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Experimental Investigation on the Properties of Recycled Concrete Using Hybrid Fibers 混杂纤维再生混凝土性能的试验研究
Pub Date : 2019-04-16 DOI: 10.4236/OJCM.2019.92009
S. Khoso, J. Raad, A. Parvin
Due to the inherent property of concrete being very weak in tension, efforts have been made to overcome this deficiency by adding various type of fibers like carbon fiber reinforced polymer (CFRP), glass fiber reinforced polymer (GFRP), polypropylene fiber (PPF) and stainlesssteel fiber (SSF) smeared into the concrete mix. The present study involves experimental investigation on the use of GFRP, CFRP and SSF fibers alone or as combination to improve the mechanical properties of concrete. Furthermore, concrete cylinders were cast and tested for compression and tension using 10% fly ash as cement replacement in all specimens. Besides fiber material types, fiber reinforcement ratios of 1% and 1.5% were tested to investigate the mechanical properties of concrete. In all concrete cylinder tests, the fiber reinforcement ratio of 1% had a significant contribution in increasing the tensile strength as oppose to compressive strength. As a result, the tensile and compressive strengths were increased by 26% and 11%, respectively as compared to the control specimen. Increasing the fiber reinforcement ratio from 1% to 1.5%, resulted in diminishing the mechanical properties of concrete. However, reduction in concrete compressive strength was more prominent than the tensile strength. Furthermore, it was observed that, the crack propagation was decreased with the increase of fiber content when compared to the control specimen.
由于混凝土固有的抗拉性能非常弱,人们一直在努力克服这一缺点,在混凝土混合料中加入各种类型的纤维,如碳纤维增强聚合物(CFRP)、玻璃纤维增强聚合物(GFRP)、聚丙烯纤维(PPF)和不锈钢纤维(SSF)。本研究对GFRP、CFRP和SSF纤维单独使用或组合使用对混凝土力学性能的改善进行了试验研究。此外,浇筑混凝土柱,并在所有试件中使用10%粉煤灰替代水泥进行压缩和拉伸试验。除纤维材料类型外,还试验了1%和1.5%的纤维配筋率对混凝土力学性能的影响。在所有混凝土圆柱体试验中,1%的纤维配筋率对抗拉强度的提高贡献显著,而不是抗压强度的提高。结果,与对照试样相比,拉伸和抗压强度分别提高了26%和11%。纤维配筋率从1%增加到1.5%,导致混凝土力学性能下降。然而,混凝土抗压强度的降低比抗拉强度的降低更为突出。此外,与对照试样相比,随着纤维含量的增加,裂纹扩展减小。
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引用次数: 9
Transverse Impact Response Analysis of Graphene Panels: Impact Limits 石墨烯面板横向冲击响应分析:冲击极限
Pub Date : 2019-04-08 DOI: 10.4236/OJCM.2019.92006
Muhammed Burak Sonmez, H. Ghasemnejad, Hamad Kamran, P. Webb
Explicit numerical studies were conducted to determine the transverse impact response of graphene panels. Although the mechanical properties of graphene are well documented in both quasi-static and dynamic conditions via nano- and microscopic studies, the impact behaviour of the material at the macroscale has not yet been studied and would provide interesting and crucial insight in to the performance of the material on a more widely recognizable scale. Firstly, a numerical impact model was validated against an analytical impact model based on continuum mechanics which showed good correlation between contact-force histories. The performance of graphene panels subjected to impact was compared to the performance of panels composed of aerospace-grade aluminium and carbon fiber reinforced polymer (CFRP) composite. The graphene panel was found to exhibit lower specific energy than aluminium and CFRP at the low-energy range due to its inherently superior stiffness and intrinsic strength. On the other hand, the ballistic limit of 3 mm thick graphene panels was found to be 3375 m/s, resulting in an impact resistance 100 times greater than for aluminium or CFRP, making graphene the most suitable material for high-velocity impact protection.
进行了明确的数值研究,以确定石墨烯面板的横向冲击响应。尽管石墨烯的机械性能在准静态和动态条件下都通过纳米和微观研究得到了很好的证明,但该材料在宏观尺度上的冲击行为尚未得到研究,这将在更广泛的范围内为该材料的性能提供有趣和关键的见解。首先,将数值冲击模型与基于连续体力学的分析冲击模型进行了对比验证,该模型显示了接触力历史之间的良好相关性。将石墨烯面板在冲击下的性能与由航空级铝和碳纤维增强聚合物(CFRP)复合材料组成的面板的性能进行了比较。石墨烯板由于其固有的优越刚度和固有强度,在低能量范围内表现出比铝和CFRP更低的比能。另一方面,发现3mm厚石墨烯板的弹道极限为3375m/s,其抗冲击性是铝或CFRP的100倍,使石墨烯成为最适合高速冲击防护的材料。
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引用次数: 2
Performance Comparison of CVD Grown Carbon Nanofiber Based on Single- and Multi-Layer Graphene Oxides in Melt-Compounded PA6.6 Nanocomposites 熔融复合PA6.6纳米复合材料中单层和多层氧化石墨烯CVD生长纳米碳纤维的性能比较
Pub Date : 2019-04-01 DOI: 10.4236/OJCM.2019.92005
Elcin Cakal Sarac, L. Poudeh, J. Zanjani, I. Letofsky-Papst, F. Cebeci, I. Aydin, Y. Menceloğlu, B. S. Okan
In the present study, newly design hybrid nanostructures were produced by growing long carbon nanofibers (CNF) on single- and multi-layer graphene oxide (GO) sheets in the presence of catalyst by chemical vapor deposition (CVD). Chemical composition analysis indicated the formation of Fe-C bonds by the deposition of carbon atoms on catalyst surface of Fe2O3 and increasing in C/O atomic ratio confirming CNF growing. These hybrid additives were distributed homogeneously through polyamide 6.6 (PA6.6) chains by high shear thermokinetic mixer in melt phase. Spectroscopic studies showed that the differences in the number of graphene layer in hybrid structures directly affected the crystalline behavior and dispersion state in polymer matrix. Flexural strength and flexural modulus of PA6.6 nanocomposites were improved up to 14.7% and 14% by the integration of 0.5 wt% CNF grown on multi-layer GO, respectively, whereas there was a significant loss in flexural properties of single-layer GO based nanocomposites. Also, the integration of 0.5 wt% multi-layer GO hybrid reinforcement in PA6.6 provided a significant increase in tensile modulus about 24%. Therefore, multi-layer GO with CNF increased the degree of crystallinity in nanocomposites by forming intercalated structure and acted as a nucleating agent causing the improvement in mechanical properties.
在本研究中,在催化剂存在下,通过化学气相沉积(CVD)在单层和多层氧化石墨烯(GO)片上生长长碳纳米纤维(CNF),制备了新设计的杂化纳米结构。化学成分分析表明,通过碳原子在Fe2O3催化剂表面的沉积和C/O原子比的增加形成了Fe-C键,证实了CNF的生长。这些混合添加剂通过高剪切热动混合器在熔融相中均匀地分布在聚酰胺6.6(PA6.6)链中。光谱研究表明,杂化结构中石墨烯层数的差异直接影响聚合物基体中的结晶行为和分散状态。通过在多层GO上生长0.5wt%的CNF,PA6.6纳米复合材料的弯曲强度和弯曲模量分别提高了14.7%和14%,而单层GO基纳米复合材料在弯曲性能方面存在显著损失。此外,在PA6.6中集成0.5wt%的多层GO混合增强体提供了拉伸模量的显著增加约24%。因此,含有CNF的多层GO通过形成插层结构提高了纳米复合材料的结晶度,并作为成核剂提高了力学性能。
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引用次数: 5
Preparation of Fluoroalkyl End-Capped Oligomers/Hexagonal Boron Nitride Nanocomposites Possessing No Weight Loss Behavior in Nanocomposites Even after Calcination at 800°C 氟烷基端端低聚物/六方氮化硼纳米复合材料的制备,纳米复合材料在800℃煅烧后仍无失重行为
Pub Date : 2019-03-14 DOI: 10.4236/OJCM.2019.92004
Jittraporn Saengkaew, T. Ogasawara, Katsumi Yamashita, Suwadee Kongparakul, H. Sawada
Fluoroalkyl end-capped acrylic acid oligomer [RF-(ACA)n-RF]/hexagonal boron nitride (h-BN) nanocomposites [RF-(ACA)n-RF/h-BN] were prepared by reaction of the corresponding oligomer with h-BN nanoparticles (mean diameter: 50 nm) under non-catalytic or alkaline conditions, respectively. Fluoroalkyl end-capped N,N-dimethylacrylamide oligomer/h-BN nanocomposites [RF-(DMAA)n-RF/h-BN] were also obtained under similar conditions. It was demonstrated that RF-(ACA)n-RF/h-BN nanocomposites, which were prepared under alkaline conditions, afforded a clear weight loss in proportion to the contents of the oligomer in the composites after calcination at 800°C; however, the non-catalytic conditions enabled the RF-(ACA)n-RF/h-BN nanocomposite to give no weight loss behavior corresponding to the contents of the oligomer even after calcination. In fact, it was demonstrated that the RF-(ACA)n-RF/h-BN nanocomposites possessing a clear weight loss property could afford the fluorescent peak around 370 nm related to h-BN in the composites; however, the same fluorescent intensity of this nanocomposite after calcination at 800°C as that of the original h-BN was observed, indicating that this nanocomposite could give a clear weigh loss behavior corresponding to the content of the oligomer during the calcination process. In contrast, the RF-(ACA)n-RF/h-BN nanocomposites possessing no weigh loss behavior were found to exhibit the similar fluorescent intensity before and even after calcination at 800°C, suggesting that the corresponding nanocomposites could provide no weight loss ability corresponding to the contents of the oligomer in the composites even after calcination. Similarly, RF-(DMAA)n-RF/h-BN nanocomposites, which were prepared under non-catalytic or alkaline conditions, were found to provide no weight loss corresponding to the contents of the oligomer even after calcination, respectively. These fluorinated h-BN nanocomposites were applied to the surface modification of PMMA [poly(methyl methacrylate)] to exhibit an oleophobic property on the modified PMMA surface. RF-(ACA)n-RF/h-BN nanocomposites possessing a clear weight loss behavior, whose composites were calcinated at 800°C, afforded not oleophobic but oleophilic property on the modified PMMA surface, quite similar to that of the pristine PMMA film surface; however, more interestingly, we found that RF-(ACA)n-RF/ and RF-(DMAA)n-RF/h-BN nanocomposites possessing no weight loss characteristic, whose composites were calcined at 800°C, could supply a good oleophobic property related to the fluoroalkyl segments in the composites on the modified PMMA surfaces, respectively.
氟烷基封端丙烯酸低聚物[RF-(ACA)n-RF]/六方氮化硼(h-BN)纳米复合材料[RF-(ACA)n-RF/h-BN]分别通过相应的低聚物与h-BN纳米颗粒(平均直径:50nm)在非催化或碱性条件下反应制备。在类似的条件下也获得了氟烷基封端的N,N-二甲基丙烯酰胺低聚物/h-BN纳米复合物[RF-(DMAA)N-RF/h-BN]。研究表明,在碱性条件下制备的RF-(ACA)n-RF/h-BN纳米复合材料在800°C下煅烧后,其重量损失与复合材料中低聚物的含量成正比;然而,非催化条件使RF-(ACA)n-RF/h-BN纳米复合材料即使在煅烧后也不会产生与低聚物含量相对应的重量损失行为。事实上,研究表明,具有明显失重性能的RF-(ACA)n-RF/h-BN纳米复合材料可以在复合材料中产生与h-BN相关的370nm附近的荧光峰;然而,在800°C下煅烧后,观察到该纳米复合材料的荧光强度与原始h-BN的荧光强度相同,这表明该纳米复合物在煅烧过程中可以给出与低聚物含量相对应的明显失重行为。相反,发现不具有失重行为的RF-(ACA)n-RF/h-BN纳米复合材料在800°C煅烧前后表现出相似的荧光强度,这表明即使在煅烧后,相应的纳米复合材料也不能提供与复合材料中低聚物含量相对应的失重能力。类似地,发现在非催化或碱性条件下制备的RF-(DMAA)n-RF/h-BN纳米复合材料,即使在煅烧后,也不会分别提供与低聚物含量相对应的重量损失。将这些氟化h-BN纳米复合材料应用于PMMA[聚甲基丙烯酸甲酯]的表面改性,以在改性的PMMA表面上表现出疏油性能。RF-(ACA)n-RF/h-BN纳米复合材料具有明显的失重行为,其复合材料在800°C下煅烧,在改性的PMMA表面上表现出不疏油但亲油的性质,与原始PMMA膜表面非常相似;然而,更有趣的是,我们发现RF-(ACA)n-RF/和RF-(DMAA)n-RF/h-BN纳米复合材料不具有失重特性,其复合材料在800°C下煅烧,可以分别在改性PMMA表面上提供与复合材料中的氟烷基链段相关的良好疏油性能。
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引用次数: 2
Corrosion and Wear Behavior of Nano-Zirconium (Zr) Coated Commercial Grade Cast Iron by Sol-Gel and Plasma Spray Process 溶胶-凝胶-等离子喷涂纳米锆涂层商品级铸铁的腐蚀磨损行为
Pub Date : 2019-03-12 DOI: 10.4236/OJCM.2019.92003
J. Hemanth, Sara Sowjanya Steevenson
Hard facing with Nickel/cobalt based alloys for steel substrates are widely used for high temperature and pressure applications in chemically reactive environments due to their good corrosion and wear resistance properties. In the present research, the ceramic material, i.e., zirconium, is coated on a hypoeutectic cast iron substrate to improve its corrosion and wear resistance. The substrate was coated with zirconium by sol-gel process as well as by the plasma spray process for comparison purpose. Results of the research indicated that the successful deposition of zirconium on the cast iron substrate by sol-gel deposition technique had improved both corrosion and wear resistance of cast iron. SEM analysis revealed that the coating was denser without any internal cracks indicating the soundness of deposition. Also, sol-gel process of coating indicated better wear resistance as compared with plasma spray coated cast iron. Thus, zirconium coating on the substrate has made cast iron sound (without any surface defects) along with excellent corrosion and wear resistance properties. This has made cast iron suitable for structural and automotive applications.
由于具有良好的耐腐蚀性和耐磨性,钢基体的镍/钴基合金的硬表面广泛用于化学反应环境中的高温和高压应用。在本研究中,陶瓷材料,即锆涂层在亚共晶铸铁基体上,以提高其耐腐蚀和耐磨性。采用溶胶-凝胶法和等离子喷涂法对基材进行了锆涂层的制备。研究结果表明,溶胶-凝胶沉积技术成功地在铸铁基体上沉积锆,提高了铸铁的耐蚀性和耐磨性。扫描电镜分析表明,涂层致密,内部无裂纹,表明沉积良好。与等离子喷涂铸铁相比,溶胶-凝胶工艺的涂层具有更好的耐磨性。因此,在基体上涂上锆涂层使铸铁具有良好的声音(没有任何表面缺陷)以及优异的耐腐蚀和耐磨性。这使得铸铁适用于结构和汽车应用。
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引用次数: 2
Synthesis and Fabrication of Graphene and Graphene Oxide: A Review 石墨烯和氧化石墨烯的合成与制备综述
Pub Date : 2019-03-11 DOI: 10.4236/OJCM.2019.92012
A. Adetayo, Damilola O. Runsewe
The field of nanotechnology has advanced following the discovery of a two-dimensional material of sp2 hybridized carbon atoms, graphene in 2004 by Geim and Novoselov. Graphene has received so much attention due to its exceptional electronic, thermal, mechanical, and optical properties in addition to its large surface area and single-atom thickness. This has led to the discovery of several techniques to obtain graphene such as chemical exfoliation, chemical vapor deposition (CVD), chemical synthesis etc. However, these techniques are majorly challenged with developing graphene with fewer defects and in large scale; thus, there is an increasing need to produce graphene in large quantities with high quality. Several studies have been carried out to find routes to producing high-quality graphene. This paper focuses majorly on the synthesis and fabrication methods of producing graphene and its derivative, graphene oxide. Characterization techniques to identify graphene such as optical microscopy, scanning electron microscopy (SEM), Raman spectroscopy, scanning probe microscopy (SPM) used to determine number of layers, quality, atomic structures, and defects in graphene is also briefly discussed. This article also covers a short description of graphene applications in transparent electrodes, composites and energy storage devices.
2004年,Geim和Novoselov发现了sp2杂化碳原子的二维材料石墨烯后,纳米技术领域取得了进展。石墨烯除了具有较大的表面积和单原子厚度外,还具有特殊的电子、热、机械和光学性能,因此受到了广泛的关注。这导致了几种获得石墨烯的技术的发现,如化学剥落、化学气相沉积(CVD)、化学合成等。然而,这些技术面临的主要挑战是开发缺陷更少、规模更大的石墨烯;因此,越来越需要大量生产高质量的石墨烯。为了找到生产高质量石墨烯的途径,已经进行了几项研究。本文主要介绍了石墨烯及其衍生物氧化石墨烯的合成和制备方法。还简要讨论了用于鉴定石墨烯的表征技术,如光学显微镜,扫描电子显微镜(SEM),拉曼光谱,扫描探针显微镜(SPM),用于确定石墨烯的层数,质量,原子结构和缺陷。本文还简要介绍了石墨烯在透明电极、复合材料和储能器件中的应用。
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引用次数: 88
On the Thermal Fatigue of a Room-Cured Neat Epoxy and Its Composite 室温固化整洁环氧树脂及其复合材料的热疲劳研究
Pub Date : 2019-03-11 DOI: 10.4236/OJCM.2019.92007
M. Mohamed, Michel B. Johnson, F. Taheri
An experimental investigation is conducted to evaluate the potential degradation in the mechanical properties of an epoxy resin and unidirectional glass fiber-reinforced epoxy (GFRE) as a result of exposure to fluctuating temperature. A commonly used room-cured epoxy resin and the GFRE are subjected to various numbers of thermal cycles (up to 1000 heating/cooling cycles). Mechanical tests are conducted to examine the influence of thermal cycles on the stiffness, ultimate strength and strain of the resin and its GFRE. The Fourier transform-Raman spectroscopy (FT-Raman) is conducted to investigate the influence of the thermal cycles on the resulting chemical changes and curing degree of the resin. In addition, the Differential Scanning Calorimetry (DSC) analysis is conducted to investigate the variation in the glass transition temperature (Tg) of the resin as a function of the applied thermal cycles.
进行了一项实验研究,以评估环氧树脂和单向玻璃纤维增强环氧树脂(GFRE)的机械性能由于暴露于波动的温度而可能退化。常用的室内固化环氧树脂和GFRE经历不同数量的热循环(高达1000个加热/冷却循环)。进行了力学试验,以检验热循环对树脂及其GFRE的刚度、极限强度和应变的影响。进行傅立叶变换拉曼光谱(FT-Raman)以研究热循环对树脂的化学变化和固化程度的影响。此外,进行差示扫描量热法(DSC)分析,以研究树脂的玻璃化转变温度(Tg)随所施加的热循环的变化。
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引用次数: 4
Dynamic Modulus of Elasticity of Some Mortars Prepared from Selected Jordanian Masonry Cements 选用约旦砌体水泥制备砂浆的动态弹性模量
Pub Date : 2019-03-11 DOI: 10.4236/OJCM.2019.92011
H. Al-Baijat
In light of the highly demanding cement market in Jordan, comprehensive studies should be undertaken to investigate the properties of the different cement types. This paper studies the Dynamic modulus of elasticity (DME) at 2, 7 and 28 days in mortars using six cement Jordanian types with CaO contents less than that of the ordinary Portland cements. It was found that the DME has strong relation with compressive strength. At the age of 28 days the mortars had some different values of DME. One important result of our work is that DME at the age of 28 days can be derived from those of the two days mixes. To account for the differences in dynamic modulus of elasticity with time, it is highly recommended to study in detail the mortars petrography under the light microscope. Using the scanning electron microscope (SEM), usually with attachment for chemical analysis at the crystal scale, in addition to X-ray diffraction technique may help characterization of the cement phases qualitatively and quantitatively.
鉴于约旦的水泥市场需求量很大,应进行全面的研究,以调查不同类型水泥的特性。本文研究了CaO含量低于普通硅酸盐水泥的6种水泥约旦型砂浆在2、7和28天的动态弹性模量(DME)。结果表明,DME与抗压强度有较强的相关性。28日龄时,两种迫击炮的DME值有所不同。我们工作的一个重要结果是,28天龄的二甲醚可以从两天的混合物中提取出来。为了解释动态弹性模量随时间的差异,强烈建议在光镜下详细研究砂浆的岩石学。利用扫描电子显微镜(SEM),通常在晶体尺度上进行化学分析,除了x射线衍射技术外,还可以帮助定性和定量地表征水泥相。
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引用次数: 2
Towards Reliability-Enhanced Mechanical Characterization of Non-Crimp Fabrics: How to Compare Two Force-Displacement Curves against a Null Material Hypothesis 迈向无卷曲织物的可靠性增强力学特性:如何比较两种力-位移曲线与零材料假设
Pub Date : 2019-03-11 DOI: 10.4236/OJCM.2019.92008
S. Sultana, A. Rashidi, M. S. Islam, B. Crawford, A. Milani
Detailed characterization of fabric reinforcements is necessary to ensure the quality of manufactured composite parts, and subsequently to prevent structural failure during service. A lack of consensus and standardization exists in selecting test methods for the mechanical characterization of fabrics. Moreover, in reality, during any experimentation there are sources of uncertainties which may result in inconsistencies in the interpretation of data and the comparison of different testing methods. The aim of this article is to show how simple statistical data analysis methods may be used to enhance the characterization of composite fabrics under individual and combined loading modes while accounting for inherent material/test uncertainties. Results using a typical glass non-crimp fabric (NCF) show that, statistically, there are significant differences between the warp and weft direction responses of a presumably balanced NCF under all deformation modes, with weft yarns being generally stiffer. Moreover, the statistical significance of warp-weft couplings under both simultaneous and sequential biaxial-shear loading modes became statistically evident, when compared to a pure biaxial deformation.
织物增强材料的详细特性对于确保制造的复合材料零件的质量以及防止使用过程中的结构故障是必要的。在选择织物机械特性的测试方法方面缺乏共识和标准化。此外,事实上,在任何实验过程中,都存在不确定性来源,这可能导致数据解释和不同测试方法的比较不一致。本文的目的是展示如何使用简单的统计数据分析方法来增强复合织物在单独和组合载荷模式下的特性,同时考虑固有的材料/测试不确定性。使用典型的玻璃无卷曲织物(NCF)的结果表明,从统计上看,在所有变形模式下,假定平衡的NCF的经纱和纬纱方向响应之间存在显著差异,纬纱通常更硬。此外,与纯双轴变形相比,在同时和连续双轴剪切加载模式下,经纬耦合的统计显著性在统计学上变得明显。
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引用次数: 1
Erratum to “Improvement on Adhesion Properties of Insert Injection Molding Composites: Effect of Inserted Parts, Adhesive Lengths and Injection Conditions” [Open Journal of Composite Materials (2017) 197-206] “镶件注射成型复合材料粘接性能的改进:镶件、粘接长度和注射条件的影响”[复合材料开放杂志(2017)197-206]
Pub Date : 2019-03-11 DOI: 10.4236/OJCM.2019.92010
Badin Pinpathomrat, H. Hamada
The original online version of this article (Pinpathomrat, B. and Hamada, H. (2017) Improvement on Adhesion Properties of Insert Injection Molding Composites: Effect of Inserted Parts, Adhesive Lengths and Injection Conditions. Open Journal of Composite Materials, 7, 197-206. https://doi.org/10.4236/ojcm.2017.74013) unfortunately contains several mistakes in Figures 1-4, and Figure 6.
本文的原始在线版本(Pinpathomrat,B.和Hamada,H.(2017)《嵌件注塑复合材料粘合性能的改进:嵌件、粘合剂长度和注射条件的影响》。复合材料公开期刊,7197-206。https://doi.org/10.4236/ojcm.2017.74013)不幸的是,在图1-4和图6中包含了几个错误。
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引用次数: 0
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