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Operator exposure and cabin protection in plant protection product application 植保产品应用中的操作人员暴露和舱室保护
IF 1.4 3区 农林科学 Q4 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-11-12 DOI: 10.1007/s00003-024-01531-7
Gabor Molnar, Katrin Ahrens, Jens Karl Wegener, Sebastian Dittmar, Enrico Peter, Sabine Martin, Jan-Niklas Schäckermann, Markus Röver

Tightly sealed driver's cabs can effectively protect the user from exposure when applying crop protection products. Therefore, under certain conditions, users in such cabins can avoid wearing personal protective equipment for skin and eyes. The protective effect depends on the technical design and handling of the different cabin types and can be divided into categories with different levels of protection. Since the level of protection of the different types of cabins and the associated possibility of not wearing personal protective equipment has not been sufficiently scientifically verified in the past, the present study was carried out to close this gap. Field and laboratory test methods were developed and used to assess exposure levels. External contamination of the cabin was measured using various dosimeters. Exposure inside the cabins was measured on coveralls and gloves to measure dermal exposure and with aerosol sampling pumps to determine inhalation exposure. Tests were conducted on tractors with different cab categories using an air-assisted orchard sprayer as a worst-case scenario for exposure to spray drift. Additionally, an alternative laboratory test method was developed and conducted to evaluate filter efficiency under controlled conditions and compare it with the field tests. The results showed that exposure inside closed cabins was generally low and was not notably correlated with the cabin category. All types of cabins tested were found to provide significant protection from dermal and inhalation exposure.

密闭的驾驶室可以有效保护使用者在使用作物保护产品时不接触到这些产品。因此,在一定条件下,驾驶室内的使用者可以不用佩戴皮肤和眼睛个人防护设备。防护效果取决于不同类型驾驶室的技术设计和操作,可分为不同防护等级的类别。由于过去没有对不同类型舱室的防护等级以及相关的不佩戴个人防护设备的可能性进行充分的科学验证,因此开展了本研究来弥补这一不足。制定了实地和实验室测试方法,用于评估暴露水平。使用各种剂量计测量船舱的外部污染。通过测量工作服和手套的皮肤暴露量以及气溶胶采样泵的吸入暴露量来确定机舱内的暴露量。在不同驾驶室类别的拖拉机上进行了测试,使用空气辅助果园喷雾器作为最坏情况下的喷雾漂移暴露情景。此外,还开发并进行了另一种实验室测试方法,以评估受控条件下的过滤效率,并与现场测试进行比较。结果表明,密闭船舱内的暴露量普遍较低,而且与船舱类别没有明显关联。测试发现,所有类型的船舱都能有效防止皮肤和吸入接触。
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引用次数: 0
Upcoming events 即将举行的活动
IF 1.4 3区 农林科学 Q4 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-11-02 DOI: 10.1007/s00003-024-01535-3
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引用次数: 0
Consumer preferences and willingness to pay for a blockchain-based food traceability system: a case study of fresh pork in China 消费者对基于区块链的食品可追溯系统的偏好和支付意愿:以中国新鲜猪肉为例
IF 1.4 3区 农林科学 Q4 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-10-29 DOI: 10.1007/s00003-024-01534-4
Minda Yang, Shi Min, Ping Qing

Blockchain-based traceability systems offer significant potential for enhancing food safety. This study investigated consumer preferences and willingness to pay (WTP) for a blockchain-based traceability system for fresh pork, and examined preferences for certification agencies. Data were gathered through an online choice experiment conducted in 5 Chinese cities. The results show favorable preferences and higher WTP for a blockchain-based traceability system, with the information intervention group demonstrating a higher mean WTP than the control group. The highest WTP is observed for a blockchain food traceability system combined with government certification. These findings provide valuable insights for promoting blockchain-based food traceability in developing countries and hold important policy implications for food safety regulation and consumer protection.

基于区块链的可追溯系统为提高食品安全提供了巨大的潜力。本研究调查了消费者对基于区块链的新鲜猪肉可追溯系统的偏好和支付意愿(WTP),并研究了对认证机构的偏好。数据是通过在中国5个城市进行的在线选择实验收集的。结果显示,基于区块链的可追溯系统具有良好的偏好和更高的WTP,信息干预组的平均WTP高于对照组。最高的WTP是区块链食品可追溯系统与政府认证相结合。这些发现为促进发展中国家基于区块链的食品可追溯性提供了有价值的见解,并对食品安全监管和消费者保护具有重要的政策意义。
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引用次数: 0
Species authentication in meat products sold in Kilosa District in Tanzania using HRM-enhanced DNA barcoding 在坦桑尼亚基洛萨地区销售的肉类产品中使用hrm增强DNA条形码进行物种认证
IF 1.4 3区 农林科学 Q4 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-10-21 DOI: 10.1007/s00003-024-01532-6
Edward John Dule, Edson Kinimi, Gaymary George Bakari, Robert Arsen Max, Charles Moses Lyimo, James Richard Mushi

Species substitution in meat products is a common form of food fraud that raises ethical, religious, dietary, and conservation issues. Measures to monitor meat substitution are being implemented in many parts of the world. However, information on similar efforts in Tanzania is scarce. This study aimed to assess species authenticity in kebabs sold in the Kilosa District. During 4 months (November 2023 to March 2024), 100 processed kebabs were purchased from fast food outlets across 3 wards: Dumila (n = 49), Kimamba (n = 24), and Mikumi (n = 27). Species authentication was conducted using High-resolution melting analysis and DNA barcoding, targeting two mitochondrial markers: cytochrome oxidase 1 (COI) and 16 S rRNA. Out of 100 kebabs, 64 were misidentified. Notably, goat-based kebabs were the most substituted, with 36 out of 43 (83.7%) containing different species: cattle (30), chicken (2), impala (1), and warthog (3). Out of 40 cattle kebabs, 18 (45%) consisted of meat from different species: chicken (7), goat (8), 2 impala (2), and 1 warthog (1). Chicken kebabs had only 7 undeclared cattle species, and all 3 samples sold as mutton kebabs were substituted with cattle (2) and goat (1). The findings indicate a high prevalence of species substitution in meat products within the Kilosa District. Undeclared wildlife species might represent illegal bushmeat harvests in the conserved ecosystems. Extensive meat inspections and educational interventions are recommended to ensure the integrity of the meat market, consumer trust, and the conservation of wildlife.

肉类产品中的物种替代是一种常见的食品欺诈形式,引发了道德,宗教,饮食和保护问题。世界许多地方正在实施监测肉类替代的措施。但是,关于坦桑尼亚类似努力的资料很少。本研究旨在评估基洛萨地区出售的烤肉串的物种真实性。在4个月内(2023年11月至2024年3月),从Dumila (n = 49)、Kimamba (n = 24)和Mikumi (n = 27) 3个区的快餐店购买了100根加工过的烤肉串。采用高分辨率熔融分析和DNA条形码技术进行物种鉴定,目标是两个线粒体标记:细胞色素氧化酶1 (COI)和16s rRNA。在100个烤肉串中,有64个被认错。值得注意的是,羊肉串被取代的最多,43个羊肉串中有36个(83.7%)含有不同的物种:牛(30)、鸡(2)、黑斑羚(1)和疣猪(3)。40个羊肉串中,18个(45%)由不同物种的肉组成。鸡(7),山羊(8),2只黑斑羚(2)和1只疣猪(1)。鸡肉串中只有7种未申报的牛,而作为羊肉串出售的3种样品都被牛(2)和山羊(1)代替。研究结果表明,Kilosa地区肉类产品中物种替代的发生率很高。未申报的野生动物物种可能代表了在受保护的生态系统中非法获取丛林肉。建议进行广泛的肉类检查和教育干预,以确保肉类市场的完整性、消费者的信任和野生动物的保护。
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引用次数: 0
Salt in foods: a definitive source of microplastics to humans 食品中的盐:人类微塑料的明确来源
IF 1.4 3区 农林科学 Q4 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-10-20 DOI: 10.1007/s00003-024-01530-8
Jamila Patterson, K. Radampola, P. B. Terney Pradeep Kumara, Glen Esmeralda, K. Immaculate Jeyasanta, M. Narmatha Sathish

The pervasive contamination of the environment with microplastics (MPs) poses a significant threat to food safety as MPs enter and move up the food chain. Understanding the exposure route via foodstuffs is essential. In this study, we analyzed MP contamination in commonly available brands of crystal and iodized powder salts from India and Sri Lanka. MPs were isolated and identified using digestion, filtration, microscopy, and Attenuated Total Reflectance-Fourier Transform Infrared (ATR-FTIR) spectroscopy. MPs were more abundant in Indian salt (17.16 ± 8.81 MPs/kg) than in Sri Lankan salt (7.9 ± 6.2 MPs/kg), with crystal salt showing higher MP levels than iodized salt in both countries. Fiber-shaped black and white MPs (< 1 mm) were the most common. ATR-FTIR analysis confirmed the polymer composition, predominantly polypropylene and polyethylene, in both Indian (56%, 24%) and Sri Lankan (42%, 28%) samples. Based on polymer hazard scores, the chemical risk of salts was categorized as level II (Sri Lanka) and IV (India). If a person consumes 5 g of salt per day (World Health Organization), Indians would ingest 0.085 MPs/day (31.025 MPs/year), and Sri Lankans would consume 0.0395 MPs/day (14.4175 MPs/year). The presence of MPs in salts is likely due to the use of contaminated water in production and specific manufacturing processes. Ingesting MPs through daily salt consumption poses a risk to human health, highlighting the need for measures to protect salt sources and improve production processes.

微塑料(MPs)对环境的普遍污染对食品安全构成了重大威胁,因为微塑料会进入食物链并向上移动。了解通过食品接触微塑料的途径至关重要。在这项研究中,我们分析了印度和斯里兰卡常见品牌的水晶盐和碘化粉盐中的微塑料污染情况。我们使用消化、过滤、显微镜和衰减全反射-傅立叶变换红外光谱法(ATR-FTIR)分离和鉴定了 MPs。印度盐(17.16 ± 8.81 MPs/kg)比斯里兰卡盐(7.9 ± 6.2 MPs/kg)含有更多的多晶萘,两国的结晶盐中多晶萘含量均高于加碘盐。纤维状的黑色和白色 MPs(1 毫米)最为常见。ATR-FTIR 分析证实了印度(56%,24%)和斯里兰卡(42%,28%)样品中的聚合物成分,主要是聚丙烯和聚乙烯。根据聚合物危害评分,盐类的化学风险被划分为二级(斯里兰卡)和四级(印度)。如果一个人每天摄入 5 克盐(世界卫生组织),印度人每天摄入 0.085 兆帕斯卡(31.025 兆帕斯卡/年),斯里兰卡人每天摄入 0.0395 兆帕斯卡(14.4175 兆帕斯卡/年)。食盐中含有多氯联苯可能是由于在生产和特定制造过程中使用了受污染的水。通过日常食盐摄入多溴联苯醚会对人类健康造成威胁,因此有必要采取措施保护盐源并改进生产工艺。
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引用次数: 0
Ubiquitous occurrence of organophosphate esters in plastic-made and paper-made food contact materials and their implication for human exposure 塑料和纸制食品接触材料中普遍存在的有机磷酸酯及其对人体摄入的影响
IF 1.4 3区 农林科学 Q4 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-10-15 DOI: 10.1007/s00003-024-01533-5
Xun Wang, Yao Liu, Jian-Ming Jiang, Xi-Long Zhang, Minjie Li, Wen-Jun Hong, Liang-Hong Guo

Human exposure to organophosphate esters (OPEs) can occur through contaminated food contact materials (FCMs), which may pose significant health risks. This study investigated the presence and migration characteristics of 26 OPEs in 60 plastic and paper-based food contact materials sourced from markets and online retailers. Migration experiments were conducted using three food simulants: 4% acetic acid, 10% ethanol, and 95% ethanol. Thirteen OPEs were identified in the packaging samples, with triphenyl phosphate and tris(1-chloro-2-propyl) phosphate being the most frequently detected, averaging 95.8 ng/g and 73.3 ng/g, respectively. During migration simulations, 11 OPEs were found to migrate into the food simulants, with migration concentrations ranging from 9.22 to 150 ng/cm². The health impact was assessed using hazard index and maximum cumulative ratio methods. Triphenylphosphine oxide, triisobutyl phosphate, and butylphenyl diphenyl phosphate contributed the most to the overall hazard among the 11 compounds. However, the overall risk of OPE exposure to humans was determined to be low.

人类可能会通过受污染的食品接触材料(FCM)接触到有机磷酸酯(OPE),这可能会对健康造成严重危害。本研究调查了来自市场和在线零售商的 60 种塑料和纸质食品接触材料中 26 种 OPE 的存在和迁移特性。迁移实验使用了三种食品模拟物:4% 乙酸、10% 乙醇和 95% 乙醇。在包装样品中发现了 13 种 OPE,其中最常检测到的是磷酸三苯酯和磷酸三(1-氯-2-丙基)酯,平均含量分别为 95.8 纳克/克和 73.3 纳克/克。在模拟迁移过程中,发现有 11 种 OPE 迁移到食品模拟物中,迁移浓度介于 9.22 纳克/平方厘米和 150 纳克/平方厘米之间。采用危害指数和最大累积比方法对健康影响进行了评估。在 11 种化合物中,三苯基氧化膦、磷酸三异丁酯和丁基二苯基磷酸酯对总体危害的影响最大。不过,经测定,人类接触 OPE 的总体风险较低。
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引用次数: 0
Climate change and mycotoxins: a growing food safety concern 气候变化与霉菌毒素:日益严重的食品安全问题
IF 1.4 3区 农林科学 Q4 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-10-10 DOI: 10.1007/s00003-024-01528-2
Esther Garcia-Cela, Alessandra Marcon Gasperini
{"title":"Climate change and mycotoxins: a growing food safety concern","authors":"Esther Garcia-Cela,&nbsp;Alessandra Marcon Gasperini","doi":"10.1007/s00003-024-01528-2","DOIUrl":"10.1007/s00003-024-01528-2","url":null,"abstract":"","PeriodicalId":622,"journal":{"name":"Journal of Consumer Protection and Food Safety","volume":"19 4","pages":"373 - 375"},"PeriodicalIF":1.4,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142636952","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
ICP-OES analysis of Lithium in honey, royal jelly, bee bread, propolis, and bees following microwave-assisted sample preparation 微波辅助样品制备后对蜂蜜、蜂王浆、蜂巢面包、蜂胶和蜜蜂中的锂进行 ICP-OES 分析
IF 1.4 3区 农林科学 Q4 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-09-16 DOI: 10.1007/s00003-024-01527-3
Annemarie Richter, Max Rüdiger, David M. Schumacher, Corinna Kürbis

Lithium is a natural, ubiquitously-occurring alkali metal found in varying amounts in foods like honey. Recently, lithium chloride (LiCl) was described to be effective against varroosis, a parasitic disease leading to loss of honey bee colonies with limited therapy options. However, LiCl treatment is not currently authorized for use in honey bee colonies. Such treatment might result in elevated lithium amounts in honey. To address this, a robust method for quantifying lithium in honey was validated using a microwave-assisted digestion technique combined with Inductively Coupled Plasma-Optical Emission Spectrometry (ICP-OES), achieving detection levels as low as 0.151 mg/kg. The method was applied to 65 commercially available, randomly chosen honey samples, all of which had lithium levels below the limit of quantitation (LOQ). Furthermore, the method was successfully adapted for use with more complex bee matrices, including royal jelly, bee bread, propolis, and whole bees.

锂是一种天然、普遍存在的碱金属,在蜂蜜等食物中含量不一。最近,氯化锂(LiCl)被描述为对变节虫病有效,变节虫病是一种导致蜜蜂失去蜂群的寄生虫病,治疗方法有限。然而,氯化锂治疗目前尚未被批准用于蜜蜂群落。这种治疗可能会导致蜂蜜中的锂含量升高。为解决这一问题,我们采用微波辅助消化技术结合电感耦合等离子体-光发射光谱法(ICP-OES),验证了一种可靠的蜂蜜中锂定量方法,其检测水平低至 0.151 mg/kg。该方法被应用于 65 个随机抽取的市售蜂蜜样品,所有样品的锂含量均低于定量限(LOQ)。此外,该方法还成功适用于更复杂的蜜蜂基质,包括蜂王浆、蜂面包、蜂胶和整只蜜蜂。
{"title":"ICP-OES analysis of Lithium in honey, royal jelly, bee bread, propolis, and bees following microwave-assisted sample preparation","authors":"Annemarie Richter,&nbsp;Max Rüdiger,&nbsp;David M. Schumacher,&nbsp;Corinna Kürbis","doi":"10.1007/s00003-024-01527-3","DOIUrl":"10.1007/s00003-024-01527-3","url":null,"abstract":"<div><p>Lithium is a natural, ubiquitously-occurring alkali metal found in varying amounts in foods like honey. Recently, lithium chloride (LiCl) was described to be effective against varroosis, a parasitic disease leading to loss of honey bee colonies with limited therapy options. However, LiCl treatment is not currently authorized for use in honey bee colonies. Such treatment might result in elevated lithium amounts in honey. To address this, a robust method for quantifying lithium in honey was validated using a microwave-assisted digestion technique combined with Inductively Coupled Plasma-Optical Emission Spectrometry (ICP-OES), achieving detection levels as low as 0.151 mg/kg. The method was applied to 65 commercially available, randomly chosen honey samples, all of which had lithium levels below the limit of quantitation (LOQ). Furthermore, the method was successfully adapted for use with more complex bee matrices, including royal jelly, bee bread, propolis, and whole bees.</p></div>","PeriodicalId":622,"journal":{"name":"Journal of Consumer Protection and Food Safety","volume":"19 4","pages":"455 - 460"},"PeriodicalIF":1.4,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00003-024-01527-3.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142266077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A high-throughput screening method for GM soybean events based on single universal primer multiplex PCR and capillary electrophoresis 基于单一通用引物多重 PCR 和毛细管电泳的转基因大豆事件高通量筛选方法
IF 1.4 3区 农林科学 Q4 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-08-28 DOI: 10.1007/s00003-024-01524-6
Liming Dong, Congcong Li, Zhenjuan Xing, Yuxuan He, Wei Xia, Yijun Liu, Likun Long, Feiwu Li

Genetically modified (GM) crops and their products are regulated in many countries. To meet increasing regulatory requirements for a growing number of GM soybean events, high-throughput and cost-effective detection methods are indispensable. In this study, 14 widely commercialized GM soybean events, including GTS40-3-2, MON89788, CV127, A2704-12, A5547-127, 305423, 356043, MON87701, MON87705, MON87708, MON87769, SYHT0H2, FG72, and DAS-444Ø6-6 were utilized as targets for event-specific identification. A high-throughput detection method was established by integrating a single universal primer multiplex PCR (SUP-M-PCR) with capillary electrophoresis technique. This method enables the identification of 14 soybean events in a single PCR reaction, addressing the limitations of conventional multiplex PCR such as self-inhibition and amplification variations between different primers. Furthermore, it significantly enhances the sensitivity and accuracy of previous multiple detection methods, achieving a detection sensitivity of 0.05% (w/w). Overall, this approach greatly improves detection efficiency and holds promising potential for the identification and detection of 14 types of GM soybean events and their derivatives.

转基因作物及其产品在许多国家都受到监管。为了满足日益增多的转基因大豆事件的监管要求,高通量、高性价比的检测方法必不可少。本研究以 GTS40-3-2、MON89788、CV127、A2704-12、A5547-127、305423、356043、MON87701、MON87705、MON87708、MON87769、SYHT0H2、FG72 和 DAS-444Ø6-6 等 14 个广泛商业化的转基因大豆事件为目标,进行事件特异性鉴定。通过将单一通用引物多重 PCR(SUP-M-PCR)与毛细管电泳技术相结合,建立了一种高通量检测方法。该方法可在一次 PCR 反应中鉴定 14 个大豆事件,解决了传统多重 PCR 的局限性,如自抑制和不同引物之间的扩增差异。此外,该方法还大大提高了以往多重检测方法的灵敏度和准确性,检测灵敏度达到 0.05%(重量比)。总之,这种方法大大提高了检测效率,有望用于 14 种转基因大豆事件及其衍生物的鉴定和检测。
{"title":"A high-throughput screening method for GM soybean events based on single universal primer multiplex PCR and capillary electrophoresis","authors":"Liming Dong,&nbsp;Congcong Li,&nbsp;Zhenjuan Xing,&nbsp;Yuxuan He,&nbsp;Wei Xia,&nbsp;Yijun Liu,&nbsp;Likun Long,&nbsp;Feiwu Li","doi":"10.1007/s00003-024-01524-6","DOIUrl":"10.1007/s00003-024-01524-6","url":null,"abstract":"<div><p>Genetically modified (GM) crops and their products are regulated in many countries. To meet increasing regulatory requirements for a growing number of GM soybean events, high-throughput and cost-effective detection methods are indispensable. In this study, 14 widely commercialized GM soybean events, including GTS40-3-2, MON89788, CV127, A2704-12, A5547-127, 305423, 356043, MON87701, MON87705, MON87708, MON87769, SYHT0H2, FG72, and DAS-444Ø6-6 were utilized as targets for event-specific identification. A high-throughput detection method was established by integrating a single universal primer multiplex PCR (SUP-M-PCR) with capillary electrophoresis technique. This method enables the identification of 14 soybean events in a single PCR reaction, addressing the limitations of conventional multiplex PCR such as self-inhibition and amplification variations between different primers. Furthermore, it significantly enhances the sensitivity and accuracy of previous multiple detection methods, achieving a detection sensitivity of 0.05% (w/w). Overall, this approach greatly improves detection efficiency and holds promising potential for the identification and detection of 14 types of GM soybean events and their derivatives.</p></div>","PeriodicalId":622,"journal":{"name":"Journal of Consumer Protection and Food Safety","volume":"19 4","pages":"445 - 454"},"PeriodicalIF":1.4,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142187421","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Migration of chloropropanols 3-MCPD and 1,3-DCP from paper straws into food simulants in comparison with cold water extraction 纸吸管中氯丙醇-3-氯丙二醇和 1,3-二氯丙醇向食品模拟物中的迁移与冷水提取的比较
IF 1.4 3区 农林科学 Q4 FOOD SCIENCE & TECHNOLOGY Pub Date : 2024-08-23 DOI: 10.1007/s00003-024-01523-7
Claudia Wälchli, Jürg Daniel, Nadine Bohni

Chloropropanols such as 1,3-dichloro-2-propanol (1,3-DCP) and 3-monochloropropane-1,2-diol (3-MCPD) can be present in wet-resistant paper food contact articles and migrate into aqueous food. Due to their potential carcinogenicity, residual levels in food are a target of consumer protection. Assessment of compliance of paper food contact articles regarding chloropropanols is commonly done using cold water extraction according to EN 645. However, this gives limited information on actual consumer exposure. To support risk assessment, migration of chloropropanols from paper straws into food simulants was compared to cold water extraction. Established methods using silylation with MSTFA and GC-MS/MS were adapted for food simulants B and D1. While absolute concentrations were higher in cold water extracts, released amounts were similar when accounting for sample weight and simulant volume. For uncoated paper under foreseeable use conditions, cold water extraction results can estimate exposure. Paper straws compliant with BfR recommendation XXXVI limits do not considerably contribute to total 3-MCPD intake. Thus, enforcing these limits is suitable to protect consumers from harmful chloropropanol exposure from food contact materials.

1,3-二氯-2-丙醇(1,3-DCP)和 3-单氯-1,2-丙二醇(3-MCPD)等氯丙醇可能存在于耐湿纸食品接触用品中,并迁移到含水食品中。由于其潜在的致癌性,食品中的残留量是消费者保护的目标之一。根据 EN 645 标准,通常使用冷水萃取法来评估纸质食品接触材料是否符合氯丙醇的要求。但是,这只能提供消费者实际接触的有限信息。为了支持风险评估,将纸吸管中的氯丙醇迁移到食品模拟物中与冷水提取进行了比较。使用 MSTFA 和 GC-MS/MS 进行硅烷化的既定方法适用于食品模拟物 B 和 D1。虽然冷水提取物中的绝对浓度较高,但考虑到样品重量和模拟物体积,释放量相差无几。在可预见的使用条件下,对于未涂布纸,冷水萃取结果可估算出暴露量。符合 BfR 建议 XXXVI 限制的纸吸管不会对氯丙二醇的总摄入量产生重大影响。因此,执行这些限值可保护消费者不会从食品接触材料中摄入有害的氯丙醇。
{"title":"Migration of chloropropanols 3-MCPD and 1,3-DCP from paper straws into food simulants in comparison with cold water extraction","authors":"Claudia Wälchli,&nbsp;Jürg Daniel,&nbsp;Nadine Bohni","doi":"10.1007/s00003-024-01523-7","DOIUrl":"10.1007/s00003-024-01523-7","url":null,"abstract":"<div><p>Chloropropanols such as 1,3-dichloro-2-propanol (1,3-DCP) and 3-monochloropropane-1,2-diol (3-MCPD) can be present in wet-resistant paper food contact articles and migrate into aqueous food. Due to their potential carcinogenicity, residual levels in food are a target of consumer protection. Assessment of compliance of paper food contact articles regarding chloropropanols is commonly done using cold water extraction according to EN 645. However, this gives limited information on actual consumer exposure. To support risk assessment, migration of chloropropanols from paper straws into food simulants was compared to cold water extraction. Established methods using silylation with MSTFA and GC-MS/MS were adapted for food simulants B and D1. While absolute concentrations were higher in cold water extracts, released amounts were similar when accounting for sample weight and simulant volume. For uncoated paper under foreseeable use conditions, cold water extraction results can estimate exposure. Paper straws compliant with BfR recommendation XXXVI limits do not considerably contribute to total 3-MCPD intake. Thus, enforcing these limits is suitable to protect consumers from harmful chloropropanol exposure from food contact materials.</p></div>","PeriodicalId":622,"journal":{"name":"Journal of Consumer Protection and Food Safety","volume":"19 4","pages":"377 - 381"},"PeriodicalIF":1.4,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142187422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Journal of Consumer Protection and Food Safety
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