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Correction to: Perfluoroalkyl and polyfluoroalkyl substances and cancer risk: results from a dose-response meta-analysis 更正:全氟烷基和多氟烷基物质与癌症风险:剂量反应荟萃分析的结果
IF 3 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-17 DOI: 10.1007/s40201-024-00916-y
Jingxuan Yang, Kui Zhang, Jingyi Shi, Zhuo Li, Hao Dai, Wenxing Yang
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引用次数: 0
Efficiency evaluation of a lab-scale photoelectric precipitator for particulate matter emission reduction 用于减少颗粒物排放的实验室规模光电除尘器的效率评估
IF 3 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-16 DOI: 10.1007/s40201-024-00913-1
Kiarash Abdollahzadeh, Somayeh Soleimani-Alyar, Rasoul Yarahmadi

The importance of studying particulate matter lies in its detrimental impact on human health and the environment. Industrial emissions often carry substantial dust content, necessitating the reduction of their environmental release. This study introduced a laboratory-scale photoelectric precipitator to assess its effectiveness in curbing particle emissions under varying temperature, humidity, and residence time conditions. This device operates in two stages: firstly, it charges particles by exposing copper wire surfaces to ultraviolet rays, generating photoelectrons in the airflow; secondly, it utilizes a positively charged collector surface for absorption and collection. Assessment under different temperature, residence time, and humidity conditions revealed that the system designed for 10 μm diameter particles displayed the highest efficiency. At 150℃, the removal efficiency was 39.55%, rising to 41.34% at 60% humidity and 43.58% with an 18-second residence time. Furthermore, increasing energy consumption from 144 j/l to 720 j/l resulted in a 10.93% efficiency increase, highlighting the correlation between energy input and system efficiency. High particulate matter levels diminish visibility, harm the climate, ecosystems, materials, and contribute to respiratory and cardiovascular ailments. These findings underline the photoelectric precipitator’s potential in mitigating particulate matter’s adverse effects on health and the environment. However, further research is warranted to optimize system design and explore additional parameters’ impact on performance, ensuring its effectiveness in industrial processes to reduce particulate matter emissions.

研究微粒物质的重要性在于其对人类健康和环境的有害影响。工业排放物通常含有大量粉尘,因此有必要减少其在环境中的释放量。本研究引入了实验室规模的光电沉淀器,以评估其在不同温度、湿度和停留时间条件下抑制颗粒物排放的效果。该装置分两个阶段运行:首先,它通过将铜丝表面暴露在紫外线下,在气流中产生光电子,从而对颗粒物充电;其次,它利用带正电荷的收集器表面进行吸收和收集。在不同的温度、停留时间和湿度条件下进行的评估显示,为直径 10 μm 的颗粒设计的系统效率最高。温度为 150℃时,清除效率为 39.55%,湿度为 60% 时上升到 41.34%,停留时间为 18 秒时上升到 43.58%。此外,能耗从 144 焦耳/升增加到 720 焦耳/升,效率提高了 10.93%,这突出表明了能量输入与系统效率之间的相关性。颗粒物含量过高会降低能见度,损害气候、生态系统和材料,并导致呼吸系统和心血管疾病。这些发现强调了光电沉淀器在减轻颗粒物对健康和环境的不利影响方面的潜力。不过,还需要进一步研究,以优化系统设计,探索其他参数对性能的影响,确保其在工业流程中减少颗粒物排放的有效性。
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引用次数: 0
Correction: Indoor air pollution by solid fuel usages for cooking is longitudinally associated with possible sarcopenia in middle-aged Chinese population 更正:使用固体燃料做饭造成的室内空气污染与中国中年人群可能出现的肌少症纵向相关
IF 3 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-13 DOI: 10.1007/s40201-024-00915-z
Guo Ming Su, Ke Xin Jia, Jun Yi Liu, Xu Chen, Yi Lin Shen, Jia Jing Cai, Qi Wei Guo, Jia Lin, Ding Zhi Fang
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引用次数: 0
Effects of exposure to trihalomethanes in swimming pool waters on metabolomics profile: a randomized parallel design trial 接触游泳池水体中的三卤甲烷对代谢组学特征的影响:随机平行设计试验
IF 3 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-07-10 DOI: 10.1007/s40201-024-00912-2
Fatemeh Momeniha, Ahmad Jonidi Jafari, Sasan Faridi, Ata Rafiee, Afsaneh Arefi Oskouie

Biological mechanisms of exposure to Trihalomethanes (THMs) in swimming pools remain unclear. Investigation of short-term changes in metabolomic profiles due to exposure to THMs during swimming can help to understand the health effects-related mechanisms. With this in view, we aimed to assess exposure of swimmers to THMs in chlorine and ozone-chlorine swimming pools using the metabolomics approach from September 2020 to January 2021 in Tehran.

Two parallel panels of 29 healthy adult subjects swam over 60 min in either of swimming pools. Blood samples were collected before and 2 h after swimming to assess metabolomic profile using Hydrogen-Nuclear Magnetic Resonance Spectroscopy (H-NMR). Differential metabolites between the two groups were identified by multivariate analysis methods such as Orthogonal Partial Least-Squares Discriminant Analysis (OPLS-DA) and Random Forest (RF).

The levels of THMs in exhaled air as a biomarker of exposure and the metabolic profile as a biomarker of the effect changed significantly between two participants of swimming pools. Based on the significant metabolites, the biochemical pathways were identified by the method of Metabolite Setts Enrichment Analysis (MSEA) and by using the Metaboanalyst platform. The pathways of tryptophan metabolism, galactose metabolism and fructose and mannose metabolism were the most important biochemically significant pathways in individuals after exposure to THMs.

Finally, findings from metabolic changes in our study indicate that exposure to THMs in swimming pools can activate the mechanisms of central nervous system disorders, increased uric acid, increased risk of bladder cancer and oxidative stress.

游泳池中接触三卤甲烷(THMs)的生物机制仍不清楚。调查游泳过程中暴露于三卤甲烷导致的代谢组学特征的短期变化有助于了解与健康影响相关的机制。有鉴于此,我们从 2020 年 9 月到 2021 年 1 月在德黑兰采用代谢组学方法评估了游泳者在氯泳池和臭氧-氯泳池中接触三卤甲烷的情况。游泳前和游泳后 2 小时采集血液样本,使用氢核磁共振波谱(H-NMR)评估代谢组学特征。通过正交部分最小二乘判别分析(OPLS-DA)和随机森林(RF)等多元分析方法,确定了两组之间的差异代谢物。根据重要的代谢物,利用代谢物集富集分析(MSEA)方法和 Metaboanalyst 平台确定了生化途径。色氨酸代谢途径、半乳糖代谢途径以及果糖和甘露糖代谢途径是暴露于三卤甲烷后个体最重要的生化重要途径。最后,我们的研究从代谢变化中得出的结论表明,暴露于游泳池中的三卤甲烷可激活中枢神经系统紊乱、尿酸增加、膀胱癌风险增加和氧化应激机制。
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引用次数: 0
Odour and indoor air quality hazards in railway cars: an Australian mixed methods case study 火车车厢异味和室内空气质量危害:澳大利亚混合方法案例研究
IF 3 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-06-24 DOI: 10.1007/s40201-024-00908-y
Shaneel Chandra, Lisa Bricknell, Sandrine Makiela, Sherie Bruce, Anjum Naweed

Purpose

This case study aimed to diagnose the cause(s) of a seasonal, and objectionable odour reported by travellers and drivers in the railway cars of Australian passenger trains. The research questions were to: (1) identify whether significant microbial colonisation was present within the air handling system of trains and causing the odours; to (2) identify other potential sources and; (3) remedial options for addressing the issue.

Methods

A mixed-methods, action research design was used adopted. Sections of the heating, ventilation, and air conditioning (HVAC) systems from odour-affected trains were swabbed for bacteria and fungi and examined for evidence of wear, fatigue and damage on-site and off-site. Insulation foam material extracted from the walls of affected trains was also subjected to a chemical assessment following exposure to varying humidity and temperature conditions in a climate simulator. This was accompanied by a qualitative sensory characterisation.

Results

Upon exposure to a variety of simulated temperature and humidity combinations to recreate the odour, volatile chemical compounds released from the insulation foam by water were identified as its likely cause. In addition, a range of potentially serious pathogenic and odour-causing microbes were cultured from the HVAC systems, although it is considered unlikely that bacterial colonies were the odour source.

Conclusion

The research has implications for the sanitising and maintenance policies for HVAC systems on public transport, especially when operating in humid environments. The sanitary imposition, especially in the wake of COVID-19 may be required to ensure the safety of the travelling public and drivers.

目的 本案例研究旨在诊断澳大利亚客运列车车厢内旅客和司机反映的季节性异味的原因。研究问题包括(方法 采用了混合方法的行动研究设计。对受异味影响列车的供暖、通风和空调(HVAC)系统部分进行了细菌和真菌拭抹,并检查了现场和场外的磨损、疲劳和损坏迹象。在气候模拟器中暴露于不同湿度和温度条件下后,还对从受影响列车内壁提取的隔热泡沫材料进行了化学评估。结果在暴露于各种模拟温度和湿度组合以重现气味后,隔热泡沫遇水释放出的挥发性化学物质被确定为可能的原因。此外,还从暖通空调系统中培养出了一系列潜在的严重致病和致臭微生物,但认为细菌菌落不太可能是臭味的来源。为确保乘客和司机的安全,可能需要实施卫生措施,特别是在 COVID-19 之后。
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引用次数: 0
Indoor air pollution by solid fuel usages for cooking is longitudinally associated with possible sarcopenia in middle-aged Chinese population 使用固体燃料做饭造成的室内空气污染与中国中年人群可能出现的肌少症纵向相关
IF 3 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-06-18 DOI: 10.1007/s40201-024-00911-3
Guo Ming Su, Ke Xin Jia, Jun Yi Liu, Xu Chen, Yi Lin Shen, Jia Jing Cai, Qi Wei Guo, Jia Lin, Ding Zhi Fang

Objectives

The Asia Working Group of Sarcopenia (AWGS) 2019 consensus proposed a new concept named “possible sarcopenia”. The present study was to estimate the association between indoor air pollution by solid fuel usages for cooking and possible sarcopenia among middle-aged and older Chinese population.

Methods

A longitudinal cohort analysis was carried out using nationally representative data from the China Health and Retirement Longitudinal Study (CHARLS). A total of 17,708 participants were recruited and followed up in the CHARLS. Cox proportional hazards models were used to estimate the effects of cooking fuel usages on the new onset of possible sarcopenia. Stratified analyses were performed according to gender and age, and sensitivity analyses were performed using the complete dataset.

Results

A total of 4,653 participants were included in the final cohort analysis. During the follow-up of 4 years (2011–2015), a total of 1,532 (32.92%) participants developed new-onset possible sarcopenia. Compared with clean fuel usages for cooking, solid fuel usages were associated with a higher risk of possible sarcopenia (HR = 1.37, 95% CI = 1.23—1.52, p-value < 0.001). After adjusting for potential confounders, there was a trend for association between solid fuel usages and an increased risk of possible sarcopenia. Stratified analyses by gender and age demonstrated a stronger association of the solid fuel usages with possible sarcopenia in the middle-aged female participants (Model 1: HR = 1.83, 95% CI = 1.24—2.69, p-value = 0.002; Model 2: HR = 1.65, 95% CI = 1.10—2.47, p-value = 0.016). Sensitivity analyses indicated that the results were robust.

Conclusion

Indoor air pollution from solid fuel usages for cooking was a modifiable risk factor for sarcopenia, especially in middle-aged female population. These findings provide a new prevention strategy to reduce the growing burden of sarcopenia, especially for middle-aged female individuals using solid fuels for cooking.

目的 亚洲肌肉疏松症工作组(AWGS)2019年共识提出了 "可能的肌肉疏松症 "这一新概念。本研究旨在估算使用固体燃料烹饪造成的室内空气污染与中国中老年人群可能患上的 "肌少症 "之间的关系。方法利用中国健康与退休纵向研究(CHARLS)中具有全国代表性的数据进行纵向队列分析。中国健康与退休纵向研究共招募并随访了 17708 名参与者。研究采用 Cox 比例危险模型来估算烹饪燃料的使用对新发肌少症的影响。根据性别和年龄进行了分层分析,并使用完整数据集进行了敏感性分析。在 4 年的随访期间(2011-2015 年),共有 1,532 人(32.92%)可能患上了新发肌少症。与使用清洁燃料做饭相比,使用固体燃料与可能患上肌肉疏松症的较高风险相关(HR = 1.37,95% CI = 1.23-1.52,P值为0.001)。在对潜在混杂因素进行调整后,使用固体燃料与可能患肌少症的风险增加之间存在关联趋势。按性别和年龄进行的分层分析表明,使用固体燃料与中年女性参与者可能患上肌少症的关系更为密切(模型 1:HR = 1.83,95% CI = 1.24-2.69,p 值 = 0.002;模型 2:HR = 1.65,95% CI = 1.10-2.47,p 值 = 0.016)。结论使用固体燃料做饭造成的室内空气污染是导致肌肉疏松症的一个可改变的风险因素,尤其是在中年女性人群中。这些发现提供了新的预防策略,以减轻日益加重的肌肉疏松症负担,尤其是对使用固体燃料烹饪的中年女性而言。
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引用次数: 0
Sustainable valorisation of kitchen waste through greenhouse solar drying and microwave pyrolysis– technology readiness level for the production of biochar 通过温室太阳能干燥和微波热解实现厨余垃圾的可持续增值--生产生物炭的技术准备水平
IF 3 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-06-18 DOI: 10.1007/s40201-024-00909-x
Prathiba Rex, Nagaraj Meenakshisundaram, Praveen Barmavatu

This study proposes an integrated and sustainable approach for the effective conversion of kitchen waste into valuable products through a two-step process. The primary step involves the implementation of greenhouse solar drying to reduce the moisture content of kitchen waste. The secondary step implies microwave pyrolysis for effective degradation of kitchen waste to biooil, biogas and biochar. Biooil and biogas can be used as renewable fuel source. Biochar can be used as soil amendment. Selection of atmospheric conditions for biochar preparation is discussed, highlighting its crucial role in biochar characteristics. This article highlights, technology readiness level of biochar production from kitchen waste to assess the economic viability for the scalability of the process. In this entirety, the conversion of kitchen waste to valuable products through microwave pyrolysis has significant potential to address the challenges posed by high moisture content and heterogenous nature. With continued research and innovation, it is possible to develop a wide array of value-added products from kitchen waste, ultimately leading to a more eco-friendly and economic approach to waste management.

Graphical Abstract

本研究提出了一种综合的可持续方法,通过两个步骤将厨余垃圾有效转化为有价值的产品。第一步是实施温室太阳能干燥,以降低厨余的水分含量。第二步是微波热解,将厨余垃圾有效降解为生物油、生物气和生物炭。生物油和沼气可用作可再生燃料。生物炭可用作土壤改良剂。文章讨论了生物炭制备过程中大气条件的选择,强调了大气条件对生物炭特性的关键作用。本文强调了利用餐厨垃圾生产生物炭的技术准备水平,以评估该工艺可扩展性的经济可行性。从整体上看,通过微波热解将厨余垃圾转化为有价值的产品,在应对高含水量和异质性带来的挑战方面具有巨大潜力。随着研究和创新的不断深入,我们有可能利用餐厨垃圾开发出多种高附加值产品,最终实现更环保、更经济的废物管理方法。
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引用次数: 0
Microplastics in anaerobic digestion: occurrence, impact, and mitigation strategies 厌氧消化中的微塑料:发生、影响和缓解策略
IF 3 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-06-18 DOI: 10.1007/s40201-024-00910-4
Mahsa Alimohammadi, Goksel N. Demirer

Microplastic pollution has emerged as a global environmental concern, with pervasive contamination in terrestrial and aquatic ecosystems. This review paper delves into the intricate dynamics of microplastics within anaerobic digestion systems, addressing their occurrence, impact, and potential mitigation strategies. The occurrence of microplastics in anaerobic digesters is widespread, entering these systems through diverse inputs, such as sewage sludge, organic waste, and etc. Microplastics in anaerobic digestion have been associated with potential adverse impacts on biogas production, process performance, microbial communities, and degradation processes, though the relationship is complex and context dependent. This review highlights the urgent need for comprehensive research into the fate of microplastics within anaerobic digesters. Mitigation strategies offer promise in alleviating microplastic contamination, with advanced separation methods, innovative techniques such as magnetic micro-submarines, photocatalytic micro-motors, membrane bioreactors combined with activated carbon filters, rapid sand filtration, or conventional activated sludge, and disintegration-oriented techniques such as electrocatalysis, biodegradation, and thermal decomposition. Nonetheless, there is a significant knowledge gap that necessitates further research into the fate and long-term effects of microplastics in digestate. Collaborative efforts are crucial to addressing this emerging concern and ensuring the sustainability of anaerobic digestion systems in the face of microplastic challenges.

微塑料污染已成为全球环境问题,陆地和水生生态系统普遍受到污染。这篇综述论文深入探讨了厌氧消化系统中微塑料的复杂动态,探讨了它们的出现、影响和潜在的缓解策略。厌氧消化器中的微塑料非常普遍,它们通过污水污泥、有机废物等各种输入物进入厌氧消化系统。厌氧消化系统中的微塑料可能会对沼气生产、工艺性能、微生物群落和降解过程产生不利影响,但这种关系非常复杂,且取决于具体情况。本综述强调,迫切需要对厌氧消化器中微塑料的归宿进行全面研究。通过先进的分离方法、创新技术(如磁性微型潜艇、光催化微型电机、结合活性炭过滤器的膜生物反应器、快速砂滤或传统活性污泥)以及以分解为导向的技术(如电催化、生物降解和热分解),缓解策略有望减轻微塑料污染。尽管如此,目前仍存在巨大的知识差距,需要进一步研究沼渣中微塑料的归宿和长期影响。要解决这个新出现的问题并确保厌氧消化系统在面对微塑料挑战时的可持续性,合作努力至关重要。
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引用次数: 0
Comprehensive systematic review and meta-analysis of microplastic prevalence and abundance in freshwater fish species: the effect of fish species habitat, feeding behavior, and Fulton’s condition factor 淡水鱼类微塑料流行率和丰度的全面系统回顾和荟萃分析:鱼类栖息地、摄食行为和富尔顿条件因子的影响
IF 3 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-06-04 DOI: 10.1007/s40201-024-00907-z
Ramin Nabizadeh Nodehi, Mahdi Hadi, Ahmad Hosseinzadeh, Nahid Azizi

Microplastics are emerging pollutants that cause health problems for aquatic organisms. Fish is one of the important organisms because of its consumption by humankind. The present study examines the abundance and prevalence of microplastics in freshwater fish species through a systematic review study while considering five important factors, i.e. water resources, habitat, feeding behavior, Fulton’s condition factor, and microplastic characteristics. A comprehensive meta-analysis was undertaken to evaluate relevant publications in terms of microplastic abundance. Articles published up to July 30, 2022 were found through Global search engines including, Web of Science, Scopus, and PubMed. In total, 786 articles were found that 53 and 42 articles were used for qualitative review and meta-analysis, respectively. This was carried out by a random-effects model with high heterogeneity (I2 = 99.76%). According to the data, the highest attention in microplastic research in body part and water sources are related to gastrointestinal tract (n = 259 (~ 80%)) and rivers (n = 189 (~ 58%)), respectively. According to the results, the average microplastic prevalence range was 5 -100%, and microplastic abundance was within the 0.04–204 items range per individual. The difference between microplastic prevalence and abundance for the key factors for parametric and nonparametric data were analyzed using Analysis of variance (ANOVA) and the Kruskal-Wallis test, respectively. According to the Baujat plot, two studies (ID: 27 and 25) revealed the minimal influence of microplastics abundance. Conclusively, the average microplastics abundance according to the pooled data, varied between 2.23 and 2.48, with a mean of 2.35 items per individual in the studies overall. It is concluded that the amount of ingested microplastics by fish is related only to physiology (height, weight, and body structure) but not feeding behavior, habitat, and surrounding water.

微塑料是新出现的污染物,会给水生生物带来健康问题。鱼类是重要的生物之一,因为人类食用鱼类。本研究通过系统综述研究探讨了淡水鱼类中微塑料的丰度和流行情况,同时考虑了五个重要因素,即水资源、栖息地、摄食行为、富尔顿条件因子和微塑料特征。我们进行了全面的荟萃分析,以评估微塑料丰度方面的相关出版物。通过全球搜索引擎,包括 Web of Science、Scopus 和 PubMed,找到了截至 2022 年 7 月 30 日发表的文章。共找到 786 篇文章,其中 53 篇和 42 篇分别用于定性审查和荟萃分析。分析采用随机效应模型,异质性较高(I2 = 99.76%)。数据显示,人体部位和水源中微塑料研究关注度最高的分别是胃肠道(n = 259(约 80%))和河流(n = 189(约 58%))。结果显示,微塑料的平均流行率范围在 5 -100% 之间,人均微塑料丰度在 0.04-204 件之间。采用方差分析(ANOVA)和Kruskal-Wallis检验分别分析了参数数据和非参数数据关键因子的微塑料流行率和丰度之间的差异。根据 Baujat 图,两项研究(编号:27 和 25)显示微塑料丰度的影响极小。最后,根据汇总数据,微塑料的平均丰度介于 2.23 和 2.48 之间,总体研究中每个个体的平均微塑料丰度为 2.35 个。结论是,鱼类摄入的微塑料数量只与生理(身高、体重和身体结构)有关,而与摄食行为、栖息地和周围水域无关。
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引用次数: 0
Ultrasound-assisted heterogeneous process for organic dye pollutants destruction using the novel MIL-101(Fe)/ZrO2/MnFe2O4 nanocomposite catalyst from water medium 利用新型 MIL-101(Fe)/ZrO2/MnFe2O4 纳米复合催化剂的超声辅助异相工艺从水介质中去除有机染料污染物
IF 3 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-06-01 DOI: 10.1007/s40201-024-00906-0
Meysam Sadeghi, Pourya Zarshenas

The heterogeneous sonocatalysis is considered as an impressive remediation approach to eliminate the dyeing wastewaters. Among the efficient sonocatalytic remediation, nanocomposite sonocatalysts have grabbed special attention in recent years. In the presence research, the novel MIL-101(Fe)/ZrO2/MnFe2O4 nanocomposite as a magnetically retrievable catalyst was elaborated using the ultrasound-assisted hydrothermal route and its sonocatalytic performance was tested applying the methylene blue (MB), rhodamine B (RhB), congo red (CR), and methyl orange (MO) organic dyes under US/H2O2 system. The as-fabricated nanocomposite is well identified via FESEM, TEM, EDX, EDX elemental dot mappings, AFM, FTIR, XRD, BET, UV-Vis DRS, and VSM. The sonocatalytic destruction outcomes have demonstrated that the MIL-101(Fe)/ZrO2/MnFe2O4 shows appreciable performance for the destruction of MB, RhB, CR, and MO with the yields of 98.17%, 96.35%, 93.40%, and 89.82%, respectively under the optimized conditions of irradiation time of 7 min, dye concentration of 25 mg/L, catalyst amount of 10 mg, US power intensity of 100 W, H2O2 concentration of 4 mM, pH of 7, and temperature of 25 ± 1 °C. The fitted kinetic curves were exhibited a first-order model and the half-life time (t1/2) and reaction rate constant (kapp) of the MB sonodestruction were determined to be 1.20 min and 0.5768 min−1 employing the MIL-101(Fe)/ZrO2/MnFe2O4/US/H2O2 system, respectively. The free OH radicals were having a crucial role in the MB sonodestruction reaction, affirmed via quenching the experiments. Besides, the reusing experiments indicate that the MIL-101(Fe)/ZrO2/MnFe2O4 represents propitious stability and long durability and reminded more than 93% after four cycles.

Graphical Abstract

The metal-organic framework MIL-101(Fe)/ZrO2/MnFe2O4 heterojunction magnetically retrievable nanocomposite was successfully prepared and used as a new sonocatalyst for the destruction of MB, RhB, CR, and MO toxic organic dye pollutants from water medium.

异相声催化被认为是消除染色废水的一种令人印象深刻的修复方法。在高效的声催化修复技术中,纳米复合声催化剂近年来备受关注。本研究采用超声辅助水热法制备了新型 MIL-101(Fe)/ZrO2/MnFe2O4 纳米复合材料作为磁性可回收催化剂,并在 US/H2O2 系统下测试了其对亚甲蓝(MB)、罗丹明 B(RhB)、刚果红(CR)和甲基橙(MO)有机染料的声催化性能。通过 FESEM、TEM、EDX、EDX 元素点阵图、AFM、FTIR、XRD、BET、UV-Vis DRS 和 VSM 对制备的纳米复合材料进行了鉴定。声催化破坏结果表明,在优化条件下,MIL-101(Fe)/ZrO2/MnFe2O4 对 MB、RhB、CR 和 MO 的破坏效果显著,产率分别为 98.17%、96.35%、93.40% 和 89.82%。在辐照时间为 7 分钟、染料浓度为 25 mg/L、催化剂用量为 10 mg、美国功率强度为 100 W、H2O2 浓度为 4 mM、pH 值为 7 和温度为 25 ± 1 °C 的优化条件下,产率分别为 98.17%、96.35%、93.40% 和 89.82%。在 MIL-101(Fe)/ZrO2/MnFe2O4/US/H2O2 系统中,甲基溴超声分解的半衰期(t1/2)和反应速率常数(kapp)分别为 1.20 分钟和 0.5768 分钟-1。通过淬灭实验证实,游离 -OH 自由基在 MB 声波破坏反应中起着关键作用。图解 摘要 成功制备了金属有机框架 MIL-101(Fe)/ZrO2/MnFe2O4异质结磁性可回收纳米复合材料,并将其作为一种新型声催化剂用于破坏水介质中的 MB、RhB、CR 和 MO 有毒有机染料污染物。
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Journal of Environmental Health Science and Engineering
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