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Electronic Transport in Alloys with Phase Separation (Composites) 相分离合金中的电子输运(复合材料)
Pub Date : 2019-01-28 DOI: 10.4236/ojcm.2019.91002
J. Sonntag, B. Lenoir, P. Ziółkowski
A measure for the efficiency of a thermoelectric material is the figure of merit defined by ZT = S2T/ρκ, where S, ρ and κ are the electronic transport coefficients, Seebeck coefficient, electrical resistivity and thermal conductiviy, respectively. T is the absolute temperature. Large values for ZT have been realized in nanostructured materials such as superlattices, quantum dots, nanocomposites, and nanowires. In order to achieve further progress, (1) a fundamental understanding of the carrier transport in nanocomposites is necessary, and (2) effective experimental methods for designing, producing and measuring new material compositions with nanocomposite-structures are to be applied. During the last decades, a series of formulas has been derived for calculation of the electronic transport coefficients in composites and disordered alloys. Along the way, some puzzling phenomenons have been solved as why there are simple metals with positive thermopower? and what is the reason for the phenomenon of the “Giant Hall effect”? and what is the reason for the fact that amorphous composites can exist at all? In the present review article, (1), formulas will be presented for calculation of σ = (-1/ρ), κ, S, and R in composites. R, the Hall coefficient, provides additional informations about the type of the dominant electronic carriers and their densities. It will be shown that these formulas can also be applied successfully for calculation of S, ρ, κ and R in nanocomposites if certain conditions are taken into account. Regarding point (2) we shall show that the combinatorial development of materials can provide unfeasible results if applied noncritically.
热电材料效率的衡量标准是ZT=S2T/ρκ定义的品质因数,其中S、ρ和κ分别是电子输运系数、塞贝克系数、电阻率和热导率。T是绝对温度。ZT在超晶格、量子点、纳米复合材料和纳米线等纳米结构材料中已经实现了较大的值。为了取得进一步的进展,(1)有必要对纳米复合材料中的载流子输运有基本的了解,(2)需要应用有效的实验方法来设计、生产和测量具有纳米复合结构的新材料组合物。在过去的几十年里,人们推导了一系列计算复合材料和无序合金中电子输运系数的公式。一路上,一些令人困惑的现象得到了解决,比如为什么会有简单的金属具有正的热电能?产生“巨霍尔效应”的原因是什么?非晶态复合材料可以存在的原因是什么?在本综述文章(1)中,将给出复合材料中σ=(-1/ρ)、κ、S和R的计算公式。R、 霍尔系数提供了关于主要电子载流子的类型及其密度的附加信息。结果表明,如果考虑到某些条件,这些公式也可以成功地应用于纳米复合材料中S、ρ、κ和R的计算。关于第(2)点,我们将证明,如果非关键性地应用,材料的组合开发可以提供不可行的结果。
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引用次数: 2
Influence of Water Ageing on Mechanical Properties of CaCO3 Filler Filled Epoxy Resin and Sansevieria/Carbon Fiber Reinforced Composites 水老化对CaCO3填充环氧树脂和Sansevieria/碳纤维增强复合材料力学性能的影响
Pub Date : 2019-01-18 DOI: 10.4236/ojcm.2019.91001
N. Anjum, B. Suresha, S. A. Prasad
The present paper studies water absorption behavior and its consequence on mechanical properties of untreated and chemically treated Sansevieria /carbon fiber reinforced hybrid epoxy (Sria/CF-Ep) composite with calcium carbonate (CaCO3) nanoparticles. Sansevieria /carbon fiber (30/5 wt%) reinforced hybrid epoxy composite with 1.5, 3 and 4.5 wt% of CaCO3 have been developed by hand lay-up method followed by heat press. The water absorption characteristics of the Sria fibers were obtained by immersing the composite samples in sea water at room temperature, until reaching their water content saturation level. The dry and water-immersed hybrid composite samples were subjected to hardness, interlaminar shear, tensile, flexural, and impact tests. The water absorption development of hybrid composites was found to follow Fickian diffusion behavior. Diffusion coefficients and maximum water uptake results were evaluated; the outcome showed that both increased with an increase in filler loading to study the consequence of water penetration in the fiber/matrix interface. The study shows that the mechanical and water-resistant properties of the Sria were improved through chemical treatment and hybridization. Nevertheless, as a result of water penetrating the fiber/matrix interface, longer water-immersion times reduced the tensile and flexural strength of the composites.
本文研究了未经处理和化学处理的Sansevieria/碳纤维增强复合环氧树脂(Sria/CF-Ep)与碳酸钙(CaCO3)纳米颗粒的吸水行为及其对力学性能的影响。采用手铺法和热压法制备了CaCO3含量分别为1.5、3和4.5wt%的Sanseveria/碳纤维(30/5wt%)增强混杂环氧树脂复合材料。Sria纤维的吸水特性是通过在室温下将复合材料样品浸入海水中,直到达到其含水量饱和水平来获得的。对干式和浸水混合复合材料样品进行了硬度、层间剪切、拉伸、弯曲和冲击试验。发现杂化复合材料的吸水发展遵循菲克扩散行为。对扩散系数和最大吸水率结果进行了评估;结果表明,两者都随着填料负载的增加而增加,以研究水在纤维/基体界面中渗透的后果。研究表明,通过化学处理和杂交,Sria的力学性能和耐水性能得到了改善。然而,由于水渗透纤维/基体界面,较长的浸水时间降低了复合材料的拉伸和弯曲强度。
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引用次数: 7
Compressive and Flexural Strengths of Cement Stabilized Earth Bricks Reinforced with Treated and Untreated Pineapple Leaves Fibres 经处理和未经处理的菠萝叶纤维增强水泥稳定土砖的抗压和抗弯强度
Pub Date : 2018-10-30 DOI: 10.4236/OJCM.2018.84012
Nounagnon A. Vodounon, C. Kanali, J. Mwero
This study compares the effect of treated pineapple leaves fibres (T-PALF) with sodium hydroxide solution and untreated fibres (N-PALF) on the compressive and flexural strength of earth bricks stabilized with 3% and 5% cement. The fibre content ranged from 0% to 5% in steps of 1% by weight. The compressive strength tests were made at 7, 14, 21 and 28 days of curing; the flexural strength test were conducted at 28th day only. The results show that the T-PALF had a higher compressive strength when comparing to the N-PALF. The highest compressive strength of the bricks was obtained at 28 days of curing. The compressive strength at 28 days of stabilized brick at 3% and 5% of cement reinforced with T-PALF were 4.01 and 4.81 MPa, respectively, while the one reinforced with N-PALF was 3.19 and 4.63 MPa, respectively. The results further show that the highest flexural strength of both stabilized bricks at 3% and 5% of cement reinforced with T-PALF and N-PALF was obtained with the bricks stabilized with 5% of cement reinforced with T-PALF. This results show that bricks stabilized with 5% cement and reinforced with 3% of treated fibres content are good for construction of load bearing walls. It was observed; a significant improvement of the reinforced blocks under flexure than under compression.
本研究比较了经氢氧化钠溶液处理的菠萝叶纤维(T-PALF)和未经处理的纤维(N-PALF)对用3%和5%水泥稳定的土砖抗压和抗弯强度的影响。纤维含量在0%至5%的范围内,以1重量%为步长。抗压强度测试在固化的第7、14、21和28天进行;仅在第28天进行弯曲强度试验。结果表明,与N-PALF相比,T-PALF具有更高的抗压强度。砖的最高抗压强度是在固化28天时获得的。T-PALF加固的稳定砖在水泥用量为3%和5%时28天的抗压强度分别为4.01和4.81MPa,而N-PALF加固时的抗压强度则分别为3.19和4.63MPa。结果进一步表明,用T-PALF和N-PALF加固的3%和5%水泥的稳定砖的抗弯强度最高,而用T-PAFF加固的5%水泥稳定砖的弯曲强度最高。结果表明,用5%水泥稳定并用3%处理过的纤维加固的砖有利于承重墙的施工。观察到;弯曲下的增强块比压缩下的显著改善。
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引用次数: 14
Function-Integrative Textile Reinforced Concrete Shells 功能一体化纺织钢筋混凝土壳体
Pub Date : 2018-10-30 DOI: 10.4236/ojcm.2018.84013
S. Gelbrich, H. Funke, L. Kroll
This paper presents the development and technological implementation of textile reinforced concrete (TRC) shells with integrated functions, such as illumination and light control. In that regard the establishment of material, structural and technological foundations along the entire value chain are of central importance: From the light-weight design idea to the demonstrator and reference object, to the technological implementation for the transfer of the research results into practice. The development of the material included the requirement-oriented composition of a high-strength fine grained concrete with an integrated textile reinforcement, such as carbon knitted fabrics. Innovations in formwork solutions provide new possibilities for concrete constructions. So, a bionic optimized shape of the pavilion was developed, realized by four connected TRC-lightweight-shells. The thin-walled TRC-shells were manufactured with a formwork made of glass-fibre reinforced polymer (GFRP). An advantage of the GFRP-formwork is the freedom of design concerning the formwork shape. Moreover, an excellent concrete quality can be achieved, while the production of the precast concrete components is simple and efficient simultaneously. After the production the new TRC-shells were installed and assembled on the campus of TU-Chemnitz. A special feature of the research pavilions are the LED light strips integrated in the shell elements, providing homogeneous illumination.
本文介绍了集照明和光控制为一体的纺织钢筋混凝土(TRC)壳体的开发与技术实现。在这方面,沿着整个价值链建立材料、结构和技术基础是至关重要的:从轻量化设计理念到演示和参考对象,再到将研究成果转化为实践的技术实施。材料的开发包括以需求为导向的高强度细粒混凝土组合物,以及集成的纺织增强物,如碳针织织物。模板解决方案的创新为混凝土结构提供了新的可能性。因此,展馆的仿生优化形状被开发出来,由四个连接的trc轻质外壳实现。薄壁trc壳由玻璃纤维增强聚合物(GFRP)制成的模板制造。gfrp模板的一个优点是模板形状的设计自由。在预制混凝土构件生产简单、高效的同时,可获得优异的混凝土质量。在生产之后,新的trc炮弹被安装并组装在TU-Chemnitz校园。研究馆的一个特点是集成在外壳元素中的LED灯条,提供均匀的照明。
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引用次数: 1
Evaluation of Sawdust and Rice Husks as Fillers for Phenolic Resin Based Wood-Polymer Composites 木屑和稻壳作为酚醛树脂基木聚合物复合材料填料的性能评价
Pub Date : 2018-07-27 DOI: 10.4236/OJCM.2018.83010
Marieme Josephine Lette, El Hadji Babacar Ly, Diène Ndiaye, A. Takasaki, T. Okabe
We produced Wood-Polymer Composites (WPCs) with phenolic resin (PR) filled with saw dust (SD) and rice husks (RH) in a PR:fillerratio of 60:40 wt.%. RH and SD were grinded and sieved into particles <160 μm. The aim of this research work was to evaluate sawdust and rice husks as fillers for sustainable phenolic resin based WPCs. Therefore, we investigated the thermal stability of PR/RH and PR/SD WPCs then we studied and compared the tensile, flexural properties of PR/SD and PR/RH WPCs samples, as well as their dimensional stability after water absorption test. Furthermore, through ultraviolet light exposure, we evaluated the effects of photo-oxidation on the water stability and mechanical properties of PR/RH and PR/SD WPCs samples compared to unexposed ones. PR filled with SD presented better mechanical properties compared to PR/RH WPCs samples. However, PR/RH WPCs showed good mechanical properties, and better thermal resistance and better water repulsion capabilities compared to PR/SD WPCs samples. Although, long time UV exposure ended up lowering considerably the mechanical properties and water resistance of PR/SD and PR/RH WPCs, both RH and SD offer great added value as fillers for PR based WPCs; SD having better interactions with PR matrix compared to RH.
我们用酚醛树脂(PR)填充木屑(SD)和稻壳(RH),以60:40wt.%的PR:填充比例生产木材聚合物复合材料(WPC)。将RH和SD研磨并筛成<160μm的颗粒。本研究工作的目的是评估木屑和稻壳作为可持续酚醛树脂基WPC的填料。因此,我们研究了PR/RH和PR/SD WPCs的热稳定性,然后研究并比较了PR/SD和PR/RH WPCs样品的拉伸、弯曲性能,以及它们在吸水试验后的尺寸稳定性。此外,通过紫外线暴露,我们评估了光氧化对PR/RH和PR/SD WPCs样品的水稳定性和机械性能的影响,与未暴露的样品相比。与PR/RH WPC样品相比,用SD填充的PR表现出更好的机械性能。然而,与PR/SD WPCs样品相比,PR/RH WPCs表现出良好的机械性能、更好的热阻和更好的斥水能力。尽管长时间紫外线暴露最终显著降低了PR/SD和PR/RH WPC的机械性能和耐水性,但RH和SD作为PR基WPC的填料都具有很大的附加值;与RH相比,SD与PR基质具有更好的相互作用。
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引用次数: 11
Laminate Tailoring of Composite Tubular Structures to Improve Crashworthiness Design at Off-Axis Loading 复合材料管状结构层合裁剪提高离轴载荷下耐撞性设计
Pub Date : 2018-07-10 DOI: 10.4236/ojcm.2018.83008
A. Rabiee, H. Ghasemnejad
This paper presents experimental and numerical investigation on the parameters effecting energy absorption capability of composite tubular structures at oblique loading to improve crashworthiness performance. Various inclined angles of 5°, 10°, 20° and 30° were selected for the study of off-axis loading. The results indicate that by increasing the lateral inclination angle the mean crushing force and also energy absorption capability of all tested sections decreased. From design perspective, it is necessary to investigate the parameters effecting this phenomenon. The off-axis loading effect that causes significant reduction in energy absorption was investigated and the effected parameters were improved to increase energy absorption capability. To establish this study, 10° off-axis loading was chosen to illustrate the obtained improvement in energy absorption capability. Five cases were studied with combinations of ply-orientation and flat trimming with 45° chamfer. This method was applied to the integrated 10° off-axis loading and the final results showed significant improvement in energy absorption capability of composite absorbers. Finite element model (FEM) was developed to simulate the crushing process of axial and off-axis composite section in LS-DYNA and the results were in good agreement with the experimental data.
本文对影响复合材料管状结构在斜向载荷下吸能性能的参数进行了实验和数值研究,以提高其耐撞性能。选择5°、10°、20°和30°的不同倾角来研究离轴载荷。结果表明,随着横向倾角的增大,所有试验断面的平均压碎力和能量吸收能力都有所下降。从设计的角度来看,有必要研究影响这种现象的参数。研究了导致能量吸收显著降低的离轴加载效应,并改进了受影响的参数以提高能量吸收能力。为了建立这项研究,选择了10°离轴载荷来说明能量吸收能力的提高。研究了5个案例,这些案例结合了帘布层方向和45°倒角的平面修剪。将该方法应用于10°离轴综合加载,结果表明复合材料吸收器的能量吸收能力显著提高。建立了有限元模型(FEM),模拟了LS-DYNA中轴向和离轴复合材料截面的破碎过程,结果与实验数据吻合较好。
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引用次数: 7
Fabrication of Manila Hemp Fiber Reinforced Cross Ply Biodegradable Composites and Their Tensile Properties 马尼拉大麻纤维增强交联生物降解复合材料的制备及其拉伸性能
Pub Date : 2018-07-02 DOI: 10.4236/ojcm.2018.83007
S. Ochi
Natural plant fibers, including flax, kenaf, jute, bamboo, ramie and much more are renewable and sustainable resources and are considered good candidates for cost-effective alternatives to glass and carbon fibers. In this research, cross ply biodegradable composites were fabricated by press-forming method. The biodegradable composites consist of Manila hemp textile as a reinforcement and starch-based biodegradable plastics as a matrix was fabricated and investigated about mechanical properties. The tensile strength increased with the fiber content until fiber content of about 50% and leveled off thereafter. This dependence on the fiber content is due to the decrease in fiber strength of loading direction caused by fiber damages introduced during hot-pressing. In order to decrease the damage of fibers aligned in loading direction, Manila hemp textile was produced by using Manila hemp fibers for warp and biodegradable resin thread for weft. As a result, the tensile strength of cross ply composites increased from 153 MPa to 202 MPa.
天然植物纤维,包括亚麻、红麻、黄麻、竹子、苎麻等,是可再生和可持续的资源,被认为是玻璃纤维和碳纤维成本效益高的替代品。本研究采用模压成型的方法制备了可生物降解的交叉层复合材料。以马尼拉大麻织物为增强材料,淀粉基生物可降解塑料为基体,制备了生物可降解复合材料,并对其力学性能进行了研究。拉伸强度随着纤维含量的增加而增加,直到纤维含量达到约50%,然后趋于平稳。这种对纤维含量的依赖性是由于在热压过程中引入的纤维损伤导致加载方向的纤维强度降低。为了减少纤维在加载方向上的损伤,采用马尼拉大麻纤维为经纱,生物可降解树脂线为纬纱,生产了马尼拉大麻织物。结果表明,交叠层复合材料的拉伸强度从153MPa提高到202MPa。
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引用次数: 1
Effect of Needle Punching Process on a Chopped Strand Mat Composite with an Open Hole 针刺工艺对开孔短切毡复合材料的影响
Pub Date : 2018-07-02 DOI: 10.4236/ojcm.2018.83009
Daiki Ichikawa, H. Hamada, A. Ohtani
The easiest and most reliable joining method is the mechanical joint with a bolt and nut or rivet. However, in the case of composite laminates, mechanical joint properties decrease because of lower interlaminar properties compared to in-plane properties around hole. This study investigated needle punching process with the aim of improving the mechanical properties in the thickness direction of fiber-reinforced plastic composite laminates with an open hole. Needle punching process was applied to glass fiber chopped strand matused as the reinforcement for the composite laminates. Open-hole tensile tests and observations of end cross-sections after the tests were performed. The tensile properties and fracture mechanism of the specimens subjected to needle punching process were investigated. In addition, characteristic distance (a parameter for evaluating resistance to fracture in open-hole tensile test specimens) was also calculated to examine the effects of needle punching process conditions on fracture toughness. Tensile strength was improved by more than 15% by needle punching process. However, when a certain needle punching density was exceeded, the mechanical properties worsened. In addition, characteristic distance increased with increasing needle punching density. Thus, these results suggest that there is an optimal needle punching density with respect to strength and characteristic distance.
最简单、最可靠的连接方法是用螺栓、螺母或铆钉进行机械连接。然而,在复合材料层压板的情况下,由于与孔周围的平面内性能相比,层间性能较低,因此机械接头性能下降。本研究旨在改善开孔纤维增强塑料复合材料层压板厚度方向的力学性能。将针刺工艺应用于玻璃纤维短切毡复合材料层压板的补强。进行裸孔拉伸试验和试验后的端部横截面观察。研究了针刺试样的拉伸性能和断裂机理。此外,还计算了特征距离(用于评估开孔拉伸试样抗断裂性能的参数),以检验针刺工艺条件对断裂韧性的影响。针刺工艺使拉伸强度提高了15%以上。然而,当超过一定的针刺密度时,机械性能恶化。此外,特征距离随着针刺密度的增加而增加。因此,这些结果表明,相对于强度和特征距离,存在最佳的针刺密度。
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引用次数: 1
Application of Nanofiber Fabricated by Cotton Candy Method to Electric Double-Layer Capacitor 棉花糖法制备纳米纤维在双电层电容器中的应用
Pub Date : 2018-07-02 DOI: 10.4236/OJCM.2018.83011
A. Tada, T. Adachi, Yoshiki Tanaka, Y. Aoi, A. Yokoyama, H. Hamada
In recent years, application of carbon-based nano material to electrode material has been paid attention, however, due to its higher cost, it would be difficult to put it into practical use. Then, we have proposed to make nano carbon fiber with lower production cost. The purpose of our research was, to apply our nano carbon fiber to electrical double-layer capacitor electrode. We used cotton candy method to make nano fiber, and applied microwave heating for carbonization. By applying nano carbon fiber to electrical double-layer capacitor electrode, we got results that thicker electrode containing nano carbon fiber leads to lower resistance value, compared with electrode without containing nano carbon fiber. From this result, it was indicated that by containing nano carbon fiber, the electric bypass was formed in the electrode.
近年来,碳基纳米材料在电极材料中的应用受到关注,但由于其成本较高,难以投入实际应用。然后,我们提出了以较低的生产成本生产纳米碳纤维。我们的研究目的是将我们的纳米碳纤维应用于双电层电容器电极。我们采用棉花糖的方法制备纳米纤维,并应用微波加热进行碳化。将纳米碳纤维应用于双电层电容器电极,结果表明,与不含纳米碳纤维的电极相比,含纳米碳光纤的电极越厚,电阻值越低。由此结果表明,通过含有纳米碳纤维,在电极中形成了电旁路。
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引用次数: 0
Energy Absorption of Pultruded Glass-Graphite/Epoxy Hybrid Composites under High Strain-Rate Induced Transverse Tension 玻璃-石墨/环氧树脂复合材料在高应变率横向拉伸下的能量吸收
Pub Date : 2018-04-12 DOI: 10.4236/OJCM.2018.82004
Damian Stoddard, Suman Babu Ukyam, R. Prabhakar, A. Rajendran
This paper focuses on the dynamic tensile response of glass-graphite/epoxy composites illustrating improvement in energy absorption through hybridization. The dynamic response and energy absorption characteristics of pultruded hybrid combinations of glass and graphite fibers in an epoxy matrix subjected to induced transverse tension at high strain-rate in a modified Split Hopkinson Pressure Bar (SHPB) apparatus, are presented. Transverse tensile strength was determined by diametral compression of disc samples (Brazilian indirect tensile test method). Diametral crack initiation and strain to failure were monitored with a Shimadzu HPV-2 high-speed video camera at a recording speed of 500,000 fps and Digital Image Correlation (DIC). Adequate measures were taken to ensure that initiation of specimen failure occurred at the exact center of the disc specimen, and propagated through the diameter along the compressive loading axis, for the induced transverse tension tests to be valid. A study of the strength and specific energy absorption demonstrates the benefits of hybridization. Under induced transverse tensile loading condition, the pure glass/epoxy (GL60) exhibited higher strength than pure graphite/epoxy (GR60). Pure graphite/epoxy (GR60) has higher specific energy absorption capacity than pure glass/epoxy (GL60) in transverse tension. Among all hybrids, GR30 has the highest specific energy absorption under transverse tension. Overall, hybrid GL48, with 48% low-cost glass fibers in the inner core and 12% high-cost graphite fibers in outer shell, was found to exhibit better performance under induced transverse tension at high strain-rates, showing the benefits of hybridization.
本文重点研究了玻璃-石墨/环氧树脂复合材料的动态拉伸响应,通过杂化改善了能量吸收。介绍了在改进的Split Hopkinson压杆(SHPB)装置中,玻璃纤维和石墨纤维在环氧树脂基体中的拉挤混合组合在高应变速率下受到诱导横向张力的动态响应和能量吸收特性。横向拉伸强度通过圆盘样品的径向压缩测定(巴西间接拉伸试验方法)。使用岛津HPV-2高速摄像机以500000 fps的记录速度和数字图像相关(DIC)监测径向裂纹萌生和应变失效。采取了充分的措施,以确保试样失效发生在圆盘试样的确切中心,并沿压缩载荷轴在直径上传播,从而使诱导横向拉伸试验有效。对强度和比能量吸收的研究证明了杂交的好处。在诱导横向拉伸载荷条件下,纯玻璃/环氧树脂(GL60)的强度高于纯石墨/环氧树脂的强度。纯石墨/环氧树脂(GR60)在横向张力下比玻璃/环氧树脂具有更高的比能吸收能力。在所有杂交种中,GR30在横向张力下具有最高的比能吸收。总体而言,在内核中含有48%的低成本玻璃纤维,外壳中含有12%的高成本石墨纤维的杂化GL48,在高应变率下,在诱导的横向张力下表现出更好的性能,显示出杂化的优点。
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引用次数: 1
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复合材料期刊(英文)
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