeng Bao, Hongbin Wu, Kai Zhu, Dianxue Cao

Sodium-ion batteries (SIBs) have garnered significant interest in energy storage due to their similar working mechanism to lithium ion batteries and abundant reserves of sodium resource. Exploring facile synthesis of a carbon-based anode materials with capable electrochemical performance is key to promoting the practical application of SIBs. In this work, a combination of petroleum pitch and recyclable sodium chloride is selected as the carbon source and template to obtain hard carbon (HC) anode for SIBs. Carbonization times and temperatures are optimized by assessing the sodium ion storage behavior of different HC materials. The optimized HC exhibits a remarkable capacity of over 430 mA·hg−1 after undergoing full activation through 500 cycles at a density of current of 0.1 A·g−1. Furthermore, it demonstrates an initial discharge capacity of 276 mAh·g−1 at a density of current of 0.5 A·g−1. Meanwhile, the optimized HC shows a good capacity retention (170 mAh·g−1 after 750 cycles) and a remarkable rate ability (166 mAh·g−1 at 2 A·g−1). The enhanced capacity is attributed to the suitable degree of graphitization and surface area, which improve the sodium ion transport and storage.

钠离子电池(SIB)因其与锂离子电池相似的工作机理和丰富的钠资源储量而在储能领域备受关注。探索具有良好电化学性能的碳基负极材料的简便合成方法是促进钠离子电池实际应用的关键。本研究选择石油沥青和可回收氯化钠作为碳源和模板,以获得用于 SIBs 的硬碳(HC)阳极。通过评估不同 HC 材料的钠离子存储行为,对碳化时间和温度进行了优化。在 0.1 A-g-1 的电流密度下,经过 500 个循环的完全活化后,优化后的 HC 显示出超过 430 mA-hg-1 的显著容量。此外,在 0.5 A-g-1 的电流密度下,它的初始放电容量为 276 mAh-g-1。同时,经过优化的 HC 显示出良好的容量保持能力(750 次循环后为 170 mAh-g-1)和显著的速率能力(2 A-g-1 时为 166 mAh-g-1)。容量的提高归功于适当的石墨化程度和表面积,它们改善了钠离子的传输和存储。
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引用次数: 0
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Frontiers of Chemical Science and Engineering
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