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2012 38th IEEE Photovoltaic Specialists Conference最新文献

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A study of thermal, voltage, and photoinduced effects on the external quantum efficiency of CuInGaSe2 (CIGS) photovoltaic devices 热、电压和光致效应对CuInGaSe2 (CIGS)光电器件外量子效率的影响研究
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6317832
R. Feist, M. Mills, R. K. Thompson, N. Ramesh
The purpose of this study was to assess the performance of CuInGaSe2 (CIGS) solar cells ranging from 6.9-11.2% efficiency to identify means of improving device performance. One of the main drivers for this work was to take an independent look at elevated operating temperatures associated with BIPV products like Dow's POWERHOUSE™ shingle system for performance differences as a function of system operating temperature independent of increasing efficiency to help future product definition. For three of the four samples we observed a clear lack of dark-light current-voltage (JV) superposition and correspondingly via external quantum efficiency (EQE) measurements an electrical field dependent carrier collection response in the blue regime. By inference this performance indicates the presence of impurities in the device, likely in the CdS film that could present an opportunity to further improve the CIGS device performance.
本研究的目的是评估效率在6.9-11.2%之间的CuInGaSe2 (CIGS)太阳能电池的性能,以确定提高器件性能的方法。这项工作的主要推动力之一是独立研究BIPV产品(如陶氏POWERHOUSE瓦板系统)的工作温度升高,以了解系统工作温度与效率无关的性能差异,从而帮助未来的产品定义。对于四个样品中的三个,我们观察到明显缺乏暗-光电流-电压(JV)叠加,相应地,通过外部量子效率(EQE)测量,在蓝色状态下存在电场依赖的载流子收集响应。通过推断,该性能表明器件中存在杂质,可能存在于CdS薄膜中,这可能为进一步提高CIGS器件性能提供了机会。
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引用次数: 0
Synthesis and optical properties of ZnTe1−xOx highly mismatched alloys for intermediate band solar cells ZnTe1−xOx中间波段太阳电池高失配合金的合成及光学性能
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6317579
T. Tanaka, T. Mochinaga, K. Saito, Q. Guo, M. Nishio, K. Yu, W. Walukiewicz
Highly mismatched ZnTe1-xOx (ZnTeO) alloys have been grown by molecular beam epitaxy. X-ray diffraction (XRD) analyses showed that a single-phase ZnTeO layer were grown with a substitutional O composition x up to 1.34% on ZnTe(001) substrate in this experiments. Optical transitions associated with the lower (E-) and upper (E+) conduction subbands resulting from the anticrossing interaction between the localized O states and the extended conduction states of ZnTe were clearly observed, and the dependence of the energy position of these bands on the O composition was consistent with the band anticrossing model. The photovoltaic activities of solar cells using ZnTeO layers are also reported.
采用分子束外延的方法制备了高度失配的ZnTe1-xOx (ZnTeO)合金。x射线衍射(XRD)分析表明,在ZnTe(001)衬底上生长出了取代O含量高达1.34%的单相ZnTeO层。在ZnTe的局域O态和扩展O态之间的反交相互作用下,清晰地观察到与下(E-)和上(E+)导子带相关的光学跃迁,并且这些能带的能量位置与O组成的依赖关系与能带反交模型一致。本文还报道了使用ZnTeO层的太阳能电池的光电活性。
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引用次数: 0
IEA PVPS Task8: Study on Very Large Scale Photovoltaic (VLS-PV) Systems 国际能源署PVPS任务8:超大规模光伏(VLS-PV)系统研究
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6317938
K. Komoto, E. Cunow, C. Breyer, D. Faiman, K. Megherbi, P. van der Vleuten
The purpose of IEA PVPS Task8, Study on Very Large Scale Photovoltaic (VLS-PV) Systems, is to examine and evaluate the potential and feasibility of VLS-PV systems, which have capacities ranging from several megawatts to gigawatts, and to develop strategies for implementation of the VLS-PV systems in the future. Our study has comprehensively analyzed the major issues involved in such large scale applications, based on the latest scientific and technological developments and by means of close international co-operation with experts from different countries. Solar power plants in desert regions increasingly count as a realistic energy option. Very Large Scale solar power plants start to appear around the world. In order to accelerate the current transition towards renewable energy, development of VLS-PV power generation systems that can be deployed on a massive scale is one of the ways for this transformation. This paper will present an overview of relevant issues and the potential of VLS-PV, guidelines for VLS-PV systems, and technical as well as strategic options for implementing VLS-PV.
国际能源署PVPS任务8“超大规模光伏(VLS-PV)系统研究”的目的是研究和评估VLS-PV系统的潜力和可行性,这些系统的容量从几兆瓦到千兆瓦不等,并制定未来实施VLS-PV系统的战略。我们的研究以最新的科学和技术发展为基础,通过与不同国家专家的密切国际合作,全面分析了这种大规模应用所涉及的主要问题。沙漠地区的太阳能发电厂日益成为一种现实的能源选择。世界各地开始出现大规模的太阳能发电厂。为了加速当前向可再生能源的过渡,开发可大规模部署的VLS-PV发电系统是这种转变的途径之一。本文将概述VLS-PV的相关问题和潜力,VLS-PV系统的指导方针,以及实施VLS-PV的技术和战略选择。
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引用次数: 7
Silver ink experiments for silicon solar cell metallization by flexographic process 柔性版工艺制备硅太阳能电池金属化银墨实验
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6318049
S. Thibert, D. Chaussy, D. Beneventi, N. Reverdy-Bruas, J. Jourdan, B. Bechevet, S. Mialon
The metallization of silicon solar cells becomes more and more critical due to the recent soaring prices of silver. Flexographic printing can be used to deposit the seed layer in a “seed and plate” scheme to replace screen printing, classically employed in production lines but limited by its resolution. To develop the process, several inks prepared from standard screen printing paste were tested. First, different rheological experiments were performed. Then the different inks were printed on silicon solar cells and a correlation was pointed out between rheological properties and printing results. The present work demonstrates that flexography is a potential candidate to deposit silver seed layer with a width as low as 30 μm with a printing speed of 0.5 m/s. Moreover the importance of rheological experiments during a printing process development is underlined.
由于最近银价的飙升,硅太阳能电池的金属化变得越来越重要。柔版印刷可用于将种子层沉积在“种子和版”方案中,以取代丝网印刷,丝网印刷通常用于生产线,但受其分辨率限制。为了开发该工艺,对几种由标准丝网印刷浆料制备的油墨进行了测试。首先,进行不同的流变实验。然后在硅太阳能电池上印刷不同的油墨,并指出其流变性能与印刷效果之间的相关性。本研究表明,柔性版印刷是一种潜在的候选方法,可以在0.5 m/s的印刷速度下沉积宽度低至30 μm的银种子层。此外,流变实验在印刷工艺开发中的重要性被强调。
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引用次数: 13
Fabrication of site specific amorphous/nanocrystalline silicon composite thin film for solar cells 太阳能电池专用非晶/纳米晶硅复合薄膜的制备
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6317822
B. Newton, Abu H. Safe, M. Benemara, S. Yu, H. Naseem
The absorption properties of amorphous silicon (α-Si) and the electron transport properties of nanocrystalline silicon are combined in a novel composite material for thin film silicon solar cells. In this work a composite film composed of α-Si with site specific areas of nanocrystalline material was created. Al was deposited through a SiO2 template containing nanometer sized apertures with an approximate diameter of 250 nm onto an α-Si film supported by a <;100>; crystalline silicon substrate. It was then annealed at 350°C. The annealing caused crystallization only at sites where the Al was in contact with the α-Si surface. The AIC created site specific three dimensional nanocrystalline structures embedded in a thin film of α-Si. After grain boundary passivation these nanocrystalline sites will provide pathways for charge carriers that are less defect dense than the α-Si film. TEM samples were fabricated from the composite film utilizing the focus ion beam. The growth characteristics of these 3D nanostructures and the α-Si thin film were characterized utilizing ESEM and the TEM.
将非晶硅(α-Si)的吸收特性和纳米晶硅的电子输运特性结合在一起,制备了一种新型薄膜硅太阳电池复合材料。本文制备了一种由α-Si和纳米晶材料的特定区域组成的复合薄膜。Al通过含有纳米孔径(直径约250 nm)的SiO2模板沉积在α-Si薄膜上;晶体硅衬底。然后在350℃下退火。退火只在Al与α-Si表面接触的部位产生结晶。AIC在α-Si薄膜中嵌入了特定位点的三维纳米晶体结构。晶界钝化后,这些纳米晶位将为缺陷密度小于α-Si薄膜的载流子提供通道。利用聚焦离子束制备了TEM样品。利用ESEM和TEM对三维纳米结构和α-Si薄膜的生长特性进行了表征。
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引用次数: 1
Analysis of the energy structure of nitrogen δ-doped GaAs superlattices for high efficiency intermediate band solar cells 高效中间带太阳能电池中氮掺杂GaAs超晶格的能量结构分析
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6317573
S. Noguchi, S. Yagi, Y. Hijikata, K. Onabe, S. Kuboya, H. Yaguchi
Nitrogen δ-doped GaAs superlattices were fabricated and their energy structures were investigated. Several transitions related to E+ band of nitrogen δ-doped regions were observed in photoreflectance (PR) spectra at energies ranging 1.5-1.7 eV for the superlattices at which no transitions were observed for uniformly doped GaAsN. The PR signal intensity of E+ related band transitions is significantly higher than those observed in uniformly doped GaAsN. This enhancement of E+ related band transitions is advantageous as an intermediate band material, and thus, nitrogen δ-doped GaAs superlattice structures are expected to be an excellent alternative for the use of intermediate band solar cells.
制备了氮掺杂GaAs超晶格,并对其能量结构进行了研究。对于均匀掺杂的GaAsN,在1.5 ~ 1.7 eV的超晶格光反射率(PR)光谱中观察到与氮δ掺杂区E+带相关的几个跃迁,而没有观察到跃迁。E+相关带跃迁的PR信号强度明显高于均匀掺杂的GaAsN。这种E+相关带跃迁的增强作为中间带材料是有利的,因此,氮δ掺杂GaAs超晶格结构有望成为中间带太阳能电池的一种极好的替代品。
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引用次数: 1
20.3% efficiency rear passivated silicon solar cells with local back contact using commercial P-Cz wafers 20.3%效率的后钝化硅太阳能电池,采用商业P-Cz晶圆
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6317806
Zhenjiao Wang, P. Han, Qinglei Meng, H. Qian, Jiaqi Wu, Yongfei Jiang, N. Tang, Hongyan Lu, Haidong Zhu, Rulong Chen, P. Yang, J. Ji, Zhengrong Shi, A. Sugianto, S. Wenhem
In this paper, progress results on the next generation Pluto technology were reported. In the next generation Pluto, we focused on the rear surface design, by improvement of the back internal reflection and passivation we got 20.3% cell efficiency with very high Jsc. Still there is further improvement of the cell design to get high FF and Eff.
本文综述了新一代冥王星探测技术的研究进展。在下一代Pluto中,我们将重点放在后表面设计上,通过改进后内反射和钝化,使电池效率达到20.3%,Jsc非常高。为了获得更高的FF和Eff,还需要进一步改进电池的设计。
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引用次数: 0
System performance analysis and estimation of degradation rates based on 500 years of monitoring data 基于500年监测数据的系统性能分析与退化率估计
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6317890
N. Reich, A. Goebel, D. Dirnberger, K. Kiefer
Fraunhofer ISE has been involved in monitoring of PV systems since the “1000-roofs-program” in the 1990s. In a few of these “old systems” equipment is still in place, metering PV electricity output and plane-of-array irradiation. The majority of ~300 PV power plants in our monitoring campaign today, however, is large-scale and built in the past 10 years. In this paper, we briefly review the historical development of the Performance Ratio (PR) and how average PR for newly built systems increased to almost 90%. This rather high PR of 90% only holds, however, if calculated by on-site irradiation acquired with c-Si reference cells and for climates comparable with those in Germany. Next, we use about 500 years of monitoring data on aggregate to perform an analysis of variations of the PR over time. To this end, data points at similar environmental conditions are extracted from long-term time series as to calculate so-called “rates-of-change” of the PR. Highly scattered “rates-of-change” are obtained, however, not allowing for the estimation of specific degradation rates on the system level yet. To this end, we finally revisit uncertainties of irradiance sensors and in particular revisit our irradiance sensor re-calibration data.
自20世纪90年代的“1000屋顶计划”以来,Fraunhofer ISE一直参与光伏系统的监测。在这些“旧系统”中,有一些设备仍然存在,用于测量光伏发电输出和面阵辐射。然而,在我们今天监测的约300个光伏电站中,大多数是在过去10年建成的大型光伏电站。在本文中,我们简要回顾了性能比(PR)的历史发展,以及新建系统的平均PR如何增加到近90%。然而,这个相当高的90%的PR只有在与德国相当的气候条件下,通过使用c-Si参考电池获得的现场辐照计算才成立。接下来,我们使用大约500年的总体监测数据来执行PR随时间变化的分析。为此,从长期时间序列中提取类似环境条件下的数据点,以计算PR的所谓“变化率”。然而,获得的“变化率”是高度分散的,但还不能估计系统层面上的具体退化率。为此,我们最后重温辐照度传感器的不确定度,特别是重温我们的辐照度传感器重新校准数据。
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引用次数: 12
Design of metamorphic dual-junction InGaP/GaAs solar cell on Si with efficiency greater than 29% using finite element analysis 利用有限元分析设计效率大于29%的变质双结InGaP/GaAs硅基太阳能电池
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6318003
N. Jain, M. Hudait
Heterogeneous integration of multijunction III-V solar cells on Si is a promising solution for the widespread commercialization of III-V cells. However, the polar on non-polar epitaxy and 4% lattice-mismatch between GaAs and Si results in formation of defects and dislocations, which can significantly impede the minority carrier lifetime and hence the cell performance. We have investigated the impact of threading dislocation density on the performance of dual-junction (2J) n+/p InGaP/GaAs solar cells on Si. Using our calibrated model, the metamorphic 2J cell on Si was optimized by tailoring the 2J cell design on Si to achieve current-matching between the subcells at a realistic threading dislocation density of 106 cm-2. We present a novel 2J InGaP/GaAs cell design on Si at a threading dislocation density of 106 cm-2 which exhibited a theoretical conversion efficiency of greater than 29% at AM1.5G spectrum, indicating a path for viable III-V multijunction cell technology on Si.
多结III-V太阳能电池在硅上的异质集成是III-V电池广泛商业化的一个有前途的解决方案。然而,GaAs和Si之间的极性和非极性外延以及4%的晶格错配导致了缺陷和位错的形成,这严重影响了少数载流子寿命,从而影响了电池的性能。我们研究了螺纹位错密度对硅基双结(2J) n+/p InGaP/GaAs太阳能电池性能的影响。利用我们的校准模型,通过调整Si上的2J电池设计,优化了硅上变质2J电池,实现了亚电池之间在106 cm-2的实际螺纹位错密度下的电流匹配。我们提出了一种新颖的2J InGaP/GaAs电池设计,在106 cm-2的线位错密度下,在AM1.5G光谱下的理论转换效率大于29%,为Si上的III-V多结电池技术指明了一条可行的道路。
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引用次数: 5
Simulation guided design of flexible photovoltaic laminates 柔性光伏板的仿真指导设计
Pub Date : 2012-06-03 DOI: 10.1109/PVSC.2012.6317978
S. Athreya, R. Sharma, K. Kauffmann, L. López, Jie Feng
Photovoltaic (PV) modules are manufactured using various PV cell technologies. The packaging requirements vary for each of the PV technologies and depend on their inherent thermo-mechanical properties and environmental stability of the cell. Thin film PV has the relative advantage of flexibility vis-à-vis their rigid and brittle competitors. This paper discusses the use of Finite Element Analysis (FEA) to develop a framework for guiding the design of flexible Building Integrated Photovoltaic (BIPV) shingles utilizing thin film PV cells. Microglass (0.2-0.3 mm thick glass) was chosen as the top barrier layer to exploit the flexibility of the thin film PV material. However, microglass alone does not provide sufficient protection to the shingle to meet regulatory impact resistance requirements. This paper discusses the use of FEA to guide the selection of reinforcing polymer layers and their placement around the microglass to enable microglass-based flexible laminates to sustain hail impact. FEA was used to guide the selection of reinforcing polymers and their placement in the laminate structure. Hail impact was modeled as static indentation and stresses were calculated in all layers of the laminate. This model was used to compare around 50 laminates generated through systematic variation of the polymer mechanical properties and laminate designs. Based on the analysis of the stresses generated in the microglass and other layers in these laminates, it is found that the optimal laminate design would consist of an elastomeric reinforcing layer above the microglass and a rigid polymer layer below it. An additional layer of a rigid polymer above the elastomeric layer can further reduce stresses in the laminate; however, relatively large thickness of this layer might be needed to get any significant stress reduction. The ideal location for the rigid reinforcing layer has been identified to be between the cell and the bottom barrier layer. The model predictions have been partially validated through hail impact testing.
光伏(PV)模块是使用各种光伏电池技术制造的。每种光伏技术的封装要求各不相同,并取决于其固有的热机械性能和电池的环境稳定性。相对于-à-vis刚性和脆性的竞争对手,薄膜光伏具有相对的灵活性优势。本文讨论了使用有限元分析(FEA)来开发一个框架,用于指导利用薄膜光伏电池的柔性建筑集成光伏(BIPV)瓦的设计。选择微玻璃(0.2-0.3 mm厚的玻璃)作为顶部阻挡层,以利用薄膜PV材料的柔韧性。然而,微玻璃本身并不能为瓦板提供足够的保护,以满足法规的抗冲击要求。本文讨论了利用有限元分析来指导增强聚合物层的选择及其在微玻璃周围的放置,以使微玻璃基柔性层压板能够承受冰雹的冲击。采用有限元分析方法指导增强聚合物的选择及其在层压板结构中的位置。冰雹冲击建模为静态压痕,并计算了层压板各层的应力。该模型用于比较大约50种通过系统改变聚合物力学性能和层压板设计而产生的层压板。通过对微玻璃层和其他层的应力分析,发现最优的层压板设计是在微玻璃层上加一层弹性增强层,在其下加一层刚性聚合物层。在弹性体层之上的另一层刚性聚合物可以进一步减小层压板中的应力;然而,相对较大的厚度的这一层可能需要得到任何显著的应力降低。已确定刚性增强层的理想位置是在单元和底部阻隔层之间。模型预测已通过冰雹冲击试验得到部分验证。
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引用次数: 1
期刊
2012 38th IEEE Photovoltaic Specialists Conference
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