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2012 38th IEEE Photovoltaic Specialists Conference最新文献

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Effect of band bending and band offset in the transport of minority carriers across the ordered/disordered interface of a-Si/c-Si heterojunction solar cell a-Si/c-Si异质结太阳能电池中少数载流子在有序/无序界面上输运的能带弯曲和能带偏移影响
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6317605
K. Ghosh, C. Tracy, S. Goodnick, S. Bowden
The transport of photogenerated minority carriers (photocarriers) across the heterointerface of amorphous silicon (a-Si) and crystalline silicon (c-Si) in a-Si/c-Si heterostructure solar cell is shown in this work to critically depend on the non-Maxwellian energy distribution function of those carriers impinging on the heterointerface. A theoretical model is presented that integrates the effect of the high electric field inversion region upon energy distribution function of the impinging carriers with the transmission probability of those carriers across the heterointerface. The transport of the photocarriers across the high electric field inversion region is simulated by the full solution of the Boltzmann transport equation by Monte Carlo technique while the transmission probability of carriers across the heterointerface is calculated through the percolation path technique. The results are discussed under two different condition of band bending; strongly inverted and weakly inverted c-Si surface. The results comparing different conditions of band bending show that the energy distribution of the carriers impinging on the heterointerface is non-Maxwellian and the integrated photocarrier collection increases with the strength of the inversion field since the carrier population is weighted towards higher energy where the transmission probability through the barrier is higher. Thus we demonstrate that hot carriers play an important role in heterostructure cell operation.
在a-Si/c-Si异质结构太阳能电池中,光生少数载流子(光载流子)在非晶硅(a-Si)和晶体硅(c-Si)异质界面上的输运严重依赖于这些载流子撞击异质界面的非麦克斯韦能量分布函数。提出了将高电场反转区对碰撞载流子能量分布函数的影响与这些载流子穿过异质界面的传输概率相结合的理论模型。利用蒙特卡罗技术对玻尔兹曼输运方程的全解模拟了光载流子在高电场反演区的输运,利用渗透路径技术计算了载流子在异质界面上的输运概率。讨论了两种不同带弯曲条件下的结果;强反转和弱反转c-Si表面。对比不同带弯曲条件的结果表明,碰撞在异质界面上的载流子的能量分布是非麦克斯韦式的,由于载流子种群向高能量方向加权,通过势垒的传输概率更高,因此随着反演场的强度增加,集成光载流子收集量增加。因此,我们证明了热载流子在异质结构电池的运行中起着重要的作用。
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引用次数: 3
Investigation of electrical characteristics of P3HT:PCBM organic solar cells P3HT:PCBM有机太阳能电池电学特性研究
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6318167
Yang Shen, Mool C. Gupta
Capacitance of P3HT(poly (3-hexylthiophene-2,5-diyl)):PCBM ([6,6]-phenyl C61-butyric acid methyl ester) bulk heterojunction solar cell was measured at different biases and different temperatures (25°C and 130°C). The capacitance was found to vary with bias voltages, and showed different trends with temperature, but the peak capacitance values and positions did not vary much. Mott-Schottky relation was used to model the behavior of capacitance in reverse bias. The capacitance of pure P3HT showed a different trend as compare to the P3HT:PCBM blend. The peak position did not vary, but the peak values decrease with temperature. Permittivity of P3HT was then calculated and the temperature dependence of exciton binding energy was revealed. The active layer thickness effect on the series resistance was also examined. The results show two regions, the slope quickly changes after certain thickness. Further investigation of electrical prosperities will provide insight on the origin of open circuit voltage and charge transport mechanism.
测定了P3HT(聚(3-己基噻吩-2,5-二基)):PCBM([6,6]-苯基c61 -丁酸甲酯)体异质结太阳能电池在不同偏置和不同温度(25℃和130℃)下的电容。电容值随偏置电压变化,随温度变化趋势不同,但峰值电容值和位置变化不大。采用Mott-Schottky关系来模拟电容在反向偏置下的行为。纯P3HT的电容量与P3HT:PCBM共混物的电容量变化趋势不同。峰的位置没有变化,但峰值随温度的升高而减小。计算了P3HT的介电常数,揭示了激子结合能的温度依赖性。研究了有源层厚度对串联电阻的影响。结果表明:在一定厚度后,坡面发生快速变化;对电繁荣的进一步研究将有助于深入了解开路电压的起源和电荷传输机制。
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引用次数: 10
Transparent conductive oxide / encapsulant interface characterization following Damp Heat exposure 湿热暴露后透明导电氧化物/密封剂界面特性
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6317659
K. Stika, S. Pélisset, S. Schreiber, F. de Borman Chautems, P. Dafniotis, Laure‐Emmanuelle Perret‐Aebi, C. Ballif
The role of surface analysis, specifically XPS (X-ray Photoelectron Spectroscopy) and SIMS (Secondary Ion Mass Spectrometry) has been explored to broaden our understanding of TCO / encapsulant interactions focusing on TCO resistivity evolution. Peel laminates of PVB, Ionomer and EVA encapsulants with LPCVD boron doped ZnO were exposed to Damp Heat and removed at different points in the aging cycle for analysis. Distinct response patterns were observed for the different encapsulant families and selected ionomers were found to be most effective at protecting and maintaining the conductivity of the TCO. Trends in interfacial ion enrichment as a function of damp heat exposure were determined by a combination of XPS and SIMS to provide the necessary quantitation, sensitivity and surface specificity. In this study, the transition from a cohesive peel within the encapsulant toward an adhesive peel between the TCO and encapsulant layers provided an important point of comparison. Depth profiling to determine the distribution of mobile species throughout the thickness of the TCO added yet another dimension to our understanding of TCO / encapsulant interactions.
表面分析,特别是XPS (x射线光电子能谱)和SIMS(次级离子质谱)的作用已经被探索,以扩大我们对TCO /封装剂相互作用的理解,重点是TCO电阻率的演变。将LPCVD硼掺杂ZnO的PVB、离聚体和EVA封装层暴露在湿热环境中,并在老化周期的不同时间点移除以进行分析。在不同的封装剂家族中观察到不同的响应模式,并且发现选择的离聚物在保护和维持TCO的导电性方面最有效。为了提供必要的定量、灵敏度和表面特异性,结合XPS和SIMS测定了界面离子富集作为湿热暴露函数的趋势。在这项研究中,从封装剂内部的粘合剥离到TCO和封装剂层之间的粘合剥离的转变提供了一个重要的比较点。通过深度分析来确定整个TCO厚度的流动物种分布,为我们对TCO /封装剂相互作用的理解增加了另一个维度。
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引用次数: 0
Novel dual-layered passivation approach for 18.8% efficiency laser doped selective emitter cells 18.8%效率激光掺杂选择性发射极电池的新型双层钝化方法
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6317772
Tseng-Jung Chang, Te-Yu Wei, S. H. Chen, Li-Wei Cheng
A new approach for performance improvement of laser doped selective emitter cells with dual dielectric passivation layers was demonstrated. Taking advantage of recovery of laser induced defects and emitter passivation of dual dielectric layer, a new scheme has been implemented to laser doped selective emitter cells. With this dual layer structure, it is shown that both of the lightly doped and laser treated areas get higher photoluminescence response and the open circuit voltage increases from 636mV to 640mV, compared to conventional single dielectric passivation layer. The slightly optical loss is a trade-off on this kind of dual-layered passivation due to non-optimum refraction match for light trapping, but this can be compensated by better internal quantum response. Laser doped selective emitter cells with dual-layered passivation scheme show 18.8% efficiency in average with 0.3%abs efficiency gain, compared to single layer passivated cells.
提出了一种提高双介质钝化层激光掺杂选择性发射极电池性能的新方法。利用激光诱导缺陷的恢复和双介质层的发射极钝化,实现了激光掺杂选择性发射极电池的新方案。结果表明,与传统的单介质钝化层相比,轻掺杂区和激光处理区都获得了更高的光致发光响应,开路电压从636mV提高到640mV。轻微的光学损失是这种双层钝化的代价,这是由于光捕获的非最佳折射匹配,但这可以通过更好的内部量子响应来补偿。与单层钝化电池相比,采用双层钝化方案的激光掺杂选择性发射极电池平均效率为18.8%,abs效率增益为0.3%。
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引用次数: 0
Large-grain polysilicon seed layers on glass for epitaxial silicon solar cells 外延硅太阳能电池用玻璃上的大颗粒多晶硅种子层
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6317639
S. Shumate, H. Mohammed, D. Hutchings, H. Naseem
Thin-film silicon solar cells remain a promising technology to approach wafer-based efficiencies at thin-film costs. Epitaxial growth of silicon cells on seed layers has been a prominent approach with demonstrated efficiencies. However, cost-effective seed layers on glass or other low-cost substrates still remain one of the biggest road blocks to the success of this technology. Top-down aluminum induced crystallization (TAIC) has been developed to produce large-grain silicon seed layers on glass. Initial cells have been fabricated by Hot-Wire CVD at the National Renewable Energy Laboratory (NREL). The seed layers with grain-gaps show poor electrical characteristics comparable to reported cells grown on wafer templates with defect densities around 2 × 106 cm-3. New seed layers without grain gaps have been developed and are in queue for cell fabrication.
薄膜硅太阳能电池仍然是一种很有前途的技术,以薄膜成本接近晶圆基效率。硅细胞在种子层上的外延生长一直是一个突出的方法,并证明了效率。然而,在玻璃或其他低成本基板上具有成本效益的种子层仍然是该技术成功的最大障碍之一。自顶向下铝诱导结晶技术(TAIC)已被开发用于在玻璃上生产大晶粒硅种子层。最初的电池是在国家可再生能源实验室(NREL)用热线CVD制造的。与在缺陷密度约为2 × 106 cm-3的晶圆模板上生长的细胞相比,具有晶粒间隙的种子层表现出较差的电特性。没有颗粒间隙的新种子层已经形成,正在等待细胞制造。
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引用次数: 3
Dry-epitaxial lift-off, integration, interconnect and encapsulation of foldable/rollable high efficiency solar cell modules 可折叠/可卷曲高效太阳能电池组件的干外延提升、集成、互连和封装
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6318187
J. Farah
OptiCOMP Networks is developing a new method for manufacturing thin, lightweight, flexible, portable high efficiency III-V PV modules that can be folded and rolled for space and terrestrial applications. Multi-junction inverted (IMM3J) and non-inverted cells are lifted off the Ge or GaAs growth wafer and transferred to inexpensive flexible polyimide permanent carrier substrate. The lift-off happens in fraction of a second. OptiCOMP uses proprietary materials and bonding techniques. No expensive ion implantation or slow chemical etching of a sacrificial layer is needed. Several cells are integrated on a common blanket polymeric sheet and interconnected by soldering copper ribbons. Both sides of the epi-layer can be contacted from the top side of the wafer. This eliminates the need for copper cladded polymeric substrates and reduces weight. The cells were fully encapsulated using transparent spray-on polyimide layer which replaces the cover glass. The thickness and CTE of the blanket polyimide layer were chosen to stress-balance the structure so that it remains flat in spite of 300°C temperature variations in orbit. The entire solar cell structure is less than 250 μm thick and achieves a specific power ratio of 340 W/kg. The base wafer is reused to grow another epi-layer and the cycle repeated. The cost of substrate materials is about 40% of the cost of the finished cell. OptiCOMP's process will result in savings in raw materials up to 30% of the cost of the cell and will enable terrestrial applications.
OptiCOMP网络公司正在开发一种制造轻薄、灵活、便携、高效的III-V型光伏模块的新方法,该模块可以折叠和卷起,用于空间和地面应用。多结倒置电池(IMM3J)和非倒置电池从Ge或GaAs生长晶片上剥离,转移到廉价的柔性聚酰亚胺永久载体衬底上。升空发生在几分之一秒内。OptiCOMP使用专有材料和粘合技术。不需要昂贵的离子注入或缓慢的化学蚀刻牺牲层。几个电池集成在一个共同的毛毯聚合物片,并通过焊接铜带相互连接。外延层的两侧可以从晶圆片的顶部接触。这消除了对铜包覆聚合物基板的需求,并减轻了重量。使用透明的喷涂聚酰亚胺层取代覆盖玻璃,将电池完全封装。选择毯子聚酰亚胺层的厚度和CTE来平衡结构的应力,使其在轨道上300°C的温度变化下保持平坦。整个太阳能电池结构厚度小于250 μm,比功率比达到340 W/kg。基础晶圆被重复使用以生长另一个外延层,并重复此循环。衬底材料的成本约占成品电池成本的40%。OptiCOMP的工艺将节省高达30%的电池成本,并将使地面应用成为可能。
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引用次数: 2
Insolation dependent solar module performance evaluation from PV monitoring data 基于光伏监测数据的太阳能组件性能评估
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6317834
V. Herbort, R. von Schwerin, B. Compton, L. Brecht, H. te Heesen
The quality and performance of the components of a photovoltaic (PV) power plant has an effect on its energy yield. Therefore, it is sensible to select the best performing components in order to get maximized energy yield. But for example the performance of PV modules is often only known at standard test conditions (STC) which are most of the time artificially created in laboratories. Measurement data of over 24,000 PV plants deployed at sites located in Central Europe has been captured for 2009 and 2010. This data was checked by routines in order to provide sufficient data quality. Then it was transformed to STC in order to compare the empiric results of components' performance. This transformation was done using temperature data and plant configuration data e.g. inverter efficiency. With this approach a quasi performance ratio can calculated which allows fair comparism of PV modules and module types under real-life conditions.
光伏电站组件的质量和性能直接影响其发电量。因此,为了获得最大的能量产出,选择性能最好的组件是明智的。但举例来说,光伏组件的性能通常只在标准测试条件(STC)下才知道,而标准测试条件大多是在实验室人为创造的。2009年和2010年,中欧地区超过24000座光伏电站的测量数据已被采集。为了提供足够的数据质量,这些数据通过例程进行检查。然后将其转换为STC,以便比较构件性能的经验结果。这种转换是使用温度数据和设备配置数据(如逆变器效率)完成的。通过这种方法,可以计算出准性能比,从而可以在实际条件下对光伏模块和模块类型进行公平比较。
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引用次数: 6
18.8 % efficient laser-doped semiconductor fingers screen-printed silicon solar cell with light-induced plating 18.8%高效激光掺杂半导体手指屏印刷硅太阳能电池
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6317805
Kee Soon Wang, D. Lin, Xinrui An, L. Mai, E. Mitchell, S. Wenham
The practical realization of high efficiency laser-doped semiconductor fingers (SCF) silicon solar cell is inhibited by high contact resistance. By plating the SCF with metal, a new SCF cell concept known as the “Advanced SCF” (AdvSCF) cell that can resolve the contact resistance problem is presented. In the first AdvSCF cells demonstrated in this work, the nickel (Ni) plating coverage across the cell was found to be non-uniform with Ni voids mostly concentrated around the busbar. This was found to be avoidable by ensuring that the spin-on phosphoric acid dopant layer was uniformly thick across the whole cell area and especially at the busbar. With uniform Ni plating coverage achieved, in a batch of 6 AdvSCF cells, an average batch efficiency of 18.40 % was achieved with the highest at 18.82 %. This was achieved without any experimental optimization of the front grid design or other cell properties, implying that there is potential to achieve significantly higher efficiency levels.
高接触电阻阻碍了高效掺激光半导体指硅太阳能电池的实际实现。通过在SCF上镀金属,提出了一种新的SCF电池概念,称为“高级SCF”(AdvSCF)电池,可以解决接触电阻问题。在这项工作中展示的第一个AdvSCF电池中,发现整个电池的镍(Ni)镀层覆盖不均匀,镍空洞主要集中在母线周围。通过确保自旋磷酸掺杂层在整个电池区域均匀厚,特别是在母线处,发现这是可以避免的。在实现均匀镀镍的情况下,在一批6个AdvSCF电池中,平均批次效率达到18.40%,最高达到18.82%。这是在没有对前网格设计或其他电池特性进行任何实验优化的情况下实现的,这意味着有可能实现显着更高的效率水平。
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引用次数: 3
A control strategy to reduce the effect of intermittent solar radiation and wind velocity in the hybrid photovoltaic/wind SCIG system without losing MPPT 一种在不损失MPPT的情况下降低光伏/风力混合SCIG系统中间歇性太阳辐射和风速影响的控制策略
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6317860
R. Wandhare, V. Agarwal
The intermittent but complimentary nature of solar photovoltaic and wind mill generated power explored a new area of research for the hybrid PV/wind systems. This paper proposes a novel strategy for the control of power conditioning units to minimize the disturbances on the output power from the hybrid system, integrated with PV and wind turbine, in spite of highly intermittent nature of these sources. The proposed scheme balances the wide variation of power yield from wind and/or PV system and provides sufficient margin to the other sources (e.g. hydro, steam turbine, etc.) connected to the system to take over, so that to maintain power balance throughout the operation. The presented strategy makes use of high energy density ultracapacitor to absorb the effect of intermittent solar radiation and widely varying wind velocity. The MPPT associated with these sources remains unaffected and does not hamper overall generation from the system. The DC link of the conventional back to back topology of the wind farm is integrated with the PV panels with their MPPT trackers. The control strategy uses an inner fast current control loop and an outer slow voltage correcting loop for both the grid side VSI and the ultracapacitor converter. Simulation results are presented in the support of effectiveness of the proposed technique. A prototype is developed with the available 1.5kW PV installation, 1.2kW emulated wind turbine and ultracapacitor bank to validate some aspect of the proposed strategy.
太阳能光伏发电和风力发电的间歇性互补特性为光伏/风力混合发电系统的研究开辟了新的领域。本文提出了一种控制功率调节单元的新策略,以最大限度地减少光伏和风力涡轮机混合系统对输出功率的干扰,尽管这些源具有高度间歇性。建议的方案平衡了风力和/或光伏系统产生的巨大变化,并为连接到系统的其他来源(例如水力,蒸汽涡轮机等)提供足够的余量来接管,从而在整个运行过程中保持功率平衡。该策略利用高能量密度的超级电容器来吸收间歇性太阳辐射和大变化风速的影响。与这些源相关联的MPPT不受影响,也不会妨碍系统的总体发电。风电场传统背靠背拓扑的直流链路与带有MPPT跟踪器的光伏板集成在一起。该控制策略对电网侧VSI和超级电容变换器都采用了内部快速电流控制环和外部慢速电压校正环。仿真结果验证了该方法的有效性。开发了一个原型,其中包括可用的1.5kW光伏装置,1.2kW模拟风力涡轮机和超级电容器组,以验证所提出策略的某些方面。
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引用次数: 18
Defect band luminescence intensity reversal as related to application of anti-reflection coating on mc-Si PV Cells 在mc-Si光伏电池上应用增透涂层的缺陷带发光强度反转
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6317606
H. Guthrey, S. Johnston, Fei Yan, B. Gorman, M. Al‐Jassim
Photoluminescence (PL) imaging is widely used to identify defective regions within mc-Si PV cells. Recent PL imaging investigations of defect band luminescence (DBL) in mc-Si have revealed a perplexing phenomenon. Namely, the reversal of the DBL intensity in various regions of mc-Si PV material upon the application of a SiNx:H anti-reflective coating (ARC). Regions with low DBL intensity before ARC application often exhibit high DBL intensity afterwards, and the converse is also true. PL imaging alone cannot explain this effect. We have used high resolution cathodoluminescence (CL) spectroscopy and electron beam induced current (EBIC) techniques to elucidate the origin of the DBL intensity reversal. Multiple sub-bandgap energy levels were identified that change in peak position and intensity upon the application of the ARC. Using this data, in addition to EBIC contrast information, we provide an explanation for the DBL intensity reversal based on the interaction of the detected energy levels with the SiNx:H ARC application. Multiple investigations have suggested that this is a global problem for mc-Si PV cells. Our results have the potential to provide mc-Si PV producers a pathway to increased efficiencies through defect mitigation strategies.
光致发光(PL)成像被广泛用于识别mc-Si光伏电池中的缺陷区域。最近对mc-Si中缺陷带发光(DBL)的PL成像研究揭示了一个令人困惑的现象。即,应用SiNx:H抗反射涂层(ARC)后,mc-Si PV材料各区域DBL强度的反转。应用ARC前DBL强度较低的区域,应用ARC后DBL强度往往较高,反之亦然。光靠PL成像无法解释这种效应。我们利用高分辨率阴极发光(CL)光谱和电子束感应电流(EBIC)技术来阐明DBL强度反转的起源。发现了多个子带隙能级,在电弧的作用下,其峰值位置和强度都发生了变化。利用这些数据,除了EBIC对比信息外,我们还提供了基于探测能级与SiNx:H ARC应用相互作用的DBL强度反转的解释。多项研究表明,这是mc-Si光伏电池的一个全球性问题。我们的研究结果有可能为mc-Si光伏生产商提供一条通过缺陷缓解策略提高效率的途径。
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引用次数: 1
期刊
2012 38th IEEE Photovoltaic Specialists Conference
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