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Elaboration and Characterization of a Hybrid Composite Material with Two Particles of the Same Size: Coco Shells and Palm Shells 椰子壳和棕榈壳两种大小相同颗粒的杂化复合材料的制备与表征
Pub Date : 2020-08-07 DOI: 10.4236/ojcm.2020.104006
Pierre Marcel Anicet Noah, E. F. Betene, Suzie Viviane Obame, Beassoum Allasra, Martin Christian Bindjeme, A. Atangana
This work aims to develop and characterize a hybrid composite material with two particles of the same size. As reinforcing particles, the hulls of palm nuts and coconut are chosen. Hybrid composite material composites in the form of specimens were produced by molding at 10%, 20% and 30% mass fractions in various sizes (0.63 mm, 1.25 mm and 2.5 mm). The samples were physically characterized (water absorption rate, moisture content, actual, theoretical and apparent density) and mechanical in 3-point flexion. The main results are: the highest and minimum water absorption rate are respectively 3.57% and 0.67% for respectively particle sizes 1.25 mm (sample P10C30) and 0.67% in the size of 0.63 mm (sample P10C10). The moisture content varies from 0.64 to 7.14% respectively for the P20C20 (2.5 mm) and P10C30 (2.5 mm) samples. The maximum and minimum real density are 1340,518 Kg/m3 and 1055.981 Kg/m3, for respectively the composites of particles sizes 1.25 mm (P20C10) and 0.63 mm (sample P20C20). The minimum real density is Its maximum theoretical density is 1194.949 Kg/m3 (for samples P20C10, P10C10 and P30C10); however, the minimum is 1189.966 Kg/m3 (P10C20 and P20C20). The bulk density varies from 933.28 Kg/m3 to 1176.1 Kg/m3, respectively, in sizes from 2.5 mm (P10C30) to 0.63 mm (for P10C30). As for the mechanical characteristics, the Modulus of Elasticity (MOE) varies from 25.664 GPa to 25.759 GPa, respectively, the samples P10C10 (1.25 mm) and P10C20 (2.5 mm). The MOE values describe a parabola whose peak is reached when the palm shell loads are 20%, that is to say P20C10, whatever the particle size distribution. In resilience, samples with small particles are more resilient with a maximum value of 22.49 J/cm2 and a minimum value of 4.45 J/cm2 to verify the principles of Hall-Petch’s law.
这项工作旨在开发和表征具有两个相同尺寸颗粒的混合复合材料。作为增强颗粒,选择了棕榈坚果和椰子的外壳。通过以10%、20%和30%的质量分数模制不同尺寸(0.63mm、1.25mm和2.5mm)的试样形式的混合复合材料复合材料来制备。对样品进行了物理表征(吸水率、含水量、实际密度、理论密度和表观密度)和三点弯曲时的力学性能。主要结果是:颗粒尺寸1.25mm(样品P10C30)的最高吸水率和最低吸水率分别为3.57%和0.67%,颗粒尺寸0.63mm(样品P10C10)的最高吸湿率和最低吸湿率分别为0.67%。P20C20(2.5 mm)和P10C30(2.5 mm。颗粒尺寸为1.25 mm(P20C10)和0.63 mm(样品P20C20)的复合材料的最大和最小实际密度分别为1340518 Kg/m3和1055.981 Kg/m3。最小实际密度为其最大理论密度为1194.949 Kg/m3(样品P20C10、P10C10和P30C10);但最小值为1189.966Kg/m3(P10C20和P20C20)。体积密度分别为933.28 Kg/m3至1176.1 Kg/m3,尺寸为2.5 mm(P10C30)至0.63 mm(P10C30)。至于力学特性,样品P10C10(1.25mm)和P10C20(2.5mm)的弹性模量(MOE)分别在25.664GPa到25.759GPa之间变化。MOE值描述了一条抛物线,其峰值在棕榈壳载荷为20%时达到,也就是说P20C10,无论颗粒尺寸分布如何。在回弹性方面,具有小颗粒的样品更具回弹性,最大值为22.49 J/cm2,最小值为4.45 J/cm2,以验证霍尔-佩奇定律的原理。
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引用次数: 2
Pyrolytic Recycling of Carbon Fibers from Prepregs and Their Use in Polyamide Composites 预浸料中碳纤维的热解回收及其在聚酰胺复合材料中的应用
Pub Date : 2020-08-07 DOI: 10.4236/ojcm.2020.104007
S. Schwarz, Thomas Höftberger, C. Burgstaller, A. Hackl, C. Schwarzinger
Carbon fibers composites are well-known as high tech materials but are also recognized as a problem after use as they have to be deposited in landfills. Pyrolysis is an attractive process for recycling carbon fibers from used composites as well as offcuts from prepregs. Pyrolysis of carbon fiber composite prepregs is carried out in a pilot plant with a single screw reactor. The pyrolysis products, carbon fibers and pyrolysis vapor are fully characterized. Variation of pyrolysis temperature is carried out to obtain carbon fibers with the best possible surface properties. In order to compare the mechanical properties of the recycled carbon fibers with virgin material, composite materials with polyamide are produced and their properties compared.
碳纤维复合材料是众所周知的高科技材料,但在使用后也被认为是一个问题,因为它们必须沉积在垃圾填埋场。热解是从用过的复合材料中回收碳纤维以及从预浸料中回收边角料的一种有吸引力的工艺。在单螺杆反应器的中试装置中进行了碳纤维复合材料预浸料的热解。对热解产物、碳纤维和热解蒸气进行了充分表征。改变热解温度以获得具有最佳表面性质的碳纤维。为了比较再生碳纤维和原材料的力学性能,制备了含有聚酰胺的复合材料,并对其性能进行了比较。
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引用次数: 10
Elaboration and Characterization of a Fiber Composite Material Made of Petioles of the Elaeis guineensis (Oil Palm) 油棕叶柄纤维复合材料的研制和表征
Pub Date : 2020-08-07 DOI: 10.4236/ojcm.2020.104008
Ze Eric Parfait, Tchotang Théodore, Souck Joseph Loic, Nfor Clins Wiryikfu, P. Joseph, Mpoung Léon Arnaud
The aim of this study is to characterize physically and mechanically a polyester/fiber palm petiole composite material. This work made it possible to provide the local database of composite materials but also to develop agricultural waste. According to BSI 2782 standard three formulations [A (10% fiber, 90% polyester); B (20% fiber, 80% polyester) and C (30% fiber, 70% polyester)]. Water Absorption rate, density, compressive and three points bending tests are carried out on the samples obtained by the contact molding method for each formulation. The material composite obtained by adding fibers from palm oil petiole has a density of 17.98% lower than the one made of pure polyester. Fiber reinforcement rate has no impact on the density of the composite. Formulation A most absorbs water while formulation C has good tensile/compression characteristics and the greatest breaking stress in bending among the three formulations.
本研究的目的是物理和机械表征聚酯/纤维棕榈叶柄复合材料。这项工作使提供复合材料的当地数据库成为可能,同时也使农业废弃物的开发成为可能。按BSI 2782标准三种配方[A](10%纤维,90%聚酯);B(20%纤维,80%聚酯)和C(30%纤维,70%聚酯)]。对各配方采用接触成型法得到的试样进行吸水率、密度、压缩和三点弯曲试验。添加棕榈油叶柄纤维制成的复合材料密度比纯聚酯低17.98%。纤维增强率对复合材料的密度没有影响。配方A吸水性最强,而配方C拉伸/压缩性能好,弯曲断裂应力最大。
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引用次数: 3
Mechanical Properties of Bio-Based Epoxy Composites Reinforced with Hybrid-Interlayer Ramie and Recycled Carbon Fibres 苎麻/再生碳纤维复合层间基环氧复合材料的力学性能
Pub Date : 2020-08-07 DOI: 10.4236/ojcm.2020.104009
Zhu Chenkai, Saihua Li, Cong Xiaoye, Liu Xiaoling
The growing environmental concerns have led to attention on bio-based composite materials, such as the natural fibres, recycled carbon fibres and bio-based resins. Herein, the bio-based epoxy composites were reinforced with ramie fibre (RF) and recycled carbon fibre (rCF) via inter-layer hybridisation. The dynamic mechanical analysis, tensile, flexural and impact properties characterisation were conducted to analyse the mechanical behaviour of the specimens. Also, the morphology of fractured surface after mechanical tests was studied under a scanning electron microscope. When the volume ratio between RF and rCF was varied from 100/0 to 0/100, the flexural and tensile strength of composites was significantly increased, while the impact strength was reduced. Thus the maximum values of flexural strength (182 MPa) and tensile strength (165 MPa) were observed for rCF reinforced composite, whilst impact strength of 24 kJ/m2 was found for RF reinforced composite. Furthermore, the values of storage and loss modulus were increased with the rCF incorporation due to a greater degree of restriction with the addition of rCF into the matrix. The hybridisation was able to combine the specific properties of RF and rCF and optimise the mechanical performance of composites. Therefore, the alternative low-cost green composites are prepared which can replace synthetic materials for semi-structural applications.
日益增长的环境问题引起了人们对生物基复合材料的关注,如天然纤维、再生碳纤维和生物基树脂。在此基础上,采用苎麻纤维(RF)和再生碳纤维(rCF)通过层间杂化的方法增强生物基环氧复合材料。进行了动态力学分析、拉伸、弯曲和冲击性能表征,分析了试件的力学行为。并在扫描电镜下对力学试验后的断口形貌进行了研究。当RF与rCF的体积比在100/0 ~ 0/100范围内变化时,复合材料的抗折强度和抗拉强度显著提高,冲击强度降低。因此,rCF增强复合材料的抗折强度最大值为182 MPa,抗拉强度最大值为165 MPa,而RF增强复合材料的冲击强度为24 kJ/m2。此外,随着rCF的加入,由于rCF对基体的限制程度更大,存储模量和损耗模量的值随着rCF的加入而增加。混合能够结合RF和rCF的特定性能,并优化复合材料的机械性能。因此,制备可替代合成材料的低成本绿色复合材料用于半结构应用。
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引用次数: 4
Development of a Composite Material Based on Wood Waste Stabilized with Recycled Expanded Polystyrene 再生膨胀聚苯乙烯稳定废木材复合材料的研制
Pub Date : 2020-06-18 DOI: 10.4236/ojcm.2020.103005
Serge Pacome Kaho, K. C. Kouadio, C. H. Kouakou, E. Eméruwa
Environmental pollution is a whole world concern. One of the causes of that pollution is the proliferation of plastic waste. Among these wastes there is expanded polystyrene (EPS), mainly from packaging. This study aims to valorize EPS waste by developing a composite material from EPS waste and wood waste. For this purpose, a resin made of EPS has been elaborated by dissolving EPS in acetone. That resin was used as a binder in volume proportions of 15%, 20%, 25% and 30% to stabilize the samples. Some of them were thermoformed. The method of elaboration was based on a device consisting of an extruder for mixing the constituents, and a manual press for shaping and compacting the samples. Analyses show that the drying time depends on the composition of the mixture. Increasing the resin content leads to reduce water absorption and porosity of the samples; it also contributes to homogenize the internal structure of the samples. However, for the same resin contents, the thermoformed samples are less porous; they have more homogeneous internal structure; and absorb less water than non-thermoformed samples.
环境污染是全世界关注的问题。造成这种污染的原因之一是塑料垃圾的扩散。在这些废物中,有膨胀聚苯乙烯(EPS),主要来自包装。本研究旨在利用EPS废弃物和木材废弃物开发复合材料,实现EPS废弃物的资源化利用。为此,通过将EPS溶解于丙酮中制备了EPS树脂。该树脂被用作粘合剂,体积比例分别为15%、20%、25%和30%,以稳定样品。有些是热成型的。阐述的方法是基于一个装置组成的挤出机混合的成分,和一个手动压力机塑造和压实的样品。分析表明,干燥时间取决于混合料的组成。树脂含量的增加导致样品的吸水率和孔隙率降低;它还有助于均匀化样品的内部结构。然而,对于相同的树脂含量,热成型样品的多孔性较小;它们有更均匀的内部结构;并且比非热成型样品吸收更少的水。
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引用次数: 7
Exploring the Potential to Uniquely Manufacture Curved VARTM Epoxy Composites Using Cost-Effective FDM Molds 探索使用具有成本效益的FDM模具独特制造弯曲VARTM环氧复合材料的潜力
Pub Date : 2020-06-18 DOI: 10.4236/ojcm.2020.103004
S.M.R. Kazmi, J. Schuster, Johannes Lutz
The Resin Infusion or the VARTM (Vacuum Assisted Resin Transfer Molding) process has significant potential to be used to manufacture curved composites. Another way to produce curved or complex geometry is to use 3D printers. 3D or FDM (Fused Deposition Modelling) printers are now being used to produce relatively cheaper curved parts using thermoplastics such as PLA. However, the strength and mechanical performance of these parts is limited and can be enhanced if the polymer is reinforced with a type of fiber for instance. Research is being carried out to produce fiber rein-forced thermoplastic composites but that process is expected to be more expensive than the alternative methods such as injection or compression molding. Furthermore, to understand the manufacture of a hybrid composite using thermoplastics, fibers and epoxy resin, research and investigation need to be carried out. In this research, there are single-sided, double-sided, reusable, disposable and consumable molds. Most of the molds were created either using an FDM printer or manually. These molds were then used to manufacture flat and curved composite structures via the resin injection process, i.e. VARTM with epoxy resin system and glass/carbon/flax fiber reinforcement. By replacing the costly metallic molds by significantly cheaper molds, the cost of production was expected to further reduce. Furthermore, using double-sided PLA molds was not expected to be a threat to the overall cost of the composite part in question compared to double-sided matched molds used in compression molding. Shear strength, tensile strength and charpy impact strength of most of the manufactured composite parts were also investigated. The strengths were compared based on the method of mold usage. The results showed that this method is effective for a cheaper production of curved epoxy resin composites. However, the strength of the part will decrease as the curved profile gets more complicated unless the basic resin infusion process is altered.
树脂注入或VARTM(真空辅助树脂转移成型)工艺在制造弯曲复合材料方面具有巨大的潜力。生成弯曲或复杂几何图形的另一种方法是使用3D打印机。3D或FDM(熔融沉积建模)打印机现在被用于使用热塑性塑料(如PLA)生产相对便宜的弯曲零件。然而,这些部件的强度和机械性能是有限的,并且如果用例如一种类型的纤维增强聚合物,则可以增强这些部件。目前正在进行生产纤维增强热塑性复合材料的研究,但预计该工艺比注射或压缩成型等替代方法更昂贵。此外,为了理解使用热塑性塑料、纤维和环氧树脂制造混合复合材料,需要进行研究和调查。在这项研究中,有单面、双面、可重复使用、一次性和耗材模具。大多数模具都是使用FDM打印机或手动创建的。然后,这些模具通过树脂注射工艺用于制造扁平和弯曲的复合材料结构,即具有环氧树脂系统和玻璃/碳/亚麻纤维增强的VARTM。通过用更便宜的模具取代昂贵的金属模具,预计生产成本将进一步降低。此外,与压缩成型中使用的双面匹配模具相比,使用双面PLA模具预计不会对所述复合材料部件的总体成本构成威胁。研究了大部分复合材料零件的剪切强度、拉伸强度和夏比冲击强度。根据模具使用方法对强度进行了比较。结果表明,该方法是一种生产弯曲环氧树脂复合材料的有效方法。然而,除非改变基本的树脂注入过程,否则随着弯曲轮廓变得更加复杂,零件的强度将降低。
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引用次数: 3
The Reinforcing Effect of Graphene on the Mechanical Properties of Carbon-Epoxy Composites 石墨烯对碳-环氧复合材料力学性能的增强作用
Pub Date : 2020-04-06 DOI: 10.4236/ojcm.2020.102003
H. Shivakumar, N. Renukappa, K. Shivakumar, B. Suresha
Graphene nanoplatelets (GNPs) are novel nanofillers holding attractive characteristics, including vigorous compatibility with majority polymers, outstanding mechanical, thermal, and electrical properties. In this study, the outstanding GNPs filler was reinforced to the epoxy matrix and carbon fabric/epoxy hybrid composite slabs to enrich their mechanical properties. Graphene nanoplatelets of 0.5, 1, 1.5 and 2 weight percentages were integrated into the epoxy and the physico-mechanical (microstructure, density, tensile, flexural and impact strength) properties were investigated. Furthermore, the mechanical properties of unfilled and 1 wt% GNPs filled carbon fabric/epoxy hybrid composite slabs were investigated. Subsequently, noteworthy improvement in the mechanical properties was conquered for the carbon fabric/epoxy hybrid composites.
石墨烯纳米片(GNP)是一种新型的纳米填料,具有吸引人的特性,包括与大多数聚合物的强烈兼容性、优异的机械、热和电学性能。在本研究中,将杰出的GNPs填料增强到环氧树脂基体和碳纤维织物/环氧树脂混合复合板上,以丰富其力学性能。将0.5、1、1.5和2重量百分比的石墨烯纳米片整合到环氧树脂中,并研究了其物理力学(微观结构、密度、拉伸、弯曲和冲击强度)性能。此外,还研究了未填充和1wt%GNP填充的碳纤维织物/环氧杂化复合材料板的力学性能。随后,碳织物/环氧树脂杂化复合材料的力学性能得到了显著改善。
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引用次数: 14
Deriving Tensile Properties of Glass Fiber Reinforced Polymers (GFRP) Using Mechanics of Composite Materials 用复合材料力学推导玻璃纤维增强聚合物(GFRP)的拉伸性能
Pub Date : 2020-01-01 DOI: 10.4236/ojcm.2020.101001
Thomas I. Altanopoulos, I. G. Raftoyiannis
This work addresses the tensile properties of glass fiber reinforced polymers (GFRP) and investigates the different ways of estimating them without the cost associated with experimentation. This attempt is achieved through comparison between experimental results, derived in accordance with the ASTM standards, and results obtained using the mechanics of composite materials. The experimental results are also compared to results derived from work by other researchers in order to corroborate the findings regarding the correlation of tensile properties of the GFRP material and the fiber volume fraction.
这项工作解决了玻璃纤维增强聚合物(GFRP)的拉伸性能,并研究了估算它们的不同方法,而无需与实验相关的成本。这一尝试是通过将根据ASTM标准导出的实验结果与利用复合材料力学得到的结果进行比较来实现的。实验结果还与其他研究人员的工作结果进行了比较,以证实关于GFRP材料的拉伸性能与纤维体积分数的相关性的发现。
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引用次数: 3
Effect of Wood Waste on Acoustic and Magnetic Properties of Composite Bricks and Correlation between Sound Velocity and Magnetic Induction in These Bricks 废木材对复合砖声磁性能的影响及复合砖中声速与磁感应强度的关系
Pub Date : 2020-01-01 DOI: 10.4236/ojcm.2020.101002
G. Ganga, A. K. Manounou, N. Malanda, M. D. Gadet, T. Nsongo
In the present study, kambala (botanical name: Chlorophora excelsa and Chlorophora regia) wood wastes were incorporated into stabilized earth bricks in order to test their acoustic insulation capacity of the walls; leading to better waste management from the timber industry. Two methods have been applied to determine the influence of the wood waste content in the stabilized earth bricks, on the weakening of the level of noise reception coming from the environmental medium, in an apartment built with composite bricks (earth + wood chips + cement). This influence has also been analyzed on the magnetic field induced by these bricks. The results showed that the level of sound reception through these bricks decreases with increasing wood waste content regardless of the method used (from 110 dB to 68 dB, respectively for Φb = 0% and Φb = 8%). The kambala wood waste in cement-stabilized clay bricks induces a magnetic field that increases with the wood waste content; the high contents of the wood chips causing an increase in the magnetic permeability of the composite medium. The correlation between the noise level and the magnetic field of the bricks shows that the noise level declines with increasing magnetic induction of the bricks.
在本研究中,为了测试稳定土砖墙体的隔声能力,将木渣加入稳定土砖中;从而更好地管理木材工业的废物。采用两种方法来确定稳定土砖中木材废料含量对环境介质噪声接收水平减弱的影响,在一个由复合砖(土+木屑+水泥)建造的公寓中。并分析了这种影响对这些砖所产生的磁场的影响。结果表明,无论使用哪种方法,通过这些砖的声音接收水平都随着木材废料含量的增加而降低(分别从110 dB到68 dB, Φb = 0%和Φb = 8%)。水泥稳定粘土砖中的坎巴拉废木产生的磁场随废木含量的增加而增大;木屑的高含量导致复合介质的磁导率增加。噪声水平与砖体磁场的相关关系表明,随着砖体磁感应强度的增大,噪声水平降低。
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引用次数: 0
Mechanical Properties of Submicron Glass Fiber Reinforced Vinyl Ester Composite 亚微米玻璃纤维增强乙烯基酯复合材料的力学性能
Pub Date : 2019-10-12 DOI: 10.4236/ojcm.2019.94023
N. T. Nhàn, K. Obunai, K. Okubo, O. Shibata, H. Tomokuni, Y. Fujita
Vinyl ester (VE) resin inherently has intrinsic brittleness due to its high cross-link density. To improve mechanical performance, micro/nano fillers are widely used to modify this matrix. In present study, glass fiber in submicron scale at low contents was added into VE to prepare submicron composite (sMC). The impact resistance of un-notched sMC degraded with the increase of sGF content while that of notched-sMC remained the unchanged. Flexural properties of sMCs also were the same with that of neat resin. The results of Dynamic mechanical analysis (DMA) test showed the slight increase of storage modulus and the decrease of tan delta value in the case of sMC compared to those of un-filled matrix. However, the Mode I fracture toughness of sMC improved up to 26% and 61% corresponding to 0.3 and 0.6 wt% glass fiber used. The compact tension sample test suggests that there is the delay of crack propagation under tensile cyclic load in resin reinforced by submicron glass fiber. The number of failure cycle enlarged proportionally with the increment of sGF content in matrix.
乙烯基酯(VE)树脂由于其高交联密度而固有地具有脆性。为了提高力学性能,微/纳米填料被广泛用于改性该基体。本研究将低含量的亚微米级玻璃纤维加入到VE中制备亚微米复合材料(sMC)。无缺口sMC的抗冲击性随着sGF含量的增加而降低,而缺口sMC保持不变。sMCs的弯曲性能也与纯树脂相同。动态力学分析(DMA)测试结果表明,与未填充基体相比,sMC的储能模量略有增加,tanδ值有所下降。然而,与使用的0.3和0.6wt%的玻璃纤维相对应,sMC的I型断裂韧性提高了26%和61%。致密拉伸试样试验表明,亚微米玻璃纤维增强树脂在拉伸循环载荷作用下存在裂纹扩展延迟。失效循环次数随基体中sGF含量的增加而成比例增大。
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引用次数: 2
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