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Prenatal blood lead levels and Birth Weight: a Meta-analysis study 产前血铅水平与出生体重:一项meta分析研究
IF 3.4 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2022-12-26 DOI: 10.1007/s40201-022-00843-w
Mohsen Vigeh, Leyla Sahebi, Kazuhito Yokoyama

Purpose

Lead, a known toxic metal, causes several adverse reproductive effects, including low birth weight. Fortunately, the exposure level has sharply decreased during the recent decades, but a definitive safe level did not introduce for pregnant women yet. The current meta-analysis study aimed to conduct a quantitative estimation of maternal and umbilical cord blood lead effects on birth weight.

Methods

Two researchers have independently searched the scientific literature for retrieving related studies using the PRISMA criteria for data extraction. Twenty-one full-text articles were selected from primary 5006 titles, limited by the English language and published between 1991 and 2020 on humans.

Results

The pooled mean of maternal and umbilical cord blood lead levels were 6.85 µg/dL (95% CI: 3.36–10.34) and 5.41 µg/dL (95%CI: 3.43–7.40), respectively. The correlation coefficient analysis showed a significant inverse association between the mean maternal blood lead level and birth weight, which was confirmed by Fisher Z-Transformation analysis (-0.374, 95% CI: -0.382, -0.365, p < 0.01). In addition, a significantly lower birth weight (∆: 229 gr, p < 0.05) was found in the relatively high level of maternal blood lead than in low-level exposure (> 5 µg/dL vs. ≤ 5 µg/dL, respectively).

Conclusion

In short, the present study findings suggest an increasing maternal blood lead levels could be a potential risk factor for reducing birth weight. Thus, pregnant women should avoid lead exposure, as much as possible.

铅是一种已知的有毒金属,会对生殖造成一些不利影响,包括出生体重过低。幸运的是,近几十年来,暴露水平急剧下降,但还没有确定孕妇的安全水平。当前的荟萃分析研究旨在定量估计母体和脐带血铅对出生体重的影响。方法两名研究者独立检索科学文献,检索相关研究,采用PRISMA标准进行数据提取。从5006个主要标题中选择21篇全文文章,受英语语言限制,并在1991年至2020年间发表在人类身上。结果产妇血铅和脐带血铅的合并平均值分别为6.85µg/dL (95%CI: 3.36 ~ 10.34)和5.41µg/dL (95%CI: 3.43 ~ 7.40)。相关系数分析显示,产妇平均血铅水平与出生体重呈显著负相关,经Fisher Z-Transformation分析证实(-0.374,95% CI: -0.382, -0.365, p < 0.01)。此外,与低水平暴露(分别为5µg/dL和≤5µg/dL)相比,母亲血铅水平相对较高时的出生体重显著降低(∆:229 g, p < 0.05)。总之,目前的研究结果表明,母亲血铅水平升高可能是降低出生体重的潜在危险因素。因此,孕妇应尽量避免接触铅。
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引用次数: 0
Prediction models for groundwater quality parameters using a multiple linear regression (MLR): a case study of Kermanshah, Iran 基于多元线性回归(MLR)的地下水水质参数预测模型:以伊朗Kermanshah为例
IF 3.4 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2022-12-23 DOI: 10.1007/s40201-022-00836-9
Parisa Dargahi, Simin Nasseri, Mahdi Hadi, Ramin Nabizadeh Nodehi, Amir Hossein Mahvi

Groundwater is one of the major sources of exploitation in arid and semiarid regions. Spatial and temporal quality distribution is an important factor in groundwater management. Thus for protecting groundwater quality, data production on spatial and temporal distribution is essential. The present study has applied multiple linear regression (MLR) techniques to predict the fitness of groundwater quality in Kermanshah province, west of Iran. The parameters examined were Total dissolved solids (TDS), Total hardness (TH), Sodium adsorption ratio (SAR). the quality variables were modelled by MLR. Finally, the performance of the models was assessed using the coefficient of determination (R2). The relationship between parameters by MLR showed that TDS and water quality parameters in semi-deep wells and aquifers had a strong positive correlation (r = 0.94, r = 0.98) and there was a strong positive significant correlation between SAR and water quality parameters in deep wells and aquifers (r = 0.98, r = 0.99). Also, TH and water quality parameters in all water sources had a strong positive correlation (r = 1). The MLR model could serve as an alternative and cost-effective tool for groundwater quality prediction where there is limitation in laboratory facilities, trained expertise or time. Consequently, the usefulness of these linear regression equations in predicting the groundwater quality is an approach, which can be applied in any other locations.

地下水是干旱半干旱区的主要开发资源之一。水质时空分布是影响地下水管理的重要因素。因此,为了保护地下水的质量,制作时空分布的数据是必不可少的。本研究应用多元线性回归(MLR)技术对伊朗西部克尔曼沙赫省地下水水质适宜性进行了预测。测定的参数有:总溶解固形物(TDS)、总硬度(TH)、钠吸附比(SAR)。质量变量采用MLR建模。最后,使用决定系数(R2)评估模型的性能。MLR与各参数之间的关系表明,TDS与半深井和含水层水质参数呈强正相关(r = 0.94, r = 0.98), SAR与深井和含水层水质参数呈强正显著相关(r = 0.98, r = 0.99)。各水源的TH与水质参数呈较强的正相关关系(r = 1)。在实验室设施、训练有素的专业知识或时间有限的情况下,MLR模型可以作为地下水质量预测的一种替代和具有成本效益的工具。因此,这些线性回归方程在预测地下水质量方面的有效性是一种可以应用于任何其他地点的方法。
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引用次数: 0
Assessment the impact of different fuels used in cement industry on pollutant emissions and ambient air quality: a case study in Egypt 评估水泥工业中使用的不同燃料对污染物排放和环境空气质量的影响:埃及案例研究
IF 3.4 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2022-11-30 DOI: 10.1007/s40201-022-00844-9
Tarek Sayad, Fawzia Ibrahim Moursy, Attia M. El-Tantawi, Mohamed Saad, Mostafa Morsy

This study aims to assess the impact of using different fuels in Egyptian Titan Alexandria Portland Cement Company on emissions and concentrations of pollutants (Total suspended particles (TSP), nitrogen dioxide (NO2‎), and sulfur dioxide (SO2)) and their influence on ambient air quality during the period 2014–2020 using AERMOD dispersion model. The results showed that changing the fuel from natural gas in 2014 to coal mixed with alternative fuels (Tire-Derived Fuel (TDF), Dried Sewage Sludge (DSS), and Refuse Derived Fuels (RDF)) in 2015–2020 caused fluctuating variations in pollutant emissions and concentrations. The highest and lowest maximum concentrations of TSP occurred in 2017 and 2014 respectively, where the TSP is positively correlated with coal, RDF, and DSS and negatively correlated with natural gas, diesel, and TDF. Also, the lowest and highest maximum NO2 concentrations were detected in 2020 and 2016 followed by 2017 respectively, where NO2 is positively correlated with DSS and negatively correlated with TDF and varies with diesel, coal, and RDF. Moreover, the maximum concentrations of SO2 were the lowest in 2018 and highest in 2016 followed by 2017 because of its considerable positive correlation with natural gas and DSS and negative correlation with RDF, TDF, and coal. Generally, it was found that increasing the percentage of TDF and RDF with decreasing the percentage of DSS, diesel, and coal will reduce pollutant emissions and concentrations and enhance ambient air quality.

本研究旨在利用AERMOD分散模型评估2014-2020年埃及泰坦亚历山大波特兰水泥公司使用不同燃料对污染物(总悬浮颗粒(TSP)、二氧化氮(NO2)和二氧化硫(SO2))排放和浓度的影响及其对环境空气质量的影响。结果表明,在2015-2020年将燃料从2014年的天然气转变为煤炭混合替代燃料(轮胎衍生燃料(TDF)、干污泥(DSS)和垃圾衍生燃料(RDF))会导致污染物排放和浓度的波动变化。TSP浓度最大值和最小最大值分别出现在2017年和2014年,其中TSP与煤、RDF和DSS呈正相关,与天然气、柴油和TDF呈负相关。此外,NO2浓度最低和最高分别出现在2020年和2016年,其次是2017年,其中NO2与DSS呈正相关,与TDF负相关,并随柴油、煤炭和RDF变化。SO2的最大浓度在2018年最低,在2016年最高,其次是2017年,因为SO2与天然气和DSS呈显著正相关,与RDF、TDF和煤炭呈显著负相关。总的来说,增加TDF和RDF的比例,降低DSS、柴油和煤炭的比例,可以减少污染物的排放和浓度,改善环境空气质量。
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引用次数: 2
Design and preparation of amino-functionalized core-shell magnetic nanoparticles for photocatalytic application and investigation of cytotoxicity effects 用于光催化应用的氨基功能化核壳磁性纳米颗粒的设计与制备及细胞毒性效应的研究
IF 3.4 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2022-11-30 DOI: 10.1007/s40201-022-00842-x
Zahra Sabouri, Mohammad Sabouri, Samaneh Sadat Tabrizi Hafez Moghaddas, Majid Darroudi

The goal of the current paper was a synthesis of Amino-functionalized Fe3O4@SiO2 core-shell magnetic nanoparticles as a unique efficient photocatalyst for removing organic dyes from aqueous environments. The magnetic Fe3O4@SiO2 core-shell was produced by a silica source to avoid aggregation by the co-precipitation method. Next, functionalized by using 3-Aminopropyltriethoxysilane (APTES) via a post-synthesis link. The chemical structure, magnetic properties, and shape of the manufactured photocatalyst (Fe3O4@SiO2-NH2) were described by XRD, VSM, FT-IR, FESEM, EDAX, and DLS/Zeta potential analyses. The XRD findings approved the successful synthesis of nanoparticles. The photocatalytic activity of Fe3O4@SiO2-NH2 nanoparticles was examined for MB degradation and the degradation performance was about 90% in the optimum conditions. Also, the cytotoxicity of Fe3O4, Fe3O4@SiO2 core-shell, and Fe3O4@SiO2-NH2 nanoparticles was examined on CT-26 cells using an MTT assay, the finding has shown that nanoparticles can be used for inhibiting cancer cells.

Graphical abstract

本文的目标是合成氨基功能化Fe3O4@SiO2核壳磁性纳米颗粒,作为一种独特的高效光催化剂,用于从水环境中去除有机染料。采用共沉淀法制备了磁性Fe3O4@SiO2核壳,避免了团聚。接下来,通过合成后的链接用3-氨基丙基三乙氧基硅烷(APTES)进行功能化。通过XRD, VSM, FT-IR, FESEM, EDAX和DLS/Zeta电位分析对制备的光催化剂(Fe3O4@SiO2-NH2)的化学结构,磁性能和形状进行了表征。XRD结果证实了纳米颗粒的成功合成。考察了Fe3O4@SiO2-NH2纳米粒子对MB的光催化降解活性,在最佳条件下,降解率约为90%。此外,利用MTT法检测了Fe3O4、Fe3O4@SiO2核壳和Fe3O4@SiO2-NH2纳米颗粒在CT-26细胞上的细胞毒性,结果表明纳米颗粒可用于抑制癌细胞。图形抽象
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引用次数: 5
Adsorption of organophosphorus malathion pesticide from aqueous solutions using nano-polypropylene-titanium dioxide composite: Equilibrium, kinetics and Optimization studies 纳米聚丙烯-二氧化钛复合材料吸附水中有机磷马拉硫磷农药:平衡、动力学和优化研究
IF 3.4 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2022-11-24 DOI: 10.1007/s40201-022-00826-x
Mehrnoosh Gholami, Zohre Mosakhani, Asma Barazandeh, Hamid Karyab

Purpose

The purpose of this study was to investigate the applicability of the adsorption process of a persistent organophosphorus pesticide (malathion) from aqueous solutions by using titanium dioxide- polypropylene nanocomposite (Nano-PP/TiO2).

Methods

The structure of Nano-PP/TiO2 was specified by field emission scanning electron microscopes (FE-SEM), fourier-transform infrared spectroscopy (FTIR), brunauer-emmett-teller (BET), and transmission electron microscope (TEM) technologies. Response surface methodology (RSM) was applied to optimize the adsorption of malathion onto Nano-PP/TiO2 and investigates the effects of various experimental parameters including contact time (5-60 min), adsorbent dose (0.5-4 g/l) and initial malathion concentration (5-20000 mg/l). Extraction and analysis of malathion were performed by dispersive liquid-liquid microextraction (DLLME) coupled with a gas chromatography, coupled with flame ionization detector (GC/FID).

Results

The isotherms obtained for Nano-PP/TiO2 revealed that it was a mesoporous material with a total pore volume of 2.06 cm3/g, average pore diameters of 2.48 nm and a surface area of 51.52 m2/g. The obtained results showed that the Langmuir type 2 was the best-fitted model for delegating the equilibrium data of isotherm studies with adsorption capacity of 7.43 mg/g, and pseudo-second-order type 1 for kinetic model. The optimized conditions to achieve the maximum removal (96%) were at a malathion concentration of 7.13 mg/L, contact time of 52 min and adsorbent dose of 0.5 g/L.

Conclusion

Due to its efficient and appropriate function in adsorbing malathion from aqueous solutions, it was revealed that Nano-PP/TiO2 can be used as an effective adsorbent as well as in further studies.

目的研究二氧化钛-聚丙烯纳米复合材料(Nano-PP/TiO2)吸附水中持久性有机磷农药马拉硫磷的适用性。方法采用场发射扫描电镜(FE-SEM)、傅里叶变换红外光谱(FTIR)、布鲁诺尔-埃米特-泰勒(BET)和透射电子显微镜(TEM)等技术对纳米pp /TiO2的结构进行表征。采用响应面法(RSM)优化了马拉硫磷在纳米pp /TiO2上的吸附效果,考察了接触时间(5 ~ 60 min)、吸附剂剂量(0.5 ~ 4 g/l)和初始浓度(5 ~ 20000 mg/l)对吸附效果的影响。采用分散液液微萃取(DLLME) -气相色谱-火焰离子化检测器(GC/FID)对马拉硫磷进行提取和分析。结果纳米pp /TiO2为介孔材料,总孔体积为2.06 cm3/g,平均孔径为2.48 nm,比表面积为51.52 m2/g。结果表明,Langmuir 2型吸附量为7.43 mg/g,是表征等温线研究平衡数据的最佳模型,动力学模型为拟二阶1型。当马拉硫磷浓度为7.13 mg/L、接触时间为52 min、吸附剂用量为0.5 g/L时,吸附去除率最高(96%)。结论纳米pp /TiO2对马拉硫磷的吸附性能良好,可作为一种有效的吸附剂,在进一步的研究中具有广阔的应用前景。
{"title":"Adsorption of organophosphorus malathion pesticide from aqueous solutions using nano-polypropylene-titanium dioxide composite: Equilibrium, kinetics and Optimization studies","authors":"Mehrnoosh Gholami,&nbsp;Zohre Mosakhani,&nbsp;Asma Barazandeh,&nbsp;Hamid Karyab","doi":"10.1007/s40201-022-00826-x","DOIUrl":"10.1007/s40201-022-00826-x","url":null,"abstract":"<div><h3>Purpose</h3><p>The purpose of this study was to investigate the applicability of the adsorption process of a persistent organophosphorus pesticide (malathion) from aqueous solutions by using titanium dioxide- polypropylene nanocomposite (Nano-PP/TiO<sub>2</sub>).</p><h3>Methods</h3><p>The structure of Nano-PP/TiO<sub>2</sub> was specified by field emission scanning electron microscopes (FE-SEM), fourier-transform infrared spectroscopy (FTIR), brunauer-emmett-teller (BET), and transmission electron microscope (TEM) technologies. Response surface methodology (RSM) was applied to optimize the adsorption of malathion onto Nano-PP/TiO<sub>2</sub> and investigates the effects of various experimental parameters including contact time (5-60 min), adsorbent dose (0.5-4 g/l) and initial malathion concentration (5-20000 mg/l). Extraction and analysis of malathion were performed by dispersive liquid-liquid microextraction (DLLME) coupled with a gas chromatography, coupled with flame ionization detector (GC/FID).</p><h3>Results</h3><p>The isotherms obtained for Nano-PP/TiO<sub>2</sub> revealed that it was a mesoporous material with a total pore volume of 2.06 cm<sup>3</sup>/g, average pore diameters of 2.48 nm and a surface area of 51.52 m<sup>2</sup>/g. The obtained results showed that the Langmuir type 2 was the best-fitted model for delegating the equilibrium data of isotherm studies with adsorption capacity of 7.43 mg/g, and pseudo-second-order type 1 for kinetic model. The optimized conditions to achieve the maximum removal (96%) were at a malathion concentration of 7.13 mg/L, contact time of 52 min and adsorbent dose of 0.5 g/L.</p><h3>Conclusion</h3><p>Due to its efficient and appropriate function in adsorbing malathion from aqueous solutions, it was revealed that Nano-PP/TiO<sub>2</sub> can be used as an effective adsorbent as well as in further studies.</p></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"21 1","pages":"35 - 45"},"PeriodicalIF":3.4,"publicationDate":"2022-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40201-022-00826-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4948169","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Microbial indicators in municipal solid waste compost and their fate after land application of compost 城市生活垃圾堆肥中的微生物指标及其在堆肥土地施用后的去向
IF 3.4 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2022-11-12 DOI: 10.1007/s40201-022-00841-y
Sepideh Sadeghi, Amir Hossein Nafez, Mahnaz Nikaeen, Farzaneh Mohammadi, Davood Jafary Tady, Maryam Hatamzadeh

Abstract

Despite the extensive agricultural use of municipal solid waste (MSW) compost, there is little information about microbial characteristics of the MSW compost and fate of microorganisms following land application. This study was designed to determine the microbial quality and germination index (GI) of the MSW compost as well as fate of indicator microorganisms after application of MSW compost. The results showed a high fraction of samples are immature (GI < 80). In 27% and 16% of samples fecal coliforms and Salmonella were detected in a range exceeding the recommended value for unrestricted application of compost, respectively. HAdV was also detected in 62% of samples. Fecal enterococci were detected with relatively high concentrations in all samples and showed higher survival rate than other indicators in land-applied MSW compost. The results showed that climate condition significantly contributed to the decline of indicator bacteria in land-applied compost. The results highlight the need for further quality monitoring of compost to ensure that its application does not lead to environmental or human health problems. Furthermore, because of the high concentrations and high survival rate of enterococci in compost samples, they can be specifically proposed as an indicator microorganism for MSW compost quality monitoring.

摘要尽管城市生活垃圾(MSW)堆肥在农业上得到了广泛的应用,但关于城市生活垃圾堆肥的微生物特性和微生物在土地利用后的命运的信息却很少。本试验旨在测定城市生活垃圾堆肥的微生物品质和萌发指数(GI),以及施用城市生活垃圾堆肥后指示微生物的命运。结果显示,大部分样品未成熟(GI < 80)。在27%和16%的样品中,粪便大肠菌群和沙门氏菌的检测值分别超过了无限制施用堆肥的推荐值。在62%的样本中也检测到hav。粪便肠球菌在所有样品中均检测到较高的浓度,其存活率高于其他指标。结果表明,气候条件对土壤堆肥中指示菌数量的下降有显著影响。研究结果强调需要进一步监测堆肥的质量,以确保其应用不会导致环境或人类健康问题。此外,由于肠道球菌在堆肥样品中的高浓度和高存活率,可以专门提出将其作为城市生活垃圾堆肥质量监测的指示微生物。
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引用次数: 0
Determination of biological activities of nanoparticles containing silver and copper in water disinfection with/without ultrasound technique 用/不用超声技术测定水消毒中含银、铜纳米粒子的生物活性
IF 3.4 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2022-11-09 DOI: 10.1007/s40201-022-00839-6
Mustafa Fayadoglu, Elif Fayadoglu, Sevda Er, A Tansu Koparal, A Savas Koparal

The final and most crucial step in obtaining clean water is disinfection. More innovative methods of water disinfection have recently been sought. Water disinfection is a promising application for nanoparticles as disinfectants. As a contribution to the literature, biofilm and metal-containing nanoparticles as antiadhesion inhibitors were used in conjunction with ultrasound in this study. The microbroth dilution test was used to reveal the microbiological antibacterial activities of different concentrations of AgNO3 and CuCl2 containing nanoparticles against the Escherichia coli ATCC 25,922 strain, which is an indicator bacterium in water systems. Antibiofilm activities were then investigated using biofilm attachment and biofilm inhibition tests. The inhibitory effect of nanoparticle ultrasonic waves on biofilm contamination was determined using a novel approach. Human keratinocyte cells (HaCaT cell line) were used in cell culture studies after water disinfection, and their cytotoxic effects were demonstrated using the MTT assay. The findings suggest that the nanoparticles utilized might be a viable choice for water disinfection applications. Furthermore, employing ultrasound at low doses with nanoparticles resulted in greater results. One feasible option is to employ nanoparticles to cleanse water without producing cytotoxicity.

获得洁净水的最后也是最关键的一步是消毒。最近人们一直在寻求更新颖的水消毒方法。水消毒是纳米颗粒消毒剂的一个很有前途的应用。作为文献的贡献,本研究将生物膜和含金属纳米颗粒作为抗粘附抑制剂与超声结合使用。采用微肉汤稀释试验,研究不同浓度AgNO3和CuCl2纳米颗粒对水系统指示菌大肠杆菌ATCC 25,922的抑菌活性。然后通过生物膜附着和生物膜抑制试验研究了抗菌膜的活性。采用一种新的方法研究了纳米粒子超声波对生物膜污染的抑制作用。用人角化细胞(HaCaT细胞系)进行水消毒后的细胞培养研究,用MTT试验证明了其细胞毒性作用。研究结果表明,所使用的纳米颗粒可能是水消毒应用的可行选择。此外,使用低剂量的超声波和纳米颗粒可以取得更好的效果。一个可行的选择是使用纳米颗粒来净化水而不产生细胞毒性。
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引用次数: 2
Microplastics in atmospheric dust samples of Sistan: sources and distribution 锡斯坦大气粉尘样品中的微塑料:来源和分布
IF 3.4 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2022-10-31 DOI: 10.1007/s40201-022-00833-y
Mehdi Shahraki, Mohammad Reza Rezaei Kahkha, Jamshid Piri, Abbas Sharafi, Massoud Kaykhaii

In this work, the amount and physical and chemical characteristics of airborne microplastics (MPs) pollution in dust samples in Sistan, located in the eastern part of Iran, is reported. Sampling stations were selected according to the wind direction and population density. MPs were collected by a static dust sampler and analyzed by optical microscopy and FT-IR spectroscopy. Results showed that the distribution frequency of MPs in residential and non-residential areas was 6 to 11 pieces per 100 g (pcs/100 g) with an average abundance of 9.8 pcs/100 g. Fragmented MPs were approximately consisted 64% of total MPs and their sizes were in the range of 0.9–3.8 mm. Polyethylene (49%), polystyrene (21%) and polyester (18%) were the main MPs presented in the dust samples. It was observed that population density and wind direction were the most important parameters affecting MPs pollution in dust.

本文报道了伊朗东部锡斯坦地区粉尘样品中空气中微塑料(MPs)污染的数量和物理化学特征。根据风向和人口密度选择采样站。采用静态粉尘采样器采集MPs,并用光学显微镜和红外光谱分析。结果表明,MPs在居民点和非居民点的分布频率为6 ~ 11个/ 100g (pcs/ 100g),平均丰度为9.8个/ 100g。碎片化MPs约占总MPs的64%,其大小在0.9 ~ 3.8 mm之间。聚乙烯(49%)、聚苯乙烯(21%)和聚酯(18%)是粉尘样品中主要的MPs。种群密度和风向是影响扬尘中MPs污染最重要的参数。
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引用次数: 4
Investigation of asbestos concentration in ambient and lavage fluids of patients referred for bronchoscopy, Ahvaz 阿瓦士市支气管镜检查患者环境液和灌洗液中石棉浓度的调查
IF 3.4 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2022-10-31 DOI: 10.1007/s40201-022-00797-z
Negar SabzeAli, Nematollah Jaafarzadeh, Maryam Haddadzadeh Shoushtari, Monireh Khadem, Seyed Hamid Borsi, Amir Zahedi, Hanieh Raji

Introduction

The amount of fibers in the lungs is considered to reflect the cumulative intensity of past asbestos exposure, and bronchoalveolar lavage (BAL) has been proposed to be a good indicator of the presence and quantity of asbestos particles in the lungs. This study evaluated the asbestos concentration in BAL fluids of asbestos-exposed and unexposed pulmonary patients and the environment of Ahvaz city.

Methods

This prospective study was conducted on 80 patients underwent diagnostic fiberoptic bronchoscopy referred to Imam Khomeini Hospital in Ahvaz, Iran, in 2019. Patients with Lung diseases were divided into three groups based on CT scan results: normal (n = 32), lung cancer (n = 40) and Interstitial lung disease (n = 8). The analysis of asbestos fiber concentration in BAL fluid was carried out by Scanning Electron Microscope (SEM).

Results

The positive asbestos test was detected in 69% of all subjects, including 64% of whom had asbestos-related jobs and 74.5% of those with non-related jobs (p = 0.240). The concentrations of asbestos fiber in the BAL in normal patients, lung cancer and interstitial fibrosis (ILD) were 8.13 ± 5.38, 9.66 ± 7.30 and 6.31 ± 1.98 f/ml, respectively (P = 0.492). There was no significant difference between the asbestos levels and exposure history (P = 0.877). The mean concentration of asbestos in the ambient air during the current year was 2.69 ± 0.57 f/ml (2.26–3.70), and the correlation between asbestos levels in BAL and the air was not significant (r = 0.147; P = 0.243).

Conclusions

The exposure of different occupational and non-occupational groups to this carcinogenic substance indicates the need for environmental and individual control measures to reduce and prevent asbestos exposure.

肺中纤维的数量被认为反映了过去石棉暴露的累积强度,支气管肺泡灌洗(BAL)被认为是肺中石棉颗粒存在和数量的良好指标。本研究评估了石棉暴露和未暴露的肺患者肺液中的石棉浓度以及阿瓦士市的环境。方法对2019年在伊朗阿瓦士伊玛目霍梅尼医院就诊的80例诊断性纤维支气管镜患者进行前瞻性研究。根据CT扫描结果将肺部疾病患者分为正常(32例)、肺癌(40例)和间质性肺疾病(8例)三组。采用扫描电镜(SEM)对BAL液中石棉纤维浓度进行了分析。结果石棉检测阳性率为69%,其中有石棉相关工作的占64%,无石棉相关工作的占74.5% (p = 0.240)。正常患者、肺癌患者和间质性纤维化患者肺BAL中石棉纤维浓度分别为8.13±5.38、9.66±7.30和6.31±1.98 f/ml (P = 0.492)。石棉水平与暴露史无显著性差异(P = 0.877)。当年环境空气中石棉的平均浓度为2.69±0.57 f/ml (2.26 ~ 3.70), BAL与空气中石棉含量的相关性无统计学意义(r = 0.147;p = 0.243)。结论不同职业和非职业人群对石棉的暴露表明,需要采取环境和个人控制措施来减少和预防石棉暴露。
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引用次数: 0
Synthesis of BiOI@NH2-MIL125(Ti)/Zeolite as a novel MOF and advanced hybrid oxidation process application in benzene removal from polluted air stream 新型MOF BiOI@NH2-MIL125(Ti)/沸石的合成及先进混合氧化工艺在污染气流中苯去除中的应用
IF 3.4 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Pub Date : 2022-10-29 DOI: 10.1007/s40201-022-00837-8
Jamal Mehralipour, Ahmad Jonidi Jafari, Mitra Gholami, Ali Esrafili, Majid Kermani

Abstract

One of the popular process in volatile organic compounds removal in gas phase is advanced oxidation process. We in this research, synthesized BiOI@NH2-MIL125(Ti)/Zeolite nanocomposite as a novel nanocomposite to degradation of benzene in hybrid advanced oxidation process. The nanocomposite synthesized via solvothermal method. The effect of airflow, ozone gas concentration, hydrogen peroxide concentration, relative humidity and initial benzene concentration are the main parameters in the UV/O3/H2O2/ nanocomposite hybrid process that were studied. The characterization by XRD, FT-IR, FESEM, EDS element mapping, TEM, BET, and UV–vis spectra indicated that nanocomposite were well synthesized. Optimal operating conditions of the process were determined at air flow of 0.1 l/min, ozone concentration of 0.3 mg/min, hydrogen peroxide concentration of 150 ppm, relative humidity of 45 ± 3% and benzene concentration of 50 ppmv. Under these conditions, more than 99% of benzene was degraded. The synergistic effect coefficient of the mechanisms is 1.53. The nanocomposite had good stability in the hybrid process and remained above 99% efficiency up to 5 times. The ozone concentration residual the system was reported to be negligible (0.013 mg/min). The CO and CO2 emissions in the hybrid process was higher than other processes, which indicates better mineralization in the hybrid process. Formaldehyde, octane, noonan, phenol, decanoic acid were reported as the main by-products. The results indicated that UV/O3/H2O2/ nanocomposite hybrid process has fantastic efficiency in the degradation of benzene as one of the indicators of VOCs.

摘要高级氧化法是气相挥发性有机物脱除的常用方法之一。在本研究中,我们合成了BiOI@NH2-MIL125(Ti)/沸石纳米复合材料,作为一种新型的纳米复合材料,用于混合深度氧化过程中苯的降解。采用溶剂热法合成纳米复合材料。研究了气流、臭氧气体浓度、过氧化氢浓度、相对湿度和初始苯浓度对UV/O3/H2O2/纳米复合复合工艺的影响。通过XRD、FT-IR、FESEM、EDS元素图、TEM、BET和UV-vis光谱等表征表明,纳米复合材料合成效果良好。确定了该工艺的最佳操作条件:空气流量0.1 l/min,臭氧浓度0.3 mg/min,过氧化氢浓度150 ppm,相对湿度45±3%,苯浓度50 ppmv。在此条件下,苯的降解率达99%以上。各机制的协同效应系数为1.53。该纳米复合材料在杂化过程中具有良好的稳定性,效率保持在99%以上的次数高达5次。据报道,该系统的臭氧残留浓度可忽略不计(0.013 mg/min)。混合过程CO和CO2排放量高于其他混合过程,表明混合过程矿化程度较好。主要副产物为甲醛、辛烷、努南、苯酚、癸酸。结果表明,UV/O3/H2O2/纳米复合杂化工艺对作为VOCs指标之一的苯具有良好的降解效果。
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引用次数: 5
期刊
Journal of Environmental Health Science and Engineering
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