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Indoor air pollution by solid fuel usages for cooking is longitudinally associated with possible sarcopenia in middle-aged Chinese population 使用固体燃料做饭造成的室内空气污染与中国中年人群可能出现的肌少症纵向相关
IF 3.4 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-06-18 DOI: 10.1007/s40201-024-00911-3
Guo Ming Su, Ke Xin Jia, Jun Yi Liu, Xu Chen, Yi Lin Shen, Jia Jing Cai, Qi Wei Guo, Jia Lin, Ding Zhi Fang

Objectives

The Asia Working Group of Sarcopenia (AWGS) 2019 consensus proposed a new concept named “possible sarcopenia”. The present study was to estimate the association between indoor air pollution by solid fuel usages for cooking and possible sarcopenia among middle-aged and older Chinese population.

Methods

A longitudinal cohort analysis was carried out using nationally representative data from the China Health and Retirement Longitudinal Study (CHARLS). A total of 17,708 participants were recruited and followed up in the CHARLS. Cox proportional hazards models were used to estimate the effects of cooking fuel usages on the new onset of possible sarcopenia. Stratified analyses were performed according to gender and age, and sensitivity analyses were performed using the complete dataset.

Results

A total of 4,653 participants were included in the final cohort analysis. During the follow-up of 4 years (2011–2015), a total of 1,532 (32.92%) participants developed new-onset possible sarcopenia. Compared with clean fuel usages for cooking, solid fuel usages were associated with a higher risk of possible sarcopenia (HR = 1.37, 95% CI = 1.23—1.52, p-value < 0.001). After adjusting for potential confounders, there was a trend for association between solid fuel usages and an increased risk of possible sarcopenia. Stratified analyses by gender and age demonstrated a stronger association of the solid fuel usages with possible sarcopenia in the middle-aged female participants (Model 1: HR = 1.83, 95% CI = 1.24—2.69, p-value = 0.002; Model 2: HR = 1.65, 95% CI = 1.10—2.47, p-value = 0.016). Sensitivity analyses indicated that the results were robust.

Conclusion

Indoor air pollution from solid fuel usages for cooking was a modifiable risk factor for sarcopenia, especially in middle-aged female population. These findings provide a new prevention strategy to reduce the growing burden of sarcopenia, especially for middle-aged female individuals using solid fuels for cooking.

目的 亚洲肌肉疏松症工作组(AWGS)2019年共识提出了 "可能的肌肉疏松症 "这一新概念。本研究旨在估算使用固体燃料烹饪造成的室内空气污染与中国中老年人群可能患上的 "肌少症 "之间的关系。方法利用中国健康与退休纵向研究(CHARLS)中具有全国代表性的数据进行纵向队列分析。中国健康与退休纵向研究共招募并随访了 17708 名参与者。研究采用 Cox 比例危险模型来估算烹饪燃料的使用对新发肌少症的影响。根据性别和年龄进行了分层分析,并使用完整数据集进行了敏感性分析。在 4 年的随访期间(2011-2015 年),共有 1,532 人(32.92%)可能患上了新发肌少症。与使用清洁燃料做饭相比,使用固体燃料与可能患上肌肉疏松症的较高风险相关(HR = 1.37,95% CI = 1.23-1.52,P值为0.001)。在对潜在混杂因素进行调整后,使用固体燃料与可能患肌少症的风险增加之间存在关联趋势。按性别和年龄进行的分层分析表明,使用固体燃料与中年女性参与者可能患上肌少症的关系更为密切(模型 1:HR = 1.83,95% CI = 1.24-2.69,p 值 = 0.002;模型 2:HR = 1.65,95% CI = 1.10-2.47,p 值 = 0.016)。结论使用固体燃料做饭造成的室内空气污染是导致肌肉疏松症的一个可改变的风险因素,尤其是在中年女性人群中。这些发现提供了新的预防策略,以减轻日益加重的肌肉疏松症负担,尤其是对使用固体燃料烹饪的中年女性而言。
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引用次数: 0
Sustainable valorisation of kitchen waste through greenhouse solar drying and microwave pyrolysis– technology readiness level for the production of biochar 通过温室太阳能干燥和微波热解实现厨余垃圾的可持续增值--生产生物炭的技术准备水平
IF 3.4 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-06-18 DOI: 10.1007/s40201-024-00909-x
Prathiba Rex, Nagaraj Meenakshisundaram, Praveen Barmavatu

This study proposes an integrated and sustainable approach for the effective conversion of kitchen waste into valuable products through a two-step process. The primary step involves the implementation of greenhouse solar drying to reduce the moisture content of kitchen waste. The secondary step implies microwave pyrolysis for effective degradation of kitchen waste to biooil, biogas and biochar. Biooil and biogas can be used as renewable fuel source. Biochar can be used as soil amendment. Selection of atmospheric conditions for biochar preparation is discussed, highlighting its crucial role in biochar characteristics. This article highlights, technology readiness level of biochar production from kitchen waste to assess the economic viability for the scalability of the process. In this entirety, the conversion of kitchen waste to valuable products through microwave pyrolysis has significant potential to address the challenges posed by high moisture content and heterogenous nature. With continued research and innovation, it is possible to develop a wide array of value-added products from kitchen waste, ultimately leading to a more eco-friendly and economic approach to waste management.

Graphical Abstract

本研究提出了一种综合的可持续方法,通过两个步骤将厨余垃圾有效转化为有价值的产品。第一步是实施温室太阳能干燥,以降低厨余的水分含量。第二步是微波热解,将厨余垃圾有效降解为生物油、生物气和生物炭。生物油和沼气可用作可再生燃料。生物炭可用作土壤改良剂。文章讨论了生物炭制备过程中大气条件的选择,强调了大气条件对生物炭特性的关键作用。本文强调了利用餐厨垃圾生产生物炭的技术准备水平,以评估该工艺可扩展性的经济可行性。从整体上看,通过微波热解将厨余垃圾转化为有价值的产品,在应对高含水量和异质性带来的挑战方面具有巨大潜力。随着研究和创新的不断深入,我们有可能利用餐厨垃圾开发出多种高附加值产品,最终实现更环保、更经济的废物管理方法。
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引用次数: 0
Microplastics in anaerobic digestion: occurrence, impact, and mitigation strategies 厌氧消化中的微塑料:发生、影响和缓解策略
IF 3.4 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-06-18 DOI: 10.1007/s40201-024-00910-4
Mahsa Alimohammadi, Goksel N. Demirer

Microplastic pollution has emerged as a global environmental concern, with pervasive contamination in terrestrial and aquatic ecosystems. This review paper delves into the intricate dynamics of microplastics within anaerobic digestion systems, addressing their occurrence, impact, and potential mitigation strategies. The occurrence of microplastics in anaerobic digesters is widespread, entering these systems through diverse inputs, such as sewage sludge, organic waste, and etc. Microplastics in anaerobic digestion have been associated with potential adverse impacts on biogas production, process performance, microbial communities, and degradation processes, though the relationship is complex and context dependent. This review highlights the urgent need for comprehensive research into the fate of microplastics within anaerobic digesters. Mitigation strategies offer promise in alleviating microplastic contamination, with advanced separation methods, innovative techniques such as magnetic micro-submarines, photocatalytic micro-motors, membrane bioreactors combined with activated carbon filters, rapid sand filtration, or conventional activated sludge, and disintegration-oriented techniques such as electrocatalysis, biodegradation, and thermal decomposition. Nonetheless, there is a significant knowledge gap that necessitates further research into the fate and long-term effects of microplastics in digestate. Collaborative efforts are crucial to addressing this emerging concern and ensuring the sustainability of anaerobic digestion systems in the face of microplastic challenges.

微塑料污染已成为全球环境问题,陆地和水生生态系统普遍受到污染。这篇综述论文深入探讨了厌氧消化系统中微塑料的复杂动态,探讨了它们的出现、影响和潜在的缓解策略。厌氧消化器中的微塑料非常普遍,它们通过污水污泥、有机废物等各种输入物进入厌氧消化系统。厌氧消化系统中的微塑料可能会对沼气生产、工艺性能、微生物群落和降解过程产生不利影响,但这种关系非常复杂,且取决于具体情况。本综述强调,迫切需要对厌氧消化器中微塑料的归宿进行全面研究。通过先进的分离方法、创新技术(如磁性微型潜艇、光催化微型电机、结合活性炭过滤器的膜生物反应器、快速砂滤或传统活性污泥)以及以分解为导向的技术(如电催化、生物降解和热分解),缓解策略有望减轻微塑料污染。尽管如此,目前仍存在巨大的知识差距,需要进一步研究沼渣中微塑料的归宿和长期影响。要解决这个新出现的问题并确保厌氧消化系统在面对微塑料挑战时的可持续性,合作努力至关重要。
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引用次数: 0
Comprehensive systematic review and meta-analysis of microplastic prevalence and abundance in freshwater fish species: the effect of fish species habitat, feeding behavior, and Fulton’s condition factor 淡水鱼类微塑料流行率和丰度的全面系统回顾和荟萃分析:鱼类栖息地、摄食行为和富尔顿条件因子的影响
IF 3.4 4区 环境科学与生态学 Q1 Medicine Pub Date : 2024-06-04 DOI: 10.1007/s40201-024-00907-z
Ramin Nabizadeh Nodehi, Mahdi Hadi, Ahmad Hosseinzadeh, Nahid Azizi

Microplastics are emerging pollutants that cause health problems for aquatic organisms. Fish is one of the important organisms because of its consumption by humankind. The present study examines the abundance and prevalence of microplastics in freshwater fish species through a systematic review study while considering five important factors, i.e. water resources, habitat, feeding behavior, Fulton’s condition factor, and microplastic characteristics. A comprehensive meta-analysis was undertaken to evaluate relevant publications in terms of microplastic abundance. Articles published up to July 30, 2022 were found through Global search engines including, Web of Science, Scopus, and PubMed. In total, 786 articles were found that 53 and 42 articles were used for qualitative review and meta-analysis, respectively. This was carried out by a random-effects model with high heterogeneity (I2 = 99.76%). According to the data, the highest attention in microplastic research in body part and water sources are related to gastrointestinal tract (n = 259 (~ 80%)) and rivers (n = 189 (~ 58%)), respectively. According to the results, the average microplastic prevalence range was 5 -100%, and microplastic abundance was within the 0.04–204 items range per individual. The difference between microplastic prevalence and abundance for the key factors for parametric and nonparametric data were analyzed using Analysis of variance (ANOVA) and the Kruskal-Wallis test, respectively. According to the Baujat plot, two studies (ID: 27 and 25) revealed the minimal influence of microplastics abundance. Conclusively, the average microplastics abundance according to the pooled data, varied between 2.23 and 2.48, with a mean of 2.35 items per individual in the studies overall. It is concluded that the amount of ingested microplastics by fish is related only to physiology (height, weight, and body structure) but not feeding behavior, habitat, and surrounding water.

微塑料是新出现的污染物,会给水生生物带来健康问题。鱼类是重要的生物之一,因为人类食用鱼类。本研究通过系统综述研究探讨了淡水鱼类中微塑料的丰度和流行情况,同时考虑了五个重要因素,即水资源、栖息地、摄食行为、富尔顿条件因子和微塑料特征。我们进行了全面的荟萃分析,以评估微塑料丰度方面的相关出版物。通过全球搜索引擎,包括 Web of Science、Scopus 和 PubMed,找到了截至 2022 年 7 月 30 日发表的文章。共找到 786 篇文章,其中 53 篇和 42 篇分别用于定性审查和荟萃分析。分析采用随机效应模型,异质性较高(I2 = 99.76%)。数据显示,人体部位和水源中微塑料研究关注度最高的分别是胃肠道(n = 259(约 80%))和河流(n = 189(约 58%))。结果显示,微塑料的平均流行率范围在 5 -100% 之间,人均微塑料丰度在 0.04-204 件之间。采用方差分析(ANOVA)和Kruskal-Wallis检验分别分析了参数数据和非参数数据关键因子的微塑料流行率和丰度之间的差异。根据 Baujat 图,两项研究(编号:27 和 25)显示微塑料丰度的影响极小。最后,根据汇总数据,微塑料的平均丰度介于 2.23 和 2.48 之间,总体研究中每个个体的平均微塑料丰度为 2.35 个。结论是,鱼类摄入的微塑料数量只与生理(身高、体重和身体结构)有关,而与摄食行为、栖息地和周围水域无关。
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引用次数: 0
Ultrasound-assisted heterogeneous process for organic dye pollutants destruction using the novel MIL-101(Fe)/ZrO2/MnFe2O4 nanocomposite catalyst from water medium 利用新型 MIL-101(Fe)/ZrO2/MnFe2O4 纳米复合催化剂的超声辅助异相工艺从水介质中去除有机染料污染物
IF 3.4 4区 环境科学与生态学 Q1 Medicine Pub Date : 2024-06-01 DOI: 10.1007/s40201-024-00906-0
Meysam Sadeghi, Pourya Zarshenas

The heterogeneous sonocatalysis is considered as an impressive remediation approach to eliminate the dyeing wastewaters. Among the efficient sonocatalytic remediation, nanocomposite sonocatalysts have grabbed special attention in recent years. In the presence research, the novel MIL-101(Fe)/ZrO2/MnFe2O4 nanocomposite as a magnetically retrievable catalyst was elaborated using the ultrasound-assisted hydrothermal route and its sonocatalytic performance was tested applying the methylene blue (MB), rhodamine B (RhB), congo red (CR), and methyl orange (MO) organic dyes under US/H2O2 system. The as-fabricated nanocomposite is well identified via FESEM, TEM, EDX, EDX elemental dot mappings, AFM, FTIR, XRD, BET, UV-Vis DRS, and VSM. The sonocatalytic destruction outcomes have demonstrated that the MIL-101(Fe)/ZrO2/MnFe2O4 shows appreciable performance for the destruction of MB, RhB, CR, and MO with the yields of 98.17%, 96.35%, 93.40%, and 89.82%, respectively under the optimized conditions of irradiation time of 7 min, dye concentration of 25 mg/L, catalyst amount of 10 mg, US power intensity of 100 W, H2O2 concentration of 4 mM, pH of 7, and temperature of 25 ± 1 °C. The fitted kinetic curves were exhibited a first-order model and the half-life time (t1/2) and reaction rate constant (kapp) of the MB sonodestruction were determined to be 1.20 min and 0.5768 min−1 employing the MIL-101(Fe)/ZrO2/MnFe2O4/US/H2O2 system, respectively. The free OH radicals were having a crucial role in the MB sonodestruction reaction, affirmed via quenching the experiments. Besides, the reusing experiments indicate that the MIL-101(Fe)/ZrO2/MnFe2O4 represents propitious stability and long durability and reminded more than 93% after four cycles.

Graphical Abstract

The metal-organic framework MIL-101(Fe)/ZrO2/MnFe2O4 heterojunction magnetically retrievable nanocomposite was successfully prepared and used as a new sonocatalyst for the destruction of MB, RhB, CR, and MO toxic organic dye pollutants from water medium.

异相声催化被认为是消除染色废水的一种令人印象深刻的修复方法。在高效的声催化修复技术中,纳米复合声催化剂近年来备受关注。本研究采用超声辅助水热法制备了新型 MIL-101(Fe)/ZrO2/MnFe2O4 纳米复合材料作为磁性可回收催化剂,并在 US/H2O2 系统下测试了其对亚甲蓝(MB)、罗丹明 B(RhB)、刚果红(CR)和甲基橙(MO)有机染料的声催化性能。通过 FESEM、TEM、EDX、EDX 元素点阵图、AFM、FTIR、XRD、BET、UV-Vis DRS 和 VSM 对制备的纳米复合材料进行了鉴定。声催化破坏结果表明,在优化条件下,MIL-101(Fe)/ZrO2/MnFe2O4 对 MB、RhB、CR 和 MO 的破坏效果显著,产率分别为 98.17%、96.35%、93.40% 和 89.82%。在辐照时间为 7 分钟、染料浓度为 25 mg/L、催化剂用量为 10 mg、美国功率强度为 100 W、H2O2 浓度为 4 mM、pH 值为 7 和温度为 25 ± 1 °C 的优化条件下,产率分别为 98.17%、96.35%、93.40% 和 89.82%。在 MIL-101(Fe)/ZrO2/MnFe2O4/US/H2O2 系统中,甲基溴超声分解的半衰期(t1/2)和反应速率常数(kapp)分别为 1.20 分钟和 0.5768 分钟-1。通过淬灭实验证实,游离 -OH 自由基在 MB 声波破坏反应中起着关键作用。图解 摘要 成功制备了金属有机框架 MIL-101(Fe)/ZrO2/MnFe2O4异质结磁性可回收纳米复合材料,并将其作为一种新型声催化剂用于破坏水介质中的 MB、RhB、CR 和 MO 有毒有机染料污染物。
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引用次数: 0
Investigation of infectious droplet dispersion in a hospital examination room cooled by split-type air conditioner 使用分体式空调冷却的医院检查室中感染性飞沫扩散情况调查
IF 3.4 4区 环境科学与生态学 Q1 Medicine Pub Date : 2024-05-29 DOI: 10.1007/s40201-024-00905-1
Bahadır Erman Yüce, Onur Can Kalay, Fatih Karpat, Adem Alemdar, Şehime Gülsün Temel, Aslı Görek Dilektaşlı, Emel Bülbül Başkan, Cüneyt Özakın, Burhan Coşkun

The novel coronavirus (SARS-CoV-2) outbreak has spread worldwide, and the World Health Organization (WHO) declared a global pandemic in March 2020. The transmission mechanism of SARS-CoV-2 in indoor environments has begun to be investigated in all aspects. In this regard, many numerical studies on social distancing and the protection of surgical masks against infection risk have neglected the evaporation of the particles. Meanwhile, a 1.83 m (6 feet) social distancing rule has been recommended to reduce the infection risk. However, it should be noted that most of the studies were conducted in static air conditions. Air movement in indoor environments is chaotic, and it is not easy to track all droplets in a ventilated room experimentally. Computational Fluid Dynamics (CFD) enables the tracking of all particles in a ventilated environment. This study numerically investigated the airborne transmission of infectious droplets in a hospital examination room cooled by a split-type air conditioner with the CFD method. Different inlet velocities (1, 2, 3 m/s) were considered and investigated separately. Besides, the hospital examination room is a model of one of the Bursa Uludag University Hospital examination rooms. The patient, doctor, and some furniture are modeled in the room. Particle diameters considered ranged from 2 to 2000 μm. The evaporation of the droplets is not neglected, and the predictions of particle tracks are shown. As a result, locations with a high infection risk were identified, and the findings that could guide the design/redesign of the hospital examination rooms were evaluated.

新型冠状病毒(SARS-CoV-2)疫情已在全球范围内蔓延,世界卫生组织(WHO)于 2020 年 3 月宣布其为全球大流行病。人们开始对 SARS-CoV-2 在室内环境中的传播机制进行全方位的研究。在这方面,许多关于社会距离和外科口罩抵御感染风险的数值研究都忽略了微粒的蒸发。同时,有人建议采用 1.83 米(6 英尺)的社交距离规则来降低感染风险。不过,需要注意的是,大多数研究都是在静态空气条件下进行的。室内环境中的空气流动是混乱的,要通过实验追踪通风房间中的所有液滴并不容易。计算流体动力学(CFD)可以跟踪通风环境中的所有微粒。本研究利用 CFD 方法对医院检查室中由分体式空调冷却的感染性飞沫的空气传播进行了数值研究。分别考虑和研究了不同的进气速度(1、2、3 m/s)。此外,医院检查室是布尔萨乌鲁达格大学医院检查室的模型。房间内有病人、医生和一些家具。考虑的微粒直径从 2 微米到 2000 微米不等。未忽略液滴的蒸发,并显示了粒子轨迹的预测结果。因此,确定了感染风险较高的位置,并对可指导医院检查室设计/重新设计的结果进行了评估。
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引用次数: 0
Management of caffeine in wastewater using MOF and perovskite materials: optimization, kinetics, and adsorption isotherm modelling 利用 MOF 和过氧化物材料治理废水中的咖啡因:优化、动力学和吸附等温线建模
IF 3 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-05-20 DOI: 10.1007/s40201-024-00904-2
Amira Essam, Samaa Imam Eldek, Nabila Shehata

Pharmaceuticals and personal care products (PPCPs) have been increasingly used all over the world and they have been reported on water cycle and cause contamination. Among these pharmaceuticals is caffeine (CAF). In this work, CAF removal from aqueous samples by metal–organic framework (UIO-66) and perovskite (La0.7Sr0.3FeO3) was achieved. Detailed studies on the preparation of MOFs and perovskite oxides compounds have been presented. Extensive characterizations such as X-Ray diffraction (XRD), field emission scanning electron microscope (FESEM), Fourier transform infrared spectra (FT-IR), N2 adsorption–desorption isotherms were also carried out to assure proper formation and to better understand the physico-chemical behavior of the synthesized samples before and after adsorption. Batch experiments of CAF adsorption onto both MOFs and perovskite were performed to compare the effectiveness of both materials on the removal competence of the CAF residue at different conditions including the effect of pH, initial concentration, and contact time. It was observed that the adsorption capacity of CAF by MOF increased with increasing acidity. On the other hand, the adsorption capacity of perovskite is stable in pH 4–10. The maximum adsorption capacities of UiO-66 and perovskite toward CAF are high as 62.5 mg g−1 and 35.25 mg g−1, respectively. Equilibrium isotherms were investigated by numerous models: Langmuir, Freundlich, Temkin, Redlich-Peterson, Sips, Langmuir-Freundlich, Toth, Kahn, Baudu, and Fritz Schlunder. Moreover, the kinetics of the CAF@MOF and CAF@Perovskite systems have been studied by five kinetic models (Pseudo-1st -order (PFO), Pseudo-2nd -order (PSO), Mixed 1st, 2nd-order, Intraparticle diffusion and Avrami). The best model described the adsorption of CAF onto both of MOF and perovskite was the mixed 1st, 2nd-order model. The metal–organic framework and perovskite were applied to quickly extract CAF from water samples successfully. The maximum removal percentage obtained for MOF and perovskite was 0.89% and 0.94% respectively within 30 min contact time which suggests that these materials are considered as promising adsorbents for CAF.

药品和个人护理产品(PPCPs)在世界各地的使用日益增多,据报道,它们会对水循环造成污染。这些药物中就包括咖啡因(CAF)。在这项工作中,利用金属有机框架(UIO-66)和包晶石(La0.7Sr0.3FeO3)去除了水样中的咖啡因。对 MOFs 和包晶氧化物化合物的制备进行了详细研究。还进行了广泛的表征,如 X 射线衍射 (XRD)、场发射扫描电子显微镜 (FESEM)、傅立叶变换红外光谱 (FT-IR)、N2 吸附-解吸等温线,以确保正确的形成,并更好地了解合成样品在吸附前后的物理化学行为。为了比较两种材料在不同条件下(包括 pH 值、初始浓度和接触时间的影响)去除 CAF 残留物的效果,对 MOFs 和 perovskite 进行了批量吸附实验。结果表明,MOF 对 CAF 的吸附能力随着酸度的增加而增加。另一方面,在 pH 值为 4-10 时,过氧化物的吸附容量比较稳定。UiO-66 和透辉石对 CAF 的最大吸附容量分别高达 62.5 mg g-1 和 35.25 mg g-1。平衡等温线通过多种模型进行了研究:这些模型包括:Langmuir、Freundlich、Temkin、Redlich-Peterson、Sips、Langmuir-Freundlich、Toth、Kahn、Baudu 和 Fritz Schlunder。此外,CAF@MOF 和 CAF@Perovskite 系统的动力学还通过五种动力学模型(伪一阶(PFO)、伪二阶(PSO)、混合一阶、二阶、粒子内扩散和阿夫拉米)进行了研究。描述 CAF 在 MOF 和包晶上吸附的最佳模型是混合一阶、二阶模型。应用金属有机框架和包晶石成功地快速萃取了水样中的 CAF。在 30 分钟的接触时间内,MOF 和 perovskite 的最大去除率分别为 0.89% 和 0.94%,这表明这些材料被认为是有前途的 CAF 吸附剂。
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引用次数: 0
Effective degradation of tetracycline in aqueous solution by an electro-Fenton process using chemically modified carbon/α-FeOOH as catalyst 以化学改性碳/α-FeOOH 为催化剂的电-芬顿工艺有效降解水溶液中的四环素
IF 3 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-05-18 DOI: 10.1007/s40201-024-00902-4
My Linh Nguyen, Hoang Long Ngo, Thuy Tien Nguyen Hoang, Duc Trung Le, Duy Dat Nguyen, Quang Sang Huynh, Thi Tuyet Trinh Nguyen, Thanh Tung Nguyen, Ruey-Shin Juang

This study applied an electro-Fenton process using chemically modified activated carbon derived from rubber seed shells loaded with α-FeOOH (RSCF) as catalyst to remove tetracycline residues from aquatic environment. Catalyst characteristics were evaluated using SEM, EDS, XRD, and XPS, showing successful insertion of iron onto the activated carbon. The effects of the parameters were investigated, and the highest treatment efficiency was achieved at pH of 3, Fe: H2O2 ratio (w/w) of 500:1, catalyst dose of 1 g/L, initial TCH concentration of 100 mg/L, and electric current of 150 mA, with more than 90% of TCH being eliminated within 30 min. Furthermore, even after five cycles of use, the treatment efficiency remains above 90%. The rate constant is calculated to be 0.218 min-1, with high regression coefficients (R2 = 0.93). The activation energy (Ea) was found to be 32.2 kJ/mol, indicating that the degradation of TCH was a simple reaction with a low activation energy. These findings showed that the RSCF is a highly efficient and cost-effective catalyst for TCH degradation. Moreover, the use of e-Fenton process has the advantage of high efficiency, low cost thanks to the recyclability of the catalyst, and environmental friendliness thanks to less use of H2O2.

本研究使用化学改性的橡胶籽壳活性碳(RSCF)作为催化剂,采用电-芬顿工艺去除水生环境中的四环素残留物。使用 SEM、EDS、XRD 和 XPS 对催化剂的特性进行了评估,结果表明铁成功地加入到活性炭中。在 pH 值为 3、铁与 H2O2 的比例(w/w)为 500:1、催化剂剂量为 1 g/L、初始 TCH 浓度为 100 mg/L、电流为 150 mA 的条件下,处理效率最高,在 30 分钟内消除了 90% 以上的 TCH。此外,即使在使用五个周期后,处理效率仍保持在 90% 以上。计算得出的速率常数为 0.218 min-1,回归系数较高(R2 = 0.93)。活化能(Ea)为 32.2 kJ/mol,表明 TCH 的降解是一个活化能较低的简单反应。这些研究结果表明,RSCF 是一种高效、经济的 TCH 降解催化剂。此外,使用 e-Fenton 工艺还具有效率高、成本低(催化剂可回收利用)以及环保(减少 H2O2 的使用)等优点。
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引用次数: 0
Long-term exposure to air pollution on cardio-respiratory, and lung cancer mortality: a systematic review and meta-analysis 长期暴露于空气污染对心肺功能和肺癌死亡率的影响:系统回顾和荟萃分析
IF 3 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-05-09 DOI: 10.1007/s40201-024-00900-6
Behrooz Karimi, Sadegh Samadi

Air pollution is a major cause of specific deaths worldwide. This review article aimed to investigate the results of cohort studies for air pollution connected with the all-cause, cardio-respiratory, and lung cancer mortality risk by performing a meta-analysis. Relevant cohort studies were searched in electronic databases (PubMed/Medline, Web of Science, and Scopus). We used a random effect model to estimate the pooled relative risks (RRs) and their 95% CIs (confidence intervals) of mortality. The risk of bias for each included study was also assessed by Office of Health Assessment and Translation (OHAT) checklists. We applied statistical tests for heterogeneity and sensitivity analyses. The registration code of this study in PROSPERO was CRD42023422945. A total of 88 cohort studies were eligible and included in the final analysis. The pooled relative risk (RR) per 10 μg/m3 increase of fine particulate matter (PM2.5) was 1.080 (95% CI 1.068–1.092) for all-cause mortality, 1.058 (95% CI 1.055–1.062) for cardiovascular mortality, 1.066 (95%CI 1.034–1.097) for respiratory mortality and 1.118 (95% CI 1.076–1.159) for lung cancer mortality. We observed positive increased associations between exposure to PM2.5, PM10, black carbon (BC), and nitrogen dioxide (NO2) with all-cause, cardiovascular and respiratory diseases, and lung cancer mortality, but the associations were not significant for nitrogen oxides (NOx), sulfur dioxide (SO2) and ozone (O3). The risk of mortality for males and the elderly was higher compared to females and younger age. The pooled effect estimates derived from cohort studies provide substantial evidence of adverse air pollution associations with all-cause, cardiovascular, respiratory, and lung cancer mortality.

空气污染是导致全球特定人群死亡的主要原因。这篇综述文章旨在通过进行荟萃分析,调查空气污染与全因、心肺和肺癌死亡风险相关的队列研究结果。我们在电子数据库(PubMed/Medline、Web of Science 和 Scopus)中搜索了相关的队列研究。我们使用随机效应模型来估算死亡率的汇总相对风险(RRs)及其 95% CIs(置信区间)。健康评估与翻译办公室(OHAT)核对表也对每项纳入研究的偏倚风险进行了评估。我们进行了异质性统计检验和敏感性分析。本研究在 PROSPERO 的注册代码为 CRD42023422945。共有 88 项队列研究符合条件并纳入最终分析。细颗粒物(PM2.5)每增加 10 μg/m3 的汇总相对风险 (RR) 为:全因死亡率 1.080 (95% CI 1.068-1.092);心血管死亡率 1.058 (95% CI 1.055-1.062);呼吸系统死亡率 1.066 (95%CI 1.034-1.097);肺癌死亡率 1.118 (95% CI 1.076-1.159)。我们观察到,暴露于 PM2.5、PM10、黑碳(BC)和二氧化氮(NO2)与全因、心血管疾病、呼吸系统疾病和肺癌死亡率呈正相关,但与氮氧化物(NOx)、二氧化硫(SO2)和臭氧(O3)的相关性不显著。男性和老年人的死亡风险高于女性和年轻人。从队列研究中得出的汇集效应估计值提供了大量证据,表明空气污染与全因、心血管、呼吸系统和肺癌死亡率之间存在不利关联。
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引用次数: 0
Improved rare mercury recovery from fluorescent lamp wastes through simultaneous leaching and heating 通过同时进行沥滤和加热,提高荧光灯废料中稀有汞的回收率
IF 3 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-05-07 DOI: 10.1007/s40201-024-00901-5
Leyla Karamzadeh, Esmaeil Salahi, Iman Mobasherpour, Armin Rajabi, Masomeh Javaheri

Mercury is one of the main components of fluorescent lamps. Considering the adverse effects of mercury on human health and the environment, recovery of mercury-containing fluorescent lamps is very important in developed countries. The glass parts of used fluorescent lamps are among the dangerous wastes whose mercury content should be reduced to the lowest possible level according to international standards. The aim of this research is to achieve a systematic approach to minimize the amount of mercury present in fluorescent lamp glass residues according to the European Commission EC95/2002 regulations. In order to extract mercury from glasses, glass pieces were washed with deionized water, using stirring to increase washing efficiency. In order to achieve the maximum amount of extraction, parameters such as ratio of glass to deionized water (S/L), stirring time, temperature and pH were changed. The results showed that, the highest mercury extraction rate is about 98% and in the conditions S/L = 0.1, stirring time of 12 h, temperature of 60 °C and pH 1, which is using a combination of HCl and H3PO4 acid 5% with a ratio of 1:4 has been obtained. The success of this method not only increases environmental sustainability, but also classifies the resulting glass waste as non-hazardous.

汞是荧光灯的主要成分之一。考虑到汞对人类健康和环境的不利影响,回收含汞荧光灯在发达国家非常重要。废旧荧光灯的玻璃部件属于危险废物,根据国际标准,其汞含量应尽可能降低到最低水平。这项研究的目的是根据欧盟委员会 EC95/2002 的规定,采用系统的方法将荧光灯玻璃残渣中的汞含量降至最低。为了提取玻璃中的汞,我们用去离子水清洗玻璃碎片,并通过搅拌提高清洗效率。为了达到最大提取量,改变了玻璃与去离子水的比例(S/L)、搅拌时间、温度和 pH 值等参数。结果表明,在 S/L = 0.1、搅拌时间为 12 小时、温度为 60 °C、pH 值为 1 的条件下,使用 5%的盐酸和 H3PO4 酸以 1:4 的比例组合,汞的萃取率最高,约为 98%。这种方法的成功不仅提高了环境的可持续发展性,还将产生的玻璃废料归类为无害物质。
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引用次数: 0
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Journal of Environmental Health Science and Engineering
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