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Research on design strategies for high-rise office buildings based on building energy and explainable machine learning algorithms 基于建筑能源和可解释机器学习算法的高层办公建筑设计策略研究
IF 3.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-29 DOI: 10.1007/s13762-025-06978-1
W. Kong, Z. Zhang, J. Li

As a typical cold-region city in China, Hohhot exhibits significant energy consumption in high-rise office buildings, while local designers lack systematic design strategies for guidance. Previous studies relied on simulation algorithms to adjust urban building designs, but this approach suffers from high time costs and limited generalizability. To address these challenges, this study proposes an innovative data-driven optimization framework for analyzing building energy performance in Hohhot’s cold climate and providing actionable design strategies. The framework integrates parametric modeling, machine learning (XGBoost/Random Forest/LightGBM/SVR), and explainable AI (SHAP) to deliver energy-efficient design solutions for high-rise offices. A case study of Hohhot’s typical high-rise building demonstrated that the XGBoost model outperformed alternatives in predicting heating/cooling/lighting demands (R2 > 0.83). Key findings revealed that heating systems account for 70–78% of total energy consumption, emphasizing compact building forms as the core design principle. SHAP analysis identified critical optimization directions for window-to-wall ratio (WWR): reducing WWR on east/west/ north facades by 30–40% decreases heating loads by 18–25%, while maintaining south-facing WWR at 35–45% balances daylight autonomy without thermal performance penalties. The proposed self-shading configuration (staggered south-facing layouts) strategically reduces cooling demand through solar occlusion. This methodology establishes a design workflow combining simulation-based approaches with explainable machine learning, offering scientific decision-making support for energy-efficient urban development in northern Chinese cities.

呼和浩特作为中国典型的寒区城市,高层办公建筑能耗大,而当地设计师缺乏系统的设计策略指导。以往的研究依赖于仿真算法来调整城市建筑设计,但这种方法存在时间成本高、通用性有限的问题。为了应对这些挑战,本研究提出了一个创新的数据驱动优化框架,用于分析呼和浩特寒冷气候下的建筑能源性能,并提供可操作的设计策略。该框架集成了参数化建模、机器学习(XGBoost/Random Forest/LightGBM/SVR)和可解释的人工智能(SHAP),为高层办公室提供节能设计解决方案。对呼和浩特典型高层建筑的案例研究表明,XGBoost模型在预测供暖/制冷/照明需求方面优于替代模型(R2 > 0.83)。主要研究结果显示,供暖系统占总能耗的70-78%,强调紧凑的建筑形式是核心设计原则。SHAP分析确定了窗墙比(WWR)的关键优化方向:将东/西/北立面的WWR降低30-40%,减少18-25%的热负荷,同时将朝南的WWR保持在35-45%,在不影响热性能的情况下平衡日光自主性。拟议的自遮阳配置(交错朝南布局)通过遮挡太阳策略性地减少了冷却需求。该方法建立了一个设计工作流,将基于仿真的方法与可解释的机器学习相结合,为中国北方城市的节能城市发展提供科学的决策支持。
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引用次数: 0
Improving geotechnical properties and shear strength of dispersive soil using cellulose nanofibers and recycled glass powder 利用纤维素纳米纤维和再生玻璃粉改善分散土的土工性能和抗剪强度
IF 3.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-27 DOI: 10.1007/s13762-025-06998-x
M. Behboudi, A. A. Zad, M. Yazdi

Dispersive clays are more erodible than typical clays due to the high concentration of sodium cations in their pore water. Using eco-friendly materials instead of conventional stabilizers (e.g., lime and cement) may play an important role in reducing energy and natural resource consumption while addressing environmental problems. This research investigated the use of cellulose nanofibers (CNF) and recycled glass powder (RGP) for dispersive soil stabilization. The results indicated that upon adding CNF and RGP compounds to the dispersive soil, dispersion potential decreased considerably. The maximum increase in UCS was observed for the compound with 1.5% CNF and 8% RGP. The UCS of these samples increased by 5.9, 10.4, and 12.5-fold after 7, 14, and 28 days of baking, respectively. XRD analysis showed that relatively strong reflections from CSH gel formed when CNF and RGP were added to the soil. Therefore, the main reason for the increase in sample strength might be the changes in the structure of the divergent soil in response to pozzolanic reactions and the formation of CSH gel. All these have led to denser structure and, ultimately, improved the strength properties of dispersive soil. Also, upon adding CNF and RGP to the soil, the increase in soil particle cohesion (c) and the internal friction angle (ϕ) enhanced shear strength. This increment would enhance the load-bearing capacity of the samples and increase the CBR value.

分散型粘土比典型粘土更易被侵蚀,这是由于其孔隙水中含有高浓度的钠离子。使用环保材料代替传统的稳定剂(如石灰和水泥)可能在减少能源和自然资源消耗,同时解决环境问题方面发挥重要作用。研究了纤维素纳米纤维(CNF)和再生玻璃粉(RGP)在分散土壤稳定中的应用。结果表明,在分散土壤中加入CNF和RGP化合物后,分散电位明显降低。当CNF为1.5%,RGP为8%时,UCS增加最多。经过7天、14天和28天的烘烤,这些样品的UCS分别增加了5.9倍、10.4倍和12.5倍。XRD分析表明,在土壤中加入CNF和RGP时,CSH凝胶的反射较强。因此,试样强度增加的主要原因可能是发散土对火山灰反应的结构变化和CSH凝胶的形成。所有这些都导致了更密集的结构,并最终提高了分散土的强度特性。此外,在土壤中加入CNF和RGP后,土壤颗粒黏聚力(c)和内摩擦角(φ)的增加均增强了抗剪强度。这种增加会提高试样的承载能力,增加CBR值。
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引用次数: 0
Trace metals distribution and potential human health risks in transboundary lagoon: a case study in West Africa 跨界泻湖中的微量金属分布和潜在的人类健康风险:西非案例研究
IF 3.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-25 DOI: 10.1007/s13762-025-07003-1
E. A. A. Yapi, N. L. B. Kouassi, B. L. G. L Zanli, K. M. Yao, B. J. G. Irié, S. Sanogo, A. S. Coulibaly

Anthropogenic pollution of border waters can be a source of contention between neighboring countries. However, little information is available on West African transboundary lagoon contamination by trace metals. The objectives of this research were to investigate into the spatial and seasonal fluctuations of mercury, arsenic, lead, and cadmium, the amount of metal pollution, and the potential health risks involved with cutaneous contact in the waters of the Aby Lagoon, a border lagoon in West Africa. The water samples were collected from February 2020 to October 2020. A one-way analysis of variance was used to investigate differences in trace metal total concentration between stations and, between seasons. Trace metal evaluation index and Human Health Risk Indices were used to assess the quality of water and the potential human health risk, respectively. Overall, the amounts of mercury, lead, cadmium, and arsenic did not vary between the stations, indicating that human activities in the area around these stations are similar. Throughout the research period, there was no seasonal change in total mercury and lead concentrations. However, total arsenic and cadmium concentrations differed greatly from season to season. The averages mercury, arsenic, cadmium, and lead concentrations were 2.28 ± 1.37 µg/L, 9.58 ± 5.80 µg/L, 0.72 ± 0.68 µg/L, and 1.16 ± 1.24 µg/L, respectively. Dermal contact with the water may expose the population to arsenic and cadmium-related cancers, as indicated by the results of the prospective human health risk indices. Based on the trace metal pollution index, most of the water is moderately to severely polluted. This study provides preliminary data on trace metals concentrations in the Côte d’Ivoire portion of the Aby Lagoon.

人为污染边界水域可能成为邻国之间争论的根源。但是,关于西非跨界泻湖受微量金属污染的资料很少。本研究的目的是调查西非边境泻湖阿比泻湖水域中汞、砷、铅和镉的空间和季节波动、金属污染的数量以及与皮肤接触有关的潜在健康风险。水样采集时间为2020年2月至2020年10月。采用单因素方差分析,对各站点间、季节间微量金属总浓度的差异进行了分析。采用微量金属评价指数和人体健康风险指数分别对水质和人体潜在健康风险进行评价。总体而言,汞、铅、镉和砷的含量在这些监测站之间没有变化,这表明这些监测站周围地区的人类活动是相似的。在整个研究期间,汞和铅的总浓度没有季节性变化。然而,总砷和总镉浓度在季节之间差异很大。汞、砷、镉和铅的平均浓度分别为2.28±1.37µg/L、9.58±5.80µg/L、0.72±0.68µg/L和1.16±1.24µg/L。预期人类健康风险指数的结果表明,与水的皮肤接触可能使人口暴露于与砷和镉有关的癌症。根据痕量金属污染指数,大部分水体为中度至重度污染。这项研究提供了艾比潟湖Côte科特迪瓦部分微量金属浓度的初步数据。
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引用次数: 0
Copper biosorption by aerobic granular sludge developed from landfill leachate: optimization and phenomenological insights 从垃圾渗滤液中开发的好氧颗粒污泥对铜的生物吸附:优化和现象学见解
IF 3.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-23 DOI: 10.1007/s13762-025-07006-y
M. Quiroz, J. Mansilla, C. Arriagada, C. Espinoza, D. Contreras, J. J. Gallardo-Rodríguez, M. Roeckel, V. Guzmán-Fierro

The utilization of aerobic granular sludge (AGS) as a biomaterial for metal recovery has the potential to enhance the economic and environmental aspects of contaminant adsorption. In this study, the optimization of operational parameters and the phenomenological mechanisms involved in copper biosorption by AGS were investigated. A Box-Behnken experimental design was used for the optimization of copper biosorption with AGS. The experiment showed that the optimal parameters for copper biosorption were sludge concentration of 1 gTS L−1, pH 6, and contact time of 6 h for the highest copper removal (30.65%). The tested temperature (18–26 °C) was not relevant in the process. The pseudo-second order kinetics (R2 = 0.9721) and the Langmuir isotherm (R2 = 0.9716, maximum adsorption capacity = 140.85 mg gST−1) described the biosorption of copper by AGS. The solution of the differential equations governing the phenomenological mechanisms revealed that adsorption on active sites dominates the copper adsorption process in AGS during the first 2.75 h. However, beyond this initial period, all mass transfer mechanisms (external diffusion, intraparticle diffusion, and adsorption at active sites) become equally relevant. In this study, the feasibility and efficiency of copper biosorption were demonstrated, establishing an alternative process for the copper removal using AGS.

利用好氧颗粒污泥(AGS)作为金属回收的生物材料具有提高污染物吸附的经济和环境方面的潜力。本文研究了AGS吸附铜的操作参数优化及现象机理。采用Box-Behnken实验设计优化AGS对铜的生物吸附效果。实验结果表明,污泥浓度为1 gTS L−1,pH为6,接触时间为6 h时,铜的最佳生物吸附参数为铜的去除率最高(30.65%)。试验温度(18-26℃)与工艺无关。拟二级动力学(R2 = 0.9721)和Langmuir等温线(R2 = 0.9716,最大吸附量= 140.85 mg gST−1)描述了AGS对铜的生物吸附。控制现象机制的微分方程的解表明,在前2.75 h内,活性位点上的吸附在AGS中的铜吸附过程中占主导地位。然而,在此初始阶段之后,所有传质机制(外部扩散、颗粒内扩散和活性位点上的吸附)都变得同样重要。本研究验证了生物吸附铜的可行性和效率,建立了AGS除铜的替代工艺。
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引用次数: 0
Evaluating the environmental-friendly stabilization of loess soil with nano iron oxide: enhanced strength and non-destructive monitoring through UPV 纳米氧化铁对黄土的环境友好稳定评价:增强强度和UPV无损监测
IF 3.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-22 DOI: 10.1007/s13762-025-06864-w
N. Esmaeili, M. Gharib, S. Soleimani Kutanaei, M. Banihashemi, N. Ranjbar Malidarreh

Loess soil, due to mechanical weaknesses, such as low strength and high sensitivity to environmental changes, needs stabilization in order to perform better in geotechnical engineering projects. Although the traditional methods of soil stabilization are efficient, due to environmental problems, using nanomaterials with unique properties, such as high specific surface area is recognized as an innovative and effective approach. In this research, the effect of nano iron oxide in different contents and different curing times on the stabilization of loess soil has been investigated. The mechanical and shear properties of the samples were evaluated using standard Proctor compaction, indirect tensile strength (ITS), unconfined compressive strength (UCS), direct shear, scanning electron microscopy and particularly ultrasonic pulse velocity (UPV) tests. This study is significant for using UPV testing as a non-destructive approach to monitor structural changes and predict soil strength. The findings indicated that incorporating nano iron oxide reduced the maximum dry density (MDD) while increasing the optimum moisture content (OMC). Furthermore, the ITS and UCS values of the sample stabilized with 1.5% nano iron oxide improved by 41% and 32%, respectively, after a curing time of 14 days. The optimum nano iron oxide content was determined to be 1.5% to achieve maximum strength. In addition, the internal friction angle and cohesion of loess soil treated with 1.5% nano iron oxide increased by approximately 15% and 207%, respectively. Results from the UPV tests further demonstrated that this method can effectively serve as a non-destructive tool for assessing soil strength evolution over time.

黄土土具有强度低、对环境变化敏感等力学弱点,需要稳定才能在岩土工程中发挥更好的作用。虽然传统的土壤稳定方法是有效的,但由于环境问题,使用具有高比表面积等独特性能的纳米材料被认为是一种创新而有效的方法。研究了纳米氧化铁不同掺量和不同固化时间对黄土土体稳定性的影响。通过标准的普罗克特压实、间接抗拉强度(ITS)、无侧限抗压强度(UCS)、直接剪切、扫描电子显微镜以及特别是超声脉冲速度(UPV)测试来评估样品的力学和剪切性能。该研究对于使用UPV测试作为非破坏性方法来监测结构变化和预测土壤强度具有重要意义。结果表明,纳米氧化铁的掺入降低了最大干密度(MDD),提高了最佳含水率(OMC)。经1.5%纳米氧化铁固化14天后,样品的ITS和UCS值分别提高了41%和32%。确定纳米氧化铁含量为1.5%可获得最大强度。此外,1.5%纳米氧化铁处理的黄土土的内摩擦角和黏聚力分别提高了约15%和207%。UPV试验的结果进一步表明,该方法可以有效地作为评估土壤强度随时间变化的非破坏性工具。
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引用次数: 0
Exploring the mechanism of tartrazine dye adsorption by Parthenium hysterophorus biochar for sustainable textile wastewater treatment 探讨宫草Parthenium hysterophorus生物炭吸附酒黄染料的机理
IF 3.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-22 DOI: 10.1007/s13762-025-06802-w
K. Younas, A. Jamil, M. Ahmad, N. Ghaffour, M. S. Nawaz

In the current study, parthenium hysterophorus-derived biochars (PTCs) were used as low-cost and environment-friendly sorbents in batch mode and fixed-bed columns to assess the adsorption behavior of tartrazine dye (TTZ) by varying operational settings and analyzing mathematical models. In the batch adsorption study, the Langmuir and pseudo-first-order models provided the best expression for TTZ adsorption onto PTCs with an uptake capacity of 95.57 mg/g at maximum. In the fixed bed column, the sorption of TTZ was promoted with greater bed height, reduced flow velocity, and higher dye concentration. Comparing the column models (Yoon-Nelson, Thomas, and Clark), the Clark model provided the best fit with the experimental data and effectively represented the adsorption process. The accompanying experimental data agreed with the breakthrough curves. The maximum adsorption capacity achieved with the column process was 8.32 mg/g. In contrast to other adsorbents, PTCs showed excellent adsorption efficiency and a strong potential for reusability.

Graphical abstract

本研究以宫草parthenium - hysteropium衍生生物炭(ptc)作为低成本、环保型的吸附剂,在间歇式和固定床柱上通过不同的操作设置和分析数学模型来评估酒黄染料(TTZ)的吸附行为。在批量吸附研究中,Langmuir模型和拟一阶模型对TTZ在ptc上的吸附效果最好,吸附量最大可达95.57 mg/g。在固定床柱中,越高的床层高度,越低的流速,越高的染料浓度,越有利于TTZ的吸附。对比柱模型(Yoon-Nelson、Thomas和Clark), Clark模型与实验数据拟合最好,能有效表征吸附过程。随附的实验数据与突破曲线吻合。柱法最大吸附量为8.32 mg/g。与其他吸附剂相比,ptc具有优异的吸附效率和较强的可重复利用潜力。图形抽象
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引用次数: 0
Correction: A review of geological and triggering factors influencing landslide susceptibility: artificial intelligence-based trends in mapping and prediction 修正:影响滑坡易感性的地质和触发因素综述:基于人工智能的制图和预测趋势
IF 3.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-22 DOI: 10.1007/s13762-025-07010-2
M. Ehsan, M. T. Anees, A. F. B. A. Bakar, A. Ahmed
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引用次数: 0
A novel approach to balancing stakeholder interests in construction waste landfill charges for advancing a circular economy 一种平衡建筑垃圾填埋收费中利益相关者利益的新方法,以促进循环经济
IF 3.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-22 DOI: 10.1007/s13762-025-06979-0
B. Yu, S. Zhang, Y. Yang, K. S. Woon, C. T. Lee, J. Wang, Y. Su, Z. Bao

Landfill charging schemes effectively reduce construction and demolition waste (C&DW) sent to landfills, advancing the global circular economy. Their success, however, depends on scientifically sound charging standards. Current methods for setting landfill charges largely rely on waste generators’ willingness to pay, with little consideration for landfill operators’ interests. To address this gap, this study proposes a novel, stakeholder-inclusive approach to develop waste landfill charging standards. Distinct from methods centered on willingness to pay, this approach integrates both generators’ cost considerations and operators’ revenue needs, alongside market realities (e.g., costs of alternative disposal facilities, transportation expenses). It comprises four progressive steps: (1) identifying the generation area and specific locations of the C&DW to be landfilled; (2) calculating the total disposal costs at alternative facilities; (3) estimating transportation costs from waste sources to the target landfill; (4) determining the final charging standard by balancing cost-efficiency for generators and operational sustainability for operators. Validated through a case study of the Litoushan Landfill in Shenzhen, China, the approach yielded an optimal charging standard ranging from CNY 106 to CNY 112/m3. This method provides a valuable, and actionable reference for policymakers worldwide to establish evidence-based C&DW landfill charging standards, strengthening waste management practices globally. Additionally, its adaptable framework can be extended to determine charging standards for other waste types (e.g., municipal solid waste, industrial solid waste), further supporting the global transition to a circular economy.

堆填区收费计划有效减少送往堆填区的建筑和拆除废物,促进全球循环经济。然而,它们的成功取决于科学合理的收费标准。目前的填埋收费主要取决于垃圾产生者的支付意愿,很少考虑填埋经营者的利益。为了解决这一差距,本研究提出了一种新颖的、包容利益相关者的方法来制定垃圾填埋场收费标准。与以支付意愿为中心的方法不同,这种方法结合了发电商的成本考虑和运营商的收入需求,以及市场现实(例如,替代处置设施的成本,运输费用)。它包括四个循序渐进的步骤:(1)确定拟堆填的生化废物的产生区和具体地点;(二)计算备选设施的总处置费用;(3)估算从垃圾源到目标填埋场的运输成本;(4)通过平衡发电机组的成本效益和运营商的可持续性来确定最终的收费标准。通过对中国深圳荔头山垃圾填埋场的案例研究,该方法得到了106元至112元/m3的最佳收费标准。该方法为世界各国决策者建立基于证据的垃圾填埋场收费标准、加强全球废物管理实践提供了有价值的、可操作的参考。此外,可扩展其适应性框架,以确定其他废物类型(如城市固体废物、工业固体废物)的收费标准,进一步支持全球向循环经济过渡。
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引用次数: 0
Assessing the environmental costs of a thermal power plant in tehran using life cycle analysis 利用生命周期分析法评估德黑兰某火电厂的环境成本
IF 3.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-22 DOI: 10.1007/s13762-025-06854-y
N Javidi, G Nabi Bidhendi, O Tavakoli, N Mehrdadi

This study assesses the environmental and economic impacts of a natural gas-fired thermal power plant in Tehran using life cycle analysis and environmental cost accounting. The analysis considers key environmental categories, including global warming potential, acidification potential, eutrophication potential, water consumption, thermal pollution, and particulate matter formation. This study used a life cycle analysis framework integrated with environmental cost accounting to assess the environmental costs of a natural gas-fired thermal power plant in Tehran. The study covered the entire life cycle of the power plant, including fuel extraction, transportation, electricity generation, greenhouse gas emissions, and waste management. The environmental impacts were then quantified in financial terms to estimate the economic burden associated with these impacts, providing a comprehensive view of the plant’s environmental footprint. The results show that the plant emits 451.5 kg CO2 equivalent per megawatt-hour, with a total annual emission of 1.63 million tons of CO2 equivalent, which significantly contributes to global climate change. The plant’s high levels of NOx and SOx emissions, which contribute to acidification and air pollution, are also of concern, along with the plant’s annual water consumption of 10.8 million cubic meters, which leads to water shortages and thermal pollution in Tehran. The economic costs associated with these environmental impacts are estimated at $31.20 per megawatt-hour, indicating hidden social costs related to public health and environmental degradation. The study emphasizes the need for policy interventions, such as upgrading emission control technologies, reducing water consumption through dry cooling systems, and transitioning to renewable energy sources to reduce the environmental and economic burdens of thermal power generation. This study also emphasizes the importance of understanding the water-energy nexus in managing resource interdependencies and achieving long-term sustainability in urban energy systems.

本研究利用生命周期分析和环境成本核算评估了德黑兰一家天然气火力发电厂的环境和经济影响。该分析考虑了关键的环境类别,包括全球变暖潜力、酸化潜力、富营养化潜力、水消耗、热污染和颗粒物形成。本研究采用生命周期分析框架与环境成本会计相结合的方法来评估德黑兰一家天然气火力发电厂的环境成本。该研究涵盖了电厂的整个生命周期,包括燃料提取、运输、发电、温室气体排放和废物处理。然后,对环境影响进行财务量化,以估计与这些影响相关的经济负担,从而全面了解工厂的环境足迹。结果表明,该电厂每兆瓦时排放451.5 kg CO2当量,年排放总量为163万吨CO2当量,对全球气候变化做出了重大贡献。该工厂高水平的氮氧化物和硫氧化物排放导致酸化和空气污染,以及该工厂每年1080万立方米的用水量也令人担忧,这导致德黑兰的水资源短缺和热污染。与这些环境影响有关的经济成本估计为每兆瓦时31.20美元,表明与公共健康和环境退化有关的隐性社会成本。该研究强调了政策干预的必要性,例如升级排放控制技术,通过干式冷却系统减少用水量,以及向可再生能源过渡以减少火力发电的环境和经济负担。本研究还强调了在管理资源相互依赖性和实现城市能源系统的长期可持续性方面了解水-能源关系的重要性。
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引用次数: 0
Comparison of activated carbons Norit RB4W and Filtrasorb 400 for the removal of vancomycin from water Norit RB4W与Filtrasorb 400活性炭对水中万古霉素的去除效果比较
IF 3.4 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-22 DOI: 10.1007/s13762-025-06987-0
H. M. Coleman, E. Theofanous, H. Rasouli Sadabad, J. Arnscheidt

Misuse of antibiotics and their presence in wastewater have led to the emergence of antibiotic resistant bacteria. Vancomycin residue in water from hospital use, is associated with the appearance and spread of vancomycin resistant bacteria, i.e. considered as a serious threat for human health. This study assessed physicochemical properties of two activated carbons and linked them to their vancomycin adsorptive performance. The influence of contact time (0–168 h), pH (3–11), adsorbent dosage (100–1000 mg), temperature (15–45 °C), and initial vancomycin concentration (5–100 μg/mL) were investigated. The equilibrium of vancomycin adsorption was reached at 120 h for both Filtrasorb 400 and Norit RB4W. The sorbents exhibited peak performance at a solution pH of 5. The highest vancomycin removal efficiency was attained with 600 mg of Filtrasorb 400 at 24 h. It achieved an almost complete removal of vancomycin from solution. 1000 mg of Norit RB4W reduced vancomycin’s concentration from 48.9 to 25.6 μg/mL (47.64%). Temperature modification showed no statistically significant effect on vancomycin concentration of Norit RB4W and control samples at 24 h. However, Filtrasorb 400 presented a notable increase in removal efficiency with increasing temperature. Moreover, removal efficiency was found to be inversely proportional to initial vancomycin concentration. Physisorption was likely to be the prevalent mechanism of vancomycin removal from aqueous samples. Filtrasorb 400 demonstrated superior performance in removing vancomycin from water as it contains wider mesopores as well as higher mesopore content and larger specific surface area, compared to Norit RB4W.

抗生素的滥用及其在废水中的存在导致了抗生素耐药细菌的出现。医院用水中的万古霉素残留与万古霉素耐药细菌的出现和传播有关,即被认为是对人类健康的严重威胁。本研究评估了两种活性炭的物理化学性质,并将其与万古霉素吸附性能联系起来。考察了接触时间(0 ~ 168 h)、pH(3 ~ 11)、吸附剂用量(100 ~ 1000 mg)、温度(15 ~ 45℃)和万古霉素初始浓度(5 ~ 100 μg/mL)的影响。Filtrasorb 400和Norit RB4W在120 h时达到万古霉素的吸附平衡。吸附剂在溶液pH为5时表现出最佳性能。滤液滤液滤液浓度为600 mg时,24 h万古霉素的去除率最高,几乎完全去除了溶液中的万古霉素。1000mg Norit RB4W使万古霉素浓度由48.9降至25.6 μg/mL(47.64%)。温度变化对24h时Norit RB4W和对照样品的万古霉素浓度无显著影响,但随着温度的升高,Filtrasorb 400的去除率显著提高。此外,去除率与初始万古霉素浓度成反比。物理吸附可能是万古霉素从水样中去除的主要机制。与Norit RB4W相比,Filtrasorb 400具有更宽的介孔、更高的介孔含量和更大的比表面积,因此在水中去除万古霉素方面表现出优异的性能。
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International Journal of Environmental Science and Technology
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